A Look Back at Ernest Solvay
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History of the Chlor-Alkali Industry
2 History of the Chlor-Alkali Industry During the last half of the 19th century, chlorine, used almost exclusively in the textile and paper industry, was made [1] by reacting manganese dioxide with hydrochloric acid 100–110◦C MnO2 + 4HCl −−−−−−→ MnCl2 + Cl2 + 2H2O (1) Recycling of manganese improved the overall process economics, and the process became known as the Weldon process [2]. In the 1860s, the Deacon process, which generated chlorine by direct catalytic oxidation of hydrochloric acid with air according to Eq. (2) was developed [3]. ◦ 450–460 C;CuCl2 cat. 4HCl + O2(air) −−−−−−−−−−−−−−→ 2Cl2 + 2H2O(2) The HCl required for reactions (1) and (2) was available from the manufacture of soda ash by the LeBlanc process [4,5]. H2SO4 + 2NaCl → Na2SO4 + 2HCl (3) Na2SO4 + CaCO3 + 2C → Na2CO3 + CaS + 2CO2 (4) Utilization of HCl from reaction (3) eliminated the major water and air pollution problems of the LeBlanc process and allowed the generation of chlorine. By 1900, the Weldon and Deacon processes generated enough chlorine for the production of about 150,000 tons per year of bleaching powder in England alone [6]. An important discovery during this period was the fact that steel is immune to attack by dry chlorine [7]. This permitted the first commercial production and distribu- tion of dry liquid chlorine by Badische Anilin-und-Soda Fabrik (BASF) of Germany in 1888 [8,9]. This technology, using H2SO4 for drying followed by compression of the gas and condensation by cooling, is much the same as is currently practiced. 17 “chap02” — 2005/5/2 — 09Brie:49 — page 17 — #1 18 CHAPTER 2 In the latter part of the 19th century, the Solvay process for caustic soda began to replace the LeBlanc process. -
Solvay Process Company and a Portion of the Village of Solvay Which Grew up Company to Use Their Process
:«:..' :•' Telephone 2-3111 Telephone 2-3111 SYRACUSE JOTJRNAIi Saturday, July 28, 193C Page 8 - SOLVAY PROCESS AMONG STATE'S MIGHTIEST PLANTS MUM) NIK BURNS BRIGHTLY AIRVIEW OF THE SOLVAY PROCESS PLANT WHICH GREW FROM WILLIAM COGSWELL'S IDEA N HISTORY OF VAST IRKS j (This is the fifth of a series of articles whhb willjg <«.»r weklv in the Saturday edition of The Syracuse • ^ourZ^topermitSyracusaJto become iamiliar with the journal, to P"™;*' industrial and commercial enter- inside story of the great industrial a™ * develoo- \ prises which have played important parts in the develop lent of the city.) _ By BICHAKD B. WELCH. Bountiful Nature which supplied Syracuse with huge qnan- Itie* of salt and limestone coupled with the lewdness 0£ a Central New Yorker who saw the l-kto»tta.-* •btainahle raw materials gave Syracuse the.S*j'««- r^™*™™ ATIP of the largest heavy industries in the state. C°T^»M£nk of the history of the Solvay Process r™J»,»T« * subsidiary of the Allied Chemical and Dye Corp- STCE* tSTo William Browne Cog^eUmw, brain tie idea' of utilizing the resources of this section first KenXhdcredit for the formation and progress' »* tfe ^|My industry must also go to Bow and1 Hazard first P^nt tfthe company, and his son, Frederick B. Hazard, who succeeded him. SH; names which burn brightly in the industrial history 01 SMrCCog^ell was born in Oswego, Sept 22,1834 of a lixie- ,ge which dated back to Sir John Cogswell in If5- He was educated in Hamilton Academy at Oneida and in private schools of Syracuse. -
Listening to Black Holes
Issue 03 Feb 2017 REDISCOVERING SCHOOL SCIENCE Page 4 LISTENING TO BLACK HOLES A publication from Azim Premji University i wonder No. 134, Doddakannelli Next to Wipro Corporate Office Sarjapur Road, Bangalore - 560 035. India Tel: +91 80 6614 9000/01/02 Fax: +91 806614 4903 www.azimpremjifoundation.org Also visit Azim Premji University website at www.azimpremjiuniversity.edu.in A soft copy of this issue can be downloaded from www.http://azimpremjiuniversity.edu.in/SitePages/resources-iwonder.aspx Editors Ramgopal (RamG) Vallath Chitra Ravi Editorial Committee REDISCOVERING SCHOOL SCIENCE Anand Narayanan Chandrika