CHEMICAL HYGIENE PLAN AND HAZARDOUS MATERIALS SAFETY MANUAL FOR LABORATORIES This is the Chemical Hygiene Plan specific to the following areas: Laboratory name or room number(s): ___________________________________ Building: __________________________________________________________ Supervisor: _______________________________________________________ Department: _______________________________________________________ EMERGENCY TELEPHONE NUMBERS: 911 for Emergency and urgent consultation 3-2035 MSU Police; 3-2066 Facilities Management 3- 2915 Dr. Mark Blankenbuehler, Associate Professor Chemistry & Chemical Safety Committee Chair; Office: 404D Lappin Hall; email: [email protected] 3-2179 or (606) 207-9425 Holly Niehoff, Director of EHS, Risk Management & Insurance; Office BCB 113; email: [email protected] 3-9022 or (606) 207-2556 Derek Lewis, Fire & Life Safety Technician; Office BCB 113; email: [email protected] 3-______ Department Chair 3-______ Building Supervisor State 24-hour warning point for HAZMAT Spill Notification If you need to report a spill in accordance with SARA Title III Section 304 and KRS 39E.190, please contact the Duty Officer at the Commonwealth Emergency Operations Center at 800.255.2587 which serves as the twenty-four (24) hour warning point and contact for the Commonwealth Emergency Response Commission. Revised November 2019 All laboratory chemical use areas must maintain a work-area specific Chemical Hygiene Plan which conforms to the requirements of the OSHA Laboratory Standard 29 CFR 19190.1450. Morehead State University laboratories may use this document as a starting point for creating their work area specific Chemical Hygiene Plan (CHP). Morehead State Chemical Hygiene Plan MSU Laboratory Awareness Certification For CHP of (Professor, Building, Room)________________________ The Occupational Safety and Health Administration (OSHA) requires that laboratory employees be made aware of the Chemical Hygiene Plan at their place of employment (29 CFR 1910.1450). The Morehead State University Chemical Hygiene Plan and Hazardous Materials Safety Manual serves as the written Chemical Hygiene Plan (CHP) for laboratories using chemicals at Morehead State University. The CHP is a regular, continuing effort, not a standby or short term activity. Departments, divisions, sections, or other work units engaged in laboratory work whose hazards are not sufficiently covered in this written manual must customize it by adding their own sections as appropriate (e.g. standard operating procedures, emergency procedures, identifying activities requiring prior approval). After reading the "Morehead State Chemical Hygiene Plan and Hazardous Material Safety Manual," complete and return a copy of this form to your supervisor or to your department’s Safety Committee Chair. By signing below you acknowledge that you are aware of the Chemical Hygiene Plan and the policies and procedures applicable to the OSHA standard (29 CFR 1910.1450). Your supervisor will provide additional information and training as appropriate. Please type or print legibly. Name: __________________________________Work Phone: _____________________ Student or staff ID number: _________________________________________________ Email address: ____________________________________________________________ Department: _____________________________________________________________ Job Classification (if employee): ______________________________________________ Building: _________________________________________________________________ Supervisor/instructor for your work area: ______________________________________ Room(s): _________________________________________________________________ Signature: ____________________________________ Date: _______________________ Completed CHP Awareness Certifications are to be filed in a central administrative location within the staff member’s department and a copy forwarded to Holly Niehoff in the Office of Environmental Health & Safety. These and all safety training records should be organized in a way that allows original records to be retrieved quickly and efficiently on request by an OSHA inspector. MSU Chemical Hygiene Plan Page 2 Morehead State University Safety Policy Statement It is the policy of Morehead State University to take every reasonable precaution to provide a work environment that is free from recognized hazards for its employees in accordance with the General Duty clause of the OSHA Act (Public Law 91-596, Section 5(a)(l)). Morehead State University is also required by the OSHA Laboratory Standard to ensure that the necessary work practices, procedures and policies are implemented to protect laboratory employees from all potentially hazardous chemicals in use in their work area. Office of