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The Dependence of the Sio Bond Length on Structural Parameters in Coesite, the Silica Polymorphs, and the Clathrasils
American Mineralogist, Volume 75, pages 748-754, 1990 The dependence of the SiO bond length on structural parameters in coesite, the silica polymorphs, and the clathrasils M. B. BOISEN, JR. Department of Mathematics, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, U.S.A. G. V. GIBBS, R. T. DOWNS Department of Geological Sciences, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, U.S.A. PHILIPPE D' ARCO Laboratoire de Geologie, Ecole Normale Superieure, 75230 Paris Cedex OS, France ABSTRACT Stepwise multiple regression analyses of the apparent R(SiO) bond lengths were com- pleted for coesite and for the silica polymorphs together with the clathrasils as a function of the variables};(O), P (pressure), f,(Si), B(O), and B(Si). The analysis of 94 bond-length data recorded for coesite at a variety of pressures and temperatures indicates that all five of these variables make a significant contribution to the regression sum of squares with an R2 value of 0.84. A similar analysis of 245 R(SiO) data recorded for silica polymorphs and clathrasils indicate that only three of the variables (B(O), };(O), and P) make a signif- icant contribution to the regression with an R2 value of 0.90. The distribution of B(O) shows a wide range of values from 0.25 to 10.0 A2 with nearly 80% of the observations clustered between 0.25 and 3.0 A2 and the remaining values spread uniformly between 4.5 and 10.0 A2. A regression analysis carried out for these two populations separately indicates, for the data set with B(O) values less than three, that };(O) B(O), P, and };(Si) are all significant with an R2 value of 0.62. -
Crystalline Silica, Cristobalite (CAS No
Crystalline Silica, Quartz (CAS No. 14808-60-7) Crystalline Silica, Cristobalite (CAS No. 14464-46-1) Crystalline Silica, Tridymite (CAS No. 15468-32-3) Diatomaceous earth (CAS No. 61790-53-2) This dossier on crystalline silica, quartz, cristobalite and tridymite and diatomaceous earth presents the most critical studies pertinent to the risk assessment of these substances in their use in drilling muds and cement additives. This dossier does not represent an exhaustive or critical review of all available data. The majority of information presented in this dossier was obtained from the ECHA database that provides information on chemicals that have been registered under the EU REACH (ECHA). Where possible, study quality was evaluated using the Klimisch scoring system (Klimisch et al., 1997). For the purpose of this dossier, crystalline silica, quartz (CAS No. 14808-60-7) has been reviewed as representative of crystalline silica cristobalite and tridymite. Crystalline silica, quartz is also considered representative of diatomaceous earth, as they both consist mainly of silicon dioxide. Screening Assessment Conclusion – Crystalline silica, quartz, cristobalite and tridymite and diatomaceous earth are classified as tier 1 chemicals and require a hazard assessment only. 1 BACKGROUND Crystalline silica is a common mineral found in the earth's crust. Materials like sand, stone, concrete and mortar contain crystalline silica. It is also used to make products such as glass, pottery, ceramics, bricks and artificial stone. Silica, in the form of sand, is used as the main ingredient in sand casting for the manufacture of metallic components in engineering and other applications. The high melting point of silica enables it to be used in such applications. -
Minnesota's Mineral Resources
