SAFETY DATA SHEET JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT

Conforms to HazCom 2012/United States SAFETY DATA SHEET JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT

Section 1. Identification GHS product identifier : JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT EPA Registration No. : 8254-5-56 EPA Label Content : See attached EPA Label Content in this PDF (Click icon on left end side of this page). Product code : 666N Other means of : Polybutene identification Product type : Liquid.

Identified uses Repellent.

Supplier's details : J.T. EATON & CO., INC. 1393 East HIGHLAND Road TWINSBURG, OH 44087 U.S.A. Tel: 330-425-7801 Toll Free: 800-321-3421 Web site: www.jteaton.com

Emergency telephone : 1-800-664-9042 or N.P.I.C. 1-800-858-7378 number (with hours of 8:30 am to 5:00 pm EST operation) Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : SKIN CORROSION/IRRITATION - Category 2 substance or mixture ASPIRATION HAZARD - Category 1

GHS label elements Hazard pictograms :

Signal word : Danger Hazard statements : Causes skin irritation. May be fatal if swallowed and enters airways. Precautionary statements Prevention : Wear protective gloves. Wash hands thoroughly after handling. Response : IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. Storage : Store locked up.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 1/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 2. Hazards identification Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of : Polybutene identification

CAS number/other identifiers CAS number : Not applicable. Product code : 666N Ingredient name % CAS number Butene, homopolymer 60 - 100 9003-29-6

Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Skin contact : Flush contaminated skin with plenty of water. Continue to rinse for at least 20 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 2/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 4. First aid measures Skin contact : Causes skin irritation. Ingestion : May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation : No known significant effects or critical hazards. Skin contact : Adverse symptoms may include the following: irritation redness Ingestion : Adverse symptoms may include the following: nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media

Specific hazards arising : No specific fire or explosion hazard. from the chemical Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide

Special protective actions : No special measures are required. for fire-fighters Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate personnel respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 3/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up Spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials incompatibilities (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation.

Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 4/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 8. Exposure controls/personal protection Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : Liquid. [Gel.] Color : Colorless. Odor : Petroleum. [Slight] Odor threshold : Not available. pH : Not available. Melting point : Not available. Boiling point : Not available. Flash point : Closed cup: >192.22°C (>378°F) [Pensky-Martens.] Evaporation rate : Negligible. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : Not available. Vapor density : Not available. Relative density : 0.89 Solubility : <1% Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 5/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions

Conditions to avoid : No specific data.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity There is no data available. Irritation/Corrosion There is no data available. Sensitization There is no data available. Carcinogenicity There is no data available. Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure) There is no data available. Aspiration hazard Name Result Butene, homopolymer ASPIRATION HAZARD - Category 1

Information on the likely : Dermal contact. Eye contact. Inhalation. routes of exposure Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : Causes skin irritation. Ingestion : May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation watering redness

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 6/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 11. Toxicological information Inhalation : No known significant effects or critical hazards. Skin contact : Adverse symptoms may include the following: irritation redness Ingestion : Adverse symptoms may include the following: nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Potential chronic health effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates There is no data available.

Section 12. Ecological information Toxicity There is no data available.

Persistence and degradability There is no data available.

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential Butene, homopolymer 7.6 to 7.8 314 to 1882 high

Mobility in soil Soil/water partition : There is no data available. coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 7/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information

DOT Classification IMDG IATA

UN number Not regulated. Not regulated. Not regulated.

UN proper - - shipping name

Transport - - - hazard class(es)

Packing group - - - Environmental No. No. No. hazards

Additional - - - information AERG : Not applicable.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according : Not available. to Annex II of MARPOL 73/78 and the IBC Code Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.

Clean Air Act Section 112 : Not listed (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 : Not listed Class I Substances

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 8/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 15. Regulatory information Clean Air Act Section 602 : Not listed Class II Substances DEA List I Chemicals : Not listed (Precursor Chemicals) DEA List II Chemicals : Not listed (Essential Chemicals) SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Immediate (acute) health hazard Composition/information on ingredients Name % Fire Sudden Reactive Immediate Delayed hazard release of (acute) (chronic) pressure health health hazard hazard Butene, homopolymer 60 - 100 No. No. No. Yes. No.

State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : None of the components are listed. Pennsylvania : None of the components are listed. California Prop. 65 No products were found. International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 9/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com JT EATON TRANSPARENT 4 the Birds® BIRD REPELLENT Section 16. Other information History Date of issue mm/dd/yyyy : 12/15/2014 Date of previous issue : 02/15/2014 Version : 1.1 Revised Section(s) : 1, 16 Prepared by : KMK Regulatory Services Inc. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) 10/10 www.kmkregservices.com www.askdrluc.com www.ghssmart.com Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013

1. PRODUCT IDENTIFICATION

Product identifier on label: ADVION COCKROACH BAIT ARENA Product No.: A20378A Use: Insecticide Manufacturer: Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

2. HAZARDS IDENTIFICATION

Classifications: Skin Sensitizer: Category 1B Signal Word (OSHA): Warning

Hazard Statements: May cause an allergic skin reaction

Hazard Symbols:

Precautionary Statements: Avoid breathing dust. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves, protective clothing, eye protection. If on skin: Wash with plenty of soap and water. See Section 4 First Aid Measures. If skin irritation or rash occurs: Get medical advice. Wash contaminated clothing before reuse. Dispose of contents and container in accordance with local regulations.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Common Name CAS Number Concentration Other inert ingredients Other inert ingredients Not Applicable 99.5% methyl (4aS)-7-chloro-2,5-dihydro-2- Indoxacarb Technical 173584-44-6 0.5% [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]in deno[1,2-e][1,3,4]oxadiazine-4a(3H)- carboxylate

Page 1 of 7 Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013 Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

4. FIRST AID MEASURES

Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.

Ingestion: If swallowed: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Eye Contact: If in eyes: Rinse eyes with water. First aid measures are not normally required. If concerned, call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: First aid measures are not normally required. Wash material from the skin. If concerned, call Syngenta (800-888-8372), a poison control center or doctor for treament advice. Inhalation: If inhaled: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Most important symptoms/effects: Allergic skin reaction

Indication of immediate medical attention and special treatment needed: There is no specific antidote if this product is ingested. Treat symptomatically. Persons suffering a temporary allergic reaction may respond to treatment with antihistamines or steroid creams and/or systemic steroids.

5. FIRE FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media: Use dry chemical, foam or CO2 extinguishing media. Specific Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.

Special protective equipment and precautions for firefighters: Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8.

Methods and materials for containment and cleaning up: Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.

Page 2 of 7 Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013 7. HANDLING AND STORAGE

Precautions for safe handling: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Conditions for safe storage, including any incompatibilities: Not Applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL.

Occupational Exposure Limits:

Chemical Name OSHA PEL ACGIH TLV Other Source

Other inert ingredients Not Applicable Not Applicable Not Applicable Not Applicable

Indoxacarb Technical Not Established Not Established 1 mg/m³ 8hr & 12hr Manufacturer TWA (respirable)

Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures:

Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely use dust-proof chemical goggles.

In case of emergency spills, use a NIOSH approved respirator with any N, R, P or HE filter.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Brown gel/paste Odor: Characteristic/bland Odor Threshold: Not Available pH: 6.6 Melting point/freezing point: Not Available Initial boiling point and boiling range: Not Available

Page 3 of 7 Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013 Flash Point (Test Method): Not Available Flammable Limits (% in Air): Not Available Flammability: Not Available

Vapor Pressure: Indoxacarb Technical Not Available Vapor Density: Not Available Relative Density: 1.09 g/ml @ 72°F (22°C) Solubility (ies): Indoxacarb Technical Not Available

Partition coefficient: n-octanol/water: Not Available Autoignition Temperature: Not Available

Decomposition Temperature: Not Available Viscosity: Not Available Other: Not Available

10. STABILITY AND REACTIVITY

Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur.

Conditions to Avoid: None known

Incompatible materials: None known

Hazardous Decomposition Products: Not Available

11. TOXICOLOGICAL INFORMATION

Health effects information Likely routes of exposure: Dermal

Symptoms of exposure: Rash, redness or itching

Delayed, immediate and chronic effects of exposure: Allergic skin reaction

Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Rat) : > 5000 mg/kg body weight

Dermal: Dermal (LD50 Rat) : > 5000 mg/kg body weight

Inhalation: Inhalation (LC50 Rat) : Not Available

Eye Contact: Non-Irritating (Rabbit)

Skin Contact: Non-Irritating (Rabbit)

Skin Sensitization: A skin sensitizer (Guinea Pig)

Page 4 of 7 Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013

Reproductive/Developmental Effects Indoxacarb Technical: Animal testing showed effects on reproduction at levels equal to or above those causing parental toxicity. Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Chronic/Subchronic Toxicity Studies Indoxacarb Technical: The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Inhalation; rat; Incoordination, mortality, red blood cell destruction causing abnormal decrease in number of red blood cells (anemia) Carcinogenicity Indoxacarb Technical: Animal testing did not show any carcinogenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Did not cause genetic damage in animals.

Chemical Name NTP/IARC/OSHA Carcinogen Other inert ingredients No methyl (4aS)-7-chloro-2,5-dihydro-2- No [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]inden o[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate

Other Toxicity Information None Toxicity of Other Components Other inert ingredients Not Applicable

Target Organs Active Ingredients Indoxacarb Technical: Nervous system Inert Ingredients Other inert ingredients: Not Applicable

12. ECOLOGICAL INFORMATION

Eco-Acute Toxicity Indoxacarb Technical: Fish (Rainbow Trout) 96-hour LC50 0.65 mg/l Bird (Bobwhite Quail) LD50 Oral 98 mg/kg Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.60 mg/l

Environmental Fate Indoxacarb Technical: Information given is based on data on the components and the ecotoxicology of similar products. Environmental Hazards: Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark.

Page 5 of 7 Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013 13. DISPOSAL CONSIDERATIONS

Disposal: Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste: Not Applicable Listed Waste: Not Applicable

14. TRANSPORT INFORMATION

DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Not regulated

Air Transport Not regulated

15. REGULATORY INFORMATION

EPA Registration Number(s): 100-1486 EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Acute Health Hazard

Section 313 Toxic Chemicals: None

California Proposition 65: Not Applicable

CERCLA/SARA 304 Reportable Quantity (RQ): Not Applicable RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA

Page 6 of 7 Safety Data Sheet

ADVION COCKROACH BAIT ARENA Date: 3/18/2014 Replaces: 11/1/2013 16. OTHER INFORMATION

NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 2 Health: 2 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme Syngenta Hazard Category: C,S

For non-emergency questions about this product call:

1-800-334-9481

Original Issued Date: 5/1/2013 Revision Date: 3/18/2014 Replaces: 11/1/2013 Section(s) Revised: 1 - 16 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

Page 7 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013

1. PRODUCT IDENTIFICATION

Product identifier on label: ADVION COCKROACH GEL BAIT Product No.: A20379A Use: Insecticide Manufacturer: Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

2. HAZARDS IDENTIFICATION

Classifications: Skin Sensitizer: Category 1B Signal Word (OSHA): Warning

Hazard Statements: May cause an allergic skin reaction

Hazard Symbols:

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Common Name CAS Number Concentration Other inert ingredients Other inert ingredients Not Applicable 99.4% methyl (4aS)-7-chloro-2,5-dihydro-2- Indoxacarb Technical 173584-44-6 0.6% [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]in deno[1,2-e][1,3,4]oxadiazine-4a(3H)- carboxylate

Page 1 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013 Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

4. FIRST AID MEASURES

Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.

5. FIRE FIGHTING MEASURES

Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8.

Page 2 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013 7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities: Not Applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:

Chemical Name OSHA PEL ACGIH TLV Other Source

Other inert ingredients Not Applicable Not Applicable Not Applicable Not Applicable

Indoxacarb Technical Not Established Not Established 1 mg/m³ 8hr & 12hr Manufacturer TWA (respirable)

Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures:

In case of emergency spills, use a NIOSH approved respirator with any N, R, P or HE filter.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Yellow gel Odor: None Odor Threshold: Not Available pH: 6.08 Melting point/freezing point: Not Available Initial boiling point and boiling range: Not Available

Page 3 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013 Flash Point (Test Method): Not Available Flammable Limits (% in Air): Not Available Flammability: Not Available

Vapor Pressure: Indoxacarb Technical Not Available Vapor Density: Not Available Relative Density: 1.0755 g/ml @ 68°F (20°C) Solubility (ies): Indoxacarb Technical Not Available

Partition coefficient: n-octanol/water: Not Available Autoignition Temperature: Not Available

Decomposition Temperature: Not Available Viscosity: Not Available Other: Not Available

10. STABILITY AND REACTIVITY

Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur.

Conditions to Avoid: None known

Incompatible materials: None known

Hazardous Decomposition Products: Not Available

11. TOXICOLOGICAL INFORMATION

Health effects information Likely routes of exposure: Dermal

Symptoms of exposure: Rash, redness or itching

Delayed, immediate and chronic effects of exposure: Allergic skin reaction

Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Rat) : > 5000 mg/kg body weight

Dermal: Dermal (LD50 Rat) : > 5000 mg/kg body weight

Inhalation: Inhalation (LC50 Female > 5.5 mg/l air - 4 hours Rat) :

Eye Contact: Non-Irritating (Rabbit)

Skin Contact: Non-Irritating (Rabbit)

Skin Sensitization: A skin sensitizer (Guinea Pig)

Page 4 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013

Other Toxicity Information None Toxicity of Other Components Other inert ingredients Not Applicable

Target Organs Active Ingredients Indoxacarb Technical: Nervous system Inert Ingredients Other inert ingredients: Not Applicable

12. ECOLOGICAL INFORMATION

Eco-Acute Toxicity Indoxacarb Technical: Fish (Rainbow Trout) 96-hour LC50 0.65 mg/l Bird (Bobwhite Quail) LD50 Oral 98 mg/kg Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.60 mg/l

Page 5 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Not regulated

Air Transport Not regulated

15. REGULATORY INFORMATION

Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: Caution: Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

EPA Registration Number(s): 100-1484 EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Acute Health Hazard

Section 313 Toxic Chemicals: None

California Proposition 65: Not Applicable

CERCLA/SARA 304 Reportable Quantity (RQ): Not Applicable RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA

Page 6 of 7 Safety Data Sheet

ADVION COCKROACH GEL BAIT Date: 3/17/2014 Replaces: 11/1/2013 16. OTHER INFORMATION

For non-emergency questions about this product call:

1-800-334-9481

Original Issued Date: 2/25/2013 Revision Date: 3/17/2014 Replaces: 11/1/2013 Section(s) Revised: 1 - 16 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

Page 7 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015

1. PRODUCT IDENTIFICATION

Product identifier on label: ARILON® Product No.: A20382A Use: Insecticide Manufacturer: Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

2. HAZARDS IDENTIFICATION

Classifications: Oral: Category 4 Inhalation: Category 4 Specific Target Organ Toxicity: Repeated Category 1 Signal Word (OSHA): Danger

Hazard Statements: Harmful if swallowed Harmful if inhaled Causes damage to organs through prolonged or repeated exposure

Hazard Symbols:

Precautionary Statements: Do not breathe mist, vapors, spray. Wash hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. If swallowed: Call a poison center, doctor or Syngenta if you feel unwell. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center, doctor or Syngenta if you feel unwell. Dispose of contents and container in accordance with local regulations.

Other Hazard Statements: May form combustible dust concentrations in air.

Page 1 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Common Name CAS Number Concentration Other ingredients Other ingredients Trade Secret 80% methyl (4aS)-7-chloro-2,5-dihydro-2- Indoxacarb Technical 173584-44-6 20% [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]in deno[1,2-e][1,3,4]oxadiazine-4a(3H)- carboxylate

Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

4. FIRST AID MEASURES

Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.

Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888- 8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Inhalation: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Most important symptoms/effects: Not Applicable

Indication of immediate medical attention and special treatment needed: There is no specific antidote if this product is ingested. Treat symptomatically.

5. FIRE FIGHTING MEASURES

Suitable (and unsuitable) extinguishing media: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. Specific Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.

Page 2 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8.

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities: Not Applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:

Chemical Name OSHA PEL ACGIH TLV Other Source

Other ingredients Not Applicable Not Applicable Not Applicable Not Applicable

Indoxacarb Technical Not Established Not Established 1 mg/m³ 8hr & 12hr Manufacturer TWA (respirable)

Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures:

Skin Contact: Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant footwear. Inhalation: A particulate filter respirator may be necessary until effective engineering controls are installed to comply with occupational exposure limits. Use NIOSH certified respirator with any N, R, P or HE filter. Use a self-contained breathing apparatus in

Page 3 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015 cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Light tan to white granules Odor: Slight Odor Threshold: Not Available pH: 8.1 - 9.1 Melting point/freezing point: Not Available Initial boiling point and boiling range: Not Available Flash Point (Test Method): Not Available Flammable Limits (% in Air): Not Available Flammability: Not Available

Vapor Pressure: Indoxacarb Technical Not Available Vapor Density: Not Available Relative Density: 0.50 - 0.70 g/ml Bulk density (tapped) Solubility (ies): Indoxacarb Technical Not Available

Partition coefficient: n-octanol/water: Not Available

Autoignition Temperature: Not Available

Decomposition Temperature: Not Available

Viscosity: Not Available Other: None

10. STABILITY AND REACTIVITY

Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur.

Conditions to Avoid: Not Available

Incompatible materials: None known.

Hazardous Decomposition Products: Not Available 11. TOXICOLOGICAL INFORMATION

Health effects information Likely routes of exposure: Dermal, Inhalation

Symptoms of exposure: Not Applicable

Delayed, immediate and chronic effects of exposure: Not Applicable

Page 4 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015 Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Rat) : 1909 mg/kg body weight

Dermal: Dermal (LD50 Rat) : > 5000 mg/kg body weight

Inhalation: Inhalation (LC50 Rat) : > 4.8 mg/l air - 4 hours

Eye Contact: Slightly Irritating (Rabbit)

Skin Contact: Slightly Irritating (Rabbit)

Skin Sensitization: Not a sensitizer in animal tests (Guinea Pig)

Chemical Name NTP/IARC/OSHA Carcinogen Other ingredients No methyl (4aS)-7-chloro-2,5-dihydro-2- No [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]inden o[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate

Other Toxicity Information None Toxicity of Other Components Other ingredients Not Applicable

Target Organs Active Ingredients Indoxacarb Technical: Nervous system Inert Ingredients Other ingredients: Not Applicable

Page 5 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015 12. ECOLOGICAL INFORMATION

Eco-Acute Toxicity Indoxacarb Technical: Fish (Rainbow Trout) 96-hour LC50 0.65 mg/l Bird (Bobwhite Quail) LD50 Oral 98 mg/kg Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.60 mg/l

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Proper Shipping Name: Environmentally Hazardous Substance, Solid, N.O.S. (Indoxacarb) Hazard Class: Class 9 Identification Number: UN 3077 Packing Group: PG III

Air Transport Proper Shipping Name: Environmentally Hazardous Substance, Solid, N.O.S. (Indoxacarb) Hazard Class: Class 9 Identification Number: UN 3077 Packing Group: PG III

15. REGULATORY INFORMATION

Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: Caution: CAUTION: Harmful if swallowed. Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact

Page 6 of 7 Safety Data Sheet

ARILON® Date: 7/1/2015 Replaces: 3/16/2015 with skin, eyes or clothing. Wash thoroughly with soap and water after handling. Harmful if inhaled. Avoid breathing (dust, vapor or spray mist). Remove contaminated clothing and wash clothing before reuse.

EPA Registration Number(s): 100-1501 EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Acute Health Hazard

Section 313 Toxic Chemicals: None

CERCLA/SARA 304 Reportable Quantity (RQ): Not Applicable RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA

16. OTHER INFORMATION

NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 2 Health: 1 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme Syngenta Hazard Category: D * Chronic

For non-emergency questions about this product call:

1-800-334-9481

Original Issued Date: 5/6/2013 Revision Date: 7/1/2015 Replaces: 3/16/2015 Section(s) Revised: 2, 4, 11, 16 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

Page 7 of 7

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 1/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

1. Product and Company Identification

Company 24 Hour Emergency Response Information BASF CORPORATION CHEMTREC: 1-800-424-9300 100 Campus Drive BASF HOTLINE: 1-800-832-HELP Florham Park, NJ 07932, USA

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Synonyms: Abamectin B1

2. Hazards Identification

Emergency overview

CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF ABSORBED THROUGH SKIN. Moderately irritating to the eyes. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling.

State of matter: solid Colour: brown Odour: characteristic

Potential health effects

Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

Acute toxicity: Relatively nontoxic after single ingestion. Slightly toxic after short-term skin contact.

Irritation / corrosion: May cause slight but temporary irritation to the eyes. May cause slight irritation to the skin.

Sensitization: Skin sensitizing effects were not observed in animal studies.

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 2/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

3. Composition / Information on Ingredients

CAS Number Content (W/W) Chemical name 71751-41-2 0.05 % Abamectin 99.95 % Proprietary ingredients

4. First-Aid Measures

General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment.

If inhaled: Remove the affected individual into fresh air and keep the person calm.

If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes.

If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing.

If swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions.

5. Fire-Fighting Measures

Flash point: not determined

Suitable extinguishing media: dry extinguishing media, carbon dioxide

Hazards during fire-fighting: carbon monoxide, carbon dioxide, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire.

Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

6. Accidental release measures

Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 3/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund').

Cleanup: Dike spillage. Sweep/shovel up. Avoid raising dust. Use wet cleaning methods when applicable. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.

7. Handling and Storage

Handling General advice: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment.

Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed.

Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials.

Storage stability: May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet.

Temperature tolerance Protect from temperatures above: 40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

8. Exposure Controls and Personal Protection

Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 4/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions.

Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit.

General safety and hygiene measures: RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.

9. Physical and Chemical Properties

Form: gel Odour: characteristic Colour: brown pH value: of low solubility, not applicable, The statements are based on the properties of the individual components. approx. 8.4 ( 1 %(m), 25 °C) The data given are those of the active ingredient. Density: 1.0651 g/cm3 ( 25 °C) Bulk density: not applicable Partitioning coefficient n- No data available. octanol/water (log Pow): Solubility in water: insoluble

10. Stability and Reactivity

Substances to avoid: caustics

Hazardous reactions: The product is chemically stable.

Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off.

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 5/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat.

Corrosion to metals: No data available.

11. Toxicological information

Acute toxicity

Dermal: Type of value: LD50 Species: rat Value: > 2,000 mg/kg

Irritation / corrosion

Skin: Species: rabbit Result: non-irritant

Eye: Species: rabbit Result: non-irritant May cause slight irritation to the eyes.

Sensitization:

Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies.

Genetic toxicity

Information on: Abamectin Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic. ------

Carcinogenicity

Information on: Abamectin In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed. ------

Reproductive toxicity

Information on: Abamectin The results of animal studies suggest a fertility impairing effect with high doses. ------

Development:

Information on: Abamectin Causes developmental effects in animals at high, maternally toxic doses. ------

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 6/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

12. Ecological Information

Fish

Information on: Abamectin Acute: OECD 203; ISO 7346; 92/69/EEC, C.1 Flow through. Oncorhynchus mykiss/LC50 (96 h): 0.0087 mg/l ------

Aquatic invertebrates

Information on: Abamectin Acute: OECD Guideline 202, part 1 static Daphnia magna/EC50 (48 h): 0.0016 mg/l ------

Aquatic plants

Information on: Abamectin Toxicity to aquatic plants: OECD Guideline 201 static green algae/EC50 (72 h): > 6.1 mg/l ------Not readily biodegradable (by OECD criteria). ------

13. Disposal considerations

Waste disposal of substance: Pesticide wastes are regulated. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.

Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.

14. Transport Information

Land transport USDOT Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains ABAMECITIN)

Sea transport IMDG Hazard class: 9

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 7/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains ABAMECITIN)

Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains ABAMECITIN)

15. Regulatory Information

Federal Regulations

Registration status: Chemical TSCA, US blocked / not listed

Crop Protection TSCA, US released / exempt

EPCRA 311/312 (Hazard categories): Acute; Chronic

16. Other Information

Recommended use: insecticide

BASF supports worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

AVERT® ROACH BAIT STATION is a registered trademark of BASF Corporation or BASF SE IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.

Safety Data Sheet AVERT® ROACH BAIT STATION Revision date : 2009/12/18 Page: 8/8 Version: 1.0 (30486706/SDS_GEN_US/EN)

END OF DATA SHEET

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 1/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

1. Product and Company Identification

Company 24 Hour Emergency Response Information BASF CORPORATION CHEMTREC: 1-800-424-9300 100 Campus Drive BASF HOTLINE: 1-800-832-HELP Florham Park, NJ 07932, USA

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Substance number: 000000396123 Synonyms: Abamectin B1

2. Hazards Identification

Emergency overview

CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. Avoid inhalation of dusts. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling.

See Product Label for additional precautionary statements.

State of matter: solid Colour: brown Odour: mild

Potential health effects

Acute toxicity: Relatively nontoxic after single ingestion. Slightly toxic after short-term skin contact.

Irritation / corrosion: May cause slight but temporary irritation to the eyes. Contact may result in skin irritation.

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 2/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

Sensitization: Skin sensitizing effects were not observed in animal studies.

3. Composition / Information on Ingredients

CAS Number Content (W/W) Chemical name 71751-41-2 0.05 % Abamectin 99.05 % Proprietary ingredients

4. First-Aid Measures

If inhaled: Remove the affected individual into fresh air and keep the person calm.

If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes.

If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing.

If swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions.

Note to physician Treatment: Treat symptomatically.

5. Fire-Fighting Measures

Flash point: Substance/product is non-flammable.

Suitable extinguishing media: dry powder, carbon dioxide, water spray

Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 3/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

6. Accidental release measures

7. Handling and Storage

Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials.

8. Exposure Controls and Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 4/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:

Respiratory protection: Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/dust are formed.

Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit.

9. Physical and Chemical Properties

Form: powder Odour: mild Colour: brown pH value: 4.9 ( 1 %(m)) Melting point: not applicable Boiling point: not applicable Relative density: 0.619 ( 23 °C) Bulk density: 672.8 kg/m3 Vapour density: not determined Solubility in water: insoluble

10. Stability and Reactivity

Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded.

Substances to avoid: caustics

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 5/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

Hazardous reactions: The product is chemically stable. No hazardous reactions when stored and handled according to instructions.

Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated.

Corrosion to metals: Corrosive effects to metal are not anticipated.

Oxidizing properties: Not an oxidizer.

11. Toxicological information

Acute toxicity

Oral: Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg (other)

Inhalation: Type of value: LC50 Not inhalable due to the physico-chemical properties of the product.

Dermal: Type of value: LD50 Species: rabbit (male/female) Value: > 2,000 mg/kg (other)

Irritation / corrosion

Skin: Species: rabbit Result: non-irritant Method: Primary skin irritation test

Eye: Species: rabbit Result: non-irritant Method: Primary eye irritation test May cause slight irritation to the eyes.

Genetic toxicity

Carcinogenicity

Information on: Abamectin

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 6/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed. ------

Reproductive toxicity

Information on: Abamectin The results of animal studies suggest a fertility impairing effect with high doses. ------

Development:

Information on: Abamectin Causes developmental effects in animals at high, maternally toxic doses. ------

12. Ecological Information

Fish

Information on: Abamectin Acute: Oncorhynchus mykiss/LC50 (96 h): 0.0036 mg/l ------

Aquatic invertebrates

Information on: Abamectin Acute: Daphnia magna/EC50 (48 h): 0.00034 mg/l ------

Aquatic plants

Information on: Abamectin Toxicity to aquatic plants: OECD Guideline 201 static green algae/EC50 (72 h): > 6.1 mg/l ------Not readily biodegradable (by OECD criteria). ------

13. Disposal considerations

14. Transport Information

Reference Bill of Lading

Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 7/7 Version: 3.2 (30472240/SDS_CPA_US/EN)

15. Regulatory Information

Federal Regulations

Registration status: Chemical TSCA, US blocked / not listed

Crop Protection TSCA, US released / exempt

EPCRA 311/312 (Hazard categories): Acute; Chronic

16. Other Information

Refer to product label for EPA registration number.

Recommended use: insecticide

We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

MSDS Prepared by: BASF NA Product Regulations [email protected] MSDS Prepared on: 2011/07/18

!"# $ Ȁ ! "#$%Ā&!'()Ā*#+!,- US EPA Reg No. 11649-4: CD PCPA Reg. No. 12098 Ȁ ! "#$%Ā.$#,Ā./$0- US EPA Reg No. 11649-6: CD PCPA Reg. No. 12095 Ȁ ! "#$%Ā1/$%(Ā.$#,Ā US EPA Reg No. 11649-7: CD PCPA Reg. No. 12096

' $ N(-"!L!)(

% $ Ȁ ! "#$%Ā.$#0$#+"!$, >>K+ !"#$%KL$M

$ 233456547833Ā965Ā/$:#-Ā;<Ā)+=-Ā+Ā>((?@ (" ) . / * $ D/!-ĀM+"(#!+%Ā!-ĀL$,-!)(#()Ā/+W+#)$:-ĀU=Ā"/(ĀFCXȀĀX+W+#)Ā.$MM: , !L+"!$,ĀC"+,)+#)Ā 967Ā.YZĀH7H3KH633@K * $ .F&OJCD POQBĀRJCDC + N(#L(,"+S(Ā$TĀ"/(ĀM!'":#(ĀL$,- !-"!,SĀ$TĀ!,S#()!(,"9-@Ā$TĀ:,? ,$> ,Ā"$'!L!"=WĀ77KIX

$ 1 +#,!,S ) $ &+=ĀT$#MĀL$MU:-"!U%(Ā):-"ĀL$,L(,"#+"!$,-Ā!,Ā+!#K ' ' , $ V$"Ā+00%!L+U%(K - $ V$"Ā+00%!L+U%(K $ V$"Ā+00%!L+U%(K $ V$"Ā+00%!L+U%(K $ G((0ĀL$,"+!,(#Ā"!S/"%=ĀL%$-()KĀĀG((0Ā+>+=ĀT#$MĀ/(+"EĀ/$"Ā-:#T+L(-EĀ-0+#?-EĀ$0(,ĀT%+M(-Ā +,)Ā$"/( #Ā!S,!"!$,Ā-$:#L(-KĀV$Ā-M$?!,SKĀĀN#( (,"Ā):- "Ā+LL:M :%+"!$, K ) $ Y!,(Ā):-"ĀL%$:)-ĀM+=ĀT$#MĀ('0%$-! (ĀM!'":#(-Ā>!"/Ā+!#KĀĀX+,)%!,SĀ+,);$#Ā0#$L(--!,SĀ$TĀ "/!-ĀM+"(#!+%ĀM+=ĀS(,(#+"(Ā+Ā):-"Ā>/!L/ĀL+,ĀL+:-(ĀM(L/+,!L+%Ā!##!"+"!$,Ā$TĀ"/(Ā(=(-E -? !,EĀ,$-(Ā+,)Ā"/#$+"K 0"* / /+ $ &!'":#( . $ V$"Ā+ +!%+U%(K

* / * $ V$"Ā+00%!L+U%(K ' $ V$"Ā+ +!%+U%(K # 1 * 54ȀM!,$0=#!)!,( 3KI I354654I

*# +!, 77KI 4

$ 1RSUHYLRXVYDOLGDWLRQ 0"* / Ȁ,= ĀL$,L(,"#+"!$,Ā-/$>, Ā+-Ā+Ā#+,S(Ā!-Ā"$Ā0#$"(L"ĀL$,T!)(,"!+%!"=Ā$#Ā!-Ā):(Ā"$ĀU+"L/Ā +#!+"!$,K 2 3 2 ) , 4 " . + 2 , 2 5" 6" $ PMM()!+"( %=ĀT%:-/Ā(=(-Ā>!"/Ā0%(,"=Ā$TĀ>+"(#EĀ$LL+-!$,+%%=Ā%!T"!,SĀ"/(Ā:00(#Ā+,)Ā%$>(#Ā (=(%!)-KĀĀ./(L?ĀT$#Ā+,)Ā#(M$ (Ā+,= ĀL$,"+L"Ā%(,-(-KĀĀ.$,"!,:(Ā"$Ā#!,-(ĀT$#Ā+"Ā%(+-"ĀH3Ā M!,:"(-KĀĀ*("ĀM()!L+%Ā+""(,"!$,Ā!TĀ!##!"+"!$,Ā$LL:#-K # $ Z(M $ (Ā !L"!MĀ"$ĀT#(-/Ā+!#Ā+,)Ā?((0Ā+"Ā#(-"Ā!,Ā+Ā0$-!"!$,ĀL$MT$#"+U%(ĀT$#ĀU#(+"/!,SKĀĀPTĀ ,$"ĀU#(+"/!,SEĀ!TĀU#(+"/!,SĀ!-Ā!##(S:%+#Ā$#Ā!TĀ#(-0!#+"$#=Ā+##(-"Ā$LL:#-EĀ0#$ !)(Ā+#"!T!L!+%Ā #(-0!#+"!$,Ā$#Ā$'=S(,ĀU=Ā"#+!,()Ā0(#-$,,(%KĀĀP"ĀM+=ĀU(Ā)+,S(#$:-Ā"$Ā"/(Ā0(#-$,Ā0#$ !)!,SĀ +!)Ā"$ĀS!(ĀM$:"/4"$4M$:"/Ā#(-:-L !"+"!$,KĀĀ*("ĀM()!L+%Ā+""(,"!$, Ā!TĀ+) (#-(Ā/(+%"/Ā(TT(L"-Ā 0(#-!-"Ā$#Ā+#(Ā-( (#(KĀĀPTĀ:,L$,-L!$:-EĀ0%+L(Ā!,Ā#(L$ (#=Ā0$-!"!$,Ā+,)ĀS("ĀM()!L+%Ā +""(,"! $,Ā!MM()!+ "(%=KĀĀ&+!,"+!,Ā+,Ā$0(,Ā+!#>+=KĀĀQ$$-(,Ā"!S/"ĀL%$"/!,SĀ-:L/Ā+-Ā+ĀL$%%+#E "!(EĀU(%"Ā$#Ā>+!-"U+,)K 3 $ 1 +-/ĀL$,"+M !,+"() Ā-?!,Ā>!"/Ā-$+0Ā+,)Ā>+"(#KĀĀZ(M$ (ĀL$,"+M!,+"( )ĀL%$"/!,SĀ+,)Ā -/$(-KĀĀ*("ĀM()!L+%Ā+""(,"!$,Ā!TĀ-=M0"$M-Ā$LL:#KĀĀ1+-/ĀL%$"/!,SĀU(T$#(Ā#(:-(KĀĀ.%(+,Ā -/$(-Ā"/$#$:S/%=ĀU(T$#(Ā#(:-(K # $ 1 +-/Ā$:"ĀM$:"/Ā> !"/Ā>+"(#KĀĀZ(M$ (Ā)(,":#(-Ā!TĀ+,=KĀĀZ(M$ (Ā !L"!MĀ"$ĀT#(-/Ā+!#Ā+,)Ā ?((0Ā+"Ā#(-"Ā!,Ā+Ā0$-!"!$,ĀL$MT$#"+U%(ĀT$#ĀU#(+"/!,SKĀĀPTĀ"/(Ā0+"!(,"Ā!-ĀL$,-L!$:-EĀ!,):L(Ā $M !"!,SĀ>!"/Ā-=#:0Ā$TĀP0(L+LĀ9!TĀ,$"Ā+ +!%+U%(EĀ-"!M:%+"(Ā"/(ĀU+L?Ā$TĀ"/(Ā"/#$+"Ā>!"/Ā T!,S(#@KĀĀĀĀPTĀ $M!"!,SĀ$LL:#-EĀ"/(Ā/(+)Ā-/$:%)ĀU(Ā?(0"Ā%$>Ā-$Ā"/+"Ā $M!"Ā)$(-Ā,$"Ā(,"(#Ā "/(Ā%:,S-KĀĀ*("ĀM()!L+%Ā+""(,"!$,Ā!TĀ+) (#-(Ā/(+%"/Ā(TT(L"-Ā0(#-!-"Ā$#Ā+#(Ā-( (#(KĀĀV( (#Ā S! (Ā+,="/!,S ĀU=ĀM$:"/Ā"$Ā+,Ā:,L$,-L !$:-Ā0(#-$,KĀĀPTĀ:,L$,-L!$: -EĀ0%+L(Ā!,Ā#(L$ (#=Ā 0$-!"!$, Ā+,)ĀS("ĀM()!L+%Ā+""(,"!$,Ā!MM()!+ "(%=KĀĀPTĀ"/(Ā0+"!(,"Ā!-Ā:,L$,-L!$:-EĀĀM+!,"+!,Ā U#(+"/!,SĀ+,)Ā/(+ #"ĀU(+"Ā9.NZĀ[Ā.+#)!$0:%M$,+#=ĀZ(-:-L !"+"!$,@KĀĀ&+!,"+!,Ā+,Ā$0(,Ā +!#>+=KĀĀQ$$-(,Ā"!S/"ĀL%$"/!,SĀ-:L/Ā+-Ā+ĀL$%%+#EĀ"!(EĀU(%"Ā$#Ā>+!-"U+,)K

8 /2 ' $ B'0$-:#(Ā"$Ā+!#U$#,(ĀL$,L(,"#+"!$,-Ā+U$ (Ā-"+":"$#=Ā$#Ā#(L$MM(, )()Ā('0$-:#(Ā%! M!"-Ā M+=ĀL+:-(Ā!##!"+"!$,Ā$TĀ"/(Ā(=(-K # $ B'0$-:#(Ā"$Ā+!#U$#,(ĀL$,L(,"#+"!$,-Ā+U$ (Ā-"+":"$#=Ā$#Ā#(L$MM(, )()Ā('0$-:#(Ā%! M!"-Ā M+=ĀL+:-(Ā!##!"+"!$,Ā$TĀ"/(Ā,$-(EĀ"/#$+"Ā+,)Ā%:,S-K 3 $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K # $ May be harmful if swallowed. ., &+ / $ Ȁ) (#-(Ā- =M0"$M-ĀM+=Ā!,L%:)(Ā"/(ĀT$%%$>!,S] !##!"+"!$, #(),(-- # $ Ȁ) (#-(Ā- =M0"$M-ĀM+=Ā!,L%:)(Ā"/(ĀT$%%$>!,S] #(-0!#+"$#=Ā"#+L"Ā!##!"+"!$, L$:S/!,S 3 $ V$Ā-0(L!T!LĀ)+"+K # $ V$Ā-0(L!T!LĀ)+"+K

# 2 7 $ D#(+"Ā-=M0"$M+"!L+%%=KĀĀ.$,"+L"Ā0$!-$,Ā"#(+"M(,"Ā-0(L!+%!-"Ā!MM()!+ "(%=Ā!TĀ%+#S(Ā \:+,"! "!(-Ā/+ (ĀU((,Ā!,S(-"()Ā$#Ā!,/+ %()K $ V$Ā-0(L!T!LĀ"#(+"M(,"K

