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180 JournaloftheMeteorological SocietyofJapanVol 57,No.2

Properties of Type Crystals Observed in at Amundsen-Scott South Pole Station,

By Katsuhiro Kikuchi

Department of Geophysics, Hokkaido University, Sapporo

and Austin W. Hogan

Atmospheric Sciences Research Center, State University of New York at Albany, Albany, New York (Manuscript received 17 November 1977, in revised form 20 May 1978)

Abstract

The properties of diamond dust type were studied from replicas obtained during the 1975 austral summer at South Pole Station, Antarctica. The time variation of the number concentration and shapes of crystals, and the length of the c-axis, the axial ratio (c/a) and the growth mode of columnar type crystal were examined at an air tempera- ture of -35*. Columnar type crystals prevailed, but occasionally more than half the number of ice crystals were plate types, including hexagonal, scalene hexagonal, pentagonal, rhombic, trapezoidal and triangular plates. A time variation of two hour periodicity was found in the number concentration of columnar and plate type crystals. When the number con- centration of columnar type crystals decreased, the length of the c-axis of columnar type crystals also decreased. When the number concentration of columnar type crystals increased, the length of the c-axis of the crystals also increased. There was sufficient vapor to grow these ice crystals in a supersaturation layer several tens to several hundred meters above the surface. The growth mode of columnar type crystals was different from that of warm and cold region columns reported by Ono (1969). The mass growth rate was 6.0* 10-10 gr*sec-1, and was similar to that obtained in cold room experiments by Mason (1953), but less than that found in field experiments by Isono, et al. (1956). The plate type crystals prevailed occasionally at an air temperature of -35*, at which the sheath, hollow and prism (column) usually prevail. An important question arises with respect to the crystal habit with air temperature lower than -22* in the Ta-* diagram consolidated by Kobayashi (1961).