CHAPTER • 9 Minnesota's Mineral Resources IN MINNESOTA the production of iron ore is far more valuable economically than the total of all other mineral products, but im portant industries are based on Minnesota's other geological forma tions as well. Architectural, monumental, and structural stone are produced from granite, limestone, dolomite, and other Minnesota rocks. Gravel and sand are excavated and processed, and clay is used for many ceramic products. :Manganese in important amounts occurs in the iron ores of the Cuyuna district. Finally, although they are often not thought of as mineral products, two of our most im portant mineral resources are water and soil. The iron ores and mining operations of the Mesabi, Vermilion, and Cuyuna iron-bearing districts and of the southeastern lYlinnesota counties will be discussed in detail in later chapters, but a few sta tistics on Minnesota's iron ore industry may remind us how impor tant this geological heritage is. The following is an estimate of Min nesota's iron ore reserves, made on lYlay 1, 1961: Gross Tons Mesabi Range 500,799,179 Vermilion Range 9,755,974 Cuyuna Range 36,530,000 Fillmore County 'il,860,337 Total iron ore 549,945,490 172 MI NESOTA'S MINERAL RESOURCES The total production of iron ore in Minne ota to January 1, 1962, was 2,529,737,553 tons. Total taxes paid on iron ore to January 1, 1961 , were approximately $1,257,448,400, a very important source of funds for the state government. Slightly over 60 per cent of the total iron ore produced in the United States has come from l\1inne- ota. -
Symposium on Agate and Cryptocrystalline Quartz
Symposium on Agate and Cryptocrystalline Quartz September 10 – 13, 2005 Golden, Colorado Sponsored by Friends of Mineralogy, Colorado Chapter; Colorado School of Mines Geology Museum; and U.S. Geological Survey 2 Cover Photos {top left} Fortification agate, Hinsdale County, Colorado, collection of the Geology Museum, Colorado School of Mines. Coloration of alternating concentric bands is due to infiltration of Fe with groundwater into the porous chalcedony layers, leaving the impermeable chalcedony bands uncolored (white): ground water was introduced via the symmetric fractures, evidenced by darker brown hues along the orthogonal lines. Specimen about 4 inches across; photo Dan Kile. {lower left} Photomicrograph showing, in crossed-polarized light, a rhyolite thunder egg shell (lower left) a fibrous phase of silica, opal-CTLS (appearing as a layer of tan fibers bordering the rhyolite cavity wall), and spherulitic and radiating fibrous forms of chalcedony. Field of view approximately 4.8 mm high; photo Dan Kile. {center right} Photomicrograph of the same field of view, but with a 1 λ (first-order red) waveplate inserted to illustrate the length-fast nature of the chalcedony (yellow-orange) and the length-slow character of the opal CTLS (blue). Field of view about 4.8 mm high; photo Dan Kile. Copyright of articles and photographs is retained by authors and Friends of Mineralogy, Colorado Chapter; reproduction by electronic or other means without permission is prohibited 3 Symposium on Agate and Cryptocrystalline Quartz Program and Abstracts September 10 – 13, 2005 Editors Daniel Kile Thomas Michalski Peter Modreski Held at Green Center, Colorado School of Mines Golden, Colorado Sponsored by Friends of Mineralogy, Colorado Chapter Colorado School of Mines Geology Museum U.S. -
Stishovite and Seifertite in Lunar Meteorite Northwest Africa 4734
71st Annual Meteoritical Society Meeting (2008) 5058.pdf FIRST EVIDENCE OF HIGH PRESSURE SILICA: STISHOVITE AND SEIFERTITE IN LUNAR METEORITE NORTHWEST AFRICA 4734. H. Chennaoui Aoudjehane1-2, A. Jambon2 1Université Hassan II Aïn Chock, Laboratoire Géosciences, BP 5366 Maârif Casa- blanca Morocco (e-mail: [email protected]), 2Université Pierre et Marie Curie-Paris6 and IPGP Laboratoire MAGIE, Case 110, 4 place Jussieu, 75252 Paris France. Introduction: Silica is a rare phase in lunar rocks; it has been described as either quartz, cristobalite and/or tridymite [1]. Northwest Africa 4734, is an uncommon type of lunar rock, which may be launched paired with the LaPaz Icefield Lunar Mare basalts found in 2002-03 in Antarctica [2-6], it is a coarse grained rock of basaltic composition, exhibits a number of sig- nificant shock features, such as PDFs, extensive fracturation of pyroxene, impact melt pockets and transformation of plagioclase to maskelynite; silica is present as a minor phase. Analytical procedures: We studied the speciation of silica polymorphs to characterize the shock, using SEM imaging, Ra- man spectroscopy, CL imaging and spectroscopy. Further details can be found in [7]. Results: According to the CL spectra [7-9], cristobalite, tridymite, high-pressure silica glass, stishovite and seifertite, are all present. Special emphasis is made on stishovite and seifertite, which, like in shergottites, exhibit specific textural features [7]. Cathodoluminescence spectra characteristic of high-pressure sil- ica phases: glass, stishovite and seifertite have been recorded in addition to the original low-pressure phases. The remanence of cristobalite and tridymite underscores a significant heterogeneity of the shock supported by the rock. -