$ 1RSUHYLRXVYDOLGDWLRQ 6" ' & $ V$Ā+L"!$,Ā-/+%%ĀU(Ā"+?(,Ā!, $% !, SĀ+,=Ā0(#-$,+%Ā#!-?Ā$#Ā>!"/$:"Ā-:!"+U%(Ā"#+!,!,SKĀĀP"ĀM+=Ā U(Ā)+,S(#$:-Ā"$Ā"/(Ā0(#-$,Ā0#$ !)!,SĀ+!)Ā"$ĀS!(ĀM$:"/4"$4M$:"/ Ā#(-:-L !"+"!$,K

+ !! 9" & + + $ J-(Ā)#=ĀL/(M !L+%EĀĀ>+"(#Ā-0#+=Ā9T$S@Ā$#ĀT$+MK : + $ R$Ā,$"Ā:-(Ā>+"(#Ā_("K

) $ Y!,(Ā):-"ĀL%$:)-ĀM+=ĀT$#MĀ('0%$-! (ĀM!'":#(-Ā>!"/Ā+!#KĀĀȀ$!)ĀS(,(#+"!,S Ā):-"^ĀT!,(Ā):-"Ā )!-0(#-()Ā!,Ā+! #Ā!,Ā-:TT!L!(,"ĀL$,L(,"#+"!$,-EĀ+,)Ā!,Ā"/(Ā0#(-( ,L(Ā$TĀ+,Ā!S,!"!$,Ā-$:#L(Ā!-Ā +Ā0$"(,"!+%Ā):-"Ā('0%$-!$,Ā/+W+#)KĀĀ*#+!,-Ā>!%%ĀU:#,Ā+"Ā/!S/(#Ā"(M0(#+":#(-K ) $ L+#U$,Ā)!$'!)( L+#U$,ĀM$,$'!)( L/%$#!,( /= )#$S(,ĀL/%$#!)(

, $ N#$M0"%=Ā!-$%+"(Ā"/(Ā-L(,(ĀU=Ā#(M$ !, SĀ+%%Ā0(#-$,-ĀT#$MĀ"/(Ā !L!,!"=Ā$TĀ"/(Ā!,L!)( ,"Ā!TĀ & "/(#(Ā!-Ā+ĀT!#(KĀĀV$Ā+L"!$,Ā-/+%%ĀU(Ā"+?(,Ā!, $%!,SĀ+,=Ā0(#-$,+%Ā#!-?Ā$#Ā>!"/$:"Ā-:!"+U%(Ā "#+!,!,SKĀĀ&$(ĀL$,"+!,(#-ĀT#$MĀT!#(Ā+#(+Ā!TĀ"/!-ĀL+,ĀU(Ā)$,(Ā>!"/$:"Ā#!-?KĀĀJ-(Ā>+"(#Ā -0#+=Ā"$Ā?((0ĀT!#(4('0$-()ĀL$,"+!,(#-ĀL$$%K , $ Y!#(4T!S/"(#-Ā-/$:%)Ā>(+#Ā+00#$0#!+"(Ā0#$"(L"!(Ā(\:!0M(,"Ā+,)Ā-(%T4L$,"+!,()ĀU#(+"/! ,SĀ 4 & +00+#+":-Ā9C.OȀ@Ā>!"/Ā+ĀT:%%ĀT+L(40!(L(Ā$0(#+"()Ā!,Ā0$-!"! (Ā0#(--: #(ĀM$)(K ;" ' 2 ,4 & $ V$Ā+L"!$,Ā-/+%%ĀU(Ā"+?(,Ā!, $% !, SĀ+,=Ā0(#-$,+%Ā#!-?Ā$#Ā>!"/$:"Ā-:!"+U%(Ā"#+!,!,SK B + L:+"(Ā-:##$:,)! ,SĀ+#(+-KĀĀG((0Ā:,,(L(-- +#=Ā+,)Ā:,0#$"(L"()Ā0(#- $,,(%ĀT#$MĀ (,"(#!,SKĀĀR$Ā,$"Ā"$:L/Ā$#Ā>+%?Ā"/#$:S/Ā-0!%%()ĀM+"(#!+%KĀĀC/:"Ā$TTĀ+%%Ā!S,!"!$,Ā-$:#L(-K V$ĀT%+#(-EĀ-M$?!,SĀ$#ĀT%+M(-Ā!,Ā/+W+#)Ā+#(+KĀĀR$Ā,$"ĀU#(+"/(Ā):-"KĀĀN#$ !)(Ā+)(\:+"(Ā (,"! %+"!$,KĀĀ1(+#Ā+00#$0#!+"(Ā#(-0!#+"$#Ā>/(,Ā (,"!%+"!$,Ā!-Ā!,+)(\:+"(KĀĀN:"Ā$,Ā +00#$0#!+"(Ā0(#-$,+%Ā0#$"(L"! (Ā(\:!0M(,"KĀĀR:-"ĀR(0$-!"-Ā-/$:%)Ā,$"ĀU(Ā+%%$>( )Ā"$Ā +LL: M:%+"(Ā$,Ā-:#T+L(-EĀ+-Ā"/(-(ĀM+=ĀT$#MĀ+,Ā('0%$-!(ĀM!'":#(Ā!TĀ"/(=Ā+#(Ā#(%(+-()Ā !,"$Ā"/(Ā+"M$-0/(#(Ā!,Ā-:TT!L!(,"ĀL$,L(,"#+"!$,KĀĀȀ $!) Ā)!-0(#-+%Ā$TĀ):-"Ā!,Ā"/(Ā+!#Ā9!K(KE L%(+#!,SĀ):-"Ā-:#T+L(-Ā>!"/ĀL$M0#(-- ()Ā+!#@K $ PTĀ-0(L!+%!W()ĀL%$"/!,SĀ!-Ā#(\:!#()Ā"$Ā)(+%Ā>!"/Ā"/( Ā-0!%%+S(EĀ"+?( Ā,$"(Ā$TĀ+,=Ā!,T$#M+"!$, Ā!,Ā C(L"!$,Ā2Ā$,Ā-:!"+U%(Ā+,)Ā:, - :!"+U%(ĀM+"(#!+%-K ĀC((Ā+%-$Ā"/(Ā!,T$#M+"!$,Ā!,ĀaY$#Ā,$,4(M(#S(,L=Ā0(#-$,,(%aK

, $ Ȁ $ !)Ā)!-0(#- +%Ā$TĀ-0!%%()ĀM+"(#!+%Ā+,)Ā#:,$TTĀ+,)ĀL$,"+L"Ā>!"/Ā-$!%EĀ>+"(#>+=-EĀ)#+!,-Ā +,)Ā-(> ( #-KĀĀP,T$#MĀ"/(Ā#(%(+,"Ā+:"/$#!"!(-Ā!TĀ"/(Ā0#$):L"Ā/+-ĀL+:-()Ā(, ! #$,M(,"+%Ā 0$%%:"!$,Ā9-(>( #-EĀ>+"(#>+=-EĀ-$!%Ā$#Ā+!#@K

8 $ &$ ( ĀL$,"+!,(#-ĀT#$MĀ-0!%%Ā+#(+KĀĀJ-(Ā-0+#?40#$$TĀ"$$%-Ā+,)Ā('0%$-!$,40#$$TĀ(\:!0M(,"K `+L::M Ā$#Ā->((0Ā:0ĀM+"(#!+%Ā+,)Ā0%+L(Ā!,Ā+Ā)(-!S,+"()EĀ%+U(%()Ā>+-"(ĀL$,"+!,(#K R!-0$-(Ā$TĀ !+Ā+Ā%!L(,-()Ā>+-"(Ā)! - 0$-+%ĀL$,"#+L"$#KĀĀPTĀ:,+):%"(#+"()EĀ0#$):L"ĀM+=ĀU(Ā 0+L?+S()Ā!, Ā$#!S!,+%ĀL$,"+!,(#ĀT$#Ā:-(K

$ 1RSUHYLRXVYDOLGDWLRQ ;" < $ &$ ( ĀL$,"+!,(#-ĀT#$MĀ-0!%%Ā+#(+KĀĀJ-(Ā-0+#?40#$$TĀ"$$%-Ā+,)Ā('0%$-!$,40#$$TĀ(\:!0M(,"K Ȁ00#$+L/Ā#(%(+-(ĀT#$MĀ:0>!,)KĀĀN#( (,"Ā(,"#=Ā!,"$Ā-(>( #-EĀ>+"(#ĀL$:#- ( -EĀU+-(M(,"-Ā $#ĀL$,T!,()Ā+#(+-KĀĀ`+L::MĀ$#Ā->((0Ā:0ĀM+"(#!+%Ā+,)Ā0%+L(Ā!,Ā+Ā)(-!S,+"()EĀ%+U(%()Ā >+-"(ĀL$,"+!,(#KĀĀȀ$!)ĀL#(+"!,SĀ):-"=ĀL$,)!"!$,-Ā+,)Ā0#( (,"Ā> !,)Ā) !-0(#-+%KĀĀR!-0$-(Ā $TĀ !+Ā+Ā%!L(,-()Ā>+-"(Ā)! - 0$-+%ĀL$,"#+L"$#KĀĀV$"(]Ā-((ĀC(L"!$,ĀHĀT$#Ā(M(#S(,L=ĀL$,"+L"Ā !,T$#M+"!$, Ā+,)ĀC(L"!$,ĀH8ĀT$#Ā>+-"(Ā)!-0$-+%KĀĀPTĀ:,+):%"(#+"()EĀ0#$):L"ĀM+=ĀU(Ā 0+L?+S()Ā!, Ā$#!S!,+%ĀL$,"+!,(#ĀT$#Ā:-(K =" ' ' , $ N:"Ā$,Ā+00#$0#!+"(Ā0(#-$,+%Ā0#$"(L"! (Ā(\: !0M(,"Ā9-((ĀC(L"!$,Ā2@KĀĀR$Ā,$"Ā!,S(-"KĀĀȀ $!)Ā L$,"+L"Ā>!"/Ā(=(-EĀ-?!,Ā+,) ĀL%$"/!,SKĀĀȀ $!)ĀU#(+"/!,SĀ):-"KĀĀȀ $!)Ā"/(ĀL#(+"!$,Ā$TĀ):-"Ā >/(,Ā/+, )%!,SĀ+,)Ā+ $!)Ā+%%Ā0$--!U%(Ā-$:#L(-Ā$TĀ!S,!"!$,Ā9-0+#?Ā$#ĀT%+M(@KĀĀN#( (,"Ā):-"Ā +LL: M:%+"!$,KĀĀZ$:"!,(Ā/$:-(? ((0!, SĀ-/$:%)ĀU(Ā!,-"!":"()Ā"$Ā(,-:#(Ā"/+"Ā):-"-Ā)$Ā,$"Ā +LL: M:%+"(Ā$,Ā-:#T+L(-KĀĀJ-(Ā$,%=Ā>!"/Ā+)(\:+"(Ā (,"!%+"!$,KĀĀ1(+#Ā+00#$0#!+"(Ā #(-0!#+"$#Ā>/(,Ā (,"!%+"!$,Ā!-Ā!,+)(\:+"(KĀĀG((0Ā!,Ā"/(Ā$#!S!,+%ĀL$,"+!,(#Ā$#Ā+,Ā+00#$ ()Ā +%"(#,+"! (ĀM+)(ĀT#$MĀ+ĀL$M0+"!U%(ĀM+"(#!+%EĀ?(0"Ā"!S/"%=ĀL%$-()Ā>/(,Ā,$"Ā!,Ā:-(K B%(L"#!L+%Ā(\:!0M(,"Ā+,)Ā%!S/"!,SĀ-/$:%)ĀU(Ā0#$"(L"()Ā"$Ā+00#$0#!+"(Ā-"+,)+#)-Ā"$Ā 0#( (,"Ā) :-"ĀL$M!,SĀ!,"$ĀL$,"+L"Ā>!"/Ā/$"Ā-:#T+L(-EĀ-0+#?-Ā$#Ā$"/(#Ā!S,!"!$,Ā-$:#L(- K D+?( Ā0#(L+:"!$,+#=ĀM(+-:#(- Ā+S+!,-"Ā(%(L"#$-"+"!LĀ)!-L/+#S(-KĀĀD$Ā+ $!)ĀT!#(Ā$#Ā ('0%$-!$,EĀ)!-- !0+"(Ā-"+"!LĀ(%(L"#!L!"=Ā):#!,SĀ"#+,-T(#ĀU=ĀS#$:,)!, SĀ+,)ĀU$,)!, SĀ L$,"+!,(#-Ā+,)Ā(\:! 0M( ,"ĀU(T$#(Ā"#+,-T(##!,SĀM+"(#!+%KĀĀBM0"=ĀL$,"+!,(#-Ā#("+!,Ā0#$):L"Ā #(-!):(Ā+,)ĀL+,ĀU(Ā/+ W+#)$:-KĀĀR$Ā,$"Ā#(:-(ĀL$,"+!,(#K , $ B+"!,SEĀ)#!,?!,SĀ+,)Ā-M$?!,SĀ-/$:%)ĀU(Ā0#$/!U!"()Ā!,Ā+#(+-Ā>/(#(Ā"/!-ĀM+"(#!+%Ā!-Ā /+,)%()EĀ-"$#()Ā+,)Ā0#$L(--( )KĀĀ1$#?(#-Ā-/$:%)Ā>+-/Ā/+,)-Ā+,)ĀT+L(ĀU(T$#(Ā(+"!,SE )#!,? !,SĀ+,)Ā-M$?!,SKĀĀZ(M$ (ĀL$,"+M!,+"() ĀL%$"/!,SĀ+,)Ā0#$"(L"! (Ā(\:! 0M(,"ĀU(T$#(Ā (,"(#!,SĀ( +"!,SĀ+#(+-KĀĀC/$>(#Ā+"Ā"/(Ā(,)Ā$TĀ(+L/Ā>$#?)+=KĀĀC((Ā+%-$ĀC(L"!$,Ā2ĀT$#Ā +))! "!$,+%Ā!,T$#M+"!$,Ā$,Ā/=S!(,(ĀM( +-:#(- K

* 2 $ C"$#(Ā!,Ā+LL$#)+,L(Ā>!"/Ā%$L+%Ā#(S:%+"!$, -KĀĀC"$#(Ā!,Ā+Ā-(S#(S+"()Ā+,)Ā+00#$ ()Ā+#(+K C"$#(Ā!,Ā$#!S!,+%ĀL$,"+!,(#Ā0#$"(L"()ĀT#$MĀ)!#(L"Ā-:,%!S/"Ā!,Ā+Ā)#=EĀL$$%Ā+,)Ā>(%%4 (,"!%+"()Ā +#(+EĀ+>+=ĀT#$MĀ!,L$M0+"!U%(ĀM+"(#!+%-Ā9-((ĀC(L"!$,ĀH3@Ā+,)ĀT$$)Ā+,)Ā)#!, ?KĀĀC"$#(Ā +0+#"ĀT#$MĀ$"/(#Ā0(-"!L!)(-EĀT(#"!%!W(#-EĀT$$)Ā$#ĀT(()Ā"/+"ĀM+=ĀL+:-(ĀL#$--4L$,"+M!,+"!$,Ā $TĀ$)$#Ā$#Ā!,-(L"Ā!,T(-"+"!$,KĀĀB%!M!,+"( Ā+%%Ā!S,!"!$,Ā-$:#L(-KĀĀC(0+#+"(ĀT#$MĀ$'!)!W!,SĀ M+"(#!+%-KĀĀG((0ĀL$,"+!,(#Ā"!S/"%=ĀL%$-()Ā+,)Ā-(+%()Ā:,"!%Ā#(+)=ĀT$#Ā:-(KĀĀ.$,"+!,(#-Ā"/+"Ā /+ ( ĀU((,Ā$0(,()ĀM : -"ĀU(ĀL+#(T:%%=Ā#(-(+%()Ā+,)Ā?(0"Ā:0#!S/"Ā"$Ā0#( (,"Ā%(+?+S(KĀĀR$Ā ,$"Ā-"$#(Ā!,Ā:,%+U(%()ĀL$,"+!,(#-KĀĀJ-(Ā+00#$0#!+"(ĀL$,"+!,M(,"Ā"$Ā+$!)Ā(, ! #$,M(,"+%Ā L$,"+M !,+"!$,K 5"+ / * . + 54ȀM!,$0=#!)!,( Ā V$,(K

*# +!,Ā): -" . '<: " ĀĀD1Ȁ]ĀH3ĀMS;Mb 7#. -<: 26/(>!0 " ĀĀD1Ȁ]Ā5ĀMS;Mb * # !9 " ĀĀD1Ȁ]Ā5ĀMS;Mb

$ J-(Ā$,%=Ā>!"/Ā+)(\:+"(Ā (,"!%+"!$,KĀĀPTĀ:-(#Ā$0(#+"!$,-ĀS(,(#+"(Ā):-"EĀT:M(-EĀS+-EĀ +0$#Ā $#ĀM!-"EĀ:-(Ā0#$L(-- Ā(,L%$-:#(-EĀ%$L+%Ā('/+:-"Ā (,"!%+"!$, Ā$#Ā$"/(#Ā(,S!, ((#!,SĀL$,"#$%-Ā "$Ā?((0Ā>$#?(#Ā('0$-:#(Ā"$Ā+!#U$#,(ĀL$,"+M!,+, "-ĀU(%$>Ā+,=Ā#(L$MM(,)()Ā$#Ā-"+":"$#=Ā %!M!"-KĀĀD/(Ā(,S!,((#!,SĀL$,"#$%-Ā+%-$Ā,(()Ā"$Ā?((0ĀS+-EĀ +0$#Ā$#Ā):-"ĀL$,L(,"#+"!$,-Ā U(%$>Ā+,=Ā%$>(#Ā('0%$-! (Ā%!M!"-KĀĀJ-(Ā('0%$-!$,40#$$TĀ (,"! %+"!$,Ā(\:! 0M(,"K

$ 1RSUHYLRXVYDOLGDWLRQ 5"+ / , + $ BM!--!$,-ĀT#$MĀ (,"! %+"!$,Ā$#Ā>$#?Ā0#$L(--Ā(\:!0M ( ,"Ā-/$:%)ĀU(ĀL/(L? ( )Ā"$Ā(,-:#(Ā "/(= ĀL$M0%=Ā>!"/Ā"/(Ā#(\:!#(M (,"-Ā$TĀ(, ! #$,M(,"+%Ā0#$"(L"!$,Ā%(S!-%+"!$,KĀĀP,Ā-$M(Ā L+-( -EĀT:M(Ā-L#:UU(#-EĀT!%"(#-Ā$#Ā(,S!,(( #!,SĀM$)!T!L+"!$,-Ā"$Ā"/(Ā0#$L(--Ā(\:!0 M(,"Ā >!%%ĀU(Ā,(L(-- +#=Ā"$Ā#():L(Ā(M!--!$,-Ā"$Ā+LL(0"+U%(Ā%((%-K

#, $ 1 +-/Ā/+,)-EĀT$#(+#M-Ā+,)ĀT+L(Ā"/$#$:S/%=Ā+T"(#Ā/+,)%!,SĀL/(M!L+%Ā0#$):L"-EĀU(T$#(Ā (+"!, SEĀ-M$?!,SĀ+,)Ā:-!,SĀ"/(Ā%+ +"$#=Ā+,)Ā+"Ā"/(Ā(,)Ā$TĀ"/(Ā>$#?!,SĀ0(#!$)K Ȁ00#$0#!+"(Ā"(L/,!\:(-Ā-/$:%) ĀU(Ā:-()Ā"$Ā#(M$ (Ā0$"(,"! +%%=ĀL$,"+M!,+"() ĀL%$"/!,SK 1 +-/ĀL$,"+M !,+"() ĀL%$"/!,SĀU(T$#(Ā#(:-!,SKĀĀB,-:#(Ā"/+"Ā(=(>+-/ Ā-"+"!$,-Ā+,)Ā-+T("=Ā -/$>( #-Ā+#(ĀL%$-(Ā"$Ā"/(Ā>$#?-"+"!$,Ā%$L+"!$,K / $ C+T("=Ā(=(>(+#ĀL$M0%=!,SĀ>!"/Ā+,Ā+00#$ ()Ā-"+,)+#)Ā-/$:%)ĀU(Ā:-()Ā> /(,Ā+Ā#!-?Ā +-- ( -- M(,"Ā!,) !L+"(-Ā"/!-Ā!-Ā,(L(- -+#=Ā"$Ā+ $!)Ā('0$-:#(Ā"$Ā%!\:!) Ā-0%+-/(-EĀM!-"-E S+-(-Ā$#Ā):-"-KĀĀPTĀL$,"+L"Ā!-Ā0$--!U%(EĀ"/(ĀT$%%$>!,SĀ0#$"(L"!$,Ā-/$:%)ĀU(Ā>$#,EĀ:,%(--Ā "/(Ā+--(- - M(,"Ā!,) !L+"(-Ā+Ā/!S/(#Ā)(S#((Ā$TĀ0#$"(L"!$,]ĀĀ-+T("=ĀS%+--(-Ā>!"/Ā-!)(4 -/!(%)-KĀĀPTĀ$0(#+"!,SĀL$,)!"!$,-ĀL+:-( Ā/!S/Ā):-"ĀL$,L(,"#+"!$, -Ā"$ĀU(Ā0#$):L()EĀ:-(Ā ):-"ĀS$SS%(-K 3 $ ./(M !L+%4#(-!-"+,"EĀ!M0(# !$: -ĀS%$(-ĀL$M0%=!,SĀ>!"/Ā+,Ā+00#$ ( ) Ā-"+,)+#)Ā-/$:%)ĀU(Ā >$#,Ā+"Ā+%%Ā"!M(-Ā>/(, Ā/+,)%!,SĀL/(M!L+%Ā0#$):L"-Ā!TĀ+Ā#!-?Ā+--(-- M(,"Ā!,) !L+"(-Ā"/!-Ā!-Ā ,(L(-- +#=KĀĀ.$,-!)(#!,SĀ"/(Ā0+#+M("(#-Ā-0(L!T!()ĀU=Ā"/(ĀS%$ (ĀM+,:T+L":#(#EĀL/(L?Ā ):#!,SĀ:-(Ā"/+"Ā"/ (ĀS%$ (-Ā+#(Ā-"!%%Ā#("+!,!,SĀ"/(!#Ā0#$"(L"!(Ā0#$0(#"!(-KĀĀP"Ā-/$:%)ĀU(Ā ,$"()Ā"/+ "Ā"/(Ā"!M(Ā"$ĀU#(+?"/#$:S/ĀT$#Ā+,=ĀS%$(ĀM+"(#!+%ĀM+=ĀU(Ā)!TT(#(,"ĀT$#Ā)!TT(#(,"Ā S%$(ĀM+,:T+L":#(#- KĀĀP,Ā"/(ĀL+-(Ā$TĀM!'":#(-EĀL$,-!-"!,SĀ$TĀ-( (#+%Ā-:U-"+,L (-EĀ"/(Ā 0#$"(L"!$,Ā"!M(Ā$TĀ"/(ĀS%$ (-ĀL+,,$"ĀU(Ā+LL: #+"(%=Ā(-"!M+"()K @ $ 1 (+#Ā+Ā%$,SĀ-%(( () Ā:,!T$#MEĀL$ (#+%%-Ā$#Ā%+UĀ_+L?("Ā>/(,Ā/+, ) %!, SĀ$#ĀU%(,)!,SĀ"/(-(Ā 0#$):L"-Ā>!"/Ā:, "#(+"()ĀS#+!,-KĀĀN(#-$,+%Ā0#$"(L"! (Ā(\:!0M (,"ĀT$#Ā"/(ĀU$)=Ā-/$:%)ĀU(Ā -(%(L"()ĀU+-()Ā$,Ā"/(Ā"+-?ĀU(!,SĀ0(#T$#M()Ā+,)Ā"/( Ā#!-?-Ā!, $% ()Ā+,)Ā-/$:%)ĀU(Ā +00#$ ( ) ĀU=Ā+Ā-0(L!+%!-"ĀU(T$#(Ā/+,)%!,SĀ"/!-Ā0#$):L"K . 3 $ Ȁ00#$0#!+"(ĀT$$">(+#Ā+,)Ā+,=Ā+))!"!$,+%Ā-?!,Ā0#$"(L"!$,ĀM(+-:#(- Ā-/$:%)ĀU(Ā-(%(L"()Ā U+-()Ā$,Ā"/(Ā"+-?ĀU(!,SĀ0(#T$#M()Ā+,)Ā"/( Ā#!-?-Ā!, $% ()Ā+, )Ā-/ $:%)ĀU(Ā+00#$()ĀU=Ā+Ā -0(L!+%!-"ĀU(T$#(Ā/+,)%!,SĀ"/!- Ā0#$):L"K - $ J-(Ā+Ā0#$0(#%=ĀT!""()EĀ0+#"!L:%+"(ĀT!%"(#Ā#(-0!#+"$#ĀL$M0%=!,SĀ>!"/Ā+,Ā+00#$ () Ā-"+,)+#)Ā!TĀ +Ā#!-?Ā+--(-- M(,"Ā!,) !L+"(-Ā"/!-Ā!-Ā,(L(- - +#=KĀĀZ(-0!#+"$#Ā-(%(L"!$,ĀM:-"ĀU(ĀU+-()Ā$,Ā ?,$> ,Ā$#Ā+,"!L!0+"()Ā('0$-:#(Ā%( (%-EĀ"/(Ā/+W+#)-Ā$TĀ"/(Ā0#$):L"Ā+,)Ā"/(Ā-+T(Ā>$#?!,SĀ %!M!"-Ā$TĀ"/(Ā-(%(L"()Ā#(-0!#+"$#KĀĀB,-:#(Ā+,Ā&CXȀ;VPFCX4+00#$()Ā#(-0!#+"$#Ā$#Ā (\:! +%(,"Ā!-Ā:-()K A"' ' $ C$%!)K * $ *# +!,ĀL$%$#K . $ F)$#%(--K . $ V$"Ā+ +!%+U%(K $ V$"Ā+ +!%+U%(K 8 $ V$"Ā+ +!%+U%(K @ $ V$"Ā+ +!%+U%(K $ V$"Ā+ +!%+U%(K , $ V$"Ā+ +!%+U%(K 2 $ V$"Ā+ +!%+U%(K < + , $ V$"Ā+ +!%+U%(K ? $ V$"Ā+ +!%+U%(K ? $ V$"Ā+ +!%+U%(K

$ 1RSUHYLRXVYDOLGDWLRQ A"' - , $ V$"Ā+ +!%+U%(K $ V$"Ā+ +!%+U%(K ' $& $ V$"Ā+ +!%+U%(K / & $ V$"Ā+ +!%+U%(K $ V$"Ā+ +!%+U%(K ? $ V$"Ā+ +!%+U%(K !>" , - , $ V$Ā-0(L!T!LĀ"(-"Ā)+"+Ā#(%+"()Ā"$Ā#(+L"!!"=Ā+ +!%+U%(ĀT$#Ā"/!-Ā0#$):L"Ā$#Ā!"-Ā!,S#()!(,"-K

* $ D/(Ā0#$):L"Ā!-Ā-"+U%(K

' ) $ J,)(#Ā,$#M +%ĀL$,)!"!$,-Ā$TĀ-"$#+S(Ā+,)Ā:-(EĀ/+W+#)$:-Ā#(+L"!$,- Ā>!%%Ā,$"Ā$LL:#K

* , $ Ȁ $ !)Ā"/( ĀL#(+"!$,Ā$TĀ):-"Ā>/(,Ā/+,) %!,SĀ+,)Ā+ $!) Ā+%%Ā0$--!U%(Ā-$:#L(- Ā$TĀ!S,!"!$,Ā 9-0+#?Ā$#ĀT%+M(@KĀĀD+?(Ā0#(L+:"!$,+#=ĀM( +-:#(-Ā+S+!,-"Ā(%(L"#$-"+"!LĀ)!-L/+#S(-KĀĀD$Ā + $!)ĀT!#(Ā$#Ā('0%$-!$,EĀ)!-- !0+"(Ā-"+"!LĀ(%(L"#!L!"=Ā):#!,SĀ"#+,-T(#ĀU=ĀS#$:,)!, SĀ+,)Ā U$,)! ,SĀL$,"+!,( #-Ā+,)Ā(\:! 0M(,"ĀU(T$#(Ā"#+,-T(##!,SĀM+"(#!+%KĀĀN#( (,"Ā):-"Ā +LL: M:%+"!$,K

# $ Z(+L"! (Ā$ #Ā!,L$M0+"!U%(Ā>!"/Ā"/( ĀT$%%$>!,SĀM+"(#!+%-] $'!)!W!,SĀM+"(#!+%-

) $ J,)(#Ā,$#M +%ĀL$,)!"!$,-Ā$TĀ-"$#+S(Ā+,)Ā:-(EĀ/+W+#)$:-Ā)(L$M0$-!"!$, Ā0#$):L"-Ā-/$:%)Ā ,$"ĀU(Ā0#$):L()KĀĀJ,)(#Ā,$#M+%ĀL$,)!"!$,-Ā$TĀ-"$#+S(Ā+,)Ā:-(EĀ/+W+#)$:-Ā 0$%=M( #!W+"!$, Ā>!%%Ā,$"Ā$LL:#K !!" + # + + ' / - + 54ȀM!,$0=#!)!,( Ā QRI3ĀF#+% Z+" 63ĀMS;?S 4 # /* V$"Ā+ +!%+U%(K ) V$"Ā+ +!%+U%(K 8 V$"Ā+ +!%+U%(K * V$"Ā+ +!%+U%(K - , + V$"Ā+ +!%+U%(K V$"Ā+ +!%+U%(K ++

$ 1RSUHYLRXVYDOLGDWLRQ !!" + V$"Ā+ +!%+U%(K + + V$"Ā+ +!%+U%(K ) V$"Ā+ +!%+U%(K

# 3 $ V$"Ā+ +!%+U%(K + ' $ B'0$-:#(Ā"$Ā+!#U$#,(ĀL$,L(,"#+"!$,-Ā+U$ (Ā-"+":"$#=Ā$#Ā#(L$MM(, )()Ā('0$-:#(Ā%! M!"-Ā M+=ĀL+:-(Ā!##!"+"!$,Ā$TĀ"/(Ā(=(-K # $ B'0$-:#(Ā"$Ā+!#U$#,(ĀL$,L(,"#+"!$,-Ā+U$ (Ā-"+":"$#=Ā$#Ā#(L$MM(, )()Ā('0$-:#(Ā%! M!"-Ā M+=ĀL+:-(Ā!##!"+"!$,Ā$TĀ"/(Ā,$-(EĀ"/#$+"Ā+,)Ā%:,S-K 3 $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K # $ May be harmful if swallowed.

2 + $ Ȁ) (#-(Ā- =M0"$M-ĀM+=Ā!,L%:)(Ā"/(ĀT$%%$>!,S] !##!"+"!$, #(),(-- # $ Ȁ) (#-(Ā- =M0"$M-ĀM+=Ā!,L%:)(Ā"/(ĀT$%%$>!,S] #(-0!#+"$#=Ā"#+L"Ā!##!"+"!$, L$:S/!,S 3 $ V$Ā-0(L!T!LĀ)+"+K # $ V$Ā-0(L!T!LĀ)+"+K

+ + ' $ V$"Ā+ +!%+U%(K ' $ V$"Ā+ +!%+U%(K < + ' $ V$"Ā+ +!%+U%(K ' $ V$"Ā+ +!%+U%(K ' V$"Ā+ +!%+U%(K $ Z(0(+"()Ā$ #Ā0#$%$,S()Ā!,/+%+"!$,Ā$TĀ):-"ĀM+=Ā%(+)Ā"$ĀL/#$,!LĀ#(-0!#+"$#=Ā!##!"+"!$,K * $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K 8 $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K , $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K $ V$Ā?,$>,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K

7 + + V$"Ā+ +!%+U%(K

$ 1RSUHYLRXVYDOLGDWLRQ !!" +

!(" + ' / - + 54ȀM!,$0=#!)!,( Ā ȀL:"(ĀB.I3Ā86 33ĀcS;%ĀY#(-/Ā>+"(# R+0/,! +Ā4ĀR+0/,!+ĀM+S,+Ā4 52Ā/$:#- d: (,! %(Ā9Y%()S%!,SEĀX+"L/%!,SE 1 (+,%!,S@ ȀL:"(ĀQ.I3Ā6583ĀcS;%ĀY#(-/Ā>+"(# Y!-/Ā4ĀPL"+%:#:-Ā0:,L"+":-Ā4Āe$:,S 7AĀ/$:#-

' V$"Ā+ +!%+U%(K

@ ,

' / < ' @* ' 54ȀM!,$0=#!)!,( Ā 3K86 5KI< %$>

8 / $ V$"Ā+ +!%+U%(K B.*

. , $ V$Ā?,$> ,Ā-!S,!T!L+,"Ā(TT(L"-Ā$#ĀL#!"!L+%Ā/+W+#)-K !0" $ D/(ĀS(,( #+"!$,Ā$TĀ>+-"(Ā-/$:%)ĀU(Ā+$!)()Ā$#ĀM!,!M!W()Ā>/(#( (# Ā0$--!U%(KĀĀR!-0$-+%Ā $TĀ"/!-Ā0#$):L"EĀ-$%:"!$,-Ā+,)Ā+,=ĀU=40#$):L"- Ā-/$:%)Ā+"Ā+%%Ā"!M( -ĀL$M0%=Ā>!"/Ā"/(Ā #(\:!#(M (,"-Ā$TĀ(, ! #$,M (,"+%Ā0#$"(L"!$,Ā+,)Ā>+-"(Ā)!-0$-+%Ā%(S!-%+"!$,Ā+,)Ā+, =ĀT()(#+%E -"+"(Ā+,)Ā#(S!$,+%Ā%$L+%Ā+:"/$#!"=Ā#(\:!#(M (,"-KĀĀR!-0$-(Ā$TĀ-: #0%:-Ā+,)Ā,$,4#(L=L%+U%(Ā 0#$):L"-Ā !+Ā+Ā%!L(,-()Ā> +-"(Ā)!-0$-+%ĀL$,"#+L"$#KĀĀ1+-"(Ā-/$:%)Ā,$"ĀU(Ā)!-0$-()Ā$TĀ :,"#(+"()Ā"$Ā"/( Ā-(>(#Ā:,%(-- ĀT:%%=ĀL$M0%!+,"Ā>!"/Ā"/( Ā#(\:!#(M (,"-Ā$TĀ+%%Ā+:"/$#!"!(-Ā>!"/Ā _:#!- )!L"!$,KĀĀ1+-"(Ā0+L?+S!,SĀ-/$:%)ĀU(Ā#(L=L%()KĀĀP,L!,(#+"!$,Ā$#Ā%+,)T!%%Ā-/$:%)Ā$,%=ĀU(Ā L$,-!)(#()Ā> /(,Ā#(L= L%!,SĀ!-Ā,$"ĀT(+-!U%(KĀĀD/!-ĀM+"(#!+%Ā+,)Ā!"-ĀL$,"+!,(#ĀM:-"ĀU(Ā )!-0$-()Ā$TĀ!,Ā+Ā-+T(Ā>+=KĀĀ.+#(Ā-/$:%)ĀU(Ā"+?(,Ā>/(,Ā/+,)%!,SĀ(M0"!()ĀL$,"+!,(#-Ā"/+"Ā /+ ( Ā,$"ĀU((,ĀL%(+,()Ā$#Ā#!,-()Ā$:"KĀĀBM0"=ĀL$,"+!,(#-Ā$#Ā%!,(#-ĀM+=Ā#("+!,Ā-$M( Ā 0#$):L"Ā#(-!):( -KĀĀȀ $!)Ā)!-0(#-+%Ā$TĀ-0!%%()ĀM+"(#!+%Ā+,)Ā#:,$TTĀ+,)ĀL$,"+L"Ā>!"/Ā-$!%E >+"(#>+=-EĀ)#+!,-Ā+,)Ā-(>(#-K : &-*- ) C'C< # *D - 54ȀM!,$0=#!)!,( ^Ā54N=#!)!,+ M!,(Ā I354654I Q!-"()K N332 !6"

. 8+ -/-# #8 # * * *

:7 V$"Ā#(S:%+"()K V$"Ā V$"Ā V$"Ā V$"Ā#(S:%+"()K V$"Ā#(S:%+"()K )("(#M !,()K )("(#M !,()K )("(#M !,()K :7 4 4 4 4 4 4

4 4 4 4 4 4 )

$ 1RSUHYLRXVYDOLGDWLRQ !6" <

' 3 444 4 4 4 , - - - - -Ā - )

444 4 4 4

$ E $Ā+%>+=-Ā"#+,-0$#"Ā!,ĀL%$-()ĀL$,"+!,(#-Ā"/+"Ā+#(Ā :0#!S/"Ā+,) Ā-(L:#(KĀB,-:#(Ā"/+"Ā0(#-$,-Ā"#+,-0$#"!,SĀ"/(Ā0#$):L"Ā?,$>Ā>/+"Ā"$Ā)$Ā!,Ā"/(Ā ( (, "Ā$TĀ+,Ā+LL!)(,"Ā$#Ā-0!%%+S(K

3 $ V$"Ā+ +!%+U%(K +## 8-'.< =0/=5 #@** !9"- :"" $ *5 '#-]Ā54ȀM!,$0=#!)!,( Ā *5 *-+ /' + ]ĀV$"Ā)("(#M!,() : , *5 ]ĀȀ%%ĀL$M0$,(,"-Ā+#(Ā%!-"()Ā$#Ā('(M 0"()K

#-# $D/ !-ĀL/(M !L+%Ā!-Ā+Ā0(-"!L!)(Ā0#$):L"Ā#(S!-"(#()ĀU=Ā"/(Ā B, !#$,M(,"+%ĀN#$"(L"!$,ĀȀS(,L=Ā+,)Ā!-Ā-:U_(L"Ā"$ĀL(#"+!,Ā%+U(%!,SĀ#(\: !#(M(,"-Ā:,)(#Ā T()(#+%Ā0(-"!L!)(Ā%+>KĀD/(-(Ā#(\:!#(M (,"-Ā)!TT(#ĀT#$MĀ"/(ĀL%+--!T!L+"!$,ĀL#!"(#!+Ā+,)Ā /+W+#)Ā!,T$#M+"!$,Ā#(\: !#()ĀT$#Ā-+T("=Ā)+"+Ā-/(("-EĀ+,)ĀT$#Ā>$#?0%+L(Ā%+U(%-Ā$TĀ,$,4 0(-"!L!)(ĀL/(M !L+%-KĀY$%%$>!,SĀ!-Ā"/(Ā/+W+#)Ā!,T$#M+"!$,Ā+-Ā#(\ :! #()Ā$,Ā"/(Ā0(-"!L!)( Ā %+U(%]

*:#.7$ X+#MT:%Ā!TĀ->+%%$>()K &+=ĀL+:-(Ā!##!"+"!$,K Ȁ $ !)ĀL$,"+L"Ā>!"/Ā(=(-Ā$#ĀL%$"/!,SK 1 +-/Ā"/$#$:S/%=Ā>!"/Ā-$+0Ā+,)Ā>+"(#Ā+T"(#Ā/+,)%!,SK

* !!( $ V$"Ā%!-"() ) ' ' * ;>( $ V$"Ā%!-"() * # * ;>( $ V$"Ā%!-"() * ## <#* $ V$"Ā%!-"() ' * <##* $ V$"Ā%!-"() * -0>(/0>6 * /

$ 1RSUHYLRXVYDOLGDWLRQ !9"- -0>('G -0>6-G 7 1 54ȀM!,$0=#!)!,( Ā f 3K8Ā4ĀgH e( -K I33Ā;ĀH33334 H333 4 -0>6-G $ 633333Ā%U-Ā;Ā73233Ā?S -0!!/0!( * $ Y!#(Ā/+W+#) * / V$Ā0#$):L"-Ā>(#(ĀT$:,)K

8 $ V$,(Ā$TĀ"/(ĀL$M0$,(,"-Ā+#(Ā%!-"()K 7 3 $ V$,(Ā$TĀ"/(ĀL$M0$,(,"-Ā+#(Ā%!-"()K 7F $ V$,(Ā$TĀ"/(ĀL$M0$,(,"-Ā+#(Ā%!-"()K ', $ V$,(Ā$TĀ"/(ĀL$M0$,(,"-Ā+#(Ā%!-"()K # * H * , <#2##I###* V$"Ā%!- "()K 8 ' +2@2*2 V$"Ā%!-"()K 3 * , ' . ' V$"Ā%!-"()K - * , ' # * '#* V$"Ā%!-"()K :7* ' '.' ,8 V$"Ā%!-"()K # 7 , $ V$"Ā)("(#M!,()K * $ V$"Ā)("(#M!,()K * $ V$"Ā)("(#M!,()K $ V$"Ā)("(#M!,()K F $ V$"Ā)("(#M!,()K 8 $ V$"Ā)("(#M!,()K 7J $ V$"Ā)("(#M!,()K ' $ V$"Ā)("(#M!,()K - B $ V$"Ā)("(#M!,()K $ V$"Ā)("(#M!,()K !;". 7 ' :"""

6 3 3 # /- ,

$ 1RSUHYLRXVYDOLGDWLRQ !;". - 7'=>6&(>>!2# ) 8 - * K!AA=27 ' 2G28>((;A" 7 ' 2 L " * K(>>!27 ' 2G28>((;A" , 2 , ) " 7'6A 7'0(92 "H 7' 2 =>6 3" ' , * F .$M UKĀR:-"- F,ĀU+-!-Ā$TĀ"(-"Ā)+"+ $ 3<;HI;63HI / $ 3<;HI;63HI , , $ No previous validation. ? $ 1 B , $ ȀDBĀhĀȀL:"(ĀD$'!L!"=ĀB-"!M+"( O.YĀhĀO!$L$,L(,"#+"!$,ĀY+L"$# *XCĀhĀ*%$U+%%=ĀX+#M$,!W()ĀC=-"(M Ā$TĀ.%+--!T!L+"!$,Ā+,)ĀQ+U(%%!,SĀ$TĀ./(M!L+%- PȀDȀĀhĀP,"(#,+"!$,+%ĀȀ!#ĀD#+,-0$#"ĀȀ-- $L!+"!$, PO.ĀhĀP,"(#M()!+"( ĀO:%?Ā.$,"+!,(# P&R*ĀhĀP,"(#,+"!$,+%Ā&+#!"!M(ĀR+,S(#$:-Ā*$$)- Q$SN$>ĀhĀ%$S+#!"/MĀ$TĀ"/(Ā$L"+,$%;>+"(#Ā0+#"!"!$,ĀL$(TT!L!(," &ȀZNFQĀ<8;<2ĀhĀP,"(#,+"!$,+%Ā.$, (, "!$,ĀT$#Ā"/(ĀN#( (,"!$,Ā$TĀN$%%:"!$,ĀY#$MĀC/!0-E H7<8Ā+-ĀM$)!T!()ĀU=Ā"/(ĀN#$"$L$%Ā$TĀH7<2KĀ9a&+#0$%aĀhĀM+#!,(Ā0$%%:"!$,@ JVĀhĀJ,!"() ĀV+"!$,- - $ V$"Ā+ +!%+U%(K # , , " 7 - 7';962 ' , + 8 2 ' 2 * ' 2 "

3 2 " , 2 ,& 2 2 , " " 3 ) " ) 2 ) +"

$ 1RSUHYLRXVYDOLGDWLRQ

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 1/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

1. Product and Company Identification

Company 24 Hour Emergency Response Information BASF CORPORATION CHEMTREC: 1-800-424-9300 100 Campus Drive BASF HOTLINE: 1-800-832-HELP Florham Park, NJ 07932, USA

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Substance number: 000000395631 Synonyms: Cyfluthrin

2. Hazards Identification

Emergency overview

CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF ABSORBED THROUGH SKIN. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling.

