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IAEA-TECDOC-1912 IAEA-TECDOC-1912 IAEA TECDOC SERIES Challenges for Coolants in Fast Neutron Spectrum Systems Challenges for Coolants in Fast IAEA-TECDOC-1912 Challenges for Coolants in Fast Neutron Spectrum Systems @ IAEA SAFETY STANDARDS AND RELATED PUBLICATIONS IAEA SAFETY STANDARDS Under the terms of Article III of its Statute, the IAEA is authorized to establish or adopt standards of safety for protection of health and minimization of danger to life and property, and to provide for the application of these standards. The publications by means of which the IAEA establishes standards are issued in the IAEA Safety Standards Series. This series covers nuclear safety, radiation safety, transport safety and waste safety. The publication categories in the series are Safety Fundamentals, Safety Requirements and Safety Guides. Information on the IAEA’s safety standards programme is available on the IAEA Internet site http://www-ns.iaea.org/standards/ The site provides the texts in English of published and draft safety standards. The texts of safety standards issued in Arabic, Chinese, French, Russian and Spanish, the IAEA Safety Glossary and a status report for safety standards under development are also available. For further information, please contact the IAEA at: Vienna International Centre, PO Box 100, 1400 Vienna, Austria. All users of IAEA safety standards are invited to inform the IAEA of experience in their use (e.g. as a basis for national regulations, for safety reviews and for training courses) for the purpose of ensuring that they continue to meet users’ needs. Information may be provided via the IAEA Internet site or by post, as above, or by email to Offi [email protected]. RELATED PUBLICATIONS The IAEA provides for the application of the standards and, under the terms of Articles III and VIII.C of its Statute, makes available and fosters the exchange of information relating to peaceful nuclear activities and serves as an intermediary among its Member States for this purpose. Reports on safety in nuclear activities are issued as Safety Reports, which provide practical examples and detailed methods that can be used in support of the safety standards. Other safety related IAEA publications are issued as Emergency Preparedness and Response publications, Radiological Assessment Reports, the International Nuclear Safety Group’s INSAG Reports, Technical Reports and TECDOCs. The IAEA also issues reports on radiological accidents, training manuals and practical manuals, and other special safety related publications. Security related publications are issued in the IAEA Nuclear Security Series. The IAEA Nuclear Energy Series comprises informational publications to encourage and assist research on, and the development and practical application of, nuclear energy for peaceful purposes. It includes reports and guides on the status of and advances in technology, and on experience, good practices and practical examples in the areas of nuclear power, the nuclear fuel cycle, radioactive waste management and decommissioning. CHALLENGES FOR COOLANTS IN FAST NEUTRON SPECTRUM SYSTEMS The following States are Members of the International Atomic Energy Agency: AFGHANISTAN GERMANY PAKISTAN ALBANIA GHANA PALAU ALGERIA GREECE PANAMA ANGOLA GRENADA PAPUA NEW GUINEA ANTIGUA AND BARBUDA GUATEMALA PARAGUAY ARGENTINA GUYANA PERU ARMENIA HAITI PHILIPPINES AUSTRALIA HOLY SEE POLAND AUSTRIA HONDURAS PORTUGAL AZERBAIJAN HUNGARY QATAR BAHAMAS ICELAND REPUBLIC OF MOLDOVA BAHRAIN INDIA BANGLADESH INDONESIA ROMANIA BARBADOS IRAN, ISLAMIC REPUBLIC OF RUSSIAN FEDERATION BELARUS IRAQ RWANDA BELGIUM IRELAND SAINT LUCIA BELIZE ISRAEL SAINT VINCENT AND BENIN ITALY THE GRENADINES BOLIVIA, PLURINATIONAL JAMAICA SAN MARINO STATE OF JAPAN SAUDI ARABIA BOSNIA AND HERZEGOVINA JORDAN SENEGAL BOTSWANA KAZAKHSTAN SERBIA BRAZIL KENYA SEYCHELLES BRUNEI DARUSSALAM KOREA, REPUBLIC OF SIERRA LEONE BULGARIA KUWAIT SINGAPORE BURKINA FASO KYRGYZSTAN SLOVAKIA BURUNDI LAO PEOPLE’S DEMOCRATIC SLOVENIA CAMBODIA REPUBLIC SOUTH AFRICA CAMEROON LATVIA SPAIN CANADA LEBANON SRI LANKA CENTRAL AFRICAN LESOTHO SUDAN REPUBLIC LIBERIA CHAD LIBYA SWEDEN CHILE LIECHTENSTEIN SWITZERLAND CHINA LITHUANIA SYRIAN ARAB REPUBLIC COLOMBIA LUXEMBOURG TAJIKISTAN CONGO MADAGASCAR THAILAND COSTA RICA MALAWI TOGO CÔTE D’IVOIRE MALAYSIA TRINIDAD AND TOBAGO CROATIA MALI TUNISIA CUBA MALTA TURKEY CYPRUS MARSHALL ISLANDS TURKMENISTAN CZECH REPUBLIC MAURITANIA UGANDA DEMOCRATIC REPUBLIC MAURITIUS UKRAINE OF THE CONGO MEXICO UNITED ARAB EMIRATES DENMARK MONACO UNITED KINGDOM OF DJIBOUTI MONGOLIA GREAT BRITAIN AND DOMINICA MONTENEGRO NORTHERN IRELAND DOMINICAN REPUBLIC MOROCCO UNITED REPUBLIC ECUADOR MOZAMBIQUE OF TANZANIA EGYPT MYANMAR