Mineralogy and Geochemistry of Tourmaline in Contrasting Hydrothermal Systems: Copiapó Area, Northern Chile

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MINERALOGY AND GEOCHEMISTRY OF TOURMALINE IN CONTRASTING HYDROTHERMAL SYSTEMS: COPIAPÓ AREA, NORTHERN CHILE

Ana C. Collins

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DEPARTMENT OF GEOSCIENCES

In Partial Fulfillment of the Requirements

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MASTER OF SCIENCE

In the Graduate College THE UNIVERSITY OF ARIZONA 2010

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As members of the Research Committee, we recommend that this thesis be accepted as fulfilling the research requirement for the degree of Master of Science.

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2 Abstract Tourmaline group minerals can be useful for petrogenetic studies due to their refractory nature, chemical and isotopic variability, and widespread occurrence in many geologic settings. Near Copiapó, Chile, tourmaline occurs in a wide range of igneous- related hydrothermal systems with widely varying types of mineral assemblages and chemical compositions, making this area an exceptional locality for studying controls on tourmaline chemistry. Copiapó tourmalines cover the majority of known tourmaline compositions excluding those associated with Li-rich pegmatites. Tourmaline formed in multiple, complex stages and is commonly intermediate schorl-dravite with a general progression in later tourmaline generations towards more Fe-rich and Al-deficient compositions with a dominant substitution of Fe3+ for Al. This compositional trend, along with the presence of several tourmaline generations, is consistent with time-varying, relatively oxidizing, saline, acidic, boron-bearing fluids and reflects a greater host rock influence with progressive hydrothermal alteration. Tourmalines from other saline environments, both mineralized and otherwise, show similar compositional trends, reflecting analogous tourmaline-forming fluid compositions. The correlation between iron enrichment and highly saline fluids may reflect progressively more effective leaching and transport of iron from the host rock with time. Boron isotope analyses of tourmaline indicate a mixed fluid source, reflective of both magmatic and evaporitic sources, and is consistent with previous fluid-related studies of mineralizing fluids associated with iron oxide-copper-gold (IOCG) mineralization in the Candelaria-Punta del Cobre district. The study of tourmaline in these settings has the potential to constrain the origin(s) of this puzzling style of mineralization and can yield insights on the diversity of conditions under which tourmaline forms.

Introduction Tourmaline occurs in a variety of geological environments and is a common accessory mineral in granitic pegmatites, low- to high-grade metamorphic rocks, and clastic sedimentary rocks. However, hydrothermal environments comprise some of the most common and diverse occurrences. Tourmaline’s complex composition reflects changes in its chemical and physical environment which, combined with its refractory

3 nature and wide range of stability, make it well-suited to explore the conditions under which it formed (Henry and Guidotti, 1985). Consequently, tourmaline has been the subject of many studies and is useful for investigating differences between contrasting hydrothermal systems. Tourmaline is a complex borosilicate mineral group that has a general structural 1+ 2+ 2+ formula of XY3Z6[T6O18](BO3)3V3W, where X = Na, Ca, K, and □, Y = Li , Mg , Fe , Mn2+, Al3+, and Ti4+, Z = Al3+, Mg2+, Fe3+, V3+, and Cr3+, T = Si, Al, and B, V = OH, O, and W = OH, O, and F (Dyar et al., 1998; Hawthorne and Henry, 1999). Usually tourmaline is considered in terms of its end members, of which there are fourteen IMA- recognized species (Table 1; Hawthorne and Henry, 1999). Solid solution in tourmaline is ubiquitous as simple or coupled substitutions. Table 2 summarizes common exchange vectors in tourmaline. Al, Fe, Na, Ca, and Mg comprise some of the most important substituent elements. Li can be important in tourmalines from rare-metal granites and pegmatites; however, it is minor or absent in most other types of settings (e.g., Henry and Guidotti, 1985). Documenting and understanding variations in these constituents is central to interpreting the significance of tourmaline in hydrothermal systems. Tourmaline is commonly associated with and co-precipitated during the formation of numerous types of mineral deposits, including copper, silver-gold, tin(-tungsten), massive sulfide, and uranium deposits, and occurs as breccia cement and clasts, veins, alteration envelopes and assemblages, and other metasomatic bodies (Slack et al., 1984; Pirajno and Smithies, 1992; Slack, 1996; Xavier et al., 2008). Tourmaline is commonly the principal host of boron in these deposits, and its durability allows it to preserve a detailed record of its formation even when dispersed during weathering and erosion. Tourmaline chemistry reflects the diverse compositions of both host rock and hydrothermal fluids, as well as differences in temperature and pressure of formation. This compositional record provides insight into mineralizing conditions, fluid flow, and possible sources of constituents in hydrothermal systems (e.g., in magmatic-hydrothermal systems: Pirajno and Smithies, 1992; Mlynarczyk and Williams-Jones, 2006; Dini et al., 2008; those sourced from external fluids: Palmer and Slack, 1989; Peng and Palmer, 2002; Xavier et al., 2008). Major-element trends have been used as guides for exploration (i.e., Clarke et al., 1989). For instance, Fe/(Fe+Mg) ratios in tourmaline vary systematically in Sn and Sn-W

4 hydrothermal deposits, with ratios decreasing with increasing distance from the magmatic source of mineralizing fluids and increasing interaction with the host rock (Pirajno and Smithies, 1992). Boron isotopes in tourmaline have been used to fingerprint the source of mineralizing fluids and can provide new insight as to the metallogenesis of various hydrothermal deposits (Palmer and Slack, 1996; Xavier et al., 2008). The abundance of tourmaline can also serve as a prospecting guide for undiscovered borate bodies and stratabound mineral deposits (Peng and Palmer, 2002; Slack, 1982). Care must be taken when using tourmaline as an exploration tool, as the compositions can be strongly influenced by the composition of the host rock, and the final composition may reflect an amalgamation of multiple sources and chemical interactions. Relatively little work has been done on the mineralogy and stability of tourmaline in many high-temperature hydrothermal systems, and tourmaline petrology and geochemistry have only recently been considered in iron oxide-copper-gold (IOCG) deposits (i.e., Xavier et al., 2008). IOCG systems are characterized by voluminous magnetite and/or hematite, variable amounts of Cu- and Fe-sulfides, gold, and REE, and low Ti contents compared to most igneous rocks (Hitzman et al., 1992; Barton and Johnson, 1996; Williams et al., 2005). In contrast to porphyry-type systems, magmatic compositions play only a secondary role on IOCG alteration mineralogy and elemental abundances (Barton and Johnson, 1996). IOCG deposits are generated by hypersaline, variably CO2-bearing, Cl-rich, and S-poor fluids, are formed at shallow to mid-crustal levels, and are closely associated with variably intense and voluminous sodic(-calcic) and potassic alteration. The origins of the ore-forming fluids are unsettled: they might be exsolved from magmas (Marschik and Fontboté, 2001; Sillitoe, 2003; Pollard, 2006) or be derived from external, evaporitic brines (Barton and Johnson, 1996; Xavier et al., 2008). Thus, understanding tourmaline in these settings has the potential to elucidate and constrain the origin(s) of this puzzling style of mineralization and, in well-chosen cases, can yield an independent set of constraints on the diversity of conditions under which tourmaline forms. This study systematically looks at igneous-related tourmaline occurrences in the Copiapó region of northern Chile, a part of the Chilean Iron Belt and one of the world's classic areas for IOCG mineralization (Marschik and Fontboté, 2001; Sillitoe, 2003). This

5 area is also the locus for widespread, though economically unimportant, porphyry copper mineralization (Maksaev et al., 2007). The first part of this project evaluates the petrographic, chemical, and isotopic characteristics of tourmaline in the diverse hydrothermal environments present near Copiapó, of which the IOCG systems in the Candelaria-Punta del Cobre district are pre-eminent examples. We then use this record to interpret the chemistry of the various hydrothermal fluids, the role of host rocks, and the identity of potential fluid sources. This involves geochemical and simple thermodynamic interpretations of the chemical and isotopic compositions in conjunction with ancillary data from other studies. Finally, we compare the Copiapó tourmaline patterns to those of tourmalines from other hydrothermal systems with the goal of gaining better insight into the controls on tourmaline composition in various hydrothermal settings and its use for interpreting their origins.

Tourmaline-bearing hydrothermal systems near Copiapó

Geologic context Chilean Coastal Batholith and related hydrothermal systems: Northern Chile contains a spatial and temporal progression of sub-parallel belts of iron, copper, and gold-rich hydrothermal systems (Fig. 1). Within the westernmost portion of these belts, the Late Jurassic to Early Cretaceous Coastal Batholith and related volcanic rocks of northern Chile host numerous hydrothermal systems, which fall mainly along the Chilean Iron Belt and can be divided into deposits affiliated with the IOCG class (Marschik and Fontboté, 2001; Sillitoe, 2003) or deposits of the porphyry copper family (e.g., Maksaev et al., 2007). Although the abundance of tourmaline within the Chilean Iron Belt and in younger porphyry copper deposits has long been recognized (e.g., Sillitoe and Sawkins, 1971), little detailed work has been done with regard to tourmaline geochemistry and its genetic implications in this region or elsewhere. The Chilean Iron Belt occurs principally along the long-lived Atacama fault system and its various splays. Hydrothermal alteration of sodic(-calcic), potassic, and hydrolytic types is nearly ubiquitous (Barton et al., 2005: unpublished mapping). The porphyry copper hydrothermal systems are present in association with the most felsic intrusive centers (tonalite to granodiorites), whereas IOCG deposits form independently of

6 magmatic composition and occur mainly in intrusive and volcanic rocks with intermediate compositions (e.g., diorites, tonalites, andesites) and to a lesser extent in the broadly coeval clastic to carbonate sedimentary rocks of the Early Cretaceous Chañarcillo Group (Marschik and Fontboté, 2001; Williams et al., 2005). Deposits range from magnetite-rich accumulations mined solely for iron with but minor amounts of copper mineralization to those with variable but typically abundant hematite (or magnetite replacing hematite) that commonly have more abundant copper, locally present in economic quantities (Sillitoe, 2003; Williams et al., 2005). Candelaria-Punta del Cobre district: The Candelaria-Punta del Cobre district is located in the Chilean Coastal Cordillera about 20 km south of Copiapó and contains a number of deposits that are classic examples of the IOCG family (Fig. 1; Williams et al., 2005)). The Candelaria deposit has proven reserves of 368 Mt at 0.55 percent Cu, 0.11 percent Au, and 1.97 percent Ag and probable reserves of 23 Mt at 0.54 percent Cu, 0.11 percent Au, and 1.91 percent Ag (Freeport-McMoran, 2009). The combined deposits from the Punta del Cobre district contain reserves of >120 Mt at 1.5 percent Cu, 0.2 – 0.6 g/t Au, and 2 – 8 g/t Ag (Marschik and Fontboté, 2001). Smaller, vein-hosted deposits occur elsewhere in the region, the largest of which contains upwards of 10 Mt of ore with grades of >1.5 percent Cu. The Candelaria and Punta del Cobre deposits are hosted by volcanic and volcaniclastic rocks of the Punta del Cobre Formation, that underlie evaporite-bearing, carbonate-dominated sedimentary rocks of the Chañarcillo Group (Marschik and Fontboté, 2001). The deposits contain chalcopyrite, magnetite, hematite, and pyrite as the principal ore minerals, with minor sphalerite and, at Candelaria, metamorphic pyrrhotite. The andesites of the Punta del Cobre Formation are intensely potassically altered over a large region, including the areas that host the IOCG mineralization; locally, the upper parts of the Punta del Cobre Formation contain high metal grades, but ore-grade mineralization is nearly absent in the overlying Chañarcillo Group (Ryan et al., 1995). To the west of Candelaria and Punta del Cobre, the Copiapó batholith intrudes the supracrustal rocks and consists of calc-alkaline plutons that range from diorite through monzodiorite, quartz monzonite and tonalite, to granodiorite. These plutons range in age from 119 to 95 Ma and have O, Os, Pb, Nd, and Sr isotopic signatures indicative of

7 mixed mantle and crustal sources (Mathur et al., 2002; Marschik and Söllner, 2006; M.D. Barton, unpublished data). Although the plutons contain voluminous sodic(-calcic) alteration and minor IOCG vein deposits (Barton et al., 2005; Kreiner and Barton, 2009), none of these intrusions appears to be associated with the IOCG mineralization in the older rocks (e.g., not found either through mapping or exploratory drilling), nor is there any recognizable zonation of alteration or mineralization away from the batholith. In contrast, local porphyry-style mineralization is linked to particular granodioritic intrusions (Ryan et al., 1995; Barton et al., 2005). Conversely, the batholith is clearly responsible for a well-developed, 1-3 km wide metamorphic aureole that contains widespread copper-poor skarn alteration in the carbonate rocks and has deformed and overprinted the ores in the adjacent Candelaria deposit, but not in the more distal orebodies of the Punta del Cobre district (Fig. 1). Mineralization involved multiple magmatic, metamorphic, and metasomatic events, with a diverse set of structural controls and incontrovertible evidence from crosscutting relationships for discrete episodes of mineralization. Ar-Ar geochronology yields ages on silicate alteration minerals that can be broken into two groups: an older group of about 114 to 116 Ma and a younger group of 110 to 112 Ma with broadly similar Re-Os ages (115 Ma) on molybdenite from Candelaria (Mathur et al., 2002). Although Marschik and Fontboté (2001) argue that copper mineralization displays a close spatial and temporal correlation with post-magnetite, calcic amphibole alteration, magnetite is abundant and widespread throughout the deposit, and there appears to be no direct correlation between copper grades and the extent of magnetite mineralization (Ryan et al., 1995). Moreover, geologic evidence, including crosscutting relationships in dated rocks from the Punta del Cobre side of the district, indicates that at least some and perhaps much of the mineralization is of Punta del Cobre age (ca. 130 Ma) and predates the batholith (Pop et al., 2000; M.D. Barton, unpublished data). Most workers in the district have inferred a magmatic source of hydrothermal fluids based on the isotopic similarity of the ores and igneous rocks and sulfide sulfur isotopic compositions that are near zero per mil (e.g., Mathur et al., 2002). Even in these proposed magmatic systems, however, the participation of non-magmatic fluids in mineralization

8 has not been ruled out (Marschik and Söllner, 2006), and recent work has demonstrated a significant component of external, non-magmatic fluids in the ores and related alteration (Barton et al., 2005; Chiaradia et al., 2006).

Tourmaline occurrences in the Copiapó region Petrographic characterization of tourmaline in over 100 polished thin sections (out of more than 1000 available sections) has been carried out as part of a multi-disciplinary geologic and geochemical study of the region (M.D. Barton and others, in progress). The optical properties, mineral assemblages, and timing relationships were determined using standard transmitted and reflected light techniques. Tourmaline is by far the most common boron mineral in the Copiapó area, although datolite and dumortierite also occur locally (Ryan et al., 1995; Kreiner and Barton, 2009). Tourmaline occurrences are diverse and include: occurrences with pluton- and volcanic-hosted IOCG mineralization of multiple styles and with several alteration types, high-temperature veins associated with biotite(-hornblende) quartz monzodiorites, locally in the contact metamorphosed rocks, and in many areas with intensely sodicly-altered, metal-depleted rocks. With the exception of tourmaline associated with quartz-feldspar assemblages in some of the granitoids, nearly all tourmaline is quite fine-grained (<100 microns), rather massive, and, therefore, subtle in appearance. This may account for the sparse attention that it has received in earlier studies. Petrographic studies, summarized in Table 3, show that tourmaline formed during multiple stages of hydrothermal activity, as indicated by crosscutting, overgrowth, and replacement relationships. Appendix 3 contains petrologic descriptions of each sample that was analyzed chemically for major and minor elements. Tourmaline is scarce in the Candelaria deposit, perhaps because of highly alkaline conditions which may have produced some of the late datolite (Ryan et al., 1995). Conversely, tourmaline is abundant in the little metamorphosed Punta del Cobre district. Tourmaline is also found in iron-dominated IOCG occurrences, such as the Cerro Iman and Cerro Negro Norte deposits. Tourmaline occurs as euhedral columnar, granular, massive, and acicular grains (Fig. 2B) in veins (as the dominant or an accessory mineral), breccia cement, brecciated

9 clasts (Fig. 2A), and as part of alteration assemblages (Fig. 2H) in advanced argillic, potassic, sericitic, sodic, and sodic-calcic types of alteration assemblages (Fig. 2).

Characteristics of Tourmalines in the Copiapó Area Tourmaline from multiple localities within the Copiapó area were analyzed via electron microprobe and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) methods to characterize the chemical and boron isotopic compositions of tourmaline and associated minerals (see footnotes of Tables 4 and 6 for operating conditions and Appendix 1 for further details). These results are combined with petrographic data to document correlations between tourmaline occurrences, textures and optical properties, and to provide the basis for interpreting the significance of tourmaline in the district.

Tourmaline compositions Tourmaline from Copiapó varies widely in chemical composition, reflecting systematic changes associated with types of hydrothermal mineral assemblages and geologic settings. Overall, tourmalines show the greatest variation in Al, Mg, Ca, Na, Fe+2 and Fe+3 concentrations and contain insignificant K, Mn, or Cl. Representative analyses of tourmaline from each sample can be found in Table 4 (complete results are provided in the Appendix). Structural formulae were calculated on the basis of 15 cations (T + Y + Z = 15). Light-element (H, Li, B, O) contents were not determined, but boron was assumed to be stoichiometric (Grice and Ercit, 1993), and hydrogen and oxygen +3 were adjusted to meet charge balance constraints. Fe /Fetotal calculations were derived from working curves using the methods outlined by Fialin et al. (2004), which is outlined in detail in Appendix 1. Analyses of Copiapó tourmalines largely fall within the alkali compositional group defined by Hawthorne and Henry (1999) (Fig. 3). The composition of the mineral assemblage exerts the primary control on tourmaline compositions that plot outside of the alkali compositional field. Alkali-deficient tourmaline from the advanced argillic type of hydrothermal mineral assemblage contain little Ca and plot along the base of the ternary

diagram along the [Na(Mg,Fe)](□Al)-1 exchange vector (refer to Table 2 for a list of common exchange vectors). Tourmalines from calcic assemblages show a core-to-rim

10 progression from moderately sodic to calcic end members along the NaAl[Ca(Mg,Fe)]-1 exchange vector in response to increasing Ca concentration with progressive evolution of the hydrothermal system. Figure 4 shows discrimination diagrams for common tourmaline end members. Tourmaline compositions trend from alkali-free (magnesiofoitite-foitite) to dravitic compositions (Fig. 4A) or from schorl-dravite to calcic (uvite-feruvite) end members (Fig. 4). These latter compositions reflect the overall assemblage, commonly towards non-acidic compositions, with higher Fe, Mg, Na, and/or Ca. For the most part, early tourmalines trend from intermediate schorl-dravite compositions to another tourmaline compositional end member. Overall, the majority of tourmaline corresponds to the dravite-schorl solid-solution series (XMg = 0.06 – 0.98) with a dominant trend towards povondraitic compositions. Copiapó tourmalines cover the majority of known tourmaline compositions in the Al-Fe- Mg and Ca-Fe-Mg compositional diagrams of Henry and Guidotti (1985), occupying all fields except that associated with Li-rich pegmatites (Figs. 5 and 6), denoting a wide array of possible exchange vectors. Within the Al-Fe-Mg diagram, the greater proportion of tourmaline generations fall within field 6, representing Fe3+-hydrothermally altered quartz-tourmaline, calc-silicate, and metapelitic rocks. According to Henry et al. (1999), tourmaline samples that fall below the schorl (buergerite)-dravite join are Al-deficient (less than 6 apfu Al) and either Fe- or Ca-Mg-rich. In the absence of a substantial calcic component, which would result in the coupled substitution of Ca and Mg or Fe2+ for Na and Al, it can be inferred that Fe3+ is a major substituent of Al in the Z-site to maintain charge balance (Fig. 7A). The implications of this will be covered in further detail in the discussion. The elements that display the greatest variation are plotted in Figure 7 to show potential exchange vectors that may play a role in the chemical complexity of Copiapó tourmaline. For the most part, tourmaline compositions (with the exception of those from potassic assemblages) do not fall along the schorl-dravite solid-solution line (Fig. 7B).

Al-deficient tourmaline tends to plot along the CaMg(NaAl)-1 or the FeAl-1 exchange vector, whereas tourmalines with slightly more than 5.5 apfu Al appear to lie along the

□Al(NaMg)-1 exchange vector, as indicated by the negative slope in Figure 7C and the

11 increasing influence of X-site vacancies in tourmalines with greater than 5.5 apfu Al (Fig. 8). Tourmalines from sodicly and some sericitically altered rocks appear to be largely

dominated by the FeAl-1 exchange vector (Fig. 7C). Magmatic tourmalines, as well as tourmalines from sodic-calcic, potassic, and some sericitic assemblages, display a dominant negative correlation between Al and Ca, whereas sodic and advanced argillic tourmalines show no correlation (Fig. 7E). Overall, tourmalines trend from greater than 6 apfu Al to less than 6 apfu Al contents.

Petrography and assemblage data Petrographic studies suggest that tourmaline was deposited in several stages of hydrothermal alteration and is found in association with many diverse types of mineral assemblages (see Table 3). Elongate tourmaline crystals show evidence of crack-seal mechanisms for their formation, indicative of multistage development of tourmaline at the vein scale. Tourmaline compositions reflect both the host rock and fluid source characteristics and are strongly controlled by the mineral assemblage. In the following sections, tourmaline-bearing mineral assemblages are discussed especially in terms of their influence and correlation to tourmaline chemical variations. Advanced argillic assemblages: Advanced argillic alteration assemblages are stable

under extremely acidic conditions (i.e., low pH or low aK+/aH+, broadly coincident with the stability of kaolinite, pyrophyllite, or andalusite in originally K-feldspar-bearing rocks) (Seedorff et al., 2005). Tourmaline-bearing advanced argillic assemblages in the Copiapó area are both hydrous and anhydrous. Hydrous tourmaline-bearing samples contain dumortierite, pyrophyllite, hematite, calcite, andalusite, and quartz. Tourmaline is light tan to light blue-brown with Mg concentrations increasing from core to rim. The latest generation of tourmaline growth, occurring as comb-like needles on preexisting tourmaline, is more aluminous than the earlier phases (Fig. 9). Overall, these tourmalines have high F contents compared to other assemblages from the Copiapó region. It is likely that this assemblage represents a metamorphic overprint by the batholith or preexisting advanced argillic assemblages in the volcanic rocks. The two chemically and morphologically distinct generations of tourmaline represent discrete periods of growth possibly reflective of formation before and following the emplacement of the intrusion.

12 Early Fe-rich cores, possibly accompanied by other Al-rich phases such as albite, were replaced by dumortierite and pyrophyllite, a low temperature, Al-rich, Na-poor assemblages with a fine-grained, calcitic groundmass. Dumortierite and pyrophyllite are then replaced by Mg-rich tourmaline, which is common for metamorphic environments (Henry and Dutrow, 1996), and calcite is recrystallized to form equant interlocking grains. Hematite probably formed early and was replaced by magnetite during the metamorphic overprint. Late hematite after magnetite ("martite") then formed during some later event. Higher temperature, largely anhydrous, advanced argillic assemblages contain fine- grained, acicular tourmaline in association with andalusite, quartz, hematite, and minor sericite and lazulite (Fig. 2B). The presence of andalusite in these assemblages may suggest a contact metamorphic overprint. Tourmalines from these assemblages have a narrow range of XMg values (0.58 – 0.61), are highly aluminous, alkali-deficient (XNa

<0.7 apfu), and plot along the dravite-magnesiofoitite, □Al(NaMg)-1, exchange vector (Fig. 7C). Sericitic-chloritic assemblages: Sericitic-chloritic assemblages are stable is an acidic

environment, though at somewhat higher pH or higher aK+/aH+ conditions than those characteristic of advanced argillic alteration (Seedorff et al., 2005). Tourmalines present in within sericitic or chloritic assemblages range from well formed to poorly formed with corroded grain boundaries. The compositions of tourmaline in these assemblages vary greatly, trending from foitite to schorl-dravite and commonly plot along the exchange

vector Na(Mg, Fe)(□Al)-1. Tourmalines are progressively enriched in Fe, possibly indicative of an increase of host rock control on tourmaline composition. Periods of distinct growth and dissolution are particularly noticeable in tourmalines from sample C2J-124, in which both early and late tourmaline have embayed cores and inclusion edges. Any zones that are present are commonly discordant. C2J-124 appears to have at least four generations of tourmaline, with an early aluminous, vacancy-rich, light blue-gray tourmaline generation followed by brown, Mg-Fe-rich anhedral tourmaline. Well-formed tourmalines in sericitic assemblages are found in the vicinity of the San Gregorio pluton. Overall, albite phenocrysts in these rocks are intact and only display sericitic alteration in the presence of tourmaline. In this case, tourmalines trends from

13 schorl to feruvite, which is possibly correlated to the breakdown of magmatic pyroxene or amphibole. A later brown, Mg-rich schorl generation, intergrown with titanite, contains among the highest Ti concentrations in the dataset. In other samples from this area, the relationship to sericitic alteration is unclear (i.e., intact tourmaline vein with scant amounts of partially sericitized plagioclase). Sodic assemblages: Sodic assemblages form as a result of Na-enrichment of host rocks by highly saline fluids (Seedorff et al., 2005). Albite is the most common mineral associated with tourmaline in these assemblages and is the only other sodic phase. Hematite and Fe-sulfides or sulfates are the next most abundant association. Sodicly- altered rocks commonly have volcaniclastic or volcanic protoliths and are variably overprinted by breccias associated with hydrothermal alteration. Tourmaline is common, typically occurring as part of the breccia cement or in veinlets. These tourmaline are largely dravitic and commonly trend from Al-saturated to slightly Al-deficient compositions. Tourmalines that occur with specular hematite are Al-deficient and Fe- rich, commonly falling within the schorl-buergerite compositional field, and are intricately zoned, which may be indicative of a fracture-fill style of formation. Early phases are granular, Mg-rich, and contain higher F (up to 0.19 apfu) and Ti than later generations, which become progressively more Fe-rich through time. In some cases, there is no compositional continuity between different tourmaline generations, indicating distinct tourmaline-forming conditions. Moreover, the grain boundaries of the earliest generations are not embayed, showing that they were not destabilized by the later mineralizing fluid. Sodic-calcic assemblages: Sodic-calcic alteration is associated with the addition of Na ± Ca by hot (>350°C), saline fluids resulting in higher temperature assemblages than those associated with sodic alteration (Seedorff et al., 2005). Tourmalines from sodic- calcic assemblages are commonly dravitic to uvitic in composition and operate along the exchange vector CaMg(NaAl)-1. These tourmalines also tend to have higher Ti values. Epidote, titanite, actinolite, and calcite are common minerals that occur with tourmaline in these assemblages. Tourmalines are also found in association with actinolite as part of a calcic overprint on earlier, potassically altered assemblages as evidenced by abundant biotite with chlorite in mafic sites. Similarly, calcic overprints on sodic assemblages are

14 also present, with early cores of unzoned, dravitic tourmaline slightly replaced by albite and later rimmed by calcic, euhedral tourmaline. The overall increase in Fe, Mg, and Ca moving from core to rim, which is evident in all samples, implies that reacting fluids became increasingly enriched in these elements during tourmaline formation. Tourmalines occur as veins and isolated clusters. Vein tourmaline occurs in sodicly- altered rocks with albite or in calcicly-altered rocks with actinolite and/or epidote. Compositionally, vein tourmaline trends from sodic to calcic compositions and generally has sharp boundaries with included minerals. In some cases late generations of tourmaline may have reaction rims (Fig.10) and commonly have dravitic overgrowths. Tourmaline clusters are generally well formed, but may have irregular edges in the presence of epidote. Tourmalines from the aureole of the San Gregorio pluton are the most oxidized and Fe-rich samples in the dataset. These tourmalines plot along two different exchange

vectors: CaFe(NaAl)-1 (schorl-feruvite substitution) and FeAl-1 (schorl-povondraite substitution). This is readily evident in Figures 7A and 7E, where both Ca and Fe concentrations show a negative correlation with Al content. Accordingly, tourmaline compositions progress from the compositional ranges normally associated with Li-rich granites in the earliest generations to that of Fe-rich hydrothermally altered rocks in the latest generation, as shown in Figure 5. Potassic assemblages: Potassic assemblages are stable in highly alkaline environments with high aK+/aH+ ratios. Potassic alteration commonly occurs at high temperatures and is linked to magmatic-dominated fluids (Seedorff et al., 2005). The majority of drill core samples from Santos, believed to represent the intermediate levels of the hydrothermal system, are characterized by potassic alteration (biotite ± K-feldspar) with actinolite, epidote, and albite present locally (Marschik and Fontboté, 2001). Allanite can also be locally abundant. Tourmalines from this area either occur as veins, breccia clasts and cement, part of the alteration envelope, in altered clasts, or columnar crystals commonly in larger biotite grains. Breccia clasts are indicative of a history of repeated brittle deformation as well as distinct phases of tourmalinization. These Santos samples are predominantly dravitic and either trend towards more Fe-rich or Mg-rich compositions. For example, tourmalines from the deepest sample (DDH628-626.3) in the

15 dataset tend to plot mostly in the Li-poor granite field with trends towards Al- undersaturated and intermediate schorl-dravite compositions from core to rim (Fig. 5). However, this chemical progression is not systematic, given that elemental abundances fluctuate at the micron scale (Fig. 11). At higher levels in the hydrothermal system, Santos tourmalines trend from the Al-saturated and Al-undersaturated metapelitic fields towards more Fe-rich and Al-deficient compositions (Fig. 5). Although tourmalines from different depths appear to have different geneses, the compositions of their later generations overlap, suggesting a second-order control on tourmaline chemistry other than depth (e.g., interaction with wall rocks). Potassic alteration postdates sericitic alteration in some areas, as evidenced by late tourmaline-biotite veins in a sericitic matrix (i.e., sample C2B-576c). Whereas Santos tourmalines are distinctly chemically zoned, these tourmalines are light blue in transmitted light, unzoned, and largely fall within field 4 of Figure 5 associated with Al- saturated phases. Optical characteristics: The petrographic characteristics of tourmaline vary considerably, and pleochroic color and intensity do not always correlate with chemical composition. In general, tourmaline is weakly to strongly pleochroic. The pleochroic characteristics of tourmalines from each sample are summarized in Table 5. In the case of pleochroic tourmaline, strong optical absorption and pleochroism suggest that the tourmaline may contain significant amounts of Fe with mixed valences (2+ and 3+), resulting in intervalence charge transfer (Mattson and Rossman, 1987). On the other hand, tourmaline that contains monovalent iron should exhibit weak absorption. Non- pleochroic tourmaline tends to also be complexly zoned and dark in color. An interesting characteristic of some of the vein tourmaline associated with the San Gregorio pluton is their intense pleochroism and optical characteristics. Sample C2B-655 contains tourmalines that are nearly optically opaque in thin section, similar to the ferridravite (now recognized as povondraite) species identified by Walenta and Dunn (1979). These are also some of the most Fe-rich tourmalines, suggesting that optical opacity may be related to high Fe concentrations relative to Al. Although Fe2+ => Ti4+ charge-transfer has been cited as the cause for blue color in kyanite and dumortierite (Parkin et al., 1977; Platonov et al., 2000), blue tourmaline from

16 Copiapó samples have among the lowest Ti concentrations and the highest Fe values in the dataset, suggesting that Fe is the primary chromophore. Brown colors appear to correspond to Mg and Ti contents, although Ti content in the Copiapó tourmaline is highly variable. Taylor and Slack (1984) interpreted the blue to black colors associated with schorl to be dominantly influenced by Fe2+ => Fe3+ and O2- => Fe3+ charge-transfer processes, and the brown hues of dravite by uv-centered O2- => Fe2+ and Fe2+ => Ti4+ processes. Copiapó tourmalines are generally optically zoned, sometimes spectacularly, varying from concentric to highly irregular. The color change can be either gradational or display sharp optical discontinuities. Cores range from irregular (common) to euhedral with euhedral to corroded rims. Unzoned tourmalines are brown or blue. The complexity of zoning evident in thin section and backscattered-electron imaging (Fig. 12) is reflected in the compositional variation of tourmalines from even one thin section.

Summary Tourmalines formed in distinct episodes of mineralization in diverse mineral assemblages. Copiapó tourmaline is commonly pleochroic and optically and chemically zoned. The chemical variation evident in tourmaline from this area is a function of fluid composition and type of hydrothermal mineral assemblage. Tourmaline compositions operate on a variety of exchange vectors, with Fe, Mg, Al, Na, and Ca contents showing the greatest variation. Most notably, tourmalines from all types of assemblages (except advanced argillic) show a negative correlation between Fe and Al (Fig. 7A). Copiapó area tourmalines largely have sodic compositions. However, advanced argillic assemblages contain the most aluminous and alkali-deficient tourmalines in the

dataset. Calcic tourmalines (operating along the Ca(Mg,Fe)(NaAl)-1 exchange vector) are found in sodic-calcic, potassic, and some sericitic types of hydrothermal mineral assemblages. Magmatic tourmalines, however, also show a dominant negative correlation between Al and Ca. Tourmalines within sericitic types of hydrothermal mineral assemblages consist of two distinct populations: one that is aluminous and trends toward more Fe-rich compositions and another that is more calcic as the result of the breakdown of magmatic mafic minerals (i.e., pyroxene or amphibole). Sodic alteration assemblages

17 contain tourmalines that show the same trend as some sericitic assemblages, but display

more compositional scatter that is dominated by substitution along the FeAl-1 exchange vector. Tourmalines present in potassic types of alteration assemblages are the only

tourmalines to plot along the FeMg-1 exchange vector and, along with sodic-calcic tourmalines, also trend towards more Fe-rich compositions.

Boron isotopic compositions Boron isotopic analyses were accomplished via LA-ICP-MS techniques at the University of Arizona. Isotope ratios for selected coarse-grained samples and analytical methods are presented in Table 6. Given the fine-grained nature of most Copiapó area tourmaline, these results are quite selective. δ11B values range from -7.5 – +4.2 per mil, with over half of the analyses falling below -1 per mil (Fig. 13). The most positive values come from vein tourmaline in sample C2B-352e, which is considered the clearest and simplest example of magmatic tourmaline in the vicinity of the San Gregorio pluton. Thus, this would indicate a mixed boron source or equilibration of magmatic boron with the host rock, thus driving δ11B values to more positive values. Smith and Yardley (1996) found that isotopically lighter tourmaline was associated with Fe enrichment and Li enrichment in the Cornwall district. However, there is no observed correlation between elemental abundances and isotopic composition in the Copiapó tourmaline, nor is there any correlation between δ11B values and tourmaline morphology or sample locality. Overall, there appears to be variations in isotope compositions where no chemical zoning is evident. The variation from magmatic to more positive values is indicative of the influx of a source with a positive signature. Potential sources will be covered in further detail in the discussion.

Controls on Tourmaline Compositions Tourmaline compositions reflect the host rock and hydrothermal fluid compositions with progressive evolution of the hydrothermal system, as well as differences in temperature and pressure of formation. This compositional record provides insight into mineralizing conditions, fluid flow, and possible sources of constituents in hydrothermal systems. Although tourmaline has a wide range of stability, it is strongly controlled by the composition of the mineralizing fluid and associated mineral assemblage.

18 Tourmaline stability Stability of tourmaline end-members: Tourmaline is stable over a broad range of pressure and temperature conditions (Henry and Dutrow, 1996); however, the composition of tourmaline solid solutions should be governed by the coexisting mineral assemblages and fluid compositions. Here we use chemographic techniques combined with available thermodynamic data to evaluate the effect of independent compositional variables on tourmaline compositions Thermodynamic data for minerals and aqueous species from the SUPCRT92 database (Johnson et al., 1992) were used to create a chemical potential diagrams for several projections within the system Na2O – B2O3 – Al2O3 – MgO – CaO – SiO2 – HCl – H2O at 400°C and 500 bars. Tourmaline, quartz, and an aluminum mineral are considered to be saturated throughout each activity diagram. The fugacity of oxygen is defined by magnetite-hematite. Comparing modeled and measured tourmaline compositions provides information on the conditions prevailing in its host environment. Tourmaline stabilities for magnesiofoitite – dravite and dravite – uvite end members are plotted in Figure 14. In highly acidic environments, magnesiofoitite predominates over dravite. Dravite is stable in environments with high Na and Mg activities, whereas uvite stability appears to be constrained to lower Mg and higher Ca activities. Stability of tourmaline: Tourmaline has a wide range of stability from low to high temperatures and pressures (<150°C to >700°C and 1 bar to >10 kbars) but is strongly influenced by the composition of the fluid phase and mineral assemblage (Henry and Dutrow, 1996). The solubility of aluminosilicate phases and components (e.g., Al) in borate fluids increases with increasing fluid alkalinity and may be indicative of changing speciation mechanisms in solution as a function of pH (Morgan and London, 1989). Thus, minerals containing relatively large amounts of alkalis that react with water to produce alkaline solutions inhibit tourmaline growth, as tourmaline formation is favored in strongly to weakly acidic fluids (Frondel and Collette, 1957; Morgan and London, 1989). Moreover, the minimum aqueous boron necessary to stabilize tourmaline increases with increasing temperature and pH. Above pH 6.5, no level of boron can stabilize

19 tourmaline and another boron-bearing phase forms. This would explain the absence of authigenic tourmaline in most evaporitic deposits (Henry and Dutrow, 1996).

The activity of Al2O3 or equivalent aqueous species also contributes to tourmaline stability and formation, which are favored in acidic fluids with high availability of Al species. However, since Al transport is facilitated by alkali borate species, such as

Na2B4O7, a mixture of acidic and alkaline boron compounds is essential to provide the necessary Al for tourmaline-forming reactions (Morgan and London, 1989). Oxygen fugacity (fO2) is another important constraint on tourmaline stability (Morgan and London, 1989). Irregular distributions of tourmaline could reflect limited boron and water

availability, variable fO2, and restricted mobility of mafic cations (e.g., Fe and Mg) necessary for tourmaline formation (Gawęda et al., 2002). Stability of tourmaline relative to other boron-bearing minerals: Tourmaline is the most common borosilicate in geologic environments. In highly alkaline and/or silica- or aluminum-undersaturated conditions, however, tourmaline growth is inhibited and other borosilicates form instead (Grew, 1996). High Ca concentrations, or high Ca/Al ratios, may not be favorable for the formation of tourmaline, and boron may be distributed in other species, such as danburite, serendibite, and axinite, to name a few (Frondel and

Collette, 1957). Like tourmaline, danburite (CaB2Si2O8) is preferentially stable in acidic fluids (Morgan and London, 1989). In highly acidic environments, dumortierite occurs over tourmaline due to the lack of alkalis, Fe, and Mg necessary for tourmaline formation (Taner and Martin, 1993). However, water is a key component for dumortierite formation (Werding and Schreyer, 1990). Tourmaline that does occur with dumortierite tends to be alkali-deficient, with some proportion of Na, and Al-rich, commonly with tetrahedral Al (Foit et al., 1989). Other borosilicates, such as serendibite, commonly form in calcic, silica-undersaturated conditions, and tourmaline that forms in these settings are typically uvitic (Grew, 1996).

Major-element variation Copiapó tourmalines are compositionally complex and formed in multiple generations. Most of the compositional variability observed in these tourmalines involves Al and Fe with lesser involvement of Mg and the alkalis. This could reflect the changing

20 nature of the mineralizing fluid as it interacts with the host rock, becoming increasingly oxidized and Fe-rich. Zoning: Tourmaline chemical composition readily responds to changes in its chemical environment. According to several authors (e.g., Taylor and Slack, 1984; Dutrow et al., 1999; Henry and Dutrow, 1996), a large, external influx of boron is commonly accompanied by the generation of considerable amounts of unzoned, weakly zoned, oscillatory zoned, and/or complexly zoned tourmaline. The fine, oscillating chemical zoning of a wide range of cations of varying charge and density recorded in tourmaline suggests that cation diffusion in tourmaline is slow (Palmer et al., 1992). Zoning in Copiapó tourmaline ranges from concentric to discordant. The complexity of zoning present in most tourmaline is indicative of open-system behavior, with possible fluctuations in chemistry, pressure, and temperature. This is demonstrated by periods of distinct growth followed by dissolution and replacement by tourmaline with a different composition, as well as fine-scale zonation, which is indicative of rapid growth in a changing chemical environment (London and Manning, 1995). Dissolution can occur as a result of changing conditions and can be recognized by discordant zoning patterns with truncated compositional zones. Alkali variation: Alkali-deficient compositions can be obtained through the exchange

vector □Al[Na(Mg,Fe)]-1. These tourmalines are associated with alkali-deficient, highly acid, low-temperature environments (Rosenberg and Foit, 1979). Early, Al-rich cores reflect growth in Al-rich, highly oxidized, but alkali-poor environments. The formation of strongly Na-deficient tourmaline requires, for any given temperature, a very low concentration of Na in the fluid, and it is unlikely that this Na-poor phase is in equilibrium with other sodic phases such as albite. Metamorphic and synthesized tourmalines have shown an increase in Na with increasing temperature (Henry and Dutrow, 1996; von Goerne et al., 2001). Although such generalizations can be made, it is essential to compare tourmaline composition to the mineral assemblage, as Na content depends on several parameters (von Goerne et al., 2001). Overall, later generations of tourmaline have higher alkali (Na and Ca) contents that are commonly reflective of the

alteration mineral assemblages. The alkali-defect exchange vector, □Al[Na(Mg,Fe)]-1, accounts for the chemical difference observed in most cores.

21 Fe variation: Tourmaline compositions from various localities generally trend toward or fall within the Fe-rich hydrothermally altered rocks domain in the Al-Fe-Mg diagram of Henry and Guidotti (1985), suggesting an important host rock control of volcaniclastic and andesitic rocks. Tourmalines associated with metapelites and metavolcanic terranes tend to have intermediate schorl-dravite compositions, similar to the early generations of Copiapó tourmaline. However, there is no consistent correlation between the Fe/(Fe+Mg) ratio of tourmaline and a particular mineral assemblage (Power, 1968; Taylor and Slack, 1984). A remarkable feature noted in the majority of tourmalines from the Copiapó region is the inverse relationship between total Fe and Al. In other studies, the transition from Al- rich to Fe-rich compositions has been linked to increasing distance from a magmatic source coincident with decreasing temperature and increasing differentiation of late magmatic fluids (Caverretta and Puxeddu, 1990) or from the breakdown of another Fe- bearing phase. Whitney et al. (1995) also found that Fe contents tend to increase with increasing salinity in sulfur-free systems. Decreasing Al content in tourmaline can be

linked to feruvite-uvite substitution, CaMg(NaAl)-1, and/or povondraite substitution,

FeAl-1 (Bačík et al., 2008). However, subsequent decreases below 5.0 apfu Al necessitate 3+ the substitution of Fe for Al. There is a clear FeAl-1 substitution trend in Copiapó 3+ tourmalines that is indicative of a povondraitic component. An increase in the Fe /Fetotal ratio may reflect the primary oxygen fugacity of the tourmaline-forming fluid, decreased Al activity, and/or higher overall Fe either from the fluid or increased fluid interaction with the host rock (i.e., Fe/(Fe+Mg) ratio of tourmaline reflects that of the bulk rock with progressive alteration; London and Manning, 1995; Gawęda et al., 2002). Galbraith et al. (2009) noted that the greater the fluid to rock ratio, the greater the evidence for hybridization of the source fluid and country rock compositions. As Fe is effectively transported as chloride complexes in hot, relatively acidic and saline solutions, this would also suggest that later evaporitic fluids were more effective at leaching Fe from the host rock.

22 Geologic controls The abundance of tourmaline in the Copiapó area is indicative of acidic, boron- bearing hydrothermal fluids. The diversity of tourmaline compositions is a function of both host rock composition, reflected in later tourmaline generations, and the composition of the original fluid, which appears to have higher Al concentrations and lower overall alkali and FeMg contents. It also appears that these hydrothermal fluids became increasingly oxidized, as reflected by the increase in Fe3+ in later tourmaline generations. The lack of significant amounts of other borosilicates indicates acidic fluids with high Al activities and sufficient ferromagnesian components to create tourmaline. The extensive sodic(-calcic) and potassic alteration in the Copiapó area suggests that alkalis are not a limiting factor; therefore, conditions for tourmaline formation would necessitate a driver towards more acidic compositions. An evaporitic source would provide the chloride ligands necessary for metal transport as well as the Na evident in hydrothermal alteration, while driving the fluids towards oxidized, relatively S-poor conditions (Barton and Johnson, 1996). The δ11B values in tourmaline, as with other compositional studies of fluid compositions in the Candelaria-Punta del Cobre deposits, suggest a mixed fluid source, suggesting both magmatic and sedimentary influences. Further evidence of highly-saline, oxidized fluids: Several interesting minerals indicative of highly saline solutions are scattered throughout the tourmaline-bearing Copiapó samples. Tourmalines from samples C2J-124 and C7B-003a, associated with sericitic and advanced argillic assemblages, respectively, contain inclusions of hypogene anhydrite 10s of microns across. These anhydrite crystals are not present within the matrix or in any other minerals. Sample C2B-808.2 from the San Gregorio pluton contains chloro-potassichastingsite, a relatively uncommon Cl-rich amphibole (in this example containing over 5 wt percent Cl) that is indicative of alkali-chloride metasomatism (Mazdab, 2003). This mineral appears to be selectively replacing an early Al-, Fe-rich, blue tourmaline and may be coincident in time with the formation of Mg-, Ti-rich tourmaline within the same sample. In the Santos mine, marialitic scapolite is also present in association with tourmaline at depth, although it appears to postdate it. This scapolite end-member forms at temperatures around 400°C and is only stable in fluids that contain greater than 40 mol percent NaCl (Vanko and Bishop, 1982).

23 Comparison with other tourmaline-bearing hydrothermal systems Copiapó tourmaline compositions are compared to other occurrences from IOCG and other economic deposits, as well as to sediment-dominated systems, to establish any common crystal-chemical characteristics. Tourmaline compositions that plot along the “oxydravite”(a hypothetical sodic variation of magnesiofoitite)-povondraite solid- solution line defined by Henry et al. (2008) are considered a consequence of tourmaline formation in an oxidizing environment, possibly in the presence of high salinity aqueous fluids with reduced H2O activities (Henry et al., 2008). Povondraite is indicative of high oxygen fugacity during crystallization (Žáček et al., 1998), and the correlation to highly saline fluids may reflect more effective leaching and transport of elements from host lithologies (Henry et al., 2008). Magmatic-hydrothermal systems (Cu-Mo, Sn-W systems): Tourmaline compositions in porphyry and other magmatic-hydrothermal ore deposits may contain substantial Fe3+- rich and uvitic components (Fig. 15A). The existence of Fe3+-rich hydrothermal tourmalines in the majority of granitoid-related Cu–Mo–Au deposits suggests formation under relatively oxidizing conditions, in contrast to tourmalines from Sn–W deposits which formed under more reducing conditions and lack significant ferric iron (Slack, 1996). In most porphyry Cu-Mo systems, tourmaline compositions range from Mg-rich to Fe-rich, and mineralization is associated with calc-alkaline to moderately felsic rocks. In rare cases, vein tourmaline associated with Sn mineralization appears to follow the povondraite-dravite trend as well. These tourmalines are found in mafic to ultramafic host rocks and thus have higher Fe contents (Mao, 1995). IOCG and similar systems: Tourmalines from the Larderello geothermal field in Italy are similarly Fe-rich (Cavaretta and Puxxedu, 1990). As expected, IOCG-related tourmaline show the same enrichment in Fe as Copiapó tourmaline (Fig. 15B). Out of all the IOCG deposits in the Carajás district, the Igarapé Bahia tourmalines appear to be the most chemically similar to the Copiapó tourmaline. IOCG mineralization is best developed in the breccias that lie between the mafic metavolcanic and metapyroclastic/metasedimentary units. Tourmalines from this locality are commonly Fe- rich dravites (Galarza et al., 2008). Boron isotopic work carried out by Xavier et al. (2008) points towards an evaporitic origin for these tourmalines, as reflected by high δ11B

24 values. Tourmaline boron isotope results from the Yerington and Humboldt IOCG deposits in Nevada also show evidence of external, non-magmatic fluid sources for mineralization, with average values ranging from -0.1 to +6.1 per mil (F.K. Mazdab, M.D. Barton, and R.L. Hervig, unpublished data) (Fig. 13) Metamorphic hydrothermal deposits: Tourmalines from various mesothermal Au- quartz deposits display intermediate schorl-dravite to dravitic compositions (Fig. 15C) and appear to be geochemically similar to non-hydrothermal, metamorphic tourmaline. The composition of these tourmalines reflects both the chemistry of the mineralizing fluid and the composition of the host rock. Metamorphic hydrothermal tourmaline is most similar to early, Al-saturated generations of Copiapó tourmaline and do not show the same “oyxdravite”-povondraite trend. Stratabound deposits: Stratabound tourmalines, associated with massive sulfide and other deposits, are commonly dravitic in composition (Slack, 1982) (Fig. 15D). The compositional variation in these tourmalines is linked to the proportions of hydrothermal fluids and seawater, the water/rock ratio of the system, and the composition of the host rock (Slack, 1996). In non-massive sulfide deposits, Mg-rich tourmalines are believed to have formed through the circulation of a seawater component or a Mg-rich evaporitic brine. Tourmalines from all of these environments commonly plot along the schorl- dravite solid-solution and only rarely show the Fe-enrichment evident in Copiapó tourmaline. Sediment-dominated systems: Similarly Fe-rich tourmalines are also found in the Challenger Dome in the Gulf of Mexico (Henry et al., 1999) and in metamorphosed evaporites (Žáček et al., 1998; Henry et al., 2008) (Fig. 15E). Tourmalines associated with meta-evaporites are commonly sodic, magnesian, moderately to highly depleted in Al, and enriched in Fe3+. These tourmalines typically fall along the “oxydravite”- povondraite join. Peng and Palmer (2002) found that although tourmalines may not be directly related to meta-evaporites, they may still exhibit an isotopic and fluid influence from meta-evaporitic sources. Tourmaline compositions that deviate from this trend likely reflect other superimposed reactions and a probable influx of reactive fluids. Tourmalines associated with the Barberton Greenstone in South Africa are very Al-enriched, even though they

25 are found in association with volcanics and evaporites, suggesting that the mineralizing fluid was far more aluminous than other evaporite-related areas (Byerly and Palmer, 1991). Notably, the Mg-rich tourmalines from the Fowler talc belt, New York (Ayuso and Brown, 1984), display similar characteristics to the distinctive early Mg-rich, Al-deficient generation in a sodic alteration assemblage observed in the Al-Fe-Mg ternary diagram and fall in field 8 of Figure 5, which is associated with metacarbonate or metapyroxenoid hosts. Ayuso and Brown (1984) hold that these tourmalines formed in specialized environments associated with evaporites, consequently having a profound effect on the bulk composition. Moreover, tourmalines from this locality also have heavy δ11B values (+13 ‰)

Origin of boron isotope systematics Boron is highly mobile and easily leached and redistributed, especially under alkaline pH conditions (Dutrow et al., 1999). Tourmaline clearly shows a close relationship with certain distinct types of geologic settings, including quartz monzodiorites, IOCG deposits, and sodicly altered rocks but is not present or rare in other types of rocks and mineral deposits (e.g., porphyries, diorites, and some vein type IOCG occurrences). Although boron may be present in the latter settings, other conditions such as high alkalinity may have inhibited tourmaline formation (Morgan and London, 1989). In general, boron isotopic data show no correlation between mineral formation temperature, major-element composition, mineral assemblage, or age of deposit (Palmer and Slack, 1989; Swihart and Moore, 1989). Moreover, the mechanical and chemical stability of tourmaline prevents significant boron isotope fractionation, preserving its boron isotopic signature through time (Slack et al., 1989). However, boron isotope

systematics are sensitive to pH, as it determines the relative abundance of B(OH)3 and

B(OH)4 complexes in solution, and to the lithologic setting (Palmer and Slack, 1989). The dominant control on δ11B values in tourmalines is the composition of the boron source (Slack et al., 1989). As 10B is preferentially incorporated into the solid phase during fluid-solid interactions, tourmaline δ11B values are systematically lower than the liquid from which it forms and are minimum estimates of the actual fluid composition

26 (Slack et al., 1989). Fractionation experiments predict a 5 per mil to 8 per mil difference between the mineralizing fluid and tourmaline (Palmer et al., 1992). As previously mentioned, the results of the boron isotopic work are biased towards coarse-grained tourmaline because of analytical constraints and thus may not reflect the complete picture of boron isotope variation in this district. The range of δ11B values of Copiapó tourmaline from -7.5 to +4.2 per mil overlaps a number of geological environments including granites, volcanics, metasediments, and non-marine evaporites. It is highly possible that the boron involved in tourmaline formation came from a mixture of these sources and maybe others that have more positive or negative δ11B values (see Fig. 13). Lighter δ11B values can be attained through mixing with a lighter source, such as granitic and volcanic host rocks, or through the loss of 11B due to vapor phase separation (Smith and Yardley, 1996), whereas heavier values commonly necessitate a marine influence. Notably, all of the potential boron sources are present in the Copiapó region, underscoring the fact that data from even the best isotopic tracers require careful interpretation and commonly have non-unique interpretations. Fluid inclusion studies on quartz and ore minerals also support a mixed source for the origin of mineralizing fluids. The initial Sr isotope compositions of the fluid inclusions found in Candelaria are notably more radiogenic than the magmatic host rock, thus providing evidence for a non-magmatic source of Sr (Barton et al., 2005; Chiaradia et al., 2006). Cl isotopic work further indicates that the ore-forming fluid is a mixture of magmatic mantle-derived fluids (low radiogenic Sr and 37Cl-rich) with a radiogenic Sr- rich and 37Cl-poor crustal source such as a basinal brine (Chiaradia et al., 2006). Chiaradia et al. (2006) suggest that the magmatic fluids mixed with basinal brines or leached evaporites after exsolution from the magma, necessitating a mixed source model for the development of these deposits. These results could also be applied to the tourmaline boron isotope results, where the range from magmatic composition to more positive values may coincide with the influx of a non-marine brine.

Conclusions Tourmalines provide a distinctive record of compositional variation in hydrothermal systems due to its wide range of stability and chemical variability. Tourmaline chemistry

27 can be used to provide a clearer understanding of ore-forming processes, related depositional environments, and the location of prospective exploration targets. Compositions of tourmalines from Copiapó reflect formation in oxidizing, acidic, highly saline environments and compositional trends toward Fe-rich compositions that reflect the compositions of the host lithologies. These results are consistent with relatively oxidized fluids that varied in composition through time, suggesting that tourmaline compositions distinguish different hydrothermal environments, even in the same area. The trend of tourmalines from Copiapó towards povondraitic compositions and their similarity to tourmalines from evaporitic sources attest to the highly saline and oxidizing nature of the mineralizing fluid. As reflected in δ11B values in Copiapó tourmaline, the boron necessary for tourmaline formation appears to have a mixed signature, with both evaporitic and magmatic fluid sources, an interpretation that is consistent with previous fluid inclusion studies in this area. This study is part of an ongoing study of IOCG mineralization in the Copiapó area and additional research may further constrain the enigmatic origin(s) of these deposits.

Acknowledgments This study and associated field work has been financially supported by National Science Foundation (NSF) grant EAR08-38157, an NSF Graduate Student Research Fellowship, Science Foundation Arizona, and Freeport-McMoRan Inc. We would like to thank Ken Domanik for technical assistance with electron microprobe analyses and Mark Baker for his help creating an analytical method for boron isotope work on the isoprobe. Thanks also go to Doug Kreiner for providing some of the samples for this study, to David Cooke for tourmaline compositional data from the Río Blanco Cu-Mo deposit in Chile, and to Eric Seedorff and Bob Downs for their reviews of this manuscript.

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36 Figure Captions Fig. 1. Regional geologic map showing the volcanic and sedimentary sequences intruded to the west by the Cretaceous Copiapó batholith (from Barton et al., 2005, modified from Arévalo, 1999).

Fig. 2. Photomicrographs in plane polarized light of various tourmaline textures and mineral assemblages from the Copiapó region. A. DDH643-430.2 (Santos). Tourmaline clast with magnetite in a chlorite matrix surrounded by quartz. Tourmaline is intermediate schorl-dravite in composition. B. C6B-160b (Vinita Azul). Advanced argillic assemblage with acicular, foititic tourmaline, quartz, hematite, and andalusite. See text for further discussion. C. DDH289-037.5 (Santos). Potassic assemblage with dravitic tourmaline, biotite, magnetite, and quartz. D. C2B-808.2 (San Gregorio S Granate). Fe-rich, blue tourmaline cluster with chloro-potassic-hastingsite replacing the bottom part of the tourmaline cluster. The host is coarse-grained albite. E. C2J-124 (Cerro Buitre Radio Tower). Sericitic assemblage with tourmaline, quartz, sericite, and zircon. Early violet gray, Al-rich tourmaline generation is rimmed by light brown tourmaline that is Na- and Mg-rich. F. C3B-429.5 (Ojancos Viejo) Sodic assemblage with strongly zoned tourmaline, albite, limonite after pyrite, and fine-grained, indeterminable Al ± Fe sulfate. G. C6B-101b (Falla Ojancos Transito San Francisco). Granular, dravitic tourmaline intergrown with albite. H. C2J-334 (Cerro Buitre Radio Tower). Calcic assemblage with uvitic tourmaline and actinolite overprinting earlier potassic alteration (bioitite). Abbreviations represent: Act = actinolite, Alb = albite, And = andalusite, Bt = biotite, CPH = chloro-potassic-hastingsite, Hem = hematite, Mt = magnetite, Qtz = Quartz, SS = sheet silicate, Tour = tourmaline.

Fig. 3. Alkali classification diagram after Hawthorne and Henry (1999). Analyses of tourmalines from various localities within the Copiapó district are plotted based on alteration assemblage type. The majority of tourmaline compositions fall within the alkali compositional group. Tourmalines from advanced argillic assemblages trend towards vacancy-rich compositions, whereas tourmalines of magmatic origin or in calcic assemblages trend towards more Ca-rich compositions.

Fig. 4. Discrimination diagrams for naming tourmaline species, with analyses of tourmalines from the Copiapó district plotted according to type of alteration assemblage. A. Sodic and vacancy-rich end members. This discrimination diagram shows solid solutions between Na- and vacancy-rich end members with varying Mg/(Mg+Fe). B. Sodic and calcic end members. This discrimination diagram shows solid solutions between Na- and Ca-rich end members with varying Mg/(Mg+Fe).

Fig. 5. Al-Fe-Mg compositional diagram of Henry and Guidotti (1985) with Copiapó tourmaline analyses plotted based on alteration assemblage type. Common end members are plotted for reference. Each field delineates various tourmaline-bearing rock types. Copiapó tourmalines cover the range of known tourmaline compositions outside of pegmatitic environments. The numbers correspond to distinct rock types: (1) Li-rich granitoid pegmatites and aplites; (2) Li-poor granitoids and their associated pegmatites and aplites; (3) Fe3+-rich quartz-tourmaline rocks (hydrothermally altered granites); (4)

37 Metapelites and metapsammites coexisting with an Al-saturating phase; (5) Metapelites and metapsammites not coexisting with an Al-saturating phase; (6) Fe3+-rich quartz- tourmaline rocks, calc-silicate rocks, and metapelites; (7) Low-Ca metaultramafics and Cr-, V-rich metasediments; and (8) Metacarbonates and meta-pyroxenites.

Fig. 6. Ca-Fe-Mg compositional diagram of Henry and Guidotti (1985) with Copiapó tourmaline analyses. Common end members are plotted for reference. Each field delineates distinct tourmaline-bearing rock types. The majority of tourmaline analyses falls within field 4. The numbered fields correspond to: (1) Li-rich granitoid pegmatites and aplites; (2) Li-poor granitoids and their associated pegmatites and aplites; (3) Ca-rich metapelites, metapsammites, and calc-silicate rocks; (4) Ca-poor metapelites, metapsammites, and quartz-tourmaline rocks; (5) metacarbonates; (6) metaultramafics.

Fig. 7. Potential exchange vectors. These figures denote the complexity of tourmaline compositional trends in this area. As discussed in the text, Copiapó tourmalines are largely Al-deficient, indicating formation in Al-undersaturated conditions. A. Al vs. Fetot. Note the negative correlation between Fe and Al. B. Mg vs. Fe graph. The bold line on the graph indicates the FeMg-1 exchange vector. As is apparent from this graph, the majority of tourmaline compositions do not fall along the schorl-dravite solid-solution line. Only tourmalines from potassic assemblages show any correlation. C. Al vs. Na graph. Tourmalines from sodic-calcic and some sericitic assemblages plot along the NaAl(CaMg)-1 exchange vector, whereas tourmaline with greater than 6 apfu Al plot along the NaMg(□Al)-1 exchange vector. Tourmalines from sodicly and some sericitically altered rocks appear to be largely dominated by the FeAl-1 exchange vector. D. Al+Ca vs Fe graph after Henry et al. (2008). This graph reinforces the negative correlation between Al and Fe along the exchange vector FeAl-1. E. Al vs Ca graph. There is a dominant negative correlation between Al and Ca for magmatic tourmaline, as well as for tourmaline from sodic-calcic, potassic, and some sericitic assemblages. Sodic and advanced argillic tourmalines show no correlation. F. X-site-vacancy vs. Ca graph. There is little correlation between X-site vacancies and overall Ca content.

Fig. 8. Al vs X-site vacancy graph showing that X-site vacancies only begin to take a role in tourmaline chemical variations at Al contents greater than 5.5 apfu.

Fig. 9. Photomicrograph in plane-polarized light of various stages of tourmaline growth in hydrous advanced argillic assemblage (sample C7B-003a from Jesus Maria). The tourmaline core tends to be Mg-rich compared to the later comb-like overgrowth that is more aluminous. Mineral abbreviations: Cal = calcite, Mar = hematite after magnetite (“martite”), Tour = tourmaline.

Fig. 10. Backscattered electron image of a complexly zoned tourmaline sample from San Gregorio (sample C2B-655). This tourmaline shows an early, embayed and slightly fractured, Fe-rich generation overgrown by an aluminous rim that is later replaced by a complexly zoned reaction rim with numerous inclusions. Mineral abbreviations: Cal = calcite, Mt = magnetite, Tour = tourmaline.

38 Fig. 11. Backscattered electron image and X-ray maps for Mg, Na, Fe, Ca, and Ti of tourmaline in Santos sample DDH628-626.3, showing micron-scale chemical variations and coalescence phenomena (subrounded cores overgrown by sub- to euhedral rims) (Pesquera et al., 2005), most evident in the Ca X-ray map. Numbers on the lower left hand corner of each X-ray map represents the approximate range of values for each element in the tourmaline cluster.

Fig. 12. Backscattered electron image and X-ray maps of a complexly zoned, blue tourmaline (sample C2B-808.2 from San Gregorio). Numbers on the lower left hand corner of each X-ray map represents the approximate range of values for each element in the tourmaline cluster. In general, early, Mg-rich tourmalines are overgrown by more aluminous, Ca-deficient, and slightly more Fe-rich compositions, which is consistent with the later superposition of sericitic alteration on an earlier igneous (roughly potassic) assemblage.

Fig. 13. Histograms of δ11B values of tourmaline from Copiapó and other mineralized locations along with δ11B values of different geological environments. A. Histogram with the δ11B values of select samples of Copiapó tourmaline. Error bar indicates an uncertainty of ± 2 per mil. B. Histogram of unpublished boron isotope data of F. Mazdab, M. Barton, and R. Hervig. This dataset contains boron isotope data from IOCG deposits (Cloncurry district, Cortez Mountains, El Romeral, Humboldt, Yerington), sodicly altered rocks (Ajo, Superior-Engels, Granite Mountain), and porphyry-style occurrences (i.e., Cananea, Copper Creek, Nacozari de Garcia, Zaaiplaats), as well as miscellaneous tourmaline occurrences in kyanite ore (Cargo Muchacho-Vitrefax Hill) and sedimentary rocks (Belt Supergroup, Boyer Ranch). The standard deviation is about ±1.1 per mil. C. Compilation of δ11B values for different geological environments modified from Palmer and Swihart (1996). The gray box indicates the range of values covered by Copiapó tourmaline.

Fig. 14. Mineral phase diagrams showing the topology of magnesiofoitite-dravite and dravite-uvite solid solution reactions at 400 ºC and 500 bars. These diagrams assume quartz and water saturation, with tourmaline stable throughout. Al is treated as an immobile element. Thermodynamic data was acquired using the SUPCRT92 program of Johnson et al. (1992). A representative reaction between tourmaline end members in the albite field is presented as an example of the effect of increasing log(K) (i.e., activity ratios of key tourmaline end members). The blue line represents the topology of pure end-member reactions between tourmaline end members. The green line represents an increase in log(K) by one log unit, and the orange line represents a decrease by one log unit. A. Magnesiofoitite to dravite reaction. This reaction is not dependent on the fugacity of oxygen. Na content increases to the right and Mg increases to the top. The stability fields move up and to the right with increasing dravite activity and down and to the left with increasing magnesiofoitite coincident with increasing acidity. B. Dravite to uvite reaction. The line on this diagram represents the topology of pure end-member reactions between dravite and uvite. Log(Ca/H2) is held constant at 2. The stability fields move up and to the left with increasing dravite activity and down and to the left with increasing

39 uvite activity. Mineral abbreviations: Alb = albite, Dr = dravite, MgF = magnesiofoitite, Qtz = quartz, Uv = uvite.

Fig. 15. Al-Fe75-Mg75 diagrams after Henry et al. (2008) comparing Copiapó tourmaline to tourmaline from other hydrothermal systems, both mineralized and otherwise. Tourmalines from other IOCG, Cu-Mo, and sediment-dominated systems appear to show similar chemical variations to Copiapó tourmaline. A. Magmatic hydrothermal systems. References: Au (green): Koval et al. (1991), Golani et al. (2002); Cu-Mo (purple): Koval et al. (1991), Lynch and Ortega (1997), Frikken (2003), Yavuz et al. (1999); Pb-Zn-Cu (pink): Yavuz et al. (2008); Sn (blue): Mao (1995); Sn-Cu (red): London and Manning (1995), Mlynarczyk and Williams-Jones (2006); Sn-W (light blue): Pirajno and Smithies (1992); W (yellow): Clarke et al. (1989); Hydrothermal breccias and veins (peach): Dini et al. (2008), Demirel et al. (2009); Yavuz et al. (2008). B. Tourmaline from IOCG and related systems. Purple: Cavarretta and Puxeddu (1990); Yellow: Frietsch et al (1997); Orange: Xavier et al. (2008). C. Metamorphic tourmaline associated with Au-quartz veins. Brown: Garda et al. (2009); Blue: King and Kerrich (1989). D. Stratabound tourmaline occurrences. Green: Jiang et al. (1995); Red: Jiang et al. (1997b); Light blue: Mao (1995); Yellow: Plimer (1986); Orange: Plimer and Lees (1988); Purple: Raith (1988); Pink: Slack and Coad (1989); Blue: Taylor and Slack (1984). Abbreviations: MSD = massive sulfide deposits (includes both SEDEX and VMS deposits), SEDEX = sedimentary exhalative, VMS = volcanogenic massive sulfide. E. Sedimentary (evaporite-related) tourmaline occurrences. Dark red: Ayuso and Brown (1984). This tourmaline is found in a Fowler talc belt in New York and is unusually Mn rich. Light blue: Bačík et al. (2008). Tourmalines from this study are reworked tourmalinites now in conglomerates with carbonates and clastic sedimentary rocks with subordinate volcanics. Late tourmaline contains ferric iron and is Al-deficient. Purple: Henry et al. (1999). This tourmaline was found in the cap rock of a salt dome and is believed to have formed diagenetically within the bedded salt sequence that ultimately formed diapirs. Red: Henry et al. (2008). These tourmalines are found in meta-evaporite, non-marine sequences in Namibia and are moderately to highly deficient in Al and enriched in ferric iron. Green: Jiang et al. (1997a). Tourmalines from this study are found in meta-evaporite sequences in association with borate deposits. There is evidence for both non-marine and marine influences on the chemistry of the Houxianyu borate deposit, China. Blue: Peng and Palmer (2002). Tourmaline is found in meta-evaporite sequences enclosed by volcanic tuffs. Orange: Žáček et al. (1998). Tourmaline occurs in the meta-evaporite Locotol Breccia. Along with other silicate minerals, tourmaline formed along the reaction rim between dikes of highly alkaline volcanic rocks and B-rich evaporites. F. Copiapó tourmaline. Note how tourmaline from this area covers a wide range of compositions and displays the same compositional trends as tourmalines from highly saline environments.

