A Rechargeable Type Battery Using Nickel Oxide Hydroxide and Metallic Cadmium As Electrodes. Disclaimer
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Introduction to Batteries
Introduction to Batteries Course No: E03-002 Credit: 3 PDH A. Bhatia Continuing Education and Development, Inc. 22 Stonewall Court Woodcliff Lake, NJ 07677 P: (877) 322-5800 [email protected] CHAPTER 2 BATTERIES LEARNING OBJECTIVES Upon completing this chapter, you will be able to: 1. State the purpose of a cell. 2. State the purpose of the three parts of a cell. 3. State the difference between the two types of cells. 4. Explain the chemical process that takes place in the primary and secondary cells. 5. Recognize and define the terms electrochemical action, anode, cathode, and electrolyte. 6. State the causes of polarization and local action and describe methods of preventing these effects. 7. Identify the parts of a dry cell. 8. Identify the various dry cells in use today and some of their capabilities and limitations. 9. Identify the four basic secondary cells, their construction, capabilities, and limitations. 10. Define a battery, and identify the three ways of combining cells to form a battery. 11. Describe general maintenance procedures for batteries including the use of the hydrometer, battery capacity, and rating and battery charging. 12. Identify the five types of battery charges. 13. Observe the safety precautions for working with and around batteries. INTRODUCTION The purpose of this chapter is to introduce and explain the basic theory and characteristics of batteries. The batteries which are discussed and illustrated have been selected as representative of many models and types which are used in the Navy today. No attempt has been made to cover every type of battery in use, however, after completing this chapter you will have a good working knowledge of the batteries which are in general use. -
Naming Coordination Compounds
Naming Coordination Compounds Author: Kit Mao Department of Chemistry, Washington University St. Louis, MO 63130 For information or comments on this tutorial, please contact K. Mao at [email protected]. Please click here for a pdf version of this tutorial. A coordination complex is a substance in which a metal atom or ion accepts electrons from (and thus associates with) a group of neutral molecules or anions called ligands. A complex can be an anion, a cation ion, or a neutral molecule. Coordination compounds are neutral substances (i.e. uncharged) in which at least one ion is present as a complex. You will learn more about coordination compounds in the lab lectures for experiment 5 in this course. The coordination compounds are named in the following way. (At the end of this tutorial, there are additional examples that demonstrate how coordination compounds are named.) A. When naming coordination compounds, always name the cation before the anion. This rule holds regardless of whether the complex ion is the cation or the anion. (This is just like naming an ionic compound.) B. In naming the complex ion: 1. Name the ligands first, in alphabetical order, and then name the metal atom or ion. Note: The metal atom or ion is written before the ligands in the chemical formula. 2. The names of some common ligands are listed in Table 1. · Anionic ligands end in “-o.” For anions that end in “-ide”(e.g. chloride, hydroxide), “-ate” (e.g. sulfate, nitrate), and “-ite” (e.g. nirite), change the endings as follows: -ide ® -o; e.g., chloride ® chloro and hydroxide ® hydroxo -ate ® -ato; e.g., sulfate ® sulfato and nitrate ® nitrato -ite ® -ito; e.g., nitrite ® nitrito · For neutral ligands, the common name of the molecule is used (e.g. -
Evaluation of Rapid Electric Battery Charging Techniques