UNITED STATES OF AMERICA EL SALVADOR NAMIBIA ERITREA NEPAL URUGUAY ESTONIA NETHERLANDS UZBEKISTAN ESWATINI NEW ZEALAND VANUATU ETHIOPIA NICARAGUA VENEZUELA, BOLIVARIAN FIJI NIGER REPUBLIC OF FINLAND NIGERIA VIET NAM FRANCE NORTH MACEDONIA YEMEN GABON NORWAY ZAMBIA GEORGIA OMAN ZIMBABWE The Agency’s Statute was approved on 23 October 1956 by the Conference on the Statute of the IAEA held at United Nations Headquarters, New York; it entered into force on 29 July 1957. The Headquarters of the Agency are situated in Vienna. Its principal objective is “to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world’’. IAEA-TECDOC-1912 CHALLENGES FOR COOLANTS IN FAST NEUTRON SPECTRUM SYSTEMS INTERNATIONAL ATOMIC ENERGY AGENCY VIENNA, 2020 COPYRIGHT NOTICE All IAEA scientific and technical publications are protected by the terms of the Universal Copyright Convention as adopted in 1952 (Berne) and as revised in 1972 (Paris). The copyright has since been extended by the World Intellectual Property Organization (Geneva) to include electronic and virtual intellectual property. Permission to use whole or parts of texts contained in IAEA publications in printed or electronic form must be obtained and is usually subject to royalty agreements. Proposals for non-commercial reproductions and translations are welcomed and considered on a case-by-case basis. Enquiries should be addressed to the IAEA Publishing Section at: Marketing and Sales Unit, Publishing Section International Atomic Energy Agency Vienna International Centre PO Box 100 1400 Vienna, Austria fax: +43 1 26007 22529 tel.: +43 1 2600 22417 email: [email protected] www.iaea.org/publications For further information on this publication, please contact: Physics Section International Atomic Energy Agency Vienna International Centre PO Box 100 1400 Vienna, Austria Email: [email protected] © IAEA, 2020 Printed by the IAEA in Austria May 2020 IAEA Library Cataloguing in Publication Data Names: International Atomic Energy Agency. Title: Challenges for coolants in fast neutron spectrum systems / International Atomic Energy Agency. Description: Vienna : International Atomic Energy Agency, 2020. | Series: IAEA TECDOC series, ISSN 1011–4289 ; no. 1912 | Includes bibliographical references. Identifiers: IAEAL 20-01316 | ISBN 978–92–0–107820–9 (paperback : alk. paper) | ISBN 978–92–0–107920–6 (pdf) Subjects: LCSH: Nuclear reactors — Cooling. | Fast reactors. | Accelerator-driven systems. | Fusion reactors. | Fast neutrons. FOREWORD Nuclear applications with a fast neutron spectrum (i.e. fusion, fission and accelerators) pose many challenges to coolants, such as material damage by irradiation, modifications by nuclear reactions and interaction of the coolant and the structure material. This is because of the neutrons’ high power densities and/or heat loads. To evaluate the different coolant options for nuclear applications with a fast neutron spectra, this publication compiles models, simulations, methods, benchmarked procedures/approaches and experiences as well as best practices from the fusion, fission and accelerator/spallation communities to create a knowledge base on coolants, identify the gaps and formulate near term R&D activities to overcome them. This publication is the outcome of two IAEA sponsored meetings: the First IAEA Workshop on Challenges for Coolants in Fast Neutron Spectrum Systems: Chemistry and Materials, held 5–7 July 2017 in Vienna, and a consultancy meeting on the topic held 2–4 July 2018 in Vienna. These meetings brought together representatives from the fusion, fission and accelerator/spallation communities to compile the current state of knowledge and to address research needs identified in experiments and in operation in the area of coolant behaviour in fast neutron spectra. The IAEA gratefully acknowledges the contributions of numerous experts to the preparation of this publication, in particular R. Stieglitz (Germany), L. El-Guebaly (United States of America), Y. Dai (Switzerland) and J. Konys (Germany). The IAEA officers responsible for this publication were M. Barbarino and S.M. Gonzalez de Vicente of the Division of Physical and Chemical Sciences. EDITORIAL NOTE This publication has been prepared from the original material as submitted by the contributors and has not been edited by the editorial staff of the IAEA. The views expressed remain the responsibility of the contributors and do not necessarily represent the views of the IAEA or its Member States. Neither the IAEA nor its Member States assume any responsibility for consequences which may arise from the use of this publication. This publication does not address questions of responsibility, legal or otherwise, for acts or omissions on the part of any person. The use of particular designations