Tables Table 1. Tourmaline end members after Hawthorne and Henry (1999) Table 2. Exchange vectors after Henry and Guidotti (1985) and Dutrow and Henry (2000) Table 3. Tourmaline-bearing mineral assemblages

40 Table 4. Representative tourmaline analyses of Copiapó samples Table 5. Pleochroic characteristics of and zoning in Copiapó tourmaline Table 6. Boron isotope results of Copiapó tourmaline

41 Figure 1 Figure 2 A Tour B Tour

Chl Hem And Mt

Qtz

100 μm 100 μm C D

Qtz

Tour Mt Alb Tour Bt 100 μm CPH 100 μm E F

Tour

Lim

Tour Alb

Tour Qtz

100 μm AFS 100 μm G H Bt

Alb

Alb Tour Tour Act

100 μm 100 μm Figure 3 Figure 4A Figure 4B Figure 5 Figure 6 Figure 7A Figure 7B Figure 7C Figure 7D Figure 7E Figure 7F Figure 8 Figure 9

Tour Cal

Mar

Tour

100 μm Figure 10

Tour

Tour 100 μm Cal

Figure 11

BSE Mg

20 μm 1.78 – 3.60 wt% High Na Fe

Low 0.94 – 1.55 wt% 7.78 – 10.84 wt% Ca Ti

0.41 - 0.85 wt% 0.01 - 0.21 wt%

Figure 12

BSE Al

High

200 μm 12.79 - 16.64 wt% Mg Fe

Low

0.43 – 2.86 wt% 11.60 – 19.05 wt% Na Ca

1.02 – 1.63 wt% 0.44 – 1.80 wt% Figure 13

B A

marine brines non-marine brine C seawater marine evaporites non-marine evaporites limestones and dolomites magmatic fresh island arc volcanics granite and rhyolite fresh mantle-derived rocks -40 -20 0 +20 +40 +60 δ11B‰ Figure 14A Magnesiofoitite to Dravite 5 400°C, 500 bars Chlorite Qtz, H2O saturation

Increasing aDr 4 )] 2

) Albite

+ 3 Increasing aMgF

/(H Increasing log(K) M g 2+ F + 2 N 2 a D Pyrophyllite + r + + log[Mg M A l g b 2 + + + 4 3 H 1 ity + cid Q a Paragonite tz ing + s 2 ea H cr In 2 O 0 123456 log(Na+/H+) Figure 14B Dravite to Uvite 6 400°C, 500 bars

Qtz, H2O saturation

5 Chlorite

4 )] 2 ) +

/(H Albite Paragonite 2+ 3

Increasing aDr Pyrophyllite 2+ 2+ Dr + Ca + Mg + 2H2O + 3Qtz log[Mg 2 Uv + Alb + 4H+

ty Increasing a idi Uv 1 c g a Increasing Ca sin ea cr Increasing log(K) In 0 123456 log(Na+/H+) Figure 15A. Magmatic hydrothermal tourmaline

Figure 15B. IOCG and related systems Figure 15C. Metamorphic hydrothermal tourmaline

Figure 15D. Stratabound tourmaline

Figure 15E. Sedimentary (evaporite-related) tourmaline

Figure 15F. Copiapó tourmaline Table 1. Tourmaline end members and classifications from Hawthorne and Henry (1999).* Alkali tourmaline

Species (X) (Y3)(Z6)T6O18 (BO3)3 V3 W

Elbaite Na Li1.5 Al1.5 Al6 Si6O18 (BO3)3 (OH)3 (OH)

Olenite Na Al3 Al6 Si6O18 (BO3)3 O3 (OH)

Dravite Na Mg3 Al6 Si6O18 (BO3)3 (OH)3 (OH)

Chromdravite Na Mg3 Cr6 Si6O18 (BO3)3 (OH)3 (OH) + 2+ Schorl Na Fe 3 Al6 Si6O18 (BO3)3 (OH)3 (OH) 3+ Buergerite Na Fe 3 Al6 Si6O18 (BO3)3 O3 F 3+ 3+ Povondraite Na Fe 3 Fe 4Mg2 Si6O18 (BO3)3 (OH)3 O Vanadiumdravite Na Mg3 V6 Si6O18 (BO3)3 (OH)3 (OH) Calcic tourmaline

Species (X) (Y3)(Z6)T6O18 (BO3)3 V3 W

Liddicoatite Ca Li2Al Al6 Si6O18 (BO3)3 (OH)3 F

Uvite Ca Mg3 MgAl5 Si6O18 (BO3)3 (OH)3 F 2+ Feruvite Ca Fe 3 MgAl5 Si6O18 (BO3)3 (OH)3 F X-site vacant tourmaline

Species (X) (Y3)(Z6)T6O18 (BO3)3 V3 W

Rossmanite □ LiAl2 Al6 Si6O18 (BO3)3 (OH)3 (OH) 2+ Foitite □ Fe 2Al Al6 Si6O18 (BO3)3 (OH)3 (OH)

Magnesiofoitite □ Mg2Al Al6 Si6O18 (BO3)3 (OH)3 (OH) *Hypothetical end members are excluded. +Most common end member Table 2. Common substitutions within and between sites including a compilation of exchange vectors after Henry and Guidotti (1985) and Henry and Dutrow (1996). Substitutions* Exchange vectors Y Y 2+ 2+ Mg = Fe Fe Mg-1 Y Y 2+ 2+ Mn = Fe Fe Mn-1 Z Z 3+ 3+ Al = Fe Fe Al-1 Z Z 3+ Al = Cr CrAl-1 O(1) - O(1) - OH = F F(OH)-1 Y 2+ Y Y 2+ 2 Fe = Li + Al LiAlFe -1 elbaite substitution X Y X Y Na + 2 Mg = □** + Al □AlNa-1Mg-1 alkali-defect substitution X Y O(1) - X Y O(1) 2- Na + Mg + OH = □ + 2 Al + O □Al2ONa-1Mg-2(OH)-1 aluminobuergerite substitution Y O(3) - Y O(3) 2- Mg + OH = Al + O AlOMg-1(OH)-1 Y 2+ O(3) - Y 3+ O(3) 2- 3+ 2+ Fe + OH = Fe + O Fe OFe -1(OH)-1 buergerite substitution

Y T Y T Mg + Si = Al + Al Al2Mg-1Si-1 Tshermaks substitution Y Y Y 2 Al = Mg + Ti MgTiAl-1 X Y X Y Na + Al = Ca + Mg CaMgNa-1Al-1 uvite substitution X Y O(1) - X Y O(1) 2- □ + Al + OH = Ca + Mg + O CaMgO(OH)-1□-1Al-1(OH)-1 Y Z O(1) - Y Z O(1) 2- 2 Mg + Al + OH = 2 Al + Mg + O CaMgO(OH)-1□-1Al-1(OH)-1 *Superscripts denote specific crystallographic sites. **This symbol represents an X-site vacancy Table 3. Mineral assemblages in tourmaline-bearing samples from Copiapó, Chile

Sample no. Mineral assemblage, textures, and relative timing* Cerro Bronce_Estrella Ep-Tour-Tit veins; Hbl[mafics]**, Act[Hbl] in envelope of Ep veins; Tit[Hbl] and some Mt (50% or so C2B-298 alt to Hem) are present throughout the rock; The host rock is comprised of Plag and Pyx Large sprays of Tour in rock with Cc-pale green Ser- C2B-708 Hem-Ep and an unknown brown phase Cerro Buitre Radio Tower Plag with a cataclastic texture dominates this section; Veins of cryptocrystalline, fine grained Qtz are present througout and cement specular Hem in some cases; C2B-287 Lim[Py]; Tour is clotty, comprises a few percent of the rock, and is most abundant where Hem is not present; Rare Apat is also present. Abundant green Bt and Musc; Hem(specular)-Bt veins cut a granular Qtz vein that contains Cpy; Other veins dominated by Bt; One such vein contains accessory C2B-576c Tour; Bt is stable adjacent to crystals (no obvious chloritization of Bt); Evidence for specular Hem after Mushk Mainly intergrown Plag (variably sericitized)-Qtz going to Qtz-Tour-Hem zones; Early blue-grey Tour is rimmed by brown Tour (majority) with later light blue C2J-124 Tour; Hem and Tour do not typically occur together, but both occur with Qtz; coarse-grained Zircon is also present Sparsely porphyritic "adamellite" with >3 mm Plag, sparse Opx and Cpx now almost completely converted to pale sheaves of Act, locally with Bt and rarely with C2J-334 blue to pink Tour(± Lim); Mt and Ilm are common (Mt>Ilm); Mt typically has Hem and both typically have Ilm rims; late Qtz is widespread but sparse and Apat is common Cerro Granate Tour vein with sparse Cc and late REE mineral veinlet grading to Tour with some Qtz locally intergrown with specular Hem; Vein envelope is Plag with sparse Rut C3B-072a and Hem; Along one edge of sample, there appears to be a Chl-Ser-Cc-oxide veinlet; The host rock is an equigranular fine grained Plag-dominant rock with distributed Ser-Chl, and minor Rut Cerro Negro Norte Coarse-grained Tour + Kfs + Cc + sulfides(Py>Cpy) + Chl ± Tit vein cuts inclusion-rich (mainly Mt) fine- grained Tour vein in rock that has sericitized Plag + Act C6B-076 ± Ep at one end and variable Act-Ep to Mt[Hem]-rich material in towards the other end; Act-Plag veinlets cut matrix and are cut by other Kfs veinlets Española Penetratively deformed rock with Qtz-Tourm veins grading outward into Tour-Alb ± bright yellow Fe- sulfate; Plag-rich zones have strong alignment of feldspars; Within the principal veins, there are two C3B-381a generations of Tour, one granular and deformed and the other coarser, undeformed generation intergrown with non-strained, non-oriented Qtz; Opaque minerals appear to be mainly Lim and minor Rut Falla Ojancos_Transito San Francisco Bands of brown Tour in Plag(albite)-rich rock are cut by coarse-grained Alb veins; Sparse Kfs is also present; C6B-101b Lighter colored part of rock has Lim[Py] and minor Mt as well as a sparse, unknown brown mineral (goethite?) Host is varied very fine-grained, felsic granular rock with a brecciated zone containing clasts with altered Plag phenocrysts; This is cut by Qtz(±Tour C6B-107 ±Lim[sulfide]) vein; Qtz veins are clearly broken and transported in the breccia; Breccia matrix consists of very fine-grained, dark green-grey Tour intergrown with Qtz Jesus Maria Tour-Dum bearing rock with a groundmass of abundant equigranular Qtz-Cc-Hem[Mt]; Certain areas of the rock also contain Pyroph; Late Tour forms comb-like C7B-003a overgrowths on embayed or euhedral edges of early Tour; Dum is present throughout the rock but are concentrated in areas where they appear to have replaced earlier grains Ojancos Viejo Tour-clay-Lim[Py] vein cuts a Plag dominated rock C3B-429.5 with an overall clastic/cataclastic texture; minor specular Hem and Lim[Py] in the matrix San Gregorio_S Granate Qtz-rich aplite, with variable textures but constant proportions of minerals is cut by a prominent Tour that contains an abundance of relatively unaltered Plag, Kfs, C2B-352e and Qtz with minor Apat; These phases all seem to have grown together; Outside of vein is weakly perthitic alk Fsp, with an abundance of Plag dusted with white micas, some Hem(Mt), and big grains of Ilm Abundant nearly jet black, opaque Tour overgrown by multi-colored, zoned Tour; Some Tour clearly replaces C2B-655 associated Act in rock; Bt, Ep, Plag, Tit, and Qtz are also present; Late Cc veinlet runs through the section Brown Tour vein with network-filling envelope with C2B-671 Albite>Act-yellow Tit adjacent to Ep-Act(Tit-Mt-Apat- Cpx) altered San Gregorio monzodiorite Brown Bt and Act[Opx]; Significant amounts of Plag and Qtz (some myrmekitic textures); Zircons are present as inclusions in Bt with radiation damage; Tour C2B-808.2 occurs in cavities where it is partially replaced by potassic-chlorohastingsite or intergrown with Bt and Tit; Oxides dominated by Mt with some Hem overprint Santos_PdC Tour-Bt-Py-Qtz(-Mt-Mushk-Apat-Albite) vein and breccia cement is present along contact of crystal-rich and crystal-poor rock types; Qtz contains Hem and local Tour and appears to fill open space; The crystal-poor rock has Plag, Qtz (vug fill, rare veinlets), and a very DDH289-037.5 fine-grained groundmass with feldspar; The crystal-rich rock contains Plag, Chl, and Fe oxide, but crystal content decreases by 1/2 approaching vein contact; Thin Qtz veins contain rare Hem ± Chl ± Bt; This rock contains abundant, scattered Bt with rare Chl[Bt].

Green, intensely biotitized mafic(?) porphyritic rock with mafic(?) sites now completely converted to green Bt as is the groundmass; Equant sites with Qtz-Ep-Bt may have been feldspar phenocrysts; Multiple veins cut the rock: two late vein types include Chl-Bt(-Ep-Qtz-Py- DDH291-188.4 Cpy ± Tour) with an envelope of Bt-Tour-Qtz and a Qtz- Tour ± Bt ± Mt vein; These both cut coarse-grained Bt- Ep-Qtz(-Cpy) veinlets that have remarkably little deformation even though the cross-cutting Qtz veinlet is clearly deformed; sulfides are restricted to the veins Tour vein is intergrown with well-formed Plag and surrounded by sericitized Kfs and Chl; Blades of specular Hem irregularly line the sides of the vein; DDH384-004.2 Yellow Ep is also present, but rare; Cc is found in variable quantities throughout the vein; There seem to be Cc-replaced grains within the vein with some evidence of flow or deformation Composite Mushk-Anhy-Qtz-Cpy-Py-Tour vein in complex biotitized porphyritic host; The central part of the vein contains Anhy(-Cpy-Py) grading into and outer zone of Mushk-Qtz(-Cpy-Tour) where Tour occurs both DDH628-094.2 as isolated small crystals and sprays of very fine-grained fibers growing off Mushk; The host is Bt-rich, but rock contains multiple events with Ep-Mt-Cpy-Qtz-Chl in addition to fine-grained Bt Intensely biotitized porphyritic volcanic rock cut by Tour-Py-Cpy-Mt[Cpy]-Allan-Chl-Bt-Kfs vein; Abundant Mt is found away from central vein and disappears approaching it; In the inner envelope Qtz DDH628-150.6 replaces most minerals and Allan is locally present; The host rock contains a thin Qtz-Bt(-Cpy-Ep) veinlet that is truncated by the large vein; Late Cc veinlet cuts the large vein Large Scap-Bt(-Chl-Py) vein lacking preferred orientation of Scap, has apparent Bt-Mt(trace Allan- Tour) envelope grading out into less Bt- (and Mt-) rich material; The large vein apparently cuts small veins DDH628-626.3 with Qtz-Apat-Bt-Mt and minor Tour; Tour also occurs in bioititized grains; Py crystals are ragged and have spotted margins in places with abundant tiny inclusions of Cpy and silicates; Mt locally contains Cpy in vein; Qtz and Apat occur along edges of Scap vein Composite Qtz-Allan-Tour-Mt/Mushk-Cpy-Kfs breccia zone with many shard-like clasts cutting through biotitized porphyritic rock with feldspar phenocrysts partly altered to Bt, but mainly secondary Albite ± Qtz; Fine-grained Mt + rare Rut in original oxide sites; These grade into Kfs-altered zone/vein toward margin DDH643-595.5 of breccia with less Mt and sparse very fine-grained Chl; Clasts appear to be mixed and cut by Qtz-Allan- Tour-Mt veins; The clasts in the Qtz vein are combinations of Allan-Qtz-Chl-Tour with various Tour or Allan rims, sugary or recrystallized Qtz zones, and accessory Mt, all cemented by several generations of Qtz-Allan(Epid)-Tour-Mt-Mushk-Cpy Very fine-grained and dark zone of Qtz-Tour with mafic free Qtz-Plag envelope and a rim of Mt(partly Mushk)- Cpy; The host is biotitized subequigranular rock with abundant fine-grained Qtz and Plag; Certain areas very DDH684-079.8 fine-grained aggregates Bt in mafic sites; similar Bt (rarely Chl) occurs along veins with Cpy-Mushk and early Py; The veins have Kfs + Qtz ± Bt (or Chl) in addition to Mushk[Py] Bt-Tour-rich vein with later Ep + Py (+ Sph-Cpy) in Bt- rich altered porphyritic volcanic rock with scattered Py and Sph(Cpy) + Ep + Qtz + Plag; Sph is abundant as ME013-538 small grains, feldspar sites, veins, and vugs; Two different colors of Bt correspond to differences in color in the rocks: pale green and deep red brown Vinita Azul Sutured Qtz-And-Hem-Rut rock with minor fibrous blue Tour, trace Lazulite and minor brownish fine- C6B-160b grained sheet silicate that appears to be late; Rock is cut by veinlet of Hem-And-Tour ± Qtz with large, poikilitic And crystals overgrowing Hem

*Mineral abbreviations: Act = actinolite, And = andalusite, Anhy = anhydrite, Apat = apatite, Bt = biotite, Cc = calcite, Cpy = chalcopyrite, Ep = epidote, Hem = hematite, Kfs = K-feldspar, Lim = limonite, Mt = magnetite, Mushk = mushketovite, Plag = plagioclase, Py = pyrite, Pyx = pyroxene, Qtz = quartz, Rut = rutile, Sph = sphalerite, Tit = titanite, Tour = tourmaline **Minerals or phases in brackets represent minerals that are being replaced. Table 4. Representative chemical analyses of tourmalines from Copiapó, Chile1

Location Cerro Bronce Estrella Cerro Buitre Radio Tower Cerro Granate Cerro Negro Norte Española Sample no. C2B-298 C2B-708 C2B-287 C2B-576c C2J-124 C2J-334 C3B-072a C6B-076 C3B-381a Spot no. 2 2 1211 2 4 2 Analysis no. t5 t1 t20 t2 t5 t1 t4 t12 t3a

SiO2 35.62 35.83 37.13 36.13 36.42 35.90 35.34 34.58 36.30

TiO2 2.35 0.00 3.83 0.46 0.04 0.42 0.22 1.82 1.79

Al2O3 23.79 32.20 29.29 31.85 34.63 28.13 28.66 22.82 32.72 † B2O3 10.26 10.49 10.73 10.46 10.77 10.43 10.24 10.05 10.66

Cr2O3 0.01 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.02

Fe2O3** 5.18 4.47 0.31 2.07 2.01 4.51 7.53 5.12 0.71 FeO 7.04 6.06 0.22 6.26 2.24 7.69 8.66 11.21 3.48 MgO 8.94 5.55 11.61 6.34 8.18 7.14 4.15 7.11 8.19 MnO 0.00 0.01 0.00 0.01 0.05 0.06 0.03 0.01 0.04 CaO 2.99 0.83 1.54 0.94 0.28 2.03 0.95 2.21 0.75

Na2O 1.32 2.24 2.12 1.72 1.80 1.65 2.15 1.64 2.29

K2O 0.02 0.02 0.03 0.05 0.01 0.04 0.03 0.06 0.09

H2O** 2.96 2.93 2.73 3.12 3.44 3.13 2.82 3.29 3.00 F 0.09 0.03 0.34 0.04 0.03 0.12 0.01 0.12 0.12 Cl 0.00 0.01 0.00 0.00 0.06 0.01 0.01 0.02 0.02 Subtotal 100.57 100.68 100.34 99.44 100.06 101.40 100.80 100.18 100.34 O = F, Cl -0.04 -0.01 -0.14 -0.02 -0.02 -0.05 -0.01 -0.05 -0.05 Total 100.54 100.66 100.19 99.42 100.04 101.34 100.80 100.12 100.29

Atomic proportions based on 15 cations (T+Y+Z = 15)‡ III B 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 T Si 6.03 5.94 6.02 6.00 5.88 5.98 6.00 5.98 5.92 B 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Al 0.00 0.06 0.00 0.00 0.12 0.02 0.00 0.02 0.08 Sum 6.03 6.00 6.02 6.00 6.00 6.00 6.00 6.00 6.00 Z Cr 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Fe3+ 0.66 0.56 0.04 0.26 0.24 0.57 0.96 0.67 0.09 Mg 0.59 0.00 0.32 0.00 0.00 0.00 0.00 0.69 0.00 Al 4.75 5.44 5.59 5.74 5.74 5.42 5.04 4.63 5.89 Sum 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Y Al 0.00 0.79 0.00 0.50 0.72 0.09 0.69 0.00 0.31 Mg 1.67 1.37 2.49 1.57 1.97 1.77 1.05 1.14 1.99 Fe2+ 1.00 0.84 0.03 0.87 0.30 1.07 1.23 1.62 0.47 Ti 0.30 0.00 0.47 0.06 0.00 0.05 0.03 0.24 0.22 Sum 2.97 3.00 2.99 2.99 2.99 2.99 2.99 3.00 2.99 X Na 0.43 0.72 0.67 0.56 0.56 0.53 0.71 0.55 0.72 K 0.01 0.01 0.01 0.01 0.00 0.01 0.01 0.01 0.02 Ca 0.54 0.15 0.27 0.17 0.05 0.36 0.17 0.41 0.13 □ 0.02 0.13 0.06 0.27 0.39 0.10 0.11 0.03 0.13 Sum 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 OH F 0.05 0.02 0.17 0.02 0.01 0.06 0.01 0.07 0.06 Cl 0.00 0.00 0.00 0.00 0.02 0.00 0.00 0.00 0.01 OH 2.79 2.77 2.58 2.95 3.25 2.96 2.66 3.11 2.84 O 1.16 1.22 1.24 1.04 0.72 0.98 1.33 0.82 1.10 Total 4.00 4.00 4.00 4.00 4.00 4 4.00 4.00 4.00

2+ Fe /Fetotal*** 0.6 0.6 0.45 0.77 0.55 0.65 0.56 0.7 0.84

1Electron microprobe analyses were carried out on a CAMECA SX50 at an accelerating voltage of 20 kV, 30 nA beam current, and 10 – 15 second counting time for major elements and 200 nA beam current with a 30 – 60 second counting time for minor elements. *Santos sample numbers correspond to the drill hole number followed by the depth in meters 3+ **H2O values were chosen to reflect an approximate Fe /Fetotal ratio that was derived via electron microprobe Fe working curves after Fialin et al. (2004). See Appendix for further discussion. ***Fe ratio determined from electron microprobe working curves after Fialin et al. (2004). See Appendix for further discussion. †Calculated on the basis of 3 apfu B ‡Site assignments are empirical estimates as structural refinement was not part of this study Falla Ojanco Transito San Francisco Jesus Maria Ojancos Viejo San Gregorio S Granate C6B-101b C6B-107 C7B-003a C3B-429.5 C2B-352e C2B-655 C2B-671 C2B-808.2 DDH289-037.5 1 2 3 1 3221 2 t5 t9 t2 t19 t12 t1 t2 t20 t14 36.14 37.59 36.45 36.33 34.47 34.51 35.32 34.70 36.86 3.00 0.38 0.15 0.60 1.45 2.30 1.47 0.03 0.28 25.92 31.94 36.33 30.74 24.76 22.50 25.05 25.78 34.16 10.40 10.79 10.71 10.50 9.99 9.99 10.23 9.99 10.72 0.15 0.01 0.02 0.00 0.00 0.01 0.00 0.01 0.01 3.29 1.29 3.31 2.51 7.65 8.56 6.41 14.26 1.34 5.34 4.97 7.39 6.00 9.34 8.71 7.09 8.30 3.75 9.22 8.31 2.94 7.05 5.28 6.45 7.71 2.22 7.35 0.00 0.00 0.00 0.00 0.01 0.08 0.06 0.08 0.03 0.83 0.92 0.02 0.80 1.94 3.09 3.22 1.08 0.67 2.45 2.33 0.85 2.25 1.69 1.20 1.17 1.88 2.28 0.03 0.01 0.05 0.02 0.04 0.05 0.05 0.18 0.00 3.13 3.25 3.07 3.07 2.73 2.57 2.78 2.28 3.05 0.07 0.05 0.32 0.01 0.13 0.17 0.10 0.05 0.02 0.00 0.00 0.04 0.00 0.01 0.00 0.01 0.04 0.00 99.98 101.98 101.63 100.30 99.59 100.19 100.67 100.92 100.68 -0.03 -0.02 -0.14 0.00 -0.06 -0.07 -0.04 -0.03 -0.01 99.95 101.96 101.49 100.30 99.53 100.12 100.62 100.89 100.67

3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00

6.04 6.05 5.91 6.01 5.99 6.01 6.00 6.04 5.97 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09 0.00 0.01 0.00 0.00 0.00 0.03 6.04 6.05 6.00 6.01 6.00 6.01 6.00 6.04 6.00 0.02 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.41 0.16 0.40 0.31 1.00 1.12 0.82 1.87 0.16 0.46 0.00 0.00 0.00 0.00 0.26 0.16 0.00 0.00 5.11 5.83 5.59 5.65 4.99 4.62 5.02 4.13 5.82 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00

0.00 0.23 1.27 0.34 0.08 0.00 0.00 1.16 0.68 1.84 2.00 0.71 1.74 1.37 1.41 1.79 0.58 1.77 0.75 0.67 1.00 0.83 1.36 1.27 1.01 1.21 0.51 0.38 0.05 0.02 0.07 0.19 0.30 0.19 0.00 0.03 2.96 2.95 3.00 3.01 3.00 2.98 2.99 2.95 3.01

0.79 0.73 0.27 0.72 0.57 0.40 0.39 0.63 0.72 0.01 0.00 0.01 0.01 0.01 0.01 0.01 0.04 0.00 0.15 0.16 0.00 0.14 0.36 0.58 0.59 0.20 0.12 0.05 0.11 0.72 0.13 0.06 0.01 0.02 0.13 0.17 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

0.04 0.03 0.16 0.01 0.07 0.09 0.05 0.03 0.01 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.01 0.00 2.95 3.06 2.90 2.90 2.58 2.43 2.62 2.15 2.87 1.01 0.91 0.93 1.10 1.35 1.48 1.32 1.81 1.12 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00

0.64 0.81 0.71 0.72 0.57 0.53 0.55 0.39 0.75 Santos PdC* Vinita Azul DDH291-188.4 DDH384-004.2 DDH628-094.2 DDH628-151.6 DDH628-626.3 DDH643-595.5 DDH684-079.8 ME013-538 C6B-160b 121222311 t1 t3 t2 t1 t6 t2 t3 t3 t2 36.37 36.69 35.98 35.60 35.26 36.37 36.36 36.18 35.90 0.28 0.38 0.80 0.07 0.04 0.52 0.39 0.67 0.22 30.08 31.50 26.91 29.91 35.00 30.46 29.29 31.95 36.40 10.46 10.56 10.41 10.29 10.52 10.49 10.48 10.65 10.76 0.07 0.01 0.00 0.01 0.01 0.00 0.01 0.01 0.02 2.57 2.02 5.35 4.64 4.92 3.60 1.40 0.00 2.00 7.85 6.59 8.67 8.90 7.89 6.91 9.45 10.70 4.67 6.50 6.73 6.88 4.64 2.63 6.28 6.93 5.17 5.63 0.01 0.01 0.03 0.04 0.04 0.00 0.03 0.00 0.03 1.05 0.73 1.61 0.28 1.02 1.08 0.88 1.16 0.03 2.05 2.05 1.90 2.24 1.25 2.10 2.10 1.56 1.90 0.06 0.02 0.06 0.05 0.03 0.01 0.03 0.07 0.01 3.21 3.20 3.22 3.15 2.82 3.01 3.56 3.39 3.27 0.04 0.09 0.05 0.03 0.02 0.05 0.03 0.01 0.07 0.00 0.01 0.01 0.00 0.09 0.00 0.01 0.01 0.01 100.61 100.60 101.88 99.84 101.54 100.88 100.94 101.55 100.97 -0.02 -0.04 -0.02 -0.01 -0.03 -0.02 -0.02 -0.01 -0.03 100.59 100.56 101.85 99.83 101.52 100.86 100.92 101.54 100.94

3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00

6.04 6.04 6.01 6.01 5.82 6.03 6.03 5.96 5.80 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.03 0.00 0.00 0.00 0.00 0.00 0.17 0.00 0.00 0.01 0.20 6.04 6.04 6.01 6.01 6.00 6.03 6.03 6.00 6.00 0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.32 0.25 0.67 0.59 0.61 0.45 0.17 0.00 0.24 0.00 0.00 0.03 0.00 0.00 0.00 0.10 0.00 0.00 5.67 5.75 5.29 5.41 5.39 5.55 5.72 6.00 5.75 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00

0.22 0.36 0.00 0.55 1.25 0.40 0.00 0.20 0.98 1.61 1.65 1.68 1.17 0.65 1.55 1.61 1.27 1.36 1.09 0.91 1.21 1.26 1.09 0.96 1.31 1.48 0.63 0.04 0.05 0.10 0.01 0.01 0.06 0.05 0.08 0.03 2.96 2.96 2.99 2.98 3.00 2.97 2.97 3.03 3.00

0.66 0.65 0.62 0.73 0.40 0.68 0.68 0.50 0.59 0.01 0.01 0.01 0.01 0.01 0.00 0.01 0.02 0.00 0.19 0.13 0.29 0.05 0.18 0.19 0.16 0.21 0.01 0.14 0.21 0.08 0.21 0.41 0.13 0.16 0.28 0.40 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

0.02 0.05 0.03 0.02 0.01 0.03 0.02 0.01 0.04 0.00 0.00 0.00 0.00 0.02 0.00 0.00 0.00 0.00 3.03 3.02 3.04 2.97 2.66 2.85 3.36 3.20 3.09 0.95 0.93 0.93 1.01 1.30 1.13 0.62 0.79 0.87 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00

0.77 0.78 0.64 0.68 0.64 0.68 0.67 0.67 0.72 Table 5. Pleochroic characteristics of and zoning in Copiapó tourmaline

Locality Sample Color parallel to c Color perpendicular to c Zoning?

Cerro Bronce Estrella C2B-298 tan; blue brown; dark blue-brown Y (on second) C2B-708 tan dark sky blue N

brown (core); blue-green to blue- Cerro Buitre Radio Tower C2B-287 light tan (core); light blue (rim) brown (rim) Y C2B-576c tan light blue N C2J-124 lavender; light tan; light greenish brown gray; brown; green-brown N C2J-334 pink; light blue dark brown; blue-brown Y

Cerro Granate C3B-072a light tan blue-green; blue-brown Y

Cerro Negro Norte C6B-076 tan/pink; light blue brown; blue-green Y

light blue-green (core); light brown blue-green (core); brown (rim); Española C3B-381a (rim); tan (late) blue-green (late) Y

Falla Ojancos Transito- C6B-101b light brown dark brown Y San Francisco C6B-107 tan brown? Y

blue-brown (core); blue-brown light blue-brown (core); light bluish (rim); dark blue-green (core); light Jesus Maria C7B-003a brown (rim); tan (core); whitish(rim) blue-green (rim) Y

light blue-green (core); light brown blue-green/blue-brown (core); Ojancos Viejo C3B-429.5 (rim) brown (rim) Y San Gregorio_S Granate C2B-352e light brown dark brown N C2B-655 tan; light yellow-green brown; blue-green Y C2B-671 light brown v. dark brown N C2B-808.2 blue; brown dark blue; v. dark brown Y

Santos_PdC DDH289-037.5 tan blue-green/blue-brown/brown Y DDH291-188.4 tan blue-green Y DDH384-004.2 tan blue-green/blue-brown Y DDH628-094.2 tan blue/blue-brown DDH628-150.6 tan dark blue; dark brown Y DDH628-626.3 tan blue/blue-green Y DDH643-595.5 tan; blue-dark blue (non-pleochroic) blue green Y DDH684-079.8 tan brown? Y ME013-538 tan blue-green Y

Vinita Azul C6B-160b tan blue Y Table 6. Boron isotope analyses of tourmalines from the Copiapó area and Cerro Negro Norte*

Locality Sample Spot no. Morphology δ11B 2s San Gregorio S Granate C2B-352e 1A vein 4.2 0.6 San Gregorio S Granate C2B-352e 1B vein 2.0 0.6 San Gregorio S Granate C2B-352e 1C vein 2.9 0.7 San Gregorio S Granate C2B-352e 3A vein 2.8 0.7 San Gregorio S Granate C2B-352e 3B vein 0.0 0.6 San Gregorio S Granate C2B-671 1A vein and fracture-fill -1.3 0.6 San Gregorio S Granate C2B-671 1B vein and fracture-fill -2.6 0.5 San Gregorio S Granate C2B-671 1C vein and fracture-fill -5.5 0.6 San Gregorio S Granate C2B-671 1D vein and fracture-fill -2.9 0.6 San Gregorio S Granate C2B-671 2A vein and fracture-fill -2.8 0.6 San Gregorio S Granate C2B-671 2B vein and fracture-fill -4.7 0.7 San Gregorio S Granate C2B-671 2C vein and fracture-fill -5.2 0.7 Cerro Bronce Estrella C2B-708 1A vein -3.2 0.5 Cerro Bronce Estrella C2B-708 1B vein -4.9 0.5 Cerro Bronce Estrella C2B-708 1C vein -3.6 0.5 Cerro Bronce Estrella C2B-708 1D vein -1.2 0.5 Cerro Bronce Estrella C2B-708 1E vein -3.1 0.5 Cerro Bronce Estrella C2B-708 1F vein -3.7 0.6 Cerro Granate C3B-072a 1A vein -1.4 0.5 Cerro Granate C3B-072a 1B vein -3.7 0.5 Cerro Granate C3B-072a 1C vein -3.7 0.4 Cerro Granate C3B-072a 1D vein -4.7 0.4 Cerro Granate C3B-072a 1E vein -5.1 0.6 Espanola C3B-381a 1A tourmalinized rock -5.9 0.7 Espanola C3B-381a 1B tourmalinized rock -6.9 0.7 Espanola C3B-381a 1C tourmalinized rock -7.4 0.9 Espanola C3B-381a 1D tourmalinized rock -7.2 0.9 Espanola C3B-381a 1E tourmalinized rock -6.7 0.7 Cerro Negro Norte C6B-076 1A vein -5.9 0.5 Cerro Negro Norte C6B-076 1B vein -7.1 0.5 Cerro Negro Norte C6B-076 1C vein -7.5 0.6 Cerro Negro Norte C6B-076 1D vein -6.6 0.4 Cerro Negro Norte C6B-076 1E vein -5.5 0.4 Cerro Negro Norte C6B-076 1F vein -4.8 0.6 Cerro Negro Norte C6B-076 1G vein -5.0 0.5

*Analyses were done on a MC-LA-ICPMS (wet plasma) at a 8 Hz laser pulse rate, 75 μm spot size, 30 sec on-peak background measurement, followed by 80 cycles of one-second integration time per cycle Appendices

Appendix 1: Analytical Methods Major- and minor-element analyses: Major-element analyses for tourmaline were performed on 27 polished thin sections on a CAMECA SX50 at the University of Arizona. Back-scattered electron imaging confirmed the complexity of elemental zonation and provided the basis for the selection of microprobe data points. Two different operating conditions were used for major and minor elements in tourmaline, respectively. For the major elements, an accelerating voltage of 20 kV, 30 nA beam current, and 10 – 15 second counting time were used. For minor elements, a 20 kV accelerating voltage, 200 nA beam current, and a 30 – 60 second counting time were employed. Standards used are diopside (Si, Mg, Ca), anorthite (Al), fayalite (Fe), albite (Na), K-feldspar (K), rhodonite (Mn), rutile (Ti), MgF2 (F), scapolite (Cl), and chromite (Cr). A PAP correction was applied to the data (Pouchou and Pichoir, 1984). Table A1 contains all tourmaline analyses from this study. Even though it is possible to analytically determine most of the major elements in tourmaline by electron microprobe, B, Li, H, and the valence states of the transition elements cannot be directly measured. In the absence of accurate analyses of these elements and transition element oxidation states, several assumptions were made in order to calculate the stoichiometry of tourmaline. First, B is assumed to be stoichiometric at 3 apfu. Although natural samples exhibit variation from 2.86 to 3.26 apfu (Dyar et al., 1998; Hughes et al., 2001), the majority of spectroscopic and structural refinement studies suggest that B is stoichiometric (e.g., Grice and Ercit, 1993; Hawthorne, 1996; Bloodaxe et al., 1999; Clark, 2007). Due to the fine-grained nature of the tourmaline and its complex relationship with other minerals, Mossbauer spectroscopy on tourmaline samples was not feasible. Therefore, Fe3+/∑Fe ratios were estimated for Copiapó area tourmalines using methods outlined by Fialin et al. (2004). This procedure uses the self-absorption-induced shift in the FeLα peak caused by unfilled 3d states to determine the relative amounts of Fe3+ to total Fe. Other than the oxidation state, the peak shift is also dependent on the total Fe concentration, as higher Fe contents result in self-adsorption effects. These measurements were carried out on polished thin sections at 20 kV and 299 nA. 70 peak searches with a dwell time of 200ms were carried out per spot. To prevent any discrepancies due to mechanical drift throughout the run, each measurement was corrected to the FeLα position for hematite. Significantly, the FeLα peak appears to be insensitive to the geometry of the Fe sites for pure Fe valence end members. The calibration curves obtained hold for the majority of tourmaline samples. However, several dravitic and uvitic tourmalines, as well as some other minerals (i.e., clinozoisite) with Fe contents less than 10 atomic wt percent, plot above the Fe2+ calibration curve, representing peak positions that are not consistent with their Fe concentrations. This could be due to Fe oxidation at the analyzed spot or intervalence charge transfer, which is particularly noticeable when Fe2+ and Fe3+ sites have similar geometries (Fialin et al., 2004). Tourmalines for which the Fe ratio could be derived were normalized to reflect that ratio. These ratios were related to the overall Fe content of these tourmalines to derive a formula that was then applied to the remainder of the tourmaline to acquire an approximate Fe3+/∑Fe ratio (Fig. A1). The fact that tourmalines from the Copiapó area appear to fit well to this trend may reflect a geologic control on tourmaline compositions. However, the real Fe3+ value may be higher or lower, in light of the chemical heterogeneity present in each sample (Table A2). 3+ To meet charge balance constraints, enough H was added to make the Fe /Fetot ratio equivalent to the estimated value for tourmalines from each sample. This H estimate, which also affects the estimate of W-site O2-, is subject to great uncertainty because it contains the errors associated with normalization assumptions and elemental analytical uncertainties (Dutrow and Henry, 2000). Tourmaline with greater than 0.2 apfu Mg has negligible concentrations of Li (Henry and Dutrow, 1996). The antipathetic nature of Li and Mg is interpreted as the result of a chemical response to the size-adjusting requirements of the edge-sharing Y and Z octahedra. The oxidation or reduction of Fe changes the cation radius at the Y-or Z-sites, such that a structural fit is best achieved for compositions between dravite–schorl and elbaite–schorl solid solution pairs and end members. However, this fit is lacking in tourmalines with intermediate Mg-Li compositions; thus, the pure dravite–elbaite solid solution is not possible (Hermon et al., 1973). Si is assumed to occupy the T site exclusively, with Al making up for any deficiencies (MacDonald and Hawthorne, 1995). Normalizations were carried out on the basis of 15 cations, exclusive of Na, K, and Ca, which assumes no vacancies in the octahedral and tetrahedral sites (Henry and Dutrow, 1996). Schreyer et al. (2002) reported that tourmalines with Al greater than 7 apfu (e.g., olenite) tend to have excess B. However, all tourmalines in this study have less than 7 apfu Al; thus, it is likely that excess B does not need to be taken into consideration. This work contains 965 data points with 590 tourmaline analyses associated with multiple mineral assemblages from various geographic locations throughout the Copiapó area. Chemical analyses of associated minerals were also obtained for a more accurate assessment of the mineralizing environment.

Boron isotope analyses: Boron isotopes were measured in-house by MC-LA-ICPMS using a Thermo Scientific Isoprobe fronted with a 193 nm ArF excimer laser (New Wave Research). Although the in-house Isoprobe is nominally set up and optimized to measure high mass species (e.g., U and Pb isotopes for geochronology), similar instrumentation has been successfully used to measure B isotopes, in solution, at other laboratories (Aggarwal et al., 2004). The desired use of laser ablation for sampling, however, necessitated minor adjustments to the method of Aggarwal et al. (2004) to achieve the maximum sensitivity for boron. In particular, Aggarwal et al. (2004) report the use of a 6.2 mL/min He collision gas in their hexapole collision cell, to facilitate the reduction of the incoming ion kinetic energy spread prior to entering the magnetic sector. Although emulating this set-up produced an adequate 11B signal from solution (approximately 800mV/ppm B; acceptable for basic tuning), the equivalent 11B signal from ablated tourmaline under standard operating conditions was only ~100mV (= ~3X10-3mV/ppm B). This signal was insufficient to achieve a desired 2σ error on individual measurements of less than ±2 per mil. Through testing of different collision gas mixtures, we determined that a combination of 1.5 mL/min He and 8.0 ml H2 increased the B signal intensity by a factor of 4, while simultaneously reducing the measured uncorrected 11B/10B ratio from values of over 8 down to values between 5 and 6 (closer to the natural

2 abundance ratio of ~4). Significantly, this reduction had the effect of minimizing the instrumental mass fractionation correction required to derive the true isotope ratios of the unknowns. The increased B signal intensity from ablated tourmaline while utilizing the adjusted collision cell gas mixture also had the anticipated effect of significantly reducing the 2σ error on individual measurements, down to ~0.7 per mil. The use of H2 in the collision gas did prompt some concern that increased hydride formation could be problematic; however, no evidence of significant hydride production was observed. Notwithstanding the collision gas composition, the Isoprobe set-up generally reflected that of Aggarwal et al. (2004). The accelerating voltage was set to 6331 kV, and the hexapole DAC was set to 13 percent to yield the maximum B signal intensity. 10B+ and 11B+ were centered in L3 and H5 faraday detectors, respectively, corresponding to a theoretical mass position of 10.4 on the axial detector. The cup positions were H5 = 5342 and L3 = 2085. Samples and standards were mounted together in a single 2.5 cm diameter epoxy block. The laser was set to an 8 Hz laser pulse rate, delivering a ~50 mJ energy output for ~25kV of potential. A spot size of 75 μm was selected as a compromise to maximize the signal intensity while maintaining adequate spatial resolution. An individual analysis consisted of a 30 sec on-peak background measurement (without firing the laser), followed by 80 cycles of one-second integration-time per cycle. Between samples, it generally took approximately 1 min for the B signal to return to background levels. Ablated material was introduced to the plasma via He carrier gas flowing at 0.290 L/min through the sample cell. This flow joined with a 0.2 L/min flow of Ar ("nebulizer gas 2"; 0.1 L/min for solution tuning). Nebulizer gas 1 Ar was set to a 0.9L/min flow rate for solution tuning, and reduced to 0.54 L/min for laser abalation. The ablated material was introduced to the plasma in "wet plasma" mode; that is, a solution of 2 percent (v/v) nitric acid was aspirated throughout the laser work. Under the tuning conditions, the Micromist concentric nebulizer (Glass Expansion) aspirated a flow rate of ~100 μL/min. The comparable flow rate under the somewhat reduced Ar flow for the laser conditions was not measured. Five to seven sample analyses were alternated with two to three analyses on three standards run consecutively. The two main standards used in this study are a uvite from Brumado, Brazil, and an elbaite from an unspecified Brazilian locality. The uvite was separated from a rock containing only fine-grained white talc and abundant 5-7 mm green transparent uvite crystals. The elbaite was a loose, 5 cm transparent crystal consisting of a voluminous, nearly colorless core ("achroite"), overgrown by a very thin rind of blue tourmaline ("indicolite"); only the colorless core was used. The uvite was previously analyzed by SIMS, against the three standard tourmalines described in Dyar et al. (2001): dravite #108796, elbaite #98144, and schorl #112566, giving a value of δ11B = +13.4 ± 0.9 per mil (2σ; n=4; unpublished data). The "achroite" was similarly previously analyzed by SIMS, giving a value of δ11B = +0.4 ± 0.2 per mil (2σ; n=2; unpublished data). The "achroite" was further analyzed by MC-LA-ICPMS against the Brumado uvite, giving a value of -0.5 ±1.0 per mil (2σ; n=20 over two sessions; unpublished data). The latter value for the achroite, based on a larger sample set and incorporating a more conservative error, was used in this study. Data were processed offline. For each analysis, a preferred mean "raw 11B/10B" ratio and standard error were calculated from the filtered data (after excluding values outside

3 of 2σ from the full 80 cycle mean). These raw values did not include a correction for instrumental mass fraction (IMF), and hence corresponded to apparent δ11B values on the order of ~355 to ~385 per mil. Because of a time-dependent cyclic drift in IMF, a 2nd order polynomial was used to graphically best-fit the IMF variations in the Brumado and achroite standards, and the derived polynomial was used to correct for IMF in the unknown samples. Despite some scatter within individual standards, there did appear to be a slight difference in the instrumental mass fractionation between the achroite and uvite standards, amounting to a maximum difference of ~3.5 per mil. Although this may be attributable to matrix effects, a definitive interpretation is difficult because there were periods of notable measurement instability (for reasons that were not clear), as well as the possibility of minor isotopic heterogeneity in the achroite. Nonetheless, data collected from a ferroan uvite secondary standard from Pierrepont, New York, measured periodically during the day's run, agreed, within error, of published results (+13 ‰; Swihart and Moore, 1989).

Appendix 2: Literature sources of tourmaline compositional data Ayuso and Brown (1984); Bačík et al. (2008); Byerly and Palmer (1991); Cavarretta and Puxeddu (1989); Clarke et al. (1989); Demirel et al. (2009); Dini et al. (2008); Frietsch et al. (1997); Frikken (2003); Garda et al. (2009); Golani et al. (2002); Henry et al. (1999) Henry et al. (2008); Jiang et al. (1995); Jiang et al. (1997a); Jiang et al. (1997b); King and Kerrich (1989); Koval et al. (1991); London and Manning (1995); Lynch and Ortega (1997); Mao (1995); Mlynarczyk and Williams-Jones (2006); Peng and Palmer (2002); Pirajno and Smithies (1992); Plimer (1986); Plimer and Lees (1988); Raith (1988); Slack and Coad (1989); Taylor and Slack (1984); Xavier et al. (2008); Yavuz et al. (1999); Yavuz et al. (2008); Žáček et al. (1998).

Appendix 3: Petrologic descriptions of each sample

Chile\Cerro Negro Norte

C6B-076 Hand sample: Dark gray, Mt-bearing, Act-altered rock with a Tour-Sulf(Py>Cpy)- Mt-Calc vein and a lighter feldspathic zone on one end.

Thin section: This sample contains a coarse-grained, inclusion poor Tour-Kfs-Ep- Calc-Sulf (Py>Cpy)-Chl(gray) ± Tit vein cutting an inclusion-rich (mainly Mt) Tour vein in a rock that has sericitized Plag-Act ± Ep at one end and variable Act-Ep-Mt-rich material in the middle and towards the other end along with Py. A considerable amount of Hem in the matrix is being replaced by Mt. Act-Plag(sericitized) veinlets cut the matrix and are cut by later Kfs veinlets. Tour is zoned, blue cores with tan rims in sections parallel to c, with variable grain sizes (0.2 – 1.8 mm) and is pleochroic (tan to dark brown, blue/tan to dark blue). Fine-grained Tour appears to be enveloped by coarser grained Tour, which are commonly fractured and intergrown in some cases. Tour also occurs outside of the vein, but has corroded edges. Ep also appears to be slightly altered. This thin section displays a complex paragenesis with Tour in several assemblages all of which are representative of what can occur in the magnetite-apatite deposits of the iron belt.

4 Chile\Copiapó\Candelaria\Cerro Bronce_Estrella

C2B-298 Hand sample: This is an intensely altered, Qtz-bearing (15%), roughly equigranular but crudely layered white rock with 15 percent dark mafic minerals in clots and a medium green vein with a pale green envelope at one end. There is no K evident from staining and there appears to be several generations of veins.

Thin section: It is unclear what the rock was originally, but it could have possibly been a volcaniclastic. Ep-Tour-Tit veins run through the sample with polycrystalline aggregates of 0.25 – 0.5 mm brown Hbl crystals with some Tit now in mafic sites. There is also a fair amount of Pyx. A part of this sample is an intergrowth of Plag and 0.1 mm diopsidic Pyx. Both Act-rich and Ep (with a little Amph) veins crosscut this assemblage. Pale Act replaces darker brown Hbl in jackets around Ep veins. Hbl appears to be zoned. The clear matrix is polygranular Plag 0.25 mm in size. Some Mt is present in the rock, but about 50 percent is now altered to Hem. Tour has highly irregular grain boundaries and appears to be unstable although it is possible that it may also be part of the alteration assemblage. Tour ranges from blue to dark blue and non-pleochroic to brown and pleochroic and from 0.06 to 0.2 mm in size. Tour appears to be intergrown with zoned Ep.

C2B-708 Thin section: Spectacular large sprays of sky blue to tan Tour in rock with Calc-Ser (with light green pleochroism)-Hem and an unknown brown phase. Tour is either columnar with or without irregular somewhat eaten edges, a morphology that is also evident in Ep and Hem. This may reflect a later sericitic overprint of a calcic assemblage. Tour also contains micron-scale inclusions of zircon. Rare Allan is also present.

Chile\Copiapó\Candelaria\Cerro Granate

C3B-072a Hand sample: Recrystallized Plag-Rut-Chl(-Ser) rock possibly replacing tuff in the Abundancia Formation(?). This is cut by Tour ± Qtz vein with inner Plag-rich envelope and outer Kfs-dominated envelope.

Thin section: The Tour vein transitions from predominantly Tour with minor Calc to Tour with some Qtz locally intergrown with specular Hem. The envelope to the vein is virtually all Plag with sparse Rut or Hem. Along one edge of sample, there appears to be a Chl-Ser-Carb veinlet. Outside of the envelope the rock is an equigranular, fine grained Plag-dominant rock with distributed Ser-Chl-Rut(?) which accounts for ~5 percent of rock. There appears to be two generations of Tour, longer laths and more granular crystals, locally intergrown with iron oxide and Plag + Ser. Ep is somewhat ratty whereas the Tour is well formed. Tour has undulatory extinction. Pleochroism ranges from a very light color to a blue-green with brown undertones in some places. A smaller, fine-grained Tour + REE veinlet appears to run through the main vein (~0.04mm across). The majority of Tour in the vein is cm-scale

5 Chile\Copiapó\Candelaria\Española

C3B-381a Hand sample: Foliated breccia of Alb(-Tour-Qtz-Py) assemblage with Qtz-rich matrix probably superimposed on Alb-Py-altered volcanic or volcaniclastic rocks similar to C2B-287.

Thin section: This is a penetratively deformed rock with Qtz-Tour veins grading outward into Tour-Alb ± Fe sulfate (bright yellow) rock. The Fe sulfate is found predominantly in Plag-rich zone, which contains strongly aligned feldspars. Within the principal veins, there appear to be two generations of Tour, an early generation which is fine-grained (<0.02 mm), corroded, and granular, and a later generation that is coarser (up to 0.3 mm) and undeformed. There is also evidence of second generation Tour overgrowths on preexisting Tour. The later Tour are lathlike, 0.03 – 0.28 mm in length, euhedral, and intergrown with non-strained, non-oriented Qtz. The majority of Tour grains are optically zoned (from blue-green to brown) and Tour laths display tan to dark- blue green pleochroism. Opaque minerals appear to be mainly Lim and minor Rut.

Chile\Copiapó\Cerro Buitre Radio Tower

C2B-287 Hand sample: Alb-Py rock deformed and veined replacing a Qtz-poor porphyritic or phaneritic igneous rock. This may represent early (pre batholith?) sodic alteration, perhaps generated in a recharge zone.

Thin section: This sample is dominated by Plag with a cataclastic texture as well as Qtz. Plag had once been > 2/3 of rock as some of the larger crystals appear to have been Fsp phenocrysts. Plag is moderately turbid with no obvious Ser. It is quite possible that there is 20 percent Kfs (20% untwinned Fsp) in this sample as indicated by staining (found only by and in veinlets). There is ~5 percent Py in the rock along with minor Tour and Apat. Veins of cryptocrystalline, fine-grained Qtz are also present, some of which display yellowish birefringence. Some fine-grained Qtz is found cementing specular Hem crystals and can also be found in specular Hem veins and with Lim after Py. Tour is commonly found in clusters in association with Plag, Py, and Qtz and comprises maybe a few percent of the rock. Tour is columnar with tan to blue green pleochroism. Crystals are commonly anhedral or can occur in splays near Hem xtls (rare). Tour grains range from 0.02 to 0.1 mm in length and some grains display brown cores with blue rims.

C2B-576c Thin section: The rock contains abundant, green Bt-rich alteration. Specular Hem veins contain evidence for alteration of specular Hem to Mt and back to specular Hem. Hem(specular)-Bt veins cuts a granular Qtz vein that contains Cpy. Mt is roughly equant, but ratty. Elsewhere in the rock is coarse muscovite (few 100 µm) intergrown with Bt. Other veins are dominated by Bt and accessory Tour with rare Apat. There is no obvious chloritization of Bt. Tour is found solely in a Tour-Bt vein. Tour is small (commonly less than 0.05 mm), columnar, and pleochroic (tan to light blue).

6 C2J-124 Hand sample: Irregular, miarolitic-looking, aplitic rock with relatively little Kfs (stain). Texture destructive acid (sericitic?) alteration of rock with abundant Qtz + Musc(Ser) ± relict(?) Plag(?) and late generations of zoned Tour filling vugs. This is probably intensely altered La Brea.

Thin section: Zones consisting of mainly intergrown Alb-Qtz grading into Qtz-Tour- Hem(Mt?) comprise this sample. The Plag is variably sericitized. Most Tour grains are either brown and not very pleochroic or tan with pleochroism ranging from brown to green with light blue late cavity filling. Early Tour cores tend to have light gray to lavender pleochroism. Tour crystals commonly have corroded edges and range from 0.15 – 0.35 mm in length. Tour can also be massive and forms a prominent brown spot on the thin section. Tour also appears to overgrow 0.05 mm, equant to elongate zircon. Hem and Tour occur in common association with Qtz, but typically not with each other. Hem also contains tiny Rut needles.

C2J-334 Hand sample: La Brea-style porphyritic aplitic diorite with sodic(-calcic) overprint affecting the mafic sites and some of the Fsp. This is perhaps superimposed on earlier biotitic alteration. The main groundmass is gray and contains gray to weakly maroon Plag phenocrysts. Considerable Kfs in groundmass of rock is typical of this type of material when fresh and may not be reflective of alteration.

Thin section: This section contains sparsely porphyritic "adamellite" with 5 percent Plag >3 mm. Rare Opx and Cpx are almost completely converted to pale sheaves of Act, locally with Bt and rarely with blue to blue-gray to white Tour (± Lim). Tour is pleochroic, blue to tan, and ranges from 0.06 to 0.2 mm in length. Tour clusters tend to have ragged edges and occur in association with pale green Act, Lim, and Mt. Tour grains with corroded edges tend to have undulatory extinction. One Tour crystal has pink to dark blue-green pleochroism is subhedral, and 0.22 mm in length. Mt and Ilm are common (Mt>Ilm). The majority of Mt has Hem on {111} and both typically have Ilm rims. Late Qtz is widespread but less than 5 percent. Apat is common, often in crystals > 0.1 mm.

Chile\Copiapó\ Falla Ojancos_Transito_San Francisco

C6B-101b Hand sample: Banded white to brown-gray, Alb(-Py±Mt/Hem) rock with banded, fine-grained, Tour-rich veins, which are later cut by coarser Alb veinlets. The host is probably volcanic or volcaniclastic rocks.

Thin section: Tour occurs as granular bands of brown, moderate relief minerals in Alb-rich rock. Tour grains range from 0.05 – 0.1 mm across. Some of Tour bands are cut by coarse-grained Alb veins. Large Tour grains are zoned from dark brown to brown and are embayed in some cases. Lighter portions of the rock have Lim after Py and minor Mt as well as a sparse brown mineral. The brown mineral in question appears to have a

7 botryoidal texture and is very fine grained. The Plag is sodic Olig as determined by Michel-Levy and some large Olig sites could be relict phenocrysts. Plag appears to be slightly altered. Allan may also be present

C6B-107 Hand sample: Angular, matrix-supported breccia of Alb(±Py±Rut) clasts and host cut by Qtz-Tour veinlets. The dark green-gray matrix is very fine-grained Tour intergrown with Qtz.

Thin section: The host is a varied, very fine-grained, granular felsic rock with some clasts containing altered Plag (Alb by Michel-Levy) phenocrysts. The host is typical of much of what is seen at Santos as clasts and cataclastic textures and size reduction are evident. The rock is cut and veined by Qtz(± Tour ± Lim after sulfides). Qtz veins are clearly broken and transported in the breccia. Individual Qtz grains appear to be slightly deformed. The breccia matrix is very fine-grained, dark green-grey, and consists primarily of elongate, zoned grains of Tour 2-5 µm across. Tour also occurs outside of the breccia matrix, are commonly larger (10-20 µm), and intergrown with Qtz.

Chile\Copiapó\Jesus Maria

C7B-003a Hand sample: Tour-Dum assemblage in Qtz-Calc-rich sediments or volcaniclastic rocks possibly contact metamorphosed by the La Brea pluton.

Thin section: Tour is light blue and visibly zoned going from light brownish blue to blue-gray to very light from core to rim. Tour ranges in size from 25 μm to slightly greater than 0.3 mm. Tour also contains inclusions of acicular needles of Dum (>0.1 mm long and only microns across) and rare Anhy. Dum is very blue and is present throughout the rock but is concentrated in certain areas where they appear to have replaced earlier grains. Dum that replaced earlier grains tends to be very fine-grained (<0.01 mm). Early Tour appears unstable in areas where Dum is abundant. Tour is rimmed by a very pale late zone that appears to be in equilibrium with the other minerals. Late Tour also forms comb-like overgrowths on embayed or euhedral edges of early Tour. The groundmass contains abundant equigranular Qtz-Calc-Mt/Hem. Mt blades contain zones of replacive, specular Hem. Minor Ep is also present. Certain areas of the rock also contain Prl.

Chile\Copiapó\Ojancos Viejo

C3B-429.5 Hand sample: Alb(-Py-Clay[?]) altered volcanic or volcaniclastic rock cut by Tour-Py veinlets partly oxidized to Lim and Jar.

Thin section: This sample contains a Tour-Clay-Py (now Lim) vein cutting a Plag- dominated rock with 30 – 40 percent 0.5 – 1 mm, generally rectangular, but commonly irregular Plag in a groundmass of fine-grained Plag. Plag is twinned, shows little zoning, is variably turbid, and exhibits fairly uniform extinction. The overall texture is clastic to

8 cataclastic with minor specular Hem and Lim after Py in the matrix. The vein contains spectacularly zoned Tour and a colorless sheet silicate with first order gray colors. Tour is optically zoned with blue-green cores to brown rims and ranges between 0.2 – 10 mm in length and averages 0.2 mm across. Tour does not appear to have a preferred orientation within the vein and numerous cross-sections are visible. The vein also contains minor amounts of Plag. Outside of the vein, Tour is rare and occurs in association with Lim and Plag.

Chile\Copiapó\ San Gregorio S Granate

C2B-352e Hand sample: Coarse-grained, microgranite grading to coarser crystals with less Bt and seriate texture (1 – 3 mm) with a few larger Plag. At one end there is a Qtz-Tour- Kfs>Plag vein with interspersed miarolitic cavities. K-staining shows more intense color in hydrothermal assemblages, but there is no evidence of replacement. Tour-rich miarolitic segregation in aplitic dike cuts relatively fresh San Gregorio pluton. This is among the clearest and simplest magmatic tourmaline in the district.

Thin section: This sample consists of a Qtz-rich aplite/microgranite with variable textures yet constant proportions of minerals. There is a prominent Tour vein at one end that contains an abundance of relatively unaltered Plag along with Kfs and Qtz. All of these phases appear to have grown together. Tour is brown and massive with inclusions of Qtz and Tit. Plag grains in Tour vein have embayed edges. Late Tour forms needlelike, light blue overgrowths on early Tour. Outside of the vein the alkali Fsp is weakly perthitic, with an abundance of Plag dusted with white micas. There is also some Hem(Mt) and large grains of Ilm that look pretty fresh in places.

C2B-655 Thin section: Nearly jet black, opaque Tour is overgrown by multi-colored (dark blue, dark green, and various shades of brown) zoned Tour. There are several textures and in some areas Act is clearly being replaced. Ep-Mt-Tit-Plag are associated with Tour as well. There is abundant, coarse-grained Bt, Ep, and Tour. Possible Fe-sulfate (bright yellow mineral) may be present. Kfs and Qtz are also present. Tour is complexly zoned and has complex associations with other tourmalines as well as other minerals. Color ranges from brown to very dark blue and late generations of Tour are highly irregular. Late Calc veinlet runs through the section. Mt is the dominant oxide. There are at least three generations of Tour and brown Tour similar to that found in C2B-352e is also present.

C2B-671 Hand sample: This sample contains a complex Tour-bearing vein in brecciated, intensely sodic-calcic altered (Act-Ep-Chl-Alb), coarse-grained diorite either of San Gregorio age or older (La Brea). Sr work indicates small component of external Sr in the Act, however the main vein tourmaline has ratios identical to magmatic values.

Thin section: Brown Tour vein with network filling envelope is found with Alb (wide twins) adjacent to Ep-Act(Tit[yellow]-Mt-Apat-Cpx) altered San Gregorio monzodiorite.

9 Alb is much more common than either Act or Tit. Remarkably all Tour shows identical extinction and there is no obvious color zoning. Pleochroism ranges from light brown to dark brown and is similar in appearance to Tour from sample C2B-352e. The Tit color is also remarkable.

C2B-808.2 Hand sample: Relatively fresh, coarse-grained San Gregorio Qtz monzodiorite with early Pyx overgrown by late Amph and Bt. There are rare, late (proto-miarolitic?) Tour- bearing zones/cavities.

Thin section: This sample contains relict Opx bordered by Mt and overgrown by Bt which is overgrown by Amph. There are significant amounts of Alb (>15%) and Qtz (10%). Zircons are also present as inclusions in Bt, as evidenced by radiation damage halos. This rock also displays myrmekitic textures. Cpx is still present in places. Oxides are dominated by Mt with a Hem overprint on about 50 percent of existing crystals. 20 percent of the mafics are an equal distribution between Pyx and Bt, with good magmatic foliation. Tour exists in cavities and in alteration assemblages along with Bt, pale green Act, and beige Chl. Tour varies in color from tan to dark blue and appears to occur in two separate generations. The tan Tour tends to have corroded edges and is commonly intergrown with Bt, Chl, and Tit. The blue to dark blue, zoned Tour, on the other hand, tends to be prismatic except where overgrown by chloro-potassichastingsite. Individual Tour grains range from 0.01 – 1.4 mm in size. Other minerals with which Tour is found in close association are Plag, Opx and Qtz.

Chile\Copiapó\Santos PdC

DDH289-037.5a Hand sample: The contact between crystal-rich and crystal-poor biotitized porphyritic andesites is a Tour-Qtz-Py-rich zone that is perhaps at the original contact. The crystal- rich (35%, 0.5 – 1 mm Fsp) side appears to have a chilled margin against the contact. Thin Qtz veins are present in the crystal-rich side up into the chill zone. At one side of the contact Mt is variable whereas on the other Mt is associated with pinkish Fsp and rare Sulf veinlets.

Thin section: This sample contains a crystal-rich Plag porphyry (50%, 0.2-1 mm Plag; <5% mafic sites) with little or no original Qtz crystals. Qtz is now altered to turbid Alb with common Chl. Sparse Mt(Mushk?) veinlets are present along with common green- brown Bt in association with green-grey Chl in matrix and in Qtz veinlets. The timing of Bt and Chl is not clear, but Bt might post-date Chl in places. The breccia zone contains complex heterolithic fragments including very fine-grained trachytic clasts and others clasts containing isolated Fsp crystals. The matrix is very fine-grained and dark, though not uniform. Tour is locally present in veins with Qtz-Py-Bt ± Mt as radial splays. Tour is zoned, commonly with lighter cores in cuts looking down the c-axis or darker cores as evident in the radial splays. Individual crystals are 0.1 – 1.2 mm in length and 0.04 mm across on average. Tour is also pleochroic ranging from light tan to dark blue-green. Qtz veinlets, some of which contain Tit, cut host and breccia, but appear to be offset by Py-

10 Bt-Tour or Py-Mt-Ser-Bt veinlets along the main zone. Tour is present in the matrix as well. Py is both euhedral and has an unusual "shattered" habit where it might be locally replaced by Mt. Rare Lim, Ilm, and Ep are also present.

DDH291-188.4 Hand sample: Fine-grained, weakly porphyritic, dark green rock cut by several vein types including: a thick gray-green Chl(-Bt)-Py(-Cpy-Ep) vein (with Bt-Tour-Qtz-rich margin); various dark green, thin Bt veinlets (±Qtz±Tour); and a larger Ep-Qtz-Bt+Cpy vein. In hand specimen, the Qtz-Bt-Tour appears to cut the Ep-Cpy-Qtz-Bt vein. Kfs is locally present at one corner of the billet. There is also a possible Bt-rich envelope on a composite Act-Py-Cpy-Mt vein in fine-grained, medium to dark gray, felsic volcaniclastic or volcanic rock.

Thin section: This sample is composed of green, intensely biotitized, mafic(?) porphyritic rock with 20 – 30 percent, 0.1 – 0.4 mm mafic(?) sites now completely converted to green Bt as is the groundmass. 1-3 percent equant sites with Qtz-Ep-Bt may have been Fsp phenocrysts (0.2 mm). Multiple veins cut the rock. Two late vein types include Chl-Bt(-Ep-Qtz-Py-Cpy ± Tour)enveloped by Bt-Tour-Qtz and Qtz-Tour ± Bt ± Mt. These both cut coarse-grained Bt-Ep-Qtz(-Cpy) veinlets that have remarkably little deformation even though the cross-cutting Qtz veinlet is clearly deformed. Tour is only 0.04 mm on average, blue to tan, and is very small in comparison to larger Bt and Ep grains. Tour is commonly found in the Bt groundmass. Sulfides are restricted to the veins. Py is zoned. Mt is equant.

DDH384-004.2 Thin section: Tour vein (about 1 mm across) surrounded by sericitized Plag and Chl although it is also intergrown with well-formed Plag. Blades of specular Hem irregularly line the sides of the vein. Calc in very fine-grained masses to coarser grains is present in variable quantities throughout the vein. There seem to be Calc-replaced grains within the vein and in some areas there appears to be evidence of flow or deformation. Tour is variably fractured, ranges in size from 0.04 mm to >1mm, and are pleochroic from tan to blue-blue brown. Tour is also found as fine needles and coexists with specular Hem, Kfs and Calc. Yellow, zoned Ep is also present, but rare.

DDH628-094.2 Hand sample: Anhy-Py-Mushk-Cpy vein fill with Mushk-Cpy-Qtz outer vein in fine- grained gray host.

Thin section: This sample contains a composite Mushk-Anhy-Qtz-Cpy-Py-Tour vein in a complexly biotitized porphyritic host, possibly brecciated. The central part of the vein contains Anhy(-Cpy-Py) grading into an outer zone of Mushk-Qtz(-Cpy-Tour) where Tour occurs as isolated grains or in small clusters. Tour is columnar, zoned and appears to be growing off of the Mushk grains in some cases. Tour displays tan to brown pleochroism or is non-pleochroic with a light blue core and dark blue rims. The Qtz is strain-free for the most part and contains relatively large fluid inclusions of various types. The Bt-rich host appears to have Scap sprays in one area. This rock contains multiple

11 events with Ep-Mt-Cpy-Qtz-Chl in addition to fine-grained Bt and may represent an original or hydrothermal breccia of a weakly porphyritic rock.

DDH628-150.6/DDH628-151.6 Hand sample: Py-Cpy-Tour vein with white envelope cuts representative massively biotitized porphyritic host rock typical of a broad interval. K-stain shows that Kfs is abundant throughout the matrix, mainly in the groundmass but appears to be absent in the white vein envelope.

Thin section: Intensely biotitized, porphyritic volcanic rock with 30 percent, 0.2 – 0.5 mm biotitized phenocrysts has abundant clouds of Mt away from central vein. Mt disappears approaching vein. Kfs might become more intense and in the inner (white) envelope Qtz replaces most minerals, although some green-brown Bt remains. There is one spot of blue-green Bt. Allan is locally present in envelope. The main vein is Tour-Py- Cpy(-Mt[Cpy]-Allan-Chl-Bt) and also contains scattered amounts of Apat. Allan shows nice twins. The host contains thin Qtz-Bt (-Cpy-Ep) veinlets that are truncated by the large vein. A late Calc veinlet cuts the large vein. The vein has abundant Tour ranging from less than 0.02 - 0.2 mm and is also found within Py and chloritized grains outside of the vein. Tour is pleochroic from tan to blue-blue brown and is variably fractured perpendicular to the c-axis

DDH628-626.3 Hand sample: This sample contains a Mushk-Py-Act-Scap veinlet with Bt-rich envelope in dark host.

Thin section: This sample contains a large Scap-pale blue-green Bt(-Chl) vein that is offset in the middle of the section by about 1.3 cm. The Scap within the vein lacks a preferred orientation. Py with minor Mt and trace Cpy occurs in the vein as well. Py crystals are ragged and have spotted margins in places with abundant tiny inclusions of Cpy and silicates. Mt within the vein locally contains Cpy as well. The vein has an apparent brown/olive green Bt-Mt(trace Allan-blue Tour) envelope grading out into less Bt-(and Mt?)rich material. The main vein cuts veinlets with Qtz-Apat-Bt-Mt. Qtz-Apat- Kfs is found along edges of the Scap vein as well. A Qtz-Tour vein cuts through the envelope, but is truncated by the Scap-Bt vein. Tour has no preferred orientation, is pleochroic (tan to blue), and can either be columnar (0.02 – 0.08 mm in length) or occur in radial splays (0.02 mm across). Tour is found within biotitized clasts (rare) as well as scattered in trace amounts throughout the groundmass.

DDH643-595.5 Hand sample: Angular, breccia zone with tan clasts with Mt rims. The matrix is Qtz with gray, variably feldspathic clasts and host. Sparse, later Mt[Py] veinlets with possible Kfs are also present.

Thin section: This sample consists of a composite Qtz-Allan-Tour-Mt/Mushk-Cpy- Kfs breccia zone with many shard-like clasts cutting through biotitized porphyritic rock. The dark host contains 10-15 percent, 0.3 – 0.8 mm Fsp phenocrysts partly altered to

12 green Bt, but mainly to secondary Fsp (possibly Alb) ± Qtz with 10 percent fine-grained Mt + rare Rut in original oxide sites(?). This grades into a Kfs-altered zone/vein towards the margin of the breccia with less Mt, sparse very fine-grained Chl, and no Bt. Other clasts on this side of the section show similar features and appear to be mixed and cut by Qtz-Allan-Tour-Mt/Mushk-Cpy-Kfs veins/matrix. A prominent trapezoidal clast is surrounded by several generations of Qtz. At one end, it has massive Chl-Allan-Mt ± Tour which grades into Mt-rich porphyry with Bt-Mt-Kfs±Qtz. This clast is cut on one side by a composite Qtz/Qtz-Tour vein and the breccia side by Qtz-Tour-Allan which had an earlier Allan-Tour vein that is later cut by a Qtz vein at the short end. The clasts in the Qtz vein are combinations of Allan-Qtz-Chl-Tour with various Tour or Allan rims, sugary or recrystallized Qtz zones, and accessory Mt. All of these features are cemented by several generations of Qtz-Allan(Ep)-Tour-Mt-Mushk-Cpy. Tour is columnar, commonly zoned with lighter cores and darker rims, and occurs in association with Allan, Bt, Mt, Mushk, Qtz, Py, Chl. The length of Tour grains ranges from to 0.01 – 0.3 mm. Tour inside clasts, some of which are deformed, appear to have the same optical character as the Tour rimming the clast. There is evident replacement of Plag(?) by Allan, Chl, Qtz, Mt, and Mushk.

DDH684-079.8 Hand sample: Fine-grained biotitzed, phenocryst-absent, volcanic rock (medium to dark green in color) with clast(?) of darker green material, cut by Fe oxide veins and by a dark dike(?) of Qtz-Tour-Py breccia fill, ragged edges, and white, Alb-rich envelope.