UNLV Theses, Dissertations, Professional Papers, and Capstones 2009 Evaluation of rapid electric battery charging techniques Ronald Baroody University of Nevada Las Vegas Follow this and additional works at: https://digitalscholarship.unlv.edu/thesesdissertations Part of the Power and Energy Commons Repository Citation Baroody, Ronald, "Evaluation of rapid electric battery charging techniques" (2009). UNLV Theses, Dissertations, Professional Papers, and Capstones. 156. http://dx.doi.org/10.34917/1392506 This Thesis is protected by copyright and/or related rights. It has been brought to you by Digital Scholarship@UNLV with permission from the rights-holder(s). You are free to use this Thesis in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/ or on the work itself. This Thesis has been accepted for inclusion in UNLV Theses, Dissertations, Professional Papers, and Capstones by an authorized administrator of Digital Scholarship@UNLV. For more information, please contact [email protected]. EVALUATION OF RAPID ELECTRIC BATTERY CHARGING TECHNIQUES By Ronald Baroody Bachelor of Science University of Nevada, Las Vegas 2005 A thesis submitted in partial fulfillment of the requirements for the Master of Science in Engineering Department of Electrical and Computer Engineering Howard R. Hughes College of Engineering Graduate -
The Effect of Morphology on the Electrochemical Properties of Nanostructured Metal Oxide Thin Films: the Studies Based on Multi
The effect of morphology on the electrochemical properties of nanostructured metal oxide thin films : the studies based on multi-scale time-resolved fast electrogravimetric techniques Fatemeh Razzaghi To cite this version: Fatemeh Razzaghi. The effect of morphology on the electrochemical properties of nanostructured metal oxide thin films : the studies based on multi-scale time-resolved fast electrogravimetric techniques. Chemical Physics [physics.chem-ph]. Université Pierre et Marie Curie - Paris VI, 2016. English. NNT : 2016PA066346. tel-01477408 HAL Id: tel-01477408 https://tel.archives-ouvertes.fr/tel-01477408 Submitted on 27 Feb 2017 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Thèse de doctorat Pour l’obtention du grade de Docteur De l’Université Pierre et Marie Curie École doctorale 388 - Chimie Physique et Chimie Analytique de Paris Centre The Effect of Morphology on the Electrochemical Properties of Nanostructured Metal Oxide Thin Films: The Studies based on Multi-scale Time-resolved Fast Electrogravimetric Techniques Par Fatemeh Razzaghi Directeur de thèse : Dr Hubert Perrot Présentée et soutenue publiquement le 29 septembre 2016, Devant un jury composé de : Nicole Jaffrezic DR CNRS Émérite Rapporteur Francois Tran-Van Prof. -
A Mathematical Model of a Lithium/Thionyl Chloride Primary Cell T
University of South Carolina Scholar Commons Faculty Publications Chemical Engineering, Department of 1989 A Mathematical Model of a Lithium/Thionyl Chloride Primary Cell T. I. Evans Texas A & M University - College Station T. V. Nguyen Texas A & M University - College Station Ralph E. White University of South Carolina - Columbia, [email protected] Follow this and additional works at: https://scholarcommons.sc.edu/eche_facpub Part of the Chemical Engineering Commons Publication Info Journal of the Electrochemical Society, 1989, pages 328-339. © The Electrochemical Society, Inc. 1989. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The ra chival version of this work was published in the Journal of the Electrochemical Society. http://www.electrochem.org/ DOI: 10.1149/1.2096630 http://dx.doi.org/10.1149/1.2096630 This Article is brought to you by the Chemical Engineering, Department of at Scholar Commons. It has been accepted for inclusion in Faculty Publications by an authorized administrator of Scholar Commons. For more information, please contact [email protected]. 328 J. Electrochem. Soc., Vol. 136, No. 2, February 1989 The Electrochemical Society, Inc. Table A-I. Concentration, density, and mole fraction of LiAICI4-SOCI2 (p +_ 0.0001) = (0.594484 • 0.000934). XLjAlCI4 solutions at 25~ based on the experiment of Venkatasetty and Saathoff (5) + (1.64388 --+ 0.00004) (R 2 = 0.99997) These lines are valid in the range 0 < XLIA~C14< 0.11, 0 < C Concentration Density < 1.50 mol/liter and 1.64 < p < 1.71 g/cm ~ and at 25~ At (mol/liter) (g/cm~) XLiAIC14a higher concentrations linear extrapolation cannot be done with confidence. -