the time variations of number concentration, 1. Introduction crystal shapes, growth mode, mass growth rate Ice crystal observations carried out till the of the ice crystals. present have generally been limited to the con- The authors made ice crystal observations in ditions of ice on the ground (Itoo (1953), the austral summer season throughout a thirty Thuman and Robinson (1954), Sakurai (1968, day period in January and February, 1975 at 1969), Ohtake (1970)), and cirrus and cumulus Amundsen-Scott South Pole Station, Antarctica aloft using observation aircraft (Mossop, (Kikuchi and Hogan, 1976). On 29 January, et al. (1967, 1969), Ono (1969, 1970)). Several 1975, we experienced a of diamond of these studies were in situ and did not treat dust type ice crystals under a condition of 22* April 1979 K. Kikuchi and A. W. Flogan 181 and 46* haloes, beneath an otherwise fine blue segments under an ordinary transmitted light sky. Although the precipitation intensity varied microscope and almost all crystals found in the greatly, the precipitation continued throughout field of view of the microscope were photo- the day. Detailed observational results will be graphed. The negatives were examined in a film described, especially addressed to crystal shapes, editor. The number of crystals were counted time variations of number concentration of ice and the length and width of the columnar type crystals, growth mode and mass growth rate of crystals were measured on the projected glass these ice crystals in the free . surface. The total magnification of the micro- scope and equipment was from 100 to 200. The 2. Technique employed total number of ice crystals on each glass slide The geographical altitude of Amundsen-Scott was from several tens, to a few thousand indi- South Pole Station is 2,804 m and the mean sur- vidual crystals. face air temperature in January is approximately 3. The shapes of ice crystals - 30* . Conventional radiosonde observations are made twice (00Z, 12Z) daily at the station A surface air temperature during this observa- during the summer season. Proper circumstances tion period was from -37* to -35*; the often exist for observations of ice crystals which air temperature at the top a few tens may form by spontaneous nucleation in the free meters aloft was -34*. As expected at these atmosphere. The low temperatures and extremely temperature ranges (Kobayashi, 1961), the pre- dry air found near the surface limit the dominant shape of the ice crystals was columnar accuracy of measurement; calculation type as shown in Fig. 1(a) and (b). An average from radiosonde data often indicates that air value of the axial ratio of c- and a-axes, that is saturated with respect to ice and sometimes with (c/a), was 2.*5.5. However, as seen in these respect to liquid water is present in the 650* figures, there were many examples of a larger 550 mb layers (100*1,000m above the surface). (c/a) of 10 or more. This was also found in the The presence of these saturated layers was observations of Klinov (1960) and Shimizu verified by dry ice seeding experiments during (1963), and in experimental results by Kobayashi this observation period by the authors (Kikuchi (1965). It was also quite common to find minute and Hogan, 1976). hexagonal plate type crystals, as shown in Fig. Precipitating ice crystals were collected near 1(c). Scalene hexagonal and pentagonal shapes the station at the entrance to the helium storage as shown in Fig. 1(d), (e), (f) and (i) were more but next door of balloon launching site. This common. Sometimes a few trapezoidal, tri- but was unheated and had a compacted snow angular and rhomboidal shapes were discovered floor. This allowed examination of the collected (Fig. 1(g), (h) and (j)). crystals without significant sublimation or melting Almost all shapes described above have been during the short period between collection and reported by Klinov (1960). These observa- examination. tions verified the existence of the possible shapes A polarizing microscope was used to make of the basal faces, except for surface structures color photographs of the shapes of ice and snow in the basal faces, examined in seeding experi- crystals, and to determine the principal axis (c- ments by Yamashita (1973). Square form crys- axis) of the crystals at approximately 10 minute tals were found frequently as shown in Fig. 1(k) intervals. Simultaneously, the crystals were col- and (1); it is possible to recognize a pair of dark lected by sedimentation and replicated on 25 * parts at the upper and lower sides in these photo- 75mm glass slides coated with 0.5% Formvar graphs. These dark parts are estimated to be the solution at 5 or 20 minute intervals. The collec- (1010) and (1100) planes; that is, these crystals tion of the diamond dust type ice crystals was are a column type which are depressed vertically by an interception technique at the same time in the (0110) plane. There were other crystals intervals. This analysis is based on examination of square form without a pair of dark parts of these formvar replicas. within the population. It is very difficult to The diamond dust crystals were quite small conclude from examination of replicated ice crys- and the crystal shapes were not identifiable by tals on a glass slide that these are a type of eye. After the collected diamond dust crystals square ice crystal. had been brought back to our laboratory, the At this stage of ice crystals, there have not slides were scrutinized carefully by 1mm width been recognized an early stage of growth of 182 Journal of the Meteorological Society of Japan Vol. 57, No. 2

Fig. 1 Typical shapes of diamond dust type ice crystals. April 1979 K. Kikuchi and A. W. Hogan 183

Fig. 2 Time variations of number concentration of ice crystals and surface air temperature.