Muralidhar Geetha Iyer Hridaykant Dewan Editor’s Desk Jayalekshmy Ayyer Julfikar Ali Propelled by science, humanity is at the cusp of becoming a spacefaring Radha Gopalan civilisation, with ‘eyes’ firmly set on distant stars and feet taking the first Rajaram Nityananda baby steps towards other planets in the Solar system. At this juncture, it Reeteka Sud is important to remember that science education can no longer be limited Richard Fernandes to telling students a plethora of facts, as if they are a given. Rather, the role of science education, as emphasized in the article Why Science Saurav Shome Matters, is to enable children understand and appreciate the scientific Sushil Joshi process that has led to the most plausible hypotheses being proven with Yasmin Jayathirtha hard data and then being presented as theories. It is also about Advisors encouraging children to make use of this process, not only in scientific Falguni Sarangi quests, but also in their day-to-day life. Effective science teachers can convey the beauty of this process and share the wonder it brings with Manoj P their students. -
Salt In, Salt Out
chapter 2 Salt In, Salt Out Following their organizational meeting in November 1917, Yongli’s promoters began work on two Herculean tasks: searching for a plant design while raising the needed capital. In the process, problems of technology transfer, shifting government policy, and limitations of China’s capital market plagued them. Yongli’s challenge of Brunner, Mond’s formidable hold on the “well regulated” market and technology was both risky and difficult, which in turn made the task of raising the necessary capital even more daunting as it battled the Rev- enue Inspectorate over the gabelle waiver. Problems of Technology Transfer As Chen Diaofu and his colleagues demonstrated in Fan Xudong’s backyard, the chemistry behind the Solvay process was a public good. However, the engineering to make it work on an industrial scale was not.1 Sodium chloride (salt), one of the three main raw materials for the process, must be purified as a solution cleared of dirt, magnesium, and other impurities. The other essential chemical, ammonia, could be generated through burning coke, or added in liquid form. Reaction is then carried out by passing the concentrated and purified brine through the first of two absorption towers. Ammonia bubbles up to saturate the brine (NaCl + NH3, Step I). Separately, carbon dioxide is produced by heating limestone in a kiln at 950–1100°C. The calcium carbonate (CaCO3) in the limestone, the third main ingredient, is partially converted to quicklime (calcium oxide, CaO) and carbon dioxide: CaCO 3 → CO 2 + CaO ( Step II) The carbon dioxide and ammoniacal brine are then fed into a second tower for carbonation. -
OCCASION This Publication Has Been Made Available to the Public on The
OCCASION This publication has been made available to the public on the occasion of the 50th anniversary of the United Nations Industrial Development Organisation. DISCLAIMER This document has been produced without formal United Nations editing. The designations employed and the presentation of the material in this document do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations Industrial Development Organization (UNIDO) concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries, or its economic system or degree of development. Designations such as “developed”, “industrialized” and “developing” are intended for statistical convenience and do not necessarily express a judgment about the stage reached by a particular country or area in the development process. Mention of firm names or commercial products does not constitute an endorsement by UNIDO. FAIR USE POLICY Any part of this publication may be quoted and referenced for educational and research purposes without additional permission from UNIDO. However, those who make use of quoting and referencing this publication are requested to follow the Fair Use Policy of giving due credit to UNIDO. CONTACT Please contact [email protected] for further information concerning UNIDO publications. For more information about UNIDO, please visit us at www.unido.org UNITED NATIONS INDUSTRIAL DEVELOPMENT ORGANIZATION Vienna International Centre, P.O. Box 300, 1400 Vienna, Austria Tel: (+43-1) 26026-0 · www.unido.org · [email protected] k r i RESTRICTED MARKET STUDY F J <"* FOR SEA CHEMICALS PROJECT I N ICELAND PREPARED FOR NATIONAL RESEARCH COUNCIL REYKJAVIK, ICELAND BY WILLIAM B. -