Origin of Fibrosity and Banding in Agates from Flood Basalts: American Journal of Science, V
Agates: a literature review and Electron Backscatter Diffraction study of Lake Superior agates Timothy J. Beaster Senior Integrative Exercise March 9, 2005 Submitted in partial fulfillment of the requirements for a Bachelor of Arts degree from Carleton College, Northfield, Minnesota. 2 Table of Contents AGATES: A LITERATURE REVEW………………………………………...……..3 Introduction………………....………………………………………………….4 Structural and compositional description of agates………………..………..6 Some problems concerning agate genesis………………………..…………..11 Silica Sources…………………………………………..………………11 Method of Deposition………………………………………………….13 Temperature of Formation…………………………………………….16 Age of Agates…………………………………………………………..17 LAKE SUPERIOR AGATES: AN ELECTRON BACKSCATTER DIFFRACTION (EBSD) ANALYSIS …………………………………………………………………..19 Abstract………………………………………………………………………...19 Introduction……………………………………………………………………19 Geologic setting………………………………………………………………...20 Methods……………………………………………………...…………………20 Results………………………………………………………….………………22 Discussion………………………………………………………………………26 Conclusions………………………………………………….…………………26 Acknowledgments……………………………………………………..………………28 References………………………………………………………………..……………28 3 Agates: a literature review and Electron Backscatter Diffraction study of Lake Superior agates Timothy J. Beaster Carleton College Senior Integrative Exercise March 9, 2005 Advisor: Cam Davidson 4 AGATES: A LITERATURE REVEW Introduction Agates, valued as semiprecious gemstones for their colorful, intricate banding, (Fig.1) are microcrystalline quartz nodules found in veins and cavities -
State Rocks Table.Pdf
GATOR GIRL ROCKS THE BEST EVER OFFICIAL STATE ROCK, GEM, MINERAL, FOSSIL, & DINOSAUR SUMMARY TABLE STATE ROCK/(STONE) GEM MINERAL FOSSIL DINOSAUR Basilosaurus cetoides Marble Star Blue Quartz Hematite ALABAMA [whale] 19691 19902 19673 19844 Jade Mammuthus primigenius Gold ALASKA [Nephrite Jade] [woolly mammoth] 1967 1968 1986 STATE ROCKS STATE – Araucarioxylon Turquoise arizonicum ARIZONA 1974 [petrified wood] 1988 Bauxite Diamond Quartz Crystal ARKANSAS 19675 19676 19677 1 Alabama, Act 69-755, Acts of Alabama, September 12, 1969. 2 Alabama, Act 90-203. Acts of Alabama, March 29, 1990. GATORGIRLROCKS.COM GATORGIRLROCKS.COM 3 Alabama, Act 67-503, Acts of Alabama, September 7, 1967. 4 Alabama, Act 84-66, Acts of Alabama, 1984. 5 Arkansas General Assembly 1967. 6 Arkansas General Assembly 1967. 7 Arkansas General Assembly 1967. ©Gator Girl Rocks (2012) – All Rights Reserved GATOR GIRL ROCKS THE BEST EVER OFFICIAL STATE ROCK, GEM, MINERAL, FOSSIL, & DINOSAUR SUMMARY TABLE STATE ROCK/(STONE) GEM MINERAL FOSSIL DINOSAUR Smilodon californicus Serpentine Benitoite Native Gold CALIFORNIA 8 9 10 [saber-tooth cat] 1965 1985 1965 11 1973 Stegosaurus stenops Yule Marble Aquamarine Rhodochrosite COLORADO [dinosaur] 200412 197113 200214 198215 STATE ROCKS STATE Garnet Eubrontes Giganteus – CONNECTICUT [almandine garnet] [dinosaur tracks] 197716 1991 8 California Gov. Code § 425.2. Senate Bill 265 (Laws Chap. 89, Sec. 1) was signed by Govenor Brown on April 20, 1965. California designated the very first official state rock with this legislation (which also created the first official state mineral). 9 California State Legislature October 1, 1985. 10 California Gov. Code § 425.1. Senate Bill 265 (Laws Chap. 89, Sec. -
The Lake Superior Agate