"peculiar shaped" snow crystals . of the altostratus clouds at 800 feet above the surface as the lowest layer clouds (L.L. 1 As 8), 4. Time variation of number concentration of and one tenth of the cirrus clouds at 10,000 feet ice crystals above the surface as the second layer clouds Fig. 2 shows the time variation of the number (S.L. 1 Ci 100). Hogan (1975) hypothesized that concentration of ice crystals. In this figure, the existence of cirrus bands at higher white, black and striped histograms denote the altitude, above the saturated layers, is an im- number concentration of column (Fig. 1(a) and portant factor initiating ice crystal falls. More (b)), hexagonal plate (Fig. 1(c)) and other plates, smaller ice crystals settling into the saturated including scalene hexagonal, triangular, and so layers serve to nucleate columnar ice crystals, on (residual figures in Fig. 1 except (a), (b) and which then precipitate to the surface . No direct (c)), respectively. This figure indicates that the correlation, however, between surface precipita- number concentration of ice crystals has a time tion and the existence of cirrus clouds was at- variation peaking at two hour intervals. Within tempted during this period. this time variation, there are characteristic in- 5. Time variation of the length of c-axis and the creases of column type crystal (for instance, at axial ratio (c/a) of ice crystals 10:30 and 14:40) and of plate type crystals (for instance, at 13:45 and 16:40). At the beginning of the observation period, The air temperature changed at the surface, almost all crystals were the column type as shown from -37* at the beginning to -35* at the in the first histogram of Fig. 2. The frequency end of observation. Tracing the temperature distributions of the length of c-axis and axial record, the air temperature increased gradually ratio (c/ a) of the replicas obtained of that time to - 35* and and velocity were are shown in Fig. 3. The total number of ice nearly constant at 90* and 10 knots. Under this crystals replicated on the glass slide was 1237, nearly steady condition, it is worthy of attention and the mean length of c-axis and mean (c/ a) that more than half of the number concentration was 90.3 *m and 4.9, respectively. The maximum was occupied frequently by the plate type crys- values were 220 *m and 18.5, respectively. These tals. values were clearly different from that of ice crys- An increase of the number concentration tals in supercooled fog observed by Sakurai around 15:00 may result from the appearance (1968). In his case, when the ice crystals co- of the cirrus clouds, which were reported in existed with supercooled fog droplets, the mean routine observations by the NOAA meteorologist lengths along c- and a-axes of ice crystals were in charge. At that time he reported one tenth nearly the same (approximately 60 *m), and 184 Journal of the Meteorological Society of Japan Vol. 57, No. 2

Fig. 3 Number and percentage frequencies of the length of c-axis and axial ratio (c/a).

Fig. 4 Time variation of frequency of the length of c-axis. D, M and N mean the mode and mean values of the length and total number measured.

when the supercooled fog droplets disappeared, respectively. In these figures, D, M and N the axes remained the same. In this case, the denote the mode and mean values and the sizes were smaller than that described above, measured number, respectively. As shown in approximately 20 *m. both figures, the time variations were very large. The time variations of the length of c-axis and At the 10:30, the maximum and mode lengths axial ratio (c/a) are shown in Figs. 4 and 5, were more than 200*m and more than 100*m. April 1979 K. Kikuchi and A. W. Hogan 185

Fig. 5 Time variation of frequency of the axial ratio (c/a). D, M and N mean the mode and mean values of the ratio and total number measured.

Fig. 6 Time variation of the mean length of c-axis versus axial ratio (c/a).

However, at the time of 11:30, the lengths were figures nearby the values are the observation only 120*m, and less than 40*m. The maximum time. As described previously, the values of the and mode values changed from 160 *m and c-axis and axial ratio (c/a) from 10:30 to 11:30 40*m at 13:45 to 220*m and 110*m at 14:40. were decreasing constantly, and this period cor- The same tendency was recognized at the same responded with that of the decreasing of the time in Fig. 5. number concentration of columnar type of ice Combining the informations in Figs. 4 and 5, crystals. In turn, both values increased from a new figure relating the mean c-axis and the 13:45 to 14:40, and this period inversely cor- mean axial ratio (c/a) was drawn as Fig. 6. In responded with that of the increasing of the this figure, black dots and white circles show number concentration of columnar type of ice the values at the morning and afternoon, and the crystals. 186 Journal of the Meteorological Society of Japan Vol. 57, No. 2