Thin section: The host is biotitized subequigranular rock with abundant 0.2 mm Qtz and Plag, probably volcaniclastic protolith. Mafic sites now contain very fine-grained aggregates of bright green Bt. Similar Bt (rarely Chl) occurs along veins with Cpy-Mushk and early Py. Py in matrix can be complexely zoned. The veins have Kfs-Qtz ± Bt (or Chl) in addition to Mushk[Py] and Sulf. Very fine-grained, dark zone of Qtz-Tour with mafic-free Qtz-Plag envelope, a rim of Mt(partly Mushk)-Cpy and inclusions of Qtz-Plag and Qtz-Tour (with sharp contacts) and interior Cpy[Py]-Py-Hem-Mt (equilibrium textures). Pale to blue Tour are very fine-grained to greater than 0.1 mm. Pleochroism ranges from pale yellow to light green or blue. Only a few tourmaline intergrown with Qtz are >0.2 mm. Tour does not occur outside of the vein.

ME013-538 Hand sample: Composite Bt-Sulf(-Tour-Ep) vein with clasts in complexly altered albitofiro. Envelope on vein appears to be Bt-rich (tan with green patches) and grades out into less altered texture-preserving material.

Thin section: This sample is comprised of red Bt-Tour-rich vein with later Ep + Py(+Sphalerite-Cpy) in a Bt-rich, altered, porphyritic volcanic rock. The host also contains scattered Py+Sph(Cpy)+Ep+Qtz. Sph is quite abundant as small grains and can be found in Fsp sites as well as veins and vugs. Two different colors of Bt correspond to differences in color in the rocks: pale green and deep red brown. Tour is small (<0.2mm), blue, columnar, and occurs with Ep, Bt, Lim, Py, Qtz, Plag.

13 Chile\Copiapó\Vinita Azul

C6B-160b Hand sample: Bedded grayish quartzite (possibly originally volcaniclastic now completely altered) with sand grains up to 0.4 mm cut with And(-Hem-Laz-Tour- Pyroph[?]) assemblage with a possible metamorphic overprint on earlier alteration assemblage.

Thin section: 66 percent sutured Qtz, 25 percent And, 5 percent Hem, and <2 percent Rut comprise this sample with minor fibrous, blue Tour, trace Lazul, and minor (<5 percent) brownish fine-grained, second order colored sheet silicate (Pyroph?) that appears to be late. The rock is cut by a veinlet of Hem-And-Tour ± Qtz with large And crystals (less than or equal to 1 mm) overgrowing Hem and may possibly be metamorphic in origin. And is subhedral and poikilitic. Rut occurs in equant grains whereas Hem is elongate. Tour tends to have a columnar crystal habit and Tour aggregates are no larger than 0.08 mm. Pleochroism ranges from light tan to blue.

Mineral abbreviations Act: actinolite, Alb: albite, Allan: allanite, Amph: amphibole, And: andalusite, Anhy: anhydrite, Apat: apatite, Bt: biotite, Calc: calcite, Carb: carbonate, Chl: chlorite, Cpx: clinopyroxene, Cpy: chalcopyrite, Dum: dumortierite, Ep: epidote, Fsp: feldspar, Hem: hematite, Hbl: hornblende, Jar: jarosite, Jsp: jasperoid, Kfs: K-feldspar, Lazul: lazulite, Lim: limonite, Mt: magnetite, Musc: muscovite, Mushk: musketovite, Olig: oligoclase, Opx: orthopyroxene, Plag: plagioclase, Prl: pyrophyllite, Py: pyrite, Pyx: pyroxene; Qtz: quartz, Rut: rutile, Scap: scapolite, Ser: sericite, Sph: sphalerite, Sulf: sulfides, Tit: titanite, Tour: tourmaline

Appendix 4: Chemical characteristics of each sample

Chile\Cerro Negro Norte

C6B-076 Tourmaline within the vein is primarily euhedral with concentric zoning. Some tourmaline grains contain anhedral cores with albite overgrowths, followed by concentric, euhedral tourmaline that becomes progressively more aluminous and magnesian and then drops back towards the initial composition. Fine-grained tourmalines appear to have low Al, but comparable Mg# values to the coarse-grained tourmaline. Outside of the vein, tourmaline is corroded and has embayed edges with cores that have higher Al and Mg/(Fe+Mg) values than the optically darker, later rims. There is a positive correlation between Na and Al, with optically lighter cores and rims displaying the highest concentrations of both elements, and a negative correlation between Ti and Al as well as Fe and Al. Tourmaline compositions changed from primarily dravitic to uvitic compositions with some variation in Fe contents.

Chile\Copiapó\Candelaria\Cerro Bronce_Estrella

C2B-298

14 The earliest generation of blue tourmaline plots on the schorl-dravite solid solution series whereas later, darker tourmaline overgrowths are more calcic and geochemically similar to the brown tourmaline found in another part of the section. Brown tourmalines from this area have intermediate Mg/(Fe+Mg) values and belong to the uvite-feruvite solid solution series. Unlike the earliest generation, later tourmalines are also Al-deficient (less than 5 apfu Al) and have higher Ti contents (up to 0.3 apfu).

C2B-708 Tourmalines in this sample have almost no Ti. Early generations of tourmaline are dravitic whereas later generations are schorls, Al-deficient, and have slightly higher Ca contents (up to 0.3 apfu). Fe-rich generations are optically darker than the dravitic generation.

Chile\Copiapó\Candelaria\Cerro Granate

C3B-072a Tourmaline from this locality plots within the schorl-buergerite compositional field and ranges from Al-rich to Al-deficient denoting an overall change from aluminous to more Fe-rich compositions. As with many of the tourmalines from this area, the chemical variation is not uniform. Overall, zoning is highly complex and it appears that the Fe-rich generation acts as fracture-fill in more aluminous phases during a different tourmaline- forming event. The Mg/(Fe+Mg) values range from about 0.2 to 0.4. Ca concentration increases from about 0 to almost 0.2 apfu in later generations, but Na is the dominant alkali.

Chile\Copiapó\Candelaria\Española

C3B-381a Late tourmaline laths and overgrowths tend to be deficient in Mg and Al in comparison to the earlier, granular generation. However, late tourmaline has higher Fe and Na concentrations than the early generation. These generations form two distinct groupings. Within the granular generation there seems to be very little variation in the Al content, but there is an overall increase in Mg and decrease in Fe from core to rim (schorl-dravite substitution along the YMg  YFe2+ exchange vector). This generation also has slightly higher Ca values (possible uvitic component). However, in some areas with dark euhedral to subhedral cores with well-preserved zonation it appears that Fe increases as Mg decreases from the core to the rim. Zones in late tourmaline display the opposite trend with decreasing Fe and slight increases in Mg and Al from core to rim. Tourmaline chemistry changes from dravite in the granular generation to schorl in the later generation.

Chile\Copiapó\Cerro Buitre Radio Tower

C2B-287 The tourmaline in this sample represent two chemically distinct generations between which there is no compositional continuum. The tourmaline is not concentrically zoned and the earlier cores have highly irregular boundaries within the later, rimming

15 generation. The first generation is Mg- and Ti-rich (averaging around 0.45 apfu, but can be as much as 0.8 apfu) whereas the second generation is Fe-rich and Ti-poor. F also tends to be higher in the first generation (up to 0.19 apfu). The Al values of both phases are comparable. Overall, these tourmalines are dravites with the later generation trending towards more intermediate schorl-dravite compositions.

C2B-576c Surprisingly, tourmalines from this sample are not zoned although there is evidence for slight chemical variation. Tourmalines from this sample are largely Fe-rich dravites and have greater than 6 apfu Al.

C2J-124 Older generations of tourmaline tend to have lower concentrations of Fe and Mg, which corresponds to a higher Al content, than the younger tourmaline host, thus forming a chemically distinct group. The first generation is also Na-poor and has embayed or corroded edges. It is evident that the early generation was destabilized and incorporated into a Na-, Fe-, and Mg-rich generation. There is also evidence for a distinct generation that is Fe-rich and Mg-poor and is part of the later rimming phase. Zoning is patchy or interfingering with optically lighter zones corresponding to higher Na contents than darker zones. This style of zonation may indicate a different substrate for tourmaline growth and/or the tourmalinization of an earlier mineral. Lighter cores surrounded by darker rims tend to have higher Fe and lower Mg concentrations than its rims. Because zonation is so complex, there is no uniform progression in elemental abundance. Later generations of tourmaline have higher Ti and F contents. The tourmalines are schorl- dravite in composition.

C2J-334 The core of a single tourmaline lath has slightly higher Al and Mg/(Fe+Mg) values than the latest rims on opposite ends. The latest rims appear to plot in a single group with lower Al, but comparable Mg/(Fe+Mg) values, than the darker cores. The latest rims also appear to have slightly higher to comparable Ca contents with little room for vacancies, whereas the earlier group has a slightly higher foitite component. The same trend is not observed in all tourmaline grains and there is no apparent correlation between Na and Al. Overall, these tourmalines are uvitic in composition.

Chile\Copiapó\ Falla Ojancos_Transito_San Francisco

C6B-101b These tourmaline have high Ti overall (up to 0.4 apfu) with respect to C6B-107. The most abundant generation is Mg-rich and may contain Fe-rich cores and rims. These tourmalines plot within the dravite compositional field.

C6B-107 In this sample, cores are more aluminous and magnesian in comparison to rims or certain sectors/apices which have low Al and slightly lower Mg/(Fe+Mg) values. Lighter zones in back scattered electron images have the highest Ca, Fe, and Ti contents and the

16 lowest Na and Al values. There is no direct correlation between Na and Al although there are two different groupings corresponding to lighter and darker zones. Tourmaline compositions are dravitic.

Chile\Copiapó\Jesus Maria

C7B-003a Tourmaline cores are Fe-rich and, where present, are rimmed by euhedral to anhedral Mg-rich tourmaline. These later phases may later be rimmed by an acicular to comb-like Al-rich tourmaline phase. F contents range from slightly greater than 0.2 apfu in the earliest generation to 0 apfu in the latest generation. In areas where dumortierite is most abundant only the early, Fe-rich tourmaline generation remains and is highly irregular. Tourmaline compositions plots along the foitite-magnesiofoitite solid solution.

Chile\Copiapó\Ojancos Viejo

C3B-429.5 Zoning is highly irregular and patchy. There appear to be three main groupings. The first appears to correlate with the zone that is closest to the center of the tourmaline in sections parallel to the c-axis. This group has the greatest Al concentrations and low Fe, Ca, and Na. The second grouping corresponds to the final, dark (in back scattered electron imaging) zone exhibited by the majority of the tourmaline grains with high Mg, higher Ca, moderate Al, lower Na, and low Fe contents (possibly indicative of YMg  YFe2+ and XNa + YAl  XCa + YMg substitution). The third group corresponds to early and late lighter zones that can be found irregularly rimming group 1, being rimmed by group 2 and, in turn, also rimming group 2. This group has the highest Na concentrations, high Fe, moderate Mg and Al, and low Ca contents. In tourmaline with concentric zones, there is no real trend. Overall, intact cores tend to have the highest Fe concentrations and the latest rims have lower Fe concentrations than the earlier rims (schorl-dravite substitution). Later rims, those with low Fe contents, have higher and highly variable Ca and Ti concentrations whereas tourmaline cores occupy a narrow range of Ca and Ti values. The composition of tourmaline is initially dravitic trending towards uvite and schorl.

Chile\Copiapó\ San Gregorio S Granate

C2B-352e Some tourmaline generations from this locality overlap the brown, Ti-rich generation found in sample C2B-808.2 as well as the blue tourmaline cluster found in the same sample. There is a late, light green, Al-rich tourmaline generation (similar to those seen in C2J-124) that forms acicular needles around preexisting tourmalines and can also be found in cavities. Tourmaline compositions from this locality range from schorl- buergerite to feruvite. There is no clear relationship between Fe, Mg, and Al or any systematic change in composition.

C2B-655

17 This sample contains Fe-rich, Al-deficient tourmaline cores, overgrown by comparably Al-rich, subhedral rims that are slightly replaced by Fe-rich, Al-deficient tourmaline. Both the early and the latest generations appear to have the same composition. The Al-rich rims have intermediate schorl-dravite compositions whereas the Fe-rich generations have intermediate feruvite-uvite compositions. The latter generations tends to have higher Ti contents (up to 0.3 apfu).Where the third generation of tourmaline is not present, the Al-rich generation is altered and appears to have multiple reaction rims and textures. A late dravitic generation is also present and tends to be subhedral and sky blue.

C2B-671 There are multiple generations of tourmaline, but for the most part they fall into two populations: a lower Al and higher Ti (slightly higher than 0.3 apfu), intermediate feruvite-uvite population that is locally rimmed and infilled by a more aluminous phase that has a higher sodic component.

C2B-808.2 This sample contains two distinct episodes of tourmaline growth. The first is blue, Fe- rich, complexly optically and compositionally zoned, and slightly replaced by chloro- potassic-hastingsite. The second generation is brown, Mg- and Ti-rich and intergrown with titanite. There is no clear relationship between Fe, Mg, and Al. The overall tourmaline composition of this sample fluctuated from schorl to feruvite back to schorl.

Chile\Copiapó\Santos PdC

DDH289-037.5 Later generations of tourmaline have higher Fe contents and lower concentrations of Na, Mg, and Al although there is no progressive trend. Tourmaline crystals with corroded or inclusion-rich cores have lower Mg/(Fe+Mg) values than well-formed tourmaline with preserved zonation. Overall, cores appear to have among the highest Mg and Fe concentrations combined with the lowest Al values in comparison to the other zones. Optically lighter cores tend to have high Al and Na contents. Within the same tourmaline lath, Na content changes by almost 0.3 apfu from one end to another. Cross-sections of tourmaline perpendicular to c show a marked increase in Al and a slight decrease in Na followed by an Al content that is midway between the core and first zone, but with lower Na content. Tourmaline compositions are primarily schorl-dravite. There appears to be no set pattern to Fe-Mg chemical variation.

DDH291-188.4 Tourmaline has intermediate schorl-dravite compositions with slightly more magnesian later generations. Ti is low and Ca is variable (up to 0.3 apfu) and tourmaline is well formed. Al contents range between 5.5 and 6 apfu.

DDH384-004.2 Early generations tend to have a higher uvitic component than later generations which have higher Na contents and are slightly more magnesian. Later generations often rim

18 earlier generations or are found in fractures. Overall, these tourmalines can be classified as dravites.

DDH628-094.2 Blue tourmalines tend to have a slightly higher X-site vacancy, Ti, and Fe values than tan tourmalines. Tourmalines from this sample display concentric to patchy zoning and are euhedral. Ca content is low. The tourmalines from this sample can be classified as Mg-rich schorls.

DDH628-151.6 There are at least three tourmaline generations from this sample. All tourmalines tend to have high Na/(Na+Ca) values (generally greater than 0.75) and have intermediate schorl-dravite compositions. Tourmaline cores tend to have slightly higher Fe values than rimming phases although rims outside of the vein tend to have high Fe contents as well. Ti contents are low overall.

DDH628-626.3 Tourmaline cores are highly deficient in Ca. The rims contain negligible Ca, but higher overall values than the core. Ti appears to be inversely correlated to Fe on the majority of the rims, but not in cores. The cores contain Fe, Mg, Al, and Na and have higher Mg/(Fe+Mg) values than the rims which tend to have higher Al concentrations and lower Mg/(Fe+Mg) values overall. In the rims, where Fe and Al are high, Mg and Na are low. The zones alternate between high Mg and Na to high Al and Fe. The final preserved rim shows high Fe and Al contents. This trend is consistent with alkali-defect [NaMg(□Al)-1] and Mg(Fe)-1 substitutions. The former substitution is supported by a positive linear correlation between Al and X-site vacancies, suggesting a magnesiofoitite component. There is also a negative linear correlation between Na and Al. In fine-grained vein tourmaline, there appears to be no progressive change in composition as the zoning is highly irregular. Overall, tourmaline compositions plot in the schorl-dravite compositional fields.

DDH643-595.5 There are three potential tourmaline generations in this sample. Tourmaline cores are commonly Fe-rich dravites and tend to have higher Na and Mg contents than later rims. The second generation has lower Na and higher Ca and Fe than the first generation, forms euhedral rims, and has intermediate schorl-dravite compositions. The latest generation is a Mg-rich schorl with higher Na/(Na+Ca) values than the first generation and comparable to slightly greater Fe contents. This later generation also has variable vacancy ratios up to 0.55. Overall, these tourmalines are only slightly Al-deficient (Al contents less than 6 apfu).

DDH684-079.8 Tourmalines from this sample are very fine-grained and have intermediate schorl- dravite compositions with low Ca and Ti.

ME013-538

19 Tourmalines from this sample are well-formed and contain low Ti and Ca. Zoning is patchy to concentric. Overall, these tourmalines are schorls with the core of one tourmaline containing a significant foititic component.

Chile\Copiapó\Vinita Azul

C6B-160b Tourmalines from this area have low F and 0.3 – 0.5 apfu X-site vacancies. Tourmaline composition falls along the dravite-magnesiofoitite solid solution and is Al- rich with greater than 6 apfu Al. There is no evident zoning.

Appendix 5: Other interesting graphs This section contains interesting graphs (Figs A2-A4) reinforcing the trend towards a similar Fe-rich composition and negative correlation between Al and total Fe as well as variations in other elements such as Ti and F. High Ti and the presence of hydrothermal titanite could be related to the breakdown of hornblende during hydrothermal alteration (Lynch and Ortega, 1997). Slack and Coad (1989) noted that systematic Ti variations may be also be controlled indirectly by the chemical potential of Al during alteration and mineralization (i.e., □Ti(NaAl)-1). F concentrations are highly variable in Copiapó tourmaline, but early generations generally have the highest F contents.

References cited in Appendix Aggarwal, J.K., Mezger, K., Pernicka, E., and Meixner, A., 2004. The effect of instrumental mass bias on d11B measurements: A comparison between thermal ionisation mass spectrometry and multiple collector ICP-MS. International Journal of Mass Spectrometry, 232, 259–263. Bloodaxe, E. S., Hughes, J. M., Dyar, M. D., Grew, E. S., and Guidotti, C. (1999). Linking structure and chemistry in the schorl-dravite series. American Mineralogist, 84, 922-928. Clark, C. M. (2007). Tourmaline; Structural formula calculations. The Canadian Mineralogist, 45, 229-237. Dutrow, B. L., and Henry, D. J. (2000). Complexly zoned fibrous tourmaline, Cruzeiro Mine, Minas Gerais, Brazil: A record of evolving magmatic and hydrothermal fluids. The Canadian Mineralogist, 38, 131-143.

20 Dyar, M. D., Taylor, M. E., Lutz, T. M., Francis, C. A., Guidotti, C. V., and Wise, M. (1998). Inclusive chemical characterization of tourmaline: Mossbauer study of Fe valence and site occupancy. American Mineralogist, 83, 848-864. Dyar, M. D., Wiedenbeck, M., Robertson, D., Cross, L. R., Delaney, J. S., Ferguson, K., Francis, C. A., Grew, E. S., Guidotti, C. V., Hervig, R. L., Hughes, J. M., Husler, J., Leeman, W., McGuire, A. V., Rhede, D., Rothe, H., Paul, R. L., Richards, I., andYates, M. (2001). Reference minerals for the microanalysis of light elements. Geostandards and Geoanalytical Research, 25(2-3), 441-463. Fialin, M., Bezos, A., Wagner, C., Magnien, V., and Humler, E. (2004). Quantitative electron microprobe analysis of Fe3+/∑Fe: Basic concepts and experimental protocol for glasses. American Mineralogist, 89(4), 654-662. Grice, J. D., and Ercit, T. S. (1993). Ordering of Fe and Mg in the tourmaline crystal structure; the correct formula. Neues Jahrbuch fuer Mineralogie Abhandlungen, 165(3), 245-266. Hawthorne, F. C. (1996). Structural mechanisms for light-element variations in tourmaline. The Canadian Mineralogist, 34, 123-132. Henry, D. J., and Dutrow, B. L. (1996). Metamorphic tourmaline and its petrologic applications. Reviews in Mineralogy, 33, 503-557. Hermon, E., Simkin, D. J., Donnay, G., and Muir, W. B. (1973). The distribution of Fe (super 2+) and Fe (super 3+) in iron-bearing tourmalines; A Mossbauer study. Tschermak's Mineralogische und Petrographische Meitteilungen, 19(2), 124-132. Hughes, K. A., Hughes, J. M., and Dyar, M. B. (2001). Chemical and structural evidence for [4]B <=> [4]Si substitution in natural tourmalines. European Journal of Mineralogy, 13, 743-747. Lynch, G., and Ortega, J. (1997). Hydrothermal alteration and tourmaline-albite equilibria at the Coxheath porphyry Cu-Mo-Au deposit, Nova Scotia. The Canadian Mineralogist, 35, 79-94. MacDonald, D. J., and Hawthorne, F. C. (1995). The crystal chemistry of Si <=> Al substitution in tourmaline. The Canadian Mineralogist, 33, 849-858. Pouchou, J. L., and Pichoir, F. (1984). A new model for quantitative x-ray microanalysis. Part I: Applications to the analysis of homogeneous samples. Recherche Aérospatiale(5), 13-38. Schreyer, W., Hughes, J. M., Bernhardt, H.-J., Kalt, A., Prowatke, S., and Ertl, A. (2002). Reexamination of olenite from the type locality: detection of boron in tetrahedral coordination. European Journal of Mineralogy, 14, 935-942. Swihart, G. H., and Moore, P. B. (1989). A reconnaissance of the boron isotopic composition of tourmaline. Geochimica et Cosmochimica Acta, 53, 911-916.

Figure Captions Fig. A1. Calibration curve for Fe and Copiapó tourmaline graph with formula

Fig. A2. Fe/(Fe+Mg) vs. Al graph. The trend to an intermediate schorl-dravite composition is most evident in this graph.

21 Fig. A3. Na vs. F graph showing distinct to gradual changes in F content. Early generations tend to have the highest F contents and either have high Mg, high Al, and/ or are vacancy-rich.

Fig. A4. Al vs. Ti graph showing an apparent negative correlation between Al and Ti when Al is less than 6 apfu. There also does not appear to be a correlation between alteration assemblage and overall Ti concentrations.

Tables

3+ Table A1: Fe /Fetotal ratios derived from working curves based on work by Fialin et al. (2004)

Table A2: All tourmaline analyses from this study

Table A3: All framework silicate analyses from this study

Table A4: All sheet silicate analyses from this study

Table A5: All pyroxene analyses from this study

Table A6: All epidote analyses from this study

Table A7: All amphibole analyses from this study

Table A8: All oxide analyses from this study

Figure A1

3+ RelationshipRelationship between Febetween and ?Fe Fe in3+ Chileanand total tourmalines Fe

1.00

0.90 y = 0.0477x - 0.0583 y = 0.0458x - 0.0528 R2 = 0.7891 R2 = 0.7197 0.80 y = 0.0371x + 0.0323 R2 = 0.6571 0.70

0.60 all valid data C2B C6B /?Fe 0.50 3+ (Linear (all valid data C2J Fe (Linear (C2B 0.40 (Linear (C6B

0.30

0.20

0.10

0.00 0 5 10 15 20 25 30 Fe wt% Figure A2 Figure A3 Figure A4

AlFe-1 NaAl(CaMg)-1

CaTi(Al)-2

NaAl(□Ti)-1 2+ Table A1. Fe /Fetotal ratios derived from working curves using the methods outlined by Fialin et al. (2004) 2+ Sample no. Fe /Fetotal Cerro Bronce_Estrella C2B-298 0.6 C2B-708 0.6 Cerro Buitre Radio Tower C2B-287 0.45 C2B-576c 0.77 C2J-124 0.55 C2J-334 0.65 Cerro Granate C3B-072a 0.56 C3B-130 0.8 Cerro Negro Norte C6B-076 0.7 Espanola C3B-381a 0.84 Falla Ojancos_Transito San Francisco C6B-101b 0.64 C6B-107 0.81 Jesus Maria C7B-003a 0.71 Ojancos Viejo C3B-429.5 0.72 San Gregorio_S Granate C2B-352e 0.57 C2B-655 0.53 C2B-671 0.55 C2B-808.2 0.39 Santos_PdC DDH289-037.5 0.75 DDH291-188.4 0.77 DDH384-004.2 0.78 DDH628-094.2 0.64 DDH628-150.6 0.68 DDH628-626.3 0.64 DDH643-595.5 0.68 DDH684-079.8 0.67 ME013-538 0.67 Vinita Azul C6B-160b 0.72 Table A2. Chemical analyses of tourmalines from Copiapó, Chile

Locality Sample Spot no. Analysis no. SiO2 TiO2 Al2O3 B2O3 Cr2O3 Fe2O3 FeO MgO Cerro Bronce Estrella C2B-298 1 t1 35.51 1.52 23.96 10.20 0.01 5.33 7.33 8.67 Cerro Bronce Estrella C2B-298 1 t3 35.11 1.75 21.52 10.07 0.01 7.12 9.79 7.76 Cerro Bronce Estrella C2B-298 1 t4 35.06 2.40 21.63 10.01 0.01 6.38 8.74 7.96 Cerro Bronce Estrella C2B-298 1 t5 35.41 1.22 23.32 10.14 0.01 5.95 8.06 8.34 Cerro Bronce Estrella C2B-298 1 t1 35.26 0.28 22.86 10.14 0.00 6.94 9.52 7.99 Cerro Bronce Estrella C2B-298 1 t2 36.24 0.43 25.26 10.37 0.00 4.55 6.23 9.77 Cerro Bronce Estrella C2B-298 1 t3 36.75 0.38 29.12 10.54 0.00 3.01 4.16 9.30 Cerro Bronce Estrella C2B-298 1 t4 35.51 0.85 23.85 10.18 0.01 5.40 7.46 8.87 Cerro Bronce Estrella C2B-298 1 t5 35.62 2.35 23.79 10.26 0.01 5.18 7.04 8.94 Cerro Bronce Estrella C2B-298 1 t6 35.71 0.55 26.17 10.28 0.00 5.83 8.02 7.18 Cerro Bronce Estrella C2B-708 1 t1 36.93 0.00 31.23 10.59 0.00 4.21 5.77 6.47 Cerro Bronce Estrella C2B-708 1 t2 36.16 0.08 28.23 10.37 0.00 5.62 7.62 6.30 Cerro Bronce Estrella C2B-708 1 t3 36.43 0.02 32.22 10.52 0.00 5.09 6.96 4.49 Cerro Bronce Estrella C2B-708 1 t4 35.81 0.00 27.78 10.32 0.00 6.42 8.74 5.62 Cerro Bronce Estrella C2B-708 1 t5 36.69 0.02 31.44 10.56 0.00 4.30 5.81 6.25 Cerro Bronce Estrella C2B-708 1 t6 35.92 0.02 28.95 10.42 0.00 5.87 7.94 5.90 Cerro Bronce Estrella C2B-708 1 t7 35.86 0.02 27.38 10.35 0.00 6.28 8.59 6.20 Cerro Bronce Estrella C2B-708 1 t8 35.75 0.15 27.91 10.24 0.00 5.73 7.87 5.84 Cerro Bronce Estrella C2B-708 2 t1 35.83 0.00 32.20 10.49 0.00 4.47 6.06 5.55 Cerro Bronce Estrella C2B-708 2 t2 35.26 0.02 29.76 10.22 0.00 7.82 10.72 1.99 Cerro Bronce Estrella C2B-708 2 t3 35.60 0.23 30.16 10.44 0.00 5.41 7.33 5.75 Cerro Buitre Radio Tower C2B-287 1 t1 36.91 0.12 28.64 10.46 0.01 6.62 4.98 6.93 Cerro Buitre Radio Tower C2B-287 1 t3 37.47 3.90 29.17 10.77 0.01 0.30 0.23 11.70 Cerro Buitre Radio Tower C2B-287 1 t5 35.99 0.36 26.60 10.33 0.00 8.42 6.20 6.66 Cerro Buitre Radio Tower C2B-287 1 t6 36.24 0.52 26.34 10.38 0.01 8.75 6.45 6.57 Cerro Buitre Radio Tower C2B-287 1 t7 37.78 3.83 29.15 10.79 0.02 0.33 0.24 11.62 Cerro Buitre Radio Tower C2B-287 1 t9 36.97 0.11 30.53 10.58 0.00 5.85 4.32 6.85 Cerro Buitre Radio Tower C2B-287 1 t10 37.01 0.12 29.51 10.56 0.01 6.41 4.80 6.85 Cerro Buitre Radio Tower C2B-287 1 t12 36.81 0.08 29.94 10.56 0.00 5.46 4.12 7.60 Cerro Buitre Radio Tower C2B-287 1 t13 36.79 0.05 29.23 10.54 0.01 6.55 4.82 7.13 Cerro Buitre Radio Tower C2B-287 1 t14 36.69 0.27 28.36 10.53 0.01 7.43 5.55 6.84 Cerro Buitre Radio Tower C2B-287 1 t15 36.44 0.16 27.45 10.45 0.01 8.03 5.95 6.84 Cerro Buitre Radio Tower C2B-287 1 t16 36.53 0.05 30.39 10.51 0.00 6.43 4.74 6.36 Cerro Buitre Radio Tower C2B-287 1 t17 37.41 3.88 29.16 10.79 0.02 0.32 0.24 11.83 Cerro Buitre Radio Tower C2B-287 1 t18 37.35 3.93 29.28 10.77 0.02 0.35 0.26 11.62 Cerro Buitre Radio Tower C2B-287 1 t19 36.98 0.05 30.68 10.61 0.00 5.68 4.24 7.10 Cerro Buitre Radio Tower C2B-287 1 t20 37.13 3.83 29.29 10.73 0.01 0.31 0.22 11.61 Cerro Buitre Radio Tower C2B-287 1 t21 36.77 0.08 30.53 10.55 0.00 5.43 4.04 7.17 Cerro Buitre Radio Tower C2B-287 1 t23 37.19 3.57 28.91 10.70 0.03 0.44 0.33 11.68 Cerro Buitre Radio Tower C2B-287 1 t24 36.79 0.06 30.21 10.54 0.00 6.30 4.72 6.58 Cerro Buitre Radio Tower C2B-287 1 t25 37.31 3.82 29.39 10.77 0.01 0.28 0.21 11.66 Cerro Buitre Radio Tower C2B-287 1 t26 36.19 0.14 27.39 10.43 0.00 8.10 5.97 6.91 Cerro Buitre Radio Tower C2B-287 1 t27 37.28 0.05 29.83 10.60 0.00 6.30 4.68 6.95 Cerro Buitre Radio Tower C2B-287 1 t28 37.16 3.80 29.06 10.69 0.02 0.28 0.21 11.58 Cerro Buitre Radio Tower C2B-287 1 t29 36.53 0.14 29.43 10.52 0.00 6.49 4.86 7.03 Cerro Buitre Radio Tower C2B-287 1 t30 36.01 0.71 26.03 10.34 0.00 8.66 6.41 6.76 Cerro Buitre Radio Tower C2B-287 1 t31 36.99 0.02 31.43 10.63 0.01 4.94 3.66 7.32 Cerro Buitre Radio Tower C2B-287 1 t32 35.80 0.26 25.63 10.28 0.00 8.92 6.71 6.77 Cerro Buitre Radio Tower C2B-287 1 t33 36.56 0.06 28.57 10.48 0.00 7.04 5.30 7.00 Cerro Buitre Radio Tower C2B-287 1 t34 36.59 0.11 29.29 10.53 0.00 6.77 5.01 6.96 Cerro Buitre Radio Tower C2B-287 1 t35 37.41 3.85 28.67 10.75 0.01 0.49 0.37 11.92 Cerro Buitre Radio Tower C2B-287 1 t36 37.53 3.58 29.20 10.79 0.02 0.39 0.28 11.77 Cerro Buitre Radio Tower C2B-287 1 t37 37.37 3.25 29.68 10.78 0.03 0.40 0.30 11.58 Cerro Buitre Radio Tower C2B-287 1 t38 36.72 0.23 29.21 10.56 0.01 6.76 4.99 7.07 Cerro Buitre Radio Tower C2B-287 2 t1 37.03 2.79 29.18 10.71 0.01 2.61 1.94 10.11 Cerro Buitre Radio Tower C2B-287 2 t2 36.59 0.06 29.24 10.53 0.00 7.29 5.43 6.49 Cerro Buitre Radio Tower C2B-287 2 t3 36.86 0.04 30.93 10.63 0.00 5.38 4.05 7.33 Cerro Buitre Radio Tower C2B-287 2 t4 37.11 0.05 32.04 10.66 0.00 4.63 3.42 7.20 Cerro Buitre Radio Tower C2B-287 2 t5 36.83 3.94 28.19 10.64 0.02 1.95 1.44 10.50 Cerro Buitre Radio Tower C2B-287 2 t6 36.65 4.72 27.08 10.59 0.01 2.46 1.87 10.30 Cerro Buitre Radio Tower C2B-287 2 t8 36.79 0.10 29.97 10.56 0.00 6.56 4.84 6.66 Cerro Buitre Radio Tower C2B-287 2 t9 36.22 6.22 22.54 10.41 0.02 4.19 3.09 10.71 Cerro Buitre Radio Tower C2B-287 2 t10 37.06 0.11 31.11 10.62 0.02 5.25 3.90 7.11 Cerro Buitre Radio Tower C2B-287 2 t11 36.66 0.08 29.37 10.53 0.00 6.86 5.16 6.71 Cerro Buitre Radio Tower C2B-287 2 t12 36.59 0.07 29.38 10.53 0.00 6.94 5.16 6.75 Cerro Buitre Radio Tower C2B-287 2 t13 37.05 0.10 31.01 10.64 0.00 5.26 3.88 7.33 Cerro Buitre Radio Tower C2B-287 2 t14 36.94 4.72 27.30 10.65 0.01 1.19 0.88 11.51 Cerro Buitre Radio Tower C2B-287 2 t15 37.25 3.84 29.52 10.77 0.02 0.27 0.20 11.60 Cerro Buitre Radio Tower C2B-287 2 t16 36.55 5.53 24.33 10.49 0.04 2.94 2.17 11.01 Cerro Buitre Radio Tower C2B-287 2 t17 36.50 0.25 27.78 10.42 0.00 7.63 5.70 6.66 Cerro Buitre Radio Tower C2B-287 2 t18 36.57 5.47 24.39 10.49 0.02 3.32 2.46 10.71 Cerro Buitre Radio Tower C2B-287 2 t19 37.64 3.21 29.67 10.78 0.02 0.38 0.28 11.54 Cerro Buitre Radio Tower C2B-287 2 t20 36.90 0.10 30.01 10.58 0.00 6.44 4.78 6.78 Cerro Buitre Radio Tower C2B-287 2 t21 37.63 3.23 29.72 10.83 0.01 0.49 0.37 11.67 Cerro Buitre Radio Tower C2B-287 2 t22 37.00 0.08 29.04 10.58 0.00 6.77 5.12 7.15 Cerro Buitre Radio Tower C2B-287 2 t23 37.56 3.20 29.98 10.83 0.02 0.38 0.27 11.64 Cerro Buitre Radio Tower C2B-287 2 t24 36.70 0.06 28.23 10.52 0.00 6.98 5.24 7.44 Cerro Buitre Radio Tower C2B-287 3 t1 36.96 0.05 31.09 10.63 0.00 5.29 3.99 7.20 Cerro Buitre Radio Tower C2B-287 3 t2 36.63 0.06 29.23 10.49 0.00 6.67 4.92 6.89 Cerro Buitre Radio Tower C2B-287 3 t3 37.09 0.09 29.27 10.59 0.00 1.97 8.14 7.64 Cerro Buitre Radio Tower C2B-287 3 t5 37.59 0.05 31.46 10.72 0.00 5.02 3.77 7.30 Cerro Buitre Radio Tower C2B-287 3 t6 37.37 4.53 27.77 10.71 0.02 0.67 0.50 11.78 Cerro Buitre Radio Tower C2B-287 3 t7 37.47 3.39 29.40 10.80 0.01 0.63 0.47 11.66 Cerro Buitre Radio Tower C2B-287 3 t8 37.47 3.48 29.67 10.82 0.02 0.37 0.28 11.69 Cerro Buitre Radio Tower C2B-287 3 t9 37.32 0.04 31.65 10.66 0.00 5.04 3.71 6.98 Cerro Buitre Radio Tower C2B-287 3 t10 37.46 3.39 29.80 10.80 0.01 0.38 0.28 11.58 Cerro Buitre Radio Tower C2B-287 3 t11 37.09 0.10 30.69 10.63 0.00 5.84 4.31 6.96 Cerro Buitre Radio Tower C2B-287 3 t13 35.71 1.14 25.26 10.31 0.01 9.02 6.74 6.78 Cerro Buitre Radio Tower C2B-287 3 t14 37.39 3.65 29.49 10.80 0.02 0.32 0.24 11.74 Cerro Buitre Radio Tower C2B-287 3 t15 37.36 0.05 31.38 10.66 0.00 5.14 3.89 7.06 Cerro Buitre Radio Tower C2B-287 3 t16 37.39 3.77 29.27 10.79 0.01 0.30 0.22 11.84 Cerro Buitre Radio Tower C2B-287 3 t18 36.76 0.11 30.12 10.52 0.01 6.15 4.59 6.62 Cerro Buitre Radio Tower C2B-287 3 t19 37.29 3.75 27.93 10.68 0.02 1.18 0.89 11.54 Cerro Buitre Radio Tower C2B-287 3 t20 36.53 0.18 28.73 10.50 0.00 6.94 5.17 7.03 Cerro Buitre Radio Tower C2B-576c 1 t1 35.59 0.40 32.55 10.44 0.00 2.08 6.43 6.00 Cerro Buitre Radio Tower C2B-576c 1 t2 36.83 0.36 34.19 10.75 0.00 1.98 6.12 5.85 Cerro Buitre Radio Tower C2B-576c 1 t3 37.08 0.27 34.04 10.67 0.00 1.81 5.58 5.83 Cerro Buitre Radio Tower C2B-576c 1 t4 36.74 0.22 31.08 10.58 0.00 2.64 7.98 6.08 Cerro Buitre Radio Tower C2B-576c 2 t1 35.72 0.36 33.57 10.49 0.00 2.02 6.09 5.64 Cerro Buitre Radio Tower C2B-576c 2 t2 36.13 0.46 31.85 10.46 0.00 2.07 6.26 6.34 Cerro Buitre Radio Tower C2J-124 2 2m 35.65 1.85 26.22 10.44 0.01 4.55 5.13 9.34 Cerro Buitre Radio Tower C2J-124 1 t1 36.45 1.24 27.64 10.52 0.02 4.49 4.97 8.65 Cerro Buitre Radio Tower C2J-124 1 t2 36.62 0.79 29.17 10.54 0.00 3.42 3.83 8.94 Cerro Buitre Radio Tower C2J-124 1 t3 35.87 1.19 28.29 10.47 0.01 4.16 4.65 8.65 Cerro Buitre Radio Tower C2J-124 1 t4 37.26 0.04 34.97 10.83 0.01 1.65 1.84 8.01 Cerro Buitre Radio Tower C2J-124 1 t5 36.42 0.04 34.63 10.77 0.00 2.01 2.24 8.18 Cerro Buitre Radio Tower C2J-124 1 t6 35.99 1.25 27.45 10.46 0.01 4.65 5.21 8.51 Cerro Buitre Radio Tower C2J-124 1 t7 35.69 1.45 26.53 10.40 0.01 5.07 5.59 8.62 Cerro Buitre Radio Tower C2J-124 1 t8 36.78 0.05 31.52 10.70 0.00 2.97 3.38 8.77 Cerro Buitre Radio Tower C2J-124 1 t10 37.59 0.02 34.78 10.89 0.01 1.54 1.71 8.44 Cerro Buitre Radio Tower C2J-124 1 t11 36.14 1.22 27.95 10.48 0.01 4.35 4.80 8.57 Cerro Buitre Radio Tower C2J-124 2 m1 37.18 0.03 32.79 10.73 0.01 2.19 2.41 8.61 Cerro Buitre Radio Tower C2J-124 2 2a 36.07 1.12 29.32 10.46 0.01 3.83 4.30 8.09 Cerro Buitre Radio Tower C2J-124 2 2b 37.49 0.06 32.89 10.75 0.00 1.95 2.21 8.66 Cerro Buitre Radio Tower C2J-124 2 2c 36.08 1.68 27.47 10.50 0.02 4.08 4.51 9.17 Cerro Buitre Radio Tower C2J-124 2 2d 35.94 1.58 26.82 10.44 0.01 4.30 4.74 9.20 Cerro Buitre Radio Tower C2J-124 2 2e 37.20 0.03 32.65 10.73 0.01 1.74 1.93 9.26 Cerro Buitre Radio Tower C2J-124 2 2f 37.30 0.02 33.18 10.79 0.00 2.01 2.23 8.87 Cerro Buitre Radio Tower C2J-124 2 2g 37.02 0.02 31.56 10.67 0.00 2.36 2.63 9.22 Cerro Buitre Radio Tower C2J-124 2 2h 35.46 1.82 25.85 10.42 0.01 4.95 5.57 9.20 Cerro Buitre Radio Tower C2J-124 2 2i 35.95 1.64 27.12 10.46 0.02 3.93 4.50 9.41 Cerro Buitre Radio Tower C2J-124 2 2j 37.38 0.03 33.40 10.84 0.00 1.63 1.80 9.30 Cerro Buitre Radio Tower C2J-124 2 2k 37.19 0.16 32.62 10.91 0.00 2.70 3.05 8.82 Cerro Buitre Radio Tower C2J-124 2 2l 36.03 1.74 26.69 10.46 0.01 4.41 4.91 9.11 Cerro Buitre Radio Tower C2J-124 3 tour2c 36.20 0.76 28.89 10.53 0.01 3.96 4.40 8.79 Cerro Buitre Radio Tower C2J-124 3 tour2b 37.33 0.21 32.02 10.73 0.00 2.51 2.79 8.74 Cerro Buitre Radio Tower C2J-124 3 tour2a 36.53 0.14 30.18 10.59 0.00 3.67 4.05 8.59 Cerro Buitre Radio Tower C2J-124 3 tour2r 36.46 0.46 29.69 10.59 0.01 3.28 3.62 9.29 Cerro Buitre Radio Tower C2J-124 3 tour2q 36.02 0.77 27.84 10.50 0.01 4.89 5.41 8.46 Cerro Buitre Radio Tower C2J-124 3 tour2bq 36.09 0.30 29.87 10.46 0.00 3.63 4.04 8.38 Cerro Buitre Radio Tower C2J-124 3 tour2b1 35.53 0.91 28.17 10.47 0.01 4.68 5.17 8.51 Cerro Buitre Radio Tower C2J-124 3 tour2b2 36.11 0.72 28.46 10.48 0.01 4.23 4.69 8.60 Cerro Buitre Radio Tower C2J-124 3 tour2b3 35.75 0.74 28.43 10.44 0.01 4.29 4.82 8.56 Cerro Buitre Radio Tower C2J-124 3 tour1a 35.94 1.12 26.92 10.41 0.01 4.70 5.31 8.66 Cerro Buitre Radio Tower C2J-124 3 tour1b 36.51 0.03 33.41 10.73 0.00 2.58 2.87 8.20 Cerro Buitre Radio Tower C2J-124 3 tour1c 35.40 0.14 29.91 10.26 0.01 3.21 3.61 8.12 Cerro Buitre Radio Tower C2J-124 3 tour1ba 35.97 1.04 28.29 10.53 0.01 4.39 4.93 8.72 Cerro Buitre Radio Tower C2J-124 3 tour1bb 35.72 0.65 27.51 10.44 0.00 4.97 5.61 8.45 Cerro Buitre Radio Tower C2J-124 3 tour1bc 37.16 0.00 33.92 10.77 0.01 1.86 2.10 8.40 Cerro Buitre Radio Tower C2J-124 3 tour1bd 36.34 0.17 28.68 10.55 0.01 4.29 4.88 8.84 Cerro Buitre Radio Tower C2J-124 3 tour1bf 35.94 0.55 28.33 10.48 0.00 4.47 4.99 8.64 Cerro Buitre Radio Tower C2J-124 3 tour1a 36.06 1.54 27.26 10.49 0.01 4.16 4.65 9.21 Cerro Buitre Radio Tower C2J-124 3 tour1b 35.95 1.46 26.91 10.42 0.01 4.19 4.66 9.16 Cerro Buitre Radio Tower C2J-334 1 t1 35.90 0.42 28.13 10.43 0.00 4.51 7.69 7.14 Cerro Buitre Radio Tower C2J-334 1 t2 36.31 0.29 29.11 10.46 0.00 4.17 7.00 6.93 Cerro Buitre Radio Tower C2J-334 1 t3 35.79 0.36 28.24 10.44 0.00 4.53 7.72 7.22 Cerro Buitre Radio Tower C2J-334 2 t1 36.16 0.39 27.53 10.38 0.00 4.48 7.58 7.26 Cerro Buitre Radio Tower C2J-334 2 t2 35.90 0.68 26.06 10.28 0.00 4.95 8.30 7.26 Cerro Buitre Radio Tower C2J-334 2 t3 35.70 0.36 28.92 10.38 0.01 4.21 7.05 6.94 Cerro Buitre Radio Tower C2J-334 2 t4 35.07 0.22 28.72 10.12 0.01 3.85 6.45 6.58 Cerro Buitre Radio Tower C2J-334 2 t5 37.05 0.40 26.89 10.40 0.00 4.34 7.31 7.50 Cerro Granate C3B-072a 1 t1 36.04 0.16 29.73 10.41 0.00 6.62 7.78 4.81 Cerro Granate C3B-072a 1 t2 35.73 0.29 31.05 10.41 0.01 6.47 7.47 4.14 Cerro Granate C3B-072a 1 t3 35.79 0.20 29.55 10.34 0.00 7.06 8.10 4.27 Cerro Granate C3B-072a 1 t4 35.39 0.16 28.35 10.24 0.00 8.69 10.01 3.03 Cerro Granate C3B-072a 1 t5 35.79 0.14 30.69 10.40 0.00 6.91 8.09 3.83 Cerro Granate C3B-072a 2 t1 36.68 0.05 32.07 10.54 0.00 6.31 7.38 3.68 Cerro Granate C3B-072a 2 t2 35.56 0.55 27.73 10.27 0.00 8.15 9.43 4.01 Cerro Granate C3B-072a 2 t3 35.40 0.11 30.09 10.33 0.00 7.67 9.10 3.24 Cerro Granate C3B-072a 2 t4 35.34 0.22 28.66 10.24 0.00 7.53 8.66 4.15 Cerro Granate C3B-072a 2 t5 35.19 0.48 27.09 10.18 0.00 8.53 10.10 3.66 Cerro Granate C3B-072a 2 t6 35.55 0.10 29.22 10.31 0.00 7.81 9.13 3.61 Cerro Granate C3B-072a 3 t1 36.02 0.10 28.09 10.37 0.00 3.44 10.99 5.70 Cerro Granate C3B-072a 3 t2 34.76 0.21 20.67 10.00 0.02 11.80 12.27 5.27 Cerro Granate C3B-072a 3 t3 35.53 0.15 30.57 10.33 0.00 1.91 12.70 3.64 Cerro Granate C3B-072a 3 t4 35.79 0.03 30.32 10.33 0.00 2.03 14.08 2.89 Cerro Negro Norte C6B-076 1 t1 35.48 1.29 24.76 10.36 0.00 4.17 8.90 8.79 Cerro Negro Norte C6B-076 1 t3 35.92 0.90 26.21 10.38 0.00 3.69 7.82 8.54 Cerro Negro Norte C6B-076 1 t4 36.35 0.51 29.52 10.58 0.00 2.99 6.39 8.15 Cerro Negro Norte C6B-076 1 t5 36.11 0.76 25.57 10.44 0.00 3.79 8.10 9.07 Cerro Negro Norte C6B-076 1 t6 35.45 0.71 25.47 10.27 0.00 3.60 7.57 9.04 Cerro Negro Norte C6B-076 1 t7 35.90 0.80 27.09 10.42 0.00 3.62 7.96 8.08 Cerro Negro Norte C6B-076 1 t8 36.13 0.71 28.08 10.50 0.00 3.47 7.41 8.06 Cerro Negro Norte C6B-076 1 t9 36.05 0.60 28.54 10.54 0.00 3.44 7.30 8.09 Cerro Negro Norte C6B-076 1 t10 36.03 0.79 27.45 10.48 0.00 3.55 7.66 8.25 Cerro Negro Norte C6B-076 1 t11 36.43 0.56 27.46 10.57 0.00 3.30 7.13 9.05 Cerro Negro Norte C6B-076 1 t13 35.98 0.49 29.76 10.49 0.00 2.83 6.16 7.88 Cerro Negro Norte C6B-076 1 t14 35.70 0.92 26.84 10.42 0.00 3.49 7.66 8.57 Cerro Negro Norte C6B-076 1 t16 36.45 0.21 30.27 10.60 0.00 2.85 6.20 7.93 Cerro Negro Norte C6B-076 1 t17 34.90 0.42 28.12 10.21 0.01 3.28 6.92 7.66 Cerro Negro Norte C6B-076 1 t18 36.05 0.43 28.40 10.47 0.01 3.34 7.02 8.10 Cerro Negro Norte C6B-076 1 t19 36.61 0.44 30.41 10.59 0.00 2.67 5.68 7.92 Cerro Negro Norte C6B-076 1 t20 36.83 0.13 31.43 10.65 0.00 2.15 4.64 8.32 Cerro Negro Norte C6B-076 1 t21 36.11 0.35 28.74 10.41 0.00 3.48 7.40 7.20 Cerro Negro Norte C6B-076 1 t22 36.25 0.70 28.74 10.47 0.00 3.11 6.57 7.93 Cerro Negro Norte C6B-076 1 t23 35.98 0.78 27.83 10.44 0.00 3.38 7.28 8.06 Cerro Negro Norte C6B-076 1 t24 35.90 0.52 27.06 10.32 0.00 3.11 6.55 8.72 Cerro Negro Norte C6B-076 1 t25 36.12 0.56 29.13 10.48 0.00 2.99 6.48 7.95 Cerro Negro Norte C6B-076 1 t26 35.74 0.84 25.86 10.31 0.00 3.60 7.82 8.58 Cerro Negro Norte C6B-076 1 t27 35.55 1.67 25.90 10.35 0.00 3.49 7.54 8.70 Cerro Negro Norte C6B-076 1 t28 36.22 0.47 29.02 10.48 0.00 3.04 6.51 7.96 Cerro Negro Norte C6B-076 1 t29 35.47 0.80 24.95 10.23 0.00 3.68 7.84 8.97 Cerro Negro Norte C6B-076 1 t30 35.71 0.99 25.14 10.29 0.00 3.90 8.41 8.48 Cerro Negro Norte C6B-076 1 t31 35.46 1.33 25.82 10.26 0.00 3.59 7.65 8.35 Cerro Negro Norte C6B-076 2 t1 36.36 0.19 29.62 10.57 0.00 2.82 6.12 8.42 Cerro Negro Norte C6B-076 2 t2 35.49 0.60 25.96 10.29 0.01 3.90 8.48 8.15 Cerro Negro Norte C6B-076 2 t3 35.96 0.57 27.69 10.42 0.01 3.30 7.16 8.31 Cerro Negro Norte C6B-076 2 t4 36.66 0.11 30.87 10.61 0.00 2.65 5.80 7.77 Cerro Negro Norte C6B-076 2 t5 36.13 0.49 27.92 10.47 0.00 3.09 6.76 8.65 Cerro Negro Norte C6B-076 2 t6 35.74 0.62 25.90 10.37 0.00 4.01 8.70 8.34 Cerro Negro Norte C6B-076 2 t7 35.47 1.16 25.07 10.35 0.01 3.74 7.97 9.32 Cerro Negro Norte C6B-076 2 t8 36.61 0.13 30.46 10.58 0.01 2.98 6.40 7.45 Cerro Negro Norte C6B-076 2 t9 36.12 0.56 27.87 10.47 0.00 3.15 6.82 8.61 Cerro Negro Norte C6B-076 2 t9-1 36.88 0.09 31.27 10.67 0.00 2.19 4.62 8.56 Cerro Negro Norte C6B-076 2 t10 36.11 0.43 28.64 10.48 0.01 2.74 5.98 8.81 Cerro Negro Norte C6B-076 2 t11 35.43 1.46 24.57 10.33 0.00 4.12 8.85 8.79 Cerro Negro Norte C6B-076 2 t12 35.61 1.40 25.17 10.37 0.01 3.85 8.36 8.87 Cerro Negro Norte C6B-076 2 t13 35.59 1.42 25.13 10.38 0.01 4.02 8.59 8.71 Cerro Negro Norte C6B-076 2 t14 36.61 0.13 31.10 10.64 0.00 2.70 5.87 7.68 Cerro Negro Norte C6B-076 2 t15 35.71 0.62 28.13 10.46 0.00 3.72 7.81 7.77 Cerro Negro Norte C6B-076 3 t2 35.26 1.48 23.68 10.27 0.01 4.33 9.19 8.91 Cerro Negro Norte C6B-076 3 t3 35.35 1.27 24.87 10.34 0.00 4.06 8.60 8.95 Cerro Negro Norte C6B-076 3 b1 36.05 0.55 28.94 10.45 0.01 3.32 7.11 7.48 Cerro Negro Norte C6B-076 3 t4 36.02 0.85 28.74 10.51 0.00 2.75 5.86 8.80 Cerro Negro Norte C6B-076 3 t5 35.85 0.73 27.01 10.46 0.00 3.20 6.92 9.26 Cerro Negro Norte C6B-076 3 t6 35.65 1.04 26.45 10.34 0.00 3.43 7.27 8.69 Cerro Negro Norte C6B-076 3 t7 35.23 1.31 24.53 10.26 0.01 3.98 8.49 8.86 Cerro Negro Norte C6B-076 3 a6 36.25 0.58 29.27 10.56 0.00 3.13 6.57 8.08 Cerro Negro Norte C6B-076 3 b1 36.05 0.55 28.94 10.45 0.01 3.28 7.15 7.48 Cerro Negro Norte C6B-076 4 t1 35.01 1.15 24.36 10.25 0.00 3.93 8.46 9.24 Cerro Negro Norte C6B-076 4 t2 36.71 0.61 29.72 10.70 0.01 2.40 5.05 9.42 Cerro Negro Norte C6B-076 4 t3 35.43 1.24 24.85 10.33 0.00 3.84 8.21 9.18 Cerro Negro Norte C6B-076 4 t4 36.52 0.39 30.38 10.55 0.00 2.70 5.69 7.75 Cerro Negro Norte C6B-076 4 t5 35.96 0.24 29.72 10.46 0.00 3.22 6.81 7.33 Cerro Negro Norte C6B-076 4 t6 35.54 1.15 25.09 10.34 0.00 3.61 7.89 9.33 Cerro Negro Norte C6B-076 4 t8 36.24 0.25 30.29 10.53 0.01 2.87 6.14 7.68 Cerro Negro Norte C6B-076 4 t9 36.00 0.59 28.12 10.43 0.00 3.26 7.04 8.07 Cerro Negro Norte C6B-076 4 t10 35.81 0.57 27.67 10.37 0.00 3.65 7.92 7.57 Cerro Negro Norte C6B-076 4 t11 35.96 0.73 29.02 10.48 0.00 3.10 6.69 7.91 Cerro Negro Norte C6B-076 4 t12 34.58 1.82 22.82 10.05 0.00 5.12 11.21 7.11 Cerro Negro Norte C6B-076 4 t13 35.76 0.83 27.75 10.37 0.00 3.42 7.31 7.82 Cerro Negro Norte C6B-076 4 t14 36.66 0.43 29.60 10.59 0.00 2.97 6.44 7.99 Española C3B-381a 1 t1 36.04 0.12 28.31 10.39 0.00 3.25 8.47 7.13 Española C3B-381a 1 t2a 35.94 1.87 32.52 10.59 0.01 0.75 3.55 8.05 Española C3B-381a 1 t2b 36.50 1.66 33.67 10.74 0.02 0.49 2.43 8.50 Española C3B-381a 1 t2c 36.43 1.91 32.56 10.65 0.01 0.45 2.15 9.04 Española C3B-381a 1 t3a 37.12 0.44 33.90 10.72 0.01 0.59 2.82 8.18 Española C3B-381a 1 t3b 37.31 0.29 34.22 10.82 0.01 0.56 2.82 8.42 Española C3B-381a 1 t3c 37.28 0.51 33.95 10.75 0.01 0.49 2.43 8.42 Española C3B-381a 2 t1a 36.64 0.06 30.32 10.48 0.00 1.50 7.55 7.07 Española C3B-381a 2 t1c 35.83 0.12 26.91 10.30 0.00 4.11 9.96 6.57 Española C3B-381a 2 t2a 35.84 0.09 28.43 10.41 0.00 3.72 8.17 7.19 Española C3B-381a 2 t3a 36.30 1.79 32.72 10.66 0.02 0.71 3.48 8.19 Española C3B-381a 2 t3b 36.66 2.11 33.03 10.74 0.01 0.17 0.83 9.70 Española C3B-381a 2 t4a 37.11 0.73 33.13 10.72 0.01 0.40 1.93 9.26 Española C3B-381a 2 t4b 36.69 2.01 32.96 10.75 0.02 0.37 1.82 9.24 Española C3B-381a 2 t4c 36.61 2.05 32.69 10.75 0.03 0.25 1.19 9.64 Española C3B-381a 2 t5 36.61 1.21 29.44 10.48 0.00 1.74 8.74 6.41 Española C3B-381a 3 t1b 36.89 1.11 34.54 10.80 0.00 0.40 1.96 8.57 Española C3B-381a 3 t1c 35.80 0.96 35.01 10.73 0.00 1.04 5.10 6.49 Española C3B-381a 3 t2 36.42 0.11 31.17 10.49 0.00 1.88 9.35 5.40 Española C3B-381a 3 t2a 36.25 0.13 31.46 10.47 0.00 1.74 8.65 5.61 Española C3B-381a 3 t3a 35.97 1.04 36.29 10.81 0.01 0.21 1.02 8.50 Española C3B-381a 3 t3c 36.27 0.18 29.47 10.46 0.01 1.95 9.58 6.43 Española C3B-381a 3 t3d 37.36 1.36 33.16 10.69 0.01 0.72 3.41 7.55 Española C3B-381a 3 t5 35.80 0.15 27.87 10.32 0.01 3.30 9.91 6.35 Falla Ojancos Transito San Francisco C6B-101b 1 t1 36.31 2.99 24.90 10.30 0.02 4.08 6.74 8.21 Falla Ojancos Transito San Francisco C6B-101b 1 t2 36.46 3.01 25.88 10.42 0.05 3.30 5.30 9.23 Falla Ojancos Transito San Francisco C6B-101b 1 t3 36.43 2.88 25.29 10.31 0.01 3.81 6.28 8.36 Falla Ojancos Transito San Francisco C6B-101b 1 t4 35.97 3.02 25.08 10.24 0.03 3.73 6.20 8.43 Falla Ojancos Transito San Francisco C6B-101b 1 t5 36.14 3.00 25.92 10.40 0.15 3.29 5.34 9.22 Falla Ojancos Transito San Francisco C6B-101b 2 t1 36.78 2.59 26.46 10.49 0.02 3.13 5.11 9.38 Falla Ojancos Transito San Francisco C6B-101b 2 t2 36.59 2.90 26.16 10.46 0.01 3.20 5.12 9.40 Falla Ojancos Transito San Francisco C6B-101b 2 t3 36.69 2.47 27.46 10.52 0.01 3.15 5.09 8.86 Falla Ojancos Transito San Francisco C6B-101b 2 t4 36.92 2.25 27.59 10.53 0.00 3.08 5.01 8.90 Falla Ojancos Transito San Francisco C6B-101b 2 t5 36.86 2.53 27.03 10.52 0.01 3.09 5.01 9.16 Falla Ojancos Transito San Francisco C6B-107 1 t1 37.84 0.54 31.72 10.81 0.01 1.28 5.10 8.22 Falla Ojancos Transito San Francisco C6B-107 1 t2 37.47 1.03 29.65 10.73 0.01 1.39 5.55 9.03 Falla Ojancos Transito San Francisco C6B-107 1 t3 37.44 1.39 28.84 10.71 0.02 1.54 6.03 9.06 Falla Ojancos Transito San Francisco C6B-107 1 t5 37.91 0.31 31.54 10.87 0.00 1.31 5.19 8.73 Falla Ojancos Transito San Francisco C6B-107 1 t7 37.19 1.03 28.78 10.69 0.00 1.72 6.67 8.94 Falla Ojancos Transito San Francisco C6B-107 1 t8 37.48 0.45 31.75 10.80 0.01 1.22 4.82 8.59 Falla Ojancos Transito San Francisco C6B-107 1 t10 38.16 0.19 31.00 10.85 0.00 1.33 5.35 8.86 Falla Ojancos Transito San Francisco C6B-107 1 t11 37.98 0.18 31.95 10.90 0.00 1.28 5.03 8.75 Falla Ojancos Transito San Francisco C6B-107 1 t12 38.09 0.38 30.81 10.80 0.00 1.46 5.65 8.43 Falla Ojancos Transito San Francisco C6B-107 1 t14 38.38 0.35 31.66 10.86 0.01 1.16 4.51 8.75 Falla Ojancos Transito San Francisco C6B-107 1 t15 38.43 0.16 31.60 10.87 0.00 1.23 4.82 8.71 Falla Ojancos Transito San Francisco C6B-107 2 t1 38.22 0.14 30.85 10.86 0.00 1.47 5.72 8.78 Falla Ojancos Transito San Francisco C6B-107 2 t2 37.71 0.39 30.25 10.75 0.00 1.69 6.66 8.16 Falla Ojancos Transito San Francisco C6B-107 2 t3 37.72 0.16 30.15 10.79 0.00 1.60 6.47 8.73 Falla Ojancos Transito San Francisco C6B-107 2 t4 38.14 0.17 31.69 10.85 0.00 1.34 5.39 8.19 Falla Ojancos Transito San Francisco C6B-107 2 t5 37.69 0.41 29.41 10.75 0.01 1.72 6.97 8.60 Falla Ojancos Transito San Francisco C6B-107 2 t6 38.26 0.23 30.93 10.86 0.01 1.39 5.34 8.80 Falla Ojancos Transito San Francisco C6B-107 2 t7 37.96 0.52 30.95 10.80 0.01 1.28 5.16 8.69 Falla Ojancos Transito San Francisco C6B-107 2 t8 38.70 0.36 31.91 10.92 0.01 1.05 4.08 8.92 Falla Ojancos Transito San Francisco C6B-107 2 t9 37.59 0.38 31.94 10.79 0.01 1.29 4.97 8.31 Falla Ojancos Transito San Francisco C6B-107 2 t10 38.06 0.18 32.09 10.85 0.00 1.24 4.84 8.38 Jesus Maria C7B-003a 1 t1 36.30 0.14 36.49 10.76 0.02 1.28 9.10 3.25 Jesus Maria C7B-003a 1 t2 36.63 0.13 37.04 10.84 0.01 1.29 9.02 3.14 Jesus Maria C7B-003a 1 t3 36.43 0.13 36.73 10.76 0.02 1.28 8.88 3.14 Jesus Maria C7B-003a 1 t4 36.49 0.13 37.00 10.77 0.02 3.06 7.00 3.08 Jesus Maria C7B-003a 2 t1 36.46 0.07 37.02 10.76 0.01 3.08 6.97 3.06 Jesus Maria C7B-003a 2 t2 38.91 0.03 36.37 11.06 0.01 0.70 1.55 7.91 Jesus Maria C7B-003a 2 t3 38.13 0.01 34.52 10.91 0.00 1.84 4.06 7.06 Jesus Maria C7B-003a 2 t4 38.56 0.01 36.15 11.01 0.00 1.66 3.72 6.36 Jesus Maria C7B-003a 2 t5 38.88 0.03 36.02 11.09 0.00 0.87 1.96 8.11 Jesus Maria C7B-003a 2 t6 36.16 0.12 36.28 10.73 0.00 3.41 7.73 3.06 Jesus Maria C7B-003a 2 t8 38.43 0.00 35.83 10.98 0.00 0.88 1.96 7.92 Jesus Maria C7B-003a 3 t1 36.77 0.12 36.56 10.78 0.01 3.31 7.49 2.91 Jesus Maria C7B-003a 3 t2 36.45 0.15 36.33 10.71 0.02 3.31 7.39 2.94 Jesus Maria C7B-003a 3 t3 38.69 0.02 35.69 11.06 0.00 0.81 1.84 8.41 Jesus Maria C7B-003a 3 t4 39.24 0.01 37.89 11.17 0.01 0.20 0.45 8.03 Jesus Maria C7B-003a 4 t1 36.02 0.07 36.88 10.72 0.01 3.32 7.37 2.88 Jesus Maria C7B-003a 4 t2 36.16 0.07 36.95 10.72 0.02 3.29 7.33 2.79 Jesus Maria C7B-003a 4 t3 36.13 0.08 36.80 10.73 0.01 3.49 7.73 2.63 Ojancos Viejo C3B-429.5 1 t1 36.75 1.13 29.53 10.58 0.03 2.38 5.56 8.19 Ojancos Viejo C3B-429.5 1 t2 36.13 1.72 27.57 10.43 0.00 3.07 7.10 7.78 Ojancos Viejo C3B-429.5 1 t3 36.60 1.18 29.51 10.57 0.03 2.34 5.52 8.29 Ojancos Viejo C3B-429.5 1 t4 36.54 0.32 31.04 10.60 0.00 2.45 5.80 7.54 Ojancos Viejo C3B-429.5 1 t5 36.56 0.08 29.36 10.49 0.00 2.91 6.74 7.63 Ojancos Viejo C3B-429.5 1 t6 36.75 1.13 29.76 10.61 0.01 2.38 5.52 8.21 Ojancos Viejo C3B-429.5 1 t7 35.90 0.55 27.02 10.36 0.00 3.57 8.34 7.59 Ojancos Viejo C3B-429.5 1 t8 36.58 0.43 29.76 10.57 0.00 2.87 6.73 7.53 Ojancos Viejo C3B-429.5 1 t9 36.16 0.40 27.61 10.42 0.00 3.45 8.03 7.59 Ojancos Viejo C3B-429.5 1 t10 36.67 1.17 29.61 10.56 0.03 2.34 5.45 8.14 Ojancos Viejo C3B-429.5 1 t11 36.07 0.05 27.83 10.41 0.00 3.67 8.54 7.25 Ojancos Viejo C3B-429.5 1 t12 36.71 1.20 29.68 10.60 0.03 2.35 5.51 8.22 Ojancos Viejo C3B-429.5 1 t13 36.90 0.22 31.61 10.63 0.01 2.33 5.44 7.36 Ojancos Viejo C3B-429.5 1 t14 36.22 0.72 27.83 10.42 0.01 3.28 7.76 7.46 Ojancos Viejo C3B-429.5 1 t15 36.75 1.05 30.38 10.66 0.03 2.31 5.36 8.21 Ojancos Viejo C3B-429.5 1 t16 35.30 0.58 23.88 10.22 0.00 5.65 11.57 6.86 Ojancos Viejo C3B-429.5 1 t17 36.50 1.27 29.23 10.57 0.03 2.45 5.80 8.29 Ojancos Viejo C3B-429.5 1 t18 36.52 0.53 31.31 10.60 0.00 2.31 5.46 7.44 Ojancos Viejo C3B-429.5 1 t19 36.33 0.60 30.74 10.50 0.00 2.51 6.00 7.05 Ojancos Viejo C3B-429.5 1 t20 36.80 1.13 29.97 10.63 0.03 2.23 5.27 8.32 Ojancos Viejo C3B-429.5 1 t21 36.80 1.15 29.55 10.60 0.03 2.35 5.53 8.26 Ojancos Viejo C3B-429.5 1 t22 35.98 0.47 27.70 10.42 0.01 3.60 8.47 7.23 Ojancos Viejo C3B-429.5 1 t23 36.48 1.20 30.02 10.64 0.03 2.35 5.55 8.27 Ojancos Viejo C3B-429.5 1 t24 36.07 0.07 27.66 10.38 0.00 4.15 9.60 6.43 Ojancos Viejo C3B-429.5 1 t25 36.45 0.05 29.00 10.51 0.00 3.25 7.68 7.36 Ojancos Viejo C3B-429.5 1 t26 35.68 0.38 25.68 10.36 0.01 4.41 10.39 7.26 Ojancos Viejo C3B-429.5 1 t27 36.75 1.15 30.04 10.69 0.03 2.42 5.74 8.26 Ojancos Viejo C3B-429.5 1 t28 36.28 0.37 26.93 10.46 0.01 3.74 8.80 7.76 Ojancos Viejo C3B-429.5 2 t1 36.95 1.12 29.87 10.63 0.03 2.31 5.34 8.26 Ojancos Viejo C3B-429.5 2 t2 35.98 0.32 27.45 10.40 0.00 3.61 8.47 7.40 Ojancos Viejo C3B-429.5 2 t3 37.10 0.17 31.99 10.68 0.01 2.10 4.96 7.63 Ojancos Viejo C3B-429.5 2 t4 36.22 0.50 29.25 10.48 0.01 2.97 6.92 7.44 Ojancos Viejo C3B-429.5 2 t5 36.84 1.15 29.83 10.59 0.04 2.24 5.28 8.14 Ojancos Viejo C3B-429.5 2 t6 36.69 0.20 29.80 10.58 0.00 2.77 6.50 7.76 Ojancos Viejo C3B-429.5 2 t7 37.18 0.18 31.71 10.73 0.00 2.05 4.77 8.17 Ojancos Viejo C3B-429.5 2 t9 36.82 0.27 29.80 10.52 0.00 2.68 6.26 7.51 Ojancos Viejo C3B-429.5 2 t11 36.67 1.10 30.14 10.64 0.04 2.32 5.49 8.17 Ojancos Viejo C3B-429.5 2 t12 36.07 0.03 30.82 10.56 0.00 2.58 6.09 7.78 San Gregorio S Granate C2B-352e 2 t1 34.92 1.95 24.50 10.17 0.00 7.54 9.20 6.00 San Gregorio S Granate C2B-352e 2 t2 35.91 1.14 26.19 10.31 0.00 6.57 7.94 6.48 San Gregorio S Granate C2B-352e 2 t3 35.61 0.06 28.81 10.28 0.00 7.50 9.05 3.92 San Gregorio S Granate C2B-352e 2 t4 36.07 0.02 29.19 10.38 0.00 7.08 8.73 4.33 San Gregorio S Granate C2B-352e 2 t5 34.98 2.13 24.10 10.17 0.00 7.45 9.25 6.21 San Gregorio S Granate C2B-352e 2 t6 35.14 2.20 23.90 10.17 0.00 7.49 9.21 6.21 San Gregorio S Granate C2B-352e 2 t7 34.98 1.83 24.62 10.14 0.00 7.58 9.08 5.81 San Gregorio S Granate C2B-352e 2 t8 36.48 0.41 28.71 10.47 0.00 6.10 7.41 6.01 San Gregorio S Granate C2B-352e 2 t9 34.92 2.23 23.36 10.13 0.00 7.94 9.60 6.10 San Gregorio S Granate C2B-352e 2 t10 35.00 2.08 23.72 10.13 0.00 7.75 9.32 6.11 San Gregorio S Granate C2B-352e 3 t1 35.67 0.52 27.01 10.24 0.00 7.38 9.10 4.88 San Gregorio S Granate C2B-352e 3 t3 36.53 0.17 30.32 10.45 0.00 6.15 7.40 4.66 San Gregorio S Granate C2B-352e 3 t4 36.59 0.29 29.53 10.46 0.01 5.88 7.07 5.56 San Gregorio S Granate C2B-352e 3 t7 35.58 1.25 25.83 10.25 0.00 7.48 9.14 5.47 San Gregorio S Granate C2B-352e 3 t8 36.24 0.83 28.23 10.43 0.00 6.23 7.51 5.95 San Gregorio S Granate C2B-352e 3 t9 35.53 1.59 24.49 10.23 0.00 7.80 9.41 5.95 San Gregorio S Granate C2B-352e 3 t10 36.26 0.10 30.42 10.44 0.00 6.45 7.97 4.28 San Gregorio S Granate C2B-352e 3 t11 35.50 0.33 27.68 10.29 0.00 7.63 9.23 4.65 San Gregorio S Granate C2B-352e 3 t12 34.47 1.45 24.76 9.99 0.00 7.65 9.34 5.28 San Gregorio S Granate C2B-352e 4 t1 34.94 2.34 23.45 10.15 0.01 7.82 9.38 6.23 San Gregorio S Granate C2B-352e 4 t2 35.98 0.02 32.41 10.39 0.00 2.18 14.89 0.91 San Gregorio S Granate C2B-352e 4 t3 36.13 0.02 32.08 10.40 0.00 1.99 14.46 1.44 San Gregorio S Granate C2B-352e 4 t4 34.88 2.24 23.12 10.10 0.00 2.12 14.65 6.27 San Gregorio S Granate C2B-352e 4 t5 35.18 2.04 23.48 10.16 0.00 2.04 14.34 6.40 San Gregorio S Granate C2B-352e 4 t6 35.13 2.13 22.63 10.09 0.01 2.00 14.45 6.63 San Gregorio S Granate C2B-352e 4 t10 35.31 2.02 23.48 10.17 0.00 2.10 14.37 6.36 San Gregorio S Granate C2B-352e 4 t11 35.19 0.02 29.80 10.10 0.00 2.22 15.48 1.48 San Gregorio S Granate C2B-655 1 t1 35.09 1.58 23.51 10.17 0.00 8.75 8.95 6.48 San Gregorio S Granate C2B-655 1 t2 36.13 0.05 28.30 10.36 0.00 6.43 6.64 6.35 San Gregorio S Granate C2B-655 1 t3 34.76 1.75 23.49 10.10 0.00 8.37 8.59 6.65 San Gregorio S Granate C2B-655 1 t4 35.96 0.50 26.04 10.29 0.01 6.20 6.38 7.93 San Gregorio S Granate C2B-655 1 t5 35.02 1.78 24.26 10.17 0.00 8.13 8.28 6.52 San Gregorio S Granate C2B-655 1 t6 36.58 0.07 30.42 10.53 0.00 5.42 5.53 6.52 San Gregorio S Granate C2B-655 1 t7 35.06 1.28 24.13 10.12 0.00 8.07 8.22 6.60 San Gregorio S Granate C2B-655 1 t8 34.70 2.07 22.31 10.06 0.00 9.02 9.32 6.48 San Gregorio S Granate C2B-655 2 t1 34.51 2.30 22.50 9.99 0.01 8.56 8.71 6.45 San Gregorio S Granate C2B-655 2 t2 35.11 0.87 22.41 10.11 0.00 9.46 9.61 6.68 San Gregorio S Granate C2B-655 2 t3 35.34 0.32 24.43 10.17 0.00 8.30 8.48 6.75 San Gregorio S Granate C2B-655 2 t4 36.01 0.03 28.93 10.33 0.00 5.44 5.62 6.88 San Gregorio S Granate C2B-655 2 t5 36.63 0.05 29.08 10.51 0.00 5.52 5.67 7.28 San Gregorio S Granate C2B-655 2 t6 36.54 0.03 30.02 10.48 0.00 4.74 4.82 7.31 San Gregorio S Granate C2B-655 2 t7 35.28 0.30 23.49 10.15 0.00 9.67 9.86 5.97 San Gregorio S Granate C2B-655 2 t8 35.47 0.28 25.77 10.23 0.00 8.01 8.19 6.28 San Gregorio S Granate C2B-655 2 t9 35.60 0.48 25.70 10.26 0.00 6.56 6.72 7.84 San Gregorio S Granate C2B-655 2 t10 35.96 0.03 27.96 10.33 0.00 8.39 8.58 4.53 San Gregorio S Granate C2B-655 3 t1 34.49 2.10 22.01 9.96 0.00 9.11 9.30 6.22 San Gregorio S Granate C2B-671 1 t1 35.15 2.60 22.62 10.14 0.00 6.94 7.77 8.06 San Gregorio S Granate C2B-671 1 t2 35.86 0.53 25.09 10.23 0.01 6.69 7.46 7.49 San Gregorio S Granate C2B-671 1 t3 35.81 0.67 25.15 10.21 0.01 7.19 7.92 6.75 San Gregorio S Granate C2B-671 1 t4 34.87 2.39 23.17 10.13 0.00 6.90 7.66 7.93 San Gregorio S Granate C2B-671 1 t5 35.83 0.53 25.34 10.24 0.03 6.77 7.57 7.26 San Gregorio S Granate C2B-671 2 t1 35.00 2.17 24.00 10.20 0.00 6.63 7.37 7.99 San Gregorio S Granate C2B-671 2 t2 35.32 1.47 25.05 10.23 0.00 6.41 7.09 7.71 San Gregorio S Granate C2B-671 2 t3 35.66 2.00 25.24 10.31 0.01 6.22 6.91 7.76 San Gregorio S Granate C2B-671 3 t1 34.76 0.63 22.48 10.05 0.00 9.50 10.54 6.04 San Gregorio S Granate C2B-671 3 t2 35.21 0.62 24.58 10.15 0.01 7.65 8.51 6.72 San Gregorio S Granate C2B-671 3 t3 35.56 0.43 25.30 10.19 0.01 6.89 7.61 7.15 San Gregorio S Granate C2B-671 3 t4 34.79 2.32 23.41 10.09 0.01 6.61 7.38 7.88 San Gregorio S Granate C2B-808.2 1 t1 34.85 0.15 27.54 10.15 0.00 13.06 7.59 2.63 San Gregorio S Granate C2B-808.2 1 t2 35.05 0.07 29.11 10.21 0.00 12.28 7.19 2.28 San Gregorio S Granate C2B-808.2 1 t3 35.71 0.01 30.92 10.36 0.00 10.90 6.34 2.44 San Gregorio S Granate C2B-808.2 1 t4 35.71 0.05 30.71 10.35 0.00 10.75 6.32 2.66 San Gregorio S Granate C2B-808.2 1 t5 35.95 0.04 31.44 10.39 0.00 11.19 6.52 1.82 San Gregorio S Granate C2B-808.2 1 t6 35.56 0.03 30.63 10.32 0.00 11.59 6.80 1.96 San Gregorio S Granate C2B-808.2 1 t7 34.88 0.10 28.53 10.18 0.00 12.76 7.57 2.19 San Gregorio S Granate C2B-808.2 1 t8 34.27 0.02 24.16 9.92 0.00 16.48 9.68 1.51 San Gregorio S Granate C2B-808.2 1 t9 35.07 0.06 29.09 10.23 0.00 12.89 7.59 1.81 San Gregorio S Granate C2B-808.2 1 t10 35.04 0.15 27.08 10.18 0.00 13.35 7.87 2.68 San Gregorio S Granate C2B-808.2 1 t11 35.47 0.15 29.16 10.33 0.00 10.78 6.31 3.80 San Gregorio S Granate C2B-808.2 1 t12 35.26 0.02 29.62 10.27 0.01 11.78 6.90 2.51 San Gregorio S Granate C2B-808.2 1 t13 34.75 0.05 28.36 10.11 0.00 14.40 8.44 0.71 San Gregorio S Granate C2B-808.2 1 t14 35.13 0.13 25.06 10.15 0.01 12.96 7.51 4.49 San Gregorio S Granate C2B-808.2 1 t15 35.59 0.10 28.23 10.33 0.00 10.85 6.31 4.48 San Gregorio S Granate C2B-808.2 1 t16 35.20 0.15 25.81 10.19 0.00 12.21 7.25 4.62 San Gregorio S Granate C2B-808.2 1 t17 35.14 0.47 25.54 10.20 0.00 12.54 7.41 4.44 San Gregorio S Granate C2B-808.2 1 t18 35.81 0.09 28.86 10.37 0.01 10.08 5.85 4.74 San Gregorio S Granate C2B-808.2 1 t19 35.02 1.15 25.91 10.12 0.00 13.01 7.75 3.01 San Gregorio S Granate C2B-808.2 1 t20 34.70 0.03 25.78 9.99 0.01 14.26 8.30 2.22 San Gregorio S Granate C2B-808.2 1 t22 34.43 0.22 23.72 9.97 0.00 16.06 9.26 2.42 San Gregorio S Granate C2B-808.2 1 t23 34.98 0.03 27.95 10.20 0.00 13.81 8.03 1.94 San Gregorio S Granate C2B-808.2 1 t24 34.72 0.16 23.50 10.02 0.00 15.85 9.29 2.63 San Gregorio S Granate C2B-808.2 1 t25 34.45 2.29 23.75 9.97 0.00 14.33 8.45 2.58 San Gregorio S Granate C2B-808.2 1 t26 34.21 0.03 26.57 10.06 0.00 14.99 8.74 1.72 San Gregorio S Granate C2B-808.2 1 t27 35.45 0.11 27.14 10.23 0.00 11.31 6.52 4.45 San Gregorio S Granate C2B-808.2 1 t28 34.91 0.42 24.91 10.12 0.00 13.03 7.69 4.28 San Gregorio S Granate C2B-808.2 1 t29 35.20 0.24 24.99 10.16 0.01 13.00 7.65 4.38 San Gregorio S Granate C2B-808.2 1 t30 35.21 0.20 26.60 10.18 0.00 13.09 7.59 3.25 San Gregorio S Granate C2B-808.2 1 t31 34.82 0.07 29.19 10.17 0.00 13.89 8.02 0.75 San Gregorio S Granate C2B-808.2 2 t1 35.34 1.98 25.55 10.23 0.01 10.94 6.31 5.15 San Gregorio S Granate C2B-808.2 2 t2 35.13 3.75 24.58 10.23 0.01 10.57 6.28 5.34 San Gregorio S Granate C2B-808.2 2 t3 34.82 4.13 22.10 10.13 0.01 11.99 7.09 5.49 San Gregorio S Granate C2B-808.2 2 t4 35.33 2.49 24.06 10.20 0.00 10.97 6.44 5.81 San Gregorio S Granate C2B-808.2 2 t5 35.18 3.09 23.28 10.11 0.00 11.48 6.70 5.30 San Gregorio S Granate C2B-808.2 2 t6 34.88 4.17 22.43 10.11 0.00 11.61 6.74 5.52 San Gregorio S Granate C2B-808.2 2 t7 34.95 3.77 22.15 10.10 0.00 12.34 7.23 5.17 San Gregorio S Granate C2B-808.2 2 t8 35.12 3.85 23.12 10.15 0.01 11.23 6.48 5.53 San Gregorio S Granate C2B-808.2 2 t9 35.18 3.86 22.49 10.14 0.01 11.29 6.53 5.82 San Gregorio S Granate C2B-808.2 2 t10 35.00 2.45 25.74 10.18 0.00 11.30 6.73 4.29 San Gregorio S Granate C2B-808.2 2 t11 36.32 0.72 29.07 10.47 0.01 9.13 5.27 5.26 San Gregorio S Granate C2B-808.2 2 t12 35.27 3.48 24.63 10.17 0.00 10.51 6.08 5.12 San Gregorio S Granate C2B-808.2 2 t13 35.96 0.99 28.30 10.39 0.00 10.02 5.88 4.72 Santos PdC DDH289-037.5 1 t1 36.80 0.20 30.72 10.58 0.01 2.18 5.90 7.61 Santos PdC DDH289-037.5 1 t2 37.35 0.07 31.80 10.65 0.00 1.94 5.34 7.28 Santos PdC DDH289-037.5 1 t3 37.44 0.12 31.18 10.68 0.00 1.78 4.87 8.24 Santos PdC DDH289-037.5 1 t4 36.11 1.30 27.21 10.43 0.01 3.06 8.61 7.43 Santos PdC DDH289-037.5 1 t5 35.86 0.65 30.46 10.46 0.03 2.26 6.24 7.23 Santos PdC DDH289-037.5 1 t6 36.63 0.17 32.01 10.61 0.03 1.96 5.44 7.26 Santos PdC DDH289-037.5 1 t7 37.35 0.15 32.97 10.76 0.00 1.36 3.75 8.24 Santos PdC DDH289-037.5 1 t8 36.82 0.17 33.92 10.77 0.00 1.27 3.56 8.03 Santos PdC DDH289-037.5 1 t10 36.16 0.12 30.93 10.50 0.00 2.21 6.18 7.31 Santos PdC DDH289-037.5 1 t11 36.80 0.13 30.63 10.56 0.00 2.30 6.35 7.31 Santos PdC DDH289-037.5 1 t13 36.28 0.50 30.91 10.59 0.04 2.53 7.14 6.77 Santos PdC DDH289-037.5 1 t14 36.71 0.30 30.80 10.64 0.04 2.53 7.00 7.03 Santos PdC DDH289-037.5 2 t1 35.94 0.75 29.66 10.45 0.03 2.30 6.25 7.58 Santos PdC DDH289-037.5 2 t2 36.63 0.37 31.82 10.63 0.03 2.01 5.55 7.31 Santos PdC DDH289-037.5 2 t3 37.27 0.05 33.52 10.69 0.00 2.45 6.86 5.21 Santos PdC DDH289-037.5 2 t4 36.20 0.28 31.21 10.55 0.01 2.33 6.31 7.03 Santos PdC DDH289-037.5 2 t5 36.80 0.23 33.78 10.73 0.01 1.43 3.97 7.58 Santos PdC DDH289-037.5 2 t3 35.83 0.75 29.72 10.50 0.03 2.61 7.13 7.33 Santos PdC DDH289-037.5 2 t4 35.90 0.40 30.23 10.43 0.04 2.56 7.09 6.70 Santos PdC DDH289-037.5 2 t5 35.60 1.42 26.15 10.33 0.01 3.19 9.06 7.63 Santos PdC DDH289-037.5 2 t6 36.09 0.48 30.12 10.42 0.03 2.18 5.91 7.43 Santos PdC DDH289-037.5 2 t8 36.09 0.35 29.70 10.41 0.03 2.78 7.57 6.58 Santos PdC DDH289-037.5 2 t9 35.49 0.37 32.80 10.49 0.03 1.99 5.46 6.62 Santos PdC DDH289-037.5 2 t9-1 36.01 0.55 29.25 10.42 0.01 2.85 7.85 6.70 Santos PdC DDH289-037.5 2 t11 37.12 0.03 32.61 10.61 0.01 2.92 8.12 4.58 Santos PdC DDH289-037.5 2 t12 37.42 0.07 30.55 10.69 0.00 2.11 5.98 8.09 Santos PdC DDH289-037.5 2 t13 35.90 0.07 27.08 10.40 0.01 3.47 9.40 7.53 Santos PdC DDH289-037.5 2 t14 36.86 0.28 34.16 10.72 0.01 1.34 3.75 7.35 Santos PdC DDH289-037.5 2 t15 36.39 0.87 30.02 10.52 0.01 2.29 6.30 7.41 Santos PdC DDH289-037.5 3 t2 36.45 0.40 29.53 10.51 0.01 2.93 7.92 6.85 Santos PdC DDH289-037.5 3 t3 36.95 0.08 32.08 10.65 0.00 2.42 6.73 6.42 Santos PdC DDH289-037.5 3 t4 36.93 0.07 32.54 10.67 0.00 2.13 5.98 6.75 Santos PdC DDH289-037.5 3 t5 36.75 0.27 29.42 10.54 0.00 2.53 7.09 7.54 Santos PdC DDH289-037.5 3 t6 36.01 0.97 28.87 10.51 0.03 2.50 7.00 7.88 Santos PdC DDH289-037.5 3 t8 36.39 0.48 31.03 10.58 0.06 2.21 6.11 7.31 Santos PdC DDH289-037.5 3 t9 36.71 0.30 30.40 10.47 0.03 3.02 8.39 5.42 Santos PdC DDH291-188.4 1 t1 36.37 0.28 30.08 10.46 0.07 2.57 7.85 6.50 Santos PdC DDH291-188.4 1 t2 36.07 0.70 27.53 10.32 0.09 3.06 9.28 6.62 Santos PdC DDH291-188.4 1 t3 37.01 0.08 29.59 10.55 0.00 2.99 9.03 6.25 Santos PdC DDH291-188.4 1 t4 36.45 0.57 27.81 10.46 0.09 1.50 11.72 6.48 Santos PdC DDH291-188.4 1 t5 37.14 0.08 30.50 10.67 0.01 1.49 9.94 6.37 Santos PdC DDH291-188.4 1 t6 36.43 0.53 29.10 10.50 0.19 1.31 9.62 6.93 Santos PdC DDH291-188.4 2 t2 36.63 0.60 27.53 10.50 0.03 3.28 10.04 6.81 Santos PdC DDH291-188.4 2 t3 36.58 0.65 28.89 10.46 0.07 2.66 8.29 6.85 Santos PdC DDH291-188.4 2 t5 37.42 0.12 30.53 10.62 0.00 2.36 7.45 6.83 Santos PdC DDH291-188.4 2 t7 36.41 0.57 28.61 10.52 0.12 3.07 9.52 6.63 Santos PdC DDH384-004.2 1 t1 36.33 1.00 29.74 10.44 0.03 2.35 7.70 6.55 Santos PdC DDH384-004.2 1 t2 37.14 0.27 32.27 10.63 0.01 1.91 6.13 6.55 Santos PdC DDH384-004.2 1 t3 36.13 0.95 28.59 10.39 0.00 2.60 8.37 6.83 Santos PdC DDH384-004.2 1 t4 37.12 0.18 32.31 10.69 0.00 1.95 6.36 6.81 Santos PdC DDH384-004.2 2 t1 36.05 1.22 27.79 10.37 0.07 2.72 8.90 6.83 Santos PdC DDH384-004.2 2 t2 36.63 0.37 31.54 10.50 0.01 2.14 6.84 6.17 Santos PdC DDH384-004.2 2 t3 36.69 0.38 31.50 10.56 0.01 2.02 6.59 6.73 Santos PdC DDH628-094.2 1 t1 37.03 0.20 31.01 10.55 0.00 4.03 6.46 5.97 Santos PdC DDH628-094.2 1 t2 35.98 0.80 26.91 10.41 0.00 5.35 8.67 6.88 Santos PdC DDH628-094.2 1 t3 36.56 0.20 30.04 10.54 0.00 4.50 7.39 6.20 Santos PdC DDH628-094.2 2 t1 37.08 0.05 32.29 10.59 0.00 4.23 6.93 4.86 Santos PdC DDH628-094.2 2 t2 36.45 0.22 30.65 10.45 0.00 4.65 7.45 5.16 Santos PdC DDH628-094.2 2 t3 36.26 0.13 29.83 10.43 0.01 5.13 8.38 5.07 Santos PdC DDH628-094.2 2 t4 36.60 0.37 29.89 10.49 0.00 4.58 7.42 5.87 Santos PdC DDH628-151.6 1 t1 36.24 0.08 31.38 10.42 0.00 3.57 6.90 5.47 Santos PdC DDH628-151.6 1 t2 36.37 0.10 31.54 10.47 0.00 3.21 6.24 6.12 Santos PdC DDH628-151.6 1 t3 36.20 0.07 30.44 10.39 0.00 3.99 7.78 5.39 Santos PdC DDH628-151.6 1 t5 36.45 0.07 31.46 10.46 0.00 3.45 6.71 5.65 Santos PdC DDH628-151.6 1 t6 36.60 0.15 32.10 10.56 0.00 3.04 5.83 6.28 Santos PdC DDH628-151.6 2 t1 35.60 0.07 29.91 10.29 0.01 4.64 8.90 4.64 Santos PdC DDH628-151.6 2 t2 37.08 0.23 32.31 10.68 0.00 3.50 6.78 5.70 Santos PdC DDH628-151.6 2 t3 36.20 0.65 29.55 10.40 0.01 4.16 8.09 5.60 Santos PdC DDH628-151.6 3 t1 36.13 0.13 30.29 10.31 0.01 3.75 7.24 5.47 Santos PdC DDH628-151.6 3 t2 36.58 0.15 30.86 10.52 0.00 3.83 7.55 5.70 Santos PdC DDH628-151.6 3 t3 36.30 0.15 30.59 10.43 0.00 3.82 7.48 5.62 Santos PdC DDH628-151.6 3 t4 36.39 0.20 30.55 10.49 0.00 3.35 6.47 6.73 Santos PdC DDH628-626.3 1 t1 36.39 0.18 32.60 10.65 0.00 4.83 7.77 4.57 Santos PdC DDH628-626.3 1 t2 35.96 0.36 33.22 10.60 0.00 5.58 8.93 2.94 Santos PdC DDH628-626.3 1 t6 37.23 0.02 31.40 10.66 0.00 4.78 7.65 5.19 Santos PdC DDH628-626.3 1 t8 37.23 0.10 31.92 10.69 0.00 4.28 6.95 5.53 Santos PdC DDH628-626.3 1 t9 36.15 0.15 32.69 10.64 0.00 5.03 8.12 4.29 Santos PdC DDH628-626.3 1 t10 37.01 0.80 30.44 10.62 0.00 4.55 7.38 5.71 Santos PdC DDH628-626.3 1 t11 36.15 0.07 32.92 10.60 0.00 4.98 8.09 3.93 Santos PdC DDH628-626.3 1 t14 37.27 0.35 32.08 10.73 0.00 3.73 6.06 6.25 Santos PdC DDH628-626.3 1 t15 37.12 0.22 32.22 10.71 0.00 3.91 6.36 5.97 Santos PdC DDH628-626.3 1 t16 36.30 0.15 32.68 10.66 0.00 5.03 8.16 4.32 Santos PdC DDH628-626.3 1 t17 36.77 0.17 32.53 10.65 0.00 4.58 7.42 4.65 Santos PdC DDH628-626.3 1 t18 36.48 0.22 33.77 10.71 0.00 4.94 8.02 3.70 Santos PdC DDH628-626.3 1 t24 37.03 0.28 32.11 10.72 0.00 4.03 6.46 5.96 Santos PdC DDH628-626.3 2 t5 37.00 0.61 31.29 10.66 0.00 4.13 6.71 5.96 Santos PdC DDH628-626.3 2 t6 35.26 0.04 35.00 10.52 0.01 4.92 7.89 2.63 Santos PdC DDH628-626.3 2 t7 36.23 0.29 33.26 10.62 0.00 4.96 8.06 3.69 Santos PdC DDH628-626.3 2 t8 36.88 0.34 32.06 10.65 0.00 3.98 6.47 5.70 Santos PdC DDH628-626.3 2 t9 35.25 0.04 34.95 10.54 0.00 5.15 8.30 2.47 Santos PdC DDH628-626.3 2 t10 36.93 0.22 32.75 10.70 0.00 3.94 6.31 5.56 Santos PdC DDH628-626.3 2 t11 36.93 0.33 32.17 10.68 0.00 3.77 6.13 6.04 Santos PdC DDH628-626.3 2 t13 35.95 0.15 32.98 10.59 0.00 4.72 7.63 4.34 Santos PdC DDH628-626.3 2 t14 36.55 0.84 30.75 10.59 0.00 4.50 7.32 5.61 Santos PdC DDH628-626.3 2 t16 37.16 0.29 32.37 10.70 0.00 3.80 6.17 5.85 Santos PdC DDH-643-595.5 1 t1 36.45 0.18 31.48 10.52 0.01 3.73 7.25 5.47 Santos PdC DDH-643-595.5 1 t2 36.78 0.58 32.35 10.63 0.00 3.63 7.03 5.22 Santos PdC DDH-643-595.5 1 t3 36.82 0.02 30.53 10.56 0.00 4.03 7.78 5.87 Santos PdC DDH-643-595.5 1 t4 36.75 0.08 32.65 10.53 0.00 4.03 7.84 4.01 Santos PdC DDH-643-595.5 1 t5 36.52 0.27 31.25 10.53 0.00 3.30 6.33 6.42 Santos PdC DDH-643-595.5 1 t6 37.16 0.07 32.91 10.66 0.00 3.95 7.65 4.44 Santos PdC DDH-643-595.5 2 t1 36.78 0.08 32.18 10.58 0.00 3.06 5.86 6.28 Santos PdC DDH-643-595.5 2 t2 36.37 0.52 30.46 10.49 0.00 3.60 6.91 6.28 Santos PdC DDH-643-595.5 2 t3 37.01 0.08 32.56 10.61 0.00 2.72 5.26 6.52 Santos PdC DDH-643-595.5 2 t4 36.84 0.07 32.61 10.60 0.00 3.70 7.17 4.96 Santos PdC DDH-643-595.5 2 t5 36.39 0.18 29.95 10.47 0.00 3.98 7.80 6.04 Santos PdC DDH-643-595.5 3 t1 36.67 1.62 30.16 10.61 0.00 4.20 8.18 5.46 Santos PdC DDH-643-595.5 3 t2 36.65 0.72 29.85 10.52 0.00 3.63 7.09 6.53 Santos PdC DDH684-079.8 1 t1 37.34 0.43 31.07 10.67 0.00 3.52 6.60 6.48 Santos PdC DDH684-079.8 1 t2 36.51 1.03 29.05 10.57 0.01 1.44 9.97 6.86 Santos PdC DDH684-079.8 1 t3 36.57 0.20 30.65 10.54 0.00 1.37 9.67 6.04 Santos PdC DDH684-079.8 2 t1 36.00 0.69 33.67 10.55 0.02 1.31 8.72 4.32 Santos PdC DDH684-079.8 2 t3 36.86 0.22 30.78 10.54 0.00 3.51 6.47 6.47 Santos PdC DDH684-079.8 2 t4 35.45 0.57 30.37 10.58 0.06 4.10 7.67 6.75 Santos PdC DDH684-079.8 2 t5 36.40 0.69 30.38 10.57 0.03 3.49 6.50 6.99 Santos PdC DDH684-079.8 3 t1 36.57 0.27 28.73 10.56 0.00 3.27 10.74 6.04 Santos PdC DDH684-079.8 3 t2 36.34 0.98 30.16 10.58 0.01 1.33 9.43 6.58 Santos PdC DDH684-079.8 3 t3 36.36 0.39 29.29 10.48 0.01 1.40 9.45 6.93 Santos PdC ME013-538 1 t1 36.90 0.58 31.31 10.64 0.00 3.87 7.14 5.84 Santos PdC ME013-538 1 t3 36.18 0.67 31.95 10.65 0.01 0.00 10.70 5.17 Santos PdC ME013-538 1 t4 36.24 0.53 32.03 10.91 0.01 1.34 9.73 5.27 Santos PdC ME013-538 2 t1 36.69 0.20 33.52 10.68 0.00 3.75 7.00 4.79 Santos PdC ME013-538 2 t2 35.60 0.20 35.54 10.62 0.00 3.96 7.50 3.20 Santos PdC ME013-538 2 t3 36.18 0.08 33.56 10.61 0.00 3.74 6.89 4.79 Santos PdC ME013-538 2 t4 36.09 0.42 33.44 10.61 0.00 3.93 7.38 4.44 Vinita Azul C6B-160b 1 t2 35.90 0.22 36.40 10.76 0.02 2.00 4.67 5.63 Vinita Azul C6B-160b 1 t3 37.13 0.12 36.20 10.84 0.01 1.96 4.55 5.61 Vinita Azul C6B-160b 1 t5 37.14 0.08 35.11 10.84 0.01 2.28 5.48 5.77 Vinita Azul C6B-160b 1 t6 37.76 0.04 36.44 10.98 0.01 1.89 4.43 5.93 Vinita Azul C6B-160b 1 t7 36.83 0.12 35.17 10.79 0.01 2.28 5.30 5.69 Vinita Azul C6B-160b 2 t1 37.43 0.07 36.35 10.87 0.02 2.01 4.68 5.38 Vinita Azul C6B-160b 2 t2 37.73 0.04 37.13 10.94 0.02 1.93 4.48 5.11 Vinita Azul C6B-160b 2 t3 36.64 0.04 36.39 10.85 0.01 2.08 4.85 5.66 Vinita Azul C6B-160b 2 t4 37.50 0.05 36.15 10.86 0.01 1.95 4.56 5.53 Vinita Azul C6B-160b 2 t5 37.39 0.08 36.42 10.88 0.01 2.08 4.85 5.28 Vinita Azul C6B-160b 2 t6 37.75 0.09 36.94 10.96 0.01 1.94 4.49 5.33 Vinita Azul C6B-160b 2 t7 37.73 0.08 37.01 10.95 0.01 1.94 4.65 5.19 Stuctural formula on the basis of 15 cations

