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Schedule 1 — Authorised Explosives [Cl
Schedule 1 — Authorised explosives [cl. 3] UN number Specified explosives of UN classification 1.1A (0129) Lead Azide (0130) Lead Styphnate (0135) Mercury Fulminate (0114) Tetrazene UN number Specified explosives of UN classification 1.1B (0029) Anoline Delay Detonators (ICI) (0029) Austin Delay Primer Delays (0225) Boosters, with Detonator (0029) Capped (Detonator) safety fuse (0360) Capped Fuse Delay Assembly (ICI) (0360) CXA MS Connectors (TES) (0030) Carrick Short Delay Detonators (ICI) (0030) Coal Mine Delay Detonators (Du Pont) (0360) Cordline Delay Detonators (ICI) (0030) Delay Detonators (0029) Detaline MS in the hole Delays (Du Pont) (0029) Detaline MS Surface Delays (Du Pont) (0029) Detaline Starter (Du Pont) (0029) Detonating Relays (0029) Detonators (0030) Du Pont Acudet Mark V Detonators (0360) Du Pont Detaslide (0030) Du Pont SSS Seismic Detonators (0030) Electric Delay Detonators (ERT) (0030) Electric Detonators (0030) Electric Instantaneous II Detonators (ICI) (0030) Electric Super SP (DWL) (0030) Electric Super Seismicdet (DNAP) (0360) Etinel Non Electric Detonators (ERT) (0360) Exel Bunchdet Detonators (ICI) (0360) Exel Connectadet Detonators (ICI) (0360) Exel Detonators (ICI) (0360) Exel Detonators (MS & LP Series) (ICI) (0360) Exel Enduredet Detonators (ICI) (0360) Exel Goldet Detonators (ICI) (0360) Exel Lead-In Line (ICI) (0360) Exel LLHD Detonators (ICI) (0360) Exel MS Connectors (ICI) (0360) Exel Trunkline Delay (ICI) (0360) Fanel Non Electrical Delay Detonators (TES) (0360) Fuse Delay Assembly (0030) High Pressure -
Hard Rock Excavation at the CSM/OCRD Test Site Using Swedish Blast Design Techniques
BMI/OCRD-4(3) Distribution Category UC-70 Hard Rock Excavation at the CSM/OCRD Test Site Using Swedish Blast Design Techniques Technical Report September 1983 Roger Holmberg of Swedish Detonic Research Foundation Consultant to Colorado School of Mines prepared for Office of Crystalline Repository Development Battelle Memorial Institute 505 King Avenue Columbus, OH 43201 The content of this report was effective as of July 1983. This report was prepared by the Department of Geological Engineering, Colorado School of Mines under Subcontract E512-04800 with Battelle Project Management Division, Office of Nuclear Waste Isolation and Office of Crystalline Repository Develop- ment under Contract Nos. EY-76-C-06-1830 and DE-ACO2-83CH10140 with the U.S. Department of Energy. REPRODUCED BY: U.S. Department of Commerce National Technical information SOP/1CO ,Springfield, Virginia 22161 BIBLIOGRAPHIC DATA Holmberg, Roger,1983. Hard Rock Excavation at the CSM/OCRD Test Site Using Swedish Blast Design Techniques, BMI/OCRD-4(3), prepared by Swedish Detonic Research Foundation for Colorado School of Mines for Office of Crystalline Repository Development, Battelle Memorial Institute, Columbus, OH. NOTICE This report was prepared as an account of work sponsored by an agency of the United Stati.L. Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. -
Synthetic Advances in the C‐H Activation of Rigid Scaffold Molecules
Synthesis Review Synthetic Advances in the C‐H Activation of Rigid Scaffold Molecules Nitika Grovera Mathias O. Senge*a a School of Chemistry, Trinity College Dublin, The University of Dublin, Trinity Biomedical Sciences Institute, 152–160 Pearse Street, Dublin 2, Ireland [email protected] Dedicated to Prof. Dr. Henning Hopf Received: only recall the epic endeavors involved in Eaton’s cubane Accepted: Published online: synthesis,3 Parquette’s preparation of dodecahedrane, DOI: Prinzbach’s pagodane route thereto, or Maier’s synthesis of Abstract The remarkable structural and electronic properties of rigid non‐ tetra-tert-butyltetrahedrane.4 conjugated hydrocarbons afford attractive opportunities to design molecular building blocks for both medicinal and material applications. The bridgehead positions provide the possibility to append diverse functional groups at specific angles and in specific orientations. The current review summarizes the synthetic development in CH functionalization of the three rigid scaffolds namely: (a) cubane, (b) bicyclo[1.1.1]pentane (BCP), (c) adamantane. 