See Product Label for additional precautionary statements.

State of matter: liquid Colour: beige to yellow Odour: characteristic

Potential health effects

Acute toxicity: Relatively nontoxic after single ingestion. Relatively nontoxic after short-term skin contact.

Irritation / corrosion: May cause slight but temporary irritation to the eyes. May cause moderate irritation to the skin.

Sensitization: Skin sensitizing effects were not observed in animal studies.

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 2/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

Potential environmental effects

Aquatic toxicity: Acutely toxic for aquatic organisms. The product has not been tested. The statement has been derived from the properties of the individual components.

3. Composition / Information on Ingredients

CAS Number Content (W/W) Chemical name 68359-37-5 6.0 % Cyfluthrin 94.0 % Proprietary ingredients

4. First-Aid Measures

If inhaled: Remove the affected individual into fresh air and keep the person calm.

If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes.

If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing.

If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow.

5. Fire-Fighting Measures

Flash point: A flash point determination is unnecessary due to the high water content.

Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray

Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, halogenated hydrocarbons, hydrocarbons If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire.

Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 3/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

6. Accidental release measures

Cleanup: Dike spillage. Pick up with suitable absorbent material. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.

7. Handling and Storage

Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials.

8. Exposure Controls and Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 4/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:

Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions.

Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit.

9. Physical and Chemical Properties

Form: liquid Odour: characteristic Colour: beige to yellow pH value: 7.5 - 8.5 Freezing point: approx. 0 °C Information applies to the solvent. Boiling point: approx. 100 °C Information applies to the solvent. Density: 0.96 g/cm3 (approx. 20 °C) Vapour density: not determined Partitioning coefficient n- not applicable octanol/water (log Pow): Solubility in water: dispersible

10. Stability and Reactivity

Substances to avoid: No substances known that should be avoided.

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 5/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

Hazardous reactions: The product is chemically stable.

Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off.

Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat.

Corrosion to metals: Corrosive effects to metal are not anticipated.

11. Toxicological information

Acute toxicity

Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg

Inhalation:

Not inhalable due to the physico-chemical properties of the product.

Dermal:

Information on: cyfluthrin Type of value: LD50 Species: rat Value: > 5,000 mg/kg ------

Irritation / corrosion

Information on: cyfluthrin Assessment of irritating effects: Not irritating to eyes and skin. ------

Sensitization

Information on: cyfluthrin Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. ------

Genetic toxicity

Information on: cyfluthrin No mutagenic effects reported. ------

Carcinogenicity

Information on: cyfluthrin In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed.

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 6/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

------

Reproductive toxicity

Information on: cyfluthrin No reproductive toxic effects reported. ------

Development:

Information on: cyfluthrin No teratogenic effects reported. ------

12. Ecological Information

Fish

Information on: cyfluthrin Acute: Oncorhynchus mykiss/LC50 (96 h): 0.000068 mg/l ------

Aquatic invertebrates

Information on: cyfluthrin Acute: Daphnia magna/EC50 (48 h): 0.00029 mg/l ------

Aquatic plants

Information on: cyfluthrin Toxicity to aquatic plants: green algae/EC50 (96 h): > 10 mg/l ------

13. Disposal considerations

14. Transport Information

Reference Bill of Lading

15. Regulatory Information

Safety Data Sheet CY-KICK CS Revision date : 2011/07/19 Page: 7/7 Version: 1.1 (30472209/SDS_CPA_US/EN)

Federal Regulations

Registration status: Chemical TSCA, US blocked / not listed

Crop Protection TSCA, US released / exempt

EPCRA 311/312 (Hazard categories): Acute;

EPCRA 313: CAS Number Chemical name 68359-37-5 beta-Cifluthrine

16. Other Information

Refer to product label for EPA registration number.

Recommended use: insecticide

NFPA Hazard codes: Health : 0 Fire: 1 Reactivity: 1 Special:

MSDS Prepared by: BASF NA Product Regulations [email protected] MSDS Prepared on: 2011/07/19

MSDS Ref. No.: 100000015827 Date Approved: 01/18/2010 Revision No.: 3

This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. The information contained herein is for the concentrate as packaged, unless otherwise noted.

1. PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: CYNOFF® Insecticide PRODUCT CODE: 6520 ACTIVE INGREDIENT(S): Zeta-cypermethrin*; Piperonyl butoxide (PBO)** CHEMICAL FAMILY: Pyrethroid Pesticide

MOLECULAR FORMULA: C22H19Cl2NO3 (zeta-cypermethrin); C19H30O5 (piperonyl butoxide) SYNONYMS: FMC 56701; (S)-cyano (3-phenoxyphenyl)methyl (+/-)cis/trans 3- (2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate; IUPAC: (S)-a-cyano-3-phenoxybenzyl-(1R)cis-trans-3-(2,2-dichlorovinyl)- 2,2-dimethylcyclopropanecarboxylate or (S)-a-cyano-3- phenoxybenzyl (1RS,3RS,1SR, 3SR)-3-(2,2-dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate*; Butylcarbityl(6-propylpiperonyl) ether, 1,3-Benzodioxole, 5-[[2-(2- butoxyethoxy)ethoxy]methyl]-6-propyl-** ALTERNATE PRODUCT NAME(S): ZETA-CYP DUST INSECTICIDE

MANUFACTURER EMERGENCY TELEPHONE NUMBERS FMC CORPORATION (800) 331-3148 (Medical - U.S.A. & Canada) Agricultural Products Group (651) 632-6793 (Medical - Collect - All Other Countries) 1735 Market Street Philadelphia, PA 19103 (215) 299-6000 (General Information) For leak, fire, spill, or accident emergencies, call: [email protected] (Email - General Information) (800) 424-9300 (CHEMTREC - U.S.A. & Canada) (703) 527-3887 (CHEMTREC - Collect - All Other Countries)

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: • Off-white, free-flowing, odorless powder. • Thermal decomposition may produce toxic by-products.

Page 1 of 10

CYNOFF® Insecticide (100000015827) Date: 01/18/2010

• Highly toxic to fish and aquatic organisms. Keep out of drains and water courses. • Expected to be moderately irritating to the skin.

POTENTIAL HEALTH EFFECTS: Effects from overexposure result from either swallowing, inhaling, or coming into contact with the eyes or skin. Symptoms of overexposure include tremors, convulsions, increased sensitivity to touch, and incoordination. Contact with zeta-cypermethrin may produce skin sensations such as numbing, burning and tingling. These sensations are reversible and usually subside within 12 hours.

MEDICAL CONDITIONS AGGRAVATED: None presently known.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name CAS# Wt.% EC No. EC Class Zeta-cypermethrin 52315-07-8 0.075 257-842-9 Xn, Xi, N; R20/22-43-50/53 Piperonyl butoxide (PBO) 51-03-6 0.15 200-076-7 Not classified per Annex I of Directive 67/548/EEC Calcium Carbonate (limestone) 1317-65-3 >90 215-279-6 Not classified

4. FIRST AID MEASURES EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, obtain medical attention.

SKIN: Remove contaminated clothing and thoroughly wash with soap and water. If irritation occurs and persists, contact a medical doctor.

INGESTION: Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. See a medical doctor immediately.

INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, contact a medical doctor.

NOTES TO MEDICAL DOCTOR: This product is expected to have low oral and dermal toxicity. It is expected to be moderately irritating to the skin and mildly irritating to the eyes. Expected to be mildly sensitizing to the skin. Reversible skin sensations (paresthesia) may occur and ordinary skin salves have been found useful in reducing discomfort. Treatment is otherwise controlled removal of exposure followed by symptomatic and supportive care.

Page 2 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Extinguish fire using agents suitable for nearby fires.

FIRE / EXPLOSION HAZARDS: Non-combustible.

FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors generated.

6. ACCIDENTAL RELEASE MEASURES

RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons and animals out of the area. Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non- combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label contents for disposal. To clean and neutralize contaminated area, scrub area with a solution of detergent (e.g. commercial product such as SuperSoap™, Tide®, Spic and Span®, or other high pH detergent) and water. Let solution sit for 5 minutes. Use a stiff brush to scrub affected area. Repeat if necessary to remove visible staining. Additional decontamination can be made by applying bleach (Clorox® or equivalent) to affected area. Absorb wash-liquid as noted above, remove visibly contaminated soil and place into recovery / disposal container (plastic, open-top steel drum or equivalent). Place all clean-up material in a container, seal and dispose of in accordance with the method outlined in Section 13 "Disposal Considerations" below. For further information on spill clean-up, waste disposal, or return of salvaged product, call the FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above.

7. HANDLING AND STORAGE HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Store in original containers only. Keep out of reach of children and animals. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.

Page 3 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS

Chemical Name ACGIH OSHA Supplier

3 3 Calcium Carbonate 10 mg/m (TWA) 15 mg/m (PEL) (limestone) (inhalable dust) 5 mg/m3 (PEL)

(respirable dust)

ENGINEERING CONTROLS: General air replacement or dilution ventilation is sufficient for material handling and storage, but local ventilation should be used when removing this product from containers. Ventilate all transport vehicles prior to unloading.

WORK HYGIENIC PRACTICES: Wash thoroughly with soap and water after handling and before eating or smoking.

9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Faint, slightly sweet APPEARANCE: Blue granules DENSITY / WEIGHT PER VOLUME: (Bulk) 1.57 g/mL (98.0 lbs/cu ft) FLASH POINT: Not applicable MOLECULAR WEIGHT: 416.3 (zeta-cypermethrin) pH: 7.0 @ 24°C (1% dispersion in water)

10. STABILITY AND REACTIVITY

CONDITIONS TO AVOID: Excessive heat and fire. STABILITY: Stable POLYMERIZATION: Will not occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, hydrogen cyanide, chlorine and hydrogen chloride.

Page 4 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

11. TOXICOLOGICAL INFORMATION EYE EFFECTS: Expected to be mildly irritating. (rabbit)

SKIN EFFECTS: Expected to be moderately irritating. (rabbit)

DERMAL LD50: > 2,000 mg/kg (rabbit)

ORAL LD50: > 5,000 mg/kg (rat)

INHALATION LC50: No data available for the formulation. Zeta-cypermethrin: 2.5 mg/l (4 h) (rat)

SENSITIZATION: No data available for the formulation. Zeta-cypermethrin: (Skin) Mildly sensitizing (guinea pig)

ACUTE EFFECTS FROM OVEREXPOSURE: This product is expected to have low oral and dermal toxicity. It is expected to be moderately irritating to the skin and mildly irritating to the eyes. Expected to be mildly sensitizing to the skin. Large doses of zeta-cypermethrin, ingested by laboratory animals, may produce signs of toxicity including tremors, incoordination, convulsions, staggered gait, and oral discharge. Experience to date indicates that contact with zeta-cypermethrin may produce skin sensations such as numbing, burning or tingling. These sensations are reversible and usually subside within 12 hours. Large oral doses of piperonyl butoxide ether may cause vomiting and diarrhea, while repeated skin contact may cause slight irritation. Clinical signs of piperonyl butoxide poisoning include nausea, vomiting, diarrhea, loss of appetite, and mild CNS depression. Reported effects on the blood include pancytopenia, thrombocytopenia, leukopenia, polycythemia, and anemias. A single oral dose of 50 mg PBO produced no ill effects in 8 male volunteers. This product is expected to have low oral, dermal and inhalation toxicity. It is expected to be moderately irritating to the eyes and skin.

CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the formulation. In studies with laboratory animals, zeta-cypermethrin did not cause reproductive effects or teratogenicity in laboratory animals. An overall absence of genotoxicity has been demonstrated in tests of mutagenicity, DNA damage and chromosome aberrations. Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes. Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weight and other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the diet for up to 12 weeks had clinical and histologic signs of liver damage; the highest dose group showed preneoplastic changes, including enlargement of hepatocyte nuclei and multinucleated cells. Kidney damage was also seen. Chronic exposure to respirable calcium carbonate may increase the risk of developing pneumoconiosis.

CARCINOGENICITY: Chemical Name IARC NTP OSHA Other Piperonyl butoxide (PBO) 3 Not listed Not listed (ACGIH) Not listed

Page 5 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

12. ECOLOGICAL INFORMATION The physical and environmental properties, as well as the environmental toxicology of zeta-cypermethrin, are similar to cypermethrin. Unless otherwise indicated, the data presented below pertains to cypermethrin.

ENVIRONMENTAL DATA: Cypermethrin is rapidly degraded in soil with a half-life of 2 to 4 weeks. It is readily hydrolyzed under basic conditions (pH = 9), but under acidic and neutral conditions, hydrolysis half-life can be 20 to 29 days. Cypermethrin has a high affinity for organic matter and a Log Pow of 5.0; yet because of the ease with which the material undergoes degradation, it has a very low potential for bioconcentration (BCF = 443) and is not mobile in soil.

ECOTOXICOLOGICAL INFORMATION: Zeta-cypermethrin is considered highly toxic to fish and aquatic arthropods and has LC50 values which range from 0.002 µg/L to 2.37 µg/L. These values are comparable to cypermethrin. Care should be taken to avoid contamination of the aquatic environment. Cypermethrin is slightly toxic to birds, and oral LD50 values are greater than 10,248 mg/kg.

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited. If spilled material cannot be disposed of by use according to label instructions, an acceptable method of disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards and regulations. However, because acceptable methods of disposal may vary by location and regulatory requirements may change, the appropriate agencies should be contacted prior to disposal.

EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned, prior to disposal, by triple rinsing. Containers which held this material may be cleaned by being triple- rinsed, and recycled, with the rinsate being incinerated. Do not cut or weld metal containers. Vapors that form may create an explosion hazard.

14. TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (DOT)

PACKAGING TYPE: Non-Bulk

ADDITIONAL INFORMATION: This material is not regulated in transportation.

PACKAGING TYPE: Bulk PROPER SHIPPING NAME: Environmentally hazardous substance, solid, n.o.s.

Page 6 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

TECHNICAL NAME(S): Zeta-cypermethrin PRIMARY HAZARD CLASS / DIVISION: 9 UN/NA NUMBER: UN 3077 PACKING GROUP: III MARINE POLLUTANT: Zeta-cypermethrin (2S) LABEL(S): 9 PLACARD(S): 9 MARKING(S): 3077

INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)

PACKAGING TYPE: Non-Bulk PROPER SHIPPING NAME: Environmentally hazardous substance, solid, n.o.s. TECHNICAL NAME(S): Zeta-cypermethrin PRIMARY HAZARD CLASS / DIVISION: 9 UN/NA NUMBER: UN 3077 PACKING GROUP: III MARINE POLLUTANT: Zeta-cypermethrin LABEL(S): 9 PLACARD(S): 9 MARKING(S): Environmentally hazardous substance, solid, n.o.s. (zeta-cypermethrin), UN 3077 + Marine Pollutants

ADDITIONAL INFORMATION: EmS Number: F-A, S-F

ADR - EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD

Page 7 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

HAZARD IDENTIFICATION NUMBER: 90 MARINE POLLUTANT: Zeta-cypermethrin LABEL(S): 9 PLACARD(S): 9 MARKING(S): UN 3077

INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) / INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)

ADDITIONAL INFORMATION: Marks: Environmentally hazardous substance, solid, n.o.s. (zeta-cypermethrin), UN3077 + Marine Pollutant.

OTHER INFORMATION: HARMONIZED SYSTEM Import to the U.S.A.: 3808.91.2500 Export from the U.S.A.: 3808.91.0000

15. REGULATORY INFORMATION UNITED STATES

SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed

SECTION 311 HAZARD CATEGORIES (40 CFR 370): Immediate

Page 8 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs; however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.: None

SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): This product does not contain any toxic chemicals subject to the reporting requirements of Section 313, Title III of the SARA (Superfund Amendments and Reauthorization Act) of 1986.

CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT)

CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4): Not listed

16. OTHER INFORMATION

NFPA

Health 1 Flammability 0 Reactivity 0 Special None No special requirements

NFPA (National Fire Protection Association)

Degree of Hazard Code: 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = Insignificant

REVISION SUMMARY: This MSDS replaces Revision #2, dated August 18, 2009. Changes in information are as follows: Section 1 (Product and Company Identification) Section 16 (Other Information)

Cynoff and FMC - FMC Trademarks Viton - E.I. du Pont de Nemours & Co. Trademark SuperSoap - Trademark of Weba Technologies, Inc.; Tide - Trademark of Proctor and Gamble; Spic and Span: Trademark of The Spic and Span Company; Clorox - Trademark of The Clorox Company

Page 9 of 10 CYNOFF® Insecticide (100000015827) Date: 01/18/2010

FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

Page 10 of 10 Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 1/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier

Trade name DELTADUST® INSECTICIDE

Product code (UVP) 05952247

SDS Number 102000004846

EPA Registration No. 432-772 Relevant identified uses of the substance or mixture and uses advised against

Use Insecticide

Restrictions on use See product label for restrictions.

Information on supplier

Supplier Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709

United States

Responsible Department Email: [email protected]

Emergency telephone no.

Emergency Telephone 1 -800-334-7577 Number (24hr/ 7 days)

Product Information 1-800-331-2867 Telephone Number

SECTION 2: HAZARDS IDENTIFICATION

Classification in accordance with regulation HCS 29CFR §1910.1200 This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Other hazards No other hazards known.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight Deltamethrin 52918-63-5 0.05 Crystalline quartz (respirable) 14808-60-7 2.50 Calcium carbonate 1317-65-3 95.4

Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 2/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.

Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed

Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Carbon dioxide (CO2), Dry chemical, Foam, Water

Unsuitable None known. Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing.

Further information Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Contain the spread of the fire-fighting media.

Flash point not applicable

Autoignition temperature no data available Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 3/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Dust explosion class no data available

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up

Methods for cleaning up Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle and open container in a manner as to prevent spillage. Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation.

Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities

Requirements for storage Store in a cool, dry place and in such a manner as to prevent cross areas and containers contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area.

Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 4/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Deltamethrin 52918-63-5 0.02 mg/m3 OES BCS* (TWA) Crystalline quartz 14808-60-7 0.025 mg/m3 02 2012 ACGIH (respirable) (TWA) (Respirable fraction.) Crystalline quartz 14808-60-7 0.05 mg/m3 2010 NIOSH (respirable) (REL) (Respirable dust.) Crystalline quartz 14808-60-7 0.1 mg/m3 1989 OSHA Z1A (respirable) (TWA) (Respirable dust.) Crystalline quartz 14808-60-7 0.1 mg/m3 06 2008 TN OEL (respirable) (TWA) (Respirable dust.) Crystalline quartz 14808-60-7 0.27ug/m3 03 2014 TX ESL (respirable) (AN ESL) Crystalline quartz 14808-60-7 14ug/m3 03 2014 TX ESL (respirable) (ST ESL) Crystalline quartz 14808-60-7 0.1 mg/m3 08 2010 US CA OEL (respirable) (TWA PEL) (Respirable dust.) Crystalline quartz 14808-60-7 0.3 mg/m3 08 2010 US CA OEL (respirable) (TWA PEL) (Total dust.) Crystalline quartz 14808-60-7 0.1 mg/m3 2000 Z3 (respirable) (TWA) (Respirable.) Crystalline quartz 14808-60-7 0.3 mg/m3 2000 Z3 (respirable) (TWA) (Total dust.) Crystalline quartz 14808-60-7 2.4millions of particles per 2000 Z3 (respirable) cubic foot of air (Respirable.) (TWA) Calcium carbonate 1317-65-3 5 mg/m3 2010 NIOSH (Respirable.) (REL) Calcium carbonate 1317-65-3 10 mg/m3 2010 NIOSH (Total) (REL) Calcium carbonate 1317-65-3 5 mg/m3 02 2006 OSHA Z1 (Respirable fraction.) (PEL) Calcium carbonate 1317-65-3 15 mg/m3 02 2006 OSHA Z1 (Total dust.) (PEL) Calcium carbonate 1317-65-3 5 mg/m3 1989 OSHA Z1A Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 5/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

(Respirable fraction.) (TWA) Calcium carbonate 1317-65-3 15 mg/m3 1989 OSHA Z1A (Total dust.) (TWA) Calcium carbonate 1317-65-3 15 mg/m3 06 2008 TN OEL (Total dust.) (TWA) Calcium carbonate 1317-65-3 5 mg/m3 06 2008 TN OEL (Respirable fraction.) (TWA) Calcium carbonate 1317-65-3 5ug/m3 03 2014 TX ESL (AN ESL) Calcium carbonate 1317-65-3 50ug/m3 03 2014 TX ESL (ST ESL)

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Safety glasses or Goggles

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

General protective measures Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance white

Physical State powder

Odor weak characteristic

Odour Threshold no data available pH no data available

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Bulk density ca. 55.5 lb/ft³(loose)

Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 6/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

Evapouration rate not applicable

Boiling Point not applicable Melting / Freezing Point not applicable

Water solubility soluble

Minimum Ignition Energy no data available

Decomposition no data available temperature

Partition coefficient: n- no data available octanol/water

Viscosity not applicable

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Dust explosion class no data available

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous No hazardous reactions known. reactions

Conditions to avoid no data available

Incompatible materials Strong acids

Hazardous decomposition no data available products

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Skin contact, Eye contact

Immediate Effects

Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 7/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

Skin May be harmful if absorbed through skin.

Information on toxicological effects

Acute oral toxicity LD50 (rat) > 5,050 mg/kg

Acute inhalation toxicity LC50 (rat) > 26.1 mg/l Exposure time: 4 h Determined in the form of dust.

LC50 (rat) > 100 mg/l Exposure time: 1 h Determined in the form of dust. Extrapolated from the 4 hr LC50.

Acute dermal toxicity LD50 (rabbit) > 2,020 mg/kg

Skin irritation No skin irritation (rabbit)

Eye irritation No eye irritation (rabbit)

Sensitisation Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity

Deltamethrin caused neurobehavioral effects and/or neuropathological changes in animal studies. The toxic effects of Deltamethrin are related to transient hyperactivity typical for pyrethroid neurotoxicity.

Assessment mutagenicity

Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment carcinogenicity

Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH

Crystalline quartz (respirable) 14808-60-7 Group A2

NTP

Crystalline quartz (respirable) 14808-60-7

IARC

Deltamethrin 52918-63-5 Overall evaluation: 3 Crystalline quartz (respirable) 14808-60-7 Overall evaluation: 1

OSHA

None.

Assessment toxicity to reproduction

Deltamethrin did not cause reproductive toxicity in a two-generation study in rats.

Assessment developmental toxicity

Deltamethrin caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Deltamethrin are related to maternal toxicity.

Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 8/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

Further information

Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.00091 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient deltamethrin.

Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.00056 mg/l invertebrates Exposure time: 48 h The value mentioned relates to the active ingredient deltamethrin.

Toxicity to aquatic plants EC50 (Algae) > 9.1 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient deltamethrin.

Biodegradability Deltamethrin: not rapidly biodegradable

Koc Deltamethrin: Koc: 10240000

Bioaccumulation Deltamethrin: Bioconcentration factor (BCF) 1,400 Does not bioaccumulate.

Mobility in soil Deltamethrin: Immobile in soil

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility. Follow advice on product label and/or leaflet.

Contaminated packaging Triple rinse containers. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke. Follow advice on product label and/or leaflet.

Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 9/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply.

SECTION 14: TRANSPORT INFORMATION

49CFR Not dangerous goods / not hazardous material

IMDG UN number 3077 Class 9 Packaging group III Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DELTAMETHRIN MIXTURE)

IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DELTAMETHRIN MIXTURE )

This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements.

Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-772 US Federal Regulations TSCA list Crystalline quartz (respirable) 14808-60-7 Calcium carbonate 1317-65-3 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 10/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

US States Regulatory Reporting CA Prop65 This product contains a chemical known to the State of California to cause cancer. Crystalline quartz (respirable) 14808-60-7

This product does not contain any substances known to the State of California to cause reproductive harm.

US State Right-To-Know Ingredients Crystalline quartz (respirable) 14808-60-7 MN Calcium carbonate 1317-65-3 MN

Canadian Regulations Canadian Domestic Substance List None.

Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label:

Signal word: Caution!

Hazard statements: May be harmful if absorbed through skin. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.

SECTION 16: OTHER INFORMATION

Abbreviations and acronyms 49CFR Code of Federal Regulations, Title 49 ACGIH US. ACGIH Threshold Limit Values CAS-Nr. Chemical Abstracts Service number EINECS European inventory of existing commercial substances ELINCS European list of notified chemical substances IARC US. IARC Monographs on Occupational Exposures to Chemical Agents IATA International Air Transport Association IMDG International Maritime Dangerous Goods Bayer Environmental Science

SAFETY DATA SHEET

DELTADUST® INSECTICIDE 11/11 Version 4.0 / USA Revision Date: 10/06/2015 102000004846 Print Date: 10/07/2015

N.O.S. Not otherwise specified NTP US. National Toxicology Program (NTP) Report on Carcinogens OECD Organization for Economic Co-operation and Development TDG Transportation of Dangerous Goods TWA Time weighted average UN United Nations WHO World health organisation

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 0 Instability - 0 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 0 Flammability - 0 Physical Hazard - 0 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: The following sections have been revised: Section 15: Regulatory information.

Revision Date: 10/06/2015

This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 1/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier

Trade name DRIONE® INSECTICIDE

Product code (UVP) 05938473

SDS Number 102000002537

EPA Registration No. 432-992 Relevant identified uses of the substance or mixture and uses advised against

Use Insecticide

Restrictions on use See product label for restrictions.

Information on manufacturer

Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States Emergency telephone no.

Emergency Telephone 1-800-334-7577 (24 hours/day) Number (24hr/ 7 days)

Product Information 1-800-331-2867 Telephone Number

SDS Information or Request [email protected]

SECTION 2: HAZARDS IDENTIFICATION

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight Pyrethrins including cinerins 8003-34-7 1.00 Piperonyl butoxide 51-03-6 10.00 Silica, amorphe 7631-86-9 40.00

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 2/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Symptoms Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea., Ingestion of larger amounts may cause defects to the central nervous system (e.g. dizziness, headache). Indication of any immediate medical attention and special treatment needed

Risks Contains hydrocarbon solvents. May pose an aspiration pneumonia hazard.

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Carbon dioxide (CO2), Dry chemical, Foam, Water

Unsuitable None known.

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 3/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

Special hazards arising Dangerous gases are evolved in the event of a fire. from the substance or mixture Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing. In the event of fire and/or explosion do not breathe fumes.

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Dust explosion class no data available

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Remove all sources of ignition. Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation. Handle and open container in a manner as to prevent spillage.

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 4/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

Advice on protection Take measures to prevent the build up of electrostatic charge. against fire and explosion

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Pyrethrins including cinerins 8003-34-7 5 mg/m3 OES BCS* (TWA) Pyrethrins including cinerins 8003-34-7 5 mg/m3 02 2012 ACGIH (TWA) Pyrethrins including cinerins 8003-34-7 5 mg/m3 2010 NIOSH (REL) Pyrethrins including cinerins 8003-34-7 5 mg/m3 02 2006 OSHA Z1 (PEL) Pyrethrins including cinerins 8003-34-7 5 mg/m3 1989 OSHA Z1A (TWA) Pyrethrins including cinerins 8003-34-7 5 mg/m3 06 2008 TN OEL (TWA) Pyrethrins including cinerins 8003-34-7 50ug/m3 07 2011 TX ESL (ST ESL) Pyrethrins including cinerins 8003-34-7 5ug/m3 07 2011 TX ESL (AN ESL) Pyrethrins including cinerins 8003-34-7 5 mg/m3 08 2010 US CA OEL (TWA PEL) Piperonyl butoxide 51-03-6 500 ppm OES BCS* (TWA) Silica, amorphe 7631-86-9 6 mg/m3 2010 NIOSH (REL) Silica, amorphe 7631-86-9 27ug/m3 02 2013 TX ESL (Particulate.) (ST ESL) Silica, amorphe 7631-86-9 2ug/m3 02 2013 TX ESL (Particulate.) (AN ESL) Silica, amorphe 7631-86-9 0.8 mg/m3 2000 Z3 Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 5/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

(TWA) Silica, amorphe 7631-86-9 20millions of particles per 2000 Z3 cubic foot of air (TWA) Distillates (petroleum), 64742-47-8 200 mg/m3 02 2012 ACGIH hydrotreated light (TWA) (Non-aerosol.) Distillates (petroleum), 64742-47-8 200 mg/m3 02 2012 ACGIH hydrotreated light (TWA) (Non-aerosol.) Distillates (petroleum), 64742-47-8 100 mg/m3 2010 NIOSH hydrotreated light (REL) Distillates (petroleum), 64742-47-8 350ug/m3 07 2011 TX ESL hydrotreated light (AN ESL) Distillates (petroleum), 64742-47-8 3500ug/m3 07 2011 TX ESL hydrotreated light (ST ESL)

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"

Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Tightly fitting safety goggles

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance white to light yellow

Physical State powder

Odor very faint

Odour Threshold no data available pH no data available Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 6/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Bulk density 12.2 lb/ft³

Evapouration rate not applicable

Boiling Point not applicable Melting / Freezing Point not applicable

Water solubility insoluble

Minimum Ignition Energy no data available

Decomposition no data available temperature

Partition coefficient: n- no data available octanol/water

Viscosity not applicable

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Dust explosion class no data available

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous No hazardous reactions when stored and handled according to reactions prescribed instructions.

Conditions to avoid Exposure to moisture.

Incompatible materials no data available

Hazardous decomposition No decomposition products expected under normal conditions of use. products

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 7/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Eye contact, Skin Absorption, Ingestion, Inhalation

Immediate Effects Eye Moderate eye irritation.

Skin Harmful if absorbed through skin. May cause slight irritation.

Ingestion Ingestion of large amounts may be harmful (see Signs and Symptoms).

Inhalation Inhalation may cause irritation of nasal passages. Information on toxicological effects

Acute oral toxicity LD50 (rat) > 5,000 mg/kg

Acute inhalation toxicity LC50 (rat) > 5.4 mg/l Exposure time: 4 h Determined in the form of dust.

LC50 (rat) > 20 mg/l Exposure time: 1 h Determined in the form of dust. Extrapolated from the 4 hr LC50.

Acute dermal toxicity LD50 (rabbit) > 2,000 mg/kg

Skin irritation Slight irritation (rabbit)

Eye irritation Mild eye irritation. (rabbit)

Sensitisation Non-sensitizing. (guinea pig) OECD Test Guideline 406, Buehler test

Repeated dose toxicity Chronic toxicity

Assessment repeated dose toxicity

Pyrethrin did not cause specific target organ toxicity in experimental animal studies. Piperonyl butoxide did not cause specific target organ toxicity in experimental animal studies.

Assessment Mutagenicity

Pyrethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Piperonyl butoxide was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity

Pyrethrin was not carcinogenic in lifetime feeding studies in rats and mice. Piperonyl butoxide was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH

Pyrethrins including cinerins 8003-34-7 Group A4

NTP

None.

IARC

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 8/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

Piperonyl butoxide 51-03-6 Overall evaluation: 3 Silica, amorphe 7631-86-9 Overall evaluation: 3

OSHA

None.

Assessment toxicity to reproduction

Pyrethrin did not cause reproductive toxicity in a two-generation study in rats. Piperonyl butoxide did not cause reproductive toxicity in a two-generation study in rats.

Assessment developmental toxicity

Pyrethrin did not cause developmental toxicity in rats and rabbits. Piperonyl butoxide did not cause developmental toxicity in rats and rabbits.

Further information

Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Biodegradability Pyrethrin: ; not rapidly biodegradable Piperonyl butoxide: ; not rapidly biodegradable

Koc Pyrethrin: Koc: 12472 - 74175 Piperonyl butoxide: Koc: 399 - 830

Bioaccumulation Pyrethrin: Bioconcentration factor (BCF) 471; Does not bioaccumulate. Piperonyl butoxide: ; Potential bioaccumulation

Mobility in soil Pyrethrin: Immobile in soil Piperonyl butoxide: Moderately mobile in soils

Environmental precautions Do not allow to get into surface water, drains and ground water. Do not apply when weather conditions favor runoff or drift. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. Apply this product as specified on the label.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Do not contaminate water, food, or feed by disposal. Follow container label instructions for disposal of wastes generated during use in compliance with the product label. Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 9/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

Never place unused product down any indoor or outdoor drain.

Contaminated packaging Completely empty container into application equipment, then dispose of empty container in a sanitary landfill, by incineration or by other procedures approved by state/provincial and local authorities. If burned, stay out of smoke. Follow advice on product label and/or leaflet.

SECTION 14: TRANSPORT INFORMATION

49CFR UN number 3077 Class 9 Packaging group III Marine pollutant Marine pollutant Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (PYRETHRINS) RQ Reportable Quantity is reached with 100 lb of product.

IMDG UN number 3077 Class 9 Packaging group III Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRETHRINS MIXTURE)

IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (PYRETHRINS MIXTURE )

Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON

Bayer Environmental Science SAFETY DATA SHEET

DRIONE® INSECTICIDE 10/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-992 US Federal Regulations TSCA list Piperonyl butoxide 51-03-6 Silica, amorphe 7631-86-9 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting Piperonyl butoxide 51-03-6 1.0% US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm.

US State Right-To-Know Ingredients Pyrethrins including cinerins 8003-34-7 CA, CT, MN, RI Piperonyl butoxide 51-03-6 NJ Silica, amorphe 7631-86-9 CA, MN

Canadian Regulations Canadian Domestic Substance List Pyrethrins including cinerins 8003-34-7 Piperonyl butoxide 51-03-6 Silica, amorphe 7631-86-9

Environmental CERCLA Pyrethrins including cinerins 8003-34-7 1 lbs Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

International Regulations European Inventory of Existing Commercial Substances (EINECS) Pyrethrins including cinerins 8003-34-7 Piperonyl butoxide 51-03-6 Silica, amorphe 7631-86-9

DRIONE® INSECTICIDE 11/11 Version 3.0 / USA Revision Date: 12/11/2014 102000002537 Print Date: 04/28/2015

Signal word: Caution!

Hazard statements: Harmful if absorbed through skin. Moderate eye irritation. Avoid contact with skin, eyes and clothing. Avoid breathing dust.

SECTION 16: OTHER INFORMATION

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 2 Instability - 0 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 2 Physical Hazard - 0 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200)

Revision Date: 12/11/2014

DYLOX® 6.2 GRANULAR INSECTICIDE 1/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier Trade name DYLOX® 6.2 GRANULAR INSECTICIDE Product code (UVP) 04399137 SDS Number 102000012263 EPA Registration No. 432-1308

Relevant identified uses of the substance or mixture and uses advised against Use Insecticide Restrictions on use See product label for restrictions.