MnO CaO Na2OK2O H2O F Cl Subtotal O=F+Cl Total B Si B Al Sum 0.03 2.85 1.46 0.07 3.00 0.07 0.05 100.07 -0.04 100.03 3.00 6.05 0.00 0.00 6.05 0.03 2.81 1.33 0.04 3.13 0.05 0.01 100.54 -0.02 100.51 3.00 6.06 0.00 0.00 6.06 0.00 2.74 1.79 0.04 2.74 0.07 0.27 99.86 -0.09 99.77 3.00 6.09 0.00 0.00 6.09 0.05 2.94 1.27 0.04 3.04 0.15 0.01 99.94 -0.07 99.88 3.00 6.07 0.00 0.00 6.07 0.03 2.88 1.39 0.01 3.28 0.10 0.01 100.69 -0.04 100.65 3.00 6.04 0.00 0.00 6.04 0.00 2.80 1.43 0.01 3.16 0.34 0.01 100.60 -0.15 100.45 3.00 6.07 0.00 0.00 6.07 0.00 1.64 1.97 0.01 3.17 0.11 0.00 100.16 -0.05 100.12 3.00 6.06 0.00 0.00 6.06 0.01 2.73 1.48 0.02 3.11 0.20 0.01 99.70 -0.09 99.62 3.00 6.07 0.00 0.00 6.07 0.00 2.99 1.32 0.02 2.96 0.09 0.00 100.57 -0.04 100.54 3.00 6.03 0.00 0.00 6.03 0.00 1.89 1.89 0.04 3.06 0.14 0.01 100.76 -0.06 100.70 3.00 6.03 0.00 0.00 6.03 0.01 0.49 2.44 0.00 3.07 0.01 0.00 101.22 0.00 101.21 3.00 6.06 0.00 0.00 6.06 0.03 1.44 2.17 0.02 2.96 0.07 0.00 101.07 -0.03 101.04 3.00 6.06 0.00 0.00 6.06 0.00 0.21 2.29 0.01 2.92 0.04 0.00 101.19 -0.02 101.18 3.00 6.02 0.00 0.00 6.02 0.01 1.12 2.31 0.02 3.03 0.10 0.00 101.27 -0.04 101.23 3.00 6.03 0.00 0.00 6.03 0.00 0.62 2.33 0.02 3.00 0.07 0.00 101.12 -0.03 101.09 3.00 6.04 0.00 0.00 6.04 0.01 1.23 2.28 0.02 3.05 0.01 0.01 101.63 -0.01 101.63 3.00 5.99 0.00 0.01 6.00 0.03 1.61 1.97 0.02 3.07 0.13 0.00 101.50 -0.05 101.45 3.00 6.02 0.00 0.00 6.02 0.01 1.40 2.20 0.02 2.85 0.08 0.00 100.04 -0.03 100.00 3.00 6.07 0.00 0.00 6.07 0.01 0.83 2.24 0.02 2.93 0.03 0.01 100.68 -0.01 100.66 3.00 5.94 0.00 0.06 6.00 0.04 0.34 2.45 0.04 2.72 0.03 0.00 101.39 -0.01 101.37 3.00 6.00 0.00 0.00 6.00 0.00 1.26 2.22 0.05 2.96 0.05 0.00 101.46 -0.02 101.44 3.00 5.93 0.00 0.07 6.00 0.00 0.30 2.69 0.03 2.94 0.04 0.00 100.73 -0.02 100.72 3.00 6.13 0.00 0.00 6.13 0.00 1.53 2.17 0.03 2.76 0.27 0.00 100.76 -0.11 100.64 3.00 6.04 0.00 0.00 6.04 0.02 0.43 2.63 0.02 3.01 0.06 0.01 100.85 -0.03 100.82 3.00 6.06 0.00 0.00 6.06 0.02 0.49 2.62 0.03 2.98 0.07 0.01 101.63 -0.03 101.60 3.00 6.07 0.00 0.00 6.07 0.00 1.54 2.23 0.03 2.71 0.24 0.01 100.94 -0.10 100.84 3.00 6.09 0.00 0.00 6.09 0.00 0.13 2.56 0.01 3.00 0.04 0.00 101.02 -0.02 101.00 3.00 6.07 0.00 0.00 6.07 0.00 0.17 2.59 0.02 3.02 0.01 0.00 101.42 -0.01 101.42 3.00 6.09 0.00 0.00 6.09 0.02 0.16 2.56 0.01 3.15 0.02 0.01 100.63 -0.01 100.62 3.00 6.06 0.00 0.00 6.06 0.03 0.31 2.54 0.01 3.08 0.05 0.01 101.19 -0.02 101.17 3.00 6.07 0.00 0.00 6.07 0.03 0.49 2.55 0.03 3.05 0.00 0.01 101.94 0.00 101.94 3.00 6.06 0.00 0.00 6.06 0.00 0.53 2.52 0.02 3.07 0.04 0.00 101.60 -0.02 101.58 3.00 6.06 0.00 0.00 6.06 0.00 0.12 2.66 0.01 2.91 0.10 0.01 100.89 -0.04 100.85 3.00 6.04 0.00 0.00 6.04 0.01 1.57 2.21 0.03 2.73 0.37 0.01 101.02 -0.16 100.86 3.00 6.03 0.00 0.00 6.03 0.00 1.52 2.20 0.03 2.71 0.33 0.01 100.79 -0.14 100.65 3.00 6.03 0.00 0.00 6.03 0.01 0.23 2.44 0.01 3.09 0.03 0.01 101.19 -0.01 101.18 3.00 6.06 0.00 0.00 6.06 0.00 1.54 2.12 0.03 2.73 0.34 0.00 100.34 -0.14 100.19 3.00 6.02 0.00 0.00 6.02 0.00 0.27 2.48 0.01 3.04 0.03 0.00 100.47 -0.01 100.46 3.00 6.06 0.00 0.00 6.06 0.00 1.53 2.14 0.03 2.84 0.17 0.01 100.08 -0.07 100.01 3.00 6.04 0.00 0.00 6.04 0.01 0.11 2.54 0.01 3.03 0.02 0.00 100.96 -0.01 100.95 3.00 6.07 0.00 0.00 6.07 0.00 1.54 2.14 0.03 2.76 0.30 0.00 100.66 -0.13 100.53 3.00 6.02 0.00 0.00 6.02 0.02 0.54 2.61 0.02 3.10 0.03 0.00 101.51 -0.01 101.49 3.00 6.03 0.00 0.00 6.03 0.00 0.23 2.52 0.02 3.05 0.00 0.00 101.55 0.00 101.54 3.00 6.11 0.00 0.00 6.11 0.00 1.50 2.11 0.02 2.73 0.31 0.00 99.93 -0.13 99.80 3.00 6.04 0.00 0.00 6.04 0.01 0.24 2.70 0.01 3.05 0.05 0.02 101.12 -0.02 101.09 3.00 6.04 0.00 0.00 6.04 0.00 0.81 2.45 0.05 2.97 0.01 0.00 101.32 0.00 101.31 3.00 6.05 0.00 0.00 6.05 0.01 0.14 2.55 0.00 3.09 0.02 0.00 100.84 -0.01 100.83 3.00 6.05 0.00 0.00 6.05 0.00 0.52 2.61 0.03 3.08 0.04 0.00 100.84 -0.02 100.82 3.00 6.05 0.00 0.00 6.05 0.01 0.36 2.57 0.02 3.11 0.00 0.00 101.14 0.00 101.13 3.00 6.06 0.00 0.00 6.06 0.02 0.28 2.66 0.02 3.08 0.00 0.00 101.36 0.00 101.36 3.00 6.04 0.00 0.00 6.04 0.00 1.67 2.07 0.03 2.83 0.23 0.01 100.62 -0.10 100.53 3.00 6.05 0.00 0.00 6.05 0.02 1.43 2.14 0.03 2.83 0.31 0.00 100.79 -0.13 100.66 3.00 6.05 0.00 0.00 6.05 0.01 1.30 2.27 0.02 2.88 0.26 0.00 100.63 -0.11 100.52 3.00 6.03 0.00 0.00 6.03 0.00 0.32 2.60 0.02 3.09 0.02 0.01 101.66 -0.01 101.65 3.00 6.04 0.00 0.00 6.04 0.00 1.04 2.35 0.04 2.94 0.12 0.00 101.20 -0.05 101.15 3.00 6.01 0.00 0.00 6.01 0.01 0.11 2.79 0.02 3.05 0.00 0.00 101.64 0.00 101.64 3.00 6.04 0.00 0.00 6.04 0.01 0.15 2.63 0.02 3.13 0.00 0.01 101.19 0.00 101.19 3.00 6.03 0.00 0.00 6.03 0.02 0.18 2.44 0.01 3.06 0.00 0.00 100.84 0.00 100.84 3.00 6.05 0.00 0.00 6.05 0.00 1.24 2.37 0.04 2.71 0.18 0.00 100.65 -0.08 100.58 3.00 6.02 0.00 0.00 6.02 0.00 1.31 2.26 0.04 2.65 0.12 0.01 100.75 -0.05 100.70 3.00 6.02 0.00 0.00 6.02 0.00 0.16 2.64 0.00 3.02 0.02 0.00 101.36 -0.01 101.35 3.00 6.06 0.00 0.00 6.06 0.00 1.74 2.13 0.04 2.59 0.06 0.01 100.93 -0.03 100.91 3.00 6.04 0.00 0.00 6.04 0.02 0.14 2.52 0.01 3.06 0.00 0.00 100.97 0.00 100.97 3.00 6.06 0.00 0.00 6.06 0.00 0.12 2.64 0.01 3.09 0.00 0.00 101.27 0.00 101.27 3.00 6.05 0.00 0.00 6.05 0.01 0.09 2.72 0.02 3.10 0.00 0.00 101.42 0.00 101.42 3.00 6.04 0.00 0.00 6.04 0.03 0.15 2.60 0.01 3.07 0.05 0.01 101.22 -0.02 101.20 3.00 6.05 0.00 0.00 6.05 0.00 1.65 2.09 0.04 2.67 0.29 0.00 100.56 -0.12 100.44 3.00 6.03 0.00 0.00 6.03 0.00 1.48 2.15 0.02 2.81 0.22 0.00 100.59 -0.09 100.50 3.00 6.01 0.00 0.00 6.01 0.00 1.81 1.93 0.03 2.64 0.11 0.01 100.54 -0.05 100.49 3.00 6.05 0.00 0.00 6.05 0.01 0.37 2.62 0.01 2.99 0.02 0.01 101.04 -0.01 101.03 3.00 6.09 0.00 0.00 6.09 0.03 1.49 2.11 0.04 2.64 0.16 0.00 100.71 -0.07 100.64 3.00 6.06 0.00 0.00 6.06 0.01 1.40 2.19 0.02 2.81 0.29 0.01 100.67 -0.12 100.55 3.00 6.07 0.00 0.00 6.07 0.01 0.22 2.54 0.01 3.06 0.00 0.00 101.45 0.00 101.45 3.00 6.06 0.00 0.00 6.06 0.00 1.35 2.21 0.02 2.90 0.26 0.01 101.14 -0.11 101.03 3.00 6.04 0.00 0.00 6.04 0.01 0.25 2.66 0.02 3.12 0.01 0.00 101.86 -0.01 101.85 3.00 6.08 0.00 0.00 6.08 0.00 1.53 2.17 0.03 2.84 0.30 0.00 101.19 -0.13 101.06 3.00 6.03 0.00 0.00 6.03 0.00 0.30 2.62 0.02 3.18 0.06 0.00 101.42 -0.02 101.40 3.00 6.06 0.00 0.00 6.06 0.00 0.15 2.57 0.02 3.08 0.03 0.00 101.12 -0.01 101.11 3.00 6.04 0.00 0.00 6.04 0.02 0.13 2.70 0.01 3.06 0.00 0.00 100.90 0.00 100.90 3.00 6.07 0.00 0.00 6.07 0.00 0.14 2.59 0.00 3.65 0.00 0.00 101.28 0.00 101.28 3.00 6.09 0.00 0.00 6.09 0.00 0.16 2.61 0.01 3.05 0.00 0.00 101.79 0.00 101.79 3.00 6.09 0.00 0.00 6.09 0.00 1.71 2.02 0.03 2.71 0.23 0.01 100.58 -0.10 100.48 3.00 6.07 0.00 0.00 6.07 0.00 1.38 2.30 0.03 2.88 0.25 0.00 101.02 -0.10 100.91 3.00 6.03 0.00 0.00 6.03 0.01 1.38 2.21 0.03 2.88 0.25 0.00 101.00 -0.11 100.90 3.00 6.02 0.00 0.00 6.02 0.02 0.20 2.35 0.00 3.02 0.04 0.00 101.08 -0.02 101.07 3.00 6.08 0.00 0.00 6.08 0.00 1.37 2.28 0.03 2.81 0.33 0.02 100.99 -0.14 100.84 3.00 6.02 0.00 0.00 6.02 0.00 0.20 2.37 0.02 3.09 0.03 0.01 101.37 -0.01 101.36 3.00 6.06 0.00 0.00 6.06 0.01 0.71 2.49 0.04 3.00 0.04 0.00 101.38 -0.02 101.36 3.00 6.02 0.00 0.00 6.02 0.00 1.49 2.17 0.04 2.83 0.28 0.01 100.91 -0.12 100.79 3.00 6.02 0.00 0.00 6.02 0.00 0.22 2.49 0.01 3.02 0.01 0.00 101.33 0.00 101.33 3.00 6.09 0.00 0.00 6.09 0.01 1.58 2.16 0.03 2.79 0.30 0.01 100.88 -0.13 100.75 3.00 6.02 0.00 0.00 6.02 0.02 0.23 2.72 0.01 2.90 0.04 0.00 100.93 -0.02 100.92 3.00 6.07 0.00 0.00 6.07 0.01 1.73 2.06 0.03 2.80 0.18 0.00 100.53 -0.08 100.45 3.00 6.07 0.00 0.00 6.07 0.01 0.47 2.63 0.02 3.01 0.08 0.01 101.37 -0.03 101.34 3.00 6.05 0.00 0.00 6.05 0.00 0.83 1.85 0.05 3.11 0.11 0.00 99.43 -0.05 99.38 3.00 5.92 0.00 0.08 6.00 0.02 0.70 1.77 0.05 3.15 0.07 0.00 101.83 -0.03 101.80 3.00 5.96 0.00 0.04 6.00 0.00 0.53 1.59 0.04 3.11 0.07 0.00 100.61 -0.03 100.59 3.00 6.04 0.00 0.00 6.04 0.02 0.40 2.39 0.04 3.28 0.05 0.00 101.50 -0.02 101.48 3.00 6.04 0.00 0.00 6.04 0.01 0.66 1.65 0.05 3.14 0.06 0.01 99.47 -0.03 99.44 3.00 5.92 0.00 0.08 6.00 0.01 0.94 1.72 0.05 3.12 0.04 0.00 99.44 -0.02 99.42 3.00 6.00 0.00 0.00 6.00 0.02 0.26 2.85 0.06 3.31 0.28 0.00 100.56 -0.12 100.44 3.00 5.94 0.00 0.06 6.00 0.01 0.21 2.68 0.06 3.20 0.31 0.00 100.86 -0.13 100.73 3.00 6.03 0.00 0.00 6.03 0.01 0.19 2.89 0.05 3.01 0.52 0.00 100.24 -0.22 100.02 3.00 6.04 0.00 0.00 6.04 0.02 0.21 2.65 0.05 3.27 0.24 0.00 100.16 -0.10 100.06 3.00 5.95 0.00 0.05 6.00 0.05 0.06 1.45 0.02 3.40 0.05 0.14 99.93 -0.05 99.87 3.00 5.98 0.00 0.02 6.00 0.05 0.28 1.80 0.01 3.44 0.03 0.06 100.06 -0.02 100.04 3.00 5.88 0.00 0.12 6.00 0.05 0.26 2.72 0.07 3.22 0.27 0.00 100.55 -0.11 100.44 3.00 5.98 0.00 0.02 6.00 0.00 0.36 2.77 0.07 3.24 0.25 0.01 100.55 -0.11 100.44 3.00 5.96 0.00 0.04 6.00 0.08 0.03 2.84 0.01 3.39 0.05 0.03 100.76 -0.03 100.74 3.00 5.98 0.00 0.02 6.00 0.00 0.00 1.68 0.00 3.47 0.04 0.00 100.44 -0.02 100.42 3.00 6.00 0.00 0.00 6.00 0.02 0.20 2.72 0.05 3.20 0.26 0.00 100.41 -0.11 100.30 3.00 6.00 0.00 0.00 6.00 0.05 0.09 2.16 0.01 3.37 0.02 0.02 99.92 -0.01 99.91 3.00 6.02 0.00 0.00 6.02 0.01 0.09 2.64 0.05 3.10 0.23 0.00 99.71 -0.10 99.61 3.00 5.99 0.00 0.01 6.00 0.04 0.54 2.25 0.00 3.15 0.01 0.03 100.25 -0.01 100.24 3.00 6.07 0.00 0.00 6.07 0.02 0.28 2.75 0.05 3.21 0.31 0.01 100.62 -0.13 100.49 3.00 5.97 0.00 0.03 6.00 0.01 0.20 2.94 0.05 3.17 0.38 0.00 100.35 -0.16 100.19 3.00 5.98 0.00 0.02 6.00 0.03 0.06 2.39 0.01 3.42 0.00 0.00 99.65 0.00 99.65 3.00 6.03 0.00 0.00 6.03 0.02 0.06 2.37 0.00 3.40 0.00 0.00 100.39 0.00 100.38 3.00 6.01 0.00 0.00 6.01 0.03 0.13 2.51 0.00 3.43 0.03 0.00 99.79 -0.01 99.78 3.00 6.03 0.00 0.00 6.03 0.02 0.63 2.77 0.07 3.28 0.21 0.06 100.95 -0.10 100.85 3.00 5.92 0.00 0.08 6.00 0.00 0.27 2.74 0.05 3.27 0.31 0.01 100.20 -0.13 100.06 3.00 5.97 0.00 0.03 6.00 0.06 0.03 2.25 0.00 3.51 0.03 0.00 100.47 -0.01 100.45 3.00 5.99 0.00 0.01 6.00 0.48 0.53 2.39 0.03 3.44 0.05 0.01 102.65 -0.02 102.62 3.00 5.93 0.00 0.07 6.00 0.00 0.20 2.74 0.05 3.26 0.29 0.00 100.47 -0.12 100.35 3.00 5.99 0.00 0.01 6.00 0.01 0.20 2.81 0.05 3.24 0.30 0.00 100.52 -0.12 100.39 3.00 5.97 0.00 0.03 6.00 0.03 0.63 2.20 0.10 3.17 0.12 0.01 100.73 -0.05 100.67 3.00 6.05 0.00 0.00 6.05 0.05 0.55 2.57 0.03 3.28 0.04 0.01 100.60 -0.02 100.58 3.00 5.99 0.00 0.005 6.00 0.04 1.27 2.12 0.03 3.21 0.16 0.01 100.53 -0.07 100.46 3.00 5.98 0.00 0.02 6.00 0.03 0.28 2.85 0.07 3.27 0.27 0.00 101.12 -0.11 101.00 3.00 5.96 0.00 0.04 6.00 0.04 0.73 2.49 0.07 3.17 0.01 0.04 99.57 -0.01 99.56 3.00 5.99 0.00 0.01 6.00 0.02 0.24 2.87 0.05 3.35 0.16 0.01 100.65 -0.07 100.58 3.00 5.90 0.00 0.10 6.00 0.03 0.18 2.71 0.05 3.27 0.25 0.00 100.20 -0.10 100.10 3.00 5.99 0.00 0.01 6.00 0.04 0.33 2.55 0.06 3.35 0.16 0.00 99.84 -0.07 99.77 3.00 5.95 0.00 0.05 6.00 0.03 0.25 2.76 0.07 3.25 0.25 0.00 100.16 -0.11 100.06 3.00 6.00 0.00 0.00 6.00 0.04 0.04 2.30 0.02 3.42 0.02 0.00 100.21 -0.01 100.20 3.00 5.92 0.00 0.08 6.00 0.08 0.54 2.36 0.03 3.12 0.04 0.06 97.16 -0.03 97.13 3.00 6.00 0.00 0.00 6.00 0.04 0.19 2.75 0.06 3.35 0.21 0.00 100.85 -0.09 100.76 3.00 5.94 0.00 0.06 6.00 0.02 0.24 2.87 0.06 3.34 0.20 0.00 100.55 -0.09 100.46 3.00 5.95 0.00 0.05 6.00 0.01 0.02 1.85 0.01 3.45 0.00 0.03 99.82 -0.01 99.81 3.00 5.99 0.00 0.01 6.00 0.03 0.27 2.81 0.07 3.35 0.28 0.00 100.92 -0.12 100.80 3.00 5.99 0.00 0.01 6.00 0.01 0.19 2.86 0.06 3.31 0.26 0.00 100.46 -0.11 100.35 3.00 5.96 0.00 0.04 6.00 0.01 0.24 2.88 0.05 3.20 0.35 0.00 100.62 -0.15 100.48 3.00 5.98 0.00 0.02 6.00 0.02 0.31 2.78 0.06 3.20 0.30 0.00 99.97 -0.13 99.84 3.00 6.00 0.00 0.00 6.00 0.06 2.03 1.65 0.04 3.13 0.12 0.01 101.40 -0.05 101.34 3.00 5.98 0.00 0.02 6.00 0.07 2.13 1.61 0.04 2.95 0.12 0.02 101.33 -0.06 101.27 3.00 6.03 0.00 0.00 6.03 0.07 2.10 1.73 0.04 3.16 0.08 0.01 101.62 -0.04 101.58 3.00 5.96 0.00 0.04 6.00 0.08 2.33 1.61 0.04 3.00 0.12 0.01 101.07 -0.05 101.01 3.00 6.05 0.00 0.00 6.05 0.06 2.55 1.51 0.04 3.00 0.09 0.01 100.83 -0.04 100.79 3.00 6.07 0.00 0.00 6.07 0.05 2.12 1.57 0.04 3.01 0.11 0.00 100.56 -0.05 100.51 3.00 5.98 0.00 0.02 6.00 0.11 1.79 1.72 0.04 2.91 0.01 0.01 97.70 -0.01 97.69 3.00 6.02 0.00 0.00 6.02 0.09 2.21 1.74 0.05 2.90 0.11 0.01 101.09 -0.05 101.05 3.00 6.19 0.00 0.00 6.19 0.01 0.94 2.24 0.03 2.84 0.04 0.00 101.68 -0.02 101.66 3.00 6.02 0.00 0.00 6.02 0.01 0.78 2.21 0.03 2.74 0.04 0.02 101.40 -0.02 101.38 3.00 5.96 0.00 0.04 6.00 0.04 0.67 2.47 0.03 2.77 0.03 0.01 101.33 -0.01 101.31 3.00 6.01 0.00 0.00 6.01 0.04 0.21 2.54 0.03 2.85 0.04 0.01 101.59 -0.02 101.58 3.00 6.01 0.00 0.00 6.01 0.03 0.88 2.17 0.03 2.74 0.03 0.00 101.74 -0.01 101.73 3.00 5.98 0.00 0.02 6.00 0.02 0.03 1.83 0.00 2.96 0.03 0.00 101.59 -0.01 101.58 3.00 6.05 0.00 0.00 6.05 0.03 0.76 2.31 0.07 2.84 0.02 0.02 101.76 -0.01 101.75 3.00 6.01 0.00 0.00 6.01 0.05 0.62 2.30 0.03 2.80 0.02 0.01 101.76 -0.01 101.75 3.00 5.95 0.00 0.05 6.00 0.03 0.95 2.15 0.03 2.82 0.01 0.01 100.80 -0.01 100.80 3.00 6.00 0.00 0.00 6.00 0.03 0.79 2.37 0.04 2.82 0.02 0.01 101.29 -0.01 101.28 3.00 6.01 0.00 0.00 6.01 0.04 0.66 2.27 0.03 2.85 0.00 0.02 101.59 0.00 101.59 3.00 5.99 0.00 0.01 6.00 0.01 0.37 2.32 0.03 3.58 0.04 0.00 101.06 -0.02 101.04 3.00 6.04 0.00 0.00 6.04 0.01 0.55 2.49 0.07 3.45 0.04 0.01 101.60 -0.02 101.59 3.00 6.04 0.00 0.00 6.04 0.02 0.80 2.15 0.02 3.30 0.01 0.00 101.15 -0.01 101.14 3.00 5.98 0.00 0.02 6.00 0.03 0.28 2.36 0.02 3.37 0.06 0.00 101.62 -0.03 101.59 3.00 6.02 0.00 0.00 6.02 0.00 2.79 1.39 0.05 3.41 0.09 0.00 101.55 -0.04 101.52 3.00 5.95 0.00 0.05 6.00 0.01 2.67 1.52 0.01 3.21 0.13 0.00 101.08 -0.05 101.03 3.00 6.01 0.00 0.00 6.01 0.00 1.78 1.97 0.02 3.25 0.04 0.00 101.61 -0.02 101.60 3.00 5.97 0.00 0.03 6.00 0.00 3.01 1.40 0.01 3.32 0.10 0.00 101.78 -0.04 101.74 3.00 6.02 0.00 0.00 6.02 0.00 3.10 1.33 0.01 3.22 0.12 0.00 99.97 -0.05 99.92 3.00 6.00 0.00 0.00 6.00 0.00 1.83 1.87 0.02 3.35 0.08 0.00 101.12 -0.03 101.09 3.00 5.99 0.00 0.01 6.00 0.00 1.91 1.85 0.03 3.30 0.05 0.02 101.61 -0.02 101.59 3.00 5.98 0.00 0.02 6.00 0.00 1.87 1.94 0.02 3.33 0.05 0.00 101.85 -0.02 101.83 3.00 5.95 0.00 0.05 6.00 0.00 2.02 1.88 0.03 3.30 0.08 0.01 101.62 -0.03 101.59 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0.05 2.99 0.03 0.03 101.20 -0.02 101.18 3.00 6.04 0.00 0.00 6.04 0.08 2.95 1.32 0.08 2.61 0.27 0.03 100.82 -0.12 100.70 3.00 6.02 0.00 0.00 6.02 0.05 3.15 1.17 0.06 2.67 0.20 0.01 101.28 -0.09 101.19 3.00 5.99 0.00 0.01 6.00 0.08 3.09 1.20 0.05 2.57 0.17 0.00 100.19 -0.07 100.12 3.00 6.01 0.00 0.00 6.01 0.01 1.43 2.08 0.04 3.19 0.14 0.00 101.13 -0.06 101.07 3.00 6.03 0.00 0.00 6.03 0.01 1.04 2.29 0.05 3.19 0.12 0.01 100.50 -0.05 100.45 3.00 6.04 0.00 0.00 6.04 0.00 0.25 2.62 0.01 3.13 0.00 0.00 99.24 0.00 99.24 3.00 6.06 0.00 0.00 6.06 0.03 0.34 2.59 0.02 3.21 0.04 0.01 100.97 -0.02 100.95 3.00 6.06 0.00 0.00 6.06 0.00 0.53 2.59 0.02 3.04 0.04 0.01 100.18 -0.02 100.16 3.00 6.06 0.00 0.00 6.06 0.00 0.59 2.49 0.04 3.33 0.00 0.01 101.17 0.00 101.17 3.00 6.04 0.00 0.00 6.04 0.01 0.69 2.45 0.05 3.18 0.04 0.01 100.68 -0.02 100.66 3.00 6.02 0.00 0.00 6.02 0.01 2.28 1.68 0.04 2.99 0.13 0.00 100.29 -0.05 100.24 3.00 6.03 0.00 0.00 6.03 0.00 0.42 2.60 0.02 2.90 0.06 0.00 101.80 -0.03 101.77 3.00 6.05 0.00 0.00 6.05 0.09 3.08 1.15 0.04 2.59 0.24 0.01 100.38 -0.10 100.28 3.00 6.02 0.00 0.00 6.02 0.04 3.68 0.86 0.05 2.73 0.08 0.01 100.72 -0.04 100.69 3.00 6.02 0.00 0.00 6.02 0.01 2.18 1.70 0.02 2.99 0.10 0.00 100.38 -0.04 100.34 3.00 6.09 0.00 0.00 6.09 0.03 1.93 1.85 0.02 2.91 0.06 0.01 100.52 -0.03 100.50 3.00 6.10 0.00 0.00 6.10 0.04 3.68 0.84 0.05 2.75 0.09 0.01 100.49 -0.04 100.45 3.00 5.98 0.00 0.02 6.00 0.01 2.14 1.60 0.01 3.02 0.07 0.00 100.44 -0.03 100.41 3.00 6.08 0.00 0.00 6.08 0.06 3.37 1.02 0.06 2.83 0.08 0.01 100.79 -0.04 100.76 3.00 5.96 0.00 0.04 6.00 0.06 3.22 1.17 0.05 2.78 0.10 0.01 100.67 -0.04 100.62 3.00 6.00 0.00 0.00 6.00 0.04 3.05 1.27 0.06 2.73 0.11 0.01 101.39 -0.05 101.34 3.00 6.01 0.00 0.00 6.01 0.05 1.78 1.97 0.04 3.17 0.02 0.01 101.04 -0.01 101.03 3.00 6.01 0.00 0.00 6.01 0.01 2.00 1.78 0.04 3.04 0.02 0.02 100.36 -0.01 100.35 3.00 6.03 0.00 0.00 6.03 0.03 2.15 1.67 0.02 2.98 0.09 0.00 100.08 -0.04 100.04 3.00 6.07 0.00 0.00 6.07 0.05 3.67 0.86 0.05 2.71 0.06 0.00 99.88 -0.03 99.86 3.00 5.99 0.00 0.01 6.00 0.06 1.62 1.68 0.02 2.23 0.11 0.09 101.82 -0.07 101.76 3.00 5.97 0.00 0.03 6.00 0.05 1.34 1.78 0.03 2.21 0.05 0.09 101.80 -0.04 101.76 3.00 5.96 0.00 0.04 6.00 0.06 0.75 2.04 0.02 2.28 0.05 0.01 101.92 -0.02 101.90 3.00 5.99 0.00 0.01 6.00 0.04 0.79 1.95 0.02 2.33 0.06 0.01 101.78 -0.03 101.75 3.00 6.00 0.00 0.00 6.00 0.04 0.62 2.06 0.03 2.20 0.01 0.01 102.38 -0.01 102.37 3.00 6.01 0.00 0.00 6.01 0.05 0.71 2.19 0.03 2.22 0.00 0.01 102.13 0.00 102.12 3.00 5.99 0.00 0.01 6.00 0.06 1.44 1.71 0.03 2.22 0.04 0.11 101.85 -0.04 101.81 3.00 5.95 0.00 0.05 6.00 0.08 1.06 2.02 0.02 2.33 0.00 0.05 101.63 -0.01 101.62 3.00 6.00 0.00 0.00 6.00 0.15 0.72 2.10 0.02 2.32 0.00 0.03 102.14 -0.01 102.13 3.00 5.96 0.00 0.04 6.00 0.08 1.69 1.82 0.03 2.21 0.08 0.09 102.40 -0.05 102.35 3.00 5.99 0.00 0.01 6.00 0.06 1.52 1.85 0.03 2.37 0.05 0.05 102.00 -0.03 101.97 3.00 5.97 0.00 0.03 6.00 0.04 0.88 2.05 0.03 2.35 0.00 0.01 101.75 0.00 101.75 3.00 5.97 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0.06 0.05 102.13 -0.03 102.10 3.00 5.91 0.00 0.09 6.00 0.08 1.46 2.00 0.03 2.49 0.02 0.01 101.40 -0.01 101.39 3.00 6.02 0.00 0.00 6.02 0.07 2.49 1.38 0.02 2.39 0.05 0.07 101.97 -0.03 101.93 3.00 5.99 0.00 0.01 6.00 0.07 2.43 1.54 0.03 2.34 0.14 0.08 102.38 -0.08 102.30 3.00 6.02 0.00 0.00 6.02 0.04 1.94 1.68 0.03 2.23 0.08 0.07 102.24 -0.05 102.19 3.00 6.01 0.00 0.00 6.01 0.17 0.83 1.99 0.03 2.13 0.01 0.04 102.20 -0.01 102.19 3.00 5.95 0.00 0.05 6.00 0.05 1.68 2.03 0.02 2.33 0.05 0.01 101.85 -0.02 101.83 3.00 6.00 0.00 0.00 6.00 0.04 1.45 2.05 0.04 2.23 0.12 0.01 102.06 -0.05 102.01 3.00 5.97 0.00 0.03 6.00 0.07 1.93 1.88 0.04 2.18 0.14 0.01 102.29 -0.06 102.23 3.00 5.98 0.00 0.02 6.00 0.02 1.85 1.87 0.03 2.35 0.16 0.01 101.78 -0.07 101.71 3.00 6.02 0.00 0.00 6.02 0.05 1.75 1.90 0.04 2.23 0.07 0.00 101.38 -0.03 101.35 3.00 6.05 0.00 0.00 6.05 0.04 1.80 1.97 0.05 2.16 0.09 0.01 101.83 -0.04 101.79 3.00 5.99 0.00 0.01 6.00 0.05 1.88 1.86 0.04 2.14 0.17 0.01 102.08 -0.07 102.01 3.00 6.01 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0.00 100.79 0.00 100.79 3.00 6.03 0.00 0.00 6.03 0.01 0.73 2.35 0.00 3.18 0.02 0.00 101.01 -0.01 101.00 3.00 5.94 0.00 0.06 6.00 0.03 0.36 2.41 0.04 3.37 0.00 0.03 99.88 -0.01 99.88 3.00 5.99 0.00 0.01 6.00 0.03 0.27 2.48 0.00 3.35 0.00 0.00 100.48 0.00 100.48 3.00 6.06 0.00 0.00 6.06 0.01 0.73 2.21 0.04 3.26 0.01 0.11 101.57 -0.03 101.55 3.00 5.96 0.00 0.04 6.00 0.01 0.59 2.39 0.01 3.28 0.05 0.04 101.93 -0.03 101.90 3.00 6.00 0.00 0.00 6.00 0.01 1.26 1.91 0.02 3.13 0.07 0.14 100.10 -0.06 100.04 3.00 5.98 0.00 0.02 6.00 0.00 0.71 2.25 0.02 3.15 0.03 0.07 101.06 -0.03 101.03 3.00 5.99 0.00 0.01 6.00 0.01 0.11 1.70 0.00 3.24 0.07 0.00 101.33 -0.03 101.30 3.00 6.06 0.00 0.00 6.06 0.01 0.94 2.43 0.01 3.10 0.05 0.00 100.95 -0.02 100.93 3.00 5.97 0.00 0.03 6.00 0.01 0.69 2.36 0.00 3.11 0.00 0.00 100.93 0.00 100.93 3.00 5.96 0.00 0.04 6.00 0.03 1.27 2.10 0.02 3.20 0.03 0.00 101.16 -0.01 101.15 3.00 5.93 0.00 0.07 6.00 0.00 0.70 2.26 0.05 3.14 0.06 0.07 100.25 -0.04 100.21 3.00 5.98 0.00 0.02 6.00 0.03 1.67 1.93 0.08 3.28 0.05 0.01 100.90 -0.02 100.88 3.00 5.99 0.00 0.01 6.00 0.00 1.32 1.98 0.01 3.06 0.01 0.03 99.61 -0.01 99.60 3.00 6.02 0.00 0.00 6.02 0.01 0.97 2.13 0.00 3.09 0.05 0.06 100.27 -0.03 100.23 3.00 6.03 0.00 0.00 6.03 0.01 0.88 2.06 0.01 3.09 0.06 0.02 99.63 -0.03 99.60 3.00 5.88 0.00 0.12 6.00 0.03 0.87 2.18 0.02 3.16 0.05 0.01 100.63 -0.02 100.61 3.00 6.01 0.00 0.00 6.01 0.01 0.04 1.74 0.00 3.24 0.02 0.01 101.26 -0.01 101.25 3.00 6.08 0.00 0.00 6.08 0.00 0.35 2.22 0.01 3.51 0.02 0.00 101.25 -0.01 101.25 3.00 6.08 0.00 0.00 6.08 0.00 1.18 2.26 0.00 3.58 0.01 0.00 101.16 0.00 101.16 3.00 6.00 0.00 0.00 6.00 0.03 0.67 2.28 0.00 3.05 0.02 0.00 100.68 -0.01 100.67 3.00 5.97 0.00 0.03 6.00 0.00 1.16 2.06 0.01 3.10 0.05 0.00 100.72 -0.02 100.70 3.00 6.01 0.00 0.00 6.01 0.00 0.70 2.22 0.01 3.35 0.08 0.00 101.15 -0.03 101.11 3.00 6.03 0.00 0.00 6.03 0.00 0.31 2.10 0.01 3.34 0.03 0.00 101.27 -0.01 101.26 3.00 6.03 0.00 0.00 6.03 0.03 0.28 2.09 0.01 3.38 0.01 0.00 100.97 0.00 100.97 3.00 6.01 0.00 0.00 6.01 0.00 0.49 2.32 0.01 3.37 0.01 0.00 100.88 0.00 100.88 3.00 6.06 0.00 0.00 6.06 0.00 1.33 2.04 0.01 3.28 0.00 0.01 101.20 0.00 101.19 3.00 5.95 0.00 0.05 6.00 0.00 0.90 2.25 0.01 3.16 0.01 0.01 101.07 -0.01 101.07 3.00 5.98 0.00 0.02 6.00 0.01 0.25 2.31 0.02 3.09 0.08 0.02 100.96 -0.04 100.92 3.00 6.09 0.00 0.00 6.09 0.01 1.05 2.05 0.06 3.21 0.04 0.00 100.61 -0.02 100.59 3.00 6.04 0.00 0.00 6.04 0.01 1.50 1.81 0.04 3.24 0.05 0.01 100.32 -0.02 100.30 3.00 6.08 0.00 0.00 6.08 0.00 0.41 2.20 0.04 3.46 0.04 0.01 101.65 -0.02 101.63 3.00 6.10 0.00 0.00 6.10 0.01 1.37 2.04 0.06 3.55 0.04 0.01 102.17 -0.02 102.15 3.00 6.05 0.00 0.00 6.05 0.00 0.63 2.37 0.04 3.56 0.00 0.00 102.81 0.00 102.81 3.00 6.05 0.00 0.00 6.05 0.01 1.32 2.00 0.04 3.45 0.04 0.01 101.47 -0.02 101.45 3.00 6.03 0.00 0.00 6.03 0.01 1.54 1.97 0.05 3.36 0.06 0.02 102.44 -0.03 102.41 3.00 6.06 0.00 0.00 6.06 0.00 1.32 2.00 0.05 3.19 0.06 0.01 101.07 -0.03 101.04 3.00 6.08 0.00 0.00 6.08 0.00 0.67 2.20 0.02 3.29 0.04 0.00 101.55 -0.02 101.54 3.00 6.12 0.00 0.00 6.12 0.00 1.46 1.90 0.05 3.35 0.08 0.01 102.29 -0.04 102.25 3.00 6.01 0.00 0.00 6.01 0.00 1.23 1.83 0.05 3.12 0.04 0.01 100.42 -0.02 100.40 3.00 6.05 0.00 0.00 6.05 0.01 0.77 1.82 0.04 3.15 0.07 0.01 100.78 -0.03 100.75 3.00 6.07 0.00 0.00 6.07 0.03 1.57 1.78 0.02 3.16 0.08 0.02 100.53 -0.04 100.49 3.00 6.04 0.00 0.00 6.04 0.01 0.74 2.33 0.01 3.19 0.02 0.00 101.74 -0.01 101.73 3.00 6.03 0.00 0.00 6.03 0.01 1.82 1.67 0.04 3.14 0.08 0.00 100.71 -0.03 100.68 3.00 6.04 0.00 0.00 6.04 0.01 0.74 1.89 0.04 3.12 0.08 0.00 100.08 -0.03 100.04 3.00 6.06 0.00 0.00 6.06 0.01 0.73 2.05 0.02 3.20 0.09 0.01 100.60 -0.04 100.56 3.00 6.04 0.00 0.00 6.04 0.00 0.66 2.18 0.01 2.97 0.06 0.01 101.14 -0.03 101.11 3.00 6.10 0.00 0.00 6.10 0.03 1.61 1.90 0.06 3.22 0.05 0.01 101.88 -0.02 101.85 3.00 6.01 0.00 0.00 6.01 0.00 0.66 2.26 0.05 3.19 0.02 0.00 101.61 -0.01 101.60 3.00 6.03 0.00 0.00 6.03 0.03 0.34 2.08 0.01 2.97 0.04 0.00 101.48 -0.02 101.46 3.00 6.08 0.00 0.00 6.08 0.01 0.90 1.91 0.04 2.93 0.02 0.09 100.91 -0.03 100.88 3.00 6.06 0.00 0.00 6.06 0.01 0.46 2.08 0.05 3.17 0.00 0.00 101.02 0.00 101.02 3.00 6.05 0.00 0.00 6.05 0.03 0.99 2.04 0.05 3.01 0.04 0.03 101.40 -0.02 101.38 3.00 6.06 0.00 0.00 6.06 0.00 0.50 1.91 0.04 3.09 0.04 0.00 99.65 -0.02 99.63 3.00 6.05 0.00 0.00 6.05 0.03 0.53 2.22 0.01 3.08 0.03 0.01 99.97 -0.01 99.95 3.00 6.04 0.00 0.00 6.04 0.03 0.43 2.18 0.02 3.14 0.00 0.00 100.07 0.00 100.07 3.00 6.05 0.00 0.00 6.05 0.01 0.55 1.90 0.01 3.12 0.00 0.00 99.84 0.00 99.84 3.00 6.06 0.00 0.00 6.06 0.01 0.49 2.06 0.01 3.15 0.01 0.01 100.32 -0.01 100.31 3.00 6.03 0.00 0.00 6.03 0.04 0.28 2.24 0.05 3.15 0.03 0.00 99.84 -0.01 99.83 3.00 6.01 0.00 0.00 6.01 0.01 0.48 2.12 0.05 3.13 0.00 0.01 102.08 0.00 102.07 3.00 6.04 0.00 0.00 6.04 0.01 0.99 1.97 0.05 3.00 0.09 0.02 100.81 -0.04 100.77 3.00 6.05 0.00 0.00 6.05 0.01 0.53 2.25 0.02 2.98 0.01 0.00 99.15 0.00 99.15 3.00 6.09 0.00 0.00 6.09 0.01 0.42 2.17 0.02 3.21 0.00 0.00 101.03 0.00 101.03 3.00 6.05 0.00 0.00 6.05 0.01 0.49 2.20 0.02 3.12 0.02 0.00 100.25 -0.01 100.24 3.00 6.05 0.00 0.00 6.05 0.00 0.57 2.20 0.01 3.24 0.02 0.00 100.22 -0.01 100.21 3.00 6.03 0.00 0.00 6.03 0.01 1.04 1.65 0.02 3.01 0.03 0.05 102.88 -0.02 102.86 3.00 5.94 0.00 0.06 6.00 0.00 0.95 1.27 0.01 2.94 0.05 0.07 102.95 -0.04 102.91 3.00 5.90 0.00 0.10 6.00 0.00 0.57 2.08 0.01 3.10 0.00 0.01 102.74 0.00 102.74 3.00 6.07 0.00 0.00 6.07 0.00 0.63 2.00 0.02 3.07 0.03 0.00 102.53 -0.01 102.52 3.00 6.05 0.00 0.00 6.05 0.01 1.19 1.46 0.01 3.03 0.04 0.04 102.96 -0.03 102.94 3.00 5.91 0.00 0.09 6.00 0.00 1.19 1.92 0.00 2.90 0.07 0.02 102.73 -0.03 102.70 3.00 6.06 0.00 0.00 6.06 0.03 1.04 1.46 0.02 2.98 0.03 0.03 102.44 -0.02 102.42 3.00 5.93 0.00 0.07 6.00 0.01 0.97 2.14 0.03 2.96 0.04 0.01 102.71 -0.02 102.69 3.00 6.04 0.00 0.00 6.04 0.00 1.04 2.05 0.03 2.98 0.00 0.00 102.71 0.00 102.70 3.00 6.02 0.00 0.00 6.02 0.03 1.10 1.56 0.02 3.05 0.02 0.04 103.17 -0.02 103.15 3.00 5.92 0.00 0.08 6.00 0.02 0.93 1.71 0.01 2.93 0.08 0.04 102.55 -0.04 102.51 3.00 6.00 0.00 0.00 6.00 0.00 0.86 1.57 0.01 2.97 0.02 0.02 103.39 -0.02 103.38 3.00 5.92 0.00 0.08 6.00 0.03 1.00 2.12 0.04 2.97 0.04 0.01 102.89 -0.02 102.87 3.00 6.01 0.00 0.00 6.01 0.01 1.14 1.93 0.03 2.94 0.06 0.01 102.56 -0.03 102.53 3.00 6.03 0.00 0.00 6.03 0.04 1.02 1.25 0.03 2.82 0.02 0.09 101.54 -0.03 101.52 3.00 5.82 0.00 0.17 6.00 0.01 0.98 1.63 0.02 2.88 0.04 0.03 102.75 -0.02 102.73 3.00 5.93 0.00 0.07 6.00 0.01 1.05 1.90 0.03 2.95 0.00 0.02 102.11 -0.01 102.11 3.00 6.02 0.00 0.00 6.02 0.00 0.94 1.18 0.02 2.91 0.00 0.06 101.82 -0.01 101.81 3.00 5.81 0.00 0.19 6.00 0.03 1.03 1.84 0.02 2.93 0.08 0.02 102.49 -0.04 102.45 3.00 6.00 0.00 0.00 6.00 0.02 1.02 2.04 0.03 2.96 0.04 0.00 102.25 -0.02 102.23 3.00 6.01 0.00 0.00 6.01 0.03 1.08 1.48 0.03 3.01 0.03 0.01 102.11 -0.02 102.09 3.00 5.90 0.00 0.10 6.00 0.03 1.24 1.80 0.02 2.95 0.00 0.02 102.38 0.00 102.37 3.00 6.00 0.00 0.00 6.00 0.00 1.00 2.06 0.03 2.85 0.08 0.14 102.59 -0.06 102.52 3.00 6.04 0.00 0.00 6.04 0.01 0.71 1.81 0.02 3.11 0.06 0.02 100.85 -0.03 100.82 3.00 6.03 0.00 0.00 6.03 0.01 0.88 1.85 0.02 2.97 0.02 0.01 101.98 -0.01 101.97 3.00 6.01 0.00 0.00 6.01 0.01 0.35 2.59 0.00 3.16 0.06 0.00 101.78 -0.03 101.76 3.00 6.06 0.00 0.00 6.06 0.04 0.24 1.35 0.02 3.15 0.03 0.00 100.72 -0.01 100.71 3.00 6.07 0.00 0.00 6.07 0.01 1.19 1.97 0.04 3.03 0.00 0.01 100.87 0.00 100.86 3.00 6.03 0.00 0.00 6.03 0.03 0.27 1.47 0.02 3.19 0.05 0.00 101.88 -0.02 101.86 3.00 6.06 0.00 0.00 6.06 0.00 0.52 2.13 0.01 3.12 0.04 0.00 100.64 -0.02 100.63 3.00 6.04 0.00 0.00 6.04 0.00 1.08 2.10 0.01 3.01 0.05 0.00 100.88 -0.02 100.86 3.00 6.03 0.00 0.00 6.03 0.01 0.52 2.04 0.01 3.13 0.00 0.00 100.46 0.00 100.46 3.00 6.06 0.00 0.00 6.06 0.01 0.24 1.86 0.01 3.17 0.01 0.00 101.25 0.00 101.25 3.00 6.04 0.00 0.00 6.04 0.00 0.94 2.00 0.02 3.16 0.06 0.00 100.99 -0.03 100.96 3.00 6.04 0.00 0.00 6.04 0.01 0.85 1.90 0.05 3.01 0.07 0.03 102.80 -0.04 102.77 3.00 6.01 0.00 0.00 6.01 0.03 1.26 1.85 0.04 3.05 0.07 0.02 101.30 -0.03 101.26 3.00 6.05 0.00 0.00 6.05 0.00 1.13 1.91 0.04 3.04 0.05 0.02 102.30 -0.03 102.27 3.00 6.08 0.00 0.00 6.08 0.02 1.40 1.88 0.03 3.46 0.04 0.01 102.30 -0.02 102.28 3.00 6.00 0.00 0.00 6.00 0.00 0.46 2.08 0.03 3.57 0.00 0.01 101.17 0.00 101.17 3.00 6.03 0.00 0.00 6.03 0.10 0.28 2.05 0.03 2.98 0.43 0.00 101.15 -0.18 100.98 3.00 5.93 0.00 0.07 6.00 0.00 0.58 2.15 0.03 3.15 0.04 0.00 100.78 -0.02 100.76 3.00 6.08 0.00 0.00 6.08 0.01 0.67 2.20 0.03 3.46 0.12 0.07 102.10 -0.06 102.04 3.00 5.82 0.00 0.18 6.00 0.00 1.06 1.97 0.03 3.19 0.05 0.02 101.36 -0.03 101.33 3.00 5.99 0.00 0.01 6.00 0.03 0.34 2.38 0.04 3.64 0.04 0.01 102.67 -0.02 102.65 3.00 6.02 0.00 0.00 6.02 0.01 1.33 1.84 0.04 3.42 0.02 0.01 102.09 -0.01 102.08 3.00 5.97 0.00 0.03 6.00 0.03 0.88 2.10 0.03 3.56 0.03 0.01 100.94 -0.02 100.92 3.00 6.03 0.00 0.00 6.03 0.01 0.98 2.13 0.04 3.00 0.01 0.03 102.48 -0.01 102.47 3.00 6.03 0.00 0.00 6.03 0.00 1.16 1.56 0.07 3.39 0.01 0.01 101.55 -0.01 101.54 3.00 5.96 0.03 0.01 6.00 0.00 1.15 1.58 0.02 3.12 0.03 0.03 102.00 -0.02 101.98 3.00 5.95 0.09 0.00 6.04 0.01 0.98 1.56 0.06 3.01 0.00 0.03 102.30 -0.01 102.29 3.00 5.97 0.00 0.03 6.00 0.01 0.06 1.17 0.02 3.22 0.07 0.05 101.24 -0.04 101.20 3.00 5.82 0.00 0.18 6.00 0.03 0.78 1.51 0.02 3.13 0.00 0.02 101.34 0.00 101.34 3.00 5.93 0.00 0.07 6.00 0.01 1.11 1.47 0.04 2.97 0.04 0.04 102.01 -0.03 101.99 3.00 5.91 0.00 0.09 6.00 0.03 0.03 1.90 0.01 3.27 0.07 0.01 100.97 -0.03 100.94 3.00 5.80 0.00 0.20 6.00 0.02 0.02 1.88 0.00 3.14 0.07 0.00 101.58 -0.03 101.55 3.00 5.95 0.00 0.05 6.00 0.03 0.01 2.15 0.02 3.19 0.12 0.01 102.30 -0.05 102.25 3.00 5.95 0.00 0.04 6.00 0.02 0.00 2.03 0.00 3.15 0.11 0.01 102.86 -0.05 102.81 3.00 5.98 0.00 0.02 6.00 0.05 0.02 2.19 0.00 3.18 0.06 0.00 101.75 -0.03 101.73 3.00 5.93 0.00 0.07 6.00 0.00 0.01 1.66 0.01 3.15 0.05 0.02 101.76 -0.03 101.73 3.00 5.99 0.00 0.01 6.00 0.01 0.02 1.54 0.00 3.10 0.07 0.00 102.17 -0.03 102.14 3.00 6.00 0.00 0.00 6.00 0.01 0.02 2.11 0.00 3.21 0.08 0.00 102.01 -0.03 101.97 3.00 5.87 0.00 0.13 6.00 0.01 0.01 1.82 0.00 3.14 0.01 0.00 101.63 0.00 101.63 3.00 6.00 0.00 0.00 6.00 0.01 0.00 1.70 0.01 3.17 0.03 0.00 101.96 -0.01 101.95 3.00 5.97 0.00 0.03 6.00 0.00 0.00 1.57 0.01 3.16 0.05 0.00 102.35 -0.02 102.33 3.00 5.99 0.00 0.01 6.00 0.00 0.00 1.60 0.02 3.12 0.09 0.01 102.46 -0.04 102.42 3.00 5.99 0.00 0.01 6.00 3+ 2+ Cr V Fe Mg Al Sum Al Mg Fe Li Sc Cu Zn Ti Sum Na K Ca 0.00 0.00 0.68 0.50 4.81 6.00 0.00 1.70 1.05 0.00 0.00 0.00 0.00 0.19 2.94 0.48 0.02 0.52 0.00 0.00 0.92 0.70 4.38 6.00 0.00 1.30 1.41 0.00 0.00 0.00 0.00 0.23 2.94 0.45 0.01 0.52 0.00 0.00 0.83 0.74 4.43 6.00 0.00 1.33 1.27 0.00 0.00 0.00 0.00 0.31 2.91 0.60 0.01 0.51 0.00 0.00 0.77 0.52 4.71 6.00 0.00 1.61 1.16 0.00 0.00 0.00 0.00 0.16 2.92 0.42 0.01 0.54 0.00 0.00 0.89 0.49 4.62 6.00 0.00 1.55 1.36 0.00 0.00 0.00 0.00 0.04 2.95 0.46 0.00 0.53 0.00 0.00 0.57 0.44 4.99 6.00 0.00 2.00 0.87 0.00 0.00 0.00 0.00 0.05 2.93 0.46 0.00 0.50 0.00 0.00 0.37 0.00 5.63 6.00 0.03 2.29 0.57 0.00 0.00 0.00 0.00 0.05 2.94 0.63 0.00 0.29 0.00 0.00 0.69 0.50 4.80 6.00 0.00 1.76 1.07 0.00 0.00 0.00 0.00 0.11 2.93 0.49 0.01 0.50 0.00 0.00 0.66 0.59 4.75 6.00 0.00 1.67 1.00 0.00 0.00 0.00 0.00 0.30 2.97 0.43 0.01 0.54 0.00 0.00 0.74 0.05 5.21 6.00 0.00 1.76 1.13 0.00 0.00 0.00 0.00 0.07 2.97 0.62 0.01 0.34 0.00 0.00 0.52 0.00 5.48 6.00 0.56 1.58 0.79 0.00 0.00 0.00 0.00 0.00 2.94 0.78 0.00 0.09 0.00 0.00 0.71 0.00 5.29 6.00 0.28 1.57 1.07 0.00 0.00 0.00 0.00 0.01 2.94 0.71 0.01 0.26 0.00 0.00 0.63 0.00 5.37 6.00 0.91 1.11 0.96 0.00 0.00 0.00 0.00 0.00 2.98 0.73 0.00 0.04 0.00 0.00 0.81 0.00 5.19 6.00 0.33 1.41 1.23 0.00 0.00 0.00 0.00 0.00 2.97 0.75 0.01 0.20 0.00 0.00 0.53 0.00 5.47 6.00 0.63 1.53 0.80 0.00 0.00 0.00 0.00 0.00 2.96 0.74 0.01 0.11 0.00 0.00 0.74 0.00 5.26 6.00 0.42 1.47 1.11 0.00 0.00 0.00 0.00 0.00 3.00 0.74 0.01 0.22 0.00 0.00 0.79 0.00 5.21 6.00 0.21 1.55 1.21 0.00 0.00 0.00 0.00 0.00 2.97 0.64 0.01 0.29 0.00 0.00 0.73 0.00 5.27 6.00 0.32 1.48 1.12 0.00 0.00 0.00 0.00 0.02 2.93 0.72 0.01 0.25 0.00 0.00 0.56 0.00 5.44 6.00 0.79 1.37 0.84 0.00 0.00 0.00 0.00 0.00 3.00 0.72 0.01 0.15 0.00 0.00 1.00 0.00 5.00 6.00 0.96 0.50 1.52 0.00 0.00 0.00 0.00 0.00 2.99 0.81 0.01 0.06 0.00 0.00 0.68 0.00 5.32 6.00 0.52 1.43 1.02 0.00 0.00 0.00 0.00 0.03 3.00 0.72 0.01 0.22 0.00 0.00 0.83 0.00 5.17 6.00 0.44 1.72 0.69 0.00 0.00 0.00 0.00 0.02 2.87 0.87 0.01 0.05 0.00 0.05 0.04 0.36 5.55 6.00 0.00 2.45 0.03 0.00 0.00 0.00 0.00 0.47 2.96 0.68 0.01 0.26 0.00 0.01 1.07 0.00 4.93 6.00 0.35 1.67 0.87 0.00 0.00 0.00 0.00 0.04 2.95 0.86 0.00 0.08 0.00 0.02 1.10 0.00 4.88 6.00 0.32 1.64 0.90 0.00 0.00 0.00 0.00 0.07 2.93 0.85 0.01 0.09 0.00 0.05 0.04 0.37 5.53 6.00 0.00 2.42 0.03 0.00 0.00 0.00 0.00 0.46 2.92 0.69 0.01 0.27 0.00 0.01 0.72 0.00 5.27 6.00 0.64 1.68 0.59 0.00 0.00 0.00 0.00 0.01 2.93 0.81 0.00 0.02 0.00 0.04 0.79 0.00 5.17 6.00 0.55 1.68 0.66 0.00 0.01 0.00 0.00 0.02 2.92 0.83 0.00 0.03 0.00 0.01 0.68 0.00 5.31 6.00 0.49 1.87 0.57 0.00 0.01 0.00 0.00 0.01 2.94 0.82 0.00 0.03 0.00 0.00 0.81 0.00 5.18 6.00 0.50 1.75 0.67 0.00 0.00 0.00 0.00 0.01 2.93 0.81 0.00 0.06 0.00 0.01 0.92 0.00 5.07 6.00 0.45 1.68 0.77 0.00 0.00 0.00 0.00 0.03 2.94 0.82 0.01 0.09 0.00 0.01 1.01 0.00 4.99 6.00 0.39 1.70 0.83 0.00 0.00 0.00 0.00 0.02 2.94 0.81 0.00 0.10 0.00 0.00 0.80 0.00 5.19 6.00 0.73 1.57 0.66 0.00 0.00 0.00 0.00 0.01 2.96 0.85 0.00 0.02 0.00 0.05 0.04 0.37 5.54 6.00 0.00 2.47 0.03 0.00 0.00 0.00 0.00 0.47 2.98 0.69 0.01 0.27 0.00 0.05 0.04 0.34 5.57 6.00 0.00 2.46 0.03 0.00 0.00 0.00 0.00 0.48 2.98 0.69 0.01 0.26 0.00 0.00 0.70 0.00 5.30 6.00 0.62 1.73 0.58 0.00 0.00 0.00 0.00 0.01 2.94 0.78 0.00 0.04 0.00 0.05 0.04 0.32 5.59 6.00 0.00 2.49 0.03 0.00 0.00 0.00 0.00 0.47 2.99 0.67 0.01 0.27 0.00 0.01 0.67 0.00 5.32 6.00 0.61 1.76 0.56 0.00 0.00 0.00 0.00 0.01 2.94 0.79 0.00 0.05 0.00 0.06 0.05 0.35 5.53 6.00 0.00 2.48 0.04 0.00 0.00 0.00 0.00 0.44 2.96 0.67 0.01 0.27 0.00 0.00 0.78 0.00 5.22 6.00 0.66 1.62 0.65 0.00 0.00 0.00 0.00 0.01 2.93 0.81 0.00 0.02 0.00 0.05 0.03 0.32 5.59 6.00 0.00 2.49 0.03 0.00 0.00 0.00 0.00 0.46 2.98 0.67 0.01 0.27 0.00 0.01 1.02 0.00 4.98 6.00 0.40 1.72 0.83 0.00 0.00 0.00 0.00 0.02 2.97 0.84 0.00 0.10 0.00 0.00 0.78 0.00 5.22 6.00 0.54 1.70 0.64 0.00 0.00 0.00 0.00 0.01 2.89 0.80 0.00 0.04 0.00 0.05 0.03 0.34 5.57 6.00 0.00 2.46 0.03 0.00 0.00 0.00 0.00 0.47 2.96 0.66 0.00 0.26 0.00 0.00 0.81 0.00 5.19 6.00 0.54 1.73 0.67 0.00 0.00 0.00 0.00 0.02 2.96 0.87 0.00 0.04 0.00 0.01 1.10 0.00 4.89 6.00 0.26 1.69 0.90 0.00 0.00 0.00 0.00 0.09 2.95 0.80 0.01 0.15 0.00 0.00 0.61 0.00 5.39 6.00 0.67 1.78 0.50 0.00 0.00 0.00 0.00 0.00 2.95 0.81 0.00 0.02 0.00 0.02 1.13 0.00 4.85 6.00 0.26 1.71 0.95 0.00 0.01 0.00 0.00 0.03 2.95 0.86 0.01 0.09 0.00 0.00 0.88 0.00 5.12 6.00 0.47 1.73 0.73 0.00 0.00 0.00 0.00 0.01 2.94 0.83 0.01 0.06 0.00 0.00 0.84 0.00 5.16 6.00 0.54 1.71 0.69 0.00 0.00 0.00 0.00 0.01 2.96 0.85 0.00 0.05 0.00 0.04 0.06 0.44 5.46 6.00 0.00 2.43 0.05 0.00 0.00 0.00 0.00 0.47 2.95 0.65 0.01 0.29 0.00 0.05 0.05 0.35 5.54 6.00 0.00 2.48 0.04 0.00 0.00 0.00 0.00 0.43 2.95 0.67 0.01 0.25 0.00 0.06 0.05 0.25 5.64 6.00 0.00 2.54 0.04 0.00 0.00 0.00 0.00 0.39 2.98 0.71 0.00 0.22 0.00 0.00 0.84 0.00 5.16 6.00 0.51 1.73 0.69 0.00 0.00 0.00 0.00 0.03 2.96 0.83 0.00 0.06 0.00 0.04 0.32 0.06 5.58 6.00 0.00 2.39 0.26 0.00 0.00 0.00 0.00 0.34 2.99 0.74 0.01 0.18 0.00 0.00 0.91 0.00 5.09 6.00 0.60 1.60 0.75 0.00 0.00 0.00 0.00 0.01 2.96 0.89 0.00 0.02 0.00 0.00 0.66 0.00 5.33 6.00 0.63 1.79 0.55 0.00 0.00 0.00 0.00 0.00 2.97 0.83 0.00 0.03 0.00 0.00 0.57 0.00 5.43 6.00 0.73 1.75 0.47 0.00 0.00 0.00 0.00 0.01 2.95 0.77 0.00 0.03 0.00 0.08 0.24 0.26 5.43 6.00 0.00 2.30 0.20 0.00 0.00 0.00 0.00 0.48 2.99 0.75 0.01 0.22 0.00 0.08 0.30 0.37 5.24 6.00 0.00 2.14 0.26 0.00 0.01 0.00 0.00 0.58 2.99 0.72 0.01 0.23 0.00 0.00 0.81 0.00 5.18 6.00 0.63 1.63 0.67 0.00 0.00 0.00 0.00 0.01 2.95 0.84 0.00 0.03 0.00 0.11 0.53 0.92 4.43 6.00 0.00 1.74 0.43 0.00 0.01 0.00 0.00 0.78 2.97 0.69 0.01 0.31 0.00 0.00 0.65 0.00 5.35 6.00 0.65 1.73 0.53 0.00 0.00 0.00 0.00 0.01 2.93 0.80 0.00 0.02 0.00 0.00 0.85 0.00 5.15 6.00 0.57 1.65 0.71 0.00 0.00 0.00 0.00 0.01 2.95 0.84 0.00 0.02 0.00 0.00 0.86 0.00 5.14 6.00 0.58 1.66 0.71 0.00 0.00 0.00 0.00 0.01 2.96 0.87 0.00 0.02 0.00 0.00 0.65 0.00 5.35 6.00 0.62 1.78 0.53 0.00 0.00 0.00 0.00 0.01 2.95 0.82 0.00 0.03 0.00 0.08 0.15 0.53 5.25 6.00 0.00 2.27 0.12 0.00 0.00 0.00 0.00 0.58 2.98 0.66 0.01 0.29 0.00 0.05 0.03 0.30 5.61 6.00 0.00 2.49 0.03 0.00 0.00 0.00 0.00 0.47 2.99 0.67 0.00 0.26 0.01 0.12 0.37 0.76 4.75 6.00 0.00 1.95 0.30 0.00 0.01 0.00 0.00 0.69 2.95 0.62 0.01 0.32 0.00 0.01 0.96 0.00 5.03 6.00 0.43 1.66 0.79 0.00 0.00 0.00 0.00 0.03 2.91 0.85 0.00 0.07 0.00 0.10 0.41 0.73 4.76 6.00 0.00 1.92 0.34 0.00 0.01 0.00 0.00 0.68 2.95 0.68 0.01 0.27 0.00 0.05 0.05 0.27 5.63 6.00 0.00 2.51 0.04 0.00 0.00 0.00 0.00 0.39 2.94 0.68 0.00 0.24 0.00 0.00 0.80 0.00 5.20 6.00 0.61 1.66 0.66 0.00 0.00 0.00 0.00 0.01 2.94 0.81 0.00 0.04 0.00 0.05 0.06 0.27 5.62 6.00 0.00 2.52 0.05 0.00 0.00 0.00 0.00 0.39 2.97 0.69 0.00 0.23 0.00 0.00 0.84 0.00 5.16 6.00 0.46 1.75 0.70 0.00 0.00 0.00 0.00 0.01 2.93 0.85 0.00 0.04 0.00 0.05 0.05 0.23 5.67 6.00 0.00 2.55 0.04 0.00 0.00 0.00 0.00 0.39 2.98 0.67 0.01 0.26 0.00 0.01 0.87 0.00 5.13 6.00 0.37 1.83 0.72 0.00 0.00 0.00 0.00 0.01 2.94 0.84 0.00 0.05 0.00 0.00 0.65 0.00 5.34 6.00 0.65 1.76 0.55 0.00 0.00 0.00 0.00 0.01 2.96 0.81 0.00 0.03 0.00 0.00 0.83 0.00 5.16 6.00 0.54 1.70 0.68 0.00 0.01 0.00 0.00 0.01 2.94 0.87 0.00 0.02 0.00 0.01 0.24 0.09 5.66 6.00 0.00 1.78 1.12 0.00 0.01 0.00 0.00 0.01 2.92 0.82 0.00 0.02 0.00 0.00 0.61 0.00 5.38 6.00 0.63 1.76 0.51 0.00 0.00 0.00 0.00 0.01 2.91 0.82 0.00 0.03 0.00 0.06 0.08 0.54 5.31 6.00 0.00 2.31 0.07 0.00 0.00 0.00 0.00 0.55 2.94 0.63 0.01 0.30 0.00 0.04 0.08 0.30 5.58 6.00 0.00 2.49 0.06 0.00 0.00 0.00 0.00 0.41 2.97 0.72 0.01 0.24 0.00 0.05 0.05 0.28 5.62 6.00 0.00 2.52 0.04 0.00 0.00 0.00 0.00 0.42 2.98 0.69 0.01 0.24 0.00 0.00 0.62 0.00 5.38 6.00 0.70 1.70 0.51 0.00 0.00 0.00 0.00 0.01 2.91 0.74 0.00 0.04 0.00 0.05 0.05 0.25 5.65 6.00 0.00 2.53 0.04 0.00 0.00 0.00 0.00 0.41 2.98 0.71 0.01 0.24 0.00 0.00 0.72 0.00 5.28 6.00 0.64 1.70 0.59 0.00 0.00 0.00 0.00 0.01 2.94 0.75 0.00 0.04 0.00 0.01 1.14 0.00 4.84 6.00 0.18 1.70 0.95 0.00 0.01 0.00 0.00 0.14 2.98 0.81 0.01 0.13 0.00 0.05 0.04 0.31 5.59 6.00 0.00 2.51 0.03 0.00 0.00 0.00 0.00 0.44 2.98 0.68 0.01 0.26 0.00 0.00 0.63 0.00 5.37 6.00 0.66 1.71 0.53 0.00 0.00 0.00 0.00 0.01 2.91 0.79 0.00 0.04 0.00 0.05 0.04 0.35 5.56 6.00 0.00 2.49 0.03 0.00 0.00 0.00 0.00 0.46 2.98 0.68 0.01 0.27 0.00 0.01 0.76 0.00 5.22 6.00 0.64 1.63 0.63 0.00 0.00 0.00 0.00 0.01 2.93 0.87 0.00 0.04 0.00 0.05 0.14 0.45 5.35 6.00 0.00 2.35 0.12 0.00 0.00 0.00 0.00 0.46 2.94 0.65 0.01 0.30 0.00 0.01 0.86 0.00 5.13 6.00 0.48 1.74 0.72 0.00 0.00 0.00 0.00 0.02 2.95 0.84 0.00 0.08 0.00 0.00 0.26 0.00 5.74 6.00 0.57 1.49 0.89 0.00 0.00 0.00 0.00 0.05 3.00 0.60 0.01 0.15 0.00 0.00 0.24 0.00 5.76 6.00 0.72 1.41 0.83 0.00 0.00 0.00 0.00 0.04 3.00 0.55 0.01 0.12 0.00 0.00 0.22 0.00 5.78 6.00 0.75 1.41 0.76 0.00 0.00 0.00 0.00 0.03 2.96 0.50 0.01 0.09 0.00 0.00 0.33 0.00 5.67 6.00 0.35 1.49 1.10 0.00 0.00 0.00 0.00 0.03 2.96 0.76 0.01 0.07 0.00 0.00 0.25 0.00 5.75 6.00 0.72 1.39 0.84 0.00 0.00 0.00 0.00 0.04 3.00 0.53 0.01 0.12 0.00 0.00 0.26 0.00 5.74 6.00 0.50 1.57 0.87 0.00 0.00 0.00 0.00 0.06 2.99 0.56 0.01 0.17 0.00 0.07 0.57 0.27 5.09 6.00 0.00 2.05 0.71 0.00 0.00 0.00 0.00 0.23 3.00 0.92 0.01 0.05 0.00 0.05 0.56 0.00 5.38 6.00 0.00 2.13 0.69 0.00 0.00 0.00 0.00 0.15 2.97 0.86 0.01 0.04 0.00 0.03 0.42 0.00 5.54 6.00 0.13 2.20 0.53 0.00 0.00 0.00 0.00 0.10 2.96 0.92 0.01 0.03 0.00 0.05 0.52 0.00 5.43 6.00 0.06 2.14 0.65 0.00 0.00 0.00 0.00 0.15 3.00 0.85 0.01 0.04 0.00 0.02 0.20 0.00 5.78 6.00 0.82 1.92 0.25 0.00 0.00 0.00 0.00 0.00 2.99 0.45 0.00 0.01 0.00 0.01 0.24 0.00 5.74 6.00 0.72 1.97 0.30 0.00 0.00 0.00 0.00 0.00 2.99 0.56 0.00 0.05 0.00 0.06 0.58 0.00 5.36 6.00 0.00 2.11 0.72 0.00 0.00 0.00 0.00 0.16 3.00 0.88 0.01 0.05 0.00 0.06 0.64 0.11 5.19 6.00 0.00 2.03 0.78 0.00 0.00 0.00 0.00 0.18 3.00 0.90 0.01 0.06 0.00 0.02 0.36 0.00 5.62 6.00 0.40 2.12 0.46 0.00 0.00 0.00 0.00 0.01 2.99 0.89 0.00 0.00 0.00 0.03 0.18 0.00 5.78 6.00 0.76 2.01 0.23 0.00 0.00 0.00 0.00 0.00 3.00 0.52 0.00 0.00 0.00 0.05 0.54 0.00 5.40 6.00 0.06 2.12 0.67 0.00 0.00 0.00 0.00 0.15 3.00 0.87 0.01 0.04 0.00 0.03 0.27 0.00 5.70 6.00 0.56 2.08 0.33 0.00 0.01 0.00 0.00 0.00 2.97 0.68 0.00 0.02 0.00 0.05 0.48 0.00 5.47 6.00 0.26 2.00 0.60 0.00 0.00 0.00 0.00 0.14 3.00 0.85 0.01 0.02 0.00 0.02 0.24 0.00 5.74 6.00 0.53 2.09 0.30 0.00 0.00 0.00 0.00 0.01 2.93 0.70 0.00 0.09 0.00 0.06 0.51 0.10 5.33 6.00 0.00 2.16 0.62 0.00 0.00 0.00 0.00 0.21 3.00 0.88 0.01 0.05 0.00 0.07 0.54 0.14 5.25 6.00 0.00 2.14 0.66 0.00 0.00 0.00 0.00 0.20 3.00 0.95 0.01 0.04 0.00 0.02 0.21 0.00 5.76 6.00 0.47 2.23 0.26 0.00 0.00 0.00 0.00 0.00 2.97 0.75 0.00 0.01 0.00 0.01 0.24 0.00 5.74 6.00 0.56 2.13 0.30 0.00 0.00 0.00 0.00 0.00 2.99 0.74 0.00 0.01 0.00 0.02 0.29 0.00 5.69 6.00 0.37 2.24 0.36 0.00 0.00 0.00 0.00 0.00 2.97 0.79 0.00 0.02 0.00 0.07 0.62 0.30 5.00 6.00 0.00 1.99 0.78 0.00 0.00 0.00 0.00 0.23 3.00 0.90 0.01 0.11 0.00 0.06 0.49 0.16 5.28 6.00 0.00 2.17 0.63 0.00 0.00 0.00 0.00 0.21 3.00 0.88 0.01 0.05 0.00 0.02 0.20 0.00 5.78 6.00 0.52 2.22 0.24 0.00 0.00 0.00 0.00 0.00 2.99 0.70 0.00 0.01 0.00 0.03 0.32 0.00 5.65 6.00 0.41 2.10 0.41 0.00 0.00 0.00 0.00 0.02 2.94 0.74 0.01 0.09 0.00 0.07 0.55 0.16 5.22 6.00 0.00 2.10 0.68 0.00 0.00 0.00 0.00 0.22 3.00 0.88 0.01 0.04 0.00 0.05 0.49 0.00 5.46 6.00 0.13 2.16 0.61 0.00 0.00 0.00 0.00 0.09 3.00 0.90 0.01 0.03 0.00 0.02 0.31 0.00 5.68 6.00 0.43 2.11 0.38 0.00 0.00 0.00 0.00 0.03 2.95 0.69 0.02 0.11 0.00 0.03 0.45 0.00 5.52 6.00 0.32 2.10 0.56 0.00 0.01 0.00 0.00 0.02 3.00 0.82 0.01 0.10 0.00 0.04 0.41 0.00 5.56 6.00 0.17 2.27 0.50 0.00 0.00 0.00 0.00 0.06 3.00 0.68 0.01 0.22 0.00 0.06 0.61 0.00 5.33 6.00 0.06 2.09 0.75 0.00 0.00 0.00 0.00 0.10 3.00 0.92 0.01 0.05 0.00 0.03 0.45 0.00 5.52 6.00 0.32 2.07 0.56 0.00 0.00 0.00 0.00 0.04 3.00 0.80 0.02 0.13 0.00 0.06 0.58 0.00 5.35 6.00 0.06 2.11 0.72 0.00 0.00 0.00 0.00 0.11 3.00 0.92 0.01 0.04 0.00 0.05 0.53 0.00 5.42 6.00 0.13 2.13 0.65 0.00 0.00 0.00 0.00 0.09 3.00 0.87 0.01 0.03 0.00 0.04 0.54 0.00 5.42 6.00 0.10 2.12 0.67 0.00 0.00 0.00 0.00 0.09 3.00 0.82 0.01 0.06 0.00 0.06 0.59 0.05 5.30 6.00 0.00 2.11 0.74 0.00 0.00 0.00 0.00 0.14 2.99 0.90 0.01 0.05 0.00 0.01 0.31 0.00 5.68 6.00 0.62 1.98 0.39 0.00 0.00 0.00 0.00 0.00 3.00 0.72 0.00 0.01 0.00 0.03 0.41 0.00 5.56 6.00 0.41 2.05 0.51 0.00 0.01 0.00 0.00 0.02 3.00 0.77 0.01 0.10 0.00 0.05 0.55 0.00 5.41 6.00 0.04 2.14 0.68 0.00 0.00 0.00 0.00 0.13 3.00 0.88 0.01 0.03 0.00 0.06 0.62 0.00 5.32 6.00 0.04 2.10 0.78 0.00 0.00 0.00 0.00 0.08 3.00 0.93 0.01 0.04 0.00 0.03 0.23 0.00 5.75 6.00 0.70 2.02 0.28 0.00 0.00 0.00 0.00 0.00 3.00 0.58 0.00 0.00 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0.55 0.15 5.30 6.00 0.00 1.72 1.02 0.00 0.00 0.00 0.00 0.05 2.80 0.56 0.01 0.40 0.00 0.00 0.83 0.00 5.17 6.00 0.68 1.20 1.09 0.00 0.00 0.00 0.00 0.02 2.98 0.73 0.01 0.17 0.00 0.00 0.81 0.00 5.19 6.00 0.89 1.03 1.04 0.00 0.00 0.00 0.00 0.04 3.00 0.72 0.01 0.14 0.00 0.00 0.89 0.00 5.11 6.00 0.75 1.07 1.14 0.00 0.00 0.00 0.00 0.02 2.98 0.80 0.01 0.12 0.00 0.00 1.11 0.00 4.89 6.00 0.78 0.77 1.42 0.00 0.00 0.00 0.00 0.02 2.99 0.83 0.01 0.04 0.00 0.00 0.87 0.00 5.13 6.00 0.89 0.95 1.13 0.00 0.00 0.00 0.00 0.02 3.00 0.70 0.01 0.16 0.00 0.00 0.78 0.00 5.22 6.00 1.02 0.90 1.02 0.00 0.00 0.00 0.00 0.01 2.95 0.59 0.00 0.01 0.00 0.00 1.04 0.00 4.96 6.00 0.57 1.01 1.33 0.00 0.00 0.00 0.00 0.07 2.98 0.76 0.01 0.14 0.00 0.00 0.97 0.00 5.03 6.00 0.89 0.81 1.28 0.00 0.00 0.00 0.00 0.01 2.99 0.75 0.01 0.11 0.00 0.00 0.96 0.00 5.04 6.00 0.69 1.05 1.23 0.00 0.00 0.00 0.00 0.03 2.99 0.71 0.01 0.17 0.00 0.00 1.10 0.00 4.90 6.00 0.55 0.93 1.44 0.00 0.00 0.00 0.00 0.06 2.99 0.79 0.01 0.14 0.00 0.00 0.99 0.00 5.01 6.00 0.79 0.91 1.29 0.00 0.00 0.00 0.00 0.01 2.99 0.74 0.01 0.12 0.00 0.00 0.43 0.02 5.55 6.00 0.00 1.41 1.54 0.00 0.00 0.00 0.00 0.01 2.96 0.76 0.01 0.07 0.00 0.00 1.54 0.22 4.23 6.00 0.00 1.15 1.78 0.00 0.00 0.00 0.00 0.03 2.96 0.84 0.02 0.10 0.00 0.00 0.24 0.00 5.76 6.00 0.28 0.91 1.79 0.00 0.00 0.00 0.00 0.02 3.00 0.70 0.01 0.14 0.00 0.00 0.26 0.00 5.74 6.00 0.27 0.73 1.98 0.00 0.00 0.00 0.00 0.00 2.98 0.77 0.00 0.05 0.00 0.01 0.53 0.61 4.85 6.00 0.00 1.59 1.25 0.00 0.00 0.00 0.00 0.16 3.00 0.45 0.01 0.50 0.00 0.01 0.46 0.35 5.17 6.00 0.00 1.78 1.10 0.00 0.00 0.00 0.00 0.11 2.99 0.49 0.00 0.48 0.00 0.01 0.37 0.00 5.62 6.00 0.06 2.00 0.88 0.00 0.00 0.00 0.00 0.06 3.00 0.63 0.00 0.31 0.00 0.01 0.48 0.49 5.02 6.00 0.00 1.76 1.13 0.00 0.00 0.00 0.00 0.10 2.98 0.45 0.00 0.54 0.00 0.01 0.46 0.45 5.08 6.00 0.00 1.83 1.07 0.00 0.00 0.00 0.00 0.09 3.00 0.44 0.00 0.56 0.00 0.01 0.45 0.22 5.31 6.00 0.00 1.79 1.11 0.00 0.00 0.00 0.00 0.10 3.00 0.61 0.00 0.33 0.00 0.01 0.43 0.10 5.45 6.00 0.00 1.88 1.03 0.00 0.00 0.00 0.00 0.09 3.00 0.59 0.01 0.34 0.00 0.01 0.43 0.07 5.49 6.00 0.00 1.92 1.01 0.00 0.00 0.00 0.00 0.07 3.00 0.62 0.00 0.33 0.00 0.01 0.44 0.20 5.34 6.00 0.00 1.84 1.06 0.00 0.00 0.00 0.00 0.10 3.00 0.61 0.01 0.36 0.00 0.01 0.41 0.27 5.31 6.00 0.00 1.95 0.98 0.00 0.00 0.00 0.00 0.07 3.00 0.56 0.00 0.42 0.00 0.01 0.35 0.00 5.64 6.00 0.14 1.95 0.85 0.00 0.00 0.00 0.00 0.06 3.00 0.67 0.01 0.01 0.00 0.01 0.44 0.32 5.23 6.00 0.00 1.81 1.07 0.00 0.00 0.00 0.00 0.11 3.00 0.52 0.00 0.45 0.00 0.01 0.35 0.00 5.64 6.00 0.18 1.94 0.85 0.00 0.00 0.00 0.00 0.03 3.00 0.73 0.00 0.17 0.00 0.01 0.42 0.00 5.57 6.00 0.01 1.94 0.99 0.00 0.00 0.00 0.00 0.05 3.00 0.68 0.00 0.30 0.00 0.01 0.42 0.03 5.54 6.00 0.00 1.97 0.97 0.00 0.00 0.00 0.00 0.05 3.00 0.68 0.01 0.28 0.00 0.01 0.33 0.00 5.66 6.00 0.22 1.94 0.78 0.00 0.00 0.00 0.00 0.05 2.99 0.67 0.00 0.28 0.00 0.00 0.26 0.00 5.73 6.00 0.31 2.02 0.63 0.00 0.00 0.00 0.00 0.02 2.99 0.70 0.00 0.17 0.00 0.01 0.44 0.00 5.55 6.00 0.10 1.79 1.03 0.00 0.00 0.00 0.00 0.04 2.97 0.73 0.01 0.16 0.00 0.01 0.39 0.00 5.60 6.00 0.02 1.96 0.91 0.00 0.00 0.00 0.00 0.09 2.98 0.61 0.00 0.31 0.00 0.01 0.42 0.11 5.45 6.00 0.00 1.89 1.01 0.00 0.00 0.00 0.00 0.10 3.00 0.65 0.00 0.33 0.00 0.01 0.39 0.22 5.37 6.00 0.00 1.96 0.92 0.00 0.00 0.00 0.00 0.07 2.95 0.56 0.00 0.44 0.00 0.01 0.37 0.00 5.62 6.00 0.07 1.96 0.90 0.00 0.00 0.00 0.00 0.07 3.00 0.63 0.01 0.30 0.00 0.01 0.46 0.39 5.14 6.00 0.00 1.76 1.10 0.00 0.00 0.00 0.00 0.11 2.97 0.47 0.00 0.53 0.00 0.01 0.44 0.45 5.10 6.00 0.00 1.73 1.06 0.00 0.00 0.00 0.00 0.21 3.00 0.54 0.01 0.45 0.00 0.01 0.38 0.00 5.61 6.00 0.06 1.97 0.90 0.00 0.00 0.00 0.00 0.06 2.99 0.62 0.01 0.31 0.00 0.01 0.47 0.52 5.00 6.00 0.00 1.75 1.11 0.00 0.00 0.00 0.00 0.10 2.97 0.39 0.00 0.59 0.00 0.01 0.50 0.48 5.01 6.00 0.00 1.65 1.19 0.00 0.00 0.00 0.00 0.13 2.97 0.47 0.01 0.49 0.00 0.02 0.46 0.37 5.16 6.00 0.00 1.74 1.08 0.00 0.00 0.00 0.00 0.17 2.99 0.50 0.01 0.46 0.00 0.01 0.35 0.00 5.64 6.00 0.07 2.06 0.84 0.00 0.00 0.00 0.00 0.02 3.00 0.71 0.00 0.20 0.00 0.01 0.50 0.33 5.16 6.00 0.00 1.73 1.20 0.00 0.00 0.00 0.00 0.08 3.00 0.56 0.00 0.39 0.00 0.01 0.41 0.14 5.44 6.00 0.00 1.93 1.00 0.00 0.00 0.00 0.00 0.07 3.00 0.60 0.00 0.37 0.00 0.00 0.33 0.00 5.67 6.00 0.29 1.90 0.79 0.00 0.00 0.00 0.00 0.01 2.99 0.74 0.00 0.11 0.00 0.01 0.39 0.14 5.46 6.00 0.00 2.00 0.94 0.00 0.00 0.00 0.00 0.06 3.00 0.62 0.00 0.35 0.00 0.01 0.51 0.38 5.10 6.00 0.00 1.70 1.22 0.00 0.00 0.00 0.00 0.08 3.00 0.56 0.01 0.39 0.00 0.01 0.47 0.60 4.92 6.00 0.00 1.73 1.12 0.00 0.00 0.00 0.00 0.15 3.00 0.44 0.01 0.55 0.00 0.00 0.37 0.00 5.63 6.00 0.27 1.82 0.88 0.00 0.00 0.00 0.00 0.02 2.99 0.75 0.00 0.11 0.00 0.01 0.39 0.15 5.45 6.00 0.00 1.98 0.95 0.00 0.00 0.00 0.00 0.07 3.00 0.57 0.00 0.38 0.00 0.01 0.27 0.00 5.73 6.00 0.27 2.08 0.63 0.00 0.00 0.00 0.00 0.01 2.99 0.73 0.00 0.14 0.00 0.01 0.34 0.06 5.59 6.00 0.00 2.11 0.83 0.00 0.00 0.00 0.00 0.05 3.00 0.59 0.00 0.34 0.00 0.01 0.52 0.64 4.83 6.00 0.00 1.57 1.25 0.00 0.00 0.00 0.00 0.18 3.00 0.44 0.01 0.50 0.00 0.01 0.49 0.56 4.94 6.00 0.00 1.65 1.17 0.00 0.00 0.00 0.00 0.18 3.00 0.51 0.01 0.47 0.00 0.01 0.51 0.56 4.92 6.00 0.00 1.61 1.20 0.00 0.00 0.00 0.00 0.18 3.00 0.46 0.01 0.49 0.00 0.00 0.33 0.00 5.66 6.00 0.31 1.87 0.80 0.00 0.00 0.00 0.00 0.02 3.00 0.71 0.00 0.11 0.00 0.01 0.46 0.09 5.44 6.00 0.00 1.84 1.09 0.00 0.00 0.00 0.00 0.08 3.00 0.63 0.01 0.30 0.00 0.01 0.55 0.74 4.70 6.00 0.00 1.51 1.30 0.00 0.00 0.00 0.00 0.19 3.00 0.39 0.01 0.58 0.00 0.01 0.51 0.61 4.87 6.00 0.00 1.63 1.21 0.00 0.00 0.00 0.00 0.16 3.00 0.45 0.01 0.49 0.00 0.01 0.42 0.00 5.57 6.00 0.09 1.85 0.99 0.00 0.00 0.00 0.00 0.07 3.00 0.68 0.01 0.27 0.00 0.01 0.34 0.09 5.56 6.00 0.00 2.08 0.81 0.00 0.00 0.00 0.00 0.11 3.00 0.58 0.00 0.33 0.00 0.01 0.40 0.35 5.25 6.00 0.00 1.95 0.96 0.00 0.00 0.00 0.00 0.09 3.00 0.48 0.01 0.47 0.00 0.01 0.43 0.33 5.23 6.00 0.00 1.85 1.02 0.00 0.00 0.00 0.00 0.13 3.00 0.55 0.01 0.41 0.00 0.01 0.51 0.61 4.87 6.00 0.00 1.63 1.20 0.00 0.00 0.00 0.00 0.17 3.00 0.48 0.01 0.50 0.00 0.01 0.39 0.00 5.60 6.00 0.04 1.98 0.90 0.00 0.00 0.00 0.00 0.07 3.00 0.63 0.01 0.30 0.00 0.01 0.41 0.00 5.58 6.00 0.08 1.85 0.99 0.00 0.00 0.00 0.00 0.07 3.00 0.68 0.01 0.27 0.00 0.01 0.50 0.68 4.81 6.00 0.00 1.65 1.20 0.00 0.00 0.00 0.00 0.15 3.00 0.41 0.01 0.58 0.00 0.01 0.29 0.04 5.66 6.00 0.00 2.24 0.69 0.00 0.00 0.00 0.00 0.07 3.00 0.64 0.00 0.30 0.00 0.01 0.49 0.62 4.89 6.00 0.00 1.69 1.15 0.00 0.00 0.00 0.00 0.16 3.00 0.46 0.01 0.51 0.00 0.01 0.33 0.00 5.66 6.00 0.24 1.90 0.78 0.00 0.00 0.00 0.00 0.05 2.98 0.71 0.00 0.24 0.00 0.01 0.40 0.00 5.59 6.00 0.20 1.81 0.95 0.00 0.00 0.00 0.00 0.03 3.00 0.69 0.01 0.27 0.00 0.01 0.46 0.59 4.94 6.00 0.00 1.75 1.11 0.00 0.00 0.00 0.00 0.15 3.00 0.43 0.01 0.53 0.00 0.01 0.36 0.00 5.64 6.00 0.23 1.89 0.85 0.00 0.00 0.00 0.00 0.03 3.00 0.69 0.01 0.25 0.00 0.01 0.41 0.06 5.52 6.00 0.00 1.94 0.98 0.00 0.00 0.00 0.00 0.07 3.00 0.62 0.00 0.32 0.00 0.01 0.46 0.07 5.46 6.00 0.00 1.82 1.11 0.00 0.00 0.00 0.00 0.07 3.00 0.66 0.01 0.24 0.00 0.01 0.39 0.00 5.60 6.00 0.02 1.95 0.93 0.00 0.00 0.00 0.00 0.09 3.00 0.64 0.01 0.31 0.00 0.02 0.67 0.69 4.63 6.00 0.00 1.14 1.62 0.00 0.00 0.00 0.00 0.24 3.00 0.55 0.01 0.41 0.00 0.01 0.43 0.09 5.47 6.00 0.00 1.86 1.02 0.00 0.00 0.00 0.00 0.10 2.99 0.61 0.01 0.33 0.00 0.01 0.37 0.00 5.63 6.00 0.10 1.95 0.88 0.00 0.00 0.00 0.00 0.05 2.99 0.64 0.01 0.24 0.00 0.00 0.41 0.01 5.58 6.00 0.00 1.77 1.18 0.00 0.00 0.00 0.00 0.01 2.97 0.81 0.01 0.04 0.00 0.02 0.09 0.00 5.89 6.00 0.31 1.97 0.49 0.00 0.00 0.00 0.00 0.23 3.00 0.69 0.01 0.13 0.00 0.02 0.06 0.00 5.92 6.00 0.41 2.05 0.33 0.00 0.00 0.00 0.00 0.20 3.00 0.71 0.01 0.14 0.00 0.02 0.05 0.00 5.93 6.00 0.27 2.20 0.29 0.00 0.00 0.00 0.00 0.23 3.00 0.68 0.01 0.18 0.00 0.02 0.07 0.00 5.91 6.00 0.57 1.98 0.38 0.00 0.00 0.00 0.00 0.05 2.98 0.73 0.01 0.12 0.00 0.03 0.07 0.00 5.90 6.00 0.57 2.02 0.38 0.00 0.00 0.00 0.00 0.03 3.00 0.66 0.00 0.14 0.00 0.02 0.06 0.00 5.92 6.00 0.55 2.03 0.33 0.00 0.00 0.00 0.00 0.06 2.97 0.69 0.01 0.16 0.00 0.00 0.19 0.00 5.81 6.00 0.12 1.75 1.05 0.00 0.00 0.00 0.00 0.01 2.92 0.77 0.01 0.07 0.00 0.00 0.52 0.12 5.35 6.00 0.00 1.53 1.41 0.00 0.00 0.00 0.00 0.02 2.95 0.91 0.01 0.03 0.00 0.00 0.47 0.00 5.53 6.00 0.05 1.79 1.14 0.00 0.00 0.00 0.00 0.01 3.00 0.82 0.01 0.05 0.00 0.02 0.09 0.00 5.89 6.00 0.31 1.99 0.47 0.00 0.00 0.00 0.00 0.22 2.99 0.72 0.02 0.13 0.00 0.03 0.02 0.00 5.95 6.00 0.29 2.34 0.11 0.00 0.00 0.00 0.00 0.26 3.00 0.70 0.02 0.18 0.00 0.01 0.05 0.00 5.94 6.00 0.39 2.24 0.26 0.00 0.00 0.00 0.00 0.09 2.98 0.70 0.02 0.18 0.00 0.02 0.04 0.00 5.93 6.00 0.28 2.23 0.25 0.00 0.00 0.00 0.00 0.24 3.00 0.72 0.02 0.17 0.00 0.03 0.03 0.00 5.94 6.00 0.27 2.33 0.16 0.00 0.00 0.00 0.00 0.25 3.01 0.70 0.02 0.18 0.00 0.01 0.22 0.02 5.75 6.00 0.00 1.57 1.21 0.00 0.00 0.00 0.00 0.15 2.93 0.75 0.01 0.13 0.00 0.01 0.05 0.00 5.94 6.00 0.55 2.06 0.26 0.00 0.00 0.00 0.00 0.13 3.00 0.66 0.01 0.16 0.00 0.01 0.13 0.00 5.87 6.00 0.62 1.57 0.69 0.00 0.00 0.00 0.00 0.12 3.00 0.69 0.01 0.12 0.00 0.00 0.23 0.00 5.76 6.00 0.32 1.33 1.30 0.00 0.00 0.00 0.00 0.01 2.97 0.73 0.00 0.01 0.00 0.00 0.22 0.00 5.78 6.00 0.38 1.39 1.20 0.00 0.00 0.00 0.00 0.02 2.98 0.64 0.00 0.04 0.00 0.01 0.03 0.00 5.97 6.00 0.70 2.04 0.14 0.00 0.00 0.00 0.00 0.13 3.00 0.66 0.00 0.22 0.00 0.00 0.24 0.00 5.75 6.00 0.02 1.59 1.33 0.00 0.00 0.00 0.00 0.02 2.97 0.82 0.01 0.04 0.00 0.02 0.09 0.00 5.89 6.00 0.46 1.83 0.46 0.00 0.00 0.00 0.00 0.17 2.92 0.68 0.01 0.14 0.00 0.00 0.42 0.04 5.53 6.00 0.00 1.55 1.40 0.00 0.00 0.00 0.00 0.02 2.97 0.84 0.01 0.04 0.00 0.00 0.52 0.53 4.95 6.00 0.00 1.54 0.95 0.00 0.00 0.00 0.00 0.38 2.87 0.85 0.01 0.11 0.01 0.00 0.41 0.49 5.09 6.00 0.00 1.80 0.74 0.00 0.00 0.00 0.00 0.38 2.92 0.82 0.01 0.15 0.00 0.00 0.48 0.49 5.02 6.00 0.00 1.61 0.89 0.00 0.00 0.00 0.00 0.36 2.86 0.83 0.01 0.11 0.00 0.00 0.48 0.50 5.02 6.00 0.00 1.63 0.88 0.00 0.00 0.00 0.00 0.39 2.89 0.79 0.01 0.13 0.02 0.00 0.41 0.46 5.11 6.00 0.00 1.84 0.75 0.00 0.00 0.00 0.00 0.38 2.96 0.79 0.01 0.15 0.00 0.00 0.39 0.44 5.17 6.00 0.00 1.88 0.71 0.00 0.00 0.00 0.00 0.32 2.91 0.80 0.01 0.17 0.00 0.00 0.40 0.48 5.12 6.00 0.00 1.85 0.71 0.00 0.00 0.00 0.00 0.36 2.92 0.78 0.01 0.16 0.00 0.00 0.39 0.26 5.35 6.00 0.00 1.92 0.70 0.00 0.00 0.00 0.00 0.31 2.93 0.80 0.01 0.11 0.00 0.00 0.38 0.25 5.36 6.00 0.00 1.94 0.69 0.00 0.00 0.00 0.00 0.28 2.91 0.83 0.01 0.12 0.00 0.00 0.38 0.35 5.26 6.00 0.00 1.90 0.69 0.00 0.00 0.00 0.00 0.31 2.91 0.79 0.01 0.14 0.00 0.02 0.15 0.00 5.82 6.00 0.19 1.97 0.69 0.00 0.01 0.00 0.00 0.06 2.92 0.72 0.00 0.16 0.00 0.04 0.17 0.13 5.66 6.00 0.00 2.05 0.75 0.00 0.00 0.00 0.00 0.13 2.93 0.56 0.00 0.33 0.00 0.03 0.19 0.26 5.52 6.00 0.00 1.93 0.82 0.00 0.00 0.00 0.00 0.17 2.92 0.62 0.00 0.30 0.00 0.03 0.16 0.00 5.82 6.00 0.13 2.08 0.69 0.00 0.01 0.00 0.00 0.04 2.95 0.69 0.00 0.12 0.00 0.02 0.21 0.25 5.52 6.00 0.00 1.92 0.91 0.00 0.00 0.00 0.00 0.13 2.95 0.62 0.00 0.29 0.00 0.03 0.15 0.00 5.82 6.00 0.20 2.06 0.65 0.00 0.02 0.00 0.00 0.05 2.98 0.72 0.00 0.17 0.00 0.01 0.16 0.00 5.83 6.00 0.03 2.12 0.72 0.00 0.00 0.00 0.00 0.02 2.89 0.70 0.00 0.11 0.00 0.01 0.15 0.00 5.83 6.00 0.17 2.08 0.67 0.00 0.00 0.00 0.00 0.02 2.95 0.74 0.00 0.10 0.00 0.02 0.18 0.00 5.81 6.00 0.04 2.02 0.76 0.00 0.00 0.00 0.00 0.05 2.87 0.70 0.01 0.12 0.00 0.01 0.14 0.00 5.85 6.00 0.13 2.09 0.60 0.00 0.00 0.00 0.00 0.04 2.86 0.67 0.00 0.13 0.00 0.01 0.15 0.00 5.84 6.00 0.12 2.08 0.64 0.00 0.00 0.00 0.00 0.02 2.86 0.73 0.00 0.12 0.00 0.01 0.18 0.00 5.82 6.00 0.00 2.09 0.77 0.00 0.00 0.00 0.00 0.02 2.88 0.74 0.00 0.09 0.00 0.01 0.21 0.02 5.77 6.00 0.00 1.95 0.90 0.00 0.00 0.00 0.00 0.05 2.90 0.75 0.01 0.16 0.00 0.01 0.19 0.07 5.73 6.00 0.00 2.03 0.87 0.00 0.00 0.00 0.00 0.02 2.92 0.72 0.01 0.11 0.00 0.04 0.16 0.00 5.80 6.00 0.19 1.96 0.72 0.00 0.00 0.00 0.00 0.02 2.89 0.72 0.00 0.04 0.00 0.01 0.21 0.17 5.61 6.00 0.00 1.91 0.94 0.00 0.00 0.00 0.00 0.05 2.90 0.72 0.00 0.22 0.00 0.03 0.17 0.00 5.80 6.00 0.03 2.10 0.72 0.00 0.01 0.00 0.00 0.03 2.89 0.72 0.00 0.12 0.00 0.02 0.16 0.00 5.82 6.00 0.05 2.08 0.69 0.00 0.00 0.00 0.00 0.06 2.90 0.65 0.00 0.17 0.00 0.02 0.13 0.00 5.86 6.00 0.13 2.12 0.54 0.00 0.00 0.00 0.00 0.04 2.84 0.72 0.00 0.16 0.00 0.01 0.16 0.00 5.83 6.00 0.23 2.00 0.67 0.00 0.00 0.00 0.00 0.05 2.95 0.73 0.00 0.16 0.00 0.02 0.15 0.00 5.83 6.00 0.23 2.00 0.65 0.00 0.01 0.00 0.00 0.02 2.91 0.73 0.00 0.16 0.00 0.00 0.16 0.00 5.84 6.00 0.97 0.78 1.23 0.00 0.00 0.00 0.00 0.02 3.00 0.33 0.00 0.00 0.00 0.00 0.16 0.00 5.84 6.00 1.02 0.75 1.21 0.00 0.00 0.00 0.00 0.02 3.00 0.29 0.01 0.00 0.00 0.00 0.16 0.00 5.84 6.00 1.03 0.76 1.20 0.00 0.00 0.00 0.00 0.02 3.00 0.27 0.00 0.00 0.00 0.00 0.37 0.00 5.63 6.00 1.30 0.74 0.94 0.00 0.00 0.00 0.00 0.02 3.00 0.27 0.00 0.00 0.00 0.00 0.37 0.00 5.62 6.00 1.31 0.74 0.94 0.00 0.00 0.00 0.00 0.01 3.00 0.27 0.00 0.00 0.00 0.00 0.08 0.00 5.92 6.00 0.82 1.85 0.20 0.00 0.00 0.00 0.00 0.00 2.88 0.33 0.00 0.01 0.00 0.00 0.22 0.00 5.78 6.00 0.70 1.68 0.54 0.00 0.00 0.00 0.00 0.00 2.92 0.38 0.00 0.02 0.00 0.00 0.20 0.00 5.80 6.00 0.92 1.50 0.49 0.00 0.00 0.00 0.00 0.00 2.91 0.35 0.00 0.01 0.00 0.00 0.10 0.00 5.90 6.00 0.75 1.89 0.26 0.00 0.00 0.00 0.00 0.00 2.91 0.43 0.00 0.02 0.00 0.00 0.42 0.00 5.58 6.00 1.20 0.74 1.05 0.00 0.00 0.00 0.00 0.01 3.00 0.37 0.00 0.00 0.00 0.00 0.10 0.00 5.90 6.00 0.79 1.87 0.26 0.00 0.00 0.00 0.00 0.00 2.92 0.35 0.00 0.01 0.00 0.00 0.40 0.00 5.60 6.00 1.28 0.70 1.01 0.00 0.00 0.00 0.00 0.01 3.00 0.24 0.00 0.00 0.00 0.00 0.40 0.00 5.59 6.00 1.27 0.71 1.00 0.00 0.00 0.00 0.00 0.02 3.00 0.27 0.01 0.00 0.00 0.00 0.10 0.00 5.90 6.00 0.71 1.97 0.24 0.00 0.00 0.00 0.00 0.00 2.92 0.28 0.00 0.00 0.00 0.00 0.02 0.00 5.98 6.00 0.97 1.86 0.06 0.00 0.00 0.00 0.00 0.00 2.89 0.12 0.00 0.01 0.00 0.00 0.41 0.00 5.59 6.00 1.30 0.70 1.00 0.00 0.00 0.00 0.00 0.01 3.00 0.28 0.00 0.00 0.00 0.00 0.40 0.00 5.60 6.00 1.32 0.67 0.99 0.00 0.00 0.00 0.00 0.01 3.00 0.27 0.00 0.00 0.00 0.00 0.43 0.00 5.57 6.00 1.31 0.63 1.05 0.00 0.00 0.00 0.00 0.01 3.00 0.28 0.00 0.00 0.00 0.03 0.29 0.00 5.67 6.00 0.05 2.01 0.76 0.00 0.00 0.00 0.00 0.14 2.96 0.87 0.01 0.04 0.00 0.04 0.38 0.16 5.41 6.00 0.00 1.77 0.99 0.00 0.01 0.00 0.00 0.22 2.99 0.69 0.01 0.20 0.00 0.03 0.29 0.00 5.67 6.00 0.05 2.03 0.76 0.00 0.00 0.00 0.00 0.15 2.99 0.86 0.01 0.03 0.00 0.03 0.30 0.00 5.67 6.00 0.32 1.84 0.80 0.00 0.01 0.00 0.00 0.04 3.01 0.73 0.01 0.16 0.00 0.02 0.36 0.00 5.61 6.00 0.12 1.88 0.93 0.00 0.00 0.00 0.00 0.01 2.95 0.81 0.00 0.08 0.00 0.03 0.29 0.00 5.67 6.00 0.08 2.00 0.76 0.00 0.00 0.00 0.00 0.14 2.98 0.89 0.01 0.03 0.00 0.05 0.45 0.16 5.34 6.00 0.00 1.74 1.17 0.00 0.00 0.00 0.00 0.07 2.98 0.67 0.01 0.26 0.00 0.03 0.36 0.00 5.61 6.00 0.16 1.85 0.93 0.00 0.00 0.00 0.00 0.05 2.99 0.73 0.01 0.19 0.00 0.05 0.43 0.09 5.43 6.00 0.00 1.79 1.12 0.00 0.00 0.00 0.00 0.05 2.97 0.70 0.01 0.25 0.00 0.04 0.29 0.00 5.67 6.00 0.07 2.00 0.75 0.00 0.00 0.00 0.00 0.14 2.97 0.90 0.01 0.03 0.00 0.03 0.46 0.03 5.48 6.00 0.00 1.77 1.19 0.00 0.00 0.00 0.00 0.01 2.98 0.84 0.00 0.10 0.00 0.03 0.29 0.00 5.67 6.00 0.07 2.01 0.76 0.00 0.00 0.00 0.00 0.15 2.98 0.89 0.01 0.03 0.00 0.02 0.29 0.00 5.69 6.00 0.40 1.79 0.74 0.00 0.01 0.00 0.00 0.03 2.97 0.68 0.00 0.13 0.00 0.04 0.41 0.07 5.47 6.00 0.00 1.78 1.08 0.00 0.01 0.00 0.00 0.09 2.96 0.71 0.01 0.23 0.00 0.03 0.28 0.00 5.68 6.00 0.15 1.99 0.73 0.00 0.00 0.00 0.00 0.13 3.00 0.86 0.01 0.03 0.00 0.02 0.72 0.46 4.79 6.00 0.00 1.28 1.65 0.00 0.00 0.00 0.00 0.07 3.00 0.69 0.01 0.28 0.00 0.04 0.30 0.00 5.65 6.00 0.01 2.03 0.80 0.00 0.00 0.00 0.00 0.16 3.00 0.90 0.01 0.04 0.00 0.03 0.29 0.00 5.68 6.00 0.36 1.82 0.75 0.00 0.01 0.00 0.00 0.07 3.01 0.76 0.01 0.15 0.00 0.03 0.31 0.00 5.65 6.00 0.34 1.74 0.83 0.00 0.02 0.00 0.00 0.07 3.01 0.72 0.01 0.14 0.00 0.03 0.27 0.00 5.69 6.00 0.09 2.03 0.72 0.00 0.00 0.00 0.00 0.14 2.98 0.87 0.01 0.03 0.00 0.03 0.29 0.00 5.67 6.00 0.04 2.02 0.76 0.00 0.00 0.00 0.00 0.14 2.97 0.88 0.01 0.03 0.00 0.05 0.45 0.05 5.45 6.00 0.00 1.75 1.18 0.00 0.01 0.00 0.00 0.06 3.00 0.69 0.01 0.23 0.00 0.03 0.29 0.00 5.67 6.00 0.08 2.02 0.76 0.00 0.00 0.00 0.00 0.15 3.00 0.88 0.01 0.03 0.00 0.02 0.52 0.00 5.46 6.00 0.00 1.60 1.34 0.00 0.00 0.00 0.00 0.01 2.96 0.89 0.01 0.07 0.00 0.03 0.40 0.00 5.57 6.00 0.09 1.82 1.06 0.00 0.00 0.00 0.00 0.01 2.97 0.86 0.00 0.07 0.00 0.04 0.56 0.33 5.07 6.00 0.00 1.49 1.46 0.00 0.00 0.00 0.00 0.05 3.00 0.76 0.01 0.20 0.00 0.03 0.30 0.00 5.67 6.00 0.07 2.00 0.78 0.00 0.00 0.00 0.00 0.14 3.00 0.85 0.01 0.04 0.00 0.04 0.47 0.22 5.27 6.00 0.00 1.70 1.22 0.00 0.00 0.00 0.00 0.05 2.97 0.76 0.00 0.20 0.00 0.03 0.28 0.00 5.68 6.00 0.08 2.01 0.73 0.00 0.00 0.00 0.00 0.14 2.96 0.88 0.01 0.03 0.00 0.05 0.45 0.09 5.41 6.00 0.00 1.76 1.18 0.00 0.00 0.00 0.00 0.04 2.99 0.68 0.01 0.25 0.00 0.02 0.26 0.00 5.72 6.00 0.42 1.85 0.68 0.00 0.02 0.00 0.00 0.02 2.98 0.71 0.01 0.08 0.00 0.04 0.37 0.00 5.59 6.00 0.13 1.84 0.96 0.00 0.00 0.00 0.00 0.06 2.99 0.67 0.00 0.22 0.01 0.03 0.28 0.00 5.68 6.00 0.09 1.99 0.73 0.00 0.00 0.00 0.00 0.14 2.96 0.88 0.01 0.02 0.00 0.04 0.34 0.00 5.62 6.00 0.15 1.90 0.89 0.00 0.00 0.00 0.00 0.02 2.97 0.70 0.01 0.19 0.00 0.02 0.25 0.00 5.73 6.00 0.33 1.97 0.65 0.00 0.01 0.00 0.00 0.02 2.98 0.72 0.00 0.11 0.00 0.03 0.33 0.00 5.64 6.00 0.17 1.85 0.87 0.00 0.01 0.00 0.00 0.03 2.92 0.73 0.00 0.18 0.01 0.03 0.29 0.00 5.67 6.00 0.12 1.99 0.75 0.00 0.00 0.00 0.00 0.14 3.00 0.86 0.01 0.03 0.00 0.01 0.32 0.00 5.67 6.00 0.25 1.91 0.84 0.00 0.00 0.00 0.00 0.00 3.00 0.86 0.00 0.06 0.00 0.02 0.97 0.11 4.90 6.00 0.00 1.42 1.31 0.00 0.00 0.00 0.00 0.25 2.99 0.47 0.01 0.48 0.00 0.01 0.83 0.00 5.15 6.00 0.05 1.63 1.12 0.00 0.00 0.00 0.00 0.14 2.94 0.68 0.01 0.25 0.00 0.00 0.95 0.00 5.04 6.00 0.70 0.99 1.28 0.00 0.00 0.00 0.00 0.01 2.97 0.64 0.01 0.15 0.00 0.00 0.89 0.00 5.11 6.00 0.65 1.08 1.22 0.00 0.00 0.00 0.00 0.00 2.96 0.70 0.01 0.10 0.00 0.02 0.96 0.19 4.83 6.00 0.00 1.39 1.32 0.00 0.00 0.00 0.00 0.27 2.99 0.44 0.01 0.51 0.00 0.02 0.96 0.20 4.81 6.00 0.00 1.38 1.32 0.00 0.00 0.00 0.00 0.28 2.98 0.45 0.01 0.51 0.00 0.01 0.98 0.03 4.97 6.00 0.00 1.45 1.30 0.00 0.00 0.00 0.00 0.24 2.99 0.49 0.01 0.46 0.00 0.01 0.76 0.00 5.23 6.00 0.38 1.49 1.03 0.00 0.00 0.00 0.00 0.05 2.95 0.71 0.01 0.18 0.00 0.02 1.03 0.24 4.72 6.00 0.00 1.32 1.38 0.00 0.00 0.00 0.00 0.29 2.99 0.43 0.01 0.54 0.00 0.02 1.00 0.18 4.79 6.00 0.00 1.38 1.34 0.00 0.00 0.00 0.00 0.27 2.98 0.44 0.02 0.53 0.00 0.00 0.94 0.00 5.05 6.00 0.35 1.24 1.29 0.00 0.00 0.00 0.00 0.07 2.94 0.61 0.01 0.28 0.00 0.00 0.77 0.00 5.23 6.00 0.72 1.15 1.03 0.00 0.00 0.00 0.00 0.02 2.92 0.73 0.00 0.11 0.00 0.00 0.74 0.00 5.26 6.00 0.52 1.38 0.98 0.00 0.00 0.00 0.00 0.04 2.92 0.75 0.01 0.14 0.00 0.01 0.95 0.00 5.04 6.00 0.13 1.38 1.30 0.00 0.00 0.00 0.00 0.16 2.96 0.63 0.01 0.30 0.00 0.01 0.78 0.00 5.21 6.00 0.33 1.48 1.05 0.00 0.00 0.00 0.00 0.10 2.96 0.69 0.01 0.22 0.00 0.01 1.00 0.09 4.90 6.00 0.00 1.42 1.34 0.00 0.00 0.00 0.00 0.20 2.96 0.61 0.01 0.33 0.00 0.00 0.81 0.00 5.19 6.00 0.78 1.06 1.11 0.00 0.00 0.00 0.00 0.01 2.96 0.74 0.00 0.10 0.00 0.00 0.97 0.00 5.03 6.00 0.48 1.17 1.30 0.00 0.00 0.00 0.00 0.04 3.00 0.64 0.01 0.28 0.00 0.01 1.00 0.00 4.99 6.00 0.08 1.37 1.36 0.00 0.00 0.00 0.00 0.19 3.00 0.57 0.01 0.36 0.00 0.02 1.01 0.25 4.72 6.00 0.00 1.34 1.34 0.00 0.00 0.00 0.00 0.30 2.99 0.45 0.01 0.50 0.00 0.00 0.27 0.00 5.72 6.00 0.66 0.23 2.08 0.00 0.00 0.00 0.00 0.00 2.98 0.56 0.00 0.03 0.00 0.00 0.25 0.00 5.75 6.00 0.57 0.36 2.02 0.00 0.00 0.00 0.00 0.00 2.95 0.59 0.00 0.05 0.00 0.02 0.27 1.02 4.69 6.00 0.00 0.59 2.11 0.00 0.00 0.00 0.00 0.29 2.99 0.42 0.02 0.52 0.00 0.02 0.26 0.98 4.73 6.00 0.00 0.65 2.05 0.00 0.00 0.00 0.00 0.26 2.97 0.43 0.01 0.50 0.00 0.02 0.26 1.12 4.59 6.00 0.00 0.58 2.08 0.00 0.00 0.00 0.00 0.28 2.94 0.42 0.02 0.54 0.00 0.02 0.27 0.98 4.73 6.00 0.00 0.64 2.05 0.00 0.00 0.00 0.00 0.26 2.96 0.46 0.01 0.51 0.00 0.00 0.29 0.00 5.71 6.00 0.33 0.38 2.23 0.00 0.00 0.00 0.00 0.00 2.94 0.67 0.02 0.07 0.00 0.00 1.13 0.15 4.73 6.00 0.00 1.50 1.28 0.00 0.00 0.00 0.00 0.20 2.99 0.41 0.01 0.55 0.00 0.00 0.81 0.00 5.19 6.00 0.41 1.59 0.93 0.00 0.00 0.00 0.00 0.01 2.93 0.73 0.02 0.16 0.00 0.00 1.08 0.18 4.74 6.00 0.00 1.53 1.24 0.00 0.00 0.00 0.00 0.23 2.99 0.44 0.01 0.52 0.00 0.00 0.79 0.03 5.18 6.00 0.00 1.96 0.90 0.00 0.00 0.00 0.00 0.06 2.93 0.54 0.01 0.43 0.00 0.00 1.05 0.08 4.87 6.00 0.00 1.58 1.18 0.00 0.00 0.00 0.00 0.23 2.99 0.46 0.01 0.49 0.00 0.00 0.67 0.00 5.33 6.00 0.59 1.60 0.76 0.00 0.00 0.00 0.00 0.01 2.96 0.73 0.01 0.13 0.00 0.00 1.04 0.07 4.89 6.00 0.00 1.62 1.18 0.00 0.00 0.00 0.00 0.17 2.96 0.44 0.02 0.54 0.00 0.00 1.17 0.29 4.54 6.00 0.00 1.38 1.35 0.00 0.00 0.00 0.00 0.27 2.99 0.39 0.01 0.58 0.00 0.00 1.12 0.26 4.62 6.00 0.00 1.41 1.27 0.00 0.00 0.00 0.00 0.30 2.98 0.40 0.01 0.58 0.00 0.00 1.22 0.24 4.54 6.00 0.00 1.47 1.38 0.00 0.00 0.00 0.00 0.11 2.97 0.69 0.01 0.26 0.00 0.00 1.07 0.01 4.92 6.00 0.00 1.71 1.21 0.00 0.00 0.00 0.00 0.04 2.96 0.76 0.01 0.19 0.00 0.00 0.69 0.00 5.31 6.00 0.42 1.73 0.79 0.00 0.00 0.00 0.00 0.00 2.94 0.85 0.00 0.05 0.00 0.00 0.69 0.00 5.31 6.00 0.36 1.79 0.78 0.00 0.00 0.00 0.00 0.01 2.94 0.83 0.01 0.06 0.00 0.00 0.59 0.00 5.41 6.00 0.46 1.81 0.67 0.00 0.00 0.00 0.00 0.00 2.94 0.83 0.01 0.09 0.00 0.00 1.25 0.01 4.74 6.00 0.00 1.51 1.41 0.00 0.00 0.00 0.00 0.04 2.96 0.83 0.01 0.11 0.00 0.00 1.02 0.00 4.98 6.00 0.18 1.59 1.16 0.00 0.00 0.00 0.00 0.04 2.97 0.81 0.01 0.12 0.00 0.00 0.84 0.03 5.13 6.00 0.00 1.95 0.95 0.00 0.00 0.00 0.00 0.06 2.96 0.55 0.01 0.41 0.00 0.00 1.06 0.00 4.94 6.00 0.60 1.13 1.21 0.00 0.00 0.00 0.00 0.00 2.95 0.85 0.01 0.08 0.00 0.00 1.20 0.28 4.53 6.00 0.00 1.34 1.36 0.00 0.00 0.00 0.00 0.28 2.97 0.39 0.01 0.58 0.00 0.00 0.89 0.54 4.57 6.00 0.00 1.52 1.11 0.00 0.00 0.00 0.00 0.34 2.97 0.29 0.01 0.68 0.00 0.00 0.86 0.12 5.02 6.00 0.00 1.78 1.06 0.00 0.00 0.00 0.00 0.07 2.91 0.56 0.01 0.40 0.00 0.00 0.92 0.03 5.05 6.00 0.00 1.68 1.13 0.00 0.00 0.00 0.00 0.09 2.90 0.61 0.01 0.35 0.00 0.00 0.89 0.44 4.67 6.00 0.00 1.59 1.10 0.00 0.00 0.00 0.00 0.31 2.99 0.28 0.01 0.68 0.00 0.00 0.86 0.06 5.07 6.00 0.00 1.77 1.07 0.00 0.00 0.00 0.00 0.07 2.92 0.53 0.00 0.39 0.00 0.00 0.85 0.37 4.78 6.00 0.00 1.66 1.05 0.00 0.00 0.00 0.00 0.28 2.99 0.34 0.01 0.62 0.00 0.00 0.82 0.16 5.02 6.00 0.00 1.79 1.01 0.00 0.00 0.00 0.00 0.19 2.99 0.39 0.01 0.59 0.00 0.00 0.79 0.19 5.01 6.00 0.00 1.76 0.97 0.00 0.00 0.00 0.00 0.25 2.98 0.41 0.01 0.55 0.00 0.00 1.24 0.18 4.58 6.00 0.00 1.37 1.52 0.00 0.00 0.00 0.00 0.08 2.98 0.66 0.01 0.33 0.00 0.00 0.99 0.05 4.96 6.00 0.00 1.67 1.22 0.00 0.00 0.00 0.00 0.08 2.97 0.59 0.01 0.37 0.00 0.00 0.88 0.03 5.09 6.00 0.00 1.79 1.09 0.00 0.00 0.00 0.00 0.06 2.93 0.55 0.01 0.39 0.00 0.00 0.86 0.39 4.75 6.00 0.00 1.63 1.06 0.00 0.00 0.00 0.00 0.30 2.99 0.29 0.01 0.68 0.00 0.00 1.68 0.00 4.32 6.00 1.21 0.67 1.09 0.00 0.00 0.00 0.00 0.02 2.99 0.56 0.00 0.30 0.00 0.00 1.57 0.00 4.43 6.00 1.37 0.58 1.02 0.00 0.00 0.00 0.01 0.01 2.99 0.59 0.01 0.24 0.00 0.00 1.38 0.00 4.62 6.00 1.49 0.61 0.89 0.00 0.00 0.00 0.00 0.00 2.99 0.67 0.00 0.14 0.00 0.00 1.36 0.00 4.64 6.00 1.43 0.67 0.89 0.00 0.00 0.00 0.00 0.01 2.99 0.63 0.00 0.14 0.00 0.00 1.41 0.00 4.59 6.00 1.61 0.45 0.91 0.00 0.00 0.00 0.01 0.01 2.98 0.67 0.01 0.11 0.00 0.00 1.47 0.00 4.53 6.00 1.54 0.49 0.96 0.00 0.00 0.00 0.00 0.00 2.99 0.72 0.01 0.13 0.00 0.00 1.64 0.00 4.36 6.00 1.34 0.56 1.08 0.00 0.00 0.00 0.00 0.01 2.99 0.56 0.01 0.26 0.00 0.00 2.17 0.00 3.83 6.00 1.16 0.40 1.42 0.00 0.00 0.00 0.00 0.00 2.98 0.68 0.01 0.20 0.00 0.00 1.65 0.00 4.35 6.00 1.43 0.46 1.08 0.00 0.00 0.00 0.00 0.01 2.98 0.69 0.00 0.13 0.00 0.00 1.72 0.00 4.28 6.00 1.16 0.68 1.12 0.00 0.00 0.00 0.00 0.02 2.99 0.60 0.01 0.31 0.00 0.01 1.37 0.00 4.63 6.00 1.13 0.95 0.89 0.00 0.00 0.00 0.00 0.02 2.99 0.60 0.01 0.27 0.00 0.00 1.50 0.00 4.50 6.00 1.38 0.63 0.98 0.00 0.00 0.00 0.00 0.00 3.00 0.67 0.01 0.16 0.00 0.00 1.86 0.00 4.14 6.00 1.58 0.18 1.21 0.00 0.00 0.00 0.01 0.01 2.99 0.62 0.01 0.28 0.00 0.01 1.67 0.00 4.32 6.00 0.74 1.14 1.08 0.00 0.00 0.00 0.00 0.02 2.98 0.49 0.01 0.46 0.00 0.01 1.37 0.00 4.62 6.00 0.96 1.12 0.89 0.00 0.00 0.00 0.00 0.01 2.99 0.57 0.00 0.33 0.00 0.01 1.57 0.00 4.43 6.00 0.76 1.17 1.03 0.00 0.00 0.00 0.00 0.02 2.99 0.48 0.00 0.46 0.00 0.02 1.61 0.00 4.37 6.00 0.75 1.13 1.06 0.00 0.00 0.00 0.00 0.06 2.99 0.50 0.01 0.42 0.00 0.01 1.27 0.00 4.72 6.00 0.98 1.18 0.82 0.00 0.00 0.00 0.00 0.01 2.99 0.66 0.00 0.24 0.00 0.01 1.68 0.00 4.31 6.00 0.94 0.77 1.11 0.00 0.00 0.00 0.00 0.15 2.98 0.58 0.01 0.33 0.00 0.00 1.87 0.00 4.13 6.00 1.16 0.58 1.21 0.00 0.00 0.00 0.00 0.00 2.95 0.63 0.04 0.20 0.00 0.00 2.11 0.00 3.89 6.00 0.98 0.63 1.35 0.00 0.00 0.00 0.00 0.03 2.99 0.72 0.01 0.24 0.00 0.00 1.77 0.00 4.23 6.00 1.34 0.49 1.14 0.00 0.00 0.00 0.00 0.00 2.99 0.66 0.01 0.22 0.00 0.00 2.07 0.00 3.93 6.00 0.88 0.68 1.35 0.00 0.00 0.01 0.00 0.02 2.94 0.71 0.02 0.24 0.00 0.02 1.88 0.00 4.10 6.00 0.78 0.67 1.23 0.00 0.00 0.00 0.00 0.30 2.98 0.69 0.01 0.23 0.00 0.00 1.95 0.00 4.05 6.00 1.27 0.44 1.26 0.00 0.00 0.00 0.00 0.00 2.99 0.66 0.00 0.24 0.00 0.01 1.45 0.00 4.54 6.00 0.89 1.13 0.93 0.00 0.00 0.00 0.00 0.01 2.96 0.66 0.01 0.27 0.00 0.02 1.68 0.00 4.30 6.00 0.73 1.10 1.10 0.00 0.00 0.00 0.00 0.05 2.99 0.46 0.01 0.46 0.00 0.01 1.67 0.00 4.31 6.00 0.72 1.12 1.09 0.00 0.00 0.00 0.00 0.03 2.97 0.51 0.01 0.45 0.00 0.00 1.68 0.00 4.31 6.00 1.04 0.83 1.08 0.00 0.00 0.00 0.00 0.03 2.98 0.56 0.01 0.36 0.00 0.00 1.79 0.00 4.21 6.00 1.62 0.19 1.15 0.00 0.00 0.01 0.01 0.01 2.98 0.66 0.01 0.15 0.00 0.02 1.40 0.00 4.58 6.00 0.53 1.30 0.90 0.00 0.00 0.00 0.00 0.25 2.99 0.67 0.00 0.31 0.00 0.03 1.35 0.00 4.62 6.00 0.27 1.35 0.89 0.00 0.00 0.00 0.00 0.48 2.99 0.67 0.01 0.26 0.00 0.04 1.55 0.00 4.41 6.00 0.03 1.41 1.02 0.00 0.00 0.00 0.00 0.53 2.99 0.63 0.01 0.35 0.00 0.03 1.41 0.00 4.57 6.00 0.26 1.47 0.92 0.00 0.00 0.00 0.00 0.32 2.98 0.62 0.01 0.34 0.00 0.03 1.48 0.00 4.49 6.00 0.23 1.36 0.96 0.00 0.00 0.00 0.00 0.40 2.95 0.63 0.01 0.32 0.00 0.03 1.50 0.00 4.46 6.00 0.07 1.41 0.97 0.00 0.00 0.00 0.00 0.54 3.00 0.66 0.01 0.33 0.00 0.03 1.60 0.00 4.37 6.00 0.12 1.33 1.04 0.00 0.00 0.00 0.00 0.49 2.98 0.62 0.01 0.35 0.00 0.03 1.45 0.00 4.52 6.00 0.14 1.41 0.93 0.00 0.00 0.00 0.00 0.50 2.98 0.60 0.01 0.36 0.00 0.03 1.46 0.00 4.51 6.00 0.04 1.49 0.94 0.00 0.00 0.00 0.00 0.50 2.96 0.60 0.01 0.37 0.00 0.02 1.45 0.00 4.53 6.00 0.63 1.09 0.96 0.00 0.00 0.00 0.00 0.31 3.00 0.71 0.01 0.23 0.00 0.01 1.14 0.00 4.84 6.00 0.84 1.30 0.73 0.00 0.00 0.00 0.00 0.09 2.97 0.76 0.00 0.15 0.00 0.03 1.35 0.00 4.62 6.00 0.34 1.30 0.87 0.00 0.00 0.00 0.00 0.45 2.97 0.66 0.01 0.25 0.00 0.01 1.26 0.00 4.73 6.00 0.85 1.18 0.82 0.00 0.00 0.00 0.00 0.13 2.98 0.74 0.00 0.17 0.00 0.04 0.27 0.00 5.69 6.00 0.26 1.86 0.81 0.00 0.01 0.00 0.00 0.02 2.97 0.74 0.00 0.17 0.00 0.04 0.24 0.00 5.72 6.00 0.40 1.77 0.73 0.00 0.00 0.00 0.00 0.01 2.91 0.72 0.00 0.05 0.00 0.03 0.22 0.00 5.75 6.00 0.23 2.00 0.66 0.00 0.01 0.00 0.00 0.01 2.91 0.69 0.00 0.11 0.00 0.04 0.38 0.23 5.34 6.00 0.00 1.62 1.20 0.00 0.01 0.00 0.00 0.16 2.99 0.67 0.01 0.25 0.00 0.05 0.28 0.00 5.67 6.00 0.26 1.79 0.87 0.00 0.01 0.00 0.00 0.08 3.01 0.67 0.00 0.18 0.00 0.04 0.24 0.00 5.72 6.00 0.46 1.77 0.74 0.00 0.02 0.00 0.00 0.02 3.01 0.74 0.00 0.11 0.00 0.02 0.16 0.00 5.82 6.00 0.46 1.98 0.51 0.00 0.02 0.00 0.00 0.02 2.98 0.72 0.00 0.07 0.00 0.01 0.15 0.00 5.83 6.00 0.56 1.93 0.48 0.00 0.01 0.00 0.00 0.02 3.01 0.73 0.00 0.13 0.00 0.03 0.28 0.00 5.70 6.00 0.32 1.80 0.86 0.00 0.01 0.00 0.00 0.01 3.00 0.77 0.01 0.06 0.00 0.03 0.28 0.00 5.69 6.00 0.25 1.79 0.87 0.00 0.01 0.00 0.00 0.02 2.95 0.79 0.00 0.05 0.01 0.04 0.31 0.00 5.64 6.00 0.30 1.66 0.98 0.00 0.02 0.00 0.00 0.06 3.01 0.70 0.01 0.13 0.01 0.05 0.31 0.00 5.63 6.00 0.29 1.71 0.96 0.00 0.02 0.00 0.00 0.04 3.02 0.76 0.00 0.10 0.00 0.06 0.29 0.00 5.65 6.00 0.15 1.88 0.87 0.00 0.02 0.00 0.00 0.09 3.02 0.62 0.01 0.22 0.00 0.04 0.25 0.00 5.71 6.00 0.41 1.78 0.76 0.00 0.02 0.00 0.00 0.05 3.02 0.71 0.01 0.13 0.00 0.02 0.30 0.00 5.68 6.00 0.74 1.26 0.93 0.00 0.00 0.00 0.00 0.01 2.94 0.54 0.00 0.02 0.00 0.05 0.29 0.00 5.66 6.00 0.37 1.73 0.87 0.00 0.02 0.00 0.00 0.04 3.02 0.78 0.00 0.17 0.00 0.01 0.17 0.00 5.81 6.00 0.60 1.83 0.54 0.00 0.02 0.00 0.00 0.03 3.01 0.74 0.00 0.12 0.00 0.05 0.33 0.00 5.62 6.00 0.11 1.81 0.99 0.00 0.03 0.00 0.00 0.09 3.03 0.67 0.01 0.23 0.01 0.06 0.32 0.00 5.62 6.00 0.30 1.66 0.99 0.00 0.03 0.00 0.00 0.05 3.03 0.73 0.01 0.12 0.00 0.05 0.40 0.37 5.18 6.00 0.00 1.54 1.27 0.00 0.02 0.00 0.00 0.18 3.02 0.63 0.02 0.30 0.00 0.05 0.27 0.00 5.67 6.00 0.25 1.85 0.82 0.00 0.02 0.00 0.00 0.06 3.00 0.64 0.00 0.23 0.00 0.03 0.35 0.00 5.62 6.00 0.23 1.64 1.06 0.00 0.04 0.00 0.00 0.04 3.01 0.69 0.00 0.17 0.00 0.02 0.25 0.00 5.73 6.00 0.56 1.63 0.76 0.00 0.01 0.00 0.00 0.05 3.01 0.66 0.00 0.16 0.00 0.05 0.36 0.00 5.59 6.00 0.16 1.67 1.09 0.00 0.04 0.00 0.00 0.07 3.03 0.71 0.01 0.16 0.00 0.02 0.36 0.00 5.62 6.00 0.68 1.12 1.11 0.00 0.01 0.00 0.00 0.00 2.92 0.55 0.00 0.01 0.00 0.02 0.26 0.00 5.72 6.00 0.13 1.96 0.81 0.00 0.01 0.00 0.00 0.01 2.93 0.70 0.00 0.06 0.00 0.03 0.44 0.20 5.33 6.00 0.00 1.68 1.31 0.00 0.01 0.00 0.00 0.01 3.01 0.73 0.00 0.21 0.00 0.01 0.16 0.00 5.82 6.00 0.68 1.77 0.51 0.00 0.01 0.00 0.00 0.03 3.01 0.72 0.00 0.12 0.00 0.05 0.28 0.00 5.66 6.00 0.18 1.83 0.87 0.00 0.02 0.00 0.00 0.11 3.01 0.66 0.00 0.21 0.00 0.02 0.36 0.00 5.61 6.00 0.14 1.69 1.10 0.00 0.00 0.00 0.00 0.05 2.98 0.71 0.00 0.12 0.00 0.02 0.30 0.00 5.69 6.00 0.48 1.56 0.92 0.00 0.00 0.00 0.00 0.01 2.98 0.67 0.00 0.05 0.00 0.01 0.26 0.00 5.73 6.00 0.52 1.64 0.82 0.00 0.00 0.00 0.00 0.01 2.98 0.66 0.00 0.05 0.00 0.04 0.31 0.00 5.65 6.00 0.07 1.85 0.98 0.00 0.04 0.00 0.00 0.03 2.97 0.74 0.00 0.09 0.00 0.07 0.31 0.03 5.58 6.00 0.00 1.91 0.97 0.00 0.03 0.00 0.00 0.12 3.03 0.65 0.00 0.24 0.01 0.05 0.27 0.00 5.67 6.00 0.31 1.79 0.84 0.00 0.03 0.00 0.00 0.06 3.03 0.72 0.00 0.16 0.00 0.04 0.38 0.00 5.58 6.00 0.36 1.34 1.16 0.00 0.02 0.00 0.00 0.04 2.93 0.74 0.01 0.04 0.01 0.00 0.32 0.00 5.67 6.00 0.22 1.61 1.09 0.00 0.00 0.00 0.00 0.04 2.96 0.66 0.01 0.19 0.01 0.00 0.39 0.13 5.47 6.00 0.00 1.53 1.31 0.00 0.00 0.00 0.00 0.09 2.92 0.59 0.01 0.27 0.00 0.00 0.37 0.00 5.63 6.00 0.11 1.53 1.24 0.00 0.00 0.00 0.00 0.01 2.90 0.70 0.01 0.07 0.01 0.00 0.19 0.36 5.44 6.00 0.00 1.25 1.63 0.00 0.00 0.00 0.00 0.07 2.94 0.66 0.01 0.24 0.00 0.00 0.18 0.00 5.82 6.00 0.04 1.55 1.35 0.00 0.00 0.00 0.00 0.01 2.95 0.75 0.01 0.11 0.02 0.00 0.16 0.14 5.68 6.00 0.00 1.57 1.33 0.00 0.00 0.00 0.00 0.07 2.97 0.64 0.01 0.23 0.00 0.00 0.41 0.22 5.37 6.00 0.00 1.47 1.39 0.00 0.00 0.00 0.00 0.07 2.93 0.63 0.01 0.27 0.01 0.00 0.33 0.00 5.66 6.00 0.00 1.69 1.15 0.00 0.00 0.00 0.00 0.08 2.92 0.64 0.01 0.23 0.00 0.00 0.29 0.00 5.71 6.00 0.18 1.67 1.02 0.00 0.00 0.00 0.00 0.01 2.88 0.70 0.01 0.12 0.01 0.00 0.38 0.03 5.57 6.00 0.00 1.60 1.32 0.00 0.00 0.00 0.00 0.07 2.99 0.61 0.01 0.26 0.00 0.00 0.29 0.00 5.70 6.00 0.13 1.62 1.07 0.00 0.00 0.00 0.00 0.13 2.95 0.59 0.01 0.22 0.00 0.00 0.23 0.00 5.76 6.00 0.46 1.60 0.84 0.00 0.00 0.00 0.00 0.03 2.92 0.58 0.01 0.13 0.00 0.00 0.33 0.04 5.63 6.00 0.00 1.66 1.17 0.00 0.00 0.00 0.00 0.12 2.95 0.58 0.01 0.28 0.00 0.00 0.24 0.00 5.76 6.00 0.43 1.65 0.87 0.00 0.00 0.00 0.00 0.02 2.97 0.73 0.00 0.13 0.01 0.00 0.34 0.16 5.49 6.00 0.00 1.55 1.25 0.00 0.00 0.00 0.00 0.15 2.95 0.54 0.01 0.33 0.00 0.00 0.27 0.00 5.73 6.00 0.42 1.52 0.95 0.00 0.00 0.00 0.00 0.05 2.94 0.61 0.01 0.13 0.00 0.00 0.25 0.00 5.75 6.00 0.36 1.65 0.91 0.00 0.00 0.00 0.00 0.05 2.96 0.65 0.01 0.13 0.00 0.00 0.50 0.00 5.50 6.00 0.52 1.47 0.89 0.00 0.00 0.00 0.00 0.02 2.90 0.70 0.00 0.12 0.00 0.00 0.67 0.03 5.29 6.00 0.00 1.68 1.21 0.00 0.00 0.00 0.00 0.10 2.99 0.62 0.01 0.29 0.00 0.00 0.56 0.00 5.44 6.00 0.40 1.52 1.02 0.00 0.00 0.00 0.00 0.02 2.97 0.72 0.01 0.12 0.00 0.00 0.52 0.00 5.48 6.00 0.77 1.19 0.95 0.00 0.00 0.00 0.00 0.01 2.91 0.66 0.00 0.06 0.00 0.00 0.58 0.00 5.42 6.00 0.59 1.28 1.04 0.00 0.00 0.00 0.00 0.03 2.93 0.62 0.01 0.16 0.00 0.00 0.64 0.00 5.35 6.00 0.51 1.26 1.17 0.00 0.00 0.00 0.00 0.02 2.95 0.67 0.01 0.08 0.00 0.00 0.57 0.00 5.43 6.00 0.41 1.45 1.03 0.00 0.00 0.00 0.00 0.05 2.93 0.65 0.01 0.18 0.00 0.00 0.45 0.00 5.55 6.00 0.62 1.36 0.96 0.00 0.00 0.00 0.00 0.01 2.95 0.62 0.01 0.09 0.00 0.00 0.40 0.00 5.60 6.00 0.57 1.51 0.87 0.00 0.00 0.00 0.00 0.01 2.96 0.72 0.00 0.09 0.00 0.00 0.50 0.00 5.50 6.00 0.50 1.34 1.09 0.00 0.00 0.00 0.00 0.01 2.94 0.71 0.01 0.08 0.00 0.00 0.43 0.00 5.57 6.00 0.60 1.40 0.93 0.00 0.00 0.00 0.00 0.01 2.94 0.61 0.00 0.10 0.00 0.00 0.38 0.00 5.62 6.00 0.61 1.54 0.80 0.00 0.00 0.00 0.00 0.02 2.97 0.66 0.00 0.09 0.00 0.00 0.59 0.00 5.41 6.00 0.55 1.17 1.26 0.00 0.00 0.00 0.00 0.01 2.98 0.73 0.01 0.05 0.00 0.00 0.43 0.00 5.57 6.00 0.63 1.38 0.92 0.00 0.00 0.00 0.00 0.03 2.96 0.67 0.01 0.08 0.00 0.00 0.52 0.00 5.48 6.00 0.34 1.40 1.13 0.00 0.00 0.00 0.00 0.08 2.95 0.64 0.01 0.18 0.00 0.00 0.48 0.00 5.52 6.00 0.50 1.37 1.02 0.00 0.00 0.00 0.00 0.02 2.91 0.74 0.01 0.10 0.00 0.00 0.48 0.00 5.52 6.00 0.49 1.40 1.04 0.00 0.00 0.00 0.00 0.02 2.95 0.70 0.01 0.07 0.00 0.00 0.48 0.00 5.52 6.00 0.49 1.40 1.04 0.00 0.00 0.00 0.00 0.02 2.95 0.71 0.01 0.09 0.00 0.00 0.42 0.00 5.58 6.00 0.38 1.66 0.90 0.00 0.00 0.00 0.00 0.02 2.97 0.71 0.00 0.10 0.00 0.00 0.59 0.00 5.40 6.00 0.80 1.11 1.06 0.00 0.01 0.00 0.00 0.02 3.01 0.52 0.00 0.18 0.00 0.01 0.69 0.00 5.30 6.00 1.01 0.72 1.22 0.00 0.00 0.00 0.00 0.04 3.00 0.40 0.00 0.17 0.00 0.00 0.59 0.00 5.41 6.00 0.62 1.26 1.04 0.00 0.00 0.00 0.00 0.00 2.93 0.66 0.00 0.10 0.00 0.00 0.52 0.00 5.47 6.00 0.65 1.34 0.95 0.00 0.01 0.00 0.00 0.01 2.95 0.63 0.00 0.11 0.00 0.01 0.62 0.00 5.37 6.00 0.82 1.05 1.11 0.00 0.01 0.00 0.00 0.02 3.00 0.46 0.00 0.21 0.00 0.01 0.56 0.00 5.43 6.00 0.44 1.39 1.01 0.00 0.01 0.00 0.00 0.10 2.95 0.61 0.00 0.21 0.00 0.01 0.61 0.00 5.38 6.00 0.92 0.96 1.11 0.00 0.01 0.00 0.00 0.01 3.00 0.46 0.00 0.18 0.00 0.01 0.45 0.00 5.54 6.00 0.59 1.51 0.82 0.00 0.01 0.00 0.00 0.04 2.97 0.67 0.01 0.17 0.00 0.00 0.48 0.00 5.52 6.00 0.64 1.44 0.86 0.00 0.01 0.00 0.00 0.03 2.98 0.64 0.01 0.18 0.00 0.00 0.62 0.00 5.38 6.00 0.82 1.05 1.11 0.00 0.00 0.00 0.00 0.02 3.00 0.49 0.00 0.19 0.00 0.00 0.56 0.00 5.43 6.00 0.83 1.13 1.01 0.00 0.01 0.00 0.00 0.02 3.00 0.54 0.00 0.16 0.00 0.01 0.60 0.00 5.39 6.00 0.99 0.89 1.09 0.00 0.00 0.00 0.00 0.03 3.00 0.50 0.00 0.15 0.00 0.01 0.49 0.00 5.50 6.00 0.64 1.44 0.88 0.00 0.01 0.00 0.00 0.03 3.00 0.67 0.01 0.17 0.00 0.01 0.51 0.00 5.49 6.00 0.53 1.45 0.91 0.00 0.00 0.00 0.00 0.07 2.97 0.61 0.01 0.20 0.00 0.00 0.61 0.00 5.39 6.00 1.25 0.65 1.09 0.00 0.00 0.00 0.00 0.01 3.00 0.40 0.01 0.18 0.00 0.01 0.61 0.00 5.38 6.00 0.96 0.90 1.10 0.00 0.00 0.00 0.00 0.04 3.00 0.52 0.00 0.17 0.00 0.01 0.49 0.00 5.51 6.00 0.66 1.39 0.88 0.00 0.01 0.00 0.00 0.04 2.98 0.60 0.01 0.18 0.00 0.00 0.64 0.00 5.36 6.00 1.24 0.61 1.14 0.00 0.00 0.00 0.00 0.01 3.00 0.38 0.01 0.17 0.00 0.01 0.48 0.00 5.51 6.00 0.76 1.35 0.86 0.00 0.01 0.00 0.00 0.03 3.00 0.58 0.00 0.18 0.00 0.01 0.46 0.00 5.53 6.00 0.64 1.47 0.84 0.00 0.01 0.00 0.00 0.04 2.99 0.64 0.01 0.18 0.00 0.00 0.58 0.00 5.41 6.00 0.87 1.06 1.05 0.00 0.01 0.00 0.00 0.02 3.00 0.47 0.01 0.19 0.00 0.01 0.56 0.00 5.43 6.00 0.51 1.37 1.00 0.00 0.01 0.00 0.00 0.10 3.01 0.57 0.01 0.22 0.00 0.01 0.46 0.00 5.53 6.00 0.67 1.42 0.84 0.00 0.00 0.00 0.00 0.04 2.97 0.65 0.01 0.17 0.00 0.00 0.46 0.00 5.53 6.00 0.60 1.35 1.00 0.00 0.00 0.00 0.00 0.02 2.97 0.58 0.01 0.13 0.00 0.00 0.45 0.00 5.55 6.00 0.68 1.27 0.96 0.00 0.00 0.00 0.00 0.07 2.99 0.59 0.01 0.15 0.00 0.00 0.50 0.00 5.50 6.00 0.42 1.44 1.07 0.00 0.00 0.00 0.00 0.00 2.94 0.83 0.00 0.06 0.00 0.00 0.50 0.00 5.50 6.00 0.85 0.99 1.08 0.00 0.00 0.00 0.00 0.01 2.93 0.43 0.01 0.04 0.00 0.00 0.41 0.00 5.59 6.00 0.49 1.58 0.87 0.00 0.00 0.00 0.00 0.03 2.97 0.63 0.01 0.21 0.00 0.00 0.48 0.00 5.52 6.00 0.81 1.08 1.04 0.00 0.00 0.00 0.00 0.01 2.94 0.46 0.01 0.05 0.00 0.00 0.38 0.00 5.62 6.00 0.61 1.54 0.81 0.00 0.00 0.00 0.00 0.01 2.96 0.68 0.00 0.09 0.00 0.00 0.45 0.00 5.55 6.00 0.40 1.55 0.96 0.00 0.00 0.00 0.00 0.06 2.97 0.68 0.00 0.19 0.00 0.00 0.34 0.00 5.66 6.00 0.62 1.59 0.72 0.00 0.00 0.00 0.00 0.01 2.94 0.65 0.00 0.09 0.00 0.00 0.46 0.00 5.54 6.00 0.76 1.21 0.98 0.00 0.00 0.00 0.00 0.01 2.96 0.59 0.00 0.04 0.00 0.00 0.50 0.00 5.50 6.00 0.36 1.49 1.08 0.00 0.00 0.00 0.00 0.02 2.96 0.64 0.01 0.17 0.00 0.00 0.52 0.00 5.48 6.00 0.34 1.33 1.12 0.00 0.00 0.00 0.00 0.20 2.99 0.60 0.01 0.15 0.00 0.00 0.45 0.00 5.55 6.00 0.26 1.61 0.98 0.00 0.00 0.00 0.00 0.09 2.94 0.59 0.01 0.22 0.00 0.00 0.43 0.00 5.57 6.00 0.39 1.57 0.90 0.00 0.00 0.00 0.00 0.05 2.92 0.60 0.01 0.20 0.00 0.00 0.18 0.19 5.63 6.00 0.00 1.49 1.37 0.00 0.00 0.00 0.00 0.13 2.99 0.60 0.01 0.25 0.00 0.00 0.17 0.00 5.83 6.00 0.13 1.48 1.33 0.00 0.00 0.00 0.00 0.02 2.97 0.66 0.01 0.08 0.00 0.00 0.16 0.00 5.83 6.00 0.64 1.06 1.20 0.00 0.00 0.00 0.00 0.09 2.99 0.65 0.01 0.05 0.00 0.00 0.44 0.00 5.56 6.00 0.42 1.59 0.89 0.00 0.00 0.00 0.00 0.03 2.92 0.69 0.01 0.10 0.01 0.00 0.51 0.00 5.49 6.00 0.22 1.65 1.05 0.00 0.00 0.00 0.00 0.07 3.00 0.70 0.01 0.12 0.00 0.00 0.43 0.00 5.56 6.00 0.31 1.71 0.89 0.00 0.00 0.00 0.00 0.09 3.00 0.63 0.01 0.19 0.00 0.00 0.41 0.02 5.57 6.00 0.00 1.46 1.48 0.00 0.00 0.00 0.00 0.03 2.97 0.76 0.01 0.06 0.00 0.00 0.16 0.03 5.80 6.00 0.00 1.58 1.30 0.00 0.00 0.00 0.00 0.12 3.00 0.59 0.01 0.23 0.00 0.00 0.17 0.10 5.72 6.00 0.00 1.61 1.31 0.00 0.00 0.00 0.00 0.05 2.97 0.68 0.01 0.16 0.00 0.00 0.48 0.00 5.52 6.00 0.50 1.42 0.98 0.00 0.00 0.00 0.00 0.07 2.97 0.67 0.01 0.17 0.00 0.00 0.00 0.00 6.00 6.00 0.20 1.27 1.48 0.00 0.00 0.00 0.00 0.08 3.03 0.50 0.02 0.21 0.00 0.00 0.17 0.00 5.83 6.00 0.36 1.29 1.33 0.00 0.00 0.00 0.00 0.07 3.05 0.50 0.01 0.20 0.00 0.00 0.46 0.00 5.54 6.00 0.86 1.16 0.95 0.00 0.00 0.00 0.00 0.02 3.00 0.49 0.01 0.17 0.00 0.00 0.49 0.00 5.51 6.00 1.17 0.78 1.03 0.00 0.00 0.00 0.00 0.02 3.00 0.37 0.01 0.01 0.00 0.00 0.46 0.00 5.54 6.00 0.87 1.17 0.94 0.00 0.00 0.00 0.00 0.01 3.00 0.48 0.01 0.14 0.00 0.00 0.48 0.00 5.52 6.00 0.85 1.08 1.01 0.00 0.00 0.00 0.00 0.05 3.00 0.47 0.01 0.19 0.00 0.01 0.24 0.00 5.75 6.00 0.98 1.36 0.63 0.00 0.00 0.00 0.00 0.03 3.00 0.59 0.00 0.01 0.00 0.01 0.24 0.00 5.76 6.00 1.03 1.34 0.61 0.00 0.00 0.00 0.00 0.01 3.00 0.58 0.00 0.00 0.00 0.01 0.28 0.00 5.72 6.00 0.87 1.38 0.73 0.00 0.00 0.00 0.00 0.01 3.00 0.67 0.00 0.00 0.00 0.00 0.23 0.00 5.77 6.00 1.00 1.40 0.59 0.00 0.00 0.00 0.00 0.00 3.00 0.62 0.00 0.00 0.00 0.01 0.28 0.00 5.72 6.00 0.90 1.37 0.71 0.00 0.00 0.00 0.00 0.01 2.99 0.68 0.00 0.00 0.00 0.01 0.24 0.00 5.75 6.00 1.08 1.28 0.63 0.00 0.00 0.00 0.00 0.01 3.00 0.51 0.00 0.00 0.00 0.00 0.23 0.00 5.76 6.00 1.19 1.21 0.60 0.00 0.00 0.00 0.00 0.00 3.00 0.47 0.00 0.00 0.00 0.01 0.25 0.00 5.74 6.00 0.99 1.35 0.65 0.00 0.00 0.00 0.00 0.00 3.00 0.65 0.00 0.00 0.00 0.00 0.23 0.00 5.76 6.00 1.06 1.32 0.61 0.00 0.00 0.00 0.00 0.01 3.00 0.56 0.00 0.00 0.00 0.00 0.25 0.00 5.74 6.00 1.08 1.26 0.65 0.00 0.00 0.00 0.00 0.01 3.00 0.53 0.00 0.00 0.00 0.01 0.23 0.00 5.76 6.00 1.13 1.26 0.60 0.00 0.00 0.00 0.00 0.01 3.00 0.48 0.00 0.00 0.00 0.01 0.23 0.00 5.76 6.00 1.15 1.23 0.62 0.00 0.00 0.00 0.00 0.01 3.00 0.49 0.00 0.00 □ Sum F Cl OH O Total 0.00 1.02 0.04 0.01 2.83 1.12 4.00 0.03 1.00 0.03 0.00 2.96 1.01 4.00 0.00 1.12 0.04 0.08 2.59 1.30 4.00 0.03 1.00 0.08 0.00 2.87 1.05 4.00 0.01 1.00 0.05 0.00 3.10 0.85 4.00 0.03 1.00 0.18 0.00 2.98 0.83 4.00 0.08 1.00 0.06 0.00 2.99 0.95 4.00 0.00 1.00 0.11 0.00 2.94 0.95 4.00 0.02 1.00 0.05 0.00 2.79 1.16 4.00 0.03 1.00 0.07 0.00 2.89 1.03 4.00 0.14 1.00 0.01 0.00 2.90 1.10 4.00 0.03 1.00 0.04 0.00 2.79 1.17 4.00 0.23 1.00 0.02 0.00 2.75 1.23 4.00 0.04 1.00 0.05 0.00 2.86 1.09 4.00 0.14 1.00 0.04 0.00 2.83 1.13 4.00 0.04 1.00 0.01 0.00 2.88 1.11 4.00 0.06 1.00 0.07 0.00 2.90 1.03 4.00 0.02 1.00 0.04 0.00 2.69 1.27 4.00 0.13 1.00 0.02 0.00 2.77 1.22 4.00 0.12 1.00 0.02 0.00 2.56 1.42 4.00 0.05 1.00 0.03 0.00 2.79 1.18 4.00 0.07 1.00 0.02 0.00 2.77 1.21 4.00 0.05 1.00 0.14 0.00 2.60 1.26 4.00 0.06 1.00 0.03 0.00 2.84 1.13 4.00 0.06 1.00 0.03 0.00 2.82 1.15 4.00 0.03 1.00 0.12 0.00 2.55 1.32 4.00 0.16 1.00 0.02 0.00 2.83 1.15 4.00 0.14 1.00 0.01 0.00 2.85 1.14 4.00 0.15 1.00 0.01 0.00 2.97 1.01 4.00 0.13 1.00 0.02 0.00 2.91 1.07 4.00 0.09 1.00 0.00 0.00 2.87 1.12 4.00 0.09 1.00 0.02 0.00 2.90 1.08 4.00 0.12 1.00 0.05 0.00 2.75 1.20 4.00 0.03 1.00 0.19 0.00 2.58 1.23 4.00 0.04 1.00 0.17 0.00 2.56 1.27 4.00 0.18 1.00 0.02 0.00 2.92 1.07 4.00 0.06 1.00 0.17 0.00 2.58 1.24 4.00 0.16 1.00 0.01 0.00 2.87 1.12 4.00 0.05 1.00 0.09 0.00 2.68 1.23 4.00 0.16 1.00 0.01 0.00 2.86 1.13 4.00 0.06 1.00 0.15 0.00 2.61 1.24 4.00 0.06 1.00 0.02 0.00 2.93 1.06 4.00 0.16 1.00 0.00 0.00 2.88 1.12 4.00 0.07 1.00 0.16 0.00 2.58 1.26 4.00 0.09 1.00 0.02 0.00 2.88 1.09 4.00 0.05 1.00 0.01 0.00 2.80 1.19 4.00 0.17 1.00 0.01 0.00 2.92 1.07 4.00 0.04 1.00 0.02 0.00 2.91 1.07 4.00 0.11 1.00 0.00 0.00 2.94 1.06 4.00 0.10 1.00 0.00 0.00 2.91 1.09 4.00 0.06 1.00 0.12 0.00 2.67 1.21 4.00 0.08 1.00 0.16 0.00 2.67 1.17 4.00 0.06 1.00 0.13 0.00 2.72 1.15 4.00 0.11 1.00 0.01 0.00 2.91 1.08 4.00 0.07 1.00 0.06 0.00 2.78 1.16 4.00 0.08 1.00 0.00 0.00 2.87 1.12 4.00 0.14 1.00 0.00 0.00 2.95 1.04 4.00 0.20 1.00 0.00 0.00 2.89 1.11 4.00 0.02 1.00 0.09 0.00 2.56 1.34 4.00 0.04 1.00 0.06 0.00 2.50 1.43 4.00 0.13 1.00 0.01 0.00 2.85 1.14 4.00 0.00 1.01 0.03 0.00 2.45 1.52 4.00 0.17 1.00 0.00 0.00 2.89 1.11 4.00 0.13 1.00 0.00 0.00 2.92 1.08 4.00 0.11 1.00 0.00 0.00 2.93 1.07 4.00 0.15 1.00 0.02 0.00 2.90 1.07 4.00 0.04 1.00 0.15 0.00 2.52 1.33 4.00 0.07 1.00 0.11 0.00 2.66 1.23 4.00 0.05 1.00 0.06 0.00 2.49 1.45 4.00 0.08 1.00 0.01 0.00 2.82 1.16 4.00 0.05 1.00 0.08 0.00 2.50 1.42 4.00 0.07 1.00 0.15 0.00 2.66 1.19 4.00 0.15 1.00 0.00 0.00 2.89 1.11 4.00 0.07 1.00 0.13 0.00 2.74 1.12 4.00 0.10 1.00 0.01 0.00 2.95 1.05 4.00 0.06 1.00 0.15 0.00 2.68 1.17 4.00 0.10 1.00 0.03 0.00 3.00 0.97 4.00 0.15 1.00 0.01 0.00 2.91 1.08 4.00 0.11 1.00 0.00 0.00 2.89 1.11 4.00 0.15 1.00 0.00 0.00 3.45 0.55 4.00 0.15 1.00 0.00 0.00 2.88 1.12 4.00 0.06 1.00 0.12 0.00 2.56 1.32 4.00 0.04 1.00 0.12 0.00 2.72 1.16 4.00 0.07 1.00 0.13 0.00 2.72 1.15 4.00 0.22 1.00 0.02 0.00 2.85 1.13 4.00 0.05 1.00 0.17 0.00 2.65 1.18 4.00 0.21 1.00 0.01 0.00 2.91 1.07 4.00 0.05 1.00 0.02 0.00 2.83 1.14 4.00 0.06 1.00 0.14 0.00 2.67 1.18 4.00 0.17 1.00 0.01 0.00 2.85 1.15 4.00 0.05 1.00 0.15 0.00 2.64 1.21 4.00 0.09 1.00 0.02 0.00 2.74 1.24 4.00 0.04 1.00 0.09 0.00 2.65 1.26 4.00 0.07 1.00 0.04 0.00 2.84 1.12 4.00 0.25 1.00 0.06 0.00 2.93 1.01 4.00 0.31 1.00 0.04 0.00 2.97 0.99 4.00 0.40 1.00 0.03 0.00 2.93 1.03 4.00 0.16 1.00 0.02 0.00 3.09 0.88 4.00 0.34 1.00 0.03 0.00 2.96 1.00 4.00 0.27 1.00 0.02 0.00 2.95 1.04 4.00 0.02 1.00 0.15 0.00 3.12 0.73 4.00 0.09 1.00 0.16 0.00 3.02 0.82 4.00 0.03 1.00 0.27 0.00 2.84 0.88 4.00 0.10 1.00 0.12 0.00 3.09 0.79 4.00 0.54 1.00 0.03 0.04 3.21 0.73 4.00 0.39 1.00 0.01 0.02 3.25 0.72 4.00 0.06 1.00 0.14 0.00 3.04 0.82 4.00 0.02 1.00 0.13 0.00 3.06 0.81 4.00 0.10 1.00 0.02 0.01 3.20 0.77 4.00 0.48 1.00 0.02 0.00 3.27 0.71 4.00 0.08 1.00 0.13 0.00 3.02 0.84 4.00 0.30 1.00 0.01 0.00 3.18 0.80 4.00 0.12 1.00 0.12 0.00 2.93 0.95 4.00 0.20 1.00 0.01 0.01 2.97 1.01 4.00 0.06 1.00 0.16 0.00 3.03 0.81 4.00 0.00 1.00 0.20 0.00 2.99 0.81 4.00 0.24 1.00 0.00 0.00 3.23 0.77 4.00 0.25 1.00 0.00 0.00 3.21 0.79 4.00 0.19 1.00 0.01 0.00 3.23 0.75 4.00 0.00 1.02 0.11 0.02 3.10 0.78 4.00 0.06 1.00 0.16 0.00 3.08 0.75 4.00 0.29 1.00 0.02 0.00 3.31 0.67 4.00 0.16 1.00 0.03 0.00 3.25 0.72 4.00 0.07 1.00 0.15 0.00 3.07 0.77 4.00 0.05 1.00 0.15 0.00 3.06 0.79 4.00 0.18 1.00 0.06 0.00 2.99 0.95 4.00 0.08 1.00 0.02 0.00 3.10 0.88 4.00 0.10 1.00 0.08 0.00 3.03 0.88 4.00 0.02 1.00 0.14 0.00 3.09 0.77 4.00 0.05 1.00 0.01 0.01 2.99 0.99 4.00 0.02 1.00 0.08 0.00 3.16 0.75 4.00 0.08 1.00 0.13 0.00 3.09 0.78 4.00 0.10 1.00 0.08 0.00 3.16 0.76 4.00 0.05 1.00 0.13 0.00 3.07 0.80 4.00 0.26 1.00 0.01 0.00 3.23 0.76 4.00 0.12 1.00 0.02 0.02 2.94 1.02 4.00 0.07 1.00 0.11 0.00 3.16 0.73 4.00 0.02 1.00 0.11 0.00 3.15 0.74 4.00 0.42 1.00 0.00 0.01 3.25 0.74 4.00 0.04 1.00 0.15 0.00 3.16 0.69 4.00 0.03 1.00 0.14 0.00 3.12 0.74 4.00 0.02 1.00 0.18 0.00 3.02 0.80 4.00 0.03 1.00 0.16 0.00 3.02 0.82 4.00 0.10 1.00 0.06 0.00 2.96 0.98 4.00 0.09 1.00 0.06 0.01 2.79 1.14 4.00 0.06 1.00 0.04 0.00 2.98 0.97 4.00 0.05 1.00 0.07 0.00 2.83 1.11 4.00 0.03 1.00 0.05 0.00 2.83 1.12 4.00 0.10 1.00 0.06 0.00 2.84 1.10 4.00 0.09 1.00 0.01 0.00 2.75 1.24 4.00 0.03 1.00 0.06 0.00 2.74 1.20 4.00 0.10 1.00 0.02 0.00 2.68 1.30 4.00 0.14 1.00 0.02 0.01 2.59 1.39 4.00 0.07 1.00 0.01 0.00 2.62 1.37 4.00 0.12 1.00 0.02 0.00 2.69 1.29 4.00 0.14 1.00 0.02 0.00 2.59 1.40 4.00 0.41 1.00 0.01 0.00 2.79 1.19 4.00 0.09 1.00 0.01 0.00 2.68 1.31 4.00 0.13 1.00 0.01 0.00 2.64 1.35 4.00 0.11 1.00 0.01 0.00 2.66 1.33 4.00 0.06 1.00 0.01 0.00 2.66 1.33 4.00 0.13 1.00 0.00 0.00 2.69 1.30 4.00 0.17 1.00 0.02 0.00 3.38 0.60 4.00 0.04 1.00 0.02 0.00 3.26 0.72 4.00 0.15 1.00 0.01 0.00 3.12 0.88 4.00 0.17 1.00 0.03 0.00 3.18 0.79 4.00 0.04 1.00 0.05 0.00 3.22 0.73 4.00 0.03 1.00 0.07 0.00 3.03 0.91 4.00 0.06 1.00 0.02 0.00 3.07 0.91 4.00 0.01 1.00 0.05 0.00 3.13 0.81 4.00 0.00 1.00 0.06 0.00 3.04 0.90 4.00 0.06 1.00 0.04 0.00 3.16 0.80 4.00 0.06 1.00 0.03 0.00 3.12 0.85 4.00 0.05 1.00 0.02 0.00 3.14 0.83 4.00 0.03 1.00 0.04 0.00 3.12 0.84 4.00 0.02 1.00 0.06 0.00 3.17 0.77 4.00 0.31 1.00 0.04 0.72 2.83 0.41 4.00 0.03 1.00 0.04 0.00 3.12 0.85 4.00 0.10 1.00 0.03 0.00 3.19 0.78 4.00 0.01 1.00 0.04 0.00 2.99 0.96 4.00 0.04 1.00 0.03 0.00 3.13 0.84 4.00 0.04 1.00 0.03 0.00 2.92 1.05 4.00 0.13 1.00 0.02 0.00 3.10 0.88 4.00 0.11 1.00 0.00 0.00 3.14 0.86 4.00 0.07 1.00 0.04 0.01 2.96 0.99 4.00 0.02 1.00 0.02 0.00 3.05 0.92 4.00 0.00 1.00 0.09 0.00 2.91 1.00 4.00 0.07 1.00 0.02 0.00 3.03 0.94 4.00 0.00 1.01 0.04 0.00 2.98 0.99 4.00 0.01 1.00 0.07 0.00 2.98 0.95 4.00 0.06 1.00 0.03 0.00 3.01 0.96 4.00 0.02 1.00 0.02 0.00 3.05 0.92 4.00 0.03 1.00 0.05 0.01 3.05 0.89 4.00 0.03 1.00 0.04 0.00 2.96 1.00 4.00 0.08 1.00 0.01 0.00 3.25 0.74 4.00 0.05 1.00 0.06 0.00 3.16 0.77 4.00 0.03 1.00 0.06 0.00 3.05 0.89 4.00 0.14 1.00 0.02 0.00 3.18 0.80 4.00 0.02 1.00 0.04 0.00 3.12 0.85 4.00 0.04 1.00 0.12 0.00 3.19 0.69 4.00 0.01 1.00 0.08 0.00 3.14 0.78 4.00 0.14 1.00 0.01 0.00 3.18 0.81 4.00 0.05 1.00 0.11 0.00 3.05 0.84 4.00 0.14 1.00 0.00 0.00 3.21 0.79 4.00 0.07 1.00 0.08 0.00 3.08 0.84 4.00 0.05 1.00 0.07 0.00 3.18 0.74 4.00 0.01 1.00 0.09 0.00 3.12 0.79 4.00 0.04 1.00 0.05 0.00 3.15 0.79 4.00 0.18 1.00 0.00 0.00 3.24 0.76 4.00 0.07 1.00 0.04 0.00 3.18 0.78 4.00 0.02 1.00 0.08 0.00 3.13 0.79 4.00 0.04 1.00 0.07 0.00 3.22 0.70 4.00 0.04 1.00 0.00 0.00 3.03 0.97 4.00 0.08 1.00 0.08 0.00 3.07 0.85 4.00 0.04 1.00 0.09 0.00 3.13 0.77 4.00 0.02 1.00 0.10 0.00 3.02 0.88 4.00 0.01 1.00 0.06 0.00 3.12 0.81 4.00 0.06 1.00 0.03 0.01 3.08 0.89 4.00 0.04 1.00 0.00 0.00 3.03 0.97 4.00 0.00 1.00 0.09 0.00 3.16 0.75 4.00 0.06 1.00 0.05 0.00 3.17 0.78 4.00 0.02 1.00 0.10 0.00 3.14 0.75 4.00 0.04 1.00 0.03 0.00 2.91 1.06 4.00 0.03 1.00 0.02 0.00 2.99 0.99 4.00 0.04 1.00 0.10 0.00 3.14 0.76 4.00 0.06 1.00 0.03 0.00 3.01 0.96 4.00 0.05 1.00 0.06 0.00 3.04 0.90 4.00 0.09 1.00 0.03 0.00 3.16 0.81 4.00 0.04 1.00 0.03 0.00 3.01 0.95 4.00 0.03 1.00 0.07 0.00 3.11 0.82 4.00 0.05 1.00 0.03 0.00 3.02 0.95 4.00 0.11 1.00 0.01 0.00 3.12 0.86 4.00 0.14 1.00 0.00 0.01 3.38 0.61 4.00 0.17 1.00 0.05 0.00 2.86 1.10 4.00 0.15 1.00 0.05 0.00 2.82 1.12 4.00 0.13 1.00 0.06 0.00 2.78 1.17 4.00 0.14 1.00 0.04 0.00 2.85 1.11 4.00 0.20 1.00 0.06 0.00 2.95 0.98 4.00 0.14 1.00 0.08 0.00 2.77 1.15 4.00 0.15 1.00 0.00 0.00 3.23 0.77 4.00 0.04 1.00 0.01 0.00 3.35 0.64 4.00 0.12 1.00 0.00 0.00 3.39 0.61 4.00 0.13 1.00 0.06 0.01 2.84 1.10 4.00 0.10 1.00 0.07 0.01 2.71 1.21 4.00 0.10 1.00 0.08 0.01 2.82 1.09 4.00 0.10 1.00 0.07 0.00 2.77 1.16 4.00 0.11 1.00 0.07 0.00 2.72 1.21 4.00 0.11 1.00 0.02 0.01 3.02 0.96 4.00 0.18 1.00 0.02 0.00 2.85 1.12 4.00 0.18 1.00 0.04 0.01 2.93 1.02 4.00 0.25 1.00 0.01 0.00 3.25 0.74 4.00 0.31 1.00 0.02 0.00 3.24 0.74 4.00 0.12 1.00 0.05 0.00 2.74 1.21 4.00 0.14 1.00 0.00 0.00 3.38 0.62 4.00 0.17 1.00 0.03 0.00 2.66 1.31 4.00 0.12 1.00 0.00 0.02 3.36 0.62 4.00 0.03 1.00 0.03 0.00 2.85 1.12 4.00 0.03 1.00 0.06 0.00 2.89 1.05 4.00 0.05 1.00 0.03 0.00 2.85 1.12 4.00 0.07 1.00 0.05 0.00 2.85 1.11 4.00 0.05 1.00 0.04 0.00 2.95 1.01 4.00 0.03 1.00 0.03 0.00 2.94 1.03 4.00 0.05 1.00 0.05 0.00 2.93 1.02 4.00 0.09 1.00 0.04 0.00 2.95 1.00 4.00 0.04 1.00 0.04 0.00 2.91 1.05 4.00 0.06 1.00 0.04 0.00 2.94 1.02 4.00 0.12 1.00 0.03 0.01 3.01 0.95 4.00 0.11 1.00 0.03 0.00 3.04 0.93 4.00 0.07 1.00 0.03 0.00 3.05 0.92 4.00 0.18 1.00 0.01 0.00 3.26 0.72 4.00 0.08 1.00 0.00 0.00 3.21 0.78 4.00 0.11 1.00 0.00 0.00 3.09 0.91 4.00 0.20 1.00 0.01 0.00 3.33 0.66 4.00 0.15 1.00 0.03 0.00 3.28 0.69 4.00 0.17 1.00 0.02 0.01 3.18 0.79 4.00 0.20 1.00 0.00 0.01 3.16 0.84 4.00 0.15 1.00 0.04 0.02 3.11 0.83 4.00 0.17 1.00 0.03 0.00 3.34 0.63 4.00 0.09 1.00 0.03 0.00 3.17 0.80 4.00 0.16 1.00 0.00 0.00 3.44 0.56 4.00 0.24 1.00 0.01 0.01 3.29 0.69 4.00 0.06 1.00 0.01 0.00 3.23 0.76 4.00 0.16 1.00 0.00 0.00 3.25 0.75 4.00 0.17 1.00 0.03 0.00 3.13 0.83 4.00 0.12 1.00 0.02 0.00 3.02 0.96 4.00 0.11 1.00 0.03 0.00 3.06 0.91 4.00 0.11 1.00 0.00 0.00 3.05 0.95 4.00 0.66 1.00 0.18 0.00 3.16 0.66 4.00 0.70 1.00 0.14 0.01 3.20 0.66 4.00 0.72 1.00 0.13 0.00 3.19 0.67 4.00 0.72 1.00 0.13 0.00 2.96 0.91 4.00 0.72 1.00 0.17 0.00 2.92 0.91 4.00 0.66 1.00 0.06 0.00 3.18 0.76 4.00 0.60 1.00 0.03 0.00 3.29 0.69 4.00 0.64 1.00 0.02 0.00 3.15 0.83 4.00 0.55 1.00 0.11 0.00 3.15 0.74 4.00 0.62 1.00 0.19 0.00 2.92 0.89 4.00 0.64 1.00 0.04 0.00 3.25 0.70 4.00 0.76 1.00 0.14 0.00 2.96 0.89 4.00 0.72 1.00 0.16 0.01 2.90 0.93 4.00 0.72 1.00 0.04 0.00 3.42 0.54 4.00 0.86 1.00 0.00 0.01 3.32 0.67 4.00 0.71 1.00 0.16 0.00 2.96 0.88 4.00 0.73 1.00 0.18 0.00 2.92 0.90 4.00 0.72 1.00 0.20 0.00 2.92 0.88 4.00 0.08 1.00 0.02 0.00 3.11 0.87 4.00 0.10 1.00 0.02 0.00 2.99 0.99 4.00 0.10 1.00 0.04 0.00 3.14 0.82 4.00 0.11 1.00 0.03 0.00 3.02 0.96 4.00 0.11 1.00 0.01 0.00 3.21 0.78 4.00 0.07 1.00 0.02 0.00 3.12 0.86 4.00 0.06 1.00 0.03 0.00 3.16 0.81 4.00 0.08 1.00 0.01 0.00 3.07 0.92 4.00 0.05 1.00 0.05 0.00 3.12 0.84 4.00 0.06 1.00 0.04 0.00 3.05 0.91 4.00 0.06 1.00 0.00 0.00 3.32 0.68 4.00 0.07 1.00 0.03 0.00 3.10 0.87 4.00 0.18 1.00 0.03 0.00 3.01 0.97 4.00 0.06 1.00 0.04 0.00 3.04 0.92 4.00 0.10 1.00 0.04 0.00 3.14 0.81 4.00 0.02 1.00 0.03 0.00 3.33 0.64 4.00 0.06 1.00 0.03 0.00 3.14 0.83 4.00 0.08 1.00 0.02 0.00 2.92 1.06 4.00 0.13 1.00 0.01 0.00 2.90 1.10 4.00 0.09 1.00 0.04 0.00 3.12 0.84 4.00 0.08 1.00 0.06 0.00 3.10 0.84 4.00 0.07 1.00 0.02 0.00 3.15 0.83 4.00 0.08 1.00 0.04 0.00 3.18 0.78 4.00 0.04 1.00 0.02 0.00 3.27 0.72 4.00 0.07 1.00 0.02 0.00 3.26 0.73 4.00 0.03 1.00 0.06 0.00 3.36 0.57 4.00 0.10 1.00 0.02 0.00 3.22 0.76 4.00 0.03 1.00 0.05 0.00 3.27 0.67 4.00 0.08 1.00 0.03 0.00 3.10 0.87 4.00 0.07 1.00 0.04 0.00 3.17 0.80 4.00 0.21 1.00 0.01 0.00 3.07 0.92 4.00 0.11 1.00 0.03 0.00 3.06 0.92 4.00 0.09 1.00 0.06 0.00 3.04 0.91 4.00 0.11 1.00 0.03 0.00 3.11 0.86 4.00 0.16 1.00 0.02 0.00 3.12 0.86 4.00 0.09 1.00 0.02 0.00 2.97 1.01 4.00 0.10 1.00 0.02 0.00 3.17 0.81 4.00 0.08 1.00 0.01 0.00 3.29 0.71 4.00 0.04 1.00 0.07 0.00 2.59 1.34 4.00 0.06 1.00 0.08 0.00 2.75 1.16 4.00 0.19 1.00 0.06 0.03 2.68 1.23 4.00 0.19 1.00 0.00 0.00 2.83 1.17 4.00 0.04 1.00 0.08 0.00 2.57 1.34 4.00 0.02 1.00 0.05 0.00 2.55 1.40 4.00 0.04 1.00 0.08 0.01 2.53 1.38 4.00 0.10 1.00 0.03 0.00 2.82 1.15 4.00 0.01 1.00 0.06 0.00 2.54 1.39 4.00 0.02 1.00 0.04 0.00 2.55 1.41 4.00 0.10 1.00 0.08 0.00 2.62 1.30 4.00 0.15 1.00 0.01 0.00 2.65 1.33 4.00 0.10 1.00 0.02 0.00 2.72 1.26 4.00 0.06 1.00 0.09 0.00 2.64 1.27 4.00 0.08 1.00 0.08 0.00 2.69 1.22 4.00 0.05 1.00 0.08 0.00 2.71 1.21 4.00 0.16 1.00 0.02 0.00 2.68 1.29 4.00 0.08 1.00 0.05 0.01 2.67 1.27 4.00 0.06 1.00 0.07 0.00 2.58 1.35 4.00 0.04 1.00 0.05 0.00 2.60 1.35 4.00 0.41 1.00 0.02 0.00 3.10 0.89 4.00 0.36 1.00 0.02 0.00 3.09 0.89 4.00 0.04 1.00 0.08 0.00 3.19 0.73 4.00 0.05 1.00 0.08 0.00 3.21 0.71 4.00 0.02 1.00 0.06 0.00 3.19 0.74 4.00 0.02 1.00 0.07 0.00 3.17 0.76 4.00 0.24 1.00 0.02 0.06 3.00 0.92 4.00 0.03 1.00 0.18 0.00 2.52 1.30 4.00 0.09 1.00 0.03 0.01 2.82 1.14 4.00 0.03 1.00 0.15 0.00 2.55 1.30 4.00 0.01 1.00 0.07 0.01 2.74 1.19 4.00 0.04 1.00 0.14 0.00 2.52 1.34 4.00 0.13 1.00 0.02 0.01 2.82 1.15 4.00 0.00 1.00 0.15 0.01 2.46 1.38 4.00 0.01 1.00 0.11 0.00 2.52 1.37 4.00 0.01 1.00 0.09 0.00 2.43 1.48 4.00 0.04 1.00 0.08 0.00 3.01 0.92 4.00 0.04 1.00 0.06 0.00 3.01 0.92 4.00 0.10 1.00 0.00 0.00 2.95 1.05 4.00 0.11 1.00 0.02 0.00 3.03 0.95 4.00 0.07 1.00 0.02 0.00 2.87 1.11 4.00 0.06 1.00 0.00 0.00 3.14 0.85 4.00 0.06 1.00 0.02 0.00 3.00 0.97 4.00 0.02 1.00 0.07 0.00 2.82 1.11 4.00 0.07 1.00 0.03 0.00 2.74 1.23 4.00 0.03 1.00 0.13 0.00 2.45 1.42 4.00 0.03 1.00 0.04 0.00 2.58 1.37 4.00 0.04 1.00 0.05 0.00 2.82 1.12 4.00 0.03 1.00 0.03 0.00 2.75 1.22 4.00 0.03 1.00 0.05 0.00 2.60 1.35 4.00 0.08 1.00 0.04 0.00 2.85 1.11 4.00 0.03 1.00 0.04 0.00 2.67 1.28 4.00 0.02 1.00 0.05 0.00 2.62 1.32 4.00 0.02 1.00 0.06 0.00 2.58 1.36 4.00 0.00 1.00 0.01 0.00 2.99 1.00 4.00 0.03 1.00 0.01 0.01 2.87 1.11 4.00 0.05 1.00 0.05 0.00 2.81 1.14 4.00 0.02 1.00 0.03 0.00 2.56 1.41 4.00 0.14 1.00 0.06 0.03 2.11 1.81 4.00 0.16 1.00 0.03 0.03 2.09 1.86 4.00 0.19 1.00 0.02 0.00 2.15 1.82 4.00 0.22 1.00 0.03 0.00 2.20 1.77 4.00 0.21 1.00 0.01 0.00 2.08 1.91 4.00 0.15 1.00 0.00 0.00 2.10 1.90 4.00 0.16 1.00 0.02 0.03 2.10 1.85 4.00 0.11 1.00 0.00 0.01 2.20 1.79 4.00 0.17 1.00 0.00 0.01 2.19 1.80 4.00 0.08 1.00 0.04 0.03 2.09 1.85 4.00 0.12 1.00 0.03 0.01 2.24 1.72 4.00 0.16 1.00 0.00 0.00 2.21 1.78 4.00 0.10 1.00 0.01 0.04 1.81 2.14 4.00 0.04 1.00 0.02 0.02 2.26 1.70 4.00 0.10 1.00 0.04 0.01 2.30 1.64 4.00 0.07 1.00 0.08 0.02 2.26 1.65 4.00 0.07 1.00 0.05 0.02 2.26 1.67 4.00 0.10 1.00 0.01 0.00 2.41 1.58 4.00 0.08 1.00 0.05 0.02 1.98 1.95 4.00 0.13 1.00 0.03 0.01 2.15 1.81 4.00 0.04 1.00 0.00 0.01 2.23 1.77 4.00 0.12 1.00 0.03 0.01 2.12 1.84 4.00 0.03 1.00 0.03 0.01 2.27 1.70 4.00 0.08 1.00 0.01 0.01 1.99 1.99 4.00 0.09 1.00 0.03 0.01 2.14 1.81 4.00 0.07 1.00 0.01 0.00 2.35 1.64 4.00 0.08 1.00 0.03 0.02 2.26 1.70 4.00 0.04 1.00 0.08 0.02 2.21 1.69 4.00 0.08 1.00 0.04 0.02 2.11 1.83 4.00 0.18 1.00 0.00 0.01 2.01 1.97 4.00 0.02 1.00 0.03 0.00 2.20 1.77 4.00 0.05 1.00 0.07 0.00 2.11 1.83 4.00 0.01 1.00 0.08 0.00 2.06 1.86 4.00 0.04 1.00 0.08 0.00 2.22 1.70 4.00 0.04 1.00 0.04 0.00 2.11 1.85 4.00 0.00 1.00 0.05 0.00 2.04 1.91 4.00 0.02 1.00 0.09 0.00 2.02 1.89 4.00 0.03 1.00 0.05 0.00 2.04 1.91 4.00 0.02 1.00 0.04 0.00 2.06 1.90 4.00 0.05 1.00 0.05 0.00 2.10 1.85 4.00 0.09 1.00 0.02 0.00 2.43 1.56 4.00 0.08 1.00 0.02 0.00 2.08 1.90 4.00 0.09 1.00 0.00 0.00 2.36 1.64 4.00 0.09 1.00 0.00 0.00 3.01 0.99 4.00 0.23 1.00 0.00 0.00 3.10 0.90 4.00 0.20 1.00 0.00 0.00 3.15 0.85 4.00 0.07 1.00 0.00 0.00 3.09 0.91 4.00 0.15 1.00 0.00 0.00 3.02 0.98 4.00 0.15 1.00 0.01 0.00 3.01 0.98 4.00 0.21 1.00 0.00 0.00 3.10 0.90 4.00 0.14 1.00 0.01 0.00 3.00 0.99 4.00 0.15 1.00 0.00 0.01 3.18 0.81 4.00 0.16 1.00 0.00 0.00 3.16 0.84 4.00 0.16 1.00 0.01 0.03 3.08 0.89 4.00 0.14 1.00 0.03 0.01 3.10 0.87 4.00 0.15 1.00 0.04 0.04 2.95 0.97 4.00 0.16 1.00 0.02 0.02 2.97 0.99 4.00 0.45 1.00 0.04 0.00 3.06 0.91 4.00 0.06 1.00 0.03 0.00 2.93 1.05 4.00 0.14 1.00 0.00 0.00 2.93 1.07 4.00 0.09 1.00 0.02 0.00 3.02 0.96 4.00 0.13 1.00 0.03 0.02 2.96 0.98 4.00 0.05 1.00 0.03 0.00 3.10 0.87 4.00 0.12 1.00 0.01 0.01 2.89 1.10 4.00 0.14 1.00 0.03 0.02 2.91 1.04 4.00 0.18 1.00 0.03 0.01 2.92 1.05 4.00 0.13 1.00 0.03 0.00 2.98 0.99 4.00 0.44 1.00 0.01 0.00 3.05 0.93 4.00 0.24 1.00 0.01 0.00 3.31 0.68 4.00 0.06 1.00 0.01 0.00 3.38 0.61 4.00 0.17 1.00 0.01 0.00 2.87 1.12 4.00 0.13 1.00 0.03 0.00 2.93 1.05 4.00 0.16 1.00 0.04 0.00 3.16 0.80 4.00 0.28 1.00 0.02 0.00 3.15 0.83 4.00 0.29 1.00 0.01 0.00 3.19 0.80 4.00 0.17 1.00 0.01 0.00 3.18 0.81 4.00 0.11 1.00 0.00 0.00 3.09 0.91 4.00 0.12 1.00 0.01 0.00 2.98 1.01 4.00 0.21 1.00 0.04 0.01 2.92 1.04 4.00 0.14 1.00 0.02 0.00 3.03 0.95 4.00 0.13 1.00 0.03 0.00 3.06 0.91 4.00 0.22 1.00 0.02 0.00 3.26 0.71 4.00 0.09 1.00 0.02 0.00 3.35 0.62 4.00 0.13 1.00 0.00 0.00 3.36 0.64 4.00 0.12 1.00 0.02 0.00 3.26 0.72 4.00 0.08 1.00 0.03 0.01 3.17 0.79 4.00 0.11 1.00 0.03 0.00 3.01 0.95 4.00 0.18 1.00 0.02 0.00 3.11 0.87 4.00 0.12 1.00 0.04 0.00 3.16 0.80 4.00 0.18 1.00 0.02 0.00 2.94 1.03 4.00 0.28 1.00 0.04 0.00 2.97 0.99 4.00 0.14 1.00 0.04 0.01 2.98 0.97 4.00 0.13 1.00 0.01 0.00 3.01 0.98 4.00 0.12 1.00 0.04 0.00 2.97 0.99 4.00 0.26 1.00 0.04 0.00 2.95 1.01 4.00 0.21 1.00 0.05 0.00 3.02 0.93 4.00 0.18 1.00 0.03 0.00 2.81 1.16 4.00 0.08 1.00 0.03 0.00 3.04 0.93 4.00 0.15 1.00 0.01 0.00 3.01 0.98 4.00 0.28 1.00 0.02 0.00 2.80 1.18 4.00 0.22 1.00 0.01 0.03 2.76 1.20 4.00 0.24 1.00 0.00 0.00 2.99 1.01 4.00 0.16 1.00 0.02 0.01 2.84 1.13 4.00 0.28 1.00 0.02 0.00 2.92 1.06 4.00 0.19 1.00 0.02 0.00 2.91 1.07 4.00 0.21 1.00 0.00 0.00 2.97 1.03 4.00 0.29 1.00 0.00 0.00 2.94 1.06 4.00 0.25 1.00 0.01 0.00 2.97 1.02 4.00 0.21 1.00 0.02 0.00 2.97 1.01 4.00 0.24 1.00 0.00 0.00 2.95 1.04 4.00 0.17 1.00 0.05 0.01 2.83 1.11 4.00 0.16 1.00 0.01 0.00 2.81 1.18 4.00 0.23 1.00 0.00 0.00 3.03 0.97 4.00 0.20 1.00 0.01 0.00 2.95 1.04 4.00 0.19 1.00 0.01 0.00 3.06 0.93 4.00 0.29 1.00 0.01 0.01 2.84 1.13 4.00 0.43 1.00 0.02 0.02 2.78 1.18 4.00 0.24 1.00 0.00 0.00 2.93 1.07 4.00 0.25 1.00 0.01 0.00 2.90 1.09 4.00 0.33 1.00 0.02 0.01 2.86 1.11 4.00 0.18 1.00 0.04 0.01 2.73 1.23 4.00 0.35 1.00 0.02 0.01 2.81 1.16 4.00 0.15 1.00 0.02 0.00 2.79 1.19 4.00 0.17 1.00 0.00 0.00 2.81 1.19 4.00 0.31 1.00 0.01 0.01 2.88 1.10 4.00 0.29 1.00 0.04 0.01 2.76 1.19 4.00 0.35 1.00 0.01 0.01 2.80 1.18 4.00 0.15 1.00 0.02 0.00 2.80 1.18 4.00 0.19 1.00 0.03 0.00 2.77 1.19 4.00 0.41 1.00 0.01 0.02 2.66 1.30 4.00 0.31 1.00 0.02 0.01 2.72 1.26 4.00 0.21 1.00 0.00 0.01 2.78 1.21 4.00 0.45 1.00 0.00 0.02 2.75 1.24 4.00 0.24 1.00 0.04 0.00 2.77 1.19 4.00 0.17 1.00 0.02 0.00 2.79 1.19 4.00 0.33 1.00 0.02 0.00 2.84 1.14 4.00 0.20 1.00 0.00 0.00 2.78 1.21 4.00 0.17 1.00 0.04 0.04 2.69 1.23 4.00 0.29 1.00 0.03 0.01 2.94 1.03 4.00 0.26 1.00 0.01 0.00 2.80 1.18 4.00 0.11 1.00 0.03 0.00 2.98 0.99 4.00 0.52 1.00 0.02 0.00 2.97 1.02 4.00 0.15 1.00 0.00 0.00 2.86 1.14 4.00 0.48 1.00 0.03 0.00 3.02 0.96 4.00 0.23 1.00 0.02 0.00 2.94 1.04 4.00 0.13 1.00 0.03 0.00 2.85 1.13 4.00 0.26 1.00 0.00 0.00 2.95 1.05 4.00 0.36 1.00 0.01 0.00 2.99 1.00 4.00 0.19 1.00 0.03 0.00 2.98 0.99 4.00 0.24 1.00 0.04 0.01 2.84 1.11 4.00 0.18 1.00 0.04 0.01 2.88 1.08 4.00 0.19 1.00 0.03 0.00 2.87 1.10 4.00 0.15 1.00 0.02 0.00 3.27 0.71 4.00 0.25 1.00 0.00 0.00 3.37 0.63 4.00 0.29 1.00 0.22 0.00 2.81 0.96 4.00 0.21 1.00 0.02 0.00 2.97 1.01 4.00 0.18 1.00 0.06 0.02 3.27 0.65 4.00 0.18 1.00 0.03 0.01 3.01 0.96 4.00 0.17 1.00 0.02 0.00 3.44 0.54 4.00 0.17 1.00 0.01 0.00 3.23 0.76 4.00 0.16 1.00 0.02 0.00 3.36 0.62 4.00 0.15 1.00 0.01 0.01 2.83 1.16 4.00 0.28 1.00 0.01 0.00 3.20 0.79 4.00 0.29 1.00 0.02 0.01 2.94 1.04 4.00 0.32 1.00 0.00 0.01 2.84 1.15 4.00 0.61 1.00 0.04 0.01 3.04 0.91 4.00 0.38 1.00 0.00 0.01 2.95 1.04 4.00 0.33 1.00 0.02 0.01 2.80 1.16 4.00 0.40 1.00 0.04 0.00 3.09 0.87 4.00 0.41 1.00 0.04 0.00 2.96 1.00 4.00 0.33 1.00 0.06 0.00 3.01 0.93 4.00 0.37 1.00 0.05 0.00 2.97 0.97 4.00 0.31 1.00 0.03 0.00 3.00 0.97 4.00 0.48 1.00 0.03 0.01 2.97 0.99 4.00 0.52 1.00 0.03 0.00 2.93 1.04 4.00 0.34 1.00 0.04 0.00 3.03 0.93 4.00 0.43 1.00 0.00 0.00 2.96 1.04 4.00 0.47 1.00 0.01 0.00 2.99 0.99 4.00 0.52 1.00 0.02 0.00 2.98 0.99 4.00 0.50 1.00 0.04 0.00 2.95 1.01 4.00 Table A3. Chemical analyses of framework silicates and andalusite from Copiapó, Chile