International the News Magazine of IUPAC
CHEMISTRY International The News Magazine of IUPAC November-December 2013 Volume 35 No. 6 A Look Back at Ernest Solvay InChI, the Chemical Identifier INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY Suffixes and the Naming of Elements From the Editor A Heartfelt Congratulations to OPCW CHEMISTRY International n 11 October 2013, the Norwegian Nobel Committee announced that The News Magazine of the International Union of Pure and Othis year’s Nobel Peace Prize will be awarded to the Organization for Applied Chemistry (IUPAC) the Prohibition of Chemical Weapons (OPCW) for its extensive efforts to eliminate chemical weapons. www.iupac.org/publications/ci This is a great and important recognition for an organization that works so diligently to make the world a safer place. I am humbled to Managing Editor: Fabienne Meyers relay IUPAC’s heartfelt congratulations to our Production Editor: Chris Brouwer OPCW colleagues for this fantastic and well- Design: pubsimple deserved recognition for their tireless work to free the world of chemical weapons. All correspondence to be addressed to: In recent years, IUPAC has been privileged Fabienne Meyers to work with OPCW, both in contributing IUPAC, c/o Department of Chemistry technical expertise to the review conferences Boston University of the Chemical Weapons Convention (CWC) Metcalf Center for Science and Engineering and in developing educational resources on the multiple uses of chemi- 590 Commonwealth Ave. cals. As recently as the July-Aug 2013 issue of Chemistry International, Boston, MA 02215, USA Leiv K. Sydnes contributed a feature outlining IUPAC’s involvement with OPCW over the last 12 years. That feature was triggered by the recent E-mail: [email protected] IUPAC Technical Report (in the April 2013 Pure and Applied Chemistry) Phone: +1 617 358 0410 titled “Impact of Scientific Developments on the Chemical Weapons Fax: +1 617 353 6466 Convention,” released in advance of the Third Review Conference of the CWC held last April. -
2015 Annual Report PROFILE
ASKING MORE 2015 Annual Report PROFILE SUSTAINABLE VALUE CREATION Our strategy is a virtuous circle in which positive actions interact to create enriching contributions centered around a single goal: creating a future with more potential. MORE talent BY ACTING RESPONSIBLY BY INNOVATING Asking from chemistry MORE MORE innovative commitment sustainable solutions BY CONTRIBUTING TO SOCIETY € 12.4 bn 30,900 145 NET SALES EMPLOYEES INDUSTRIAL SITES AND A PRESENCE IN 53 COUNTRIES Who we are An international chemical and advanced materials company, Solvay assists its customers in innovating, developing, and delivering high-value, sustainable products and solutions that consume less energy and reduce CO2 emissions, optimize the use of resources and improve the quality of life. Solvay serves diversified global end markets including automotive and aerospace, consumer goods and healthcare, energy and environment, electricity and electronics, building and construction, as well as industrial applications. Solvay is headquartered in Brussels with about 30,000 employees spread across 53 countries. It generated pro forma net sales of €12.4 bn in 2015, with 90% made from activities where it ranks among the world’s top 3 players. Solvay SA (SOLB.BE) is listed on Euronext in Brussels and Paris (Bloomberg: SOLB.BB – Reuters: SOLB.BR). SOLVAY 2015 ANNUAL REPORT Asking from chemistry The 2015 Solvay Annual Report takes you inside our journey of transformation. We’re implementing an ambitious strategy to build a new model of sustainable chemistry that addresses the environmental and societal factors impacting our world. The challenge we have set ourselves is to achieve these strategic targets while continuing to drive value creation and profitable growth in a responsible way. -