Information on manufacturer Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States

Emergency telephone no. All Emergencies, 24hr/ 7 days 1-800-334-7577

Product Information Telephone No.

SDS Information or Request [email protected]

SECTION 2: HAZARDS IDENTIFICATION

Classification in accordance with regulation HCS 29CFR §1910.1200 Acute toxicity (Inhalation): Category 4 Eye irritation : Category 2B

Signal word: Warning

Hazard statements Harmful if inhaled. Causes eye irritation.

Precautionary statements Avoid breathing dust. Use only outdoors or in a well-ventilated area. Wash face, hands and any exposed skin thoroughly after handling. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 2/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Other hazards This product contains an cholinesterase inhibitor.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Average % by Weight Trichlorfon 52-68-6 6.20

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Inhalation, dermal absorption or ingestion of this product may result in systemic intoxication due to inhibition of the enzyme cholinesterase. Symptoms of poisoning may only appear several hours later.

Inhalation If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Move to fresh air. Keep patient warm and at rest.

Skin contact Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated clothing and shoes immediately. Call a physician or poison control center immediately.

Ingestion Never give anything by mouth to an unconscious person. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Rinse out mouth and give water in small sips to drink. Call a physician or poison control center immediately.

Most important symptoms and effects, both acute and delayed

Symptoms This product causes reversible cholinesterase inhibition without long term effects., Repeated overexposure may cause more severe cholinesterase inhibition with more pronounced symptoms.

The symptoms of cholinesterase inhibition include:

Nausea, Salivation, Lachrymation, Blurred vision, Constriction of pupils Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 3/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

Indication of any immediate medical attention and special treatment needed

Risks This product contains an anticholinesterase compound. Do not use if under medical advice not to work with such compounds.

Treatment The following antidotes are generally accepted: atropin and oximes.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable None known.

Special hazards arising Dangerous gases are evolved in the event of a fire., In the event of from the substance or fire the following may be released:, Chloral mixture

Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing.

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 4/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Isolate hazard area. Avoid dust formation. Methods and materials for containment and cleaning up

Methods for cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal. Scrub contaminated area with detergent and bleach solution. Flush with water. Contaminated soil may have to be removed and disposed.

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle and open container in a manner as to prevent spillage. Use only in area provided with appropriate exhaust ventilation. Avoid contact with skin, eyes and clothing.

Conditions for safe storage, including any incompatibilities

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Trichlorfon 52-68-6 0.28 mg/m3 OES BCS* (TWA) Trichlorfon 52-68-6 1 mg/m3 02 2012 ACGIH (Inhalable fraction.) (TWA) Trichlorfon 52-68-6 1 ug/m3 07 2011 TX ESL (AN ESL) Trichlorfon 52-68-6 10 ug/m3 07 2011 TX ESL (ST ESL) *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 5/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Safety glasses with side-shields or Goggles

Skin and body protection Long-sleeved shirt and long pants Shoes plus socks

General protective Follow manufacturer's instructions for cleaning/maintaining PPE. If measures no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance tan

Physical State granular

Odor sweet

Odour Threshold no data available

pH ca. 4.6 (1 %)

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Bulk density 30 - 35 lb/ft³

Evapouration rate not applicable

Boiling Point not applicable

Melting / Freezing Point not applicable

Water solubility no data available

Minimum Ignition Energy no data available

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 6/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

Decomposition no data available temperature

Partition coefficient: n- no data available octanol/water

Viscosity not applicable

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under normal conditions.

Possibility of hazardous No hazardous reactions when stored and handled according to reactions prescribed instructions.

Conditions to avoid Exposure to moisture.

Incompatible materials Strong oxidizing agents, Bases

Hazardous decomposition Chloral products Dimethyl hydrogen phosphite Carbon monoxide Oxides of phosphorus

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Eye contact, Skin Absorption, Skin contact, Inhalation

Immediate Effects Eye Moderate eye irritation.

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 7/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

Ingestion Harmful if swallowed.

Inhalation Harmful if inhaled.

Information on toxicological effects

Acute oral toxicity LD50 (male rat) > 5,100 mg/kg

LD50 (female rat) > 5,000 mg/kg

Acute inhalation toxicity LC50 (male/female combined rat) > 2 mg/l Exposure time: 4 h Determined in the form of dust.

LC50 (male/female combined rat) > 8 mg/l Exposure time: 1 h Determined in the form of dust. Extrapolated from the 4 hr LC50.

Acute dermal toxicity LD50 (male/female combined rat) > 5,000 mg/kg

Skin irritation No skin irritation (rabbit)

Eye irritation Mild eye irritation. (rabbit)

Sensitisation Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity Trichlorfon did not cause specific target organ toxicity in experimental animal studies.

Assessment Mutagenicity Trichlorfon was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity Trichlorfon was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH None.

NTP None.

IARC None.

OSHA None.

Assessment toxicity to reproduction Trichlorfon is not considered a reproductive toxicant at non-maternally toxic dose levels.

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 8/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

Assessment developmental toxicity Trichlorfon did not cause developmental toxicity in rats and rabbits.

Further information Only acute toxicity studies have been performed on the formulated product.

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Leuciscus idus (Golden orfe)) 0.52 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient trichlorfon.

LC50 (Rainbow trout (Oncorhynchus mykiss)) 0.7 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient trichlorfon.

Toxicity to aquatic LC50 (Water flea (Daphnia magna)) 0.00096 mg/l invertebrates Exposure time: 48 h The value mentioned relates to the active ingredient trichlorfon.

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus) 347 mg/l Exposure time: 72 h The value mentioned relates to the active ingredient trichlorfon.

Environmental precautions Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not allow to get into surface water, drains and ground water. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent sites. Apply this product as specified on the label.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility.

Contaminated packaging Empty remaining contents. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke.

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 9/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

SECTION 14: TRANSPORT INFORMATION

49CFR UN number 3077 Class 9 Packaging group III Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (TRICHLORFON) RQ Reportable Quantity is reached with 1,612 lb of product.

IMDG UN number 3077 Class 9 Packaging group III Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TRICHLORFON MIXTURE)

IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TRICHLORFON MIXTURE )

Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1308 US Federal Regulations TSCA list None. Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 10/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting Trichlorfon 52-68-6 1.0% US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients Trichlorfon 52-68-6 CA, CT, NJ

Canadian Regulations Canadian Domestic Substance List Trichlorfon 52-68-6

Environmental CERCLA Trichlorfon 52-68-6 100 lbs Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

International Regulations European Inventory of Existing Commercial Substances (EINECS) Trichlorfon 52-68-6

Signal word: Caution!

Hazard statements: Causes eye irritation. Cholinesterese inhibitor Avoid contact with skin, eyes and clothing. Avoid breathing dust or spray mist. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

SECTION 16: OTHER INFORMATION

Bayer Environmental Science SAFETY DATA SHEET

DYLOX® 6.2 GRANULAR INSECTICIDE 11/11 Version 3 / USA Revision Date: 09/12/2013 102000012263 Print Date: 01/05/2017

NFPA 704 (National Fire Protection Association): Health - 2 Flammability - 1 Instability - 1 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 1 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: The following sections have been revised: Section 5: Fire Fighting Measures. Section 9: Physical and Chemical Properties.

Revision Date: 09/12/2013

Individual protection measures: Wear long pants, shoes, socks and SAFETY DATA SHEET waterproof gloves when handling this product. Follow manufacturer’s instructions for cleaning/maintaining PPE, or else wash with detergent and Section 1: Identification hot water. Keep and wash PPE separately from other laundry. Remove ® PPE immediately after handling this product. Wash the outside of gloves Product identifier: FirstStrike Soft Bait before removing. Wash hands thoroughly after applying bait and before Other identifier(s): EPA Registration Number 7173-258 eating, drinking, chewing gum, using tobacco or using the toilet, and change Uses or restrictions: Rodenticide with difethialone into clean clothing. Manufacturer: Liphatech, Inc. Section 9: Physical and Chemical Properties 3600 W. Elm Street, Milwaukee, WI 53209 Emergency phone: 800-351-1476 Monday - Friday 8:00 am - 4:30 pm Appearance: Soft paste, blue color, raw grain odor. Odor threshold not (US Central time zone) determined. After hours: Call CHEMTREC at 1-800-424-9300 Water solubility: Negligible pH: Not applicable Relative density: 1.11 g/cc Viscosity: Not applicable Section 2: Hazard Identification % Volatile (volume): Not applicable Evaporation rate: Not applicable Hazard class: Specific Target Organ Toxicity (Single exposure), Category 2; Vapor density: Not applicable Vapor pressure: Not applicable Specific Target Organ Toxicity (Repeated exposure), Category 2 Boiling point: Not determined Freezing point: Not applicable Warning: May cause damage to blood and reduce the clotting Flash point (ASTM D92): >150 oC Autoignition temp.: Not determined ability of blood if swallowed, inhaled or absorbed through skin. Flammability: Not a flammable solid Decomposition temp.: Not determined Do not breathe dust. Do not eat, drink or smoke when using this Explosive limits - Lower limit: Not applicable; Upper limit: Not applicable product. Wash hands thoroughly after handling. If exposed or if Partition coefficient (n-octanol/water): Not applicable you feel unwell, call a poison control center or doctor. Dispose of container Section 10: Stability and Reactivity and contents according to instructions on product label. Store locked up. Reactivity: Not reactive, not sensitive to shock or static discharge Section 3: Composition / Information on Ingredients Chemical stability: Stable Hazardous reactions: None Hazardous ingredients: Incompatible materials: None Conditions to avoid: None Difethialone (CAS registry no. 104653-34-1) ...... 0.0025% Hazardous decomposition products: Oxides of carbon Section 4: First Aid Measures Section 11: Toxicological Information Likely routes of exposure: Ingestion, skin absorption. Emergency overview: This material may reduce the clotting ability of the Symptoms of toxicity: Lethargy, loss of appetite, reduced clotting ability of blood and cause bleeding. Symptoms of toxicity include lethargy, loss of blood, and bleeding. appetite, reduced clotting ability of blood, and bleeding. Have the product Eye effects/eye irritation: Mild, transient irritant label with you when obtaining treatment advice. Acute oral effects: LD50 (oral-rat): >5000 mg/kg If swallowed: Call a poison control center or doctor. Have person sip a glass Acute inhalation effects: LC50 (rat, 4 hour): 200 mg/L (extrapolated) of water if able to swallow. Do not induce vomiting unless told to do so by Acute dermal effects: LD50 (dermal-rabbit): >2000 mg/kg the poison control center or doctor. Skin irritation: Non-irritating If inhaled: Move person to fresh air. If person is not breathing, call an Skin sensitization: Not a skin sensitizer ambulance, then give artificial respiration and call poison control or doctor. Carcinogenicity: No ingredient listed by NTP, IARC or OSHA If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then Section 12: Ecological Information continue rinsing eye. Call a poison control center or doctor. This product is extremely toxic to birds and mammals. Do not apply this If on skin or clothing: Take off contaminated clothing. Rinse skin with plenty product directly to water, where surface water is present or to intertidal areas of cool water for 15-20 minutes. Call a poison control center or doctor. below the mean high water mark. Carefully follow label cautions and Note to Physician or Veterinarian: Contains anticoagulant ingredient. For directions to reduce hazards to children, pets and non-target wildlife. humans or animals ingesting bait and/or showing obvious poisoning Section 13: Disposal Considerations symptoms (bleeding or prolonged prothrombin times), give Vitamin K1 intramuscularly or orally. In severe cases, blood transfusions may be needed. Disposal: Wastes resulting from the use of this product according to the label instructions must be disposed of as specified on the product label. Section 5: Fire-fighting Measures RCRA waste status: This product is not regulated as a hazardous waste Extinguishing media: Use media suitable for the surrounding fire under Federal law. State and local regulation may affect the disposal of this Specific fire or explosion hazards: None known product. Consult your state or local environmental agency for disposal of Special cautions for firefighters: Wear self-contained breathing apparatus waste generated other than by use according to label instructions. (full facepiece) & full protective clothing. Contain runoff to prevent pollution. Section 14: Transport Information Section 6: Accidental Release Measures Transportation data (49 CFR): This product is not regulated as a Precautions, PPE and Procedures: Wearing PPE as specified in Section 8, hazardous material for all modes of transportation within the U.S. isolate and contain spill. Limit access to spill area to necessary personnel. Hazard Class, Packing Group and UN ID No.: Not applicable Do not allow spilled material to enter sewers, streams or other waters. Section 15: Regulatory Information Methods and materials: Scoop up spilled material and place in a closed, labeled container for use according to label instructions or disposal. TSCA: All components of this product are listed on the TSCA inventory. SARA section 313: Contains no reportable components. Section 7: Handling and Storage CA Proposition 65: Contains no substances subject to Prop 65 requirements. Precautions for safe handling: Read the entire product label before using FIFRA: This product is registered as a pesticide with the U.S. Environmental this rodenticide. Conditions for safe storage: Store in original container in Protection Agency. The label requirements under Federal pesticide law differ a cool, dry area out of reach of children, pets and domestic animals. Do not from the classification criteria and hazard information required by OSHA on contaminate water, food or feed. Keep container tightly closed. Do not this Safety Data Sheet. Read and follow all cautions, directions and use remove or destroy the product label. restrictions on the product label on the container. Section 8: Exposure Controls / Personal Protection Section 16: Other Information Established exposure limits: Not applicable Prepared by: T. Schmit Date: 1 July 2016 Appropriate engineering controls: Special ventilation is not required for This Safety Data Sheet is believed to be accurate at time of publication. No warranty, expressed or implied, is made with regard to this information. This information may not the normal handling and use of this product when following label instructions. be adequate for every application, and the user must determine the suitability of this information due to the manner or conditions of use or storage, or local regulation. MATERIAL SAFETY DATA SHEET FIRSTLINE™ TERMITE BAIT

MSDS Ref. No.: 4151-50-2-4 Date Approved: 08/18/2004 Revision No.: 4

This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The information contained herein is for the concentrate as packaged, unless otherwise noted.

1. PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: FIRSTLINE™ TERMITE BAIT PRODUCT CODE: 1629 ACTIVE INGREDIENT(S): Sulfluramid CHEMICAL FAMILY: Fluoroaliphatic sulfonamide

MOLECULAR FORMULA: C10H6F17NO2S (sulfluramid) SYNONYMS: FMC 66898; GX071; F1898; N-ethyl perfluorooctanesulfonamide; IUPAC: N-ethyl perfluoro-octane-1-sulfonamide

MANUFACTURER EMERGENCY TELEPHONE NUMBERS FMC CORPORATION (800) 424-9300 (CHEMTREC - U.S.A. & Canada) Agricultural Products Group (202) 483-7616 (CHEMTREC - All Other Countries) 1735 Market Street (800) 331-3148 (FMC - U.S.A. & Canada) Philadelphia, PA 19103 (716) 735-3765 (Reverse charges - FMC) (800) 321-1362 (General Information)

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: • Brown to tan, odorless, solid (cardboard treated with 100 ppm). • Combustible. Will support combustion at elevated temperatures. • Thermal decomposition and burning may form toxic by-products. • For large exposures or fire, wear personal protective equipment. • Slightly toxic to fish and aquatic organisms. Keep out of drains and water courses.

POTENTIAL HEALTH EFFECTS: Effects from overexposure result from swallowing this product. Symptoms of overexposure include diarrhea.

MEDICAL CONDITIONS AGGRAVATED: None presently known.

Page 1 of 7

FIRSTLINE™ TERMITE BAIT (4151-50-2-4) Date: 08/18/2004

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name CAS# Wt.% EC No. EC Class Sulfluramid 4151-50-2 0.01 223-980-3 Not classified

4. FIRST AID MEASURES EYES: Flush with plenty of water. Get medical attention if irritation occurs and persists.

SKIN: Wash with plenty of soap and water.

INGESTION: Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. If any discomfort persists, obtain medical attention.

INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain medical attention.

NOTES TO MEDICAL DOCTOR: This product is expected to have low oral, dermal and inhalation toxicity. It is expected to be practically non-irritating to the skin and eyes. Treatment is otherwise controlled removal of exposure followed by symptomatic and supportive care.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if necessary. Contain all runoff.

FIRE / EXPLOSION HAZARDS: Combustible. May support combustion at elevated temperatures.

FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors generated.

Page 2 of 7 FIRSTLINE™ TERMITE BAIT (4151-50-2-4) Date: 08/18/2004

6. ACCIDENTAL RELEASE MEASURES

RELEASE NOTES: Wear protective clothing and personal protective equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons and animals out of the area. To clean spill area, wash with a solution of soap and water. Sweep or scrape up material, place it into a container, and label contents. Dispose of containerized wastes according to the method given in Section 13, "Disposal Considerations".

7. HANDLING AND STORAGE HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Do not use or store near heat, open flame or hot surfaces. Store in original containers only. Keep out of reach of children and animals. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS: Use local exhaust at all process locations where dust may be emitted. Ventilate all transport vehicles prior to unloading.

PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: For dust exposure, wear chemical protective goggles or a face shield.

RESPIRATORY: For dust exposure wear, as a minimum, a properly fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S. NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection must be based on airborne concentrations.

PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills, wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and watchbands - that become contaminated should be removed and destroyed. Launder all work clothing before reuse (separately from household laundry).

GLOVES: Wear chemical protective gloves made of materials such as rubber, neoprene or nitrile. Thoroughly wash the outside of gloves with soap and water prior to removal. Inspect regularly for leaks.

WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking or using tobacco. Shower at the end of the workday.

Page 3 of 7 FIRSTLINE™ TERMITE BAIT (4151-50-2-4) Date: 08/18/2004

9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Odorless APPEARANCE: Brown to tan solid (cardboard 100 ppm) MOLECULAR WEIGHT: 527.2 (sulfluramid) SOLUBILITY IN WATER: Insoluble

10. STABILITY AND REACTIVITY

CONDITIONS TO AVOID: Excessive heat and fire. STABILITY: Stable POLYMERIZATION: Will not occur HAZARDOUS DECOMPOSITION PRODUCTS: May produce hydrogen fluoride.

11. TOXICOLOGICAL INFORMATION EYE EFFECTS: Expected to be practically non-irritating.

SKIN EFFECTS: Expected to be practically non-irritating.

DERMAL LD50: > 2,000 mg/kg (rat)

ORAL LD50: > 5,000 mg/kg (rat)

INHALATION LC50: Sulfluramid: > 4.4 mg/l (4 h) (rat)

SENSITIZATION: A similarly-formulated product produces moderate skin sensitization in laboratory animals, and may produce similar effects in humans.

ACUTE EFFECTS FROM OVEREXPOSURE: This product is expected to have low oral, dermal and inhalation toxicity. It is expected to be practically non-irritating to the skin and eyes. Large doses of a similarly-formulated product, administered to laboratory animals, have produced symptoms such as diarrhea and abdominogenital staining.

CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the formulation. In a battery of tests, sulfluramid was shown to be non-mutagenic. Sulfluramid was shown to be non-teratogenic in developmental toxicity studies with laboratory animals. Preliminary studies in dogs suggest that the ingestion of high doses for prolonged periods may arrest spermatogenesis.

Page 4 of 7 FIRSTLINE™ TERMITE BAIT (4151-50-2-4) Date: 08/18/2004

CARCINOGENICITY: NTP: Not listed IARC: Not listed OSHA: Not listed OTHER: (ACGIH) Not listed

COMMENTS: The data presented above are for a similarly-formulated product, or for the active ingredient, as noted.

12. ECOLOGICAL INFORMATION Unless otherwise indicated, the data presented below are for the active ingredient.

ENVIRONMENTAL DATA: Sulfluramid has a Log Pow of >6.85, is considered immobile in soil, and is unlikely to enter groundwater.

ECOTOXICOLOGICAL INFORMATION: Sulfluramid is considered slightly toxic to fish and aquatic arthropods (LC50 values >6.6 - 10 mg/L). The toxicity to birds is considered moderate by single oral exposure, but high when the exposure is via the diet. The oral LD50 in bobwhite quail is 474 mg/kg, while the dietary LC50 is 300 ppm. The dietary LC50 in the mallard is 165 ppm.

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited. Empty containers can be disposed of with ordinary household trash, as per label recommendations.

EMPTY CONTAINER: For larger quantities, as in the case of spills, the preferred method of disposal is to incinerate in accordance with local, state and national laws and regulations. If this method is not available, then dispose of empty container in a sanitary landfill. However, because acceptable methods of disposal may vary by location, and regulatory requirements may change, contact the appropriate regulatory authority prior to disposal.

14. TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (DOT)

PACKAGING TYPE: Non-Bulk

Page 5 of 7 FIRSTLINE™ TERMITE BAIT (4151-50-2-4) Date: 08/18/2004

ADDITIONAL INFORMATION: This material is not a hazardous material as defined by US Department of Transportation at 49 CFR Parts 100 through 185.

15. REGULATORY INFORMATION UNITED STATES

SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed

SECTION 311 HAZARD CATEGORIES (40 CFR 370): Immediate, Delayed

SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): There are no ingredients in this product, which are subject to Section 313 reporting requirements.

CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT)

CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4): Not listed

FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT U.S. EPA Signal Word: CAUTION

INTERNATIONAL LISTINGS Australian Hazard Code: 3XE

16. OTHER INFORMATION

REVISION SUMMARY: This MSDS replaces Revision #3, dated July 23, 2003. Changes in information are as follows: New Format, as well as: Section 3 (Composition / Information on Ingredients)

Page 6 of 7 FIRSTLINE™ TERMITE BAIT (4151-50-2-4) Date: 08/18/2004

Section 14 (Transport Information) Section 16 (Other Information)

FirstLine and FMC Logo - FMC Trademarks

FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

Page 7 of 7 Date Issued: June, 2010 Supersedes: March, 2006

MATERIAL SAFETY DATA SHEET ZOECON GENTROL® IGR CONCENTRATE

Manufacturer: Wellmark International Address: 1501 E. Woodfield Rd., Suite 200W, Schaumburg, IL 60173 Emergency Phone: 1-800-248-7763 Transportation Emergency Phone: CHEMTREC: 1-800-424-9300

1. CHEMICAL PRODUCT INFORMATION

Product Name: Zoecon Gentrol® IGR Concentrate Chemical Name/Synonym: (S)-Hydroprene: (Ethyl(2E,4E,7S)-3,7,11-trimethyl-2,4-dodecadienoate Chemical Family: Isoprenoid Formula: C17 H30 O2 EPA Registration No.: 2724-351 RF Number: 259

2. COMPOSITION / INFORMATION ON INGREDIENTS

Component (chemical, common name) CAS Weight Tolerance Number (S)-Hydroprene: (Ethyl(2E,4E,7S)-3,7,11-trimethyl-2,4- 65733-18-8 9.0% Not established dodecadienoate) Inert ingredients (non hazardous and/or trade secret): 91.0% Not established

3. HAZARD INFORMATION PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS - CAUTION: KEEP OUT OF THE REACH OF CHILDREN. HARMFUL IF SWALLOWED OR ABSORBED THROUGH THE SKIN. CAUSES MODERATE EYE IRRITATION. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING.

SIGNS AND SYMPTOMS OF OVEREXPOSURE No known health conditions are aggravated by exposure to this product.

PRIMARY ROUTE OF ENTRY Dermal/Eye: Yes Oral: No Inhalation No

ACUTE TOXICITY Oral: No specific hazard identified Dermal: No specific hazard identified. May cause moderate skin irritation Inhalation: No specific hazard identified

OTHER TOXICOLOGICAL INFORMATION Skin Irritation: Avoid contact with skin. May cause skin irritation Eye Irritation: Avoid contact with eyes. May cause moderate eye irritation Sensitizer: Is not a sensitizer.

Page 1 of 4

4. FIRST AID MEASURES

If in eyes: • Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. • Call a poison control center or doctor for treatment advice.

If on Skin: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice.

If swallowed: • Immediately call a poison control center or doctor. • Do not induce vomiting unless told to by a poison control center or doctor. • Do not give any liquid to the person. • Do not give anything to an unconscious person.

If inhaled: • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice.

Note to Physician: Contains petroleum distillates. Vomiting may cause aspiration pneumonia.

5. FIRE FIGHTING MEASURES

NFPA Rating: Health: 2 Fire: 2 Reactivity: 0 Flammability Class: Class IIIB (flash point ≥ 200ºF) Flash Point: 200° F Explosive Limits (% of Volume): Not known Extinguishing Media: CO2, foam, water Special Protective Equipment: Firefighters should wear full protective equipment including self contained breathing apparatus. Fire Fighting Procedures: Normal procedures. Do not allow firefighting water to escape into waterways or sewers. Combustion Products: Oxides of carbon and oxides of sulfur. Unusual Fire/Explosion Hazards: None known

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken: Contain spill and do not allow to enter waterways. Soak up with absorbent material and place in a container for disposal. Absorbents: Clay granules, sawdust, dirt, or equivalent. Incompatibles: Strong oxidizers.

7. HANDLING AND STORAGE

Handling: Avoid inhalation of vapors and contact with skin, eyes, and clothing. Wash hands, arms and face thoroughly with soap and water after handling product. Do not use this product in or on an electrical portion of equipment due to possibility of shock hazard. Storage: Do not contaminate water, food, or feed by storage or disposal. Store in a cool area away from children.

Page 2 of 4

8. EXPOSURE CONTROL / PERSONAL MEASURES

Exposure Limits: Not established Ventilation: Use with adequate ventilation.

Personal Protective Equipment: If prolonged exposure is anticipated, it is recommended for handlers to wear impermeable gloves, goggles and other protective clothing to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor: Straw colored liquid with mild petroleum solvent odor. Boiling Point: Not known Melting Point: Not applicable Vapor Pressure (mm Hg): Not known Vapor Density (Air = 1): Not known Specific Gravity: 0.85 Bulk Density: 7.1 lbs/gal Solubility: Emulsifies in water Evaporation Rate: Not known pH: 6.22

10. STABILITY AND REACTIVITY

Stability: Stable Reactivity: Not reactive Incompatibility w/ Other Strong Oxidizers Materials: Decomposition Products: Carbon oxides, sulfur oxides Hazardous Polymerization: Will not occur

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY Acute oral toxicity: LD50 >5100 mg/kg Acute dermal toxicity: LD50 >2100 mg/kg Acute inhalation toxicity: 4-Hour LC50 >7.2 mg/L Skin irritation: Moderate irritant Eye irritation: Mild irritant

SUBCHRONIC TOXICITY [Specific to Active Ingredient(s)] In a 90-day subchronic feeding study in rats, the NOEL was 50 mg/kg/day. Changes in body weight and organ weights were observed at higher dose levels. Liver and ovaries were identifed as target organs. No immunotoxic effects were observed in a study in mice when (S)-Hydroprene was fed (diet) at dose levels up to and including 1,200 mg/kg/day, continuously for 30 days. CHRONIC TOXICITY/CARCINOGENICITY [Specific to Active Ingredient(s)] A chronic toxicity/carcinogenicity study in rats identified ovaries and the thyroid as target organs. An increased incidence of benign thyroid tumors was present in male rats only at the highest dose tested. Increased weights and macroscopic and microscopic changes in the ovaries were observed at the highest doses. NOEL for males was 1,000 ppm and for females 100 ppm.

Page 3 of 4

DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)] Parental reproductive performance in rats remained unaffected up to a dose level of 7,500 ppm, when evaluated in a 2- generation reproduction/toxicity study. Histologically, all females of 7,500 ppm dose group had cytoplasmic vacuolation in the ovaries, but without affecting reproductive performance. The NOEL for pup development was 1,500 ppm. No teratogenic or fetotoxic effects were observed in rats when pregnant animals were exposed (gavage) to (S)- Hydroprene at levels up to 1,000 mg/kg/day (highest dose tested). NOEL for maternal toxicity was 1,000 mg/kg/day. .

MUTAGENICITY [Specific to Active Ingredient(s)] (S)-Hydroprene has been found negative for mutagenicity potential. It has tested negative in: 1) Ames Test, 2) in vivo cytogenetic assay, 3) micronucleus test (in vivo) and in 4) test for DNA effects - UDS in rats (in vitro).

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL FATE [Active Ingredients Only] Hydrolysis: Not available Photolysis: Not available Soil half life: Not available Water solubility: <2 ppm, emulsifies in water

ECOTOXICITY [Active Ingredients Only] Acute Toxicity: Fish: Not available; Aquatic invertebrates: Not available

13. DISPOSAL CONSIDERATIONS

Wastes resulting from use of this product should be disposed of in accordance with all federal, state and local requirements. For additional regulatory information, see section 15 of this document. ANSPORT INFORMATION

14. TRANSPORT INFORMATION

DOT49CFR Description: Not regulated Freight Classification: Insecticides, other than poison, N.O.I. NMFC-155050 SUB 11 Class 70

15. REGULATORY INFORMATION

CERCLA (Superfund): Not regulated as hazardous RCRA: Not regulated as hazardous

SARA 311/312 HAZARD CATEGORIES Immediate Health: Yes (Irritant) Delayed Health: No Fire: No Sudden Pressure: No Reactivity: No

The information presented herein, while not guaranteed, was prepared by technically knowledgeable personnel and to the best of our knowledge is true and accurate. It is not intended to be all inclusive and the manner and conditions of use and handling may involve other or additional considerations.

Page 4 of 4 Date Issued: 9 February 2009 Supersedes: November, 2004

MATERIAL SAFETY DATA SHEET GENTROL® POINT SOURCE ROACH CONTROL DEVICE

Manufacturer: Wellmark International Address: 1501 East Woodfield Road, Suite 200-West Schaumburg, IL 60173 Emergency Phone: 1-800-248-7763 Transportation Emergency Phone: CHEMTREC: 1-800-424-9300

1. CHEMICAL PRODUCT INFORMATION

Product Name: Gentrol® Point Source Roach Control Device Chemical Name/Synonym: (S)-Hydroprene: (Ethyl(2E,4E,7S)-3,7,11-trimethyl-2,4-dodecadienoate Chemical Family: Isoprenoid Formula: C17 H30 O2 EPA Registration No.: 2724-469 RF Number:

2. COMPOSITION / INFORMATION ON INGREDIENTS

Component (chemical, common name) CAS Weight Tolerance Number (S)-Hydroprene: (Ethyl(2E,4E,7S)-3,7,11-trimethyl-2,4- 65733-18-8 90.6% Not established dodecadienoate) Inert ingredients (non hazardous and/or trade secret): 9.4% Not established

3. HAZARD INFORMATION

PRECAUTIONARY STATEMENT Caution: Keep out of the reach of children. Avoid contact with eyes. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

SIGNS AND SYMPTOMS OF OVEREXPOSURE

PRIMARY ROUTE OF ENTRY Dermal/Eye: Yes. Oral: No. Inhalation: No.

Due to the unique nature of the product form, acute toxicity hazards are not anticipated.

ACUTE TOXICITY Oral: Not Available. Dermal: Not Available. Inhalation: Not Available.

OTHER TOXICOLOGICAL INFORMATION Skin Irritation: Mild irritant (rabbit). Eye Irritation: Mild to moderate irritant (rabbit). Sensitizer: Positive skin sensitization in guinea pigs.

Gentrol® Point Source Roach Control Device

Page 1 of 4

4. FIRST AID MEASURES

Eye: Hold eye open and flush slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Wash affected area with soap and water. Get medical attention if irritation persists. Ingestion: Due to the product form, ingestion is unlikely, but if ingestion should occur, give 1-2 glasses of water to drink and induce vomiting by sticking finger down the throat. Repeat until vomitus is clear. Do not induce vomiting in an unconscious individual. Inhalation: Remove victim to fresh air. Note to Physician: Treat symptomatically.

5. FIRE FIGHTING MEASURES

NFPA Rating: Health: 0 Fire: 2 Reactivity: 0 Flammability Class: Combustible liquid (active ingredient). Flash Point: 182F/84C. Explosive Limits (% of Volume): Not known. Extinguishing Media: Water, foam, CO2, dry chemical. Special Protective Equipment: Firefighters should wear full protective equipment including self contained breathing apparatus. Fire Fighting Procedures: Normal procedures. Do not allow firefighting water to escape into waterways or sewers. Combustion Products: None known. Unusual Fire/Explosion Hazards: None known.

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken: Due to the product form, the possibilities of a spill are remote, but should one occur, sweep up spill and place in trash collection for disposal. Absorbents: Due to product form, absorbents should not be necessary. If mixed with a liquid, absorb with clay granules, sawdust, dirt or equivalent. Incompatibles: None known.

7. HANDLING AND STORAGE

Handling: Do not activate device until ready to use. This product may be used in areas where food is handled or prepared. Placements include areas for receiving, storage, packing, edible waste storage, machinery and enclosed processing systems. Serving areas would be considered as a food area. Do not place the device within three feet of any food handling or food preparation area. Storage: Do not contaminate water, food, or feed by storage. Store in cool area away from children.

Gentrol® Point Source Roach Control Device

Page 2 of 4

8. EXPOSURE CONTROL / PERSONAL MEASURES

Exposure Limits: Not established. Ventilation: Use with adequate ventilation. Personal Protective Equipment: None required. If prolonged exposure is anticipated it is recommended for a handler to wear impervious gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor: Clear round plastic station with a faint fruity odor. Boiling Point: Not known. Melting Point: Not applicable. Vapor Pressure (mm Hg): Less than 1 at 25C. Vapor Density (Air = 1): Not known. Specific Gravity: 0.89 (H2O=1). Bulk Density: 7.4 lbs/gal. Solubility: .54 ppm. Evaporation Rate: Less than butyl acetate. pH: Not applicable.

10. STABILITY AND REACTIVITY

Stability: Stable. Reactivity: Not reactive. Incompatibility w/ Other None known. Materials: Decomposition Products: None known. Hazardous Polymerization: Will not occur.

11. TOXICOLOGICAL INFORMATION

SUBCHRONIC TOXICITY [Specific to Active Ingredient(s)] In a 90-day subchronic feeding study in rats, the NOEL was 50 mg/kg/day. Changes in body weight and organ weights were observed at higher dose levels. Maximum tolerated dose (MTD) was suggested to be between 250 and 1,000 mg/kg/day. No immunotoxic effects were observed in a study in mice when (S)-Hydroprene was fed (diet) at dose levels up to and including 1,200 mg/kg/day, continuously for 30 days. DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)] Parental reproductive performance in rats remained unaffected up to a dose level of 7,500 ppm, when evaluated in a 2- generation reproduction/toxicity study. Histologically, all females of 7,500 ppm dose group had cytoplasmic vacuolation in the ovaries and regression of corpora lutea, but without affecting reproductive performance. The NOEL for pup development was 1,500 ppm. No teratogenic or fetotoxic effects were observed in rats when pregnant animals were exposed (gavage) to (S)-Hydroprene at levels up to 1,000 mg/kg/day (highest dose tested) during days 6 to 15 of gestation. NOEL for maternal toxicity was 1,000 mg/kg/day. Minor skeletal anomalies observed at lower dose levels were absent in the high dose animals, indicating an observation unrelated to the dose treatment. MUTAGENICITY [Specific to Active Ingredient(s)] (S)-Hydroprene is not a mutagen.

Gentrol® Point Source Roach Control Device

Page 3 of 4

12. ECOLO.12. ECOLOGICAL INFORMATION

ENVIRONMENTAL FATE [Active Ingredients Only] Hydrolysis: Not available. Photolysis: Not available. Soil half life: Not available. Water solubility: <2 ppm, emulsifies in water.

ECOTOXICITY [Active Ingredients Only] Acute Toxicity: fish:Not available; aquatic invertebrates:Not available.

13. DISPOSAL CONSIDERATIONS

Wastes resulting from use of this product should be disposed of in accordance with all federal, state and local requirements. For additional regulatory information, see section 15 of this document.

14. TRANSPORT INFORMATION

DOT49CFR Description: Not regulated under D.O.T. Freight Classification: Insecticides, N.O.I. o/t poison; NMFC I-102120.

15. REGULATORY INFORMATION

CERCLA (Superfund): Not regulated. RCRA: Not regulated as hazardous.

SARA 311/312 HAZARD CATEGORIES Immediate Health: Yes (Irritant). Delayed Health: No. Fire: Yes. Sudden Pressure: No. Reactivity: No.

Gentrol® Point Source Roach Control Device

Page 4 of 4 Date Issued: January 2011 Supersedes: November, 2004

MATERIAL SAFETY DATA SHEET

STARBAR GOLDEN MALRIN FLY BAIT Manufacturer: Wellmark International Address: 1501 E. Woodfield Rd., Suite 200-West, Schaumburg, IL 60173 Emergency Phone: 1-800-347-8272 Transportation Emergency Phone: CHEMTREC: 1-800-424-9300

1. CHEMICAL PRODUCT INFORMATION

Product Name: Starbar Golden Malrin Fly Bait Chemical Name/Synonym: Methomyl; S-methyl N-[(methylcarbamoyl)oxy]thioacetimidate Chemical Family: Carbamate Formula: C5 H10 N2 O2 S EPA Registration No.: 2724-274 RF Number: 128E

2. COMPOSITION/INFORMATION ON INGREDIENTS

Component (chemical, common name) CAS Weight Tolerance Number Methomyl: (S-Methyl N-[(methylcarbamoyl)oxy] thioacetimidate 16752-77-5 1% 2.5 mg/m3 (OSHA & ACGIH) (Z)-9 Tricosene 27519-02-4 0.049% Not established Inert ingredients (non-hazardous and/or trade secret) 98.851 Not established

3. HAZARD INFORMATION

PRECAUTIONARY STATEMENT KEEP OUT OF THE REACH OF CHILDREN CAUTION: HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH THE SKIN. AVOID BREATHING DUST. AVOID CONTACT WITH SKIN, EYES OR CLOTHING. DO NOT ALLOW CHILDREN INTO TREATED AREAS.

SIGNS AND SYMPTOMS OF OVEREXPOSURE Active ingredient is a cholinesterase inhibitor: may cause excessive sweating, salivation, nausea, vomiting, headaches, diarrhea, slurred speech, muscle twitching, pin-point pupils, ataxia, tightness in chest, vomiting, cyanosis, pulmonary edema.

PRIMARY ROUTE OF ENTRY Dermal/Eye: No Oral: Yes Inhalation: Yes

ACUTE TOXICITY Oral: LD50 (rat): 3,106 mg/kg Dermal: LD50 (rabbit): >2,100 mg/kg (highest dose level tested) Inhalation: Unknown

«PN2» Page 1 of 4

OTHER TOXICOLOGICAL INFORMATION Skin Irritation: Non-irritating (rabbit) Eye Irritation: Very minimal (rabbit) Sensitizer: Not considered a sensitizer

4. FIRST AID MEASURES Eye: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 – 20 minutes Ingestion: Immediately call poison control center or doctor for advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by poison control center or doctor. Do not give anything by mouth to an unconscious person. Inhalation: Remove to clear air area. Note to Physician: Methomyl is a cholinesterase inhibitor. Atropine is antidotal. Where symptoms are visible, atropine I.V. to effect is suggested.