Locality Sample Spot no. Analysis no. Mineral SiO2 TiO2 Al2O3 Cr2O3 Fe2O3 FeO Cerro Bronce Estrella C2B-298 1 p1 Oligoclase 64.61 0.00 20.90 0.00 1.07 0.00 Cerro Buitre Radio Tower C2B-287 1 p1 Albite 68.78 0.02 19.95 0.00 0.00 0.00 Cerro Buitre Radio Tower C2B-287 1 p2 Albite 68.44 0.01 19.95 0.00 0.01 0.00 Cerro Buitre Radio Tower C2B-287 1 p3 Albite 68.28 0.01 20.05 0.00 0.03 0.00 Cerro Buitre Radio Tower C2B-287 2 t7 Albite 68.37 0.03 20.11 0.00 0.16 0.00 Cerro Buitre Radio Tower C2B-287 2 p1 Albite 68.18 0.00 20.04 0.00 0.06 0.00 Cerro Buitre Radio Tower C2B-287 2 p2 Albite 68.15 0.00 19.89 0.00 0.05 0.00 Cerro Buitre Radio Tower C2B-287 2 p3 Albite 68.76 0.01 19.92 0.01 0.08 0.00 Cerro Buitre Radio Tower C2B-287 2 p5 Albite 68.84 0.01 19.93 0.00 0.02 0.00 Cerro Buitre Radio Tower C2B-576c 1 m1 K-feldspar 62.93 0.01 18.52 0.00 0.13 0.00 Cerro Buitre Radio Tower C2B-576c 1 k1 K-feldspar 63.69 0.01 18.76 0.00 0.05 0.00 Cerro Buitre Radio Tower C2B-576c 2 k1 K-feldspar 63.89 0.11 17.97 0.00 0.85 0.00 Cerro Buitre Radio Tower C2B-576c 2 k1-1 K-feldspar 61.52 0.05 19.79 0.01 0.43 0.00 Cerro Buitre Radio Tower C2B-576c 2 t4 Oligoclase 59.65 0.00 24.81 0.00 0.00 0.09 Cerro Buitre Radio Tower C2J-124 1 p1 Albite 68.41 0.00 19.67 0.00 0.17 0.00 Cerro Buitre Radio Tower C2J-124 1 t9 Albite 67.88 0.01 20.25 0.00 0.24 0.00 Cerro Buitre Radio Tower C2J-124 3 tour2bp Albite 68.43 0.00 19.81 0.00 0.15 0.00 Cerro Buitre Radio Tower C2J-334 1 k1 K-feldspar 62.21 0.05 17.27 0.00 0.00 1.74 Cerro Buitre Radio Tower C2J-334 1 m1 K-feldspar 64.71 0.03 19.04 0.00 0.05 0.00 Cerro Buitre Radio Tower C2J-334 1 p1 K-feldspar 64.38 0.03 18.79 0.00 0.03 0.00 Cerro Buitre Radio Tower C2J-334 1 k2 K-feldspar 63.46 0.01 18.34 0.01 0.32 0.27 Cerro Buitre Radio Tower C2J-334 1 p4 Oligoclase 62.64 0.02 23.18 0.00 0.15 0.00 Cerro Buitre Radio Tower C2J-334 2 p1 K-feldspar 62.71 0.01 17.91 0.00 0.00 0.45 Cerro Buitre Radio Tower C2J-334 2 p2 Andesine 55.28 0.06 27.52 0.01 0.28 0.12 Cerro Buitre Radio Tower C2J-334 2 p3 Andesine 55.08 0.06 27.90 0.00 0.37 0.00 Cerro Buitre Radio Tower C2J-334 2 p4 Albite 53.91 0.12 27.95 0.00 0.10 0.16 Cerro Buitre Radio Tower C2J-334 2 p5 K-feldspar 63.31 0.02 18.43 0.01 0.07 0.00 Cerro Buitre Radio Tower C2J-334 2 p6 Albite 59.61 0.03 25.53 0.00 0.07 0.00 Cerro Buitre Radio Tower C2J-334 2 p7 K-feldspar 64.12 0.05 18.65 0.00 0.12 0.00 Cerro Buitre Radio Tower C2J-334 3 p1 K-feldspar 64.38 0.04 18.73 0.00 0.18 0.00 Cerro Buitre Radio Tower C2J-334 3 p2 Oligoclase 61.63 0.03 24.18 0.00 0.10 0.00 Cerro Buitre Radio Tower C2J-334 3 p3 K-feldspar 64.13 0.07 19.16 0.00 0.12 0.00 Cerro Buitre Radio Tower C2J-334 3 m3 K-feldspar 64.05 0.03 18.56 0.00 0.05 0.00 Cerro Buitre Radio Tower C2J-334 3 p4 Oligoclase 61.36 0.02 24.51 0.00 0.20 0.00 Cerro Buitre Radio Tower C2J-334 3 a3 K-feldspar 63.72 0.02 18.62 0.00 0.05 0.00 Cerro Buitre Radio Tower C2J-334 3 p5 K-feldspar 64.12 0.04 18.56 0.01 0.07 0.00 Cerro Granate C3B-072a 2 q1 Albite 69.41 0.00 19.93 0.00 0.08 0.00 Cerro Granate C3B-072a 3 p1 Albite 68.35 0.01 19.96 0.00 0.15 0.00 Cerro Negro Norte C6B-076 1 t2 Albite 67.05 0.02 21.08 0.00 0.46 0.00 Cerro Negro Norte C6B-076 1 p1 Albite 65.77 0.02 21.29 0.00 0.49 0.00 Cerro Negro Norte C6B-076 2 k2 Albite 66.89 0.00 20.56 0.00 0.00 0.06 Cerro Negro Norte C6B-076 3 p1 Albite 65.42 0.01 21.76 0.00 0.37 0.00 Cerro Negro Norte C6B-076 3 p2 Oligoclase 61.56 0.00 23.99 0.00 0.26 0.00 Cerro Negro Norte C6B-076 3 p3 Oligoclase 61.31 0.01 24.26 0.00 0.29 0.00 Cerro Negro Norte C6B-076 4 p1 Oligoclase 64.96 0.01 22.06 0.00 0.10 0.00 Cerro Negro Norte C6B-076 4 p2 Oligoclase 61.79 0.01 24.19 0.00 0.20 0.00 Española C3B-381a 2 p1 Albite 68.17 0.02 20.13 0.00 0.28 0.00 Española C3B-381a 3 p1 Albite 68.30 0.00 19.92 0.00 0.22 0.00 Española C3B-381a 3 p2 Albite 67.98 0.01 19.68 0.00 0.06 0.00 Española C3B-381a 3 p3 Albite 69.40 0.01 20.04 0.00 0.10 0.00 Falla Ojancos Transito San Francisco C6B-101b 1 p1 Albite 67.41 0.02 20.29 0.00 0.09 0.00 Falla Ojancos Transito San Francisco C6B-101b 1 k1 K-feldspar 64.12 0.00 18.60 0.01 0.00 0.00 Falla Ojancos Transito San Francisco C6B-101b 2 k1 K-feldspar 64.46 0.00 18.65 0.00 0.01 0.00 Falla Ojancos Transito San Francisco C6B-101b 2 p1 Albite 68.89 0.00 20.37 0.00 0.08 0.00 Jesus Maria C7B-003a 3 t5 Andalusite 36.05 0.02 61.83 0.00 2.59 0.00 Ojancos Viejo C3B-429.5 1 q2 Albite 68.59 0.00 20.29 0.00 0.11 0.00 Ojancos Viejo C3B-429.5 1 p1 Albite 69.74 0.00 20.24 0.00 0.13 0.00 Ojancos Viejo C3B-429.5 1 p2 K-feldspar 64.57 0.00 19.27 0.00 0.04 0.00 Ojancos Viejo C3B-429.5 1 p3 Albite 68.31 0.02 20.44 0.00 0.10 0.00 Ojancos Viejo C3B-429.5 1 p4 Albite 68.10 0.00 20.63 0.00 0.17 0.00 Ojancos Viejo C3B-429.5 2 p1 Albite 68.87 0.02 20.20 0.00 0.30 0.00 Ojancos Viejo C3B-429.5 2 p2 Albite 68.16 0.00 20.33 0.00 0.13 0.00 Ojancos Viejo C3B-429.5 2 p3 Albite 68.18 0.02 20.44 0.00 0.09 0.00 Ojancos Viejo C3B-429.5 2 p4 Albite 67.90 0.00 20.43 0.00 0.19 0.00 Ojancos Viejo C3B-429.5 2 p5 Albite 68.48 0.00 20.41 0.00 0.11 0.00 Ojancos Viejo C3B-429.5 2 p6 Albite 68.76 0.02 20.44 0.00 0.11 0.00 Ojancos Viejo C3B-429.5 2 p7 Albite 67.88 0.00 20.52 0.00 0.14 0.00 Ojancos Viejo C3B-429.5 2 p8 Albite 68.33 0.02 20.33 0.00 0.30 0.00 Ojancos Viejo C3B-429.5 2 p9 Albite 68.14 0.00 20.65 0.00 0.27 0.00 San Gregorio S Granate C2B-352e 1 t1 Albite 68.82 0.00 20.00 0.00 0.07 0.00 San Gregorio S Granate C2B-352e 1 q1 Albite 69.04 0.01 20.12 0.00 0.04 0.00 San Gregorio S Granate C2B-352e 1 p1 Albite 67.87 0.02 20.18 0.01 0.06 0.00 San Gregorio S Granate C2B-352e 1 p2 K-feldspar 64.16 0.00 18.57 0.00 0.07 0.00 San Gregorio S Granate C2B-352e 1 p2 Oligoclase 62.77 0.00 23.83 0.00 0.00 0.00 San Gregorio S Granate C2B-352e 1 p3 K-feldspar 64.55 0.01 18.62 0.00 0.08 0.00 San Gregorio S Granate C2B-352e 2 p1 Albite 68.21 0.01 20.48 0.00 0.07 0.00 San Gregorio S Granate C2B-352e 2 p3 K-feldspar 64.65 0.00 18.68 0.01 0.08 0.00 San Gregorio S Granate C2B-352e 2 p5 K-feldspar 64.11 0.00 18.62 0.00 0.04 0.00 San Gregorio S Granate C2B-352e 2 k1 K-feldspar 64.04 0.00 18.64 0.00 0.07 0.00 San Gregorio S Granate C2B-352e 2 k2 K-feldspar 64.13 0.03 18.65 0.00 0.40 0.00 San Gregorio S Granate C2B-352e 3 k1 K-feldspar 64.08 0.00 18.71 0.00 0.04 0.00 San Gregorio S Granate C2B-352e 3 k2 K-feldspar 64.12 0.00 18.40 0.00 0.11 0.00 San Gregorio S Granate C2B-352e 3 t2 K-feldspar 64.48 0.01 18.66 0.00 0.32 0.00 San Gregorio S Granate C2B-352e 3 p1 Albite 68.69 0.00 20.08 0.00 0.23 0.00 San Gregorio S Granate C2B-352e 3 p2 Albite 68.37 0.01 20.24 0.00 0.23 0.00 San Gregorio S Granate C2B-352e 3 p3 Albite 68.93 0.01 19.90 0.00 0.22 0.00 San Gregorio S Granate C2B-352e 3 t5 K-feldspar 64.17 0.00 18.56 0.00 0.26 0.00 San Gregorio S Granate C2B-352e 3 t6 K-feldspar 64.07 0.01 18.56 0.00 0.25 0.00 San Gregorio S Granate C2B-352e 3 p4 Albite 68.93 0.00 19.99 0.00 0.02 0.00 San Gregorio S Granate C2B-352e 4 p1 Albite 68.85 0.01 19.96 0.01 0.08 0.00 San Gregorio S Granate C2B-352e 4 p2 Albite 68.56 0.00 19.99 0.00 0.04 0.00 San Gregorio S Granate C2B-352e 4 p3 Albite 68.84 0.01 19.99 0.00 0.17 0.00 San Gregorio S Granate C2B-352e 4 k1 K-feldspar 64.02 0.01 18.43 0.00 0.08 0.00 San Gregorio S Granate C2B-352e 4 k2 K-feldspar 64.32 0.00 18.70 0.01 0.07 0.00 San Gregorio S Granate C2B-352e 4 k3 K-feldspar 63.70 0.00 18.79 0.00 0.15 0.00 San Gregorio S Granate C2B-655 1 p1 Albite 68.65 0.00 19.80 0.00 0.29 0.00 San Gregorio S Granate C2B-655 1 p2 Albite 67.39 0.00 19.97 0.01 0.07 0.00 San Gregorio S Granate C2B-671 1 p1 Albite 67.84 0.00 19.93 0.00 0.04 0.00 San Gregorio S Granate C2B-808.2 1 p1 Andesine 59.98 0.05 25.44 0.01 0.21 0.00 San Gregorio S Granate C2B-808.2 2 p1 Andesine 60.45 0.05 25.34 0.01 0.23 0.00 San Gregorio S Granate C2B-808.2 2 p2 Andesine 59.68 0.03 25.85 0.00 0.21 0.00 San Gregorio S Granate C2B-808.2 2 p3 K-feldspar 64.83 0.07 19.27 0.00 0.05 0.00 San Gregorio S Granate C2B-808.2 3 p1 Andesine 60.01 0.04 25.25 0.00 0.22 0.00 San Gregorio S Granate C2B-808.2 3 k1 K-feldspar 64.03 0.00 18.80 0.00 0.08 0.00 San Gregorio S Granate C2B-808.2 3 k2 K-feldspar 65.03 0.00 18.82 0.00 0.11 0.00 Santos PdC DDH289-037.5a 3 p1 Albite 69.19 0.00 20.01 0.00 0.11 0.00 Santos PdC DDH289-037.5a 3 p2 Albite 69.64 0.02 20.16 0.00 0.24 0.00 Santos PdC DDH384-004.2 1 k1 K-feldspar 63.30 0.00 18.46 0.00 0.07 0.00 Santos PdC DDH384-004.2 2 k1 K-feldspar 63.88 0.00 18.55 0.00 0.07 0.00 Santos PdC DDH628-094.2 1 k1 K-feldspar 64.18 0.00 18.57 0.01 0.30 0.00 Santos PdC DDH628-151.6 1 k1 K-feldspar 63.67 0.02 18.37 0.00 0.24 0.00 Santos PdC DDH628-626.3 1 k1 K-feldspar 63.79 0.00 18.44 0.00 0.00 0.00 Santos PdC DDH628-626.3 1 p1 K-feldspar 65.44 0.00 19.02 0.00 0.57 0.00 Santos PdC DDH628-626.3 1 p2 K-feldspar 66.32 0.00 18.61 0.00 0.46 0.00 Santos PdC DDH628-626.3 1 sc1 K-feldspar 65.82 0.00 18.87 0.00 0.16 0.00 Santos PdC DDH628-626.3 1 sc2 K-feldspar 65.71 0.01 18.74 0.00 0.23 0.00 Santos PdC DDH628-626.3 1 sc3 K-feldspar 66.19 0.00 19.27 0.00 0.47 0.00 Santos PdC DDH628-626.3 1 sc4 K-feldspar 65.82 0.01 18.77 0.00 0.27 0.00 Santos PdC DDH628-626.3 1 sc5 K-feldspar 65.13 0.00 18.89 0.00 0.13 0.00 Santos PdC DDH628-626.3 1 sc6 K-feldspar 65.65 0.01 18.74 0.00 0.24 0.00 Santos PdC DDH628-626.3 1 sc1 Scapolite 57.02 0.00 22.12 0.00 0.00 0.10 Santos PdC DDH628-626.3 1 sc2 Scapolite 56.73 0.00 22.29 0.00 0.00 0.03 Santos PdC DDH628-626.3 1 sc3 Scapolite 56.95 0.00 22.21 0.00 0.00 0.12 Santos PdC DDH628-626.3 2 t1 Andesine 59.15 0.00 26.92 0.00 0.28 0.00 Santos PdC DDH628-626.3 2 t2 K-feldspar 62.72 0.01 19.42 0.00 1.17 0.00 Santos PdC DDH628-626.3 2 t3 K-feldspar 64.14 0.01 19.88 0.00 0.39 0.00 Santos PdC DDH628-626.3 2 t4 Oligoclase 64.19 0.01 23.73 0.00 0.32 0.00 Santos PdC DDH643-595.5 2 m1 K-feldspar 63.77 0.00 18.48 0.00 0.13 0.00 Santos PdC DDH684-079.8 2 t2 K-feldspar 63.20 0.00 18.59 0.01 0.14 0.00 Santos PdC DDH684-079.8 3 k1 K-feldspar 63.58 0.02 18.48 0.00 0.26 0.00 Santos PdC ME013-538 1 k1 K-feldspar 64.05 0.00 18.74 0.00 0.10 0.00 Santos PdC ME013-538 1 p1 Andesine 58.68 0.02 26.23 0.00 0.19 0.00 Santos PdC ME013-538 2 p1 Albite 68.42 0.00 20.29 0.00 0.24 0.00 Vinita Azul C6B-160b 1 a1 Andalusite 35.25 0.02 64.81 0.00 0.68 0.00 Vinita Azul C6B-160b 1 a3 Andalusite 35.77 0.02 64.42 0.01 0.65 0.00 Vinita Azul C6B-160b 2 a1 Andalusite 36.10 0.00 64.11 0.01 0.63 0.00 Vinita Azul C6B-160b 2 a2 Andalusite 36.23 0.00 63.81 0.00 0.79 0.00 Vinita Azul C6B-160b 2 a3 Andalusite 36.04 0.01 64.19 0.00 0.91 0.00 Vinita Azul C6B-160b 2 a4 Andalusite 35.69 0.01 64.55 0.01 0.63 0.00 3+ MgO MnO CaO Na2OK2O F Cl Subtotal O=F+Cl Total Si Fe Al Sum Na K 0.10 0.00 2.20 10.22 0.14 0.04 0.08 99.36 -0.03 99.32 2.87 0.04 1.09 4.00 0.88 0.01 0.00 0.01 0.14 11.67 0.05 0.00 0.07 100.71 -0.02 100.70 2.98 0.00 1.02 4.00 0.05 0.90 0.00 0.01 0.09 11.55 0.04 0.03 0.00 100.14 -0.01 100.13 2.98 0.00 1.02 4.00 0.98 0.00 0.00 0.01 0.09 11.78 0.03 0.01 0.05 100.33 -0.01 100.32 2.98 0.00 1.02 4.00 0.97 0.00 0.00 0.17 0.17 11.59 0.04 0.03 0.02 100.71 -0.02 100.69 3.98 0.00 0.02 4.00 0.00 0.00 0.00 0.02 0.21 11.70 0.07 0.01 0.08 100.38 -0.02 100.36 2.97 0.01 1.03 4.00 0.97 0.00 0.00 0.00 0.03 11.57 0.03 0.03 0.00 99.75 -0.01 99.73 2.97 0.00 1.03 4.00 0.99 0.00 0.00 0.00 0.11 11.60 0.05 0.01 0.02 100.58 -0.01 100.57 2.97 0.00 1.02 4.00 0.98 0.00 0.00 0.00 0.03 11.64 0.05 0.02 0.00 100.56 -0.01 100.55 3.99 0.00 0.01 4.00 0.00 0.00 0.00 0.00 0.00 1.01 15.29 0.03 0.02 97.94 -0.02 97.92 2.97 0.00 1.03 4.00 0.09 0.92 0.00 0.01 0.00 1.21 15.12 0.00 0.00 98.86 0.00 98.86 2.97 0.00 1.03 4.00 0.11 0.90 0.15 0.02 0.01 0.80 14.83 0.02 0.01 98.65 -0.01 98.64 2.98 0.03 0.99 4.00 0.07 0.88 0.09 0.02 0.00 1.11 14.65 0.05 0.00 97.71 -0.02 97.69 2.89 0.02 1.10 4.00 0.10 0.88 0.00 0.00 6.15 8.25 0.19 0.02 0.00 99.17 -0.01 99.16 2.68 0.00 1.32 4.00 0.72 0.01 0.00 0.09 0.16 10.57 0.10 0.00 1.14 100.34 -0.26 100.08 2.98 0.01 1.01 4.00 0.89 0.01 0.21 0.01 0.09 10.24 0.06 0.04 0.03 99.09 -0.02 99.07 2.95 0.01 1.04 4.00 0.86 0.00 0.01 0.01 0.22 10.28 0.05 0.06 0.27 99.31 -0.09 99.22 2.98 0.00 1.02 4.00 0.87 0.00 1.33 0.06 1.20 0.82 13.83 0.08 0.01 98.61 -0.03 98.58 2.96 0.00 1.04 4.00 0.08 0.84 0.00 0.01 0.12 2.38 12.96 0.04 0.25 99.59 -0.07 99.52 2.97 0.00 1.03 4.00 0.21 0.76 0.01 0.00 0.03 1.30 14.69 0.00 0.02 99.29 0.00 99.29 2.97 0.00 1.02 4.00 0.12 0.87 0.26 0.02 0.34 0.97 14.78 0.00 0.00 98.81 0.00 98.81 2.97 0.01 1.02 4.00 0.09 0.88 0.01 0.02 4.45 8.73 0.12 0.00 0.02 99.37 0.00 99.37 2.78 0.00 1.21 4.00 0.75 0.01 0.25 0.00 0.27 1.02 14.66 0.04 0.01 97.33 -0.02 97.31 2.98 0.00 1.02 4.00 0.09 0.89 0.02 0.02 9.59 6.12 0.15 0.00 0.07 99.26 -0.02 99.25 2.51 0.01 1.48 4.00 0.54 0.01 0.01 0.00 9.86 5.92 0.14 0.00 0.03 99.37 -0.01 99.36 2.50 0.01 1.49 4.00 0.52 0.01 0.02 0.01 10.18 5.68 0.17 0.03 0.03 98.38 -0.02 98.36 2.47 0.00 1.52 4.00 0.51 0.01 0.00 0.00 0.01 0.77 15.48 0.03 0.04 98.16 -0.02 98.14 2.98 0.00 1.02 4.00 0.07 0.93 0.01 0.00 6.86 7.75 0.09 0.00 0.03 99.98 -0.01 99.97 2.66 0.00 1.34 4.00 0.67 0.01 0.00 0.02 0.01 1.06 14.98 0.01 0.00 99.04 0.00 99.04 2.97 0.00 1.02 4.00 0.10 0.89 0.01 0.00 0.03 1.12 14.93 0.00 0.01 99.44 0.00 99.44 2.97 0.01 1.02 4.00 0.10 0.88 0.00 0.01 5.48 8.21 0.13 0.02 0.01 99.79 -0.01 99.78 2.73 0.00 1.26 4.00 0.71 0.01 0.00 0.01 0.42 1.78 13.71 0.05 0.00 99.47 -0.02 99.45 2.95 0.00 1.04 4.00 0.16 0.81 0.01 0.01 0.03 0.97 15.22 0.03 0.07 99.04 -0.03 99.02 2.98 0.00 1.02 4.00 0.09 0.90 0.01 0.03 5.62 8.35 0.14 0.04 0.00 100.30 -0.02 100.29 2.71 0.01 1.28 4.00 0.72 0.01 0.00 0.00 0.02 0.75 15.39 0.00 0.04 98.61 -0.01 98.60 2.97 0.00 1.03 4.00 0.07 0.92 0.00 0.00 0.01 1.26 14.80 0.03 0.01 98.94 -0.02 98.92 2.98 0.00 1.02 4.00 0.11 0.88 0.00 0.02 0.02 11.10 0.07 0.03 0.00 100.67 -0.01 100.65 2.99 0.00 1.01 4.00 0.93 0.00 0.01 0.01 0.24 11.74 0.07 0.00 0.02 100.56 0.00 100.56 2.97 0.01 1.02 4.00 0.99 0.00 0.03 0.01 1.01 10.89 0.05 0.01 0.01 100.61 0.00 100.60 2.91 0.02 1.08 4.00 0.92 0.00 0.06 0.01 1.76 10.36 0.08 0.00 0.02 99.86 0.00 99.86 2.88 0.02 1.10 4.00 0.88 0.00 0.00 0.00 1.07 10.55 1.22 0.00 0.02 100.39 -0.01 100.38 2.93 0.00 1.07 4.00 0.90 0.07 0.01 0.00 2.02 10.18 0.21 0.00 0.02 100.02 0.00 100.01 2.86 0.01 1.12 4.00 0.86 0.01 0.00 0.00 5.11 8.62 0.29 0.00 0.00 99.85 0.00 99.85 2.73 0.01 1.26 4.00 0.74 0.02 0.00 0.00 5.24 8.61 0.24 0.00 0.00 99.98 0.00 99.98 2.72 0.01 1.27 4.00 0.74 0.01 0.00 0.00 2.47 10.26 0.10 0.00 0.00 99.97 0.00 99.96 2.85 0.00 1.14 4.00 0.87 0.01 0.00 0.00 5.14 8.78 0.18 0.00 0.00 100.29 0.00 100.29 2.73 0.01 1.26 4.00 0.75 0.01 0.00 0.00 0.18 8.48 0.31 0.01 0.07 97.67 -0.02 97.65 2.96 0.01 1.03 4.00 0.71 0.02 0.00 0.00 0.13 11.05 0.08 0.00 0.05 99.75 -0.01 99.74 2.97 0.01 1.02 4.00 0.93 0.00 0.00 0.01 0.14 10.41 0.09 0.04 0.15 98.59 -0.05 98.53 2.98 0.00 1.02 4.00 0.89 0.00 0.01 0.00 0.11 10.53 0.07 0.00 0.08 100.36 -0.02 100.34 2.98 0.00 1.01 4.00 0.88 0.00 0.01 0.00 0.63 11.11 0.26 0.02 0.00 99.84 -0.01 99.83 2.95 0.00 1.05 4.00 0.94 0.01 0.02 0.01 0.00 0.38 16.22 0.06 0.00 99.42 -0.02 99.40 2.98 0.00 1.02 4.00 0.03 0.96 0.00 0.01 0.00 0.32 16.31 0.04 0.00 99.81 -0.02 99.79 2.98 0.00 1.02 4.00 0.03 0.96 0.00 0.00 0.52 10.54 0.48 0.00 0.00 100.88 0.00 100.88 2.96 0.00 1.03 4.00 0.88 0.03 0.00 0.01 0.01 0.00 0.01 0.05 0.01 100.58 -0.02 100.55 0.98 0.05 1.97 3.00 0.00 0.00 0.00 0.00 0.35 9.85 0.29 0.02 0.00 99.52 -0.01 99.51 2.96 0.00 1.03 4.00 0.83 0.02 0.00 0.00 0.25 10.55 0.12 0.02 0.02 101.08 -0.01 101.06 2.98 0.00 1.02 4.00 0.87 0.01 0.02 0.00 0.04 4.10 11.14 0.03 0.01 99.23 -0.01 99.22 2.96 0.00 1.04 4.00 0.36 0.65 0.00 0.00 0.41 11.04 0.14 0.00 0.02 100.48 0.00 100.48 2.95 0.00 1.04 4.00 0.93 0.01 0.00 0.00 0.48 10.69 0.16 0.00 0.00 100.22 0.00 100.22 2.94 0.01 1.05 4.00 0.90 0.01 0.00 0.00 0.18 10.89 0.08 0.00 0.05 100.60 -0.01 100.59 2.96 0.01 1.03 4.00 0.91 0.00 0.00 0.01 0.39 9.87 0.35 0.00 0.00 99.24 0.00 99.24 2.96 0.00 1.04 4.00 0.83 0.02 0.00 0.00 0.36 9.76 0.35 0.02 0.00 99.22 -0.01 99.21 2.95 0.00 1.04 4.00 0.82 0.02 0.00 0.00 0.41 10.06 0.31 0.01 0.00 99.31 0.00 99.31 2.95 0.01 1.05 4.00 0.85 0.02 0.00 0.01 0.38 10.12 0.29 0.00 0.00 99.82 0.00 99.82 2.96 0.00 1.04 4.00 0.85 0.02 0.00 0.00 0.39 10.10 0.34 0.01 0.00 100.17 0.00 100.17 2.96 0.00 1.04 4.00 0.84 0.02 0.00 0.01 0.38 10.00 0.34 0.01 0.00 99.28 0.00 99.28 2.95 0.00 1.05 4.00 0.84 0.02 0.00 0.00 0.32 10.29 0.19 0.00 0.00 99.79 0.00 99.79 2.95 0.01 1.04 4.00 0.86 0.01 0.00 0.00 0.64 10.23 0.27 0.04 0.01 100.25 -0.02 100.23 2.94 0.01 1.05 4.00 0.86 0.01 0.00 0.01 0.17 11.43 0.14 0.01 0.04 100.71 -0.01 100.70 2.98 0.00 1.02 4.00 0.96 0.01 0.00 0.03 0.17 11.78 0.21 0.03 0.00 101.44 -0.01 101.43 2.98 0.00 1.02 4.00 0.98 0.01 0.00 0.01 0.45 10.96 0.18 0.00 0.01 99.75 0.00 99.75 2.96 0.00 1.04 4.00 0.93 0.01 0.00 0.02 0.00 0.69 15.70 0.00 0.02 99.25 0.00 99.24 2.98 0.00 1.02 4.00 0.06 0.93 0.00 0.01 4.57 9.00 0.06 0.00 0.02 100.28 0.00 100.28 2.76 0.00 1.24 4.00 0.77 0.00 0.00 0.00 0.03 0.62 15.65 0.02 0.06 99.65 -0.02 99.63 2.98 0.00 1.01 4.00 0.06 0.92 0.00 0.00 0.63 11.19 0.06 0.03 0.02 100.72 -0.02 100.70 2.95 0.00 1.05 4.00 0.94 0.00 0.00 0.00 0.00 0.67 15.59 0.05 0.01 99.74 -0.02 99.72 2.98 0.00 1.02 4.00 0.06 0.92 0.00 0.00 0.01 0.25 16.32 0.01 0.06 99.44 -0.02 99.42 2.98 0.00 1.02 4.00 0.02 0.97 0.00 0.01 0.00 0.34 16.14 0.00 0.00 99.26 0.00 99.26 2.98 0.00 1.02 4.00 0.03 0.96 0.01 0.00 0.02 0.24 16.24 0.03 0.02 99.80 -0.02 99.78 2.97 0.01 1.02 4.00 0.02 0.96 0.00 0.02 0.11 0.50 15.62 0.00 0.26 99.35 -0.06 99.30 2.97 0.00 1.02 4.00 0.05 0.93 0.00 0.00 0.07 0.38 15.58 0.02 0.35 99.05 -0.09 98.96 2.99 0.00 1.01 4.00 0.03 0.93 0.00 0.00 0.00 0.20 16.38 0.05 0.00 100.13 -0.02 100.11 2.97 0.01 1.02 4.00 0.02 0.96 0.00 0.00 0.15 11.66 0.06 0.02 0.01 100.89 -0.01 100.88 2.97 0.01 1.02 4.00 0.98 0.00 0.00 0.02 0.44 11.43 0.06 0.01 0.00 100.82 -0.01 100.81 2.96 0.01 1.03 4.00 0.96 0.00 0.01 0.01 0.14 11.62 0.04 0.01 0.00 100.90 -0.01 100.90 2.98 0.01 1.01 4.00 0.97 0.00 0.01 0.02 0.00 0.18 16.31 0.00 0.01 99.53 0.00 99.53 2.98 0.01 1.01 4.00 0.02 0.96 0.00 0.01 0.00 0.16 16.31 0.01 0.01 99.43 -0.01 99.42 2.97 0.01 1.02 4.00 0.01 0.97 0.00 0.02 0.05 11.85 0.04 0.00 0.00 100.91 0.00 100.91 2.98 0.00 1.02 4.00 0.99 0.00 0.02 0.00 0.23 11.32 0.06 0.00 0.03 100.58 -0.01 100.57 2.98 0.00 1.02 4.00 0.95 0.00 0.01 0.00 0.19 11.47 0.07 0.04 0.00 100.37 -0.02 100.36 2.98 0.00 1.02 4.00 0.97 0.00 0.00 0.00 0.09 11.56 0.07 0.02 0.01 100.77 -0.01 100.76 2.98 0.01 1.02 4.00 0.97 0.00 0.01 0.01 0.00 0.23 16.30 0.03 0.02 99.15 -0.02 99.13 2.98 0.00 1.01 4.00 0.02 0.97 0.00 0.00 0.00 0.45 16.12 0.01 0.16 99.85 -0.04 99.81 2.98 0.00 1.02 4.00 0.04 0.95 0.00 0.00 0.02 0.34 16.13 0.00 0.10 99.25 -0.02 99.22 2.96 0.01 1.03 4.00 0.03 0.96 0.00 0.00 0.03 11.59 0.05 0.05 0.01 100.47 -0.02 100.45 2.98 0.01 1.01 4.00 0.98 0.00 0.00 0.01 0.42 11.53 0.10 0.01 0.04 99.55 -0.01 99.54 2.96 0.00 1.04 4.00 0.98 0.01 0.00 0.01 0.34 11.47 0.07 0.03 0.02 99.76 -0.02 99.74 2.97 0.00 1.03 4.00 0.97 0.00 0.00 0.00 6.72 7.55 0.42 0.00 0.00 100.38 0.00 100.38 2.66 0.01 1.33 4.00 0.65 0.02 0.00 0.00 6.35 7.89 0.36 0.00 0.01 100.69 0.00 100.68 2.67 0.01 1.32 4.00 0.68 0.02 0.00 0.01 6.91 7.79 0.30 0.00 0.00 100.79 0.00 100.79 2.64 0.01 1.35 4.00 0.67 0.02 0.00 0.00 0.25 2.41 12.82 0.02 0.00 99.73 -0.01 99.72 2.96 0.00 1.04 4.00 0.21 0.75 0.01 0.02 6.62 7.68 0.44 0.03 0.00 100.35 -0.01 100.33 2.67 0.01 1.32 4.00 0.66 0.03 0.00 0.03 0.25 1.06 14.49 0.10 0.18 99.07 -0.08 98.99 2.97 0.00 1.03 4.00 0.10 0.86 0.00 0.02 0.04 0.56 15.43 0.02 0.22 100.29 -0.06 100.23 2.98 0.00 1.02 4.00 0.05 0.90 0.00 0.00 0.27 10.93 0.08 0.05 0.03 100.69 -0.03 100.66 2.98 0.00 1.02 4.00 0.91 0.00 0.02 0.03 0.28 10.99 0.10 0.02 0.06 101.54 -0.02 101.52 2.98 0.01 1.02 4.00 0.91 0.01 0.00 0.01 0.00 0.26 16.45 0.01 0.00 98.57 0.00 98.56 2.97 0.00 1.02 4.00 0.02 0.99 0.00 0.00 0.00 0.24 16.43 0.00 0.00 99.18 0.00 99.18 2.98 0.00 1.02 4.00 0.02 0.98 0.00 0.00 0.00 0.13 16.59 0.00 0.00 99.79 0.00 99.79 2.97 0.01 1.02 4.00 0.01 0.98 0.00 0.00 0.00 0.57 15.94 0.00 0.01 98.81 0.00 98.80 2.98 0.01 1.01 4.00 0.05 0.95 0.01 0.00 0.00 0.77 15.54 0.00 0.00 98.54 0.00 98.54 2.98 0.00 1.02 4.00 0.07 0.93 0.00 0.00 0.01 0.58 15.90 0.05 0.01 101.59 -0.02 101.57 2.96 0.02 1.02 4.00 0.05 0.92 0.00 0.02 0.00 0.39 15.91 0.04 0.04 101.82 -0.02 101.79 2.99 0.02 0.99 4.00 0.03 0.92 0.00 0.01 0.00 0.36 16.08 0.03 0.01 101.36 -0.01 101.35 2.99 0.01 1.01 4.00 0.03 0.93 0.01 0.03 0.00 0.31 16.09 0.00 0.01 101.14 0.00 101.14 2.99 0.01 1.00 4.00 0.03 0.93 0.01 0.02 0.05 0.72 15.66 0.03 0.00 102.44 -0.01 102.43 2.97 0.02 1.02 4.00 0.06 0.90 0.00 0.00 0.00 0.34 16.14 0.10 0.00 101.47 -0.04 101.42 2.99 0.01 1.00 4.00 0.03 0.93 0.00 0.03 0.00 0.67 15.73 0.00 0.01 100.61 0.00 100.61 2.98 0.00 1.02 4.00 0.06 0.92 0.00 0.00 0.00 0.67 15.60 0.04 0.10 101.07 -0.04 101.03 2.99 0.01 1.01 4.00 0.06 0.91 0.00 0.00 5.68 10.32 1.22 0.00 4.09 100.55 -0.92 99.62 8.23 0.00 3.76 11.99 2.89 0.23 0.00 0.01 6.02 9.86 1.23 0.03 3.93 100.13 -0.90 99.23 8.20 0.00 3.80 12.00 2.76 0.23 0.00 0.01 5.86 9.98 1.33 0.03 4.05 100.54 -0.93 99.62 8.21 0.00 3.77 11.99 2.79 0.24 0.01 0.00 7.74 7.04 0.62 0.00 0.01 101.78 0.00 101.78 2.60 0.01 1.39 4.00 0.60 0.03 0.59 0.03 0.10 0.46 15.04 0.02 0.02 99.58 -0.01 99.57 2.90 0.04 1.06 4.00 0.04 0.89 0.11 0.01 0.40 0.98 14.24 0.02 0.09 100.28 -0.03 100.26 2.92 0.01 1.07 4.00 0.09 0.83 0.01 0.00 4.26 9.18 0.20 0.02 0.01 101.94 -0.01 101.93 2.78 0.01 1.21 4.00 0.77 0.01 0.00 0.00 0.00 0.30 16.30 0.02 0.01 99.01 -0.01 99.00 2.98 0.00 1.02 4.00 0.03 0.97 0.01 0.00 0.06 0.30 15.20 0.03 0.14 97.69 -0.04 97.64 2.97 0.00 1.03 4.00 0.03 0.91 0.00 0.02 0.06 0.33 16.00 0.02 0.23 99.00 -0.06 98.94 2.97 0.01 1.02 4.00 0.03 0.95 0.00 0.01 0.00 0.88 15.18 0.08 0.00 99.06 -0.03 99.02 2.97 0.00 1.02 4.00 0.08 0.90 0.00 0.00 7.35 6.71 1.43 0.07 0.00 100.71 -0.03 100.68 2.62 0.01 1.38 4.00 0.58 0.08 0.00 0.01 0.63 11.16 0.14 0.00 0.14 101.05 -0.03 101.02 2.96 0.01 1.03 4.00 0.94 0.01 0.00 0.00 0.01 0.01 0.00 0.00 0.00 100.79 0.00 100.79 0.94 0.01 2.04 3.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.06 0.00 100.94 -0.02 100.91 0.96 0.01 2.03 3.00 0.00 0.00 0.01 0.00 0.00 0.02 0.00 0.05 0.00 100.94 -0.02 100.92 0.97 0.01 2.02 3.00 0.00 0.00 0.00 0.00 0.00 0.01 0.01 0.00 0.00 100.87 0.00 100.87 0.97 0.02 2.01 3.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 101.19 0.00 101.19 0.96 0.02 2.02 3.00 0.00 0.00 0.01 0.00 0.00 0.02 0.00 0.02 0.01 100.97 -0.01 100.96 0.95 0.01 2.03 3.00 0.00 0.00 2+ Ca Mg Ti Cr Fe Mn Sum F Cl O Total 0.10 0.01 0.00 0.00 0.00 0.00 0.99 0.01 0.01 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.95 0.00 0.02 7.98 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.01 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.01 0.99 0.00 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.01 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 8.00 8.00 0.00 0.01 0.00 0.00 0.00 0.00 0.96 0.00 0.00 8.00 8.00 0.00 0.01 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.30 0.00 0.00 0.00 0.00 0.00 1.03 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.91 0.00 0.08 7.92 8.00 0.00 0.01 0.00 0.00 0.00 0.00 0.87 0.01 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.88 0.01 0.02 7.97 8.00 0.06 0.09 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.02 7.98 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.02 0.02 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.21 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.01 0.02 0.00 0.00 0.00 0.00 1.00 0.01 0.00 7.99 8.00 0.47 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.01 7.99 8.00 0.48 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 8.00 8.00 0.50 0.00 0.00 0.00 0.00 0.00 1.02 0.00 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 7.99 8.00 0.33 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.26 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.01 7.99 8.00 0.27 0.00 0.00 0.00 0.00 0.00 0.99 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.93 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.05 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.08 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.05 0.00 0.00 0.00 0.00 0.00 1.02 0.00 0.00 8.00 8.00 0.09 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.24 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.25 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.12 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.24 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.74 0.00 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.94 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.90 0.01 0.01 7.98 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.89 0.00 0.01 7.99 8.00 0.03 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.01 0.00 7.99 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.93 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.86 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.89 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.02 0.00 0.00 7.99 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.95 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.93 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.92 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.87 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.86 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.88 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.88 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.88 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.88 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.89 0.00 0.00 8.00 8.00 0.03 0.00 0.00 0.00 0.00 0.00 0.90 0.01 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.96 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.22 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 7.99 8.00 0.03 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.02 7.98 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.96 0.00 0.03 7.97 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.96 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.01 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.01 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.02 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 8.00 8.00 0.02 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 7.99 8.00 0.32 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.30 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.33 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.00 8.00 8.00 0.32 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.97 0.01 0.01 7.97 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.95 0.00 0.02 7.98 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.93 0.01 0.00 7.99 8.00 0.01 0.00 0.00 0.00 0.00 0.00 0.93 0.00 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.01 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.97 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.95 0.00 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.96 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.96 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.96 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.96 0.01 0.00 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.96 0.01 0.01 7.99 8.00 0.88 0.00 0.00 0.00 0.01 0.00 4.00 0.00 1.00 0.00 1.00 0.93 0.00 0.00 0.00 0.00 0.00 3.93 0.01 0.96 0.02 1.00 0.91 0.00 0.00 0.00 0.01 0.00 3.95 0.01 0.99 0.00 1.00 0.36 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.00 0.04 0.00 0.00 0.00 0.00 0.93 0.00 0.00 8.00 8.00 0.02 0.01 0.00 0.00 0.00 0.00 0.93 0.00 0.01 7.99 8.00 0.20 0.00 0.00 0.00 0.00 0.00 0.98 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.94 0.00 0.01 7.98 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.99 0.00 0.02 7.98 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.98 0.01 0.00 7.99 8.00 0.35 0.00 0.00 0.00 0.00 0.00 1.01 0.01 0.00 7.99 8.00 0.03 0.00 0.00 0.00 0.00 0.00 0.97 0.00 0.01 7.99 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 8.00 8.00 Table A4. Chemical analyses of sheet silicates and dumortierite from Copiapó, Chile

