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Antimony Pentachloride Hazard Summary

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Antimony Pentachloride Hazard Summary Common Name: ANTIMONY PENTACHLORIDE CAS Number: 7647-18-9 DOT Number: UN 1730 (Liquid) RTK Substance number: 0143 UN 1731 (Solution) Date: February 1998 Revision: June 2004 --------------------------------------------------------------------------- --------------------------------------------------------------------------- HAZARD SUMMARY * Antimony Pentachloride can affect you when breathed in * Exposure to hazardous substances should be routinely and by passing through your skin. evaluated. This may include collecting personal and area * Antimony Pentachloride is a CORROSIVE CHEMICAL air samples. You can obtain copies of sampling results and contact can severely irritate and burn the skin and from your employer. You have a legal right to this eyes. information under OSHA 1910.1020. * Exposure to Antimony Pentachloride can irritate the * If you think you are experiencing any work-related health nose, mouth, throat and lungs causing coughing and/or problems, see a doctor trained to recognize occupational shortness of breath. diseases. Take this Fact Sheet with you. * Antimony Pentachloride can cause headaches, nausea, vomiting, abdominal pain and loss of sleep. WORKPLACE EXPOSURE LIMITS * Prolonged or repeated contact can cause ulcers or sores in The following exposure limits are recommended for Antimony the nose. and compounds (measured as Antimony): * Repeated exposure can affect the lungs and cause an abnormal chest x-ray to develop. OSHA: The legal airborne permissible exposure limit * Antimony Pentachloride may damage the kidneys, liver (PEL) is 0.5 mg/m3 averaged over an 8-hour and heart. workshift. NIOSH: The recommended airborne exposure limit is IDENTIFICATION 3 Antimony Pentachloride is a colorless to reddish-yellow, 0.5 mg/m averaged over a 10-hour workshift. oily liquid with an offensive odor. It is used in dyeing and in many organic chemical reactions. ACGIH: The recommended airborne exposure limit is 3 0.5 mg/m averaged over an 8-hour workshift. REASON FOR CITATION * The above exposure limits are for air levels only. When * Antimony Pentachloride is on the Hazardous Substance skin contact also occurs, you may be overexposed, even List because it is regulated by OSHA and cited by though air levels are less than the limits listed above. ACGIH, DOT, NIOSH, DEP, NFPA and EPA. * This chemical is on the Special Health Hazard Substance List because it is CORROSIVE. WAYS OF REDUCING EXPOSURE * Definitions are provided on page 5. * Where possible, enclose operations and use local exhaust ventilation at the site of chemical release. If local exhaust HOW TO DETERMINE IF YOU ARE BEING ventilation or enclosure is not used, respirators should be worn. EXPOSED * Wear protective work clothing. The New Jersey Right to Know Act requires most employers * Wash thoroughly immediately after exposure to Antimony to label chemicals in the workplace and requires public Pentachloride and at the end of the workshift. employers to provide their employees with information and * Post hazard and warning information in the work area. In training concerning chemical hazards and controls. The addition, as part of an ongoing education and training federal OSHA Hazard Communication Standard, 1910.1200, effort, communicate all information on the health and requires private employers to provide similar training and safety hazards of Antimony Pentachloride to potentially information to their employees. exposed workers. ANTIMONY PENTACHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all If symptoms develop or overexposure is suspected, the potential and most severe health hazards that may result from following are recommended: exposure. Duration of exposure, concentration of the substance and other factors will affect your susceptibility to any of the * Consider chest x-ray after acute overexposure. potential effects described below. * EKG. ---------------------------------------------------------------------------- * Liver and kidney function tests. - Any evaluation should include a careful history of past and HEALTH HAZARD INFORMATION present symptoms with an exam. Medical tests that look for damage already done are not a substitute for controlling Acute Health Effects exposure. The following acute (short-term) health effects may occur immediately or shortly after exposure to Antimony Request copies of your medical testing. You have a legal right Pentachloride: to this information under OSHA 1910.1020. * Contact can severely irritate and burn the skin and eyes. Mixed Exposures * Exposure to Antimony Pentachloride can irritate the nose, * Because smoking can cause heart disease, as well as lung mouth, throat and lungs causing coughing and/or shortness