Thulhu Muttur
THULHUUS009793542B2 MUTTUR (12 ) United States Patent ( 10 ) Patent No. : US 9 , 793 ,542 B2 Nelson et al. ( 45 ) Date of Patent: Oct . 17 , 2017 (54 ) BETA - DELITHIATED LAYERED NICKEL (58 ) Field of Classification Search OXIDE ELECTROCHEMICALLY ACTIVE CPC .. .. HO1M 4 /244 ; HOTM 4 / 366 ; HOTM 4 /52 ; CATHODE MATERIAL AND A BATTERY HOTM 4 / 131; HOTM 4 / 32 ; HO1M 4 / 525 INCLUDING SAID MATERIAL See application file for complete search history . ( 71 ) Applicant : DURACELL U . S . OPERATIONS, ( 56 ) References Cited ??? INC ., Wilmington , DE (US ) U . S . PATENT DOCUMENTS (72 ) Inventors : Jennifer Anne Nelson , Waltham , CT 2 , 956 , 860 A 10 / 1960 Welsh et al . ( US ) ; David Lloyd Anglin , Brookfield , 3 ,437 ,435 A 4 /1969 Moore et al . CT (US ) ; Mariarosa Brundu , Budduso (Continued ) (IT ) ; Paul Albert Christian , Norton , MA (US ) FOREIGN PATENT DOCUMENTS ( 73 ) Assignee : DURACELL U . S . OPERATIONS , 1263697 12 / 1989 INC . , Wilmington , DE (US ) 0 702 421 A1 3 / 1996 (Continued ) ( * ) Notice : Subject to any disclaimer, the term of this ???????? patent is extended or adjusted under 35 OTHER PUBLICATIONS U . S . C . 154 ( b ) by 213 days. PCT International Search Report with Written Opinion in corre ( 21) Appl. No .: 14 /625 ,876 sponding Int' l appln . PCT/ US2015 /021381 dated Aug . 11 , 2015 . ( 22 ) Filed : Feb . 19 , 2015 (Continued ) Primary Examiner — Stewart Fraser (65 ) Prior Publication Data Assistant Examiner — Rachel L Zhang (74 ) Attorney , Agent, or Firm — Marshall , Gerstein & US 2015 /0280234 A1 Oct . 1 , 2015 Borun LLP Related U . S . Application Data (57 ) ABSTRACT The invention is directed towards an electrochemically (60 ) Provisional application No . 61 / 971, 667 , filed on Mar. -
Development of Cathode Materials for Magnesium Primary Cell K
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by KnowledgeCuddle Publication (E-Journals) International Journal of Research in Advance Engineering, (IJRAE) Vol. 2, Issue 5, Sep-Oct-2016, Available at: www.knowledgecuddle.com/index.php/IJRAE Development of cathode materials for magnesium primary cell K. Narthana1, M. Selvam1, K. Saminathan, V. Rajendran and Karan V.I.S. Kaler2 aCentre for nano science and technology, K S Rangasamy College of technology, Tiruchengode -637 215, Tamil Nadu, India bSchulich School of Engineering , Department of Electrical and Computer Engineering, University of Calgary, Calgary, Alberta, Canada. Abstract: The Zinc Sulfide nanoparticles were synthesized by simple chemical reaction of ZnCl2 and Sulphur powder in aqueous solution. The main advantage of this method is the use of non-toxic precursors and water as solvent. The BZ1 and NZ2 samples reveal an average particle size respectively 510 and 43.7 nm. The structural, morphological, chemical composition and optical properties of the nanoparticles were investigated by X-ray diffraction, Scanning electron Microscopy, and Energy-dispersive X-ray Spectroscopy, Ultra Violet Spectroscopy and Electrochemical studies. The NZ2 sample showed a high discharge capacity of 362 mAh g -1, whereas the BZ1 sample showed a discharge capacity of 120 mAh g -1. The discharge capacity of NZ2 sample based cathode was 33.1 % higher than BZ1 sample based cathode. Thus, the above studies confirm that zinc sulfide nano powders show promise application as a cathode material for Mg/ZnS primary cell. Key words: BZ1 sample, NZ2 sample, Discharge capacity, Electro chemical studies, Band gap *Corresponding author: [email protected] I. -
Salts in Organic Synthesis: an Overview and Their Diversified Use