Locality Sample Spot no. Analysis no. Mineral SiO2 TiO2 Al2O3 B2O3 Cr2O3 Fe2O3 Cerro Bronce Estrella C2B-708 2 m1 Mica 44.88 0.00 32.44 0.00 0.01 0.88 Cerro Bronce Estrella C2B-708 2 m1-1 Mica 46.81 0.00 33.24 0.00 0.00 0.55 Cerro Bronce Estrella C2B-708 2 b1 Mica 44.35 0.00 30.95 0.00 0.00 0.92 Cerro Bronce Estrella C2B-708 2 b2 Mica 43.79 0.00 31.71 0.00 0.00 0.91 Cerro Buitre Radio Tower C2B-576c 1 b1 Mica 35.02 2.22 18.86 0.00 0.00 2.50 Cerro Buitre Radio Tower C2B-576c 1 b2 Mica 34.75 2.11 18.21 0.00 0.00 2.51 Cerro Buitre Radio Tower C2B-576c 1 m2 Mica 45.24 0.55 34.14 0.00 0.00 0.47 Cerro Buitre Radio Tower C2B-576c 2 b1 Mica 34.07 2.22 18.18 0.00 0.01 2.59 Cerro Buitre Radio Tower C2J-124 3 tour1be Mica 42.58 0.12 25.75 0.00 0.00 0.56 Cerro Buitre Radio Tower C2J-124 3 m1 Chlorite 28.36 0.04 23.30 0.00 0.00 0.71 Cerro Buitre Radio Tower C2J-124 3 m2 Mica 47.08 0.24 31.00 0.00 0.01 0.28 Cerro Buitre Radio Tower C2J-124 3 m4 Mica 45.45 0.47 31.78 0.00 0.00 0.42 Cerro Buitre Radio Tower C2J-124 3 k Mica 45.77 0.34 30.98 0.00 0.00 0.41 Cerro Buitre Radio Tower C2J-124 3 k2 Mica 49.53 0.25 31.92 0.00 0.01 0.36 Cerro Buitre Radio Tower C2J-334 1 c2 Mica 36.88 2.78 14.17 0.00 0.01 2.38 Cerro Buitre Radio Tower C2J-334 2 a1 Mica 36.29 2.52 14.32 0.00 0.00 2.45 Cerro Negro Norte C6B-076 4 m1 Chlorite 27.44 0.02 19.15 0.00 0.00 2.51 Cerro Negro Norte C6B-076 4 m3 Chlorite 28.60 0.01 18.69 0.00 0.00 2.45 Jesus Maria C7B-003a 4 a1 Diaspore 0.03 0.06 85.05 0.00 0.00 0.30 Jesus Maria C7B-003a 2 d1 Pyrophyllite 65.72 0.00 27.89 0.00 0.00 0.49 Jesus Maria C7B-003a 2 d2 Pyrophyllite 67.47 0.01 28.87 0.00 0.00 0.37 Jesus Maria C7B-003a 1 d3 Pyrophyllite 66.02 0.01 29.50 0.00 0.00 0.28 Jesus Maria C7B-003a 1 d2 Dumortierite 30.01 2.32 61.42 6.28 0.01 0.84 Jesus Maria C7B-003a 4 d1 Dumortierite 30.69 2.38 60.00 6.28 0.00 0.92 Jesus Maria C7B-003a 4 d2 Dumortierite 28.19 2.03 62.04 6.28 0.00 0.93 San Gregorio S Granate C2B-352e 1 b1 Chlorite 33.37 4.41 12.35 0.00 0.00 0.00 San Gregorio S Granate C2B-352e 3 m1 Chlorite 27.07 0.01 16.41 0.00 0.00 2.03 San Gregorio S Granate C2B-808.2 2 b3 Mica 35.45 4.62 13.07 0.00 0.00 2.95 San Gregorio S Granate C2B-808.2 2 b4 Mica 35.80 4.73 12.86 0.00 0.00 2.91 San Gregorio S Granate C2B-808.2 2 b5 Mica 34.68 4.13 13.60 0.00 0.01 3.06 San Gregorio S Granate C2B-808.2 2 b6 Mica 34.67 4.77 12.48 0.00 0.00 2.94 San Gregorio S Granate C2B-808.2 2 c1 Mica 46.42 1.16 6.42 0.00 0.00 2.53 San Gregorio S Granate C2B-808.2 2 b7 Mica 36.64 4.90 13.54 0.00 0.01 2.71 San Gregorio S Granate C2B-808.2 2 b8 Mica 36.46 4.79 13.38 0.00 0.01 2.91 San Gregorio S Granate C2B-808.2 2 b9 Mica 36.32 4.77 13.28 0.00 0.01 3.02 San Gregorio S Granate C2B-808.2 3 b1 Mica 36.53 4.19 13.34 0.00 0.00 2.97 San Gregorio S Granate C2B-808.2 3 b2 Mica 36.33 4.60 13.09 0.00 0.00 2.88 Santos PdC DDH289-037.5a 1 b1 Mica 35.79 1.67 18.16 0.00 0.03 2.35 Santos PdC DDH289-037.5a 1 b2 Mica 36.20 1.77 17.42 0.00 0.06 2.49 Santos PdC DDH289-037.5a 1 b3 Mica 36.26 1.65 17.99 0.00 0.03 2.53 Santos PdC DDH289-037.5a 1 b4 Chlorite 25.97 0.08 21.97 0.00 0.03 3.00 Santos PdC DDH289-037.5a 1 b5 Mica 37.25 1.65 17.61 0.00 0.04 2.18 Santos PdC DDH289-037.5a 1 b6 Mica 36.97 1.53 17.69 0.00 0.04 2.34 Santos PdC DDH289-037.5a 1 b7 Mica 35.06 1.75 18.12 0.00 0.04 2.49 Santos PdC DDH289-037.5a 1 b8 Mica 36.78 1.73 17.14 0.00 0.06 2.31 Santos PdC DDH289-037.5a 1 b9 Mica 38.59 1.55 18.23 0.00 0.04 2.28 Santos PdC DDH289-037.5a 1 m1 Chlorite 26.12 0.08 22.43 0.00 0.10 2.69 Santos PdC DDH289-037.5a 1 m2 Chlorite 26.57 0.08 23.09 0.00 0.13 3.02 Santos PdC DDH289-037.5a 1 m3 Mica 35.58 1.83 17.76 0.00 0.04 2.44 Santos PdC DDH289-037.5a 1 b11 Mica 35.64 1.75 17.84 0.00 0.07 2.55 Santos PdC DDH289-037.5a 2 b1 Mica 35.49 1.20 18.03 0.00 0.03 2.44 Santos PdC DDH289-037.5a 2 b2 Mica 35.94 1.82 17.57 0.00 0.04 2.47 Santos PdC DDH289-037.5a 2 m1 Chlorite 25.44 0.07 21.65 0.00 0.04 2.89 Santos PdC DDH289-037.5a 2 t7 Chlorite 26.14 0.17 21.54 0.00 0.03 2.84 Santos PdC DDH289-037.5a 2 b3 Mica 36.37 1.40 17.50 0.00 0.01 2.48 Santos PdC DDH289-037.5a 2 b4 Chlorite 28.15 0.37 21.05 0.00 0.06 2.92 Santos PdC DDH289-037.5a 2 m4 Mica 37.76 1.22 16.63 0.00 0.01 2.43 Santos PdC DDH289-037.5a 2 t10 Mica 35.92 1.80 18.25 0.00 0.03 2.53 Santos PdC DDH291-188.4 1 b1 Mica 37.89 1.23 16.68 0.00 0.03 1.98 Santos PdC DDH291-188.4 1 b2 Mica 38.17 1.37 16.85 0.00 0.12 1.98 Santos PdC DDH291-188.4 1 b3 Mica 38.51 1.25 16.85 0.00 0.07 2.11 Santos PdC DDH291-188.4 2 b1 Mica 37.87 1.18 17.29 0.00 0.09 2.23 Santos PdC DDH384-004.2 2 c1 Chlorite 27.15 0.07 20.92 0.00 0.00 2.65 Santos PdC DDH628-094.2 2 b1 Chlorite 28.22 0.08 19.18 0.00 0.00 2.54 Santos PdC DDH628-094.2 2 b2 Mica 35.98 1.88 16.46 0.00 0.00 2.40 Santos PdC DDH628-094.2 2 b1 Mica 37.42 0.47 17.10 0.00 0.00 2.06 Santos PdC DDH628-151.6 2 c1 Chlorite 26.85 0.02 19.67 0.00 0.00 2.70 Santos PdC DDH628-151.6 2 c2 Mica 36.99 0.07 17.99 0.00 0.00 2.35 Santos PdC DDH628-626.3 1 b1 Mica 36.36 1.30 17.11 0.00 0.00 2.31 Santos PdC DDH628-626.3 1 b2 Mica 36.51 1.52 17.61 0.00 0.00 2.41 Santos PdC DDH628-626.3 1 b3 Chlorite 28.32 0.02 21.04 0.00 0.00 2.75 Santos PdC DDH628-626.3 1 b4 Mica 39.09 0.01 16.77 0.00 0.00 2.02 Santos PdC DDH628-626.3 1 b5 Mica 38.43 0.06 17.93 0.00 0.01 2.10 Santos PdC DDH628-626.3 1 b6 Chlorite 26.46 0.01 22.20 0.00 0.00 2.62 Santos PdC DDH628-626.3 1 b7 Mica 37.88 0.08 18.25 0.00 0.00 2.18 Santos PdC DDH628-626.3 2 b1 Mica 37.39 1.40 17.55 0.00 0.00 3.35 Santos PdC DDH628-626.3 2 b2 Mica 37.31 1.41 18.16 0.00 0.00 2.29 Santos PdC DDH628-626.3 2 b3 Mica 36.37 1.21 17.42 0.00 0.00 2.48 Santos PdC DDH628-626.3 2 b4 Mica 36.99 1.48 17.35 0.00 0.01 2.35 Santos PdC DDH628-626.3 1 sc1 Scapolite 57.02 0.00 22.12 0.00 0.00 0.00 Santos PdC DDH628-626.3 1 sc2 Scapolite 56.73 0.00 22.29 0.00 0.00 0.00 Santos PdC DDH628-626.3 1 sc3 Scapolite 56.95 0.00 22.21 0.00 0.00 0.00 Santos PdC DDH643-595.5 1 c1 Chlorite 26.78 0.02 19.29 0.00 0.00 3.20 Santos PdC DDH684-079.8 3 b2 Chlorite 28.15 0.05 19.54 0.00 0.00 2.83 Santos PdC ME013-538 1 b1 Mica 35.49 1.17 17.86 0.00 0.00 2.63 Santos PdC ME013-538 1 b2 Mica 35.88 0.58 18.46 0.00 0.01 2.48 Santos PdC ME013-538 1 b3 Mica 35.30 1.50 20.54 0.00 0.00 2.18 Santos PdC ME013-538 2 b1 Mica 35.47 1.67 17.52 0.00 0.00 2.55 Santos PdC ME013-538 2 t5 Mica 37.63 2.04 16.48 0.00 0.00 2.34 Santos PdC ME013-538 2 t6 Chlorite 27.94 0.02 19.35 0.00 0.00 2.71 IV 3+ FeO MgO MnO CaO Na2OK2OH2O F Cl Subtotal O=F+Cl Total Si B Al Fe Sum 6.28 0.36 0.00 0.00 0.11 10.31 4.36 0.03 0.02 99.70 -0.02 99.68 3.07 0.00 0.93 0.00 4.00 4.06 0.35 0.03 0.08 0.11 10.55 4.44 0.05 0.01 100.27 -0.02 100.25 3.14 0.00 0.86 0.00 4.00 6.27 1.71 0.03 0.00 0.11 10.88 4.30 0.06 0.04 99.60 -0.03 99.57 3.06 0.00 0.94 0.00 4.00 6.39 0.93 0.05 0.00 0.11 10.83 4.29 0.02 0.09 99.11 -0.03 99.08 3.04 0.00 0.96 0.00 4.00 17.54 9.87 0.16 0.06 0.10 8.45 3.82 0.18 0.16 98.93 -0.11 98.82 2.66 0.00 1.34 0.00 4.00 17.33 9.59 0.10 0.01 0.15 9.13 3.78 0.14 0.16 97.96 -0.09 97.87 2.68 0.00 1.32 0.00 4.00 3.16 0.63 0.00 0.00 0.43 10.51 4.44 0.00 0.01 99.58 0.00 99.58 3.06 0.00 0.94 0.00 4.00 18.09 9.16 0.12 0.00 0.07 9.68 3.75 0.14 0.17 98.25 -0.10 98.15 2.65 0.00 1.35 0.00 4.00 3.72 16.82 0.20 0.13 1.63 1.72 4.38 0.10 0.04 97.84 -0.05 97.79 2.88 0.00 1.12 0.00 4.00 5.27 28.39 0.37 0.01 0.01 0.02 12.43 0.14 0.00 99.11 -0.06 99.05 2.72 0.00 1.28 0.00 4.00 2.27 1.74 0.01 0.00 0.17 9.34 4.37 0.01 0.00 96.77 -0.01 96.76 3.23 0.00 0.77 0.00 4.00 3.01 1.52 0.02 0.01 0.35 9.98 4.32 0.08 0.01 97.69 -0.04 97.66 3.12 0.00 0.88 0.00 4.00 3.05 6.29 0.11 0.01 0.19 8.71 4.50 0.01 0.02 100.55 -0.01 100.54 3.05 0.00 0.95 0.00 4.00 2.85 1.85 0.01 0.05 0.12 9.62 4.51 0.13 0.01 101.38 -0.06 101.33 3.24 0.00 0.76 0.00 4.00 16.54 11.81 0.38 0.14 0.14 9.10 3.80 0.17 0.14 98.66 -0.10 98.56 2.82 0.00 1.18 0.00 4.00 16.92 11.84 0.38 0.07 0.06 9.43 3.78 0.18 0.14 98.58 -0.11 98.47 2.79 0.00 1.21 0.00 4.00 16.66 19.31 0.08 0.08 0.02 0.01 11.49 0.08 0.01 96.90 -0.03 96.86 2.86 0.00 1.14 0.00 4.00 17.38 19.78 0.14 0.12 0.00 0.00 11.74 0.04 0.01 99.01 -0.02 98.99 2.92 0.00 1.08 0.00 4.00 0.11 0.00 0.00 0.01 0.00 0.00 15.09 0.00 0.00 100.65 0.00 100.65 0.00 0.00 1.00 0.00 1.00 0.00 0.19 0.02 0.20 0.07 0.07 4.91 0.07 0.05 99.69 -0.04 99.64 3.97 0.00 0.03 0.00 4.00 0.00 0.07 0.00 0.09 0.06 0.05 5.08 0.02 0.00 102.09 -0.01 102.08 3.97 0.00 0.03 0.00 4.00 0.00 0.01 0.00 0.29 0.04 0.01 5.03 0.03 0.00 101.21 -0.01 101.20 3.92 0.00 0.08 0.00 4.00 0.00 0.11 0.00 0.30 0.02 0.00 0.56 0.07 0.00 101.94 -0.03 101.91 2.75 0.00 0.25 0.00 3.00 0.00 0.12 0.00 0.00 0.00 0.00 0.56 0.10 0.01 101.06 -0.04 101.02 2.85 0.00 0.15 0.00 3.00 0.00 0.13 0.00 0.01 0.01 0.00 0.56 0.22 0.00 100.41 -0.09 100.32 2.62 0.00 0.38 0.00 3.00 22.41 9.44 0.27 0.33 0.24 7.74 10.11 0.12 0.44 101.48 -0.15 101.33 3.89 0.00 0.11 0.00 4.00 33.14 9.12 0.36 0.06 0.09 0.03 10.90 0.03 0.02 99.52 -0.02 99.50 2.97 0.00 1.03 0.00 4.00 20.56 9.03 0.17 0.01 0.14 9.10 3.60 0.16 0.69 99.85 -0.22 99.62 2.76 0.00 1.20 0.04 4.00 20.28 9.37 0.19 0.00 0.16 9.12 3.64 0.22 0.52 100.11 -0.21 99.90 2.77 0.00 1.17 0.06 4.00 21.56 9.29 0.24 0.01 0.15 7.89 3.62 0.20 0.45 99.17 -0.19 98.99 2.71 0.00 1.25 0.03 4.00 21.27 8.47 0.18 0.02 0.12 9.20 3.56 0.15 0.58 98.70 -0.19 98.50 2.75 0.00 1.17 0.09 4.00 17.47 10.36 0.46 10.93 1.19 0.64 4.03 0.12 0.31 102.20 -0.12 102.08 3.34 0.00 0.54 0.11 4.00 20.16 9.79 0.21 0.01 0.16 9.16 3.70 0.27 0.54 102.14 -0.24 101.90 2.77 0.00 1.21 0.03 4.00 20.00 9.78 0.21 0.02 0.13 9.11 3.69 0.25 0.56 101.60 -0.23 101.37 2.77 0.00 1.20 0.03 4.00 19.94 9.71 0.14 0.01 0.13 9.08 3.64 0.32 0.55 101.22 -0.26 100.96 2.77 0.00 1.19 0.04 4.00 19.96 10.06 0.18 0.01 0.07 9.32 3.64 0.30 0.62 101.49 -0.27 101.22 2.78 0.00 1.20 0.02 4.00 20.11 9.76 0.17 0.00 0.11 9.22 3.62 0.28 0.66 101.13 -0.26 100.86 2.78 0.00 1.18 0.04 4.00 17.93 9.72 0.18 0.00 0.08 9.67 3.72 0.24 0.47 100.19 -0.21 99.99 2.72 0.00 1.28 0.00 4.00 16.82 9.77 0.15 0.00 0.12 9.24 3.71 0.25 0.34 98.55 -0.18 98.37 2.77 0.00 1.23 0.00 4.00 17.53 9.87 0.18 0.00 0.09 9.60 3.77 0.21 0.40 100.32 -0.18 100.14 2.74 0.00 1.26 0.00 4.00 20.67 16.15 0.28 0.01 0.00 0.14 11.63 0.05 0.04 100.10 -0.03 100.07 2.67 0.00 1.33 0.00 4.00 17.07 10.15 0.22 0.00 0.08 9.64 3.78 0.33 0.25 100.47 -0.20 100.28 2.79 0.00 1.21 0.00 4.00 16.60 10.28 0.13 0.00 0.08 9.62 3.79 0.26 0.26 99.80 -0.17 99.63 2.79 0.00 1.21 0.00 4.00 18.06 9.55 0.25 0.00 0.11 9.64 3.67 0.24 0.53 99.72 -0.22 99.49 2.68 0.00 1.32 0.00 4.00 16.22 9.65 0.21 0.06 0.09 9.58 3.68 0.32 0.32 98.33 -0.21 98.12 2.81 0.00 1.19 0.00 4.00 15.66 10.11 0.21 0.15 0.32 9.43 3.81 0.37 0.36 101.35 -0.24 101.12 2.84 0.00 1.16 0.00 4.00 21.02 15.65 0.30 0.01 0.05 0.02 11.69 0.00 0.03 100.31 -0.01 100.30 2.68 0.00 1.32 0.00 4.00 20.16 15.55 0.27 0.04 0.08 0.00 11.82 0.01 0.03 100.94 -0.01 100.93 2.69 0.00 1.31 0.00 4.00 17.13 9.93 0.15 0.01 0.07 9.48 3.71 0.26 0.35 98.98 -0.19 98.79 2.72 0.00 1.28 0.00 4.00 18.19 10.46 0.23 0.00 0.09 8.85 3.74 0.26 0.38 100.28 -0.20 100.09 2.70 0.00 1.30 0.00 4.00 17.46 10.20 0.19 0.01 0.11 9.19 3.74 0.17 0.37 98.81 -0.16 98.65 2.72 0.00 1.28 0.00 4.00 17.95 9.78 0.19 0.04 0.09 9.61 3.69 0.20 0.62 100.24 -0.22 100.01 2.73 0.00 1.27 0.00 4.00 20.32 15.74 0.26 0.04 0.03 0.11 11.41 0.02 0.05 98.15 -0.02 98.13 2.67 0.00 1.33 0.00 4.00 20.38 16.10 0.28 0.01 0.01 0.43 11.58 0.04 0.05 99.70 -0.03 99.67 2.70 0.00 1.30 0.00 4.00 16.73 10.38 0.18 0.00 0.07 9.66 3.74 0.26 0.32 99.29 -0.18 99.11 2.77 0.00 1.23 0.00 4.00 20.17 15.14 0.26 0.00 0.00 1.90 11.81 0.05 0.10 102.08 -0.04 102.03 2.85 0.00 1.15 0.00 4.00 16.41 10.99 0.13 0.00 0.09 9.05 3.78 0.23 0.35 99.26 -0.18 99.08 2.85 0.00 1.15 0.00 4.00 18.16 9.98 0.18 0.00 0.08 9.62 3.74 0.20 0.60 101.29 -0.22 101.07 2.70 0.00 1.30 0.00 4.00 15.07 12.30 0.15 0.01 0.08 9.56 3.86 0.21 0.13 99.21 -0.12 99.09 2.84 0.00 1.16 0.00 4.00 13.92 12.42 0.14 0.01 0.04 9.01 3.85 0.26 0.11 98.24 -0.13 98.10 2.86 0.00 1.14 0.00 4.00 14.41 12.49 0.12 0.00 0.09 9.62 3.88 0.24 0.18 99.83 -0.14 99.69 2.86 0.00 1.14 0.00 4.00 14.93 12.40 0.14 0.00 0.07 9.84 3.90 0.22 0.15 100.33 -0.13 100.20 2.81 0.00 1.19 0.00 4.00 17.94 18.36 0.18 0.00 0.00 0.01 11.70 0.03 0.04 99.04 -0.02 99.02 2.78 0.00 1.22 0.00 4.00 17.10 20.10 0.34 0.03 0.01 0.01 11.80 0.03 0.01 99.45 -0.01 99.43 2.86 0.00 1.14 0.00 4.00 16.16 11.56 0.25 0.00 0.11 9.64 3.77 0.18 0.26 98.64 -0.13 98.51 2.75 0.00 1.25 0.00 4.00 14.52 13.02 0.25 0.07 0.13 9.30 3.88 0.16 0.08 98.46 -0.09 98.37 2.82 0.00 1.18 0.00 4.00 19.30 17.19 0.22 0.03 0.03 0.04 11.42 0.03 0.02 97.51 -0.02 97.50 2.81 0.00 1.19 0.00 4.00 15.57 11.72 0.17 0.00 0.04 9.76 3.83 0.20 0.17 98.84 -0.12 98.72 2.80 0.00 1.20 0.00 4.00 16.64 13.25 0.23 0.92 0.02 8.14 3.85 0.22 0.28 100.73 -0.16 100.57 2.71 0.00 1.29 0.00 4.00 16.60 11.97 0.17 0.00 0.01 9.56 3.87 0.17 0.24 100.74 -0.13 100.61 2.73 0.00 1.27 0.00 4.00 18.46 17.46 0.20 0.01 0.00 1.03 11.91 0.03 0.04 101.28 -0.02 101.26 2.85 0.00 1.15 0.00 4.00 14.55 14.34 0.12 0.00 0.08 8.68 3.94 0.23 0.11 99.97 -0.12 99.85 2.88 0.00 1.12 0.00 4.00 14.82 13.23 0.11 0.00 0.10 9.60 3.94 0.23 0.11 100.67 -0.12 100.54 2.83 0.00 1.17 0.00 4.00 18.48 17.96 0.16 0.02 0.03 0.06 11.77 0.03 0.02 99.84 -0.02 99.82 2.69 0.00 1.31 0.00 4.00 15.01 12.86 0.11 0.00 0.11 9.49 3.89 0.21 0.24 100.34 -0.14 100.20 2.80 0.00 1.20 0.00 4.00 15.20 11.86 0.11 0.00 0.06 9.85 3.92 0.18 0.17 101.16 -0.11 101.05 2.77 0.00 1.23 0.00 4.00 16.29 12.32 0.12 0.00 0.09 9.63 3.95 0.15 0.24 102.07 -0.12 101.96 2.74 0.00 1.26 0.00 4.00 16.78 12.34 0.16 0.01 0.03 8.72 3.78 0.15 0.53 100.05 -0.19 99.86 2.73 0.00 1.27 0.00 4.00 15.85 12.04 0.09 0.01 0.09 9.33 3.91 0.10 0.18 99.88 -0.08 99.79 2.77 0.00 1.23 0.00 4.00 0.10 0.00 0.00 5.68 10.32 1.22 0.00 0.00 4.09 100.55 -0.92 99.62 8.23 0.00 3.76 0.00 11.99 0.03 0.00 0.01 6.02 9.86 1.23 0.00 0.03 3.93 100.13 -0.90 99.23 8.20 0.00 3.80 0.00 12.00 0.12 0.00 0.01 5.86 9.98 1.33 0.00 0.03 4.05 100.54 -0.93 99.62 8.21 0.00 3.77 0.00 11.99 22.30 15.83 0.32 0.01 0.00 0.01 11.43 0.06 0.03 99.29 -0.03 99.26 2.80 0.00 1.20 0.00 4.00 17.45 19.21 0.36 0.00 0.00 0.02 11.77 0.03 0.02 99.42 -0.02 99.40 2.86 0.00 1.14 0.00 4.00 17.90 10.33 0.25 0.01 0.07 9.58 3.77 0.22 0.20 99.53 -0.14 99.39 2.71 0.00 1.29 0.00 4.00 17.63 10.53 0.23 0.00 0.04 9.84 3.84 0.15 0.19 99.94 -0.11 99.83 2.72 0.00 1.28 0.00 4.00 17.18 8.47 0.22 0.10 0.39 8.18 3.84 0.12 0.16 98.21 -0.09 98.12 2.69 0.00 1.31 0.00 4.00 18.61 10.11 0.27 0.01 0.12 9.48 3.80 0.13 0.31 100.11 -0.12 99.99 2.70 0.00 1.30 0.00 4.00 17.62 10.55 0.25 0.04 0.11 9.23 3.85 0.23 0.17 100.54 -0.14 100.41 2.82 0.00 1.18 0.00 4.00 21.27 16.56 0.35 0.04 0.00 0.01 11.67 0.03 0.01 100.58 -0.01 100.56 2.87 0.00 1.13 0.00 4.00 Oct X OH Al Mg Fe2+ Fe3+ Mn Ti Cr □ Sum Na K Ca □ Sum F Cl OH 1.69 0.04 0.36 0.05 0.00 0.00 0.00 0.86 3.00 0.01 0.90 0.00 0.08 1.00 0.01 0.00 1.99 1.77 0.03 0.23 0.03 0.00 0.00 0.00 0.94 3.00 0.01 0.90 0.01 0.08 1.00 0.01 0.00 1.99 1.58 0.18 0.36 0.05 0.00 0.00 0.00 0.83 3.00 0.01 0.96 0.00 0.03 1.00 0.01 0.00 1.98 1.63 0.10 0.37 0.05 0.00 0.00 0.00 0.85 3.00 0.01 0.96 0.00 0.03 1.00 0.00 0.01 1.99 0.35 1.12 1.12 0.14 0.01 0.13 0.00 0.13 3.00 0.01 0.82 0.00 0.16 1.00 0.04 0.02 1.94 0.34 1.10 1.12 0.15 0.01 0.12 0.00 0.17 3.00 0.02 0.90 0.00 0.08 1.00 0.03 0.02 1.95 1.77 0.06 0.18 0.02 0.00 0.03 0.00 0.93 3.00 0.06 0.91 0.00 0.04 1.00 0.00 0.00 2.00 0.31 1.06 1.17 0.15 0.01 0.13 0.00 0.17 3.00 0.01 0.96 0.00 0.03 1.00 0.04 0.02 1.94 0.93 1.69 0.21 0.03 0.01 0.01 0.00 0.12 3.00 0.21 0.15 0.01 0.63 1.00 0.02 0.00 1.97 1.36 4.06 0.42 0.05 0.03 0.00 0.00 0.07 6.00 0.00 0.00 0.00 0.99 1.00 0.04 0.00 7.96 1.73 0.18 0.13 0.01 0.00 0.01 0.00 0.92 3.00 0.02 0.82 0.00 0.16 1.00 0.00 0.00 2.00 1.70 0.16 0.17 0.02 0.00 0.02 0.00 0.91 3.00 0.05 0.87 0.00 0.08 1.00 0.02 0.00 1.98 1.48 0.62 0.17 0.02 0.01 0.02 0.00 0.68 3.00 0.02 0.74 0.00 0.24 1.00 0.00 0.00 2.00 1.71 0.18 0.16 0.02 0.00 0.01 0.00 0.92 3.00 0.02 0.80 0.00 0.18 1.00 0.03 0.00 1.97 0.10 1.35 1.06 0.14 0.02 0.16 0.00 0.16 3.00 0.02 0.89 0.01 0.08 1.00 0.04 0.02 1.94 0.09 1.36 1.09 0.14 0.02 0.15 0.00 0.14 3.00 0.01 0.93 0.01 0.06 1.00 0.04 0.02 1.94 1.20 2.99 1.45 0.20 0.01 0.00 0.00 0.14 6.00 0.00 0.00 0.01 0.99 1.00 0.03 0.00 7.97 1.16 3.01 1.48 0.19 0.01 0.00 0.00 0.15 6.00 0.00 0.00 0.01 0.99 1.00 0.01 0.00 7.98 0.00 0.00 0.00 0.00 0.00 0.00 0.00 3.00 3.00 0.00 0.00 0.00 1.00 1.00 0.00 0.00 1.00 1.96 0.02 0.00 0.02 0.00 0.00 0.00 1.00 3.00 0.01 0.01 0.01 0.97 1.00 0.01 0.01 1.98 1.98 0.01 0.00 0.02 0.00 0.00 0.00 1.00 3.00 0.01 0.00 0.01 0.98 1.00 0.00 0.00 2.00 1.99 0.00 0.00 0.01 0.00 0.00 0.00 1.00 3.00 0.00 0.00 0.02 0.98 1.00 0.01 0.00 1.99 6.39 0.01 0.00 0.06 0.00 0.16 0.00 0.37 7.00 0.00 0.00 0.03 0.97 1.00 0.02 0.00 0.34 6.41 0.02 0.00 0.06 0.00 0.17 0.00 0.34 7.00 0.00 0.00 0.00 1.00 1.00 0.03 0.00 0.35 6.43 0.02 0.00 0.07 0.00 0.14 0.00 0.34 7.00 0.00 0.00 0.00 1.00 1.00 0.06 0.00 0.35 1.59 1.64 2.19 0.00 0.03 0.39 0.00 0.14 6.00 0.05 1.15 0.04 0.00 1.25 0.04 0.09 7.87 1.10 1.49 3.04 0.17 0.03 0.00 0.00 0.14 6.00 0.02 0.00 0.01 0.97 1.00 0.01 0.00 7.99 0.00 1.05 1.34 0.13 0.01 0.27 0.00 0.18 3.00 0.02 0.90 0.00 0.08 1.00 0.04 0.09 1.87 0.00 1.08 1.31 0.11 0.01 0.28 0.00 0.19 3.00 0.02 0.90 0.00 0.08 1.00 0.05 0.07 1.88 0.00 1.08 1.41 0.15 0.02 0.24 0.00 0.09 3.00 0.02 0.79 0.00 0.19 1.00 0.05 0.06 1.89 0.00 1.00 1.41 0.09 0.01 0.28 0.00 0.19 3.00 0.02 0.93 0.00 0.05 1.00 0.04 0.08 1.88 0.00 1.11 1.05 0.03 0.03 0.06 0.00 0.71 3.00 0.17 0.06 0.84 0.00 1.07 0.03 0.04 1.93 0.00 1.10 1.27 0.13 0.01 0.28 0.00 0.19 3.00 0.02 0.88 0.00 0.09 1.00 0.06 0.07 1.87 0.00 1.11 1.27 0.13 0.01 0.27 0.00 0.19 3.00 0.02 0.88 0.00 0.10 1.00 0.06 0.07 1.87 0.00 1.10 1.27 0.14 0.01 0.27 0.00 0.19 3.00 0.02 0.88 0.00 0.10 1.00 0.08 0.07 1.85 0.00 1.14 1.27 0.15 0.01 0.24 0.00 0.17 3.00 0.01 0.90 0.00 0.08 1.00 0.07 0.08 1.85 0.00 1.11 1.29 0.12 0.01 0.26 0.00 0.18 3.00 0.02 0.90 0.00 0.08 1.00 0.07 0.09 1.85 0.34 1.10 1.14 0.13 0.01 0.10 0.00 0.17 3.00 0.01 0.94 0.00 0.05 1.00 0.06 0.06 1.88 0.34 1.11 1.08 0.14 0.01 0.10 0.00 0.20 3.00 0.02 0.90 0.00 0.08 1.00 0.06 0.04 1.90 0.34 1.11 1.11 0.14 0.01 0.09 0.00 0.18 3.00 0.01 0.92 0.00 0.06 1.00 0.05 0.05 1.90 1.34 2.48 1.78 0.23 0.02 0.01 0.00 0.14 6.00 0.00 0.02 0.00 0.98 1.00 0.02 0.01 7.98 0.35 1.13 1.07 0.12 0.01 0.09 0.00 0.20 3.00 0.01 0.92 0.00 0.07 1.00 0.08 0.03 1.89 0.36 1.15 1.05 0.13 0.01 0.09 0.00 0.20 3.00 0.01 0.93 0.00 0.06 1.00 0.06 0.03 1.90 0.32 1.09 1.16 0.14 0.02 0.10 0.00 0.16 3.00 0.02 0.94 0.00 0.04 1.00 0.06 0.07 1.87 0.36 1.10 1.04 0.13 0.01 0.10 0.00 0.24 3.00 0.01 0.93 0.00 0.05 1.00 0.08 0.04 1.88 0.42 1.11 0.96 0.13 0.01 0.09 0.00 0.26 3.00 0.05 0.89 0.01 0.06 1.00 0.09 0.04 1.87 1.39 2.39 1.80 0.21 0.03 0.01 0.01 0.16 6.00 0.01 0.00 0.00 0.98 1.00 0.00 0.01 7.99 1.45 2.35 1.71 0.23 0.02 0.01 0.01 0.21 6.00 0.02 0.00 0.00 0.98 1.00 0.00 0.01 7.99 0.32 1.13 1.10 0.14 0.01 0.11 0.00 0.17 3.00 0.01 0.93 0.00 0.06 1.00 0.06 0.05 1.89 0.29 1.18 1.15 0.14 0.01 0.10 0.00 0.11 3.00 0.01 0.85 0.00 0.13 1.00 0.06 0.05 1.89 0.35 1.16 1.12 0.14 0.01 0.07 0.00 0.14 3.00 0.02 0.90 0.00 0.08 1.00 0.04 0.05 1.91 0.30 1.11 1.14 0.14 0.01 0.10 0.00 0.17 3.00 0.01 0.93 0.00 0.05 1.00 0.05 0.08 1.87 1.35 2.46 1.78 0.23 0.02 0.01 0.00 0.15 6.00 0.01 0.01 0.00 0.98 1.00 0.01 0.01 7.98 1.32 2.48 1.76 0.22 0.02 0.01 0.00 0.17 6.00 0.00 0.06 0.00 0.94 1.00 0.01 0.01 7.98 0.33 1.18 1.06 0.14 0.01 0.08 0.00 0.18 3.00 0.01 0.94 0.00 0.05 1.00 0.06 0.04 1.90 1.36 2.28 1.71 0.22 0.02 0.03 0.00 0.37 6.00 0.00 0.25 0.00 0.75 1.00 0.02 0.02 7.97 0.33 1.24 1.04 0.14 0.01 0.07 0.00 0.17 3.00 0.01 0.87 0.00 0.12 1.00 0.05 0.04 1.90 0.32 1.12 1.14 0.14 0.01 0.10 0.00 0.16 3.00 0.01 0.92 0.00 0.07 1.00 0.05 0.08 1.88 0.32 1.38 0.95 0.11 0.01 0.07 0.00 0.17 3.00 0.01 0.92 0.00 0.07 1.00 0.05 0.02 1.93 0.35 1.39 0.87 0.11 0.01 0.08 0.01 0.18 3.00 0.01 0.86 0.00 0.13 1.00 0.06 0.01 1.92 0.33 1.38 0.89 0.12 0.01 0.07 0.00 0.19 3.00 0.01 0.91 0.00 0.07 1.00 0.06 0.02 1.92 0.32 1.37 0.93 0.12 0.01 0.07 0.01 0.17 3.00 0.01 0.93 0.00 0.06 1.00 0.05 0.02 1.93 1.30 2.80 1.53 0.20 0.02 0.01 0.00 0.14 6.00 0.00 0.00 0.00 1.00 1.00 0.01 0.01 7.98 1.16 3.04 1.45 0.19 0.03 0.01 0.00 0.12 6.00 0.00 0.00 0.00 0.99 1.00 0.01 0.00 7.99 0.24 1.32 1.03 0.14 0.02 0.11 0.00 0.15 3.00 0.02 0.94 0.00 0.04 1.00 0.04 0.03 1.92 0.34 1.46 0.92 0.12 0.02 0.03 0.00 0.13 3.00 0.02 0.89 0.01 0.08 1.00 0.04 0.01 1.95 1.24 2.69 1.69 0.21 0.02 0.00 0.00 0.14 6.00 0.01 0.00 0.00 0.99 1.00 0.01 0.00 7.99 0.40 1.32 0.98 0.13 0.01 0.00 0.00 0.14 3.00 0.01 0.94 0.00 0.05 1.00 0.05 0.02 1.93 0.21 1.47 1.04 0.13 0.01 0.07 0.00 0.06 3.00 0.00 0.77 0.07 0.15 1.00 0.05 0.04 1.91 0.28 1.33 1.04 0.14 0.01 0.09 0.00 0.12 3.00 0.00 0.91 0.00 0.09 1.00 0.04 0.03 1.93 1.34 2.62 1.55 0.21 0.02 0.00 0.00 0.27 6.00 0.00 0.13 0.00 0.87 1.00 0.01 0.01 7.98 0.33 1.57 0.90 0.11 0.01 0.00 0.00 0.08 3.00 0.01 0.82 0.00 0.17 1.00 0.05 0.01 1.93 0.38 1.45 0.91 0.12 0.01 0.00 0.00 0.13 3.00 0.01 0.90 0.00 0.08 1.00 0.05 0.01 1.93 1.35 2.72 1.57 0.20 0.01 0.00 0.00 0.13 6.00 0.01 0.01 0.00 0.98 1.00 0.01 0.00 7.99 0.40 1.42 0.93 0.12 0.01 0.00 0.00 0.12 3.00 0.02 0.90 0.00 0.09 1.00 0.05 0.03 1.92 0.30 1.31 0.94 0.19 0.01 0.08 0.00 0.18 3.00 0.01 0.93 0.00 0.06 1.00 0.04 0.02 1.94 0.31 1.35 1.00 0.13 0.01 0.08 0.00 0.13 3.00 0.01 0.90 0.00 0.09 1.00 0.04 0.03 1.93 0.28 1.38 1.05 0.14 0.01 0.07 0.00 0.07 3.00 0.00 0.84 0.00 0.16 1.00 0.04 0.07 1.90 0.30 1.34 0.99 0.13 0.01 0.08 0.00 0.14 3.00 0.01 0.89 0.00 0.09 1.00 0.02 0.02 1.95 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.01 2.89 0.23 0.88 0.00 3.99 0.00 1.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 2.76 0.23 0.93 0.07 3.99 0.01 0.96 0.02 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.02 2.79 0.24 0.91 0.05 3.98 0.01 0.99 0.00 1.18 2.47 1.95 0.25 0.03 0.00 0.00 0.12 6.00 0.00 0.00 0.00 1.00 1.00 0.02 0.01 7.97 1.21 2.91 1.48 0.22 0.03 0.00 0.00 0.15 6.00 0.00 0.00 0.00 1.00 1.00 0.01 0.00 7.99 0.32 1.18 1.14 0.15 0.02 0.07 0.00 0.13 3.00 0.01 0.93 0.00 0.06 1.00 0.05 0.03 1.92 0.37 1.19 1.12 0.14 0.01 0.03 0.00 0.13 3.00 0.01 0.95 0.00 0.04 1.00 0.04 0.02 1.94 0.53 0.96 1.09 0.12 0.01 0.09 0.00 0.19 3.00 0.06 0.79 0.01 0.14 1.00 0.03 0.02 1.95 0.27 1.15 1.19 0.15 0.02 0.10 0.00 0.13 3.00 0.02 0.92 0.00 0.06 1.00 0.03 0.04 1.93 0.27 1.18 1.10 0.13 0.02 0.11 0.00 0.18 3.00 0.02 0.88 0.00 0.10 1.00 0.05 0.02 1.92 1.21 2.53 1.83 0.21 0.03 0.00 0.00 0.15 6.00 0.00 0.00 0.00 0.99 1.00 0.01 0.00 7.99 Sum 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 8.00 2.00 2.00 2.00 2.00 2.00 2.00 8.00 8.00 1.00 2.00 2.00 2.00 0.36 0.38 0.41 8.00 8.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 8.00 2.00 2.00 2.00 2.00 2.00 8.00 8.00 2.00 2.00 2.00 2.00 8.00 8.00 2.00 8.00 2.00 2.00 2.00 2.00 2.00 2.00 8.00 8.00 2.00 2.00 8.00 2.00 2.00 2.00 8.00 2.00 2.00 8.00 2.00 2.00 2.00 2.00 2.00 1.00 1.00 1.00 8.00 8.00 2.00 2.00 2.00 2.00 2.00 8.00 Table A5. Chemical analyses of pyroxenes from Copiapó, Chile