cancer, emphysema, and other respiratory problems, it may of breath. worsen respiratory conditions caused by chemical exposure. * Antimony Pentachloride can cause headaches, nausea, Even if you have smoked for a long time, stopping now will vomiting, abdominal pain and loss of sleep. reduce your risk of developing health problems. * Because more than light alcohol consumption can cause Chronic Health Effects liver damage, drinking alcohol can increase the liver The following chronic (long-term) health effects can occur at damage caused by Antimony Pentachloride. some time after exposure to Antimony Pentachloride and can last for months or years: WORKPLACE CONTROLS AND PRACTICES Cancer Hazard Unless a less toxic chemical can be substituted for a hazardous * According to the information presently available to the New substance, ENGINEERING CONTROLS are the most Jersey Department of Health and Senior Services, effective way of reducing exposure. The best protection is to Antimony Pentachloride has not been tested for its ability enclose operations and/or provide local exhaust ventilation at to cause cancer in animals. the site of chemical release. Isolating operations can also reduce exposure. Using respirators or protective equipment is Reproductive Hazard less effective than the controls mentioned above, but is * According to the information presently available to the New sometimes necessary. Jersey Department of Health and Senior Services, Antimony Pentachloride has not been tested for its ability In evaluating the controls present in your workplace, consider: to affect reproduction. (1) how hazardous the substance is, (2) how much of the substance is released into the workplace and (3) whether Other Long-Term Effects harmful skin or eye contact could occur. Special controls * Prolonged or repeated contact can cause ulcers or sores in should be in place for highly toxic chemicals or when the nose. significant skin, eye, or breathing exposures are possible. * Repeated exposure can affect the lungs and cause an abnormal chest x-ray to develop. In addition, the following control is recommended: * Antimony Pentachloride may damage the kidneys, liver and heart. * Where possible, automatically pump liquid Antimony Pentachloride from drums or other storage containers to MEDICAL process containers. Good WORK PRACTICES can help to reduce hazardous Medical Testing exposures. The following work practices are recommended: For those with frequent or potentially high exposure (half the PEL or greater), the following is recommended before * Workers whose clothing has been contaminated by beginning work and at regular times after that: Antimony Pentachloride should change into clean clothing promptly. * Urine test for Antimony. * Do not take contaminated work clothes home. Family members could be exposed. ANTIMONY PENTACHLORIDE page 3 of 6 * Contaminated work clothes should be laundered by * Where the potential exists for exposure over 0.5 mg/m3 (as individuals who have been informed of the hazards of Antimony), use a NIOSH approved supplied-air respirator exposure to Antimony Pentachloride. with a full facepiece operated in a pressure-demand or other * Eye wash fountains should be provided in the immediate positive-pressure mode. For increased protection use in work area for emergency use. combination with an auxiliary self-contained breathing * If there is the possibility of skin exposure, emergency apparatus operated in a pressure-demand or other positive- shower facilities should be provided. pressure mode. * On skin contact with Antimony Pentachloride, * Exposure to 50 mg/m3 (as Antimony) is immediately immediately wash or shower to remove the chemical. At dangerous to life and health. If the possibility of exposure the end of the workshift, wash any areas of the body that above 50 mg/m3 (as Antimony) exists, use a NIOSH may have contacted Antimony Pentachloride, whether or approved self-contained breathing apparatus with a full not known skin contact has occurred. facepiece operated in a pressure-demand or other positive- * Do not eat, smoke, or drink where Antimony pressure mode equipped with an emergency escape air Pentachloride is handled, processed, or stored, since the cylinder. chemical can be swallowed. Wash hands carefully before eating, drinking, smoking, or using the toilet. QUESTIONS AND ANSWERS PERSONAL PROTECTIVE EQUIPMENT Q: If I have acute health effects, will I later get chronic health effects? WORKPLACE CONTROLS ARE BETTER THAN A: Not always. Most chronic (long-term) effects result from PERSONAL PROTECTIVE EQUIPMENT. However, for repeated exposures to a chemical. some jobs (such as outside work, confined space entry, jobs done only once in a while, or jobs done while workplace Q: Can I get long-term effects without ever having short- controls are being installed),
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