5. FIRE FIGHTING MEASURES

NFPA Rating: Health: 1 Fire: 0 Reactivity: 0 Flammability Class: Combustible solid Flash Point: Does not flash Explosive Limits (% of Volume): N/A Extinguishing Media: Water, foam, dry chemical, CO2 Special Protective Equipment: Fire fighters should wear full protective clothing including self-contained breathing apparatus. Fire Fighting Procedures: Normal procedures. Do not allow fire fighting water to escape into waterways or sewers. Combustion Products: Carbon monoxide Unusual Fire/Explosion Hazards: Will ignite if exposed to intense heat or open flame. Fire or intense heat may rupture container.

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken: Small amounts may be swept up and spread in planned use areas as directed on label or placed in container for disposal. Absorbents: If in liquid form, use clay granules, sawdust, dirt or equivalent. Incompatibles: Reactive metals, strong oxidizers

7. HANDLING AND STORAGE

Handling: Avoid breathing dust, avoid contact with skin, eyes or clothing. Wear the following personal protective clothing during loading, application, repairing, and cleaning of application equipment, and disposal of the pesticide: Long- legged pants; shoes and socks; gloves. Always wash hands, face and arms with soap and water before using tobacco products, eating, drinking, or toileting. Storage: Do not store near water, food, or feed. Store in a dry cool place not reachable by children.

«PN2» Page 2 of 4

8. EXPOSURE CONTROL/PERSONAL MEASURES

Exposure Limits: Methomyl = 2.5 mg/m3 (OSHA PEL & ACGIH TLV) Ventilation: Ventilate to keep airborne exposures below recommended limits Personal Protective Equipment: If excessive exposure is anticipated, it is recommended for handlers to wear a MSHA/NIOSH approved organic respirator with a dust prefilter, impervious gloves, goggles with side shields, and other appropriate clothing to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor: Solid blue granules with characteristic sulfurous odor. Boiling Point: N/A Melting Point: N/A Vapor Pressure (mm Hg): N/A Vapor Density (Air = 1): N/A Specific Gravity: >1 Bulk Density: 0.84 g/ml (0.80 - 0.90) Solubility: Soluble in water Evaporation Rate: N/A pH: N/A

10. STABILITY AND REACTIVITY

Stability: Stable Reactivity: Nonreactive Incompatibility w/ Other Reactive metals, strong oxidizers Materials: Decomposition Products: Oxides of nitrogen, carbon monoxide, carbon dioxide Hazardous Polymerization: Will not occur

11. TOXICOLOGICAL INFORMATION

CHRONIC TOXICITY [Specific to Active Ingredient(s)] In a 2 year feeding study in rats at feeding levels, 0, 50, 100, 200 and 400 ppm; the no effect level (NOEL) was 100 ppm based on slight hemolytic anemia and/or body weight effects observed at the higher dietary concentrations. No compound related neoplastic lesions were observed. In a 2 year feeding study in mice at feeding levels, 0, 50, 75, and 200 ppm; no compound related neoplastic or non-neoplastic histologic effects were found at any level. The NOEL was considered to be 50 ppm based on transient hemolytic anemia and increased mortality at the higher dietary concentrations. In a 2 year feeding study in dogs at feeding levels 0, 50, 100, 400, and 1,000 ppm the NOEL of 100 ppm was based on hemolytic anemia and non-neoplastic changes within the kidney and spleen at the higher dietary concentrations. There were no neoplastic effects at any dose DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)] A 3-generation rat reproduction study at rates of 50 and 100 ppm showed no adverse effect upon fertility, and no compound related histologic effect. A 2-generation rat study conducted at 75, 600, and 1,200 ppm in the diet showed similar results. In rats, no embryotoxic or teratogenic effects were observed at levels up to 400 ppm (highest level fed). In rabbits, the highest dietary dose level (100 mg/kg) did not cause any observed compound related abnormalities.

«PN2» Page 3 of 4

MUTAGENICITY [Specific to Active Ingredient(s)] Methomyl was negative in numerous assays to evaluate mutagenicity and genotoxicity, including Ames test, Reverse Mutation Assay, Recessive Lethal Assay, three DNA damage studies, an unscheduled DNA Synthesis Assay, and in vitro and in vivo cytogenic assays. Methomyl is not listed as a carcinogen by the IARC, NTP, OSHA and ACGIH.

12. ECOLOGICAL INFORMATION

ENVIRONMENTAL FATE [Active Ingredients Only] Hydrolysis: N/A Photolysis: N/A Soil half life: N/A Water solubility: Soluble in water

Do not apply directly to water, or to areas where surface water is present. This chemical is known to leach through soil into ground water, especially where soils are permeable or water table is near the surface.

ECOTOXICITY [Active Ingredients Only] Acute Toxicity: fish:LC50 (rainbow trout): 3.4 ppm (96 hour study), (bluegill sunfish): 0.72 mg/L (96 hour study); aquatic invertebrates:LC50 (daphnia magna): 31.7 ppb (48 hour study). Toxic to birds.

13. DISPOSAL CONSIDERATIONS

Do not contaminate water, food or feed by disposal. Waste resulting from the use of this product may be disposed of on site or an approved waste disposal facility. Container Disposal: Triple rinse (or equivlent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or by other approved state and local procedures.

14. TRANSPORT INFORMATION

DOT49CFR Description: Not applicable Freight Classification: Insecticides, Animal, NOI, O/T Poison NMFC I-102120 Class 60

15. REGULATORY INFORMATION

CERCLA (Superfund): Reportable Quantity (RQ) = Methomyl 100 lbs. If a spill exceeds the RQ contact the National Response Center at (800)424-8802 RCRA: Methomyl (PO66)

SARA 311/312 HAZARD CATEGORIES Immediate Health: Yes (irritant) Delayed Health: Yes Fire: No Sudden Pressure: No Reactivity: No

«PN2» Page 4 of 4 Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0 Revision Date: 01/26/2007

SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Number 102000015432 EPA Registration No. 432-1460

Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 USA

For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day) For Product Information call: 1-800-331-2867

SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Average % by Weight Fipronil 120068-37-3 0.05

SECTION 3. HAZARDS IDENTIFICATION

NOTE: Please refer to Section 11 for detailed toxicological information. Emergency Overview Caution! Keep exposed gel away from open food and food contact surfaces. Harmful if absorbed through skin. Moderate eye irritation. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.

Physical State gel

Appearance brown

Routes of Exposure Eye contact, Skin Absorption, Skin contact, Ingestion

Immediate Effects Eye Avoid contact with eyes. Moderately irritating to the eyes following prolonged direct contact.

Skin Avoid contact with skin, eyes and clothing. Harmful if absorbed through skin. Moderately irritating to skin following prolonged direct contact.

Page 1 of 7 Bayer Environmental Science A Business Group of Bayer CropScience

Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0

Ingestion Do not take internally.

Medical Conditions No specific medical conditions are known which may be aggravated by exposure Aggravated by Exposure to this product.

SECTION 4. FIRST AID MEASURES

General When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Eye Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.

Skin Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Notes to Physician Treatment There is no specific antidote. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended.

SECTION 5. FIRE FIGHTING MEASURES

Flash point not applicable

Fire and Explosion In the event of fire the following can be released: Hazards Sulphur oxides nitrogen oxides (NOx) Hydrogen fluoride

Suitable Extinguishing Dry chemical, Foam, Water, Carbon dioxide (CO2) Media

Page 2 of 7

Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0

Fire Fighting Keep out of smoke. Fight fire from upwind position. Do not allow run-off from fire Instructions fighting to enter drains or water courses.

In the event of fire and/or explosion do not breathe fumes. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces.

Methods for Cleaning Up Clean contaminated floors and objects thoroughly, observing environmental regulations. Decontaminate tools and equipment following cleanup.

Additional Advice Use personal protective equipment. If spilled on the ground, the affected area should be scraped clean and placed in an appropriate container for disposal.

SECTION 7. HANDLING AND STORAGE

Handling Procedures Product will stain porous surfaces.

Storing Procedures Keep tightly closed in a dry, cool and well-ventilated place. Keep out of reach of children and animals. Protect against heat/overheating. Keep away from direct sunlight.

Work/Hygienic Keep away from food, drink and animal feedingstuffs. Procedures

Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

General Protection Follow all label instructions. Train employees in safe use of the product.

Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry.

Engineering Controls Ensure adequate ventilation.

Eye/Face Protection protective eyewear

Hand Protection Chemical resistant nitrile rubber gloves

Page 3 of 7

Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0

Body Protection Skin contact should be prevented. Use suitable protective clothing, gloves and footwear, selected with regard to use conditions and exposure potential.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance brown

Physical State gel

Bulk Density 9.51 lbs/gal

SECTION 10. STABILITY AND REACTIVITY

Chemical Stability Stable under normal conditions.

Conditions to Avoid Extremes of temperature and direct sunlight. Exposure to moisture.

Incompatibility Strong oxidizing agents Strong bases Strong acids

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity data have been bridged from a similar formulation containing a slightly higher percentage of the active ingredient, fipronil. The non-acute information pertains to technical-grade active ingredient.

Acute Oral Toxicity rat: LD50: > 5,000 mg/kg

Acute Dermal Toxicity rat: LD50: > 2,000 mg/kg

Acute Inhalation Toxicity rat: LC50: > 2.9 mg/l Exposure time: 4 h

rat: LC50: > 11.6 mg/l Exposure time: 1 h Extrapolated from the 4 hr LC50.

Skin Irritation rabbit: Slight irritation.

Eye Irritation rabbit: No eye irritation.

Sensitization guinea pig: Non-sensitizing.

Chronic Toxicity Fipronil caused liver, kidney or thyroid effects and/or neurobehavioral effects

Page 4 of 7

Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0

(e.g., tremors) in chronic toxicity studies in rats and dogs. Fipronil did not induce any microscopic lesions in the neural tissues.

Assessment Carcinogenicity Fipronil has been classified by EPA as a Category C carcinogen based on thyroid tumors in rats only. These tumors are produced by a mechanism which is not relevant to human cancer. Fipronil did not produce an increase in tumor incidence in mice.

ACGIH None. NTP None. IARC None. OSHA None.

Reproductive & REPRODUCTION: Fipronil was not considered a primary reproductive toxicant Developmental Toxicity in rats.

DEVELOPMENTAL TOXICITY: Fipronil was not a developmental toxicant in rats and rabbits.

Neurotoxicity Fipronil caused transient neurobehavioral effects (e.g., tremors) in neurotoxicity studies in rats. Delays in developmental landmarks were observed in rats at maternally toxic doses.

Mutagenicity Fipronil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

SECTION 12. ECOLOGICAL INFORMATION

Environmental Do not apply directly to water, to areas where surface water is present or to Precautions intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label.

Page 5 of 7

Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0

SECTION 13. DISPOSAL CONSIDERATIONS

General Disposal It is best to use all of the product in accordance with label directions. If it is Guidance necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Never place unused product down any indoor or outdoor drain.

Container Disposal Do not re-use empty containers. Place empty container in trash. Follow advice on product label and/or leaflet.

SECTION 14. TRANSPORT INFORMATION

TRANSPORTATION CLASSIFICATION: Not regulated for shipment by any mode

FREIGHT CLASSIFICATION: Insecticides or Fungicides, N.O.I.; other than poison

SECTION 15. REGULATORY INFORMATION

EPA Registration No. 432-1460

US Federal Regulations TSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm.

US State Right-To-Know Ingredients None.

Canadian Regulations Canadian Domestic Substance List None.

Page 6 of 7

Bayer Environmental Science

Material Safety Data Sheet MSDS Number: 102000015432 MAXFORCE® FC MAGNUM ROACH KILLER BAIT GEL MSDS Version 1.0

Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

SECTION 16. OTHER INFORMATION

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Reactivity - 0 Others - none 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason to Revise: New Material Safety Data Sheet.

Revision Date: 01/26/2007

Page 7 of 7

Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 1/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier

Trade name MAXFORCE® FC ROACH KILLER BAIT STATIONS

Product code (UVP) 05826399

SDS Number 102000013976

EPA Registration No. 432-1257 Relevant identified uses of the substance or mixture and uses advised against

Use Insecticide

Restrictions on use See product label for restrictions.

Information on manufacturer

Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States Emergency telephone no.

Emergency Telephone 1-800-334-7577 (24 hours/day) Number (24hr/ 7 days)

Product Information 1-800-331-2867 Telephone Number

SDS Information or Request [email protected]

SECTION 2: HAZARDS IDENTIFICATION

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight Fipronil 120068-37-3 0.05

Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 2/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Water, Foam, Carbon dioxide (CO2), Dry chemical

Unsuitable None known.

Special hazards arising Dangerous gases are evolved in the event of a fire. from the substance or mixture Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing.

Further information Fight fire from upwind position. Keep out of smoke. Do not allow run-off from fire fighting to enter drains or water courses.

Flash point > 93.4 °C Autoignition temperature no data available Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 3/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up

Methods for cleaning up Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use only in area provided with appropriate exhaust ventilation.

Hygiene measures Keep away from food, drink and animal feedingstuffs. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Conditions for safe storage, including any incompatibilities

Requirements for storage Keep containers tightly closed in a dry, cool and well-ventilated place. areas and containers Keep out of reach of children and animals.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Fipronil 120068-37-3 50ug/m3 02 2013 TX ESL (Particulate.) (ST ESL) Fipronil 120068-37-3 5ug/m3 02 2013 TX ESL Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 4/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

(Particulate.) (AN ESL) Fipronil 120068-37-3 0.035 mg/m3 OES BCS* (TWA) 1,2-Propanediol 57-55-6 1000ug/m3 02 2013 TX ESL (Vapor.) (ST ESL) 1,2-Propanediol 57-55-6 50ppb 02 2013 TX ESL (Vapor.) (AN ESL) 1,2-Propanediol 57-55-6 500ppb 02 2013 TX ESL (Vapor.) (ST ESL) 1,2-Propanediol 57-55-6 100ug/m3 02 2013 TX ESL (Vapor.) (AN ESL) 1,2-Propanediol 57-55-6 10 mg/m3 2010 WEEL (Aerosol.) (TWA)

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

Respiratory protection Respiratory protection is not required under anticipated circumstances of exposure.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Safety glasses with side-shields

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance light tan to brown

Physical State pasty

Odor characteristic

Odour Threshold no data available pH no data available

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Specific Gravity no data available

Evapouration rate no data available

Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 5/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

Boiling Point no data available Melting / Freezing Point no data available

Water solubility no data available

Minimum Ignition Energy not applicable

Decomposition not applicable temperature

Partition coefficient: n- not applicable octanol/water

Viscosity no data available

Flash point > 93.4 °C Autoignition temperature no data available

Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition not applicable

Chemical stability Stable under normal conditions.

Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions

Conditions to avoid Extremes of temperature and direct sunlight. Exposure to moisture.

Incompatible materials Strong bases, Strong acids, Strong oxidizing agents

Hazardous decomposition No decomposition products expected under normal conditions of use. products

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Skin contact, Ingestion

Information on toxicological effects

Acute oral toxicity LD50 (rat) > 5,000 mg/kg

Acute inhalation toxicity no data available

Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 6/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

Acute dermal toxicity LD50 (rat) > 5,000 mg/kg

Skin irritation Slight irritation (rabbit)

Eye irritation Minimally irritating. (rabbit)

Sensitisation Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity

Fipronil caused specific target organ toxicity in experimental animal studies in the following organ(s): liver. Fipronil caused neurobehavioral effects and/or neuropathological changes in animal studies.

Assessment Mutagenicity

Fipronil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity

Fipronil caused an increased incidence of tumours in rats in the following organ(s): Thyroid. The mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to humans.

ACGIH

None.

NTP

None.

IARC

None.

OSHA

None.

Assessment toxicity to reproduction

Fipronil caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Fipronil is related to parental toxicity.

Assessment developmental toxicity

Fipronil did not cause developmental toxicity in rats and rabbits.

Further information

Acute toxicity studies have been bridged from a similar formulation(s). The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.25 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient fipronil.

Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 0.19 mg/l Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 7/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

invertebrates Exposure time: 48 h The value mentioned relates to the active ingredient fipronil.

Toxicity to aquatic plants EC50 (Scenedesmus subspicatus) 0.068 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient fipronil.

Biodegradability Fipronil: ; not rapidly biodegradable

Koc Fipronil: Koc: 427 - 1278

Bioaccumulation Fipronil: Bioconcentration factor (BCF) 321; Does not bioaccumulate.

Mobility in soil Fipronil: Slightly mobile in soils

Environmental precautions Do not allow to get into surface water, drains and ground water. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Follow container label instructions for disposal of wastes generated during use in compliance with the product label. Never place unused product down any indoor or outdoor drain.

Contaminated packaging Do not re-use empty containers. Wrap and discard in trash. Follow advice on product label and/or leaflet.

SECTION 14: TRANSPORT INFORMATION

According to national and international transport regulations this material is not classified as dangerous goods / hazardous material.

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1257 US Federal Regulations TSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 8/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm.

US State Right-To-Know Ingredients None.

Canadian Regulations Canadian Domestic Substance List None.

Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

Signal word: Caution!

Hazard statements: Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.

SECTION 16: OTHER INFORMATION

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Instability - 0 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 0 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Bayer Environmental Science SAFETY DATA SHEET

MAXFORCE® FC ROACH KILLER BAIT STATIONS 9/9 Version 3.0 / USA Revision Date: 11/06/2014 102000013976 Print Date: 11/06/2014

Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200)

Revision Date: 11/06/2014

niban'GRANULAR BAIT Health Emergencies: CHEMTREC@ (S00) 424-ggOO

I, PRODUCT AND COMPANY INFORMATION Special Protective Equipment and Precautions for Fire-Fighting lnstructions: Firefìghters should wear positive pressure self-contained Product ldentity: Niban@ Granular Bait breathing apparatus and full protective clothing. Contain runoff. Recommended use of the chemical and restrict¡ons on use: A 6. ACCIDENTAL RELEASE weather/moisture resistant bait to kill and control ants (except fire MEASURES ants), carpenter ants, cockroaches, crickets, mole crickets, earuvigs, Personal Precautions, Protective Equipment, and Emergency silverfish, snails, and slugs. Read and understand the entire label Procedures: Wear appropriate protective clothing as described in before using. Use only according to label directions. lt is a violation of Section L Do not apply directly to water or contaminate water. Federal law to use this product in a manner incons¡stent to label Methods and Mater¡als for Containment directions. and Clean¡ng Up: Collect and place in appropriate containers for disposal. Avoid generating Manufacturer: Nisus Corporation dust. Clean spill area thoroughly. Prevent spill from entering sewers 100 Nisus Drive and watercourses. Report releases as required by local, state and Rockford, TN 37853 federal authorities. Telephone: Phone: (800) 264-0870 7, HANDLING AND STORAGE Fax: (865) 577-5825 Precaut¡ons for Safe Handling: Avoid contact with the eyes, skin and Emergency Phone: 800-424-9300 (CHEMTREC) clothing. Avoid breathing dusts. Wear protective cloth¡ng and SDS Date of Preparation: 4/28/1 5 equipment as described in Section 8. Wash thoroughly with soap and 2. HAZARDS IDENTIFICATION water after handling. Remove contaminated clothing immediately and wash before reuse. Remove PPE immediately after handling. Wash GHS Class¡f¡cat¡on thoroughly after using and change into clean clothing. Do not apply this product in a way that will contact workers or other persons, either Phvsical Health Env¡ronment directly or through drift. Only protected handlers may be in the area Acute Toxicity Oral during application. Keep conta¡ners closed when not in use. Refer Category 4 product label for additional information on use and handling. Aquatic Acute Not Hazardous Specific Target Organ Nonrefillable container. Do not reuse Product residues Toxicity Category 3 containers. in Toxicity - Repeat empty containers can be hazardous. Follow all SDS precautions when Exposure Category 2 handling empty containers. GHS Label Elements: Cond¡t¡ons for Safe Storage, lnclud¡ng Any lncompat¡bilities: None Required Store in a dry area away from incompatible materials. Do not store Statements of Hazard Precaut¡onary Statements where children or animals may gain access. None Required None Required 8, EXPOSURE CONTROLS/PERSONAL PROTECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Exposure Guidelines: 2 mglm" TWA ACGIH TLV (inhalable) Boric Acid Component CAS No. Amount 6 mgim'STEL ACGIH TLV (inhalable) Boric Acid 10043-35-3 5o/o Engineering Controls: Use with adequate vent¡lation to maintain Non-Hazardous lnqredient Proprietarv 9SYo exposure levels below the occupational exposure limits. Refer product label for additional information. The exact formulation is being withheld as a trade secret, Respiratory Protect¡onr ln operations where exposure levels are exceeded, a NIOSH approved respirator with dusvmist cartridges 4. FIRST AID MEASURES appropriate for the form and concentration ofthe contaminants should Eye: Flush victim's eyes with large quantities of water, while holding be used. Selection and use of respiratory equipment must be in the eyelids apart. Get medical attention if irritation develops or persists. accordance with OSHA 1910.134 and good industrial hygiene practice. Skin: Wash skin thoroughly with soap and water. Get medical attention Refer to the product label for additional information. if initation develops. Remove and launder clothing before re-use. Skin Protection: Use gloves for normal application of this product. lngestion: Do not induce vomiting unless directed to do so by a Eye Protection: Wear safety glasses to prevent eye contact. medical professional. Get medical attention for large ingestions or if Other: Wear long-sleeve shirts, long pants, socks and shoes when symptoms develop or if you feel unwell. using this product. Suitable washing facilities should be available in the work area. lnhalation: Remove victim to fresh air. lf breathing is difficult or irritation persists, get med¡cal attention. 9. PHYSICAL AND CHEMICAL PROPERTIES Most important Symptoms: May cause eye and skin irritation. Appearance And Odor: Brown, granular particles lnhalation of mists may cause mild mucous membrane and respiratory with no odor. Physical State: Granular particles irritation. Harmful if swallowed. Repeated ingestion may cause kidney Odor Threshold: Not established damage. Vapor Density: Not determined ln¡t¡al Boil¡ng PoinURange: Not determined lndication of immediate medical attent¡on/special treatment: Solubility ln Water: Not soluble Vapor Pressure: Negligible lmmediate medical ättention is required for large ingestions. Relative Density: 0.62 of water Evaporation Rate: NiA 5. FIRE FIGHTING MEASURES Melting/Freezing Point: N/A pH: N/A Percent Volatile: Minimal OctanolMater Coeff¡c¡ent: NiA (and Suitable Unsuitable) Ext¡ngu¡shing Med¡a: Use media Solubility: Not soluble Decompos¡tion Temperature: N/A appropriate for surrounding fire. Viscosity: N/A hazards particles Specific ar¡sing from the chemical: Fine may Flammability (sol¡d, gas): Fine dust may form explosive mixtures in present an explosion hazard if suspended in air. Burning may produce air carbon monoxide and carbon dioxide. Flashpoint: >451"F (233'C) TOC Autoignition Temperature: None Flammable Limits: LEL: Not determined UEL: N/A 10. STABILITY AND REACTIVITY I 5, REGULATORY INFORMATION Reactivity: Not ly reactive This chemical is a pesticide product registered by the Un¡ted States Chemical Stability: Stable under normal storage and handling Environmental Protection Agency and is subject to certain labeling conditions. requ¡rements under federal pesticide law. These requirements differ Possib¡l¡ty of Hazardous Reactions: None known. from the classification criteria and hazard information required for Conditions to Avoid: Avoid generating fine dust. safety data sheets (SDS), and for workplace labels of non-pesticide lncompatible Materials: None known chemicals. The hazard information required on the pesticide label is Hazardous Decomposit¡on Products: When heated to reproduced below. The pesticide label also includes other important decomposition emits carbon monox¡de and carbon dioxide. information, including directions for use. FIFRA Labeling: 1 I. TOXICOLOGICAL INFORMAT¡ON Niban Granular Eait HEALTH HAZARDS: EPA Reg. No. 64405-2 lngestion: May be harmful quantities if large are ingested. Keep Out of Reach of Children lnhalation: lnhalation of dust may cause irritation of the nose, throat CAUTlON and upper respiratory tract. PRECAUTIONARY STATEMENTS Eye: May cause slight irr¡tation. Hazards to Humans & Domestic Animals Skin: Not expected to cause irritation. Caution: Harmful if absorbed through skin. Causes moderate eye Chronic: Borates have been shown have to some chronic toxicity in irr¡tation. Avoid contact with skin, eyes or clothing. animals fed high doses, but this has not been found in humans. product Sens¡tization: This material is not expected to cause sensitizat¡on. CERCLA: This is not subject to reporting under CERCLA. Carcinogenicity: None of the components is listed as a carcinogen or Some states have more stringent reporting requirements. Report all suspected carcinogen by IARC, NTP or OSHA. spills ¡n accordance with local, state, and federal regulations. Germ Cell Mutagenic¡ty: No data available SARA Hazard Category p111312): Not hazardous Reproductive Toxicity: Borates been found have have to some SARA 313: This product contains the following chemicals subject to reproductive toxicity in animals, but this has not been found in humans. Annual Release Reporting Requirements Under SARA Title lll, Section Numerical Measurès of Toxicity: 313 (40 CFR 372): Product Toxicitv Data: None Oral rat LDso: >5000 mg/kg; Dermal rabbit LC5e: >5050 mg/kg EPA TSCA lnventory: This product is regulated under FIFRA, thus 12. ECOLOGTCAL N exempt. This product breaks down naturally in the environment to provide I6, OTHER INFORMATION organic matter and boron micro nutr¡ents. Boron occurs naturally in NFPA Rating: sea water at an average concentration of 5 mg Bil and fresh water at 1 Health=0 Flammability=g lnstability=Q mg B/l or less. ln dilute aqueous solutions the predominant boron spec¡es present is und¡ssociated boric acid. HMIS Rating: Health=1 Flammability=g PhysicalHazard=0 Ecotox¡c¡ty: SDS Revision 01107114: ECro Green Algae'. 24 mg B/l; LCso Daphnía magna: 530 mg 8/l/96 hr; History: New SDS 04128115: Revised LCso Dab: 74 mg BlllfiShr; LCso Rainbow Trout: 88 mg B/li24hr; LCso Goldfish: 71 mg BlllT2ht WARRANW DISCLAIMER Persistence and Degradability: Boron is naturally occurring and The ¡nformation, data and recommendations contained herein are ubiquitous in the environment. Niban decomposes in the environment believed to be accurate but may not be all inclusive and should only be to natural borate. used as a guide. The information is furnished upon the condition that person Bioaccumulative Potential: Not determined. the receiving it shall make his own determination of the product particular Mobility in Soil: Boric acid is soluble in water and is leachable through suitability of the for his use and on condition that normal soil. they assume the risk of the use thereof. With respect to this publication product Other Adverse Effects: Some plants are sensitive to boron. This and the related thereto, unless otherwise expressly provided product is designed to be used for certain types of insects. Use by Manufacturer in writing, MANUFACTURER MAKES NO product only as directed on the label. See product label for full EXPRESS OR IMPLIED WARRANW OF MERCHANTABILITY, instructions and restrictions on use. FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. I 3. DISPOSAL CONSIDERATION Remedy/Liability Limits Dispose in accordance with local, state and federal environmental The exclusive remedy for losses or damages resulting from this regulat¡ons. Do not apply directly to water, to areas where surface publication or the related product (including claims based on contract, water is present or to intertidal areas below the mean high-water mark. negligence, strict liability or other legal theories) shall be l¡mited to, at Do not contam¡nate'water when disposing of equipment washwaters or Manufacturer's sole election, one of the following: rinsate. Wastes resulting from the use of this product may be disposed 1. Refund of purchase price paid by buyer or user for product of on site or at an approved waste disposal facility. Non-refillable bought, or container: do not reuse or refill th¡s container. Completely empty 2. Replacement of amount of product used. container into applicat¡on equipment, then offer for recycling, if Manufacturer shall not be liable for losses or damages resulting from available; otheMise dispose of empty container in a sanitary landfill or use of this publication or handling or use of this product, lN NO CASE by incineration. For guidance contact your state water board or SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR regional office of the EPA. INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES I4. TRANSPORTATION INFORMATION OR INJURIES. The terms of this Warranty Discla¡mer and Remedy/L¡ab¡l¡ty L¡m¡ts DOT Hazardous Mater¡als Description: Not Regulated cannot be varied by any wr¡tten or verbal statements or agreements. Sea Transport IMDG, not classified as dangerous No employee or sales agent of Manufacturer or the seller is author¡zed Air Trasnport IATA/ICAO, not classified as dangerous to vary or exceed the terms of this Warranty Disclaimer or Limitat¡on of Remedies in any manner. ffilH @ 100 Nisus Drive . Rockford, TN 37853 USA. (800) 264-0870 Niban ând Nisus Corporation are registered trademarks of Nisus Corporation. O2015. #NB-SDS-042815a Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 1/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier Trade name PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS Product code (UVP) 04399455 SDS Number 102000007120 EPA Registration No. 432-1332

Relevant identified uses of the substance or mixture and uses advised against Use Insecticide Restrictions on use See product label for restrictions.

Information on manufacturer Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States

Emergency telephone no. All Emergencies, 24hr/ 7 days 1-800-334-7577

Product Information Telephone No.

SDS Information or Request [email protected]

SECTION 2: HAZARDS IDENTIFICATION

Classification in accordance with regulation HCS 29CFR §1910.1200 Eye irritation : Category 2B Acute toxicity (Oral, Inhalation): Category 4

Signal word: Warning

Hazard statements Causes eye irritation. Harmful if swallowed. Harmful if inhaled.

Precautionary statements Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 2/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. Dispose of contents/container in accordance with local regulation.

Other hazards No other hazards known.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Average % by Weight Imidacloprid 138261-41-3 75.00

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Most important symptoms and effects, both acute and delayed

Symptoms To date no symptoms are known.

Indication of any immediate medical attention and special treatment needed

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 3/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Water, Carbon dioxide (CO2), Foam, Dry chemical

Unsuitable None known.

Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing.

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Dust explosion class no data available

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up

Additional advice Use personal protective equipment.

Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 4/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle and open container in a manner as to prevent spillage. Use only in area provided with appropriate exhaust ventilation.

Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Contaminated work clothing should not be allowed out of the workplace. Remove contaminated clothing immediately and dispose of safely.

Conditions for safe storage, including any incompatibilities

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Imidacloprid 138261-41-3 0.7 mg/m3 OES BCS* (TWA) Imidacloprid 138261-41-3 5 ug/m3 07 2011 TX ESL (AN ESL) Imidacloprid 138261-41-3 50 ug/m3 07 2011 TX ESL (ST ESL) Sodium aluminium silicate 1344-00-9 1 mg/m3 02 2012 ACGIH (Respirable fraction.) (TWA) Sodium aluminium silicate 1344-00-9 5 ug/m3 02 2013 TX ESL (Particulate.) (AN ESL) Sodium aluminium silicate 1344-00-9 50 ug/m3 02 2013 TX ESL (Particulate.) (ST ESL) *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"

Exposure controls

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 5/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Tightly fitting safety goggles

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance white to light beige

Physical State powder

Odor none

Odour Threshold no data available

pH 7 (1 %) suspension in water

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Bulk density 30 lb/ft³ (bulk density tapped)

Evapouration rate not applicable

Boiling Point not applicable

Melting / Freezing Point not applicable

Water solubility dispersible

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 6/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Minimum Ignition Energy no data available

Decomposition no data available temperature

Partition coefficient: n- no data available octanol/water

Viscosity not applicable

Flash point not applicable

Autoignition temperature no data available

Lower explosion limit not applicable

Upper explosion limit not applicable

Explosivity no data available

Dust explosion class no data available

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous No hazardous reactions when stored and handled according to reactions prescribed instructions.

Conditions to avoid no data available

Incompatible materials no data available

Hazardous decomposition Hydrogen cyanide (hydrocyanic acid) products Carbon monoxide Nitrogen oxides (NOx) Hydrogen chloride (HCl)

SECTION 11: TOXICOLOGICAL INFORMATION

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 7/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Exposure routes Ingestion, Eye contact, Skin contact, Skin Absorption, Inhalation

Immediate Effects Eye Causes eye irritation.

Skin Harmful if absorbed through skin.

Ingestion Harmful if swallowed.

Inhalation Harmful if inhaled.

Information on toxicological effects

Acute oral toxicity LD50 (male rat) 2,591 mg/kg

LD50 (female rat) 1,858 mg/kg

Acute inhalation toxicity LC50 (male rat) 2.65 mg/l Exposure time: 4 h Determined in the form of liquid aerosol. (actual)

LC50 (female rat) 2.75 mg/l Exposure time: 4 h Determined in the form of liquid aerosol. (actual)

LC50 (male rat) 10.6 mg/l Exposure time: 1 h Determined in the form of liquid aerosol. Extrapolated from the 4 hr LC50. (actual)

LC50 (female rat) 11.0 mg/l Exposure time: 1 h Determined in the form of liquid aerosol. Extrapolated from the 4 hr LC50. (actual)

Acute dermal toxicity LD50 (male/female combined rat) > 2,000 mg/kg

Skin irritation Slight irritation (rabbit)

Eye irritation Minimally irritating. (rabbit)

Sensitisation Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity Imidacloprid did not cause specific target organ toxicity in experimental animal studies.

Assessment Mutagenicity Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 8/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH None.

NTP None.

IARC None.

OSHA None.

Assessment toxicity to reproduction Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity.

Assessment developmental toxicity Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Imidacloprid are related to maternal toxicity.

Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic EC50 (Water flea (Daphnia magna)) 85 mg/l invertebrates Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid.

LC50 (Chironomus riparius (non-biting midge)) 0.0552 mg/l Exposure time: 24 h The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus) > 10 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid.

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 9/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Biodegradability Imidacloprid: not rapidly biodegradable

Koc Imidacloprid: Koc:225

Bioaccumulation Imidacloprid: Does not bioaccumulate. Mobility in soil Imidacloprid: Moderately mobile in soils

Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Do not contaminate water, food, or feed by disposal. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.

Contaminated packaging Follow advice on product label and/or leaflet. Do not re-use empty containers.

SECTION 14: TRANSPORT INFORMATION

49CFR Not dangerous goods / not hazardous material

IMDG UN number 3077 Class 9 Packaging group III Marine pollutant YES Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 10/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (IMIDACLOPRID MIXTURE)

IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (IMIDACLOPRID MIXTURE )

Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1332 US Federal Regulations TSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients None.

Canadian Regulations Canadian Domestic Substance List None.

Environmental CERCLA None. Bayer Environmental Science SAFETY DATA SHEET

PREMISE® 75 INSECTICIDE IN WATER SOLUBLE PACKETS 11/11 Version 2 / USA Revision Date: 12/19/2013 102000007120 Print Date: 01/05/2017

Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

Signal word: Caution!

Hazard statements: Harmful if swallowed, inhaled or absorbed through the skin. Causes eye irritation. Avoid contact with skin, eyes and clothing. Avoid breathing dust or vapour. Wash thoroughly with soap and water after handling. Remove and wash contaminated clothing before re-use.

SECTION 16: OTHER INFORMATION

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Instability - 1 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 1 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200)

Revision Date: 12/19/2013

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 1/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier Trade name PREMISE® FOAM Product code (UVP) 06335683 SDS Number 102000011452 EPA Registration No. 432-1391

Relevant identified uses of the substance or mixture and uses advised against Use Insecticide Restrictions on use See product label for restrictions.

Information on manufacturer Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States

Emergency telephone no. All Emergencies, 24hr/ 7 days 1-800-334-7577 (24 hours/day)

Product Information 1-800-331-2867 Telephone No.

SDS Information or Request [email protected]

SECTION 2: HAZARDS IDENTIFICATION

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Average % by Weight Imidacloprid 138261-41-3 0.05 Isobutane 75-28-5 7.50 Glycerine 56-81-5 4.77 Fatty alcohol ethoxylate 66455-15-0 2.00

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 2/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Most important symptoms and effects, both acute and delayed

Symptoms To date no symptoms are known.

Indication of any immediate medical attention and special treatment needed

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Water, Carbon dioxide (CO2), Dry chemical, Foam

Unsuitable None known.

Special hazards arising Product is contained in a pressurised container which may explode from the substance or on heating. mixture

Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing.

PREMISE® FOAM 3/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

Flash point 93.3 °C

Autoignition temperature no data available

Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Remove all sources of ignition. Avoid contact with spilled product or contaminated surfaces. Isolate hazard area. Keep unauthorized people away. Methods and materials for containment and cleaning up

Methods for cleaning up Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Contents under pressure. Use only in area provided with appropriate exhaust ventilation.

Advice on protection Keep away from heat and sources of ignition. Do not use this against fire and explosion product in or on electrical equipment due to the possibility of shock hazard.

Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics.

Conditions for safe storage, including any incompatibilities

Requirements for storage Keep containers tightly closed in a dry, cool and well-ventilated areas and containers place. BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Store in original container and out of the reach of children, preferably in a locked storage area.

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 4/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Imidacloprid 138261-41-3 0.7 mg/m3 OES BCS* (TWA) Imidacloprid 138261-41-3 5 ug/m3 07 2011 TX ESL (AN ESL) Imidacloprid 138261-41-3 50 ug/m3 07 2011 TX ESL (ST ESL) Isobutane 75-28-5 1,000 ppm 02 2012 ACGIH (TWA) Isobutane 75-28-5 1,000 ppm 02 2012 ACGIH NIC (STEL) Isobutane 75-28-5 1,900 mg/m3 / 800 ppm 2010 NIOSH (REL) Isobutane 75-28-5 800 ppb 07 2011 TX ESL (AN ESL) Isobutane 75-28-5 2040 ppb 07 2011 TX ESL (ST ESL) Isobutane 75-28-5 1900 ug/m3 07 2011 TX ESL (AN ESL) Isobutane 75-28-5 4800 ug/m3 07 2011 TX ESL (ST ESL) Glycerine 56-81-5 10 mg/m3 02 2012 ACGIH (Mist.) (TWA) Glycerine 56-81-5 15 mg/m3 02 2006 OSHA Z1 (Total dust.) (PEL) Glycerine 56-81-5 5 mg/m3 02 2006 OSHA Z1 (Respirable fraction.) (PEL) Glycerine 56-81-5 10 mg/m3 1989 OSHA Z1A (Total dust.) (TWA) Glycerine 56-81-5 5 mg/m3 1989 OSHA Z1A (Respirable fraction.) (TWA) Glycerine 56-81-5 10 mg/m3 06 2008 TN OEL (Total dust and mist.) (TWA) Glycerine 56-81-5 5 mg/m3 06 2008 TN OEL (Respirable fraction and dust (TWA) or fume.) Glycerine 56-81-5 5 ug/m3 03 2012 TX ESL (AN ESL) Glycerine 56-81-5 100 ug/m3 03 2012 TX ESL (AN ESL) Glycerine 56-81-5 50 ug/m3 03 2012 TX ESL (ST ESL) Glycerine 56-81-5 1000 ug/m3 03 2012 TX ESL (ST ESL) Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 5/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"

Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

Respiratory protection Respiratory protection is not required under anticipated circumstances of exposure.