Locality Sample Spot no. Analysis no. Mineral SiO2 TiO2 Al2O3 B2O3 Cr2O3 Fe2O3 FeO MgO Cerro Bronce Estrella C2B-298 1 s2 Augite 53.78 0.03 0.26 0.00 0.03 1.13 2.78 16.07 San Gregorio S Granate C2B-808.2 2 c4 Augite 51.74 0.10 0.46 0.00 0.00 1.03 12.89 11.46 San Gregorio S Granate C2B-808.2 2 o1 Orthopyroxene 50.17 0.30 0.42 0.00 0.00 0.71 30.84 14.81 San Gregorio S Granate C2B-808.2 2 o2 Orthopyroxene 50.82 0.39 0.46 0.00 0.00 0.73 28.19 16.48 San Gregorio S Granate C2B-808.2 2 o3 Orthopyroxene 50.86 0.30 0.62 0.00 0.00 0.14 27.07 16.33 San Gregorio S Granate C2B-808.2 3 o1 Augite 51.67 0.09 0.51 0.00 0.00 1.19 12.41 11.61 San Gregorio S Granate C2B-808.2 3 o2 Augite 51.86 0.09 0.45 0.00 0.00 0.46 12.46 11.73 San Gregorio S Granate C2B-808.2 3 o3 Augite 51.54 0.25 0.93 0.00 0.00 1.27 10.43 12.35 San Gregorio S Granate C2B-808.2 3 o4 Augite 50.03 0.78 3.88 0.00 0.00 0.00 16.98 13.01 San Gregorio S Granate C2B-808.2 3 o5 Augite 52.02 0.03 0.22 0.00 0.01 0.65 12.41 11.43 IV A 3+ 2+ MnO CaO Na2OK2O F Cl Subtotal O=F+Cl Total Si Fe Al Sum Al Fe Na K 0.27 24.65 0.23 0.00 0.00 0.00 99.24 0.00 99.24 1.99 0.03 0.00 2.02 0.01 0.09 0.02 0.00 0.64 21.12 0.25 0.00 0.05 0.01 99.79 -0.02 99.77 1.98 0.03 0.00 2.01 0.02 0.41 0.02 0.00 1.39 1.22 0.00 0.00 0.00 0.01 99.96 0.00 99.96 1.97 0.02 0.01 2.00 0.01 1.01 0.00 0.00 0.95 1.97 0.00 0.01 0.00 0.00 100.08 0.00 100.08 1.97 0.02 0.01 2.00 0.01 0.91 0.00 0.00 0.93 2.82 0.07 0.00 0.00 0.01 99.23 0.00 99.23 1.98 0.00 0.02 2.00 0.01 0.88 0.01 0.00 0.64 21.06 0.27 0.01 0.04 0.00 99.56 -0.02 99.54 1.98 0.03 0.00 2.01 0.02 0.40 0.02 0.00 0.62 21.26 0.23 0.00 0.06 0.00 99.28 -0.03 99.25 1.98 0.01 0.00 2.00 0.02 0.40 0.02 0.00 0.51 21.78 0.22 0.00 0.01 0.00 99.35 0.00 99.35 1.96 0.04 0.00 2.00 0.04 0.33 0.02 0.00 0.45 10.99 0.86 0.35 0.19 0.17 97.82 -0.12 97.70 1.94 0.00 0.06 2.00 0.12 0.55 0.06 0.02 0.65 21.92 0.15 0.00 0.00 0.00 99.56 0.00 99.55 1.99 0.02 0.00 2.01 0.01 0.40 0.01 0.00 O Ca Mg Sc Ti V Cr Mn Cu Zn Sum F Cl O Total 0.98 0.88 0.00 0.00 0.00 0.00 0.01 0.00 0.00 1.98 0.00 0.00 6.00 6.00 0.86 0.65 0.00 0.00 0.00 0.00 0.02 0.00 0.00 1.99 0.01 0.00 5.99 6.00 0.05 0.87 0.00 0.01 0.00 0.00 0.05 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.08 0.95 0.00 0.01 0.00 0.00 0.03 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.12 0.95 0.00 0.01 0.00 0.00 0.03 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.86 0.66 0.00 0.00 0.00 0.00 0.02 0.00 0.00 1.99 0.00 0.00 6.00 6.00 0.87 0.67 0.00 0.00 0.00 0.00 0.02 0.00 0.00 2.00 0.01 0.00 5.99 6.00 0.89 0.70 0.00 0.01 0.00 0.00 0.02 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.46 0.75 0.00 0.02 0.00 0.00 0.01 0.00 0.00 2.00 0.02 0.01 5.96 6.00 0.90 0.65 0.00 0.00 0.00 0.00 0.02 0.00 0.00 1.99 0.00 0.00 6.00 6.00 Table A6. Chemical analyses of epidote from Copiapó, Chile