The gradient of mean length of c-axis versus to 600*m, and the maximum length of the a- axial ratio (c/a) was consistent in both periods, axis was approximately 90*m. It is apparent and this gradient reached the value obtained by that these size ranges are relatively too large to Sakurai (1968) on at Asahikawa, Hok- consider as early stage of crystal growth of kaido. This means that the time variation of the columnar type of ice crystals. length of a-axis was less than that of the c-axis. Fig. 7(a) and (b) show the relation between a- However, the value of axial ratio (c/a) from and c-axes of column type crystals alone, when 14:40 to 15:40 did not change. Therefore, in this the columnar type of ice crystals prevailed at period the rate of change of both lengths of the 10:30 and 14:40, as described previously in Figs. c- and a-axes was constant. Around at 17:00 2, 4, 5 and 6. In this examination, we did not neither the length of c-axis nor the value of measure the length of the crystal less than 10*m (c/a) showed any change of their values. of a- and c-axes of crystal. In small sized crys- tals, less than 10*m, the crystal shapes collected 6. Growth mode of relatively small columnar and replicated on glass slides are globular and type of ice crystals are difficult to define the c-axis. Almost all Examinations of growth mode, especially the columnar crystals were solid columns, which lengths of c- and a-axes, axial ratio (c/a), and were confirmed by simultaneous measurement of so on, of columnar type of ice crystals has been the unreplicated crystals using a polarizing micro- carried out by several workers. Kikuchi (1968) scope. The greater part of crystals were dis- treated single bullet and combination of bullet tributed and concentrated inside of sheath region type crystals, and Iwai (1973) examined needle, separated and drawn by Ono (1969). A few sheath and column type crystals. Both types of percents were distributed inside of warm and cold ice crystals examined were relatively long; in the column region at 10:30. In the case of 14:40 former case, a size range of the c-axis of bullet in Fig. 7, although more were distributed inside was from 0.1mm to 1.5mm, and in the latter, of column region, the great number were inside was from 0.1mm to more than 2.0mm. Ono the sheath region. A limit of the maximum length (1969, 1970) examined the shapes, riming proper- of the a-axis was 50*m even in the column ties and growth mode of ice crystals shorter than region, and this 50*m coincided with the boader the previous data in natural clouds. His data line between sheath and column regions which shows, in both cases of warm and cold region the length of c-axis was longer than 200*m. columns, the length of c-axis was from 200*m The 50*m length of the a-axis coincided with

Fig. 7 Relation between lengths of c- and a-axes of columnar type ice crystals when columnar type crystals prevailed in diamond dust. April 1979 K. Kikuchi and A. W. Hogan 187

Fig. 8 Relation between lengths of c- and a-axes of columnar type ice crystals when plate type crystals prevailed in diamond dust. that obtained by dry ice seeding in a supercooled fog by Isono, et al. (1956). Fig. 8(a) and (b) show the same relation of column type as Fig. 7 except that observation times when the plate type of ice crystals pre- vailed were at 13:45 and 16:40. The distributions of relation between both axes were scattered more than Fig. 7, and shifted from sheath to column region as compared with Fig. 7 in which column type crystals prevailed. The length of c-axis was shorter than that of Fig. 7, especially in the case of 16:40. 7. Time cross section of *i and air temperature During the observation period, approximately Fig. 9 Time cross section of air temperature and 10 hours, the surface air temperature changed supersaturation with respect to ice (*i) at only 2*, from -37* to -35*, as shown Amundsen-Scott South Pole Station. in Fig. 2. The crystal shapes observed were column type, relatively long columns, and plate lines) were nearly constant, and both factors had types (hexagonal plates and other plates, includ- stratified throughout the observation period from ing scalene hexagonal and triangular). Occasion- 08:00 to 18:00. Generally at the South Pole ally plate types of ice crystals were observed as Station in summer season, the surface tempera- 50 percent or more of total number of crystals; ture inversion is not exceptionally strong because for instance, at 13:45 and from 16:00 to 18:00, of the continuous sunshine. At observation time, except around 17:00. A time cross section of 12:00 on the 29th, the surface temperature inver- 4 *i (percent of supersaturation with respect to sion was only 2*; that is, the temperature of ice) and air temperature was made up (Fig. 9) the inversion top was - 34*. The top of the based on the routine radiosonde data made twice moist layer was around 550 mb, approximately a day. 1,500 m above the surface. The air was super- As seen in Fig. 9, the distribution curves of saturated with respect to ice only at 200m above air temperature (dashed lines) and *i (solid the surface. Above this height, a deep super- 188 Journal of the Meteorological Society of Japan Vol. 57, No. 2