Minnesota Gem: The Lake Superior Agate Its wide distribution and iron-rich bands of color reflect the state gemstone's geologic history in Minnesota Scott F. Wolter N 1969 the dream of Mrs. Jean it was the best choice. The agate IDahlberg was realized: The Lake reflects many aspects of Minnesota. Superior agate was designated by the It was formed during violent, fiery lava Minnesota Legislature as the official eruptions that occurred in our state state gemstone. about a billion years ago. The stone's The late Mrs. Dahlberg, long-time predominant red color comes from rock hound and ardent fan of the agate, iron, the major industrial mineral in testified before the state legislative our state. Finally, the widely distrib- committee considering the bill. She uted agate reveals the impact of gla- knew how perfect the Lake Superior cial movement across Minnesota agate was for the state gemstone. 10,000 to 15,000 years ago. However, there were other logical The Lake Superior agate is inti- candidates. The brazen red Bing- mately related to two prominent geo- hamite and blazing yellow silkstone, logic features of Minnesota: the both iron-rich jaspers found in the majestic and rugged lava flows Cuyuna iron range area, were logical exposed along the shoreline of Lake selections. Thompsonite, the beau- Superior and the lake-freckled glacial tiful and popular zeolite mineral found debris that covers nearly all the state. only in Minnesota on an isolated More than a billion years ago, the stretch along Lake Superior, was North American continent began to another strong candidate. -
General Information- Michigan's Gem Stones
CONTENTS: INDUSTRIES MAP —————— FACING I GENERAL INFORMATION- —————— I MICHIGAN'S GEM STONES- —————— 4 ASSAYS AND TESTS———— ————— I I ARTICLES, PERIODICALS, BOOKS- —————12 SOCIETIES—————————————————— ———— 23 MUSEUMS—————————————————— ———— 26 GEOLOGIC TIME SCALE ———— 30 GEOLOGIC MAP —————— ————— 3 I NMICHIGAN DEPARTMENT OF CONSERVATION ^GEOLOGICAL SURVEY DIVISION FREE DISTRIBUTION ONLY PREFACE TO THIRD EDITION The first edition, published in April, 1958 was needed in responding to queries following a mineral show on the Depart- ment T-V program "Michigan Conservation11. The second edition, July, 1959) was characterized by the addition of the section on gem stones* An abstracted version of the second edition titled "Pebbles to Pendants" was published in the July, 1958 issue of "Michigan Conservation". The present 'third edition is another major revision. Among the new materials added are: l) bedrock geologic map, 2) mineral industries map, 3) rock column and time scale, 4) mineral and fossil sketches, and 5) locality sketch maps* These, along with the cover, were prepared by Jim Campbell of our staff. The book list has been expanded and several titles were added to the articles list. Suggestions received from Arthur Johnstone, of the Michigan Mineralogical Society, were particularly helpful. Information regarding mineral and lapidary businesses may be found in the appropriate advertising media as well as from many of the clubs. Robert W. Kelley, Geologist Geological Survey Division Michigan Dept. Conservation March, I960 Lansing MICHIGAN'S MIN ERAL EXTRACTING INDUSTRIES D NON-METALLIC B BRINE H SALT 0 CLAY 0 SHALE 9 DOLOMITE H LIMESTONE 13 SAND& GRAVELCPRINCIPAL AREA) H GLASS SAND 0 GYPSUM B SANDSTONE D MARLCPRINCIPAL AREA) B PEAT • MISCELLANEOUS STONE A METALLIC L COPPER A IRON O FUELS <D GAS • OIL MAJOR FIELDS € OIL & GAS INDIANA O H I O GENERAL INFORMATION INTRODUCTION Interest in collecting minerals and gem stones and in doing lapidary work certainly is on the increase today. -
Epr Investigation of Carbonaceous Natural
Canodian Mineralogist Yol. 27, pp. 219-224(1989) EPRINVESTIGATION OF CARBONACEOUSNATURAL OUARTZ SINGLE CRYSTALS PILLUTLA S. RAO, JOHN A. WEIL AND JOHN A.S. WILIAMS Departmentof Chemistry,University of Saskatchewan,Saskatoon, Saskatchewan S7N 0W0 ABSTRACT Nos donn€esne rdvblent aucune 6vidence de centresi liai- sonscarbone-oryglne daus lesquels le C pourrait substi- As part of an investigation of whether carbon can sub- tuer au Si. stitute for silicon in ming1sfu, electron paramagnetic resonancestudies were carried out on natural crystals of Clraduit par la Rddaction) a4;laftz from carbonaceous surroutrding.s, i.e., a cat- bonized log found in Utah, For these, as obtained, the Mots<lds:carbone, charbon, lacunes, r6sonance 6lectro- room-teNnperatureresufts at 9.6 GHz indicate f.hepresence nique paramagn€tique,quartz, dioxydede silicium. of the well-known oxygen vacancy (Er ') silicon center and an isotropic broad line with g-factor 2.