1 Introduction 2 Cubane 2.1 Cubane Synthesis 2.2 Cubane Functionalization 3 BCP 3.1 BCP Synthesis 3.2 BCP Functionalization 4 Adamantane 4.1 Adamantane Synthesis 4.2 Adamantane Functionalization 5 Conclusion and Outlook Key words Cubane, bicyclo[1.1.1]pentane, adamantane, rigid scaffolds, CH‐ functionalization. Figure 1 The structures of cubane, BCP and adamantane and the five platonic hydrocarbon systems. The fascinating architecture of these systems significantly 1 Introduction differs from scaffolds realized in natural compounds. Hence, they attracted considerable attention from synthetic and The practice of synthetic organic chemistry of non-natural physical organic chemists to investigate their properties and to compounds with rigid organic skeletons provides a deep establish possible uses.3,5 Significantly, over the past twenty understanding of bonding and reactivity. -
Octanitrocubane - the Most Powerful Explosive of All?
Octanitrocubane - The most powerful explosive of all? Since the invention of gunpowder in 9th in the international edition of "Angewandte century China[1] and its subsequent distribution Chemie" in Jan. 2000[6]. over Europe and Arabia, humanity has since strived for new and better forms of explosives, What finally culminated in Eaton's and especially after the military relevance of such Zhang's successful synthesis had been a long compounds became obvious. It took, however, and tedious journey: For over 10 years several centuries until notable progress was synthetic chemists had worked on adding nitrate groups to cubane, one by one, until made, aside from improving the already [5] known gunpowder: In the middle of the 19th octanitrocubane was finally created . It is no century Nitroglycerine became one of the first wonder, that the final synthesis is not only very complex, but also difficult: No less than practical explosives not derived from [5] gunpowder thanks to the ongoing 40 steps were required to get to the final product, while only yielding it in sparse advancements in science and technology [4] (mainly in chemistry).[2] Since then the quantities . diversity of explosives has steadily increased. Now only one question stays unanswered: It is no wonder, that at some point, after the Can the "real" octanitrocubane stand up to its very elementary principles of explosives had "theoretical" twin? Does it exhibit the finally been discovered, scientists started to predicted properties? Well, yes and no: theorize, which compound might be the most While it is insensitive to shock and friction as powerful of all explosives. -
Guide for the Selection of Commercial Explosives Detection Systems For
2.5.3.8 EXPRAY Field Test Kit EXPRAY is a unique, aerosol-based field test kit for the detection of what the manufacturer refers to as Group A explosives (TNT, DNT, picric acid, etc.), Group B explosives (Semtex H, RDX, PETN, NG, smokeless powder, etc.), and compounds that contain nitrates that are used in improvised explosives. Detection of explosive residue is made by observing a color change of the test paper. EXPRAY can be used in a variety of applications, and although in some aspects it does not perform as well as many of the other trace detectors discussed in this section, it costs only $250. This very low cost, coupled with simplicity and ease of use, may make it of interest to many law enforcement agencies (see the EXPRAY kit in fig. 13). The EXPRAY field kit2 is comprised of the following items: - one can of EXPRAY-1 for Group A explosives, - one can of EXPRAY-2 for Group B explosives, - one can of EXPRAY-3 for nitrate-based explosives (ANFO, black powder, and commercial and improvised explosives based on inorganic nitrates), - special test papers which prevent cross contamination. Figure 13. Photo of the EXPRAY Field Test Kit for explosives Initially, a suspected surface (of a package, a person’s clothing, etc.) is wiped with the special test paper. The paper is then sprayed with EXPRAY-1. The appearance of a dark violet-brown color indicates the presence of TNT, a blue-green color indicates the presence of DNT, and an orange color indicates the presence of other Group A explosives. -