saturation was maintained throughout the ob- spheroid (Mason, 1953) with actual values of the servation period. Therefore, almost all types of axial lengths derived from our data. The initial ice crystals grew in the temperature range from lengths of the crystals were taken as 10*m, and -37* to -34* and the ice supersaturation the axial ratio (c/a) was approximated by a range less than 40%. However, as it is said that straight relationship drawn by a solid line in Fig. radiosonde data relating to humidity measure- 7(a). A bulk density of 0.9 for the crystal was ments at lower air temperature around -40°C adopted and the effect of ventilation was ignored. sometimes have a marginal error more than The calculated result is dm/ dt = 6.0 * 10-10 gr• 20%, it should be thought that lower atmos-* sec-1. This value coincides fairly well with that phere at this time was a supersaturation with of the cold room experiments for column type respect to ice or water saturation, because the crystal carried out by Mason (1953) of 6.25*7* external shapes of ice crystals were very sharp. 10-10 gr•sec-1. It is less than that of the field Furthermore, sometimes at South Pole area, it experiments for column type crystal carried out have been confirmed the existence of water by Isono, et al. (1956) of 2~6* 10-9 gr•sec-1 saturation layer at 20 m above snow surface referred by Ono (1970). The figures on the (Kikuchi and Hogan, 1976). growth line in Fig. 7(a) are the growth time in Kobayashi (1961) made up a Ta-* diagram minutes and they are comparable to the result for snow crystal habit. He emphasized that even of Isono, et al. (1956) referred by Ono (1970). though the temperature could be decreased from The difference between both growth rates may -22* to -90* , any changes in the crystal depend on the following: in the case investigated habit was impossible and the diagram was con- by the authors, they adopted the mean values of solidated under the single-crystalline edifice (Ko- the length of the crystals, but Isono worked in bayashi, 1965, 1975). According to his opinion, the presence of supercooled fog particles of a the crystal habit at lower than the temperature several tens to 50*m in diameter. (Ta) of -22* was not plate types but prism 9. Conclusions (column) or sheath types as seen in the diagram. Therefore, there is an important difference be- Observations of diamond dust type ice crystals, tween our observation result and his Ta-* carried out at around -35* air temperature diagram, especially with respect to crystal habit. during the austral summer season at Amundsen- Recently, Gonda (1977) reported that the habit Scott South Pole Station, yield the following and the growth feature of small ice crystals of results. less than 50*m diameter depended not only on Throughout the observation period, columnar the temperature and the degree of supersatura- type of ice crystals prevailed. However, occasion- tion, but also on the diffusion coefficient of water ally more than half the number of ice crystals vapor, the thermal conductivity of the carrier were plate types, including hexagonal, scalene gas, and the size of crystals. hexagonal, pentagonal, rhombic, trapezoidal and triangular plates. Plate type crystals, larger than 8. Mass growth rate of columnar type of ice 200*m, prevailed under the conditions of air crystals temperature around - 35*. This is an important As described previously, the vertical distribu- to think the crystal habit comparing with Ta- tions of air temperature and supersaturation 4* diagram of Kobayashi (1961). Almost all throughout the observation period was linearly shapes of the scalene hexagon reported by stratified. This facilitates calculation of mass Klinov (1960) and studied by Yamashita growth rate of the columnar type of crystals (1973), were observed. No crystal of the initial based upon the diffusion of . Although stage of "peculiar shapes" reported by the authors the examination of mass growth rate has been (Kikuchi (1969, 1970, 1971), Kikuchi and Yanai done by several workers, there are only a few (1971), Kikuchi and Hogan (1976)) was recog- analyses of columnar type crystals based on field nized in these stages of diamond dust. The num- experiments until the present (Isono, et al. (1956), ber concentration of ice crystals varied cyclically, Ono (1970)). with peaks appearing at two hours intervals. Calculations have been made on the mass Coincident with the time variation, there were growth rate of columnar type ice crystals at the characteristic increases of columnar type and conditions of 650 mb, - 35* and water satura- of plate type crystals. When the number con- tion, assuming diffusional