Salts in Organic Synthesis: an overview and their diversified use Dirgha Raj Joshi1* and Nisha Adhikari2 1. College of Pharmacy, Yonsei University International Campus, Incheon, Republic of Korea 2. College of Pharmacy, Gachon University Medical Campus, Incheon, Republic of Korea *Correspondence: Dirgha Raj Joshi Email:[email protected], [email protected] ORCID ID: 0000-0002-0303-5677 Abstract The chemistry of salt is of great importance due to its immense potential from the daily life use to the synthetic chemistry like as workup material, as reagents, as phase transfer catalyst, as acid, as base, as catalyst, as agents for asymmetric synthesis, for some specific reaction transformation, to increase yield, decrease reaction time, ecofriendly synthesis, handling easiness and many more. This review summarizes the basic background of salts, its application, synthesis of new salts, and list of individual categories of major commercially available salts with some structure. Keywords: Organic synthesis, green chemistry, salts, catalyst, reagent, asymmetric synthesis, acid, base Introduction In chemistry, the salt is usually a solid chemical compound having related numbers of positively charged ions called cation and negatively charged ions called anions which are assembled to form a solid mass, so the whole mass is electrically neutral 2- (no net charge). These ions particle can be either organic (acetate- CH3CO ) or inorganic (chloride- Cl-, fluoride- F- etc.) and can be as a monoatomic (chloride- - 2- Cl ) or polyatomic (sulfate- SO 4)[1]. For organic synthesis, the considerations about various factors play a crucial role. With this respect, the organic and inorganic salts always remain core corner in the reagents category. -
Battery Recycling: Defining the Market and Identifying the Technology Required to Keep High Value Materials in the Economy and out of the Waste Dump
Battery Recycling: defining the market and identifying the technology required to keep high value materials in the economy and out of the waste dump By Timothy W. Ellis Abbas H. Mirza Page 1 of 33 Introduction: The accumulation of post consumer non-Lead/Acid batteries and electrochemical (n-PbA) cells has been identified as a risk in the waste stream of modern society. The n-PbA’s contain material that is environmentally unsound for disposal; however, do represent significant values of materials, e.g. metals, metal oxides, and carbon based material, polymers, organic electrolytes, etc. The desire is to develop systems whereby the nPbA’s are reprocessed in a hygienic and environmentally astute manner which returns the materials within the n-PbA’s to society in an economically and environmentally safe and efficient manner. According to information published in the Fact File on the “Recycling of Batteries” by the Institution of Engineering and Technology (www.theiet.org) the following, Table 1, describes the recycling market. Table 1: Recoverable Metals from Various Battery Types Battery Type Recycling Alkaline & Zinc Carbon Recycled in the metals industry to recover steel, zinc, ferromanganese Nickel – (Cadmium, Metal Hydride) Recycled to recover Cadmium and Nickel with a positive market value Li-Ion Recycled to recover Cobalt with a positive market value Lead-Acid Recycled in Lead industry with a positive market value Button Cells Silver is recovered and has a positive market value; Mercury is recovered by vacuum thermal processes A literature search on “Recycling and Battery” on the STN Easy data base produced over 2500 hits. -
Electric Current Is a Flow of Charge
Page 1 of 7 KEY CONCEPT Electric current is a flow of charge. BEFORE, you learned NOW, you will learn • Charges move from higher to • About electric current lower potential • How current is related to • Materials can act as conductors voltage and resistance or insulators • About different types of • Materials have different levels electric power cells of resistance VOCABULARY EXPLORE Current electric current p. 28 How does resistance affect the flow of charge? ampere p. 29 Ohm’s law p. 29 PROCEDURE MATERIALS electric cell p. 31 • pencil lead 1 Tape the pencil lead flat on the posterboard. • posterboard 2 Connect the wires, cell, bulb, and bulb • electrical tape holder as shown in the photograph. • 3 lengths of wire 3 Hold the wire ends against the pencil lead • D cell battery about a centimeter apart from each other. • flashlight bulb