Schedule 1 — Authorised Explosives [Cl
Schedule 1 — Authorised explosives [cl. 3] UN number Specified explosives of UN classification 1.1A (0129) Lead Azide (0130) Lead Styphnate (0135) Mercury Fulminate (0114) Tetrazene UN number Specified explosives of UN classification 1.1B (0029) Anoline Delay Detonators (ICI) (0029) Austin Delay Primer Delays (0225) Boosters, with Detonator (0029) Capped (Detonator) safety fuse (0360) Capped Fuse Delay Assembly (ICI) (0360) CXA MS Connectors (TES) (0030) Carrick Short Delay Detonators (ICI) (0030) Coal Mine Delay Detonators (Du Pont) (0360) Cordline Delay Detonators (ICI) (0030) Delay Detonators (0029) Detaline MS in the hole Delays (Du Pont) (0029) Detaline MS Surface Delays (Du Pont) (0029) Detaline Starter (Du Pont) (0029) Detonating Relays (0029) Detonators (0029) DRC Detonators (Orica) (0030) Du Pont Acudet Mark V Detonators (0360) Du Pont Detaslide (0030) Du Pont SSS Seismic Detonators (0030) Electric Delay Detonators (ERT) (0030) Electric Detonators (0030) Electric Instantaneous II Detonators (ICI) (0030) Electric Super SP (DWL) (0030) Electric Super Seismicdet (DNAP) (0360) Etinel Non Electric Detonators (ERT) (0360) Exel Bunchdet Detonators (ICI) (0360) Exel Connectadet Detonators (ICI) (0360) Exel Detonators (ICI) (0360) Exel Detonators (MS & LP Series) (ICI) (0360) Exel Enduredet Detonators (ICI) (0360) Exel Goldet Detonators (ICI) (0360) Exel Lead-In Line (ICI) (0360) Exel LLHD Detonators (ICI) (0360) Exel MS Connectors (ICI) (0360) Exel Trunkline Delay (ICI) (0360) Fanel Non Electrical Delay Detonators (TES) (0360) Fuse Delay -
Synthesis and Characterization of Metal Complexes Containing
Wayne State University Wayne State University Dissertations 1-1-2010 Synthesis And Characterization Of Metal Complexes Containing Tetrazolate, Poly(tetrazolyl)borate, And Aryl Pentazole Ligands As High Energy Density Materials Dongmei Lu Wayne State University Follow this and additional works at: http://digitalcommons.wayne.edu/oa_dissertations Part of the Inorganic Chemistry Commons Recommended Citation Lu, Dongmei, "Synthesis And Characterization Of Metal Complexes Containing Tetrazolate, Poly(tetrazolyl)borate, And Aryl Pentazole Ligands As High Energy Density Materials" (2010). Wayne State University Dissertations. Paper 68. This Open Access Dissertation is brought to you for free and open access by DigitalCommons@WayneState. It has been accepted for inclusion in Wayne State University Dissertations by an authorized administrator of DigitalCommons@WayneState. SYNTHESIS AND CHARACTERIZATION OF METAL COMPLEXES CONTAINING TETRAZOLATE, POLY(TETRAZOLYL)BORATE, AND ARYL PENTAZOLE LIGANDS AS HIGH ENERGY DENSITY MATERIALS by DONGMEI LU DISSERTATION Submitted to the Graduate School of Wayne State University, Detroit, Michigan in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY 2010 MAJOR: CHEMISTRY (Inorganic) Approved by: ______________________________ Advisor Date ______________________________ ______________________________ ______________________________ DEDICATION To my parents ii ACKNOWLEDGMENTS I would like to express my sincere gratitude to my advisor, Professor Charles H. Winter, for his guidance and support though the years at Wayne State University. I am grateful to my committee members, Professor Stephanie L. Brock, Professor Jin K. Cha, and Professor Mark Ming-Cheng Cheng, for reviewing my thesis and giving valuable comments and suggestions. I would like to thank Dr. Mary Jane Heeg for determining all the crystal structures, and Dr. Bashar Ksebati for his help with the NMR experiments. -
Explosives Detection Technologies and Equipment 2004
