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Safety Data Sheet the Dow Chemical Company SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: TRIETHYLENETETRAMINE. Issue Date: 03/04/2015 Print Date: 03/05/2015 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. IDENTIFICATION Product name: TRIETHYLENETETRAMINE. Recommended use of the chemical and restrictions on use Identified uses: Chemical additive. Polyamide resins. Curing agent. COMPANY IDENTIFICATION THE DOW CHEMICAL COMPANY 2030 WILLARD H DOW CENTER MIDLAND MI 48674-0000 UNITED STATES Customer Information Number: 800-258-2436 [email protected] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 800-424-9300 Local Emergency Contact: 989-636-4400 2. HAZARDS IDENTIFICATION Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Acute toxicity - Category 4 - Oral Acute toxicity - Category 4 - Dermal Skin corrosion - Category 1 Serious eye damage - Category 1 Skin sensitisation - Category 1 Reproductive toxicity - Category 1B Effects on or via lactation Label elements Hazard pictograms ® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 13 company of Dow Product name: TRIETHYLENETETRAMINE. Issue Date: 03/04/2015 Signal word: DANGER! Hazards Harmful if swallowed or in contact with skin Causes severe skin burns and eye damage. May cause an allergic skin reaction. May damage fertility or the unborn child. May cause harm to breast-fed children. Precautionary statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Avoid contact during pregnancy/ while nursing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ protective clothing/ eye protection/ face protection. Use personal protective equipment as required. Response IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF exposed or concerned: Get medical advice/ attention. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. Storage Store locked up. Disposal Dispose of contents/ container to an approved waste disposal plant. Other hazards Causes burns of the mouth and throat. Page 2 of 13 Product name: TRIETHYLENETETRAMINE. Issue Date: 03/04/2015 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: 3,6-Diazaoctanethylene- diamin; triethylenetetramine This product is a substance. Component CASRN Concentration Triethylenetetramine mixture 112-24-3 < 98.4 % Aminoethylethanolamine 111-41-1 < 1.6 % Aminoethylpiperazine 140-31-8 < 1.3 % Tetraethylenepentamine mixture 112-57-2 < 1.1 % 4. FIRST AID MEASURES Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air; if effects occur, consult a physician. Skin contact: Immediate continued and thorough washing in flowing water for at least 30 minutes is imperative while removing contaminated clothing. Prompt medical consultation is essential. Wash clothing before reuse. Properly dispose of leather items such as shoes, belts, and watchbands. Suitable emergency safety shower facility should be immediately available. Eye contact: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: Do not induce vomiting. Give one cup (8 ounces or 240 ml) of water or milk if available and transport to a medical facility. Do not give anything by mouth unless the person is fully conscious. Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Chemical eye burns may require extended irrigation. Obtain prompt consultation, preferably from an ophthalmologist. If burn is present, treat as any thermal burn, after decontamination. Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggest endotracheal/esophageal control if lavage is done. No specific antidote. Page 3 of 13 Product name: TRIETHYLENETETRAMINE. Issue Date: 03/04/2015 Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective. Unsuitable extinguishing media: Do not use direct water stream. May spread fire. Special hazards arising from the substance or mixture Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Heat is generated when product mixes with water. Container may rupture from gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Water should be applied in large quantities as fine spray. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Evacuate area. Refer to section 7, Handling, for additional precautionary measures. Keep upwind of spill. Ventilate area of leak or spill. Only trained and properly protected personnel must be involved in clean-up operations. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Small spills: Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Do NOT use absorbent Page 4 of 13 Product name: TRIETHYLENETETRAMINE. Issue Date: 03/04/2015 materials such as: Cellulose. Sawdust. Moist organic absorbents. Peat moss. Ground corn cobs. Large spills: Dike area to contain spill. Collect in suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional information. 7. HANDLING AND STORAGE Precautions for safe handling: Do not get in eyes, on skin, on clothing. Do not swallow. Avoid prolonged or repeated contact
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