@28(l) attributed to coal-like macro-regions in the crystals. No signals from INTRoDUCTIoN tAlo4lo or other 4lrrmins6 hole centers usually found in o-quartz were observable,even at low lemperaturs (35 XC We undertook the current investigation pasly in and after X-irradiation. Thus the dark color is not that of the hope of finding a paramagnetic center involving smoky quartz, but is due to macroscopic coal-like impuri- carbon occurring substitutionally for silicon in srys- ties. A weak Mn2+ spectrum could be observedat 2A C,Hz talline quartz. Certainly the question of whether car- but not at9.6 GHaIn concurrent masuremetrts of Her- bon ever enters silicate structures substitutionally is (New kimer "diamonds" York state), doubly terminated of considerable interest. -
Rockhounding North America
ROCKHOUNDING NORTH AMERICA Compiled by Shelley Gibbins Photos by Stefan and Shelley Gibbins California Sapphires — Montana *Please note that the Calgary Rock and Lapidary Quartz — Montana Club is not advertising / sponsoring these venues, but sharing places for all rock lovers. *Also, remember that rules can change; please check that these venues are still viable and permissible options before you go. *There is some risk in rockhounding, and preventative measures should be taken to avoid injury. The Calgary Rock and Lapidary Club takes no responsibility for any injuries should they occur. *I have also included some locations of interest, which are not for collecting Shells — Utah General Rules for Rockhounding (keep in mind that these may vary from place to place) ! • Rockhounding is allowed on government owned land (Crown Land in Canada and Bureau of Land Management in USA) ! • You can collect on private property only with the permission of the landowner ! • Collecting is not allowed in provincial or national parks ! • The banks along the rivers up to the high water mark may be rock hounded ! • Gold panning may or may not need a permit – in Alberta you can hand pan, but need a permit for sluice boxes ! • Alberta fossils are provincial property and can generally not be sold – you can surface collect but not dig. You are considered to be the temporary custodian and they need to stay within the province Fossilized Oysters — BC Canada ! Geology of Provinces ! Government of Canada. Natural resources Canada. (2012). Retrieved February 6/14 from http://atlas.gc.ca/site/ english/maps/geology.html#rocks. -
Josephine County, Oregon, Historical Society Document Oregon, Minerals
) OREGON WELCOMES rock hunters to ROCKHOUND RULES the Agate State.... Oregon is a collector's paradise, but Collectors of every age enjoy the thrill of even in a paradise it is wise to follow a few discovering a flawless gem or a rare fossil, and simple rules ... certainly they will tend to Oregon is the place to find them. assure the best possible success. Come on out and try your luck in one or all of the state's many rich deposits. However, don't be disappointed if you fail I. Select several sites within a to "strike it rich" on your first outing ...it took fairly small area to avoid spreading the residents of Canyon City, in central Ore valuable collecting time too thin ... gon, I 0 years to discover they had paved their become informed on the material streets with gold-bearing gravel! available and its exact location. 2. Don't hesitate to ask local col lectors for information about se lected sites ...check with rockhound clubs wherever they are found. 3. Bring along the proper tools and equipment-including boots and sturdy clothing-for field work ... depending on the material sought, you may find use for a rockhammer, shovel, prybar, sledge and chisel, or light pick mattock. 4. Make special preparations for seasonal weather conditions-can teens, C?PS and sunglasses for the pesert, warm jackets for the moun 0 tains, etc. 5. Obtain permission of land owners before entering private property ... don't leave campsite debris scattered about and BE CAREFUL WITH FIRE. 6. Take care in entering aban doned mine shafts-you enter at your own risk.