growth of a prolate centration of columnar type crystal decreased, April 1979 K. Kikuchi and A. W. Hogan 189 the length of c-axis of columnar type crystal Iwai, K., 1973: On the characteristic features of among all ice crystals decreased; consequently, snow crystals developed along c-axis. J. Meteor. the axial ratio (c/a) decreased. When the num- Soc. Japan, 51, 458-466. ber concentration of columnar type crystal in- Kikuchi, K., 1968: On snow crystals of bullet type. J. Meteor. Soc. Japan, 46, 128-132. creased, the length of c-axis of the crystal in- 1959: Unknown and peculiar -, shapes of creased. Therefore, since the column type crystal snow crystals observed at Syowa Station, Antarc- grew more in length when the number con- tica. J. Fac. Sci., Hokkaido Univ., Ser. VII, 3, centration of ice crystals increased, it was ex- 99-116. pected that there was sufficient water vapor to -, 1970: Peculiar shapes of solid precipita- grow the ice crystals in the atmosphere at the tion observed at Syowa Station, Antarctica. J. height of several tens to several hundred meters Meteor. Soc. Japan, 48, 243-249. above the surface. 1971: Peculiar shapes -,of snow crystals of The length of a-axis of almost all columnar Antarctic type observed at Hokkaido. Geophys. Bull. Hokkaido Univ., No. 25, 167-180. (in Japa- type crystals was shorter than 50*m, and this nese with English summary). result coincided with the observation result ob- and A. W. Hogan, 1976: Snow crystal tained by seeding experiments in outdoor field observations in summer season at Amundsen- by Isono, et al. (1956). The growth mode of Scott South Pole Station, Antarctica. J. Fac. Sci., columnar type crystals was fairly different from Hokkaido Univ., Ser. VII, 5, 1-20. that of warm and cold regions column obtained and K. Yanai, 1971: Observation on the by aircraft observations by Ono (1969). The shapes of snow crystals in the south pole region mass growth rate was 6.0* 10-10 gr•sec-1 and in the summer. Antarctic Record, 41, 34-41. coincided with that of the cold room experiment Kobayashi, T., 1961: The growth of snow crystals by Mason (1953). However, it was less than at low supersaturations. Phil. Mag., 6, 1363-1370. 1965: Vapour growth of ice crystal -, be- that of the field experiments by Isono, et al. tween -40 and -90*. J. Meteor. Soc. Japan, (1956). 43, 359-367. Acknowledgements 1975: -, Crystal growth of snow and ice. Oyo Butsuri (Applied Physics), 44, 1234-1248. The authors express their hearty thanks to (in Japanese with English abstract). Prof. C. Magono and Mr. T. Harimaya, Depart- Mason, B. J., 1953: The growth of ice crystals in a ment of Geophysics, Hokkaido University, for supercooled water cloud. Quart. J. Roy. Meteor. their comments through the course of this study, Soc., 79, 104-111. and to Dr. Torii, Japan Polar Research Associa- Mossop, S. C. and A. Ono, 1969: Measurements of tion, for his support and suggestions. ice crystal concentration in clouds. J. Atmos. This work was supported by NSF Grant Sci., 26, 130-137. Opp7422534; K. Kikuchi's travel to joint the -, -and K.J. Heffernan, 1967: expedition at Hickam was supported by the Studies of ice crystals in natural clouds. J. Rech. General Electric Foundation. The authors also Atmos., 3, 45-64. Ohtake, T., 1970: Studies on ice fog. Final Report. express their thanks to Messrs. R. Maestas and Geophys. Inst., Univ. of Alaska. Ken Martinson of NOAA, NWS and Dale Ono, A., 1969: The shape and riming properties of Niehaus, USN for the great assistance they pro- ice crystals in natural clouds. J. Atmos. Sci., 26, vided. 138-147. -, 1970: Growth mode of ice crystals in References natural clouds. J. Atmos. Sci., 27, 649-658. Gonda, T., 1977: The growth of small ice crystals Sakurai, K., 1968: Observation of ice crystals in in gases of high and low pressures at -30 and supercooled fog. J. Meteor. Soc. Japan, 46, 110- -44* . J. Meteor. Soc. Japan, 55, 142-146. 119. Hogan, A. W., 1975: Summer ice crystal precipita- -, 1969: Observation of supercooled fog tion at the South Pole. J. Appl. Meteor., 14, containing ice crystals. J. Meteor. Soc. Japan, 47, 246-249. 324-328. Isono, K., M. Komabayasi, Y. Yamanaka and H. Shimizu, H., 1963: "Long Prism" crystals observed Fujita, 1956: An experimental investigation of in precipitation in Antarctica. J. Meteor. Soc. the growth of ice crystals in a supercooled fog. Japan, 41, 305-307. J. Meteor. Soc. Japan, 34, 158-163. Thuman, W. C. and E. Robinson, 1954: Studies of Itoo, K., 1953: Forms of ice crystals in the air. Alaskan ice fog particles. J. Meteor., 11, 151- Papers in Meteor, and Geophys., 3, 207-216. 156. 190 Journal of the Meteorological Society of Japan Vol. 57, No. 2