Hand protection Chemical resistant nitrile rubber gloves

Eye protection Safety glasses with side-shields

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance white

Physical State Foam

Odor almost odourless

Odour Threshold no data available

pH 5.0 - 7.0 (10 %)

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Density ca. 1.01 g/cm³ at 20 °C

Evapouration rate no data available

Boiling Point no data available

Melting / Freezing Point no data available

Water solubility soluble

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 6/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

Minimum Ignition Energy no data available

Decomposition no data available temperature

Partition coefficient: n- no data available octanol/water

Viscosity 3 mPa.s at 25 °C

Flash point 93.3 °C

Autoignition temperature no data available

Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous No hazardous reactions when stored and handled according to reactions prescribed instructions.

Conditions to avoid Heat, flames and sparks.

Incompatible materials no data available

Hazardous decomposition Thermal decomposition can lead to release of: products Hydrogen cyanide (hydrocyanic acid) Carbon oxides Nitrogen oxides (NOx)

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Skin contact, Ingestion, Eye contact

Immediate Effects Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 7/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

Eye No eye irritation

Skin May cause slight irritation.

Ingestion Harmful if swallowed.

Information on toxicological effects

Acute oral toxicity LD50 (female rat) > 5,000 mg/kg

Acute inhalation toxicity Cannot be prepared and tested in a respirable form. no data available

Acute dermal toxicity LD50 (male/female combined rat) > 5,000 mg/kg

Skin irritation Slight irritation (rabbit)

Eye irritation No eye irritation (rabbit)

Sensitisation Non-sensitizing. (guinea pig) OECD Test Guideline 406, Buehler test

Assessment repeated dose toxicity Imidacloprid did not cause specific target organ toxicity in experimental animal studies.

Assessment Mutagenicity Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH None.

NTP None.

IARC None.

OSHA None.

Assessment developmental toxicity Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Imidacloprid are related to maternal toxicity. Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 8/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic EC50 (Water flea (Daphnia magna)) 85 mg/l invertebrates Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid.

LC50 (Chironomus riparius (non-biting midge)) 0.0552 mg/l Exposure time: 24 h The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic plants EC50 (Desmodesmus subspicatus) > 10 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid.

Biodegradability Imidacloprid: not rapidly biodegradable

Koc Imidacloprid: Koc:225

Bioaccumulation Imidacloprid: Does not bioaccumulate. Mobility in soil Imidacloprid: Moderately mobile in soils

Environmental precautions Apply this product as specified on the label. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility.

Contaminated packaging Do not re-use empty containers. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 9/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

Place empty container in trash.

SECTION 14: TRANSPORT INFORMATION

49CFR UN number 1950 Class 2.2 Packaging group Proper shipping name AEROSOLS

IMDG UN number 1950 Class 2.2 Packaging group Marine pollutant NO Proper shipping name AEROSOLS

IATA UN number 1950 Class 2.2 Packaging group Environm. Hazardous Mark NO Proper shipping name AEROSOLS, NON-FLAMMABLE

Freight Classification: CONSUMER COMMODITY - HAZMAT shipping papers not required for surface shipment per CFR49, 172.200(b)(3)

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-1391 US Federal Regulations TSCA list Isobutane 75-28-5 Glycerine 56-81-5 Fatty alcohol ethoxylate 66455-15-0 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 10/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients Isobutane 75-28-5 CT, MN, NJ Glycerine 56-81-5 MN, RI

Canadian Regulations Canadian Domestic Substance List Isobutane 75-28-5 Glycerine 56-81-5 Fatty alcohol ethoxylate 66455-15-0

Environmental CERCLA Isobutane 75-28-5 100 lbs Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

International Regulations European Inventory of Existing Commercial Substances (EINECS) Isobutane 75-28-5 Glycerine 56-81-5

Signal word: Caution!

Hazard statements: Harmful if swallowed. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.

SECTION 16: OTHER INFORMATION

Bayer Environmental Science SAFETY DATA SHEET

PREMISE® FOAM 11/11 Version 3 / USA Revision Date: 10/16/2013 102000011452 Print Date: 05/05/2015

NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 2 Instability - 1 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 2 Physical Hazard - 1 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200)

Revision Date: 10/16/2013

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 1/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

1. Identification

Product identifier used on the label

PT WASP FREEZE II

Recommended use of the chemical and restriction on use Recommended use*: insecticide

* The “Recommended use” identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet

Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA

Telephone: +1 973 245-6000

Emergency telephone number

CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357)

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Other means of identification Substance number: 597802 EPA Register number: 499-550 Synonyms: Prallethrin

2. Hazards Identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

Asp. Tox. 1 Aspiration hazard

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 2/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

Label elements

Pictogram:

Signal Word: Danger

Hazard Statement: H304 May be fatal if swallowed and enters airways.

Precautionary Statements (Response): P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting.

Precautionary Statements (Storage): P405 Store locked up.

Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point.

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Emergency overview

CAUTION: KEEP OUT OF REACH OF CHILDREN. May cause moderate but temporary irritation to the eyes. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. Aerosol container contains flammable gas under pressure.

3. Composition / Information on Ingredients

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

CAS Number Content (W/W) Chemical name 23031-36-9 0.1 % Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1- propen-1-yl)-, 2-methyl-4-oxo-3-(2-propyn-1-yl)-2- cyclopenten-1-yl ester 124-38-9 >= 1.0 - <= 5.0 % carbon dioxide 64742-47-8 Distillates (petroleum), hydrotreated light >= 95.0 % Proprietary ingredients

4. First-Aid Measures

Description of first aid measures

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 3/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

If inhaled: Remove the affected individual into fresh air and keep the person calm.

If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes.

If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing.

If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow.

Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.

Indication of any immediate medical attention and special treatment needed

5. Fire-Fighting Measures

Extinguishing media

Suitable extinguishing media: foam, dry powder, carbon dioxide

Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire. Aerosol container contains flammable gas under pressure.

Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 4/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.

Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund').

Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.

7. Handling and Storage

Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment.

Protection against fire and explosion: Aerosol container contains flammable gas under pressure. The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials.

Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene (LDPE)

8. Exposure Controls/Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 5/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

Components with occupational exposure limits Distillates (petroleum), hydrotreated light ACGIH TLV TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin.

carbon dioxide OSHA PEL PEL 5,000 ppm 9,000 mg/m3 ; ACGIH TLV TWA value 5,000 ppm ; STEL value 30,000 ppm ;

Distillates (petroleum), hydrotreated light ACGIH TLV TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin.

Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:

Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 6/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit.

9. Physical and Chemical Properties

Form: aerosol Odour: characteristic, of petroleum distillate (e.g. gasoline, kerosene) Colour: colourless pH value: approx. 5.7 ( 23.7 °C) Flammability of Aerosol > 18 in (ASTM D 3065 Products: no flashback NFPA 30B flammability: Level 3 Aerosol Density: approx. 0.8 ( 25 °C) g/cm3 Partitioning coefficient n- not applicable octanol/water (log Pow): Thermal decomposition: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. Viscosity, dynamic: 2.32 cps ( 21.6 °C) Solubility in water: dispersible

10. Stability and Reactivity

Reactivity No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: Corrosive effects to metal are not anticipated.

Chemical stability The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions The product is chemically stable.

Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures.

Incompatible materials

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 7/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

strong oxidizing agents, alkali or alkaline-earth metal

Hazardous decomposition products

Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off.

11. Toxicological information

Primary routes of exposure

Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases.

Acute Toxicity/Effects

Acute toxicity Assessment of acute toxicity: Relatively nontoxic after single ingestion. Relatively nontoxic after short-term skin contact. Relatively nontoxic after short-term inhalation.

Oral Type of value: LD50 Species: rat (female) Value: > 5,000 mg/kg

Inhalation Type of value: LC50 Species: rat (male/female) Value: > 2.08 mg/l Exposure time: 4 h

Dermal Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg

Irritation / corrosion Assessment of irritating effects: May cause slight but temporary irritation to the eyes. May cause moderate irritation to the skin.

Skin Species: rabbit Result: moderately irritating

Eye Species: rabbit Result: Slightly irritating.

Sensitization

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 8/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

Assessment of sensitization: Skin sensitizing effects were not observed in animal studies.

Buehler test Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies.

Chronic Toxicity/Effects

Genetic toxicity

Information on: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, 2-methyl-4- oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl ester Assessment of mutagenicity: Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic. ------

Carcinogenicity

Reproductive toxicity

Information on: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, 2-methyl-4- oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl ester Assessment of reproduction toxicity: Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. ------

Teratogenicity

Symptoms of Exposure

The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.

12. Ecological Information

Toxicity

Toxicity to fish

Information on: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, 2-methyl-4- oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl ester LC50 (96 h) 0.012 mg/l, Oncorhynchus mykiss

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 9/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

------

Aquatic invertebrates

Information on: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, 2-methyl-4- oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl ester EC50 (48 h) 0.0062 mg/l, daphnia ------

13. Disposal considerations

Container disposal: Do not cut, puncture, crush, or incinerate empty aerosol containers. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Empty aerosol cans may meet the definition of RCRA D003. Consult local and/or regional EPA for further guidance.

14. Transport Information

Land transport USDOT Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Proper shipping name: AEROSOLS (contains HYDROTREATED LIGHT DISTILLATES (PETROLEUM))

Sea transport IMDG Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Marine pollutant: NO Proper shipping name: AEROSOLS (contains HYDROTREATED LIGHT DISTILLATES (PETROLEUM))

Air transport IATA/ICAO Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Proper shipping name: AEROSOLS, FLAMMABLE (contains HYDROTREATED LIGHT DISTILLATES (PETROLEUM))

Further information DOT: This product may be classified as ORM-D (Consumer Commodity) or Limited Quantity. After 12/31/2020, ORM-D will not apply.

Safety Data Sheet PT WASP FREEZE II Revision date : 2014/08/11 Page: 10/10 Version: 2.0 (30599963/SDS_CPA_US/EN)

15. Regulatory Information

Federal Regulations

Registration status: Chemical TSCA, US blocked / not listed

Crop Protection TSCA, US released / exempt

EPCRA 311/312 (Hazard categories): Acute; Chronic; Fire; Sudden release of pressure

State regulations

State RTK CAS Number Chemical name MA, NJ, PA 124-38-9 carbon dioxide MA, NJ, PA 64742-47-8 Distillates (petroleum), hydrotreated light

16. Other Information

SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2014/08/11

Material Safety Data Sheet Vimar Corporation 9230 Neils Thompson Dr. Suite #111 Austin, TX 78758 (512) 680-5304 Emergency Number: (512) 680-5304

Manufacturer:

SECTION 1 – PRODUCT INFORMATION PRODUCT NAME: Rat Sorb Fragrance

SECTION 2 – PHYSICAL DATA APPEARANCE: Yellow Liquid ODOR: Camphoraceous citric odor SPECIFIC GRAVITY: 1.046 H2 O SOLUBILITY: Insoluble

SECTION 3 – FIRE AND EXPLOSION HAZARDS FLASH POINT: 180O F ( METHOD – TCC) FIRE/EXPLOSION HAZARD: Combustible Liquid EXTINGUISHING MEDIA: Foam, Dry Chemical, CO2. HAZARDOUS COMBUSTION PRODUCTS: Burning will produce carbon dioxide, carbon monoxide and smoke. SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn when fighting chemical fires. STABILITY: Stable CONDITIONS/MATERIALS TO AVOID: Avoid strong oxidizing agents. SECTION 4 – HEALTH HAZARD INFORMATION The identity of individual components of this mixture is proprietary information and is regarded to be a trade secret. The mixture as a whole has not been tested. However, we will apply a health hazard statement based on any component present at greater than or equal to 1% (carcinogens greater than or equal to 0.1%) Carcinogen: NTP: no OSHA: no IARC: no Liquid may be irritating to the skin and eyes. Vapors may irritate respiratory tract. Overexposure may cause nausea, vomiting and dizziness.

BOILING POINT: N/A MELTING POINT: N/A VAPOR DENSITY: N/A VAPOR PRESSURE: N/A

SECTION 5 – EMERGENCY AND FIRST AID PROCEDURES INHALATION: Remove victim from contaminated area. Call a physician as necessary. If not breathing, begin resuscitation procedures promptly. EYE CONTACT: Flush eyes with running water for at least 15 minutes. If irritation persists, obtain medical advice. SKIN CONTACT: Remove contaminated clothing. Wash affected area for at least 15 minutes. If irritation persists, obtain medical advice. INGESTION: Dilute with water. Do not induce vomiting. Contact physician. SECTION 6 – PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT

RESPIRATORY: NIOSH/OSHA approved vapor respirator recommended when working in poorly ventilated areas.

VENTILATION: Local exhaust meeting ACGIH criteria. PROTECTVE GLOVES: Use chemical resistant glove as needed to avoid prolonged or repeated contact. EYE PROTECTION: Splash protective goggles or face shield.

SECTION 7 – HANDLING AND STORAGE PROCEDURES HANDLING PROCEDURES: Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of work period. Contaminated clothing and shoes should be cleaned before reuse. Good manufacturing practices dictate that an eyewash fountain and/or safety shower should be available in the work area.

STORAGE REQUIREMENTS Store in cool, dry, ventilated area away from any heat sources. Keep containers tightly closed when not in use.

SECTION 8 – SPILL, LEAK AND DISPOSAL PROCEDURES Eliminate all ignition sources. If this product is liquid it can be absorbed using standard absorbents (sawdust/ vermiculite) and swept up. If this product is powder or crystal it can be swept up. Dispose of this product in accordance with federal, state, and local regulations.

SECTION 9 – SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) TITLE III NOTIFICATION This mixture doesn’t contain any toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

Vimar Corporation considers the specific identity of such ingredients to be a trade secret under provisions of 29 CFR 1910.1200. However the toxic chemical(s) subject to these requirements fall into the following generic classification(s) and concentrations

SECTION 10 – TOXIC SUBSTANCE AND CONTROL ACT The components of this product are listed in the TSCA Inventory.

MATERIAL SAFETY DATA SHEET PREPARED BY:

PRODUCT SAFETY DEPARTMENT Vimar Corporation March 6, 2001

The information on this MSDS was obtained from current and reputable sources. However, the data is provided without any warranty, expressed or implied regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of this product are beyond Vimar Corporation control, it is the responsibility of the user both to determine safe conditions for use of this product and to assume liability for loss, damage, or expense arising out of the product’s improper use. No warranty expressed or implied regarding the product described herein shall be created by or inferred from any statement or omission in the MSDS. This MSDS supersedes any previous MSDS for this product. Various federal, state, or provincial agencies may have specific regulations concerning the transportation, handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance.

NE = not established NF = not found NA = not applicable

Section 8: Exposure Controls / Personal Protection SAFETY DATA SHEET Established exposure limits: See Section 3; also 29 CFR 1910.1000 Z-3. Section 1: Identification Appropriate engineering controls: Special ventilation is not required for ® the normal handling and use of this product when following label instructions. Product identifier: Rozol Tracking Powder Individual protection measures: All handlers (including applicators) must Other identifier(s): EPA Registration Number 7173-113 wear: long sleeved shirt and long pants, shoes plus socks, gloves, protective Uses or restrictions: Restricted Use Pesticide eyewear and a dust/mist filtering respirator (MSHA/NIOSH approval number Manufacturer: Liphatech, Inc. prefix TC-21C), or a NIOSH approved respirator with any N, R, P or HE filter. 3600 W. Elm Street, Milwaukee, WI 53209 Follow manufacturer’s instructions for cleaning/maintaining PPE, or else Emergency phone: 800-351-1476 Monday - Friday 8:00 am - 4:30 pm wash with detergent and hot water. Keep and wash PPE separately from (US Central time zone) other laundry. Remove PPE immediately after handling this product. Wash After hours: Call CHEMTREC at 1-800-424-9300 the outside of gloves before removing. Wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco or Section 2: Hazard Identification using the toilet, and change into clean clothing. Hazard class: Carcinogenicity, Category 1; Section 9: Physical and Chemical Properties Specific Target Organ Toxicity (Single exposure), Category 2; Specific Target Organ Toxicity (Repeated exposure), Category 2 Appearance: Powder, off-white color, no odor. Odor threshold: none. Danger: May cause cancer or silicosis by inhalation of Water solubility: Negligible pH: Not applicable Relative density: 0.885 g/cc Viscosity: Not applicable crystalline silica. May cause damage to blood and reduce the % Volatile (volume): Not applicable Evaporation rate: Not applicable clotting ability of blood if swallowed, inhaled or absorbed through Vapor density: Not applicable Vapor pressure: Not applicable skin. Obtain special instructions before use. Do not handle until all safety Boiling point: Not determined Freezing point: Not applicable precautions have been read & understood. Wear respirator, protective gloves Flash point (ASTM D92): None Autoignition temp.: Not determined & clothing, eye and face protection. Do not breathe dust. Do not eat, drink or Flammability: Not a flammable solid Decomposition temp.: Not determined smoke when using this product. Wash hands thoroughly after handling. If Explosive limits - Lower limit: Not applicable; Upper limit: Not applicable exposed or if you feel unwell, call poison control center or doctor. Dispose of Partition coefficient (n-octanol/water): Not applicable container & contents according to instructions on product label. Store locked up. Section 10: Stability and Reactivity Section 3: Composition / Information on Ingredients Reactivity: Not reactive, not sensitive to shock or static discharge Hazardous ingredients % in mixture, and established exposure limits Chemical stability: Stable Hazardous reactions: None Chlorophacinone (CAS no. 3691-35-8): 0.2% No exposure limit established Incompatible materials: None Conditions to avoid: None Crystalline silica (CAS no. 14808-60-7): 30-45% ACGIH TLV: 0.05 mg/m3 Hazardous decomposition products: Oxides of carbon respirable quartz, OSHA PEL: 10 mg/m3 ÷ (% silica +2) respirable quartz Section 11: Toxicological Information 3 Amorphous silica (CAS no. 61790-53-2): 0-40% ACGIH TLV: 10 mg/m total Likely routes of exposure: Ingestion, skin absorption, inhalation. 3 3 dust, 3 mg/m respirable dust; OSHA PEL: 80 mg/m ÷ % silica Symptoms of toxicity: Lethargy, loss of appetite, reduced clotting ability of Aluminum oxide (CAS no. 1344-28-1): 10-28% ACGIH TLV: 10 mg/m3, blood, and bleeding. OSHA PEL: 15 mg/m3 total dust, 5 mg/m3 respirable dust Eye effects/eye irritation: Mild, transient irritant Section 4: First Aid Measures Acute oral effects: LD50 (oral-rat): >5000 mg/kg Acute inhalation effects: LC50 (rat, 4 hour): >2.1 mg/L Emergency overview: This material may reduce the clotting ability of the Acute dermal effects: LD50 (dermal-rabbit): >2000 mg/kg blood and cause bleeding. Symptoms of toxicity include lethargy, loss of Skin irritation: Non-irritating Skin sensitization: Not a skin sensitizer appetite, reduced clotting ability of blood, and bleeding. Have the product Carcinogenicity: Crystalline silica is listed as carcinogen by NTP and IARC. label with you when obtaining treatment advice. Inhalation of crystalline silica may cause silicosis (irreversible fibrosis of lung tissue) and lung cancer. Section 12: Ecological Information If swallowed: Call a poison control center or doctor. Have person sip a glass This product is toxic to fish and wildlife. Do not apply this product directly to of water if able to swallow. Do not induce vomiting unless told to do so by water, where surface water is present or to intertidal areas below the mean the poison control center or doctor. high water mark. Carefully follow label cautions and directions to reduce If inhaled: Move person to fresh air. If person is not breathing, call an hazards to children, pets and non-target wildlife. ambulance, then give artificial respiration and call poison control or doctor. Section 13: Disposal Considerations If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 Disposal: Wastes resulting from the use of this product according to the minutes. Remove contact lenses, if present, after the first 5 minutes, then label instructions must be disposed of as specified on the product label. continue rinsing eye. Call a poison control center or doctor. RCRA waste status: This product is not regulated as a hazardous waste If on skin or clothing: Take off contaminated clothing. Rinse skin with plenty under Federal law. State and local regulation may affect the disposal of this of cool water for 15-20 minutes. Call a poison control center or doctor. product. Consult your state or local environmental agency for disposal of Note to Physician or Veterinarian: Contains anticoagulant ingredient. For waste generated other than by use according to label instructions. humans or animals ingesting bait and/or showing obvious poisoning Section 14: Transport Information symptoms (bleeding or prolonged prothrombin times), give Vitamin K1 Transportation data (49 CFR): This product is not regulated as a intramuscularly or orally. In severe cases, blood transfusions may be needed. hazardous material for all modes of transportation within the U.S. Section 5: Fire-fighting Measures Hazard Class, Packing Group and UN ID No.: Not applicable Extinguishing media: Use media suitable for the surrounding fire Section 15: Regulatory Information Specific fire or explosion hazards: None known TSCA: All components of this product are listed on the TSCA inventory. Special cautions for firefighters: Wear self-contained breathing apparatus EPCRA Sec. 302 TPQ, Sec. 304 RQ: 100 pounds of chlorophacinone powder. (full facepiece) & full protective clothing. Contain runoff to prevent pollution. SARA section 313: No reportable components. Section 6: Accidental Release Measures CA Proposition 65: Crystalline silica (airborne particles of respirable size) is known to the State of California to be a carcinogen. Precautions, PPE and Procedures: Wearing PPE as specified in Section 8, FIFRA: This product is registered as a pesticide with the U.S. Environmental isolate and contain spill. Limit access to spill area to necessary personnel. Protection Agency. The label requirements under Federal pesticide law differ Do not allow spilled material to enter sewers, streams or other waters. from the classification criteria and hazard information required by OSHA on Methods and materials: Scoop up spilled material and place in a closed, this Safety Data Sheet. Read and follow all cautions, directions and use labeled container for use according to label instructions or disposal. restrictions on the product label on the container. Section 7: Handling and Storage Section 16: Other Information Precautions for safe handling: Read the entire product label before using Prepared by: T. Schmit Date: 2 February 2015 this rodenticide. Conditions for safe storage: Store in original container in This Safety Data Sheet is believed to be accurate at time of publication. No warranty, a cool, dry area out of reach of children, pets and domestic animals. Do not expressed or implied, is made with regard to this information. This information may not contaminate water, food or feed. Keep container tightly closed. Do not be adequate for every application, and the user must determine the suitability of this remove or destroy the product label. information due to the manner or conditions of use or storage, or local regulation.

Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 1/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier

Trade name SUSPEND® SC INSECTICIDE

Product code (UVP) 05946468

SDS Number 102000003167

EPA Registration No. 432-763 Relevant identified uses of the substance or mixture and uses advised against

Use Insecticide

Restrictions on use See product label for restrictions.

Information on manufacturer

Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States

Emergency Telephone 1-800-334-7577 Number (24hr/ 7 days)

Product Information Telephone Number

SDS Information or Request [email protected]

SECTION 2: HAZARDS IDENTIFICATION

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight Deltamethrin 52918-63-5 4.75 1,2-Propanediol 57-55-6 15.20 Nonylphenol ethoxylate, branched 127087-87-0 2.85

Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 2/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.

Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.

Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed

Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media

Suitable Carbon dioxide (CO2), Dry chemical, Foam, Water

Unsuitable None known.

Special hazards arising Dangerous gases are evolved in the event of a fire. from the substance or mixture Advice for firefighters

Special protective Firefighters should wear NIOSH approved self-contained breathing equipment for fire-fighters apparatus and full protective clothing.

Further information Evacuate personnel to safe areas. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.

Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 3/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

Flash point no data available

Autoignition temperature no data available

Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Isolate hazard area. Keep unauthorized people away. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up

Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Decontaminate tools and equipment following cleanup. Clean contaminated floors and objects thoroughly, observing environmental regulations.

Additional advice Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Avoid contact with skin, eyes and clothing. Handle and open container in a manner as to prevent spillage. Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation.

Advice on protection Keep away from heat and sources of ignition. against fire and explosion

Hygiene measures Smoking, eating and drinking should be prohibited in the application area. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities

Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 4/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

Requirements for storage Store in original container. Store in a cool, dry place and in such a areas and containers manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Protect from freezing.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components CAS-No. Control parameters Update Basis Deltamethrin 52918-63-5 0.02 mg/m3 OES BCS* (TWA) Silicon dioxide 7631-86-9 6 mg/m3 2010 NIOSH (REL) Silicon dioxide 7631-86-9 27ug/m3 02 2013 TX ESL (Particulate.) (ST ESL) Silicon dioxide 7631-86-9 2ug/m3 02 2013 TX ESL (Particulate.) (AN ESL) Silicon dioxide 7631-86-9 0.8 mg/m3 2000 Z3 (TWA) Silicon dioxide 7631-86-9 20millions of particles per 2000 Z3 cubic foot of air (TWA) 1,2-Propanediol 57-55-6 1000ug/m3 02 2013 TX ESL (Vapor.) (ST ESL) 1,2-Propanediol 57-55-6 50ppb 02 2013 TX ESL (Vapor.) (AN ESL) 1,2-Propanediol 57-55-6 500ppb 02 2013 TX ESL (Vapor.) (ST ESL) 1,2-Propanediol 57-55-6 100ug/m3 02 2013 TX ESL (Vapor.) (AN ESL) 1,2-Propanediol 57-55-6 10 mg/m3 2010 WEEL (Aerosol.) (TWA) Nonylphenol ethoxylate, 127087-87-0 600ug/m3 10 2003 TX ESL branched (ST ESL) Nonylphenol ethoxylate, 127087-87-0 60ug/m3 10 2003 TX ESL branched (AN ESL)

*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls

Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply.

SUSPEND® SC INSECTICIDE 5/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

Hand protection Chemical-resistant gloves made of waterproof material such as neoprene, butyl rubber, barrier laminate or nitrile rubber.

Eye protection Tightly fitting safety goggles

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.

General protective measures Eye wash facility and safety shower should be available. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. Follow all label instructions. Train employees in safe use of the product.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance white

Physical State liquid suspension

Odor none

Odour Threshold no data available pH <= 7.0 at 100 %

Vapor Pressure no data available

Vapor Density (Air = 1) no data available

Density ca. 1.05 g/cm³ at 20 °C

Evapouration rate no data available

Boiling Point no data available Melting / Freezing Point no data available

Water solubility immiscible

Minimum Ignition Energy not applicable

Decomposition no data available temperature

Partition coefficient: n- no data available octanol/water

Viscosity 1,300 - 1,800 cps

Flash point no data available

Autoignition temperature no data available

Lower explosion limit no data available

Upper explosion limit no data available

Explosivity not applicable

Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 6/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

SECTION 10: STABILITY AND REACTIVITY

Reactivity

Thermal decomposition no data available

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous No hazardous reactions when stored and handled according to reactions prescribed instructions.

Conditions to avoid freezing

Incompatible materials Strong oxidizing agents, Strong reducing agents

Hazardous decomposition No decomposition products expected under normal conditions of use. products

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Inhalation, Skin contact, Eye contact, Ingestion

Immediate Effects

Skin Contact with product may result in transient tingling and reddening of the skin.

Inhalation Harmful if inhaled. Information on toxicological effects

Acute oral toxicity LD50 (rat) > 15,000 mg/kg

Acute inhalation toxicity LC50 (rat) > 1.02 mg/l Exposure time: 4 h Determined in the form of liquid aerosol. Highest attainable concentration. No deaths

LC50 (rat) > 4.08 mg/l Exposure time: 1 h Determined in the form of liquid aerosol. Extrapolated from the 4 hr LC50.

Acute dermal toxicity LD50 (rabbit) > 10,000 mg/kg

Skin irritation Slight irritation (rabbit)

Eye irritation Minimally irritating. (rabbit)

Sensitisation Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity

Deltamethrin caused neurobehavioral effects and/or neuropathological changes in animal studies. The Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 7/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

toxic effects of Deltamethrin are related to transient hyperactivity typical for pyrethroid neurotoxicity.

Assessment Mutagenicity

Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity

Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice.

ACGIH

None.

NTP

None.

IARC

Deltamethrin 52918-63-5 Overall evaluation: 3

OSHA

None.

Assessment toxicity to reproduction

Deltamethrin did not cause reproductive toxicity in a two-generation study in rats.

Assessment developmental toxicity

Deltamethrin caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Deltamethrin are related to maternal toxicity.

Further information

Acute toxicity studies have been bridged from a similar formulation(s). The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.00026 mg/l Exposure time: 96 h

LC50 (Lepomis macrochirus (Bluegill sunfish)) 0.00017 mg/l Exposure time: 96 h

Toxicity to aquatic LC50 (Eastern Oyster) 0.0082 mg/l invertebrates Exposure time: 96 h

LC50 (Mysidopsis bahia (mysid shrimp)) 0.000001 mg/l Exposure time: 96 h

Biodegradability Deltamethrin: ; not rapidly biodegradable

Koc Deltamethrin: Koc: 10240000

Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 8/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

Bioaccumulation Lepomis macrochirus (Bluegill sunfish)

Bioconcentration factor (BCF): 189 - 3,930

Bioaccumulation Deltamethrin: Bioconcentration factor (BCF) 1,400; Does not bioaccumulate.

Mobility in soil Deltamethrin: Immobile in soil

Environmental precautions Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. Apply this product as specified on the label.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.

Contaminated packaging Triple rinse containers. Add washings to sprayer at time of filling. Puncture container to avoid re-use. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke. Follow advice on product label and/or leaflet.

SECTION 14: TRANSPORT INFORMATION

49CFR Not dangerous goods / not hazardous material

IMDG UN number 3082 Class 9 Packaging group III Marine pollutant YES Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 9/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DELTAMETHRIN SOLUTION)

IATA UN number 3082 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DELTAMETHRIN SOLUTION )

Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON

SECTION 15: REGULATORY INFORMATION

EPA Registration No. 432-763 US Federal Regulations TSCA list 1,2-Propanediol 57-55-6 Nonylphenol ethoxylate, branched 127087-87-0 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive harm.

US State Right-To-Know Ingredients 1,2-Propanediol 57-55-6 MN

Canadian Regulations Canadian Domestic Substance List Nonylphenol ethoxylate, branched 127087-87-0

Environmental CERCLA Bayer Environmental Science SAFETY DATA SHEET

SUSPEND® SC INSECTICIDE 10/10 Version 3.0 / USA Revision Date: 07/01/2014 102000003167 Print Date: 05/04/2016

None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None.

International Regulations European Inventory of Existing Commercial Substances (EINECS) Deltamethrin 52918-63-5

Signal word: Caution!

Hazard statements: Harmful if inhaled. Do not breathe vapours or spray mist. Contact with product may result in transient tingling and reddening of the skin. Remove and wash contaminated clothing before re-use.

SECTION 16: OTHER INFORMATION

NFPA 704 (National Fire Protection Association): Health - 2 Flammability - 1 Instability - 0 Others - none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 2 Flammability - 1 Physical Hazard - 0 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200)

Revision Date: 07/01/2014

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A

1. PRODUCT IDENTIFICATION

Product identifier on label: TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Product No.: A10976W Use: Rodenticide Manufacturer: Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

2. HAZARDS IDENTIFICATION

Classifications: Specific Target Organ Toxicity: Respiratory Irritation Category 3 Carcinogenicity: Category 1A Specific Target Organ Toxicity: Repeated Category 1 Dermal: Category 3 Signal Word (OSHA): Danger

Hazard Statements: Toxic in contact with skin May cause respiratory irritation May cause cancer Causes damage to organs through prolonged or repeated exposure

Hazard Symbols:

Precautionary Statements: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust. Wash hands and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, eye protection. If on skin: Wash with plenty of soap and water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed or concerned: Get medical advice/attention. Call a poison center, doctor or Syngenta if you feel unwell.

Page 1 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A Take off immediately all contaminated clothing and wash it before reuse. Store locked up. Dispose of contents and container in accordance with local regulations.

Other Hazard Statements: This product presents no significant hazards under normal conditions of use. May form combustible dust concentrations in air.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Common Name CAS Number Concentration Crystalline Silica, Quartz and Cristobalite Crystalline Silica, Quartz and Cristobalite 14808-60-7 Trade Secret Kaolin Clay Kaolin Clay 1332-58-7 Trade Secret Other ingredients Other ingredients Trade Secret 99.995% 3-[3-(4'-bromo[1,1'-biphenyl]-4-yl)-1,2,3,4- Brodifacoum Technical 56073-10-0 0.005% tetrahydro-1-naphthalenyl]-4-hydroxy-2H- 1-benzopyran-2-one

Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

4. FIRST AID MEASURES

Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.

Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Wash skin with soap and water. Inhalation: If inhaled: Move person to fresh Not applicable. Most important symptoms/effects: Anticoagulation effects.

Indication of immediate medical attention and special treatment needed: This product may reduce the clotting ability of the blood and cause hemorrhaging. If poisoning occurs, intramuscular and oral administration of Vitamin K1 are indicated, as in poisoning from overdose of bishydroxy coumarin. For human cases, Vitamin K1 is antidotal at doses of 10 - 20 mg (not mg/kg). For animal cases, Vitamin K1 is antidotal at 2 - 5 mg/kg. Repeated doses may need to be given up to two weeks (based on monitoring of prothrombin time). In severe cases, blood transfusions may be necessary. Further information is available from the Syngenta emergency number provided in this document.

Page 2 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A 5. FIRE FIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8.

Methods and materials for containment and cleaning up: Control the spill at its source. Clean up spills immediately, observing precautions outlined in Section 8. Sweep up material and place in a compatible disposal container. Once all material is collected, seal container and arrange for disposition.

7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities: Store locked up.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:

Chemical Name OSHA PEL ACGIH TLV Other Source

Crystalline Silica, Quartz and 10 mg/m³/(%SiO2+2) 0.025 mg/m³ 0.05 mg/m³ NIOSH Cristobalite (respirable dust) (respirable silica) (respirable dust) Kaolin Clay 15 mg/m³ TWA (total); 5 2 mg/m³ TWA 10 mg/m³ TWA NIOSH mg/m³ TWA (respirable) (respirable) (total); 5 mg/m³ TWA (respirable) Other ingredients Not Applicable Not Applicable Not Applicable Not Applicable

Brodifacoum Technical Not Established Not Established 0.002 mg/m³ TWA Syngenta

Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures:

Page 3 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Eye protection is not required for normal handling. Where eye contact is likely, wear tight-fitting chemical goggles.

Skin Contact: Gloves are not required for normal handling. Where heavy contact is likely, wear chemical resistant (such as nitrile or butyl) gloves. Inhalation: Respiratory protection is not required for normal handling. In the event of an unusual dust exposure, use engineering controls or a NIOSH-certified particulate respirator (N, P, R or HE filter) to keep exposure below the Occupational Exposure Limit.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Green pellets Odor: Faint grain-like Odor Threshold: Not Available pH: Not Available Melting point/freezing point: Not Available Initial boiling point and boiling range: 442 - 446 °F (Brodifacoum) Flash Point (Test Method): > 375°F (paraffin wax) Method: PMCC Flammable Limits (% in Air): Not Available Flammability: Not Available

Vapor Pressure: Brodifacoum Technical 6 x 10(-6) mmHg @ 68°F (20°C) Vapor Density: Not Available Relative Density: 40 lbs/ft³ Solubility (ies): Brodifacoum Technical Insoluble

Partition coefficient: n-octanol/water: Not Applicable

Autoignition Temperature: Not Available

Decomposition Temperature: Not Available

Viscosity: Not Available Other: Not Available

10. STABILITY AND REACTIVITY

Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur.

Conditions to Avoid: None known.

Page 4 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A

Incompatible materials: None known.

Hazardous Decomposition Products: None known.

11. TOXICOLOGICAL INFORMATION

Health effects information Likely routes of exposure: Dermal, Inhalation

Symptoms of exposure: Anticoagulant effects.

Delayed, immediate and chronic effects of exposure: Anticoagulant effects.

Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Rat) : > 5000 mg/kg body weight

Dermal: Dermal (LD50 Rat) : > 500 mg/kg body weight

Inhalation: Inhalation (LC50 Rat) : See "Other Toxicity Information", Sec. 11

Eye Contact: See "Other Toxicity Information", Sec. 11

Skin Contact: See "Other Toxicity Information", Sec. 11

Skin Sensitization: Not Available

Reproductive/Developmental Effects Brodifacoum Technical: Not teratogenic, embryotoxic or fetotoxic in rats or rabbits at doses up to 0.02 mg/kg/day - the dose causing excessive maternal toxicity. Non-genotoxic in a range of assays. Chronic/Subchronic Toxicity Studies Brodifacoum Technical: The biological half-life for brodifacoum in body tissue in rats is > 100 days. Adverse clinical effects can develop from body accumulation. Prolonged prothrombin time, depression, pallor, subcutaneous hemorrhage, bleeding of nose or gums, gastrointestinal hemorrhage, cerebral hemorrhage, shock and death can develop following exposures. No neurotox studies have been conducted. Carcinogenicity Brodifacoum Technical: Unlikely to be carcinogenic.

Chemical Name NTP/IARC/OSHA Carcinogen Crystalline Silica, Quartz and Cristobalite IARC 1; ACGIH A2 Kaolin Clay No Other ingredients No 3-[3-(4'-bromo[1,1'-biphenyl]-4-yl)-1,2,3,4- No tetrahydro-1-naphthalenyl]-4-hydroxy-2H-1- benzopyran-2-one

Other Toxicity Information Effects of overexposure are those of anticoagulant overdose, i.e., reduced blood clotting ability with spontaneous bleeding in various organs. Body accumulation can result from repeated exposures since the half-life of brodifacoum is > 100 days. Individuals with blood clotting disorders may be more susceptible to overexposure effects.

Page 5 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A

Systemically toxic concentrations of this product will probably not be absorbed through human skin. No toxic effects are known to be associated with inhalation of dust from this material. No irritation is likely to develop following contact with human eyes. Irritation will probably not develop following contact with human skin. Toxicity of Other Components Crystalline Silica, Quartz and Cristobalite Chronic inhalation exposure to crystalline silica is known to cause silicosis and pulmonary fibrosis in humans. Experimental animals exposed to crystalline silica developed respiratory tract cancers. Kaolin Clay May cause eye and respiratory tract irritation. Long-term exposure to high concentrations of this dust may produce x-ray evidence of dust in the lungs. Continued long-term exposure may affect respiratory function in some individuals. Other ingredients Not Applicable

Target Organs Active Ingredients Brodifacoum Technical: Blood Inert Ingredients Crystalline Silica, Quartz and Respiratory tract Cristobalite: Kaolin Clay: Eye, respiratory tract, lung Other ingredients: Not Applicable

12. ECOLOGICAL INFORMATION

Eco-Acute Toxicity Brodifacoum Technical: Fish (Rainbow Trout) 96-hour LC50 0.02 ppm Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.98 ppm Bird (Mallard Duck) 21-day LD50 0.26 mg/kg

Environmental Fate Brodifacoum Technical: The information presented here is for the active ingredient, brodifacoum. Not persistent in soil. Stable in water. Immobile in soil. Sinks in water (after 24 h).

13. DISPOSAL CONSIDERATIONS

Disposal: Do not reuse empty container except for holding additional product. Characteristic Waste: Not Applicable Listed Waste: Not Applicable

Page 6 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A 14. TRANSPORT INFORMATION

DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Not regulated

Air Transport Not regulated

15. REGULATORY INFORMATION

Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: Caution: Harmful if swallowed or absorbed through skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin, or on clothing. All handlers (including applicators) must wear shoes plus socks, and gloves. Any person who retrieves carcasses or unused bait following application of this product must wear waterproof gloves.