Observe the bulb. • bulb holder 4 Keeping the wire ends in contact with the lead, slowly move them apart. As you move the wire ends apart, observe the bulb. WHAT DO YOU THINK? • What happened to the bulb as you moved the wire ends apart? • How might you explain your observation? Electric charge can flow continuously. Static charges cannot make your television play. For that you need a different type of electricity. You have learned that a static charge contains a specific, limited amount of charge. You have also learned that a static charge can move and always moves from higher to lower VOCABULARY potential. However, suppose that, instead of one charge, an electrical Don’t forget to make a four square diagram for the pathway received a continuous supply of charge and the difference in term electric current. -
INVESTIGATION on the STRUCTURAL and OPTICAL PROPERTIES of Nio NANOFLAKES
D. Abubakar, N. Mahmoud, Sh. Mahmud doi: 10.15407/ujpe62.11.0970 D. ABUBAKAR,1 N. MAHMOUD,2 SH. MAHMUD3 1 Physics Department, Bauchi State University Gadau (65, Itas/Gadau – Bauchi Nigeria; e-mail: [email protected]) 2 Nano-Optoelectronics Research Laboratory (NOR) – School of Physics Universiti Sains Malaysia (11800 Gelugor Pulau Pinang – Malaysia) 3 Nano-Optoelectronics Research Laboratory (NOR) – School of Physics, Universiti Sains Malaysia (11800 Gelugor Pulau Pinang – Malaysia) INVESTIGATION ON THE STRUCTURAL AND OPTICAL PROPERTIES OF NiO NANOFLAKES. PACS 68.55.-a, 78.20.-e, 81.15.Lm CHEMICAL BATH DEPOSITION OF Ni(OH)2 THIN FILMS Porous nickel oxide (NiO) nanoflakes are grown by the chemical bath deposition. The thin films are produced on an ITO/glass substrate and annealed at a variable temperature ina furnace. The structural and optical properties and the surface morphology of the thin films are studied and analyzed. FESEM results display the presence of nanoflakes with the structure of NiO/Ni(OH)2 in thin films that appear to increase in size with the annealing temperature. The sample grown at 300 ∘C is observed to have the highest surface area dimension. The EDX result reveals that the atomic ratio and weight of the treated sample has a non-stoichiometric value, which results in the p-type behavior of the NiO thin film. The result obtained by AFM indicates the highest roughness value (47.9 nm) for a sample grown at 300 ∘C. The analysis on XRD shows that the NiO nanoflakes possess a cubic structure with the orientation peaks of (111), (200), and (220). -
Nickel-Cadmium Battery
NICKEL-CADMIUM BATTERY ELECTROCHEMICAL ENERGY STORAGE 1. Technical description A. Physical principles C. Key performance data A Ni-Cd Battery System is an energy storage system based on electrochemical charge/discharge reactions that occur between a positive electrode (cathode) Power range Some kW - some that contains nickel oxyde-hydroxide as the active material and a negative electrode (anode) that is composed of metallic cadmium. Energy range < some 10 M Wh The electrodes are separated by a permeable membrane which allows for Discharge time Some mn – some h electron and ionic flow between them and are immersed in an electrolyte that is made up of aqueous potassium hydroxide and that undergoes no significant changes during operation. Cycle life 1 000-5 000 cycles During discharge, the nickel oxide-hydroxide combines with water and produces Life duration 10 – 20 years nickel hydroxide and a hydroxide ion. Cadmium hydroxide is produced at the negative electrode. To charge the battery the process can be reversed. Reaction time Some ms Illustration: Charging principle of Ni-Cd Efficiency 60-70 % Energy (power) density 30-70 Wh/kg Positive Negative CAPEX: energy 400 - 700 € / kWh NiO2 H2-x Cd x CAPEX: power 500 – 1 500 € / kW Electrolyte D. Design variants (non exhausitive) KOH The following design variants are available: Different electrode thickness according to the power/energy ratio Different cell size from 2 Ah up to 200 Ah Different cell shapes: cylindrical (small cells) or prismatic (large cells), - Different battery systems according