Klinov, F. Ya., 1960: Voda v Atmosfere pri Nizkikh 170 pp. Temperaturakh. Izdatelstvo Akademii Nauk SSSR.

夏季 の南極点基地 で観測 された細氷 の性 質

菊 地 勝 弘 北海道大学理学部地球物理学教室

Austin W. Hogan

ニ ュ ー ヨ ー ク州 立 大 学 大 気 科 学 研 究 セ ン タ ー

1975年1月 か ら2月 に か け て,南 極 点 基 地 で 一35*の 温 度 条 件 下 で 観 測 され た 細 氷 時 の 氷 晶 の性 質,特 に氷 晶 の 空 間濃 度 の時 間 変 化,結 晶 形,角 柱 状 結 晶 の 主 軸 の 長 さや 軸 比(c/a),成 長 様 式 等 が 解 析 され た 。 こ の よ うな 温 度 条 件 下 で は,一 般 的 に は 角 柱 状 の 氷 晶 が 卓 越 す る と言 わ れ て お り,事 実 そ の 通 りで あ った が,時 に は氷 晶 の半 数 以 上 が 不 等辺 六 角 形 を 含 む,五 角 形,四 角 形,三 角 形 等 の 角 板 状 の 氷 晶が 卓 越 した 。 空 間 濃 度 に約2時 間 程 度 の変 動 が認 め られ た が,氷 晶 の空 間濃 度 が 減 少 す る と氷 晶は 短 い角 柱 状 にな り,逆 に 濃 度 が 増 加 す る と長 い角 柱 にな る こ とが わ か っ た。 こ の こ とか ら雪 面 上 わ ず か 数10~ 数100m上 空 に は 氷 晶 を 成 長 させ るに 十 分 な 水 蒸 気 が あ り,時 と し て水 飽 和 の 層 も認 め られ た。 角 柱 の 成 長 様 式 はOno(1969)に よっ て 報 告 され た 温 暖 お よび 寒 冷 領 域 の 角 柱 とは か な り異 な って い た。 一・方 成 長 速 度 は6×10-10gr・sec-1で,Mason(1953)の 低 温 室 で の実 験 の値 に近 か った が,Isono etal.(1956)一5* の 前 後 で の 野 外 実 験 の値 よ りは 小 さか った 。 角 板 状 の 氷 晶 が 成 長 した と考 え られ る温 度 の 時 間 的 空 間 的 な 変 動 の範 囲 は せ い ぜ い 一37*~ 一34*で あ り, Kobayashi (1961)のTa-*ダ イ ヤ グラ ムか ら推 定 され る 一22*以 下 の温 度 領 域 で の結 晶形 の鞘 状,中 空,無 垢 角 柱 とは 異 な って お り,結 晶 習 性 に関 して は 新 らた な問 題 点 が 提起 され た。