The author(s) shown below used Federal funds provided by the U.S. Department of Justice and prepared the following final report: Document Title: Survey of Commercially Available Explosives Detection Technologies and Equipment 2004 Author(s): Lisa Thiesan, David Hannum, Dale W. Murray, John E. Parmeter Document No.: 208861 Date Received: February 2005 Award Number: 96-MU-MU-K011 This report has not been published by the U.S. Department of Justice. To provide better customer service, NCJRS has made this Federally- funded grant final report available electronically in addition to traditional paper copies. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. Department of Justice. This document is a research report submitted to the U.S. Department of Justice. This report has not been published by the Department. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. Department of Justice. Survey of Commercially Available Explosives Detection Technologies and Equipment 2004 Written by: Lisa Theisen, Ph.D. David W. Hannum Dale W. Murray John E. Parmeter, Ph.D. For: The National Law Enforcement and Correction Technology Center, a Program of the National Institute of Justice, U.S. Department of Justice November 2004 This document is a research report submitted to the U.S. Department of Justice. This report has not been published by the Department. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. -
Chapter 3 STORAGE
Chapter 3 STORAGE GENERAL STORAGE INFORMATION Storage shall conform to part 55, Subpart K of Title 27 CFR (BATF). Exceptions to Title 27 CFR, other than more stringent regulations of local, state, or federal agencies, shall be approved by the Director of BATF (see ATF P 5400.9) dated 6/90. PERMANENT MAGAZINES Post magazines with signs reading “EXPLOSIVES-KEEP OFF.” Locate signs to minimize the possibility of a bullet traveling in the direction of the magazine if anyone shoots at the sign. Day boxes shall not be used for permanent storage. 27 CFR, SUBPART K - STORAGE 55.201 GENERAL (a) Section 842(j) of the Act and 55.29 of this part requires that the storage of explosive materials must be in accordance with regulations in this part. Further, section 846 of this Act authorizes regulations to prevent the recurrence of accidental explosions in which explosive materials were involved. The stor- age standards prescribed by this subpart confer no right or privileges to store explosive materials in a manner contrary to state or local law. 39 (b)The director may authorize alternate construction for explosives storage magazine construction that is substantially equivalent to the standards of safety and security contained in this subpart. Any alternate explosive magazine construction approved by the director prior to August 9, l982, will continue as approved unless notified in writing by the director. Any person intending to use alternate magazine construction shall submit a letter of application to the regional director (compliance) for transmittal to the director, specifically describing the proposed magazine. Explosive materials may not be stored in alternate magazines before the applicant has been notified that the application has been approved. -
Forensic Analysis of Explosives
Forensic analysis of explosives Youngeun Choi, Dario Remmler, Maximilian Ries, Felix Rösicke, Radwan Sarhan, Felix Stete, Zhiyang Zhang Detecting and identifying explosives is of great importance ●Airport and airline security ●Demining Picture: Wo st 01/Wikipedia ●Removal of unexploded ordnance Picture: MatthiasKabel/Wikipedia ●Forensic analysis Picture: Tom Oates/Wikipedia Picture: Mark A. Moore/Wikipedia Outline ● Forensic analysis ● Common explosives ■ Inorganic explosives ● examples and sample preparation ● selected analytical techniques ■ Organic explosives containing Nitro-moieties ● Principle of detection ● selected analytical techniques ■ Other important explosives Forensic analysis After an incident with an explosion: Where was the source of the explosion? Which explosive was used? Where did the explosive come from? Commonly used explosives Inorganic explosives: Explosives with containing Nitro- Others: moieties: K++ + S + C Black powder Trinitrotoluene (TNT) Triacetone triperoxide (TATP) Dust of flammable materials Ammonium nitrate Nitroglycerin (NG) Inorganic Explosives Pure compounds Type Decomposition mechanism Characteristic ions − + Ammonium nitrate 2 NH4NO3 → 4 H2O + 2 N2 + O2 NO3 , NH4 − - + Ammonium perchlorate 2 NH4ClO4 → Cl2 + 2 O2 + N2 + 4 H2O NO3 , ClO4 , NH4 Ignition needed! Inorganic Explosives Pure compounds Mixtures Type Composition Characteristic ions − + + ANFO NH4NO3, fuel oil NO3 , NH4 , MeNH3 (Ammonium nitrate fuel oil) (long chain hydrocarbons) − 2- 2− Black powder Nitrates, sulfur, charcoal NO3 , SO4 , -