EPA Registration Number(s): 100-1050 EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Acute Health Hazard

Section 313 Toxic Chemicals: None

CERCLA/SARA 304 Reportable Quantity (RQ): Not Applicable RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA

16. OTHER INFORMATION

NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 1 Health: 1* 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme Syngenta Hazard Category: A * Chronic

For non-emergency questions about this product call:

Page 7 of 8 Safety Data Sheet

TALON®-G Rodenticide Bait Pack Mini-Pellets With Bitrex® Date: 7/21/2014 Replaces: N\A

1-800-334-9481

Original Issued Date: 7/21/2014 Revision Date: Replaces: Section(s) Revised: 1-16 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

Page 8 of 8 Material Safety Data Sheet TALSTARÒ PROFESSIONAL INSECTICIDE

MSDS #: 1349-A Revision Date: 2013-02-20 Version 1

______

This MSDS has been prepared to meet U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200 And Canadian Workplace Hazardous Materials Information System (WHMIS) requirements. ______

1. PRODUCT AND COMPANY IDENTIFICATION

Product name TALSTARÒ PROFESSIONAL INSECTICIDE

Formula code 1349

Active Ingredient(s) Bifenthrin

Chemical Family Pyrethroid Pesticide

Recommended use: Insecticide

Manufacturer Emergency telephone number

FMC Corporation For leak, fire, spill or accident emergencies, call: Agricultural Products Group 1 800 / 424 9300 (CHEMTREC - U.S.A.) 1735 Market Street 1 703 / 527 3887 (CHEMTREC - Collect - All Other Countries) Philadelphia, PA 19103 Medical Emergencies: General Information: 1 800 / 331-3148 (PROSAR - U.S.A. & Canada) Phone: (215) 299-6000 1 651 / 632-6793 (PROSAR - All Other Countries - Collect) E-Mail: [email protected]

2. HAZARDS IDENTIFICATION

Appearance Beige liquid

Physical state Liquid

Odor Mild

Potential health effects

Acute effects Eyes May cause slight irritation. Skin May cause moderate skin irritation. Inhalation May cause irritation of respiratory tract. May cause additional effects as listed under "Ingestion". Ingestion Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause drowsiness and dizziness.

Chronic effects Repeated or prolonged exposure may cause central nervous system effects.

Environmental hazard Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 12 for additional Ecological Information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Page 1 / 7 TALSTARÒ PROFESSIONAL INSECTICIDE MSDS #: 1349-A Revision Date: 2013-02-20 Version 1 Hazardous ingredients

Chemical Name CAS-No Weight % Bifenthrin 82657-04-3 7.9 Propylene glycol 57-55-6 5-10*

4. FIRST AID MEASURES

Eye contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice.

Skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.

Inhalation Move person to fresh air. If person is not breathing, call 911 (within the U.S. and Canada) or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.

Ingestion Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.

Notes to physician This product is a pyrethroid. If large amounts have been ingested, the stomach and intestines should be evacuated. Treatment is symptomatic and supportive. Digestible fats, oils, or alcohol may increase absorption and so should be avoided.

5. FIRE-FIGHTING MEASURES

Flash Point > 100 °C / > 212 °F Method Tag Closed Cup

Sensitivity to Mechanical Impact Not applicable Sensitivity to Static Discharge Not applicable

Suitable extinguishing media Foam. Carbon dioxide (CO 2). Dry chemical. Soft stream or water fog only if necessary.

Protective equipment and precautions As in any fire, wear self-contained breathing apparatus and full protective gear. for firefighters

NFPA Health Hazard 1 Flammability 1 Stability 0 Special Hazards -

Page 2 / 7 TALSTARÒ PROFESSIONAL INSECTICIDE MSDS #: 1349-A Revision Date: 2013-02-20 Version 1 6. ACCIDENTAL RELEASE MEASURES

Personal precautions Isolate and post spill area. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8.

Environmental precautions Keep people and animals away from and upwind of spill/leak. Keep material out of lakes, streams, ponds, and sewer drains. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.

Methods for containment Dike to confine spill and absorb with non-combustible absorbent such as clay, sand or soil.

Methods for cleaning up To clean and neutralize a contaminated area, scrub area with a solution of detergent (e.g. commercial product such as SuperSoapÔ, Tide®, Spic and Span®, or other high pH detergent) and water. Let solution sit for 5 minutes. Use a stiff brush to scrub affected area. Repeat if necessary to remove visible staining. Additional decontamination can be made by applying bleach (Clorox® or equivalent) to affected area. Absorb rinsate and add to the collected waste. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated in Section 13.

Other For further clean-up instructions call CHEMTREC listed in Section 1 "Product and Company Identification" above.

7. HANDLING AND STORAGE

Handling Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.

Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep out of reach of children and animals. Store in original container only.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Exposure guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.

Chemical Name British Columbia Quebec Ontario TWAEV Alberta Propylene glycol TWA: 10 mg/m3 TWA: 50 57-55-6 ppm TWA: 155 mg/m3

Occupational exposure controls

Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.

Personal Protective Equipment

General Information If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers. These recommendations apply to the product as supplied.

Respiratory protection For dust, splash, mist or spray exposures wear a filtering mask.

Eye/face protection For dust, splash, mist or spray exposure, wear chemical protective goggles or a face-shield

Skin and body protection Wear long-sleeved shirt, long pants, socks, shoes, and gloves.

Hand protection Protective gloves

Hygiene measures Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry.

9. PHYSICAL AND CHEMICAL PROPERTIES

Page 3 / 7 TALSTARÒ PROFESSIONAL INSECTICIDE MSDS #: 1349-A Revision Date: 2013-02-20 Version 1

Basic Physical and Chemical Properties

Appearance Beige liquid Color Beige Physical state Liquid Odor Mild pH 6.7 Melting Point/Range No information available. Freezing point No information available Boiling Point/Range Not applicable Flash Point > 100 °C / > 212 °F Tag Closed Cup Evaporation rate Not applicable Vapor pressure No information available Vapor density No information available Density 8.53 lb/gal Specific Gravity 1.024 @ 20 °C Water solubility Dispersible in water Percent volatile No information available Partition coefficient Not applicable Viscosity No information available

10. STABILITY AND REACTIVITY

Stability Stable under recommended storage conditions.

Conditions to avoid Heat, flames and sparks

Hazardous decomposition products Carbon oxides, Hydrogen chloride, Hydrogen fluoride, Chlorine, Fluorine.

Hazardous polymerization Hazardous polymerization does not occur.

11. TOXICOLOGICAL INFORMATION

Acute effects

Eye contact Slightly or non-irritating (rabbit) Skin contact May cause moderate skin irritation based on the components in this product. Ingestion Large doses of bifenthrin ingested by laboratory animals produced signs of toxicity including convulsions, tremors and bloody nasal discharge.

LD50 Dermal > 2,000 mg/kg (rabbit) LD50 Oral 632 mg/kg (Rat) LC50 Inhalation 11.58 mg/L 1 hr (Rat)

Sensitization Bifenthrin: May cause sensitization by skin contact.

Chronic effects

Chronic Toxicity Repeated or prolonged exposure may cause central nervous system effects.

Carcinogenicity Bifenthrin: Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH). Did not show carcinogenic effects in animal experiments.

Mutagenicity Bifenthrin: Not genotoxic in animal studies

Neurological Effects Tremors were associated with chronic exposure of laboratory animals to bifenthrin, which may disappear with continued exposure

Developmental Toxicity Bifenthrin: Not teratogenic in animal studies.

Page 4 / 7 TALSTARÒ PROFESSIONAL INSECTICIDE MSDS #: 1349-A Revision Date: 2013-02-20 Version 1 Target Organ Effects Bifenthrin: A slight increase in male mouse urinary bladder tumors at the highest dose was probably not of toxicological concern.

Chronic Toxicity - Other Ingredient(s) Repeated overexposure to propylene glycol can produce central nervous system depression, hemolysis and minimal kidney damage.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Ecotoxicity effects .

Bifenthrin (82657-04-3) Active Ingredient(s) Duration Species Value Units Bifenthrin EC50 Aquatic organisms 0.11 - 0.57 µg/L Bifenthrin 96 h LC50 Fish 0.1 - 2.0 µg/L Bifenthrin LD50 Oral Bobwhite quail >1800 mg/kg Bifenthrin LD50 Oral Mallard duck >2150 mg/kg Bifenthrin LD50 Bee 0.1 µg/bee

Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates Propylene glycol 19000 mg/L EC50 96 h LC50= 51600 mg/L EC50 > 10000 mg/L 24 h EC50 (Pseudokirchneriella Oncorhynchus mykiss 96 h > 1000 mg/L 48 h subcapitata) LC50 41 - 47 mL/L Oncorhynchus mykiss 96 h LC50= 51400 mg/L Pimephales promelas 96 h LC50= 710 mg/L Pimephales promelas 96 h

Environmental Fate

Bifenthrin (82657-04-3) Active Ingredient(s) Type of Test Result Bifenthrin Bioconcentration factor (BCF) 1709 Bifenthrin Half-life in soil ~85 days Bifenthrin log Pow 6.6 Bifenthrin Mobility in soil Not expected to reach groundwater Bifenthrin Stability in water Stable to hydrolysis over a wide range of pH values.

13. DISPOSAL CONSIDERATIONS

Waste disposal methods Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance.

Contaminated packaging Containers must be disposed of in accordance with local, state and federal regulations. Refer to the product label for container disposal instructions.

14. TRANSPORT INFORMATION

DOT This material is not a hazardous material as defined by U.S. Department of Transportation at 49 CFR Parts 100 through 185.

Page 5 / 7 TALSTARÒ PROFESSIONAL INSECTICIDE MSDS #: 1349-A Revision Date: 2013-02-20 Version 1 Packaging Type Bulk, Non-Bulk

TDG Classification below is only applicable when shipped by vessel and is not applicable when shipped by road or rail only. UN/ID No UN3082 Proper shipping name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing group III Marine pollutant Bifenthrin. Description UN3082, Environmentally hazardous substance, liquid, n.o.s. (Bifenthrin), 9 PG III

ICAO/IATA UN/ID No UN3082 Proper shipping name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing group III Marine pollutant Bifenthrin Description UN3082, Environmentally hazardous substance, liquid, n.o.s. (Bifenthrin), 9 PG III Limited quantity 30 kg G

IMDG/IMO UN/ID No UN3082 Proper shipping name Environmentally hazardous substance, liquid, n.o.s. Hazard Class 9 Packing group III EmS No. F-A, S-F Marine pollutant Bifenthrin Description UN3082, Environmentally hazardous substance, liquid, n.o.s. (Bifenthrin), 9 PG III

Page 6 / 7 TALSTARÒ PROFESSIONAL INSECTICIDE MSDS #: 1349-A Revision Date: 2013-02-20 Version 1 15. REGULATORY INFORMATION

U.S. Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight % SARA 313 - Threshold Values % Bifenthrin 82657-04-3 7.9 1.0

SARA 311/312 Hazard Categories Acute Health Hazard yes Chronic Health Hazard yes Fire Hazard no Sudden Release of Pressure Hazard no Reactive Hazard no

CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.

International Regulations

Mexico - Grade Slight risk, Grade 1 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class D2B Toxic materials

16. OTHER INFORMATION

Revision Date: 2013-02-20 Reason for revision: (M)SDS sections updated.

Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information.

Prepared By FMC Corporation FMC Logo - Trademark of FMC Corporation

End of Material Safety Data Sheet

Page 7 / 7

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 1/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

1. Identification

Product identifier used on the label

TERMIDOR SC TERMITICIDE/INSECTICIDE

Recommended use of the chemical and restriction on use Recommended use*: insecticide

* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet

Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA

Telephone: +1 973 245-6000

Emergency telephone number

CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357)

Other means of identification Substance number: 256709 EPA Register number: 7969-210 Molecular formula: C12 H4 Cl2 F6 N4 O S Chemical family: phenyl pyrazole Synonyms: fipronil

2. Hazards Identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

Acute Tox. 4 (Inhalation - vapour) Acute toxicity Acute Tox. 4 (oral) Acute toxicity STOT RE 2 Specific target organ toxicity — repeated exposure

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 2/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Label elements

Pictogram:

Signal Word: Warning

Hazard Statement: H332 Harmful if inhaled. H302 Harmful if swallowed. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements (Prevention): P271 Use only outdoors or in a well-ventilated area. P261 Avoid breathing vapours. P260 Do not breathe dust/gas/mist/vapours. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling.

Precautionary Statements (Response): P312 Call a POISON CENTER or doctor/physician if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P330 Rinse mouth.

Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point.

Hazards not otherwise classified

Labeling of special preparations (GHS): The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 3 % dermal The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 5 % Inhalation - vapour The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 5 % Inhalation - mist

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Emergency overview

CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. HARMFUL IF INHALED. Causes eye irritation. Do not get in eyes, on skin, or on clothing. Do not breathe vapours/mists. Wash thoroughly after handling.

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 3/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

3. Composition / Information on Ingredients

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

CAS Number Content (W/W) Chemical name 120068-37-3 9.1 % fipronil 137-20-2 0.3 - 1.0 % Ethanesulfonic acid, 2-[methyl(1-oxo-9- octadecenyl)amino]-, sodium salt, (Z)- 2634-33-5 < 0.1 % 1,2-benzisothiazol-3(2H)-one

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

CAS Number Content (W/W) Chemical name 120068-37-3 9.1 % fipronil 57-55-6 3.0 % Propylene glycol 87.9 % Proprietary ingredients

4. First-Aid Measures

Description of first aid measures

If inhaled: Remove the affected individual into fresh air and keep the person calm.

If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes.

If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing.

If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow.

Most important symptoms and effects, both acute and delayed

Symptoms: CNS stimulation, tremors, convulsions Hazards: All injection injuries must be treated as potential threats to the future viability of the hand, foot, or limb. Injection wounds containing dirt, leather, product or other infectious detritus should be considered dangerous to the viability of the hand, foot or limb. Surgical exploration and debridement may be required.

Indication of any immediate medical attention and special treatment needed

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 4/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Note to physician Antidote: No known specific antidote. Treatment: Treat symptomatically. Anticonvulsant therapy as routinely administered to humans. Based on animal studies diazepam and phenobarbital prevented convulsions. Due to the slow elimination of the active compound and its metabolites, the treatment must be continued for several days, gradually decreasing the dose of anticonvulsant based on the clinical response.

5. Fire-Fighting Measures

Extinguishing media

Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray

Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, hydrogen fluoride, Hydrogen chloride, nitrogen oxides, sulfur oxides, acid halides If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released if the product is involved in a fire.

Advice for fire-fighters Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing.

Further information: In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.

Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water.

Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal.

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 5/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

7. Handling and Storage

Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment.

Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials.

Further information on storage conditions: Keep only in the original container in a cool, dry, well- ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Protect from temperatures below: 0 °C Changes in the properties of the product may occur if substance/product is stored below indicated temperature for extended periods of time. Protect from temperatures above: 40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

8. Exposure Controls/Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.

Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 6/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions.

Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit.

General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs.

9. Physical and Chemical Properties

Form: suspension Odour: characteristic Odour threshold: Not determined since harmful by inhalation. Colour: beige pH value: 7.2 ( 10 g/l) onset of boiling: approx. 100 °C ( 1,013 hPa) Information applies to the solvent. Flash point: > 206.96 °F Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Autoignition: Information applies to the solvent. not applicable Vapour pressure: approx. 23.3 hPa ( 20 °C) Information applies to the solvent. Density: 1.06 g/cm3 ( 20 °C) Vapour density: not applicable Partitioning coefficient n- not applicable octanol/water (log Pow):

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 7/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Self-ignition not self-igniting temperature: Thermal decomposition: carbon monoxide, carbon dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, Sulphur dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. If product is heated above decomposition temperature hazardous fumes may be released. Viscosity, dynamic: approx. 1,600 - ( 21.6 °C) 1,850 mPa.s Solubility in water: dispersible Molar mass: 437.15 g/mol Evaporation rate: not applicable Other Information: If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Reactivity No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: Corrosive effects to metal are not anticipated.

Oxidizing properties: Not an oxidizer. not fire-propagating

Chemical stability The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated.

Incompatible materials strong acids, strong oxidizing agents, strong bases strong oxidizing agents

Hazardous decomposition products

Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off.

Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, Sulphur dioxide

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 8/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. If product is heated above decomposition temperature hazardous fumes may be released.

11. Toxicological information

Primary routes of exposure

Acute Toxicity/Effects

Acute toxicity Assessment of acute toxicity: Slightly toxic after single ingestion. Slightly toxic after short-term skin contact. Slightly toxic after short-term inhalation.

Oral Type of value: LD50 Species: rat Value: 1,999 mg/kg

Inhalation Type of value: LC50 Species: rat Value: > 1.7 mg/l Exposure time: 4 h

Type of value: LC50 Species: rat Value: 6.8 mg/l (calculated) Exposure time: 1 h

Dermal Type of value: LD50 Species: rat Value: > 2,000 mg/kg

Irritation / corrosion Assessment of irritating effects: May cause slight irritation to the skin. May cause moderate but temporary irritation to the eyes.

Skin Species: rabbit Result: Slightly irritating.

Eye Species: rabbit Result: Slightly irritating.

Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies.

Species: guinea pig Result: Non-sensitizing.

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 9/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Chronic Toxicity/Effects

Repeated dose toxicity Assessment of repeated dose toxicity: Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Genetic toxicity Assessment of mutagenicity: Not classified, due to lack of data.

Information on: fipronil Assessment of mutagenicity: Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic. ------

Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.

Information on: fipronil Assessment of carcinogenicity: In long-term studies in rats the substance induced thyroid tumors. In long-term studies in rodents exposed to high doses, a tumorigenic effect was found; however, these results are thought to be due to a rodent-specific liver effect that is not relevant to humans. ------

Reproductive toxicity

Information on: fipronil Assessment of reproduction toxicity: Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. ------

Teratogenicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. ------

Symptoms of Exposure

CNS stimulation, tremors, convulsions

Medical conditions aggravated by overexposure Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures.

12. Ecological Information

Toxicity

Aquatic toxicity Assessment of aquatic toxicity: Very toxic (acute effect) to aquatic organisms.

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 10/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Toxicity to fish LC50 (96 h) 3.89 mg/l, Brachydanio rerio

Aquatic invertebrates EC50 (48 h) 0.2 mg/l, Daphnia pulex

Aquatic plants

Information on: fipronil EC50 (96 h) 0.068 mg/l (biomass), Scenedesmus subspicatus EC50 (336 h) > 0.160 mg/l, Lemna minor EC50 (120 h) > 0.140 mg/l, Selenastrum capricornutum EC50 (120 h) > 0.170 mg/l, Anabaena flos-aquae EC50 (120 h) > 0.120 mg/l, Navicula sp. ------

Assessment of terrestrial toxicity With high probability not acutely harmful to terrestrial organisms.

Other terrestrial non-mammals

Information on: fipronil LD50 (48 d) 0,00593 ug/bee (contact), Apis mellifera LD50 (48 d) 0,00417 ug/bee (oral), Apis mellifera ------

Persistence and degradability

Elimination information

Not readily biodegradable (by OECD criteria).

Mobility in soil

Assessment transport between environmental compartments The product has not been tested. The statement has been derived from the properties of the individual components.

Additional information

Other ecotoxicological advice: The ecological data given are those of the active ingredient. Do not release untreated into natural waters.

13. Disposal considerations

Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.

Container disposal: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 11/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.

RCRA: This product is not regulated by RCRA.

14. Transport Information

Land transport USDOT Not classified as a dangerous good under transport regulations

Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains FIPRONIL 9%)

Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains FIPRONIL 9%)

15. Regulatory Information

Federal Regulations

Registration status: Chemical TSCA, US blocked / not listed

Crop Protection TSCA, US released / exempt

EPCRA 311/312 (Hazard categories): Acute; Chronic

State regulations

State RTK CAS Number Chemical name PA 57-55-6 Propylene glycol

NFPA Hazard codes:

Safety Data Sheet TERMIDOR SC TERMITICIDE/INSECTICIDE Revision date : 2015/04/30 Page: 12/12 Version: 5.0 (30357978/SDS_CPA_US/EN)

Health : 2 Fire: 1 Reactivity: 1 Special:

Labeling requirements under FIFRA

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label.

16. Other Information

SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2015/04/30

Issuing Date 6/02/2015

The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier T211

Product Name TERRO® PCO Liquid Ant Killer

Other means of identification

Synonyms Ant Bait

Size 128 fl. oz. Recommended use of the chemical and restrictions on use

Recommended Use Insecticide - Crawling Bug - Non-Aerosol

Uses advised against It is a violation of Federal law to use this product in a manner inconsistent with its labeling

Details of the supplier of the safety data sheet

Supplier Name Senoret Chemical Company, Inc. Supplier Address 69 North Locust St. Lititz PA 17543 US Supplier Phone Number Phone:(717) 626-2125 Fax:(717) 626-1912 Contact Phone(800) 800-1819

Regulatory Licenses EPA Reg. No. 149-8

2. HAZARDS IDENTIFICATION

Classification

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Page 1 / 10 TERRO® PCO Liquid Ant Killer

GHS Label elements, including precautionary statements

Emergency Overview

None of the ingredients of this material meet the definition of "Hazardous Chemical" given in OSHA Hazard communication regulation 29CFR1910.1200(C)

Appearance Clear Physical State Liquid Odor Sweet

Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required

Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention

Precautionary Statements - Storage Store locked up

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Unknown Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity

Other information

No information available

Interactions with Other Chemicals No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-% Trade Secret Sucrose 57-50-1 40 - 70 * Sodium borate 1303-96-4 3 - 7 * *The exact percentage (concentration) of composition has been withheld as a trade secret

Page 2 / 10 TERRO® PCO Liquid Ant Killer

4. FIRST AID MEASURES

First aid measures

General Advice Show this safety data sheet to the doctor in attendance.

Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician.

Skin Contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician.

Inhalation Remove to fresh air. If symptoms persist, call a physician.

Ingestion Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.

Most important symptoms and effects, both acute and delayed

Most Important Symptoms and No information available. Effects

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical No information available.

Hazardous Combustion Products Carbon oxides.

Explosion Data Sensitivity to Mechanical Impact No.

Sensitivity to Static Discharge No.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Page 3 / 10 TERRO® PCO Liquid Ant Killer

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Avoid contact with eyes.

Environmental Precautions

Environmental Precautions Refer to protective measures listed in Sections 7 and 8.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. HANDLING AND STORAGE

STORAGE & DISPOSAL: Do not contaminate water, food, or feed by storage and disposal.

STORAGE: Store in a cool dry place. Do not store where children or animals may gain access.

PESTICIDE DISPOSAL AND CONTAINER HANDLING: Nonrefillable Container. Do not reuse or refill this container. If empty: Place in trash or offer for recycling if available. If partly filled:

Incompatible Products None known based on information supplied.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sucrose TWA: 10 mg/m3 TWA: 15 mg/m3 total dust TWA: 5 TWA: 10 mg/m3 total dust 57-50-1 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust (vacated) TWA: 15 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction Sodium borate STEL: 6 mg/m3 inhalable fraction (vacated) TWA: 10 mg/m3 TWA: 5 mg/m3 1303-96-4 TWA: 2 mg/m3 inhalable fraction ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters

Appropriate engineering controls

Page 4 / 10 TERRO® PCO Liquid Ant Killer

Engineering Measures Showers Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection No special protective equipment required.

Skin and Body Protection Wear protective gloves and protective clothing.

Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties

Physical State Liquid Appearance Clear Odor Sweet Color No information available Odor Threshold No information available

Property Values Remarks/ Method pH 8.1 None known Melting / freezing point N/A / -13 °F None known Boiling point / boiling range 100 °C / 212 °F None known Flash Point > 300 °F None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Specific Gravity 1.21 None known Water Solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/waterNo data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive properties No data available Oxidizing Properties No data available

Other Information

Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution

Page 5 / 10 TERRO® PCO Liquid Ant Killer

10. STABILITY AND REACTIVITY

Reactivity

No data available.

Chemical stability Stable under recommended storage conditions.

Possibility of Hazardous Reactions None under normal processing.

Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to avoid None known based on information supplied.

Incompatible materials None known based on information supplied.

Hazardous Decomposition Products Carbon oxides.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information Product does not present an acute toxicity hazard based on known or supplied information.

Inhalation Specific test data for the substance or mixture is not available.

Eye Contact Specific test data for the substance or mixture is not available.

Skin Contact Specific test data for the substance or mixture is not available.

Ingestion Specific test data for the substance or mixture is not available.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sodium borate = >5 g/kg ( Rat ) > 5,000 mg/kg ( Rabbit ) > 5 mg/L ( Rat ) 4 h 1303-96-4

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Mutagenic Effects No information available.

Page 6 / 10 TERRO® PCO Liquid Ant Killer

Carcinogenicity None of the components is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA.

Chemical Name ACGIH IARC NTP OSHA Sodium borate 1303-96-4

Reproductive Toxicity No information available

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Chronic Toxicity No known effect based on information supplied.

Target Organ Effects No information available

Aspiration Hazard No information available.

12. ECOLOGICAL INFORMATION

Ecotoxicity The environmental impact of this product has not been fully investigated.

Persistence and Degradability No information available.

Bioaccumulation No information available

Other adverse effects No information available.

Page 7 / 10 TERRO® PCO Liquid Ant Killer

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging Dispose of contents/containers in accordance with local regulations.

California Hazardous Waste Codes 232

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Sodium borate Toxic 1303-96-4

14. TRANSPORT INFORMATION

DOT NOT REGULATED Proper Shipping Name NON-REGULATED Hazard Class N/A

TDG Not regulated

MEX Not regulated

ICAO Not regulated

IATA Not regulated Proper Shipping Name NON-REGULATED Hazard Class N/A

IMDG/IMO Not regulated Hazard Class N/A

RID Not regulated

ADR Not regulated

ADN Not regulated

15. REGULATORY INFORMATION International Inventories

TSCA Complies DSL All components are listed either on the DSL or NDSL.

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

Page 8 / 10 TERRO® PCO Liquid Ant Killer

US Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard Yes Fire Hazard No Sudden release of pressure hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

US State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Supplier Trade Secret X X Sodium borate X X X X 1303-96-4 EPA Pesticide Registration Number 149-8

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.

Pesticide Label Signal Word: Caution

Page 9 / 10 TERRO® PCO Liquid Ant Killer

16. OTHER INFORMATION

NFPA Health Hazards 1 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazards 1* Flammability 0 Physical Hazard 0 Personal Protection X Chronic Hazard Star Legend * = Chronic Health Hazard

Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Issuing Date 03-Nov-2010 Revision Date 05-Oct-2014 Revision Note No information available

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

Page 10 / 10 Issue Date: 11/1999 Material Safety Data Sheet Revised Date: 11/2010

INSECTICIDE, AND FUNGICIDE ® Health Emergencies: CHEMTREC (800) 424-9300

SECTION I – COMPANY AND PRODUCT Ingestion: Swallowing small quantities (one teaspoon) will cause no INDENTIFICATION harm to healthy adults. If larger amounts are swallowed, give two glasses of water to drink and seek medical attention. Manufacturer: Nisus Corporation Note to physicians: Observation only is required for adult ingestion 100 Nisus Drive in the range of 4-8 grams of Tim-Bor Professional. For ingestion of Rockford, TN 37853 larger amounts, maintain adequate kidney function and force fluids. (800) 264-0870 Fax: (865) 577-5825 Gastric lavage is recommended for symptomatic patients only. Product name: Tim-bor® Professional Hemodialysis should be reserved for massive acute ingestion or Grade: Technical patients with renal failure. Boron analyses of urine or blood are only Product use: Termiticide, insecticide, fungicide useful for documenting exposure and should not be used to evaluate Chemical formula: Na2B8O13 •4H2O severity of poisoning or to guide treatment. Refer to Section 11 for Chemical name/synonyms: Disodium octaborate tetrahydrate details. Chemical family: Inorganic borates CAS registry number: 12280-03-4 SECTION V – FIRE FIGHTING MEASURES EPA registration number: 64405-8 General hazard: None, because TIM-BOR Professional is not (Refer to Section I5 for TSCA/DSL Chemical inventory listing) flammable, combustible or explosive. The product is itself a flame SECTION II – COMPOSITION/INFORMATION ON retardant. INGREDIENTS Extinguishing Media: Any extinguishing media may be used on nearby fires. This product contains greater than 98 percent (%) disodium octaborate Flammability Classification (29 CFR 1910.1200): tetrahydrate, Na B 0 •4H 0, which is hazardous under the OSHA 2 8 13 2 Non-flammable solid. Hazard Communication Standard and under the Canadian Controlled Products Regulations of the Hazardous Products Act (WHMLS), based SECTION VI – ACCIDENTAL RELEASE MEASURES on animal chronic toxicity studies. Refer to Sections 3 and 11 for General: TIM-BOR Professional is a water-soluble white powder details on hazards. that may, at high concentrations, cause damage to trees or vegetation SECTION III – HAZARD IDENTIFICATION by root absorption. At low concentrations it is a micronutrient. (Refer to Ecological Information, Section 12, for specific information.) Emergency overview: TIM-BOR Professional is a white, odorless, powdered substance that is not flammable, combustible, or Land spill: Vacuum, shovel or sweep up TIM-BOR Professional explosive and has low acute oral and dermal toxicity. and place in containers for disposal in accordance with applicable local Potential ecological effects: Large amounts of TIM-BOR regulations. Avoid contamination of water bodies during cleanup and Professional can be harmful to plants and other species. Therefore, disposal. releases to the environment should be minimized. Spillage into water: Where possible, remove any intact containers Potential heath effects: Routes of exposure: Inhalation is the from the water. Advise local water authority that none of the affected most significant route of exposure in occupational and other settings. water should be used for irrigation or for the abstraction of potable Dermal exposure is not usually a concern because TIM-BOR water until natural dilution returns the boron value to its normal Professional is poorly absorbed through intact skin. environmental background level. Inhalation: Occasional mild irritation effects to nose and throat may TIM-BOR Professional is a non-hazardous waste when spilled or occur from inhalation of TIM-BOR Professional dust at levels disposed of, as defined in the Resource Conservation and Recovery 3 greater than 10 mg/m . Act (RCRA) regulations (40 CFR 261 ). (Refer to Regulatory Eye contact: TIM-BOR Professional is non-irritating to eyes in information, Section 15, for additional references.) normal use. SECTION VII – HANDLING AND STORAGE Skin contact: TIM-BOR Professional does not cause irritation to intact skin. General: No special handling precautions are required, but dry indoor Ingestion: Products containing TIM-BOR Professional are not storage is recommended. To maintain package integrity and to intended for ingestion. TIM-BOR Professional has a low acute minimize caking of the product, bags should be handled on a first-in, toxicity. Small amounts (e.g., a teaspoonful) swallowed accidentally first-out basis. Good housekeeping procedures should be followed to are not likely to cause effects; swallowing amounts larger than that minimize dust generation and accumulation. may cause gastrointestinal symptoms. Storage temperature: Ambient Cancer: TIM-BOR Professional is not a known carcinogen. Storage pressure: Atmospheric Reproductive/developmental: Animal ingestion studies in several Special sensitivity: Moisture (caking) species, at high doses, indicate that borates cause reproductive and developmental effects. A human study of occupational exposure to SECTION VIII – EXPOSURE CONTROLS / PERSONAL borate dust showed no adverse effect on reproduction. PROTECTION Target organs: No target organ has been identified in humans. Engineering controls: Use local exhaust ventilation to keep Signs and symptoms of exposure: Symptoms of accidental airborne concentrations of TIM-BOR Professional dust below over-exposure to TIM-BOR Professional might include nausea, permissible exposure levels. vomiting, and diarrhea, with delayed effects of skin redness and Personal protection: Refer to label for actual regulatory personal peeling. These symptoms have been associated with the accidental protection requirements. Where airborne concentrations are expected over-exposure to the chemically related substance boric acid by to exceed exposure limits (e.g. confined spaces), NIOSH/MSHA ingestion or absorption through large area of damaged skin. certified respirators must be used. Eye protection, protective clothing Refer to Section 11 for details on toxicological data. and waterproof gloves may also be warranted under certain high SECTION IV – FIRST AID MEASURES exposure conditions. Inhalation: If symptoms such as nose or throat irritation are Occupational exposure limits: Disodium octaborate tetrahydrate observed, remove person to fresh air. (TIM-BOR Professional) is treated by OSHA, Cal OSHA and Eye contact: Use eye wash fountain or fresh water to cleanse eye. If ACGIH as “Particulate Not Otherwise Classified” or “Nuisance Dust”. The OSHA/PEL (Permissible Exposure Level) is 15 mg/m3 total dust irritation persists for more than 30 minutes, seek medical attention. 3 3 Skin contact: No treatment necessary because non-irritating. and 5 mg/m respirable dust. The Cal OSHA/PEL is 10 mg/m . The ACGIH/TLV (Threshold Limit Value) is 10 mg/m3.

SECTION IX – PHYSICAL AND CHEMICAL PROPERTIES 96-hr LC50 74 MG B/L* Freshwater: Appearance: White, odorless, powder Rainbow trout, S. gairdneri (embryo-larval stage) Bulk density: 320 to 480 kg/m3 24-day LC = 88 mg B/L* Vapor pressure: Negligible @ 200C 50 32-day LC = 54 mg B/L* Solubility in water: 9.7% @ 200C; 34.3% @ 500C 50 Goldfish, Carassius auratus (embryo-larval stage) Melting point: 8150C 7-day LC50 = 65 mg B/L* pH @ 20°C: 8.3 (3.0% solution) 3-day LC = 71 mg B/L* 7.6 (10.0% solution) 50 Molecular Weight: 412.52 *Test substance: sodium tetraborate SECTION X – STABILITY AND REACTIVITY Environmental Fate Data Persistence/degradation: Boron is naturally occurring and General: TIM-BOR Professional is a stable product. ubiquitous in the environment. TIM-BOR Professional decomposes Incompatible materials and conditions to avoid: Reaction with in the environment to natural borate. strong reducing agents, such as metal hydrides or alkali metals, will Octanol/water partition coefficient: No value. In aqueous generate hydrogen gas, which could create explosive hazard. solution disodium octaborate tetrahydrate is converted substantially Hazardous decomposition: None. into undissociated boric acid. SECTION XI – TOXICOLOGICAL INFORMATION Soil Mobility: TIM-BOR Professional is soluble in water and is Acute toxicity leachable through normal soil.

Ingestion: Low acute oral toxicity; LD50 in rats is 2,550 mg/kg of body SECTION XIII – DISPOSAL CONSIDERATONS weight. Disposal Guidance: Small quantities of TIM-BOR Professional Skin/dermal: Low, acute dermal toxicity; LD50 in rabbits is greater can usually be disposed of at landfill sites. No special disposal than 2,000 mg/kg of body weight. TIM-BOR Professional is poorly treatment is required, but local authorities should be consulted about absorbed through intact skin. any specific local requirements. Tonnage quantities of product are not

Inhalation: Low acute inhalation toxicity; LD50 in rats is greater than recommended to be sent to landfills. Such product should, if possible, 2.0 mg/L (or g/m3). be used for an appropriate application. Skin irritation: Non-irritant. RCRA (40 CFR 261): TIM-BOR Professional is not listed under Eye irritation: Draize test in rabbits produced mild eye irritation any sections of the Federal Resource Conservation and Recovery Act effects. Years of occupational exposure to TIM-BOR Professional (RCRA). indicates no adverse effects on human eye. Therefore TIM-BOR Refer to Section 15 for additional regulatory information. Professional is not considered to be a human eye irritant in normal SECTION XIV – TRANSPORT INFORMATION industrial use. DOT HAZARDOUS CLASSIFICATION: Disodium octaborate Sensitization: TIM-BOR Professional is not a skin sensitizer. tetrahydrate (TIM-BOR Professional) is not regulated by the U.S. Other Department of Transportation (DOT) and is therefore not considered a Reproductive/developmental toxicity: Animal feeding studies in hazardous material/substance. rat, mouse and dog, at high doses, have demonstrated effects on International transportation: Disodium octaborate tetrahydrate fertility and testes. Studies with the chemically related boric acid in the (TIM-BOR Professional) has no UN Number, and is not regulated rat, mouse and rabbit, at high doses, demonstrate developmental under international rail, road, water or air transport regulations. effects on the fetus, including fetal weight loss and minor skeletal variations. The doses administered were many times in excess of SECTION XV – REGULATORY INFORMATION those to which humans would normally be exposed. OSHA/Cal OSHA: This MSDS document meets the requirements of Carcinogenicity/mutagenicity: No evidence of carcinogenicity in both OSHA (29 CFR 1910.1200) and Cal OSHA (Title 8 CCR 5194 (g)) mice. No such effects have been observed in humans for boric acid in hazard communication standards. Refer to Section 8 for regulatory a battery of short-term mutagenicity assays. exposure limits. Human data: Human epidemiological studies show no increase in FIFRA: TIM-BOR Professional is registered with the EPA (EPA pulmonary disease in occupational populations with chronic exposures Reg. No. 64405-8), in accordance with Section 3 of the Federal to boric acid dust and sodium borate dust. A recent epidemiology study Professional, Fungicide and Rodenticide Act (FIFRA), as a pesticide under the conditions of normal occupational exposure to borate dusts product. Refer to EPA approved product label for additional product indicated no effect on fertility. hazard and precautionary information. SECTION XII – ECOLOGICAL INFORMATION Chemical Inventory Listing: Disodium octaborate tetrahydrate (TIM-BOR Professional), 12280-03-4, appears on several chemical Ecotoxicity Data inventory lists, including the EPA TSCA inventory, under the CAS No. General: Boron (B) is the element in disodium octaborate representing the anhydrous form of this inorganic salt. tetrahydrate (TIM-BOR Professional) which is used by convention U.S. EPA TSCA Inventory 12008-41-2 to report borate product ecological effects. It occurs naturally in RCRA: Disodium octaborate tetrahydrate is not listed as a hazardous seawater at an average concentration of 5 mg B/L and generally waste under any sections of the Resource Conservation and Recovery occurs in freshwater at concentrations up to 1mg B/L. In dilute Act (RCRA) or regulations (40 CFR 261 et seq). aqueous solutions the predominant boron species present is California Proposition 65: Disodium octaborate tetrahydrate undissociated boric acid. To convert disodium octaborate tetrahydrate (TIM-BOR Professional) is not listed on the Proposition 65 list of into the equivalent boron (B) content, multiply by 0.2096. carcinogens or reproductive toxicants. Phytotoxicity: Boron is an essential micronutrient for healthy growth Superfund: CERCLA/SARA. Disodium octaborate tetrahydrate is not of plants; however, it can he harmful to boron sensitive plants (e.g. listed under CERCLA or its 1986 amendments, SARA, including grass and ornamentals) in high quantities. Care should be taken to substances listed under Section 313 of SARA, Toxic Chemicals, 42 minimize the amount of TIM-BOR Professional accidentally spilled USC 11023, 40 CFR 372.65, Section 302 of SARA, Extremely and released to the environment. Hazardous Substances, 42 USC 11002, 40 CFR 355, or the CERCLA Algal Toxicity: Green algae, Scenedesmus subspicatus Hazardous Substances list, 42 USC 9604, 40 CFR 302.. 96-hr EC = 24 mg B/L* 10 Safe Drinking Water Act (SDWA): Disodium octaborate Invertebrate Toxicity: Daphnids, Daphnia magna straus tetrahydrate is not regulated under the SDWA, 42 USC 300g-I, 40 CFR 24-hr EC50=242 mg B/L* 141 et seq. Consult state and local regulations for possible water Fish Toxicity: quality advisories regarding boron compounds. Seawater: Clean Water Act (CWA) (Federal Water Pollution Control Dab, Limanda limanda Act):

Tim-bor Professional MSDS • p. 2 of 3

33 USC 1251 et seq. Clean Air Act (Montreal Protocol): TIM-BOR Professional a) Disodium octaborate tetrahydrate (TIM-BOR was not manufactured with and does not contain any Class I or Class II Professional) is not itself a discharge covered by any ozone depleting substances. water quality criteria of Section 304 of the CWA, 33 USC SECTION XVI – OTHER INFORMATION 1314. b) It is not on the Section 307 List of Priority Pollutants, 33 USC REFERENCES For general information on the toxicity of inorganic borates, see Patty’s 1317, 40 CFR 129. th c) It is not on the Section 311 List of Hazardous Substances, Industrial Hygiene and Toxicology, 4 Ed. Vol. II (1994), Chap. 42, 33 USC 1321, 40 CFR 116. Boron; ECETOC Tech. Report No. 63 (1995). IARC: The International Agency for Research on Cancer (IARC) (a Product label text hazard information: unit of the World Health Organization) does not list or categorize Refer to EPA (United States) approved product specimen label for disodium octaborate tetrahydrate as a carcinogen. additional product hazard and precautionary information. NTP Biennial Report on Carcinogens: Disodium octaborate For further information contact: tetrahydrate is not listed. NISUS Corporation OSHA carcinogen: Disodium octaborate tetrahydrate is not listed. Technical and Sales Support 800-264-0870

100 Nisus Drive • Rockford, TN 37853 (800) 264-0870

*Timbor and the House Design trademark are registered trademarks of U. S. Borax, Inc. and are used under license. Nisus is a registered trademark of Nisus Corporation. ©2010 Nisus Corporation #TP-MSDS-OSHA-1110

Tim-bor Professional MSDS • p. 3 of 3

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 1/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

1. Product and Company Identification

Company 24 Hour Emergency Response Information BASF CORPORATION CHEMTREC: 1-800-424-9300 100 Campus Drive BASF HOTLINE: 1-800-832-HELP Florham Park, NJ 07932

Registrant: Whitmire Micro-Gen Research Laboratories, Inc. 3568 Tree Court Industrial Blvd. St. Louis, MO 63122

Substance number: 000000395959 Synonyms: Pyrethrins + piperonyl butoxide + amorphous silica dixoide

2. Hazards Identification

Emergency overview

CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. Moderately irritating to the eyes. Avoid inhalation of dusts. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling.