Translations Whatever Happened to Homberg's
9 h plt prr nldn lt f ttnd vn dtr nrl f lbrr rrh t nrvl th tr n Wrdr "rdn f th Cnr n Chtr ld n h rlt hh t ntrtn ppr th Ch Illn At 1 t 193" . A. Ch. S., 193 Whatever Happened To ... ? ln , 35 (n nbr d Otbr 1h ppr r ttrd thrht . A. Ch. S. fr WHATEVER HAPPENED TO HOMBERG'S 193 nd 19 bt r prl dntfd hvn rntd t th PYROPHORUS? Cnr 11 W Clr t l "Intrntnl Chl Cnr" . William B. Jensen, University of Cincinnati A. Ch. S., 19 6, 880. 1h nl ntn f th rl tn b th St "br rphr" dntll dvrd b rrd n th prlnr nnnnt fr th nd Intrntnl Wlhl br (15-1715 t rnd 1 hl Cnr f Appld Chtr hld n r n 19; Ann . ttptn t extract n "drl ht l" fr hn A. Ch. S., 19 , 37 xrnt fr th prp f trntn rr nt lvr (1 In th r f th xprnt br dtlld th xrnt th d vrt f thr trl n f James J. Bohning is Professor of Chemistry at Wilkes College, hh hppnd t b n pth r pt l Wilkes-Barre, PA 18766 and is particularly interested in the [K2(SO4Al2(SO4321 nd ntd tht ftr ln th history of the ACS. He is a Past-Chair of the Division and is pprt nd brn pn th ltn th dr rd n th currently serving as its historian. rtrt pntnl brt nt fl h rlt t ntrll ht br ttntn n f h bdn fntn l tht f n f h ntprr th th prprtn nd td f tr- TRANSLATIONS l hh r thr pntnl nflbl r phph- rnt r bth Indd drn h tdnt trvl n Itl h The following experiment is taken from Tiberius Cavallo' s "A hd nvttd th prprtn nd prprt f th -lld Treatise on the Nature and Properties of Air," London, 1781. -
027402A0.Pdf
402 NATURE [Feb. 22, 1883 x88o they produced x8,8oo tom, and their output is now at the and at the same time will ccnfer an inestimable boon on the towns rate of 52,000 tons per annum. The new works no•v in course where coal is now largely used as fuel. of construction in this country and on the Continent, when com These three couroes, says Mr. Weldon, must be all adopted by pleted, will at once increase the production of ammonia soda by the English soda-maker. If, in addition to doing thi•, the 65,exx> to 7o,ooo tons annually. strictest economy in manufacture is practised and the purest and What then can the manufacturer of Leblanc soda expect save best product that can be made is always turned out, the manu· utter collapse? But the state of the alkali-maker threatens to facturer of soda by the old Leblanc method may yet hope to become even worse than it is. The source of the sulphur which hold his own against the new and wonderfully successful is used in the Leblanc process is pyrites ; the pyrites employed ammonia proce>s. M. M. P. M. in this country is almost exclusively imported by three large companies from Spain and Portugal ; it contains from 2 to 3 per cent. of copper, and very small quantities of silver and gold. UNIVERSITY AND EDUCATIONAL When the soda manufacturer has burnt off the sulphur, he >ends INTELLIGENCE the residual ore to the -copper extractor, who is able to sell the OxFORD.-The following persons have been elected Members iron oxide which remains when he has taken out the copper at of the Committee for the nomination of examiners in the Natural ab::mt 12s. -
Branding Brussels Musically: Cosmopolitanism and Nationalism in the Interwar Years
BRANDING BRUSSELS MUSICALLY: COSMOPOLITANISM AND NATIONALISM IN THE INTERWAR YEARS Catherine A. Hughes A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Music. Chapel Hill 2015 Approved by: Annegret Fauser Mark Evan Bonds Valérie Dufour John L. Nádas Chérie Rivers Ndaliko © 2015 Catherine A. Hughes ALL RIGHTS RESERVED ii ABSTRACT Catherine A. Hughes: Branding Brussels Musically: Cosmopolitanism and Nationalism in the Interwar Years (Under the direction of Annegret Fauser) In Belgium, constructions of musical life in Brussels between the World Wars varied widely: some viewed the city as a major musical center, and others framed the city as a peripheral space to its larger neighbors. Both views, however, based the city’s identity on an intense interest in new foreign music, with works by Belgian composers taking a