Enhanced Performance from Insensitive Explosives
Calhoun: The NPS Institutional Archive Faculty and Researcher Publications Faculty and Researcher Publications Collection 2013 Enhanced performance from insensitive explosives Brown, Ronald Monterey, California. Naval Postgraduate School 2013 Insensitive Munitions and Energetic Materials Technology SymposiumPaper 16169 http://hdl.handle.net/10945/47519 Approved for Public Release ENHANCED PERFORMANCE FROM INSENSITIVE EXPLOSIVES Ronald Brown, John Gamble, Dave Amondson, Ronald Williams, Paul Murch, and Joshua Lusk Physics Department Naval Postgraduate School, Monterey, CA 93943 Contact: [email protected] 2013 Insensitive Munitions and Energetic Materials Technology Symposium Paper 16169 Approved for Public Release Acknowledgement Dr. Kevin Vandersall Lawrence Livermore National Laboratory Technical Staff ANSYS-AUTODYN Berkeley, CA 2013 Insensitive Munitions and Energetic Materials Technology Symposium Paper 16169 Approved for Public Release Projected 14 Demonstrated Levels of Increase 12 “ONC” = Octanitrocubane “N8” = Octaazacubane > - e Overview of s c a e 10 e s r / c > - Achievements n m I e k s , a y e t i Relative to 8 r c c o n l I e V n o 6 i t Explosives a n o t Chronology e D 4 2 0 TNT RDX HMX CL-20 ONC N8 IMX HPX HPX+ 2013 Insensitive Munitions and Energetic Materials Technology Symposium Paper 16169 Approved for Public Release OUTLINE • Objective • Background • Modeling & Validations • Effect of Detonation Convergence on Energy Partitioning • Coaxial Initiation Limitations • Results of Novel Dynamic Compression • Conclusions 2013 Insensitive Munitions and Energetic Materials Technology Symposium Paper 16169 Approved for Public Release Develop means for enhancing directed energy from explosive weapon systems by exploiting the effects of overdriven detonation. Explore means for overcoming the limitations of coaxial charges. -
Local Minima Then Are Used As Starting Points for the Third Step of the Procedure
LA-I142-MSI CiC-14REPO”RTCollection -- c. 3 REPRODUCTION ‘“” COPY ~ -.;,. .1.! Los Alamos Nal,onal Laboratory IS operated by the Unwersity of Cal,fornla for the Umted States Department of Energy under conlracl W.7405.ENG.36. 1 -——.Procedqre for Estima ting the Crystal SN- ,-:~.-.....—.-:”.–:,--- ~~~=m --:.”-”..... ... Densities of Organzc ~xploswes ““”P. ~-. -. .. ...- .. ‘= - - -- .- — . Los Alamos National Laboratory ~O~~l~~~~LOSA,amOSN.WM~x,Co,,,,, 9 This work was supported by the U.S. Department of Energyand the Naval Surface Weapons Center, Silver Spring, Maryland. DISCLAIMER This repon waspreparedasanaeeount of worksponsoredbyan ageneyofthe UnitedStatesGovernment. Neithcrthe UnitedStatesGovernment noranyagcney thereof,noranyoftheiremployecs, makesany warmnty,expressor implied,or assumesany legalliabilityor responsibilityfor theaccuracy, completeness, or usefulnessof any information,apparatus.product, or prmessdiselosed,or representsthat its usewould not infringeprivatelyownedrighls.Referencehereinto any specificcommercial product, process,or service bytradersame, trademark,manufacturer,or otherwise,does not necessarilyconstituteor implyits endorsemermrecommendation,or favoringby~heUnitedStatesGovemmenl or any agencythereof.The viewsandopinionsof authorsexpressedhereindo not necessarilystateor reflect!hoseof the Uni~edStates Govemmermorany ageniy thereof. LA-11142-MS UC-45 Issued: November 1987 A Procedure for Estimatingthe Crystal Densities of Organic Explosives Don T. Cromer Herman L. Ammon’ James R. Holden** . -- , “. .—.-—. ,..—,.--