See Product Label for additional precautionary statements.

State of matter: solid Colour: white Odour: faint odour

Potential health effects

Acute toxicity: Relatively nontoxic after single ingestion. Slightly toxic after short-term skin contact. Relatively nontoxic after short-term inhalation.

Irritation / corrosion: May cause moderate but temporary irritation to the eyes. May cause slight irritation to the skin.

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 2/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

Sensitization: Skin sensitizing effects were not observed in animal studies.

Signs and symptoms of overexposure: Vomiting may cause aspiration pneumonia due to the ingredients.

Potential environmental effects

Aquatic toxicity: Acutely toxic for aquatic organisms. The product has not been tested.

3. Composition / Information on Ingredients

CAS Number Content (W/W) Chemical name 8003-34-7 1.0 % Pyrethrins 51-03-6 10.0 % Piperonylbutoxide 112926-00-8 40.0 % Silica gel, precipitated, crystalline free 64742-47-8 >= 10.0 % Distillates (petroleum), hydrotreated light <= 39.0 % Proprietary ingredients

4. First-Aid Measures

If inhaled: Remove the affected individual into fresh air and keep the person calm.

If on skin: Rinse skin immediately with plenty of water for 15 - 20 minutes.

If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing.

If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow.

Note to physician Treatment: Aspiration of this product during induced emesis can result in lung injury. If evacuation of stomach contents is considered necessary, use method least likely to cause aspiration, such as gastric lavage after endotracheal intubation.

5. Fire-Fighting Measures

Flash point: 177 °F

Suitable extinguishing media: foam, dry extinguishing media, carbon dioxide

Hazards during fire-fighting: carbon monoxide, carbon dioxide,

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 3/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire.

Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

6. Accidental release measures

7. Handling and Storage

Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials.

Storage stability:

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 4/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet.

8. Exposure Controls and Personal Protection

Users of a pesticidal product should refer to the product label for personal protective equipment requirements.

Components with workplace control parameters Pyrethrins OSHA PEL 5 mg/m3 ; ACGIH TWA value 5 mg/m3 ; Distillates (petroleum), hydrotreated light ACGIH TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin.

Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment.

Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:

Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit.

9. Physical and Chemical Properties

Form: powder Odour: faint odour

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 5/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

Colour: white pH value: of low solubility, not determined Density: 0.278 g/cm3 (approx. 70 °F) Solubility in water: slightly soluble

10. Stability and Reactivity

Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme temperatures. Avoid prolonged exposure to extreme heat. Avoid contamination. Avoid electro-static discharge. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded.

Substances to avoid: strong oxidizing agents

Hazardous reactions: The product is chemically stable.

Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off.

Corrosion to metals: Corrosive effects to metal are not anticipated.

11. Toxicological information

Acute toxicity

Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg

Inhalation: Type of value: LC50 Species: rat Value: > 4.3 mg/l

Dermal: Type of value: LD50 Species: rabbit Value: > 2,000 mg/kg

Irritation / corrosion

Skin: Species: rabbit Result: non-irritant

Eye: Species: rabbit Result: non-irritant

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 6/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

May cause slight irritation to the eyes.

Genetic toxicity

Information on: pyrethrum No mutagenic effects reported.

Information on: Piperonyl butoxide Results from a number of mutagenicity studies with microorganisms and mammalian cell culture are available. Taking into account all of the information, there is no indication that the substance is mutagenic.

Information on: Silica gel, precipitated, crystalline free The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell culture. The substance was not mutagenic in studies with mammals.

Information on: Distillates (petroleum), hydrotreated light In the majority of tests performed (bacteria/microorganisms/cell cultures) a mutagenic effect was not found. A mutagenic effect was also not observed in in-vivo assays. Literature data. ------

Carcinogenicity

Information on: pyrethrum Not Likely to Be Carcinogenic to Humans. Information on: Piperonyl butoxide The US EPA has classified this substance with the rating of 'C', possible human carcinogen. ------

Reproductive toxicity

Information on: pyrethrum No reproductive toxic effects reported. Information on: Piperonyl butoxide No reproductive toxic effects reported. ------

Development:

Information on: pyrethrum No indications of a developmental toxic / teratogenic effect were seen in animal studies. Information on: Piperonyl butoxide No indications of a developmental toxic / teratogenic effect were seen in animal studies. Information on: Distillates (petroleum), hydrotreated light No indications of a developmental toxic / teratogenic effect were seen in animal studies. Literature data. ------

12. Ecological Information

Fish

Information on: pyrethrum Acute: Oncorhynchus mykiss/LC50 (96 h): 0.0051 mg/l

Information on: Piperonyl butoxide Acute: other Oncorhynchus mykiss/LC50 (96 h): 6.12 mg/l

Information on: Distillates (petroleum), hydrotreated light Acute: Brachydanio rerio/LC50 (96 h): 7.3 mg/l

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 7/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

The product has not been tested. The statement has been derived from products of a similar structure and composition. Literature data. ------

Aquatic invertebrates

Information on: pyrethrum Acute: Daphnia magna/EC50 (48 h): 0.0116 mg/l

Information on: Piperonyl butoxide Acute: other Daphnia magna/EC50 (48 h): 0.51 mg/l

Information on: Distillates (petroleum), hydrotreated light Acute: Daphnia magna/EL50 (48 h): 1.4 - 21 mg/l The product has not been tested. The statement has been derived from products of a similar structure and composition. Literature data. ------

Aquatic plants

Information on: Piperonyl butoxide Toxicity to aquatic plants: other green algae/EC50:

Information on: Distillates (petroleum), hydrotreated light Toxicity to aquatic plants: algae/EC50 (72 h): 3.7 - 8.3 mg/l Literature data. ------

13. Disposal considerations

14. Transport Information

Reference Bill of Lading

15. Regulatory Information

Federal Regulations

Registration status: Chemical TSCA, US blocked / not listed

Crop Protection TSCA, US released / exempt

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 8/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

EPCRA 311/312 (Hazard categories): Acute; Chronic

EPCRA 313: CAS Number Chemical name 51-03-6 Piperonylbutoxide

CERCLA RQ CAS Number Chemical name 1 LBS 121-21-1 pyrethrin I

State regulations

State RTK CAS Number Chemical name MA, NJ, PA 8003-34-7 Pyrethrins

16. Other Information

Refer to product label for EPA registration number.

Recommended use: insecticide

Local Contact Information Product Stewardship 919 547-2000

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR

Safety Data Sheet TRI-DIE SILICIA + PYRETRHUM DUST Revision date : 2009/12/18 Page: 9/9 Version: 1.0 (30472235/SDS_CPA_US/EN)

TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF SPARKS LLC HEREUNDER ARE GIVEN GRATIS AND BASF SPARKS LLC ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF POLYURETHANE FOAM ENTERPRISES LLC HEREUNDER ARE GIVEN GRATIS AND BASF POLYURETHANE FOAM ENTERPRISES LLC ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

Uncle Albert’s Super Smart Ant™ Bait Material Safety Data Sheet

Section 1. Chemical Products and Company Identification

Trade Name of this Product: Uncle Albert’s Super Smart™ Ant Bait

Manufacturer Prepared by Green Star Group, LTD John C. Mills 1834 Carpenter Road Hutchins, TX 75141 +1-866-KILL-ANTS (+1-866-545-5268)

Effective Date Emergency Phone January 2007 +1-214-507-7299

Section 2. Composition and Information on Ingredients

This product is not hazardous as defined in 29 CFR 1910.1200, based on the following compositional information: Ingredient CAS Number Weight % ACGIH TLV OSHA TVL PEL STEL PEL STEL Disodium octaborate tetrahydrate 12280-03-4 <1 NE ppm NE ppm NE ppm NE ppm

Section 3. Hazard Identification

******EMERGENCY OVERVIEW******* * The Flash Point is >300 degrees F. * This product is a pale to clear odorless viscous liquid. * This product has very low acute dermal and oral toxicity. * This product is not listed on the NPT, IARC, OSHA or ACGIH lists of suspected/confirmed carcinogens. * This product is registered with the EPA (Reg. 83487-1) and is not listed on the RCRA, Cal. Prop. 65, Superfund, SDWA, or CWA lists as a hazardous substance or pollutant. * This product is readily biodegradable in the presence of air and sunlight. * Spilled material may be slippery when wet. ******END OF EMERGENCY OVERVIEW******

+1-866-Kill-Ants (+1-866-545.5268) Page 1 of 6

Uncle Albert’s Super Smart Ant™ Bait

Section 3. Hazard Identification - Continued

POTENTIAL HEALTH EFFECTS PRIMARY ROUTE OF ENTRY INGESTION This product is not intended for ingestion. Accidental ingestion of small amounts (500ml) are not likely to cause effects. Larger amounts may cause mild gastrointestinal symptoms. Secondary Routes of Exposure: EYES Tests on similar materials indicate this product may be slightly irritating to eyes due to its viscosity. SKIN Tests on similar materials indicate this product is a non-irritant. CHRONIC (CANCER INFORMATION) Carcinogen listed by: National Toxicology Program (No) I.A.R.C. (No) OSHA (No) ACGIH (No) This product does not require a cancer hazard warning in accordance with the OSHA Hazard Communication Standard. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Personnel with pre-existing open skin lesions should avoid contact with this product.

Section 4. First Aid Information

EYES Flush eyes with fresh water, occasionally lifting lower and upper lids, for at least 15 minutes or until irritation subsides. If irritation persists more than 30 minutes, seek medical attention. SKIN Wash thoroughly with soap and water. INGESTION Dilute by drinking a glass of fresh water. Induce vomiting if more than 500ml is ingested. Never give anything by mouth to an unconscious person. INHALATION Not a probable route of entry due to the viscous nature of the liquid.

+1-866-Kill-Ants (+1-866-545.5268) Page 2 of 6

Uncle Albert’s Super Smart Ant™ Bait

Section 5. Fire Fighting Measures

FLAMMABLE PROPERTIES FLASH POINT: above 300OF AUTOIGNITION: above 500oF FLAMMABILITY CLASS: Non-Flammable Liquid LOWER EXPLOSIVE LIMIT (%): n/a UPPER EXPLOSIVE LIMIT (%): n/a

FIRE AND EXPLOSION HAZARDS None. EXTINGUISHING MEDIA Not Applicable. FIRE FIGHTING INSTRUCTIONS Use water to cool containers exposed to flames. Do not enter an enclosed or confined workspace without proper protective equipment.

Section 6. Accidental Release Measure

This product is a non-hazardous waste when spilled or disposed of, as defined by RCRA regulations (40 CFR 261).

Section 7. Handling and Storage

HANDLING No special handling precautions are required; dry indoor storage is recommended. See Section 8 for additional personal protection advice on handling this product.

STORAGE Store in a cool dry area.

SPECIAL PRECAUTIONS None.

EMPTY CONTAINER WARNING All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations.

WORK/HYGIENIC PRACTICES Wash hands with soap and water before eating, drinking, smoking or use of toilet facilities. Do not use harsh abrasive skin cleaners for washing exposed skin areas.

+1-866-Kill-Ants (+1-866-545.5268) Page 3 of 6

Uncle Albert’s Super Smart Ant™ Bait

Section 8. Exposure Controls and Personal Protection

EYE/FACE PROTECTION Safety glasses, as appropriate. SKIN PROTECTION Wearing of vinyl or latex gloves is recommended as a safety measure and to avoid product contamination when placing product in target locations. RESPIRATORY PROTECTION None required.

Section 9. Physical and Chemical Properties

APPEARANCE Pale to clear odorless viscous liquid.

ODOR None. ODOR THRESHOLD N/A PHYSICAL PROPERTIES PHYSICAL STATE: Viscous Liquid BOILING POINT: IBP >242OF, IBP >117OC MELTING POINT: 35oF (approx.) VAPOR PRESSURE: n/e SPECIFIC GRAVITY: 1.23 Water = 1 o SOLUBILITY (H2O): 100% @ 77 F PERCENT VOLATILES: 65% (approx.) Physical data may vary slightly to meet specifications.

+1-866-Kill-Ants (+1-866-545.5268) Page 4 of 6

Uncle Albert’s Super Smart Ant™ Bait

Section 10. Stability and Reactivity

STABILITY Stable. CONDITIONS TO AVOID Strong reducing agents such as metal hydrides or alkali metals. Contact with such may generate hydrogen gas, which might create an explosive hazard. INCOMPATIBLE MATERIALS Strong reducing agents such as metal hydrides or alkali metals. HAZARDOUS DECOMPOSITION PRODUCTS None. HAZARDOUS POLYMERIZATION: Will not occur.

Section 11. Toxicological Information

SKIN EFFECTS May cause irritation or dermatitis with prolonged and repeated contact. ORAL EFFECTS Tests on similar materials indicate a low order of acute oral toxicity. INHALATION EFFECTS Acute toxicity expected on inhalation due to viscosity of liquid (e.g. suffocation). MEDICAL CONDITIONS AGGRAVED BY OVEREXPOSURE Dermatitis and sensitive skin – this product is not listed as carcinogenic or a potential carcinogen by the national toxicology program, by the I.A.R.C. monographs or by OSHA. Nevertheless, good industrial hygienic practices are recommended.

Section 12. Ecological Information

This product is neither phytotoxic nor Algal toxic. It is toxic to certain arthropods (its target population). It is not toxic to fish under normal usage, but may coat gill structures resulting in suffocation if spilled in shallow, non-moving water at dilution ratios above 20%. Undiluted product may be slightly toxic to amphibians by preventing dermal respiration. This product is rapidly biodegradable. Biodegradation occurs within 10 to 20 days in aerobic environments at temperatures above 70oF (21oC).

+1-866-Kill-Ants (+1-866-545.5268) Page 5 of 6

Uncle Albert’s Super Smart Ant™ Bait

Section 13. Disposal Considerations

Product as supplied does not meet the characteristics of a hazardous waste as defined in 40 CFR 261.21-24.

Section 14. Transportation Information

This product is not regulated by the US Department of Transportation. This product is not regulated by the International Air Transport Association.

Section 15. Regulatory Information

U.S. FEDERAL REGULATORY INFORMATION SARA 302 Threshold Planning Quantity: NOT APPLICABLE SARA 304 Reportable quantity: NOT APPLICABLE SARA TITLE 3 – Section 311/312 Hazard classes: NOT APPLICABLE Comprehensive Environmental Response. Compensation and Liability Act (CERCLA): No chemicals in this product are subject to the reporting requirements of CERCLA Section 101(14)(F).

Section 16. Other Information

HAZARDOUS MATERIAL RATINGS HMIS NFPA 704 KEY Health 1 0 4 = Severe Flammability 0 0 3 = Serious Reactivity 0 0 2 = Moderate 1 = Slight 0 = Minimal HMIS – Hazardous Materials Identification System NFPA 704 – National Fire Protection Association

The information contained herein is based on data believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. As this product is registered with the United States Environmental Protection Agency, the labeling must contain certain prescribed warnings not necessarily related to the actual hazard presented by the product. By way of comparison, this product is more than 50 times LESS toxic to mammals (based on LD50 data for rats) than all natural organic table salt.

+1-866-Kill-Ants (+1-866-545.5268) Page 6 of 6 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011

1. PRODUCT IDENTIFICATION

Product identifier on label: WEATHERBLOK® XT Product No.: A12720G Use: Rodenticide Manufacturer: Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419

Manufacturer Phone: 1-800-334-9481

Emergency Phone: 1-800-888-8372

2. HAZARDS IDENTIFICATION

Classifications: Not Applicable Signal Word (OSHA): Not Applicable

Hazard Statements: Not Applicable

Hazard Symbols:

Precautionary Statements: Not Applicable

Other Hazard Statements: May form combustible dust concentrations in air.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Common Name CAS Number Concentration Paraffin Wax Paraffin Wax 8002-74-2 Trade Secret Oat Flour Oat Flour Not Applicable Trade Secret 3-[3-(4'-bromo[1,1'-biphenyl]-4-yl)-1,2,3,4- Brodifacoum Technical 56073-10-0 (0.005%) tetrahydro-1-naphthalenyl]-4-hydroxy-2H- 1-benzopyran-2-one

Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

Page 1 of 7 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011 4. FIRST AID MEASURES

Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment.

Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Wash skin with soap and water. Inhalation: If inhaled: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Most important symptoms/effects:

Indication of immediate medical attention and special treatment needed: This product contains anticoagulants with an effect similar to warfarin in that they act by interfering with the synthesis of prothrombin. The specific measure of effect is the prothrombin time. Note this may not become prolonged until 12-18 hours after ingestion. The specific antidote is Vitamin K1 (Phytomenandione BP). Antidote must be administered under medical supervision. Initially, antidote should be given by injection (10-20 mg, or 0.25 mg/kg for children, by slow intravenous infusion at a rate not exceeding 1 mg/minute. In severe cases the use of fresh frozen plasma may be required). Maintenance treatment is given orally (40 mg/day in divided doses for adults; up to 20 mg/day in divided doses for children). The prothrombin time and the hemoglobin should be monitored. Patients should be kept under medical supervision until the prothrombin time has been normal for 3 consecutive days. Oral treatment may need to be continued for several months (20 mg/day in divided doses for adults, and up to 20 mg/day in divided doses for children). (For animal cases the dose is 2-5 mg/kg). Each 20 g bar contains 1 mg of brodifacoum. Further information is available from the Syngenta emergency number provided in this document.

5. FIRE FIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8.

Page 2 of 7 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011 7. HANDLING AND STORAGE

Conditions for safe storage, including any incompatibilities: Not Applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:

Chemical Name OSHA PEL ACGIH TLV Other Source

Paraffin Wax Not Established 2 mg/m³ TWA (fume) 2 mg/m³ TWA (fume) NIOSH

Oat Flour Not Established Not Established Not Established Not Applicable

Brodifacoum Technical Not Established Not Established 0.002 mg/m³ TWA Syngenta

Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures:

Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Eye protection is not required for normal handling. Where eye contact is likely, wear tight-fitting chemical goggles.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Blue solid Odor: Slight cereal and wax odor Odor Threshold: Not Available pH: Not Available Melting point/freezing point: 130 °F (paraffin wax) Initial boiling point and boiling range: Not Applicable

Page 3 of 7 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011 Flash Point (Test Method): > 375°F (paraffin wax) Method: PMCC Flammable Limits (% in Air): Not Available Flammability: Not Applicable

Vapor Pressure: Brodifacoum Technical 6 x 10(-6) mmHg @ 68°F (20°C) Vapor Density: Not Available Relative Density: 1.15 g/ml Solubility (ies): Brodifacoum Technical Insoluble

Partition coefficient: n-octanol/water: Not Available Autoignition Temperature: Not Available

Decomposition Temperature: Not Available Viscosity: Not Available Other: None

10. STABILITY AND REACTIVITY

Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur.

Conditions to Avoid: None known.

Incompatible materials: None known.

Hazardous Decomposition Products: None known.

11. TOXICOLOGICAL INFORMATION

Health effects information Likely routes of exposure: Dermal, Inhalation

Symptoms of exposure: Not Applicable

Delayed, immediate and chronic effects of exposure: Not Applicable

Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Rabbit) : > 5000 mg/kg body weight

Dermal: Dermal (LD50 Rat) : See "Other Toxicity Information", Sec. 11

Inhalation: Inhalation (LC50 Rat) : See "Other Toxicity Information", Sec. 11

Eye Contact: See "Other Toxicity Information", Sec. 11

Skin Contact: See "Other Toxicity Information", Sec. 11

Skin Sensitization: Not Available

Page 4 of 7 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011

Chemical Name NTP/IARC/OSHA Carcinogen Paraffin Wax No Oat Flour No 3-[3-(4'-bromo[1,1'-biphenyl]-4-yl)-1,2,3,4- No tetrahydro-1-naphthalenyl]-4-hydroxy-2H-1- benzopyran-2-one

Other Toxicity Information Systemically toxic concentrations of this product will probably not be absorbed through human skin. Because this product is a wax block, inhalation is not expected to be a normal route of exposure. No irritation is likely to develop following contact with human eyes. Irritation will probably not develop following contact with human skin.

Effects of overexposure are those of anticoagulant overdose, i.e., reduced blood clotting ability with spontaneous bleeding in various organs. Body accumulation can result from repeated exposures since the half-life of brodifacoum is > 100 days. Individuals with blood clotting disorders may be more susceptible to overexposure effects. Toxicity of Other Components Oat Flour In normal use this product does not present a serious health risk and ingestion has no adverse effects. Paraffin Wax Inhalation may cause eye, skin and respiratory tract irritation.

Target Organs Active Ingredients Brodifacoum Technical: Blood Inert Ingredients Oat Flour: Lung Paraffin Wax: Eye, skin, respiratory tract

12. ECOLOGICAL INFORMATION

Eco-Acute Toxicity Brodifacoum Technical: Fish (Rainbow Trout) 96-hour LC50 0.02 ppm Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.98 ppm

Page 5 of 7 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011 Bird (Mallard Duck) 21-day LD50 0.26 mg/kg

13. DISPOSAL CONSIDERATIONS

Disposal: Do not reuse empty container except for holding additional product. Characteristic Waste: Not Applicable Listed Waste: Not Applicable

14. TRANSPORT INFORMATION

DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Not regulated.

Air Transport Not regulated.

15. REGULATORY INFORMATION

Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: Caution: Harmful if swallowed or absorbed through the skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing.

EPA Registration Number(s): 100-1055 EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Acute Health Hazard

Section 313 Toxic Chemicals: None

CERCLA/SARA 304 Reportable Quantity (RQ): None

Page 6 of 7 Safety Data Sheet

WEATHERBLOK® XT Date: 12/9/2014 Replaces: 2/4/2011 RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA

16. OTHER INFORMATION

NFPA Hazard Ratings HMIS Hazard Ratings 0 Minimal Health: 1 Health: 1 1 Slight Flammability: 1 Flammability: 1 2 Moderate Instability: 0 Reactivity: 0 3 Serious 4 Extreme Syngenta Hazard Category: A * Chronic

For non-emergency questions about this product call:

1-800-334-9481

Original Issued Date: 9/20/2000 Revision Date: 12/9/2014 Replaces: 2/4/2011 Section(s) Revised: 1-16 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

Page 7 of 7 ZP® RODENT OAT BAIT AG™

SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA DATE OF ISSUE: PREPARED BY: Hazard Communication Standard 29 CFR 1910.1200 January 2016 CAR SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier: ZP® RODENT OAT BAIT AG™ EPA Registration Number: 12455-102 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Acute Rodenticide - Ready to use – Restricted Use Uses advised against: Use only for the purpose described above

MANUFACTURER/SUPPLIER: Bell Laboratories, Inc. 3699 Kinsman Blvd. Madison, WI 53704, USA Email: [email protected] Phone: 608-241-0202 Medical or Vet Emergency: 877-854-2494 or 952-852-4636 Spill or Transportation Emergency: 800-424-9300 (CHEMTREC) SECTION 2. HAZARDS IDENTIFICATION Classification according to Regulation OSHA 1910.1200(d): Not classified Signal Word: None See Section 15 for information on FIFRA applicable safety, health, and environmental classifications. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. % By weight Zinc Phosphide 1314-84-7 2.0% Inert and Non-Hazardous Ingredients Proprietary 98.0% (Unlisted components are non-hazardous) SECTION 4. FIRST AID MEASURES Description of first aid measures Ingestion: Call physician or emergency number immediately. Do not drink water. Do not give anything by mouth or induce vomiting unless instructed by physician. Inhalation: Move person to fresh air. If not breathing, call an ambulance, then give artificial respiration, preferably mouth to mouth, if possible. Eye contact: Hold eye open and rinse slowly with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, abdominal pain, tightness in the chest, eye irritation, or weakness. Advice to physician: There is no specific antidote. Probable mucosal damage may contradict the use of gastric lavage. Sodium bicarbonate can be given orally to neutralize the stomach acidity. The stomach and intestinal tract can be evacuated, oxygen administered and cardiac and circulatory stimulants given. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs, induce vomiting by using hydrogen peroxide. Sodium bicarbonate can be given orally to neutralize the stomach acidity. The stomach and intestinal tract can be evacuated, oxygen administered and cardiac and circulatory stimulants given.

Trade Name: ZP Rodent Oat Bait AG Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 1 of 4 SECTION 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: Dry chemical, soda ash, sand, or inert gas. Unsuitable Extinguishing Media: Avoid water or foam as they may form phosphine gas upon contact with zinc phosphide. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic or flammable gases, which may include flammable phosphine gas, oxides of phosphorus, and zinc. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus. Fight fire upwind and evacuate downwind as appropriate.

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves, long sleeve shirt, long pants, shoes, and socks should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Carefully sweep up spilled material immediately. Avoid contact with dust. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations.

SECTION 7. HANDLING AND STORAGE Precautions for safe handling: Do not handle the product near food, animal foodstuffs or drinking water. Keep out of reach of children. Do not use near heat sources, open flame, or hot surfaces. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco, or using the toilet. Conditions for safe storage, including any incompatibilities: Store only in original container in a cool, dry place, inaccessible to pets and wildlife. Do not contaminate water, food or feed by storage or disposal. Keep containers closed and away from other chemicals.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Established Limits Component OSHA ACGIH Other Limits Zinc Phosphide Not Established Not Established Not Established

Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Persons loading pellets or baits into aircraft or mechanical ground equipment and persons loading/applying with a hand-pushed or hand-held equipment, such as a push-type spreader or cyclone spreader, must wear a dust/mist filtering respiration (MSHA/NIOSH approval number prefix TC-21C or a NIOSH-approved respirator with a R, P, or HE filter). Eye protection: Protective eyewear. Skin protection: Gloves, long sleeve shirt, long pants, shoes, and socks should be worn when handling the bait. Hygiene recommendations: Keep and wash PPE separately from other laundry. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco or using the toilet, and change into clean clothing.

Trade Name: ZP Rodent Oat Bait AG Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 2 of 4 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance/Color: Grey oat groat Odor: Garlic-like Odor Threshold: Not applicable, odor not associated with a hazardous material. pH: Not applicable, is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, does not contain components classified as flammable. Evaporation rate: Not applicable, is a solid. Flammability: Not applicable, is a solid. Upper/lower flammability or explosive limits: Not applicable, does not contain components classified as flammable or explosive. Vapor Pressure: Not applicable to rodenticide bait Vapor Density: Not applicable, is a solid Relative Density: 1.27 g/mL @ 20°C Solubility (water): Not water soluble Solubility (solvents): Not applicable to rodenticide bait Partition coefficient: n-octanol/water: Not applicable to rodenticide bait Auto-ignition temperature: Not applicable, does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, is not a liquid.

SECTION 10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0°C or above 40°C). Incompatible materials: Avoid water, acidic materials. Hazardous decomposition products: Avoid exposure to acidic conditions, light, heat, and extreme humidity. Exposure to acidic conditions may result in the liberation of flammable phosphine gas. Oxides of zinc and phosphide. SECTION 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >2000 mg/kg (rats) (Zinc phosphide Rat LD50 oral: 21.0 mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Zinc phosphide rabbit LD50 dermal: 2000 - 5000 mg/kg bw). LC50, inhalation: Product is an oat groat and therefore exposure by inhalation is not relevant. Skin corrosion/irritation : Not irritating to skin. Serious eye damage/Irritation: Slight eye irritation potential Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Contains no components known to have a mutagenetic effect. Carcinogenicity: Contains no components known to have a carcinogenetic effect. Components NTP IARC OSHA Zinc Phosphide Not listed Not listed Not listed Reproductive Toxicity: No data Aspiration Hazard: Not applicable. Product is an oat groat. Target Organ Effects: None SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Product is inherently biodegradable. Zinc phosphide rapidly decomposes in water. Bioaccumulative potential: Not determined. Zinc phosphide water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined. Mobility of zinc phosphide in soil is considered to be limited. Other adverse effects: None.

Trade Name: ZP Rodent Oat Bait AG Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 3 of 4 SECTION 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store only in original container in a cool, dry place inaccessible to children and pets. Keep containers closed and away from other chemicals. Pesticide Disposal: Wastes resulting from the use of this product may be placed in trash or delivered to an approved waste disposal facility. Container Handling: Non-refillable container. Do not reuse or refill this container. [Plastic:] Offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill; or by incineration. In most states, burning is not allowed. [Paper:] Dispose of empty container by placing in trash, at an approved waste disposal facility or by incineration. In most states, burning is not allowed. SECTION 14. TRANSPORT INFORMATION UN number: Not regulated UN proper shipping name: Not regulated Transport hazard class(es): Not regulated Packing group : Not regulated Environmental Hazards DOT Road/Rail: Not considered hazardous for transportation via road/rail. DOT Maritime: Not considered hazardous for transportation by vessel. DOT Air: Not considered hazardous for transportation by air. Freight Classification: LTL Class 60 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable Special precautions for user: None SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains phosphine producing active ingredient, zinc phosphide. Harmful if swallowed or inhaled. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed

TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed SECTION 16. OTHER INFORMATION For additional information, please contact the manufacturer noted in Section 1.

NFPA Health: 2 (caution) Flammability: 1 (slight) Reactivity: 0 (stable) Specific Hazard: None HMIS Health: 2 (moderate) Flammability: 1 (slight) Reactivity: 0 (minimal) Protective Equipment: B

Disclaimer: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Bell Laboratories, Inc. provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. The user is responsible to ensure that they have all current data, including the approved product label, relevant to their particular use.

Trade Name: ZP Rodent Oat Bait AG Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 4 of 4 ZP® TRACKING POWDER

SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA DATE OF ISSUE: PREPARED BY: Hazard Communication Standard 29 CFR 1910.1200 January 2015 CAR SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier: ZP® TRACKING POWDER EPA Registration Number: 12455-16 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Acute Rodenticide - Ready to use – Restricted Use Uses advised against: Use only for the purpose described above MANUFACTURER/SUPPLIER: Bell Laboratories, Inc. 3699 Kinsman Blvd. Madison, WI 53704, USA Email: [email protected] Phone: 608-241-0202 Medical or Vet Emergency: 877-854-2494 or 952-852-4636 Spill or Transportation Emergency: 800-424-9300 (CHEMTREC) SECTION 2. HAZARDS IDENTIFICATION Classification according to Regulation OSHA 1910.1200(d):

Signal Word/Pictogram: DANGER. Hazard Statement: Toxic if swallowed

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. % By weight Zinc Phosphide 1314-84-7 10.0% Inert and Non-Hazardous Ingredients Proprietary 90.0% (Unlisted components are non-hazardous) SECTION 4. FIRST AID MEASURES Description of first aid measures Ingestion: Call physician or emergency number immediately. Do not drink water. Do not give anything by mouth or induce vomiting unless instructed by physician. Inhalation: Move person to fresh air. If not breathing, call an ambulance, then give artificial respiration, preferably mouth to mouth, if possible. Eye contact: Hold eye open and rinse slowly with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, abdominal pain, tightness in the chest, eye irritation, or weakness. Advice to physician: There is no specific antidote. Probable mucosal damage may contradict the use of gastric lavage. Sodium bicarbonate can be given orally to neutralize the stomach acidity. The stomach and intestinal tract can be evacuated, oxygen administered and cardiac and circulatory stimulants given. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs, induce vomiting by using hydrogen peroxide. Sodium bicarbonate can be given orally to neutralize the stomach acidity. The stomach and intestinal tract can be evacuated, oxygen administered and cardiac and circulatory stimulants given.

Trade Name: ZP Tracking Powder Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 1 of 4 SECTION 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: Dry chemical, soda ash, sand, or inert gas. Unsuitable Extinguishing Media: Avoid water or foam as they may form phosphine gas upon contact with zinc phosphide. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic or flammable gases, which may include flammable phosphine gas, oxides of phosphorus, and zinc. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus. Fight fire upwind and evacuate downwind as appropriate.

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Water-proof gloves, long sleeve shirt, long pants, chemical resistant shoes, and socks should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Carefully sweep up spilled material immediately. Avoid contact with dust. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Established Limits Component OSHA ACGIH Other Limits Zinc Phosphide Not Established Not Established Not Established

Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Persons handling this product must wear a dust/mist filtering respiration (MSHA/NIOSH approval number prefix TC-21C or a NIOSH-approved respirator with a R, P, or HE filter). Eye protection: Protective eyewear. Skin protection: Water-proof gloves, long sleeve shirt, long pants, chemical resistant shoes, and socks should be worn when handling the bait. Hygiene recommendations: Keep and wash PPE separately from other laundry. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco or using the toilet, and change into clean clothing.

Trade Name: ZP Tracking Powder Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 2 of 4 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance/Color: Grey powder Odor: Garlic-like Odor Threshold: Not applicable, odor not associated with a hazardous material. pH: Not applicable, is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, does not contain components classified as flammable. Evaporation rate: Not applicable, is a solid. Flammability: Not applicable, is a solid. Upper/lower flammability or explosive limits: Not applicable, does not contain components classified as flammable or explosive. Vapor Pressure: Not applicable to rodenticide bait Vapor Density: Not applicable, is a solid Relative Density: 1.60 g/mL @ 20°C Solubility (water): Not water soluble Solubility (solvents): Not applicable to rodenticide bait Partition coefficient: n-octanol/water: Not applicable to rodenticide bait Auto-ignition temperature: Not applicable, does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, is not a liquid.

SECTION 10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0°C or above 40°C). Incompatible materials: Avoid water, acidic materials. Hazardous decomposition products: Avoid exposure to acidic conditions, light, heat, and extreme humidity. Exposure to acidic conditions may result in the liberation of flammable phosphine gas. Oxides of zinc and phosphide. SECTION 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): 275 mg/kg (rats) (Zinc phosphide Rat LD50 oral: 21.0 mg/kg bw). LD50, dermal (skin contact): > 2000 mg/kg (rats) (Zinc phosphide rabbit LD50 dermal: 2000 - 5000 mg/kg bw). LC50, inhalation: 19.6 mg/L (rats) (Zinc phosphide Rat LD50 inhalation: not <0.05 mg/L) Skin corrosion/irritation : May cause skin burns. Serious eye damage/Irritation: Slight eye irritation potential Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Contains no components known to have a mutagenetic effect. Carcinogenicity: Contains no components known to have a carcinogenetic effect. Components NTP IARC OSHA Zinc Phosphide Not listed Not listed Not listed Reproductive Toxicity: No data Aspiration Hazard: Avoid breathing dust. Harmful if inhaled. Target Organ Effects: None SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Product is inherently biodegradable. Zinc phosphide rapidly decomposes in water. Bioaccumulative potential: Not determined. Zinc phosphide water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined. Mobility of zinc phosphide in soil is considered to be limited. Other adverse effects: None.

Trade Name: ZP Tracking Powder Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 3 of 4 SECTION 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store only in original container in a cool, dry place inaccessible to children and pets. Keep containers closed and away from other chemicals. Pesticide Disposal: Wastes resulting from the use of this product may be placed in trash or delivered to an approved waste disposal facility. Container Handling: Non-refillable container. Do not reuse or refill this container. [Plastic:] Offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill; or by incineration. In most states, burning is not allowed. [Paper:] Dispose of empty container by placing in trash, at an approved waste disposal facility or by incineration. In most states, burning is not allowed. SECTION 14. TRANSPORT INFORMATION UN number: Not regulated UN proper shipping name: Not regulated Transport hazard class(es): Not regulated Packing group : Not regulated Environmental Hazards DOT Road/Rail: Not considered hazardous for transportation via road/rail. DOT Maritime: Not considered hazardous for transportation by vessel. DOT Air: Not considered hazardous for transportation by air. Freight Classification: LTL Class 60 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable Special precautions for user: None SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use.

Signal Word/Pictogram: DANGER. Precautionary Statements: Contains phosphine producing active ingredient, zinc phosphide. Fatal if swallowed or absorbed through the skin. Causes skin burns. Harmful if inhaled. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin. Fatal if absorbed through the skin. Inhalation: Avoid breathing dust Ingestion: Fatal if swallowed

NFPA Health: 2 (caution) Flammability: 1 (slight) Reactivity: 0 (stable) Specific Hazard: None HMIS Health: 2 (moderate) Flammability: 1 (slight) Reactivity: 0 (minimal) Protective Equipment: E

Trade Name: ZP Tracking Powder Date Created: January 2016 Supplier: Bell Laboratories, Inc. Page 4 of 4