Environmental Health & Safety Mission Statement The Office of Environmental Health and Safety is a service unit of the University that is committed to maintaining a healthful, safe and secure environment for all members of the campus community. The Office of EHS oversees the development and University-wide implementation of integrated risk management, loss prevention, safety and regulatory compliance programs. Assessments of the potential for loss to the University and the appropriate financial management of such risks. The Office of Environmental Health and Safety ensures compliance with all Federal, State and local regulations and standards involving environmental management, chemical control, industrial hygiene, general campus safety and fire safety as well as overseeing the procurement and management of university property, casualty, and liability insurance and claims against the University and participates in the review of litigation. MSU Chemical Hygiene Plan Page 3 TABLE OF CONTENTS Chemical Hygiene Plan Awareness Certification 2 Morehead State University Policy Statement 3 PART I THE OSHA LABORATORY STANDARD AND Morehead State CHP 7 THE OSHA LAB STANDARD 8 EMPLOYEE RIGHTS AND RESPONSIBILITIES 8 HAZARDOUS CHEMICALS 9 MATERIAL SAFETY DATA SHEETS (MSDSs) 11 HCS PICTOGRAMS & HAZARDS 18 CHEMICAL PROCUREMENT 19 CHEMICAL INVENTORIES 19 LABORATORY SECURITY 19 MOREHEAD STATE UNIVERSITY CHEMICAL HYGIENE PLAN 21 SCOPE AND APPLICATION 21 RESPONSIBILITY 21 EXPOSURE LIMITS 24 EMPLOYEE INFORMATION AND TRAINING 24 Information 24 Training 25 Documentation 25 Basic Lab Safety Awareness Training from EHS 25 MEDICAL CONSULTATIONS AND EXAMINATIONS 25 HAZARD IDENTIFICATION 26 CHEMICALS DEVELOPED IN THE LABORATORY 27 USE OF RESPIRATORS 27 STANDARD OPERATING PROCEDURES 27 CONTROL MEASURES 28 PROTECTIVE EQUIPMENT 28 SPECIAL HAZARDS 28 AVAILABILITY 28 ANNUAL REVIEW 28 PART II HAZARDOUS MATERIALS SAFE HANDLING INFORMATION 30 MINIMIZE ALL CHEMICAL EXPOSURES 31 RISK ASSESSMENTS 31 SAFE HANDLING OF CHEMICALS 33 MSU Chemical Hygiene Plan Page 4 GENERAL SAFETY GUIDELINES 33 ENGINEERING CONTROLS 35 Ventilation Controls 36 Proper Use of Ventilation Systems 36 FUME HOOD GUIDELINES 37 ADMINISTRATIVE CONTROLS 38 Signage & Restricted Access Areas 38 PERSONAL PROTECTIVE EQUIPMENT 39 General Considerations 39 Hazards Assessments 39 Protection Against Inhalation Hazards 40 Protection of Skin and Body 40 CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT 41 EMERGENCY SHOWER & EYEWASH STATIONS 42 CHEMICAL STORAGE 42 TRANSFERING CHEMICALS 43 MODEL WRITTEN SOPs: SPECIAL PRECAUTIONS 44 PHYSICAL HAZARDS 44 Flammables and Combustibles 45 Corrosives 46 Oxidizers 47 Water-Reactive Materials 48 Pyrophoric Materials 49 Peroxidizables 50 Light-Sensitive Materials 51 Shock-Sensitive or Explosive Materials 52 Compressed Gases 53 Cryogens 54 HEALTH HAZARDS 55 Allergens 56 Embryotoxins and Reproductive Toxins 57 Chemicals of Moderate Chronic or High Acute Toxicity 58 Chemicals of High Chronic Toxicity 59 Animal Work with Chemicals of High Chronic Toxicity 60 Nanoparticles and Nanomaterials 61 BIOLOGICAL HAZARDS 62 MSU Chemical Hygiene Plan Page 5 RADIOACTIVE MATERIAL HAZARDS 62 IONIZING AND NON-IONIZING RADIATION HAZARDS 62 TRANSPORTATION OF HAZARDOUS MATERIALS 63 TRANSPORTATION OVER THE ROAD 63 TRANSPORTATION INSIDE BUILDINGS AND BY FOOT 63 WASTE DISPOSAL 64 EMERGENCY RESPONSE 65 BASIC STEPS FOR EMERGENCY RESPONSE 65 PLAN A, HIGH HAZARD EMERGENCIES 65 PLAN B, LOW HAZARD EMERGENCIES 66 FIRE AND FIRE-RELATED EMERGENCIES 66 MERCURY SPILLS 67 INJURY AND ILLNESS 67 APPENDICES 69 APPENDIX A University Chemical Safety Committee Charter 70 APPENDIX B Incompatible Chemicals 71 APPENDIX C Peroxidizables 73 APPENDIX D Shock-Sensitive Materials 74 APPENDIX E Industrial Toxicology Overview 75 APPENDIX F Laboratory Safety/Supply Checklist 80 APPENDIX G Chemicals Resistant Glove Guide 81 APPENDIX H Glossary 84 APPENDIX I EPCRA Reportable Quantities List of Lists 99 APPENDIX J Sample Chemical Inventory Form 119 APPENDIX K Hazard Assessment Form 120 APPENDIX L Select Agents and Toxins List 124 APPENDIX M References 126 MSU Chemical Hygiene Plan Page 6 PART I The OSHA Laboratory Standard and Morehead State University Chemical Hygiene Plan MSU Chemical Hygiene Plan Page 7 THE OSHA LABORATORY STANDARD The basis for this standard (29 CFR 1910.1450) is a determination by the Occupational Safety and Health Administration (OSHA), after careful review of the complete rule-making record, that laboratories typically differ from industrial operations in their use and handling of hazardous chemicals and that a different approach than that found in OSHA's substance specific health standards is warranted to protect workers. The final standard applies to all laboratories that