secondary importance. This modern and cosmopolitan concept of cultural achievement offered an alternative to the more traditional model of national identity as being built solely on creations by native artists sharing local traditions. Such a model eluded a country with competing ethnic groups: the Francophone Walloons in the south and the Flemish in the north. Openness to a wide variety of music became a hallmark of the capital’s cultural identity. As a result, the forces of Belgian cultural identity, patriotism, internationalism, interest in foreign culture, and conflicting views of modern music complicated the construction of Belgian cultural identity through music. By focusing on the work of the four central people in the network of organizers, patrons, and performers that sustained the art music culture in the Belgian capital, this dissertation challenges assumptions about construction of musical culture. -
Fugitive Emissions)
AEAT/R/ENV/1000 Issue 1 Appendix 3 Energy (Fugitive Emissions) CONTENTS 1 INTRODUCTION 2 2 COAL MINING 2 3 SOLID FUEL TRANSFORMATION 3 3.1 Coke Production 3 3.2 Solid Smokeless Fuel Production 4 4 OIL AND NATURAL GAS 5 4.1 Offshore Flaring 6 4.2 Offshore Gas Use 7 4.3 Well Testing 8 4.4 Other Emissions from Platforms and Terminals 9 4.5 Loading Emissions 9 4.6 Leakage from the Gas Transmission System. 10 4.7 Petrol Distribution 11 4.8 Refineries and Petroleum Processes 11 4.9 Gasification Processes 12 5 REFERENCES 13 AEA Technology A3.1 AEAT/R/ENV/1000 Issue 1 1 Introduction This Appendix outlines the emissions of greenhouse gases arising from the production, extraction of coal, oil and natural gas; their storage, processing and distribution. These emissions are fugitive emissions and are reported in IPCC Table 1B. Emissions from fuel combustion during these processes are reported in IPCC Table 1A and are described in Appendix 2. In certain cases the methodology of some of these fuel combustion emissions are discussed in this Appendix, because they have links with the methodologies used for fugitive emissions. 2 Coal Mining The NAEI reports emissions of methane from coal mining in the categories deep mined coal; coal storage and transport; open cast coal. These map onto the IPCC categories 1B1ai Underground Mines-mining, 1B1ai Underground Mines-post-mining and 1B1aii Surface Mines respectively. Emissions are calculated from saleable coal production statistics reported in DTI, (2001). Data on the shallower licensed mines are not published and were supplied to us by Barty (1995) up to 1994. -
Herman Frasch (German Immigrant Chemist, Standard Oil, Petroleum; Ohio, Louisiana)
Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1984 Herman Frasch (German Immigrant Chemist, Standard Oil, Petroleum; Ohio, Louisiana). William Ralph Sutton Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Sutton, William Ralph, "Herman Frasch (German Immigrant Chemist, Standard Oil, Petroleum; Ohio, Louisiana)." (1984). LSU Historical Dissertations and Theses. 3971. https://digitalcommons.lsu.edu/gradschool_disstheses/3971 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. INFORMATION TO USERS This reproduction was made from a copy of a document sent to us for microfilming. While the most advanced technology has been used to photograph and reproduce this document, the quality of the reproduction is heavily dependent upon the quality of the material submitted. The following explanation of techniques is provided to help clarify markings or notations which may appear on this reproduction. 1.The sign or “target” for pages apparently lacking from the document photographed is “Missing Page(s)”. If it was possible to obtain the missing page(s) or section, they are spliced into the film along with adjacent pages. This may have necessitated cutting through an image and duplicating adjacent pages to assure complete continuity. 2. When an image on the film is obliterated with a round black mark, it is an indication of either blurred copy because of movement during exposure, duplicate copy, or copyrighted materials that should not have been filmed.