Locality Sample Spot no. Analysis no. SiO2 TiO2 Al2O3 Cr2O3 Fe2O3 FeO MgO MnO CaO Cerro Bronce Estrella C2B-298 2 e1 37.70 0.07 26.04 0.00 10.31 0.00 0.05 0.03 23.84 Cerro Negro Norte C6B-076 2 e1 36.19 0.00 25.54 0.01 10.99 0.00 0.03 0.26 22.97 Cerro Negro Norte C6B-076 2 e2 36.56 0.01 26.84 0.00 9.73 0.00 0.05 0.24 23.37 Cerro Negro Norte C6B-076 2 e3 36.78 0.02 23.58 0.00 13.33 0.00 0.02 0.11 23.22 San Gregorio S Granate C2B-352e 1 m1 38.65 0.01 31.29 0.00 1.74 0.25 0.00 1.62 23.52 San Gregorio S Granate C2B-671 1 e1 38.19 0.03 25.79 0.01 11.12 0.07 0.00 0.06 23.56 Santos PdC DDH289-037.5a 2 e1 37.25 0.12 24.37 0.04 12.28 0.00 0.02 0.15 23.52 Santos PdC DDH289-037.5a 2 e2 37.16 0.12 24.36 0.06 12.11 0.00 0.02 0.15 23.72 Santos PdC DDH291-188.4 1 e1 37.82 0.17 24.85 0.04 11.98 0.18 0.03 0.18 23.11 Santos PdC DDH291-188.4 1 e2 38.14 0.30 27.11 0.03 9.09 0.12 0.02 0.12 23.67 Santos PdC DDH384-004.2 1 e1 35.86 0.00 15.99 0.01 22.80 0.01 0.00 0.01 22.28 Santos PdC DDH384-004.2 1 e2 37.35 0.00 26.28 0.00 9.54 0.00 0.00 0.01 23.39 Santos PdC DDH384-004.2 1 e3 36.75 0.02 21.48 0.00 15.50 0.10 0.00 0.10 22.58 Santos PdC DDH384-004.2 1 x1 37.01 0.02 21.56 0.00 15.29 0.39 0.00 0.39 22.39 Santos PdC DDH628-094.2 2 e1 37.12 0.52 21.52 0.00 16.08 0.07 0.03 0.06 23.02 Santos PdC DDH643-595.5 2 e1 37.08 0.05 23.94 0.00 12.87 0.00 0.00 0.06 23.34 Santos PdC DDH643-595.5 2 e2 36.26 0.00 20.26 0.00 17.02 0.20 0.02 0.48 22.36 Santos PdC DDH643-595.5 3 e1 36.97 0.07 21.82 0.00 15.84 0.07 0.07 0.06 22.21 Santos PdC DDH684-079.8 1 s1 37.25 0.01 22.89 0.00 15.26 0.12 0.01 0.12 22.93 Santos PdC ME013-538 1 e1 37.46 0.03 23.37 0.00 13.91 0.20 0.03 0.19 22.86 Santos PdC ME013-538 2 e1 37.85 0.08 24.41 0.00 12.63 0.24 0.02 0.23 22.99 Santos PdC ME013-538 2 e2 37.63 0.00 25.56 0.00 11.32 0.00 0.00 0.10 23.56 Santos PdC ME013-538 2 e3 37.31 0.07 22.77 0.00 14.87 0.00 0.05 0.06 23.25 Santos PdC ME013-538 2 e4 37.93 0.05 23.86 0.00 13.86 0.13 0.03 0.13 23.14 IV Oct 2+ 3+ Na2OK2OH2O F Cl Subtotal O=F+Cl Total Si Al Sum Al Mg Mn Mn 0.01 0.00 1.89 0.04 0.00 99.97 -0.02 99.95 2.96 0.04 3.00 2.37 0.01 0.00 0.00 0.00 0.00 1.79 0.16 0.00 97.97 -0.07 97.90 2.91 0.09 3.00 2.33 0.00 0.00 0.02 0.02 0.00 1.81 0.17 0.00 98.86 -0.07 98.79 2.90 0.10 3.00 2.41 0.01 0.00 0.02 0.00 0.00 1.85 0.04 0.00 99.03 -0.02 99.01 2.95 0.05 3.00 2.18 0.00 0.00 0.01 0.02 0.07 1.94 0.00 0.02 99.20 -0.01 99.20 2.98 0.02 3.00 2.82 0.00 0.02 0.09 0.00 0.00 1.92 0.00 0.00 100.76 0.00 100.76 2.98 0.02 3.00 2.36 0.00 0.00 0.00 0.00 0.01 1.87 0.04 0.00 99.95 -0.02 99.93 2.95 0.05 3.00 2.23 0.00 0.00 0.01 0.00 0.00 1.89 0.00 0.00 99.86 0.00 99.86 2.95 0.05 3.00 2.22 0.00 0.00 0.01 0.03 0.01 1.89 0.03 0.00 100.33 -0.01 100.31 2.98 0.02 3.00 2.29 0.00 0.01 0.00 0.00 0.00 1.91 0.04 0.00 100.55 -0.02 100.53 2.97 0.03 3.00 2.46 0.00 0.01 0.00 0.00 0.00 1.76 0.07 0.00 98.79 -0.03 98.76 3.00 0.00 3.00 1.57 0.00 0.00 0.00 0.03 0.00 1.86 0.06 0.00 98.52 -0.03 98.50 2.97 0.03 3.00 2.43 0.00 0.00 0.00 0.01 0.00 1.82 0.04 0.00 98.42 -0.02 98.40 3.00 0.00 3.00 2.06 0.00 0.01 0.00 0.00 0.01 1.85 0.00 0.00 98.90 0.00 98.90 3.00 0.00 3.00 2.06 0.00 0.03 0.00 0.00 0.00 1.85 0.04 0.00 100.31 -0.02 100.29 2.98 0.02 3.00 2.01 0.00 0.00 0.00 0.03 0.00 1.85 0.05 0.00 99.27 -0.02 99.24 2.96 0.04 3.00 2.22 0.00 0.00 0.00 0.01 0.00 1.81 0.04 0.00 98.45 -0.02 98.44 2.97 0.03 3.00 1.93 0.00 0.01 0.02 0.00 0.01 1.80 0.10 0.02 99.03 -0.05 98.98 3.00 0.00 3.00 2.08 0.01 0.00 0.00 0.00 0.00 1.86 0.05 0.00 100.51 -0.02 100.49 2.96 0.04 3.00 2.11 0.00 0.01 0.00 0.03 0.02 1.85 0.06 0.03 100.06 -0.03 100.03 2.98 0.02 3.00 2.18 0.00 0.01 0.00 0.00 0.01 1.89 0.02 0.00 100.38 -0.01 100.37 2.99 0.01 3.00 2.26 0.00 0.02 0.00 0.00 0.01 1.89 0.04 0.00 100.15 -0.02 100.13 2.96 0.04 3.00 2.33 0.00 0.00 0.01 0.00 0.00 1.86 0.03 0.04 100.32 -0.02 100.30 2.97 0.03 3.00 2.11 0.01 0.00 0.00 0.00 0.00 1.91 0.00 0.00 101.43 0.00 101.43 2.98 0.02 3.00 2.19 0.00 0.01 0.00 AOH 3+ Fe Ti Cr Sum Na K Ca Sum F Cl OH Sum 0.61 0.00 0.00 2.99 0.00 0.00 2.01 2.01 0.01 0.00 0.99 1.00 0.67 0.00 0.00 3.02 0.00 0.00 1.98 1.98 0.04 0.00 0.96 1.00 0.58 0.00 0.00 3.01 0.00 0.00 1.98 1.99 0.04 0.00 0.96 1.00 0.80 0.00 0.00 3.00 0.00 0.00 2.00 2.00 0.01 0.00 0.99 1.00 0.12 0.00 0.00 3.05 0.00 0.01 1.94 1.95 0.00 0.00 1.00 1.00 0.66 0.00 0.00 3.03 0.00 0.00 1.97 1.97 0.00 0.00 1.00 1.00 0.73 0.01 0.00 3.00 0.00 0.00 2.00 2.00 0.01 0.00 0.99 1.00 0.72 0.01 0.00 2.99 0.00 0.00 2.01 2.01 0.00 0.00 1.00 1.00 0.72 0.01 0.00 3.04 0.00 0.00 1.95 1.96 0.01 0.00 0.99 1.00 0.54 0.02 0.00 3.03 0.00 0.00 1.97 1.97 0.01 0.00 0.99 1.00 1.43 0.00 0.00 3.01 0.00 0.00 1.99 1.99 0.02 0.00 0.98 1.00 0.57 0.00 0.00 3.00 0.00 0.00 1.99 2.00 0.02 0.00 0.98 1.00 0.96 0.00 0.00 3.03 0.00 0.00 1.97 1.97 0.01 0.00 0.99 1.00 0.96 0.00 0.00 3.05 0.00 0.00 1.95 1.95 0.00 0.00 1.00 1.00 0.97 0.03 0.00 3.02 0.00 0.00 1.98 1.98 0.01 0.00 0.99 1.00 0.77 0.00 0.00 3.00 0.00 0.00 2.00 2.00 0.01 0.00 0.99 1.00 1.06 0.00 0.00 3.03 0.00 0.00 1.97 1.97 0.01 0.00 0.99 1.00 0.97 0.00 0.00 3.07 0.00 0.00 1.93 1.93 0.03 0.00 0.97 1.00 0.92 0.00 0.00 3.04 0.00 0.00 1.96 1.96 0.01 0.00 0.99 1.00 0.85 0.00 0.00 3.04 0.00 0.00 1.95 1.96 0.02 0.00 0.98 1.00 0.77 0.00 0.00 3.05 0.00 0.00 1.95 1.95 0.00 0.00 1.00 1.00 0.67 0.00 0.00 3.01 0.00 0.00 1.99 1.99 0.01 0.00 0.99 1.00 0.89 0.00 0.00 3.02 0.00 0.00 1.98 1.98 0.01 0.01 0.99 1.00 0.83 0.00 0.00 3.05 0.00 0.00 1.95 1.95 0.00 0.00 1.00 1.00 Table A7. Chemical analyses of amphiboles from Copiapó, Chile

Locality Sample Spot no. Analysis no. Mineral SiO2 TiO2 Al2O3 B2O3 Cr2O3 Fe2O3 FeO Cerro Buitre Radio Tower C2J-334 1 c1 Magnesiohornblende 45.87 0.28 7.86 0.00 0.01 5.50 11.97 Cerro Buitre Radio Tower C2J-334 1 b1 Magnesiohornblende 48.56 0.28 5.31 0.00 0.01 4.33 10.90 Cerro Buitre Radio Tower C2J-334 1 m2 Magnesiohornblende 49.57 0.25 4.89 0.00 0.00 3.84 10.94 Cerro Buitre Radio Tower C2J-334 1 b2 Magnesiohornblende 48.80 0.31 5.44 0.00 0.00 4.29 10.91 Cerro Buitre Radio Tower C2J-334 1 b3 Magnesiohornblende 46.97 0.17 7.16 0.00 0.01 5.53 11.74 Cerro Buitre Radio Tower C2J-334 1 b4 Magnesiohornblende 49.15 0.19 5.42 0.00 0.00 5.72 10.00 Cerro Buitre Radio Tower C2J-334 1 b6 Magnesiohornblende 46.96 0.68 6.68 0.00 0.00 0.00 15.15 Cerro Buitre Radio Tower C2J-334 1 a2 Actinolite 52.04 0.17 2.37 0.00 0.01 2.81 9.58 Cerro Buitre Radio Tower C2J-334 2 a2 Magnesiohornblende 47.87 0.29 5.61 0.00 0.00 4.57 11.46 Cerro Buitre Radio Tower C2J-334 2 a3 Magnesiohornblende 48.24 0.26 5.83 0.00 0.01 4.51 11.70 Cerro Buitre Radio Tower C2J-334 2 a4 Magnesiohornblende 47.25 0.11 6.66 0.00 0.00 3.29 12.44 Cerro Buitre Radio Tower C2J-334 2 a5 Actinolite 51.83 0.19 3.43 0.00 0.00 3.53 9.92 Cerro Buitre Radio Tower C2J-334 2 a6 Magnesiohornblende 49.46 0.20 4.91 0.00 0.00 3.13 11.69 Cerro Buitre Radio Tower C2J-334 2 c1 Magnesiohornblende 50.85 0.24 4.39 0.00 0.01 3.14 10.94 Cerro Buitre Radio Tower C2J-334 3 a1 Magnesiohornblende 49.96 0.20 4.59 0.00 0.00 3.40 11.31 Cerro Buitre Radio Tower C2J-334 3 a2 Magnesiohornblende 48.95 0.23 5.62 0.00 0.00 5.28 10.48 Cerro Buitre Radio Tower C2J-334 3 a4 Magnesiohornblende 51.25 0.21 4.67 0.00 0.01 3.98 10.15 Cerro Negro Norte C6B-076 3 a1 Magnesiohornblende 50.17 0.43 4.61 0.00 0.00 3.96 6.44 Cerro Negro Norte C6B-076 3 a2 Magnesiohornblende 49.40 0.45 5.21 0.00 0.00 5.85 5.30 Cerro Negro Norte C6B-076 3 a3 Magnesiohornblende 50.98 0.33 3.97 0.00 0.00 4.16 5.83 Cerro Negro Norte C6B-076 3 a4 Magnesiohornblende 51.43 0.31 3.63 0.00 0.00 1.89 7.89 Cerro Negro Norte C6B-076 3 a5 Actinolite 52.41 0.27 3.15 0.00 0.00 2.74 6.43 Cerro Negro Norte C6B-076 4 a1 Magnesiohornblende 52.00 0.24 4.22 0.00 0.00 3.13 6.70 Cerro Negro Norte C6B-076 4 a2 Magnesiohornblende 50.46 0.43 4.81 0.00 0.00 4.36 6.34 Cerro Negro Norte C6B-076 4 a3 Actinolite 53.13 0.05 2.70 0.00 0.00 2.08 8.17 Cerro Negro Norte C6B-076 4 a4 Magnesiohornblende 49.62 0.46 5.25 0.00 0.01 4.58 6.33 Cerro Negro Norte C6B-076 4 a5 Magnesiohornblende 50.74 0.40 4.64 0.00 0.00 4.81 5.97 Cerro Negro Norte C6B-076 4 t15 Magnesiohornblende 49.97 0.21 6.97 0.00 0.00 0.00 10.90 San Gregorio S Granate C2B-655 1 cpx1 Actinolite 52.69 0.02 1.38 0.00 0.00 1.84 15.38 San Gregorio S Granate C2B-655 1 cpx2 Actinolite 52.54 0.02 1.19 0.00 0.01 0.91 17.07 San Gregorio S Granate C2B-655 1 a1 Actinolite 52.82 0.02 1.19 0.00 0.00 1.34 15.61 San Gregorio S Granate C2B-655 2 a1 Actinolite 53.06 0.05 1.40 0.00 0.00 0.74 14.13 San Gregorio S Granate C2B-655 2 a2 Magnesiohornblende 50.83 0.07 3.59 0.00 0.00 3.60 12.57 San Gregorio S Granate C2B-655 2 e1 Actinolite 53.18 0.03 1.21 0.00 0.00 0.00 13.37 San Gregorio S Granate C2B-671 1 a1 Actinolite 51.39 0.05 3.25 0.00 0.00 2.21 12.74 San Gregorio S Granate C2B-671 2 a1 Actinolite 52.65 0.15 2.44 0.00 0.00 1.30 10.21 San Gregorio S Granate C2B-671 2 a2 Magnesiohornblende 50.62 0.20 3.78 0.00 0.00 4.56 10.81 San Gregorio S Granate C2B-671 2 a3 Actinolite 52.20 0.23 2.63 0.00 0.00 1.38 10.52 San Gregorio S Granate C2B-808.2 1 c1 Chloro-potassichastingsite 35.13 0.06 10.22 0.00 0.00 8.62 25.59 San Gregorio S Granate C2B-808.2 1 c2 Chloro-potassichastingsite 35.15 0.03 11.89 0.00 0.00 8.48 24.57 San Gregorio S Granate C2B-808.2 2 b1 Actinolite 52.90 0.18 1.08 0.00 0.00 1.28 17.09 San Gregorio S Granate C2B-808.2 2 b2 Actinolite 51.80 0.30 1.72 0.00 0.00 2.65 18.35 San Gregorio S Granate C2B-808.2 2 c1 Ferrohornblende 46.42 1.16 6.42 0.00 0.00 0.35 19.42 San Gregorio S Granate C2B-808.2 2 c2 Magnesiohornblende 47.35 0.93 5.74 0.00 0.00 0.51 19.10 San Gregorio S Granate C2B-808.2 2 c3 Magnesiohornblende 47.14 1.10 5.82 0.00 0.00 0.00 19.05 San Gregorio S Granate C2B-808.2 3 c1 Ferro-edenite 46.33 1.34 6.44 0.00 0.00 0.14 19.33 San Gregorio S Granate C2B-808.2 3 c2 Ferro-edenite 46.09 1.34 6.53 0.00 0.00 0.57 19.43 San Gregorio S Granate C2B-808.2 3 c3 Edenite 46.85 1.24 6.02 0.00 0.01 0.00 18.87 IV M1, M2, M3, M4

MgO MnO CaO Na2OK2OH2O F Cl Subtotal O=F+Cl Total Si B Al Sum Al Mg 11.31 0.53 11.86 0.97 0.58 1.97 0.03 0.09 98.95 -0.03 98.91 6.86 0.00 1.14 8.00 0.25 2.52 13.19 0.59 12.07 0.72 0.36 1.97 0.09 0.05 98.52 -0.05 98.47 7.20 0.00 0.80 8.00 0.13 2.92 13.58 0.56 12.14 0.67 0.30 1.96 0.12 0.07 99.00 -0.07 98.94 7.29 0.00 0.71 8.00 0.14 2.98 13.24 0.51 12.05 0.71 0.38 2.00 0.04 0.05 98.84 -0.03 98.81 7.20 0.00 0.80 8.00 0.15 2.91 11.93 0.46 12.10 0.87 0.46 1.97 0.08 0.07 99.66 -0.05 99.61 6.95 0.00 1.05 8.00 0.20 2.63 13.68 0.50 12.24 0.66 0.36 2.02 0.05 0.06 100.16 -0.03 100.13 7.16 0.00 0.84 8.00 0.09 2.97 13.16 0.52 10.36 0.44 1.70 1.90 0.14 0.05 97.85 -0.07 97.78 7.10 0.00 0.90 8.00 0.29 2.96 15.58 0.54 12.46 0.32 0.11 2.00 0.09 0.02 98.26 -0.04 98.22 7.61 0.00 0.39 8.00 0.02 3.40 12.62 0.54 12.03 0.72 0.39 1.94 0.11 0.06 98.31 -0.06 98.25 7.15 0.00 0.85 8.00 0.13 2.81 12.64 0.51 12.11 0.77 0.38 1.97 0.09 0.07 99.19 -0.05 99.13 7.14 0.00 0.86 8.00 0.16 2.79 12.20 0.47 12.30 0.79 0.35 1.93 0.11 0.05 98.03 -0.06 97.97 7.09 0.00 0.91 8.00 0.26 2.73 14.87 0.59 12.23 0.43 0.20 2.02 0.08 0.03 99.41 -0.04 99.37 7.51 0.00 0.49 8.00 0.10 3.21 13.20 0.53 12.11 0.61 0.30 1.97 0.09 0.04 98.31 -0.05 98.26 7.33 0.00 0.67 8.00 0.19 2.92 14.01 0.55 12.19 0.51 0.30 1.99 0.13 0.03 99.36 -0.06 99.30 7.42 0.00 0.58 8.00 0.17 3.05 13.49 0.54 12.10 0.56 0.31 2.01 0.04 0.04 98.62 -0.02 98.60 7.37 0.00 0.63 8.00 0.16 2.96 13.22 0.58 12.07 0.74 0.30 1.97 0.14 0.04 99.74 -0.07 99.67 7.17 0.00 0.83 8.00 0.14 2.89 14.56 0.67 12.18 0.35 1.16 2.03 0.12 0.04 101.48 -0.06 101.43 7.34 0.00 0.66 8.00 0.13 3.11 16.88 0.02 12.13 0.93 0.38 1.94 0.22 0.10 98.25 -0.11 98.14 7.29 0.00 0.71 8.00 0.08 3.65 16.70 0.04 11.84 1.03 0.41 1.95 0.18 0.11 98.50 -0.10 98.40 7.16 0.00 0.84 8.00 0.05 3.61 17.31 0.05 12.09 0.78 0.32 1.95 0.20 0.10 98.10 -0.11 97.99 7.38 0.00 0.62 8.00 0.06 3.74 17.16 0.04 12.71 0.60 0.29 1.96 0.17 0.09 98.21 -0.09 98.12 7.46 0.00 0.54 8.00 0.08 3.71 17.77 0.03 12.42 0.52 0.23 1.97 0.20 0.06 98.21 -0.10 98.11 7.55 0.00 0.45 8.00 0.08 3.81 17.02 0.03 12.42 0.44 0.10 2.05 0.08 0.00 98.47 -0.03 98.44 7.47 0.00 0.53 8.00 0.18 3.64 17.01 0.05 12.21 0.99 0.42 1.95 0.24 0.10 99.40 -0.12 99.28 7.25 0.00 0.75 8.00 0.07 3.64 17.25 0.04 12.79 0.33 0.08 2.00 0.14 0.07 98.86 -0.07 98.79 7.63 0.00 0.37 8.00 0.09 3.69 16.63 0.02 12.14 0.94 0.48 1.93 0.22 0.14 98.77 -0.12 98.65 7.19 0.00 0.81 8.00 0.09 3.59 17.12 0.02 12.21 0.86 0.39 1.94 0.26 0.10 99.49 -0.13 99.36 7.27 0.00 0.73 8.00 0.06 3.66 15.38 0.04 10.69 0.68 0.19 1.94 0.15 0.11 97.28 -0.09 97.19 7.36 0.00 0.64 8.00 0.56 3.37 13.07 0.22 12.56 0.16 0.07 1.96 0.09 0.11 99.55 -0.06 99.49 7.76 0.00 0.24 8.00 0.00 2.87 12.09 0.28 12.38 0.15 0.08 1.95 0.06 0.11 98.86 -0.05 98.81 7.83 0.00 0.17 8.00 0.04 2.69 12.95 0.27 12.44 0.16 0.06 1.98 0.05 0.10 98.98 -0.04 98.94 7.82 0.00 0.18 8.00 0.03 2.86 13.94 0.18 12.42 0.18 0.08 1.97 0.09 0.07 98.31 -0.05 98.26 7.83 0.00 0.17 8.00 0.08 3.07 13.51 0.15 12.42 0.42 0.14 1.94 0.17 0.08 99.51 -0.09 99.42 7.46 0.00 0.54 8.00 0.08 2.96 14.64 0.12 12.44 0.22 0.05 1.98 0.09 0.02 97.34 -0.04 97.30 7.88 0.00 0.12 8.00 0.09 3.23 13.89 0.15 12.51 0.31 0.22 1.96 0.05 0.20 98.94 -0.07 98.87 7.56 0.00 0.44 8.00 0.12 3.05 16.07 0.09 12.56 0.38 0.13 1.98 0.11 0.08 98.16 -0.06 98.10 7.67 0.00 0.33 8.00 0.09 3.49 13.71 0.41 11.94 0.43 0.23 1.96 0.10 0.15 98.89 -0.08 98.81 7.44 0.00 0.56 8.00 0.09 3.00 15.65 0.14 12.48 0.38 0.14 1.97 0.12 0.08 97.92 -0.07 97.86 7.65 0.00 0.35 8.00 0.10 3.42 0.48 0.46 10.58 0.99 3.02 0.35 0.02 5.51 101.09 -1.25 99.84 5.99 0.00 2.01 8.00 0.04 0.12 0.75 0.53 10.92 0.65 3.27 0.87 0.04 3.57 100.78 -0.82 99.96 5.88 0.00 2.12 8.00 0.22 0.19 11.94 0.38 12.33 0.07 0.05 1.97 0.09 0.03 99.45 -0.05 99.40 7.84 0.00 0.16 8.00 0.03 2.64 10.46 0.44 12.11 0.15 0.08 1.98 0.05 0.05 100.18 -0.03 100.15 7.71 0.00 0.29 8.00 0.01 2.32 10.36 0.46 10.93 1.19 0.64 1.84 0.12 0.31 99.80 -0.12 99.68 7.03 0.00 0.97 8.00 0.18 2.34 10.86 0.55 10.80 1.08 0.55 1.83 0.19 0.26 99.87 -0.14 99.73 7.14 0.00 0.86 8.00 0.16 2.44 11.17 0.43 10.78 1.23 0.63 1.79 0.27 0.29 99.82 -0.18 99.64 7.11 0.00 0.89 8.00 0.15 2.51 10.74 0.40 10.82 1.28 0.73 1.79 0.25 0.30 100.07 -0.18 99.89 7.00 0.00 1.00 8.00 0.15 2.42 10.38 0.48 10.85 1.23 0.70 1.81 0.20 0.32 100.08 -0.15 99.93 6.98 0.00 1.02 8.00 0.14 2.34 11.15 0.44 10.79 1.32 0.66 1.82 0.19 0.29 99.83 -0.15 99.69 7.07 0.00 0.93 8.00 0.14 2.51 AOH 2+ 3+ Fe Fe Mn Ti Cr Ca Sum Na K □ Sum F Cl OH Sum Mg/Mg+Fe 1.50 0.62 0.07 0.03 0.00 1.90 6.90 0.28 0.11 0.61 1.00 0.02 0.02 1.96 2.00 0.63 1.35 0.48 0.07 0.03 0.00 1.92 6.92 0.21 0.07 0.72 1.00 0.04 0.01 1.94 2.00 0.68 1.35 0.42 0.07 0.03 0.00 1.91 6.91 0.19 0.06 0.75 1.00 0.05 0.02 1.93 2.00 0.69 1.35 0.48 0.06 0.03 0.00 1.91 6.91 0.20 0.07 0.73 1.00 0.02 0.01 1.97 2.00 0.68 1.45 0.62 0.06 0.02 0.00 1.92 6.92 0.25 0.09 0.66 1.00 0.04 0.02 1.94 2.00 0.64 1.22 0.63 0.06 0.02 0.00 1.91 6.91 0.19 0.07 0.75 1.00 0.02 0.01 1.96 2.00 0.71 1.92 0.00 0.07 0.08 0.00 1.68 7.00 0.13 0.33 0.54 1.00 0.07 0.01 1.92 2.00 0.61 1.17 0.31 0.07 0.02 0.00 1.95 6.95 0.09 0.02 0.89 1.00 0.04 0.00 1.95 2.00 0.74 1.43 0.51 0.07 0.03 0.00 1.92 6.92 0.21 0.07 0.72 1.00 0.05 0.02 1.93 2.00 0.66 1.45 0.50 0.06 0.03 0.00 1.92 6.92 0.22 0.07 0.71 1.00 0.04 0.02 1.94 2.00 0.66 1.56 0.37 0.06 0.01 0.00 1.98 6.98 0.23 0.07 0.70 1.00 0.05 0.01 1.94 2.00 0.64 1.20 0.38 0.07 0.02 0.00 1.90 6.90 0.12 0.04 0.84 1.00 0.04 0.01 1.96 2.00 0.73 1.45 0.35 0.07 0.02 0.00 1.92 6.92 0.18 0.06 0.77 1.00 0.04 0.01 1.95 2.00 0.67 1.33 0.34 0.07 0.03 0.00 1.90 6.90 0.14 0.06 0.80 1.00 0.06 0.01 1.93 2.00 0.70 1.39 0.38 0.07 0.02 0.00 1.91 6.91 0.16 0.06 0.78 1.00 0.02 0.01 1.97 2.00 0.68 1.28 0.58 0.07 0.02 0.00 1.89 6.89 0.21 0.06 0.73 1.00 0.06 0.01 1.93 2.00 0.69 1.22 0.43 0.08 0.02 0.00 1.87 6.87 0.10 0.21 0.69 1.00 0.05 0.01 1.94 2.00 0.72 0.78 0.43 0.00 0.05 0.00 1.89 6.89 0.26 0.07 0.67 1.00 0.10 0.02 1.88 2.00 0.82 0.64 0.64 0.00 0.05 0.00 1.84 6.84 0.29 0.08 0.64 1.00 0.08 0.03 1.89 2.00 0.85 0.71 0.45 0.01 0.04 0.00 1.88 6.88 0.22 0.06 0.72 1.00 0.09 0.02 1.88 2.00 0.84 0.96 0.21 0.00 0.03 0.00 1.98 6.98 0.17 0.05 0.78 1.00 0.08 0.02 1.90 2.00 0.79 0.77 0.30 0.00 0.03 0.00 1.92 6.92 0.14 0.04 0.81 1.00 0.09 0.02 1.89 2.00 0.83 0.80 0.34 0.00 0.03 0.00 1.91 6.91 0.12 0.02 0.86 1.00 0.03 0.00 1.97 2.00 0.82 0.76 0.47 0.01 0.05 0.00 1.88 6.88 0.28 0.08 0.65 1.00 0.11 0.02 1.87 2.00 0.83 0.98 0.22 0.00 0.01 0.00 1.97 6.97 0.09 0.02 0.89 1.00 0.06 0.02 1.92 2.00 0.79 0.77 0.50 0.00 0.05 0.00 1.88 6.88 0.26 0.09 0.65 1.00 0.10 0.03 1.87 2.00 0.82 0.72 0.52 0.00 0.04 0.00 1.87 6.87 0.24 0.07 0.69 1.00 0.12 0.03 1.86 2.00 0.84 1.34 0.00 0.01 0.02 0.00 1.69 7.00 0.20 0.04 0.77 1.00 0.07 0.03 1.91 2.00 0.72 1.90 0.20 0.03 0.00 0.00 1.98 6.98 0.05 0.01 0.94 1.00 0.04 0.03 1.93 2.00 0.60 2.13 0.10 0.04 0.00 0.00 1.98 6.98 0.04 0.02 0.94 1.00 0.03 0.03 1.94 2.00 0.56 1.93 0.15 0.03 0.00 0.00 1.97 6.97 0.05 0.01 0.94 1.00 0.02 0.03 1.95 2.00 0.60 1.74 0.08 0.02 0.01 0.00 1.97 6.97 0.05 0.02 0.93 1.00 0.04 0.02 1.94 2.00 0.64 1.54 0.40 0.02 0.01 0.00 1.95 6.95 0.12 0.03 0.85 1.00 0.08 0.02 1.90 2.00 0.66 1.66 0.00 0.01 0.00 0.00 1.97 6.97 0.06 0.01 0.93 1.00 0.04 0.01 1.95 2.00 0.66 1.57 0.24 0.02 0.01 0.00 1.97 6.97 0.09 0.04 0.87 1.00 0.02 0.05 1.93 2.00 0.66 1.25 0.14 0.01 0.02 0.00 1.96 6.96 0.11 0.02 0.87 1.00 0.05 0.02 1.93 2.00 0.74 1.33 0.50 0.05 0.02 0.00 1.88 6.88 0.12 0.04 0.83 1.00 0.05 0.04 1.92 2.00 0.69 1.29 0.15 0.02 0.03 0.00 1.96 6.96 0.11 0.03 0.87 1.00 0.06 0.02 1.92 2.00 0.73 3.65 1.11 0.07 0.01 0.00 1.93 6.93 0.33 0.66 0.02 1.00 0.01 1.59 0.40 2.00 0.03 3.44 1.07 0.08 0.00 0.00 1.96 6.96 0.21 0.70 0.09 1.00 0.02 1.01 0.97 2.00 0.05 2.12 0.14 0.05 0.02 0.00 1.96 6.96 0.02 0.01 0.97 1.00 0.04 0.01 1.95 2.00 0.55 2.28 0.30 0.06 0.03 0.00 1.93 6.93 0.04 0.02 0.94 1.00 0.02 0.01 1.96 2.00 0.50 2.46 0.04 0.06 0.13 0.00 1.77 7.00 0.35 0.12 0.53 1.00 0.06 0.08 1.86 2.00 0.49 2.41 0.06 0.07 0.11 0.00 1.74 7.00 0.32 0.11 0.58 1.00 0.09 0.07 1.84 2.00 0.50 2.40 0.00 0.06 0.13 0.00 1.74 7.00 0.36 0.12 0.52 1.00 0.13 0.07 1.80 2.00 0.51 2.44 0.02 0.05 0.15 0.00 1.75 7.00 0.38 0.14 0.48 1.00 0.12 0.08 1.80 2.00 0.50 2.46 0.07 0.06 0.15 0.00 1.76 7.00 0.36 0.13 0.50 1.00 0.09 0.08 1.82 2.00 0.49 2.38 0.00 0.06 0.14 0.00 1.74 7.00 0.39 0.13 0.49 1.00 0.09 0.07 1.83 2.00 0.51 Table A8. Chemical analyses of oxides from Copiapó, Chile

Locality Sample Spot no. Analysis no. Mineral SiO2 TiO2 Al2O3 Cr2O3 Fe2O3 Cerro Bronce Estrella C2B-298 1 s1 Titanite 29.95 35.23 2.95 0.01 1.12 Cerro Bronce Estrella C2B-298 1 r1 Rutile 0.06 99.15 0.00 0.03 0.64 Cerro Bronce Estrella C2B-708 2 h1 Hematite 0.00 0.03 0.59 0.00 98.01 Cerro Buitre Radio Tower C2J-124 3 h2 Hematite 0.06 9.01 0.12 0.02 79.92 Cerro Buitre Radio Tower C2J-334 1 h1 Magnetite 0.07 0.12 0.09 0.03 100.13 Cerro Buitre Radio Tower C2J-334 2 m1 Magnetite 0.09 0.15 0.05 0.06 99.00 Cerro Buitre Radio Tower C2J-334 3 m1 Titanite 29.79 39.08 0.71 0.00 1.00 Cerro Buitre Radio Tower C2J-334 3 m2 Ilmenite 0.04 48.25 0.00 0.00 7.67 Cerro Buitre Radio Tower C2B-576c 1 h1 Magnetite 0.25 0.13 0.23 0.01 96.63 Cerro Granate C3B-072a 2 h1 Hematite 0.31 0.53 0.64 0.00 96.44 Cerro Negro Norte C6B-076 1 o1 Titanite 29.84 36.18 2.03 0.00 1.05 Cerro Negro Norte C6B-076 1 o2 Titanite 29.77 37.48 1.42 0.00 0.86 Cerro Negro Norte C6B-076 2 m1 Magnetite 1.98 0.04 0.47 0.01 96.15 Cerro Negro Norte C6B-076 2 m2 Magnetite 0.14 0.04 0.15 0.02 100.03 Cerro Negro Norte C6B-076 4 m2 Magnetite 0.12 0.02 0.06 0.01 98.77 Falla Ojancos Transito San Francisco C6B-101b 1 i1 Ilmenite 0.15 47.45 0.08 0.04 6.36 Falla Ojancos Transito San Francisco C6B-160b 1 r1 Rutile 0.26 97.80 0.02 0.01 1.07 Falla Ojancos Transito San Francisco C6B-160b 1 h1 Hematite 0.09 10.04 0.16 0.03 79.00 Falla Ojancos Transito San Francisco C6B-160b 1 h2 Hematite 0.07 8.40 0.14 0.03 83.12 Falla Ojancos Transito San Francisco C6B-160b 2 h1 Hematite 0.07 15.39 0.09 0.03 67.77 Falla Ojancos Transito San Francisco C6B-160b 2 s1 Rutile 0.36 97.64 0.00 0.00 0.98 Jesus Maria C7B-003a 3 m1 Hematite 0.00 4.52 0.35 0.03 90.17 San Gregorio S Granate C2B-352e 1 h1 Ilmenite 0.03 49.03 0.00 0.00 6.56 San Gregorio S Granate C2B-352e 1 s1 Titanite 31.31 28.66 7.87 0.00 0.73 San Gregorio S Granate C2B-655 1 m1 Magnetite 1.01 0.07 0.40 0.01 99.84 San Gregorio S Granate C2B-671 2 s1 Titanite 29.91 37.40 0.94 0.07 0.81 San Gregorio S Granate C2B-671 4 s1 Titanite 29.39 36.56 1.02 0.00 1.56 San Gregorio S Granate C2B-671 4 s2 Titanite 29.50 37.40 0.91 0.00 1.20 San Gregorio S Granate C2B-671 4 s3 Titanite 29.93 37.60 1.02 0.00 1.33 San Gregorio S Granate C2B-808.2 2 s1 Titanite 30.34 37.50 1.38 0.00 1.33 San Gregorio S Granate C2B-808.2 2 s2 Titanite 30.21 36.78 1.98 0.00 1.50 San Gregorio S Granate C2B-808.2 2 h1 Magnetite 0.07 1.35 1.36 0.03 98.00 San Gregorio S Granate C2B-808.2 3 i1 Ilmenite 0.03 51.12 0.00 0.00 3.60 San Gregorio S Granate C2B-808.2 3 m1 Magnetite 0.08 1.75 0.74 0.03 97.35 San Gregorio S Granate C2B-808.2 3 m2 Magnetite 0.07 1.78 0.77 0.04 97.78 San Gregorio S Granate C2B-808.2 3 i2 Ilmenite 0.05 49.11 0.00 0.00 6.62 San Gregorio S Granate C2B-808.2 3 m3 Magnetite 0.06 1.43 0.49 0.04 98.01 Santos PdC DDH289-037.5a 1 h1 Magnetite 0.47 3.59 0.26 0.16 96.35 Santos PdC DDH289-037.5a 1 r1 Rutile 0.13 97.10 0.02 0.00 2.46 Santos PdC DDH289-037.5a 1 r2 Rutile 6.95 66.77 0.19 0.00 18.53 Santos PdC DDH289-037.5a 1 r3 Rutile 0.06 98.73 0.00 0.01 0.60 Santos PdC DDH289-037.5a 1 r4 Rutile 0.15 97.86 0.02 0.00 0.77 Santos PdC DDH289-037.5a 2 r1 Ilmenite 0.02 50.34 0.00 0.00 4.62 Santos PdC DDH289-037.5a 2 r2 Ilmenite 0.04 49.87 0.02 0.00 4.99 Santos PdC DDH289-037.5a 3 r1 Rutile 0.06 98.18 0.02 0.00 1.36 Santos PdC DDH289-037.5a 3 r2 Ilmenite 8.94 36.36 8.62 0.01 8.56 Santos PdC DDH289-037.5a 3 r3 Rutile 0.32 91.91 0.04 0.00 4.92 Santos PdC DDH289-037.5a 2 h1 Magnetite 1.15 0.09 0.48 0.02 99.30 Santos PdC DDH289-037.5a 2 h2 Magnetite 0.19 0.03 0.07 0.05 100.75 Santos PdC DDH291-188.4 1 h1 Magnetite 0.51 0.07 0.17 0.62 101.50 Santos PdC DDH291-188.4 2 m1 Magnetite 0.36 0.03 0.04 0.49 101.53 Santos PdC DDH384-004.2 1 h1 Hematite 0.02 0.00 0.08 0.00 99.67 Santos PdC DDH628-094.2 1 h1 Hematite 0.94 0.08 0.47 0.01 100.29 Santos PdC DDH628-151.6 3 m1 Magnetite 0.15 0.02 0.04 0.00 100.38 Santos PdC DDH643-595.5 3 m1 Magnetite 0.17 0.02 0.04 0.01 101.76 Santos PdC DDH684-079.8 1 m1 Magnetite 2.95 0.05 0.07 0.01 92.33 Santos PdC ME013-538 2 s1 Titanite 30.31 38.17 1.23 0.07 1.16 VI 3+ 2+ FeO MgO MnO CaO Na2OK2OH2O Cl Subtotal O=F+Cl Total Si Fe Fe 0.00 0.00 0.00 28.53 0.01 0.01 0.53 0.01 98.35 -0.23 98.13 0.98 0.03 0.00 0.00 0.02 0.00 0.18 0.01 0.01 0.00 0.01 100.12 0.00 100.12 0.00 0.01 0.00 0.00 0.03 0.01 0.00 0.00 0.04 0.01 0.00 98.72 0.00 98.72 0.00 1.98 0.00 7.80 0.04 0.04 0.01 0.00 0.07 0.00 0.01 98.00 0.00 98.00 0.00 1.61 0.18 0.00 0.00 0.18 0.05 0.01 0.01 0.00 0.01 101.12 0.00 101.12 0.00 1.98 0.00 0.00 0.03 0.11 0.16 0.01 0.01 0.01 0.00 100.00 -0.01 99.99 0.00 1.98 0.00 0.00 0.00 0.09 27.83 0.00 0.14 0.23 0.00 100.62 -0.10 100.52 0.97 0.02 0.00 39.25 0.36 3.37 0.02 0.00 0.01 0.01 0.01 101.06 -0.01 101.05 0.00 0.14 0.82 0.20 0.03 0.04 0.08 0.00 0.00 0.00 0.01 97.62 0.00 97.61 0.01 1.97 0.00 0.66 0.00 0.00 0.02 0.02 0.02 0.02 0.01 98.66 -0.01 98.65 0.01 1.94 0.01 0.00 0.03 0.00 27.92 0.00 0.00 0.30 0.00 99.03 -0.13 98.91 0.98 0.03 0.00 0.00 0.00 0.00 27.88 0.00 0.01 0.13 0.00 99.21 -0.06 99.16 0.98 0.02 0.00 0.58 0.46 0.00 0.29 0.05 0.14 0.06 0.08 100.34 -0.04 100.30 0.05 1.89 0.01 0.04 0.03 0.04 0.03 0.00 0.00 0.00 0.00 100.61 0.00 100.61 0.00 1.98 0.00 0.00 0.00 0.00 0.08 0.01 0.06 0.02 0.10 99.31 -0.03 99.28 0.00 1.99 0.00 37.65 0.05 4.95 0.05 0.00 0.01 0.00 0.02 96.79 0.00 96.79 0.00 0.12 0.82 0.00 0.00 0.03 0.01 0.03 0.01 0.03 0.00 103.90 -0.01 103.88 0.00 0.01 0.00 9.10 0.02 0.00 0.00 0.00 0.00 0.00 0.00 99.28 0.00 99.28 0.00 1.57 0.20 7.42 0.05 0.01 0.00 0.02 0.00 0.00 0.01 100.08 0.00 100.08 0.00 1.64 0.16 13.81 0.01 0.01 0.02 0.01 0.00 0.00 0.00 98.20 0.00 98.20 0.00 1.36 0.31 0.00 0.00 0.01 0.03 0.00 0.00 0.04 0.00 103.51 -0.02 103.50 0.00 0.01 0.00 4.01 0.02 0.00 0.02 0.00 0.00 0.02 0.00 99.15 -0.01 99.14 0.00 1.81 0.09 42.05 0.05 1.88 0.00 0.01 0.01 0.01 0.00 101.70 0.00 101.70 0.00 0.12 0.88 0.00 0.00 0.00 28.54 0.02 0.01 1.52 0.01 99.99 -0.64 99.36 1.00 0.02 0.00 0.31 0.07 0.05 0.22 0.07 0.06 0.01 0.00 102.11 0.00 102.11 0.03 1.94 0.01 0.00 0.00 0.00 27.94 0.00 0.00 0.23 0.00 97.31 -0.10 97.21 1.00 0.02 0.00 0.00 0.00 0.00 27.34 0.03 0.00 0.23 0.00 96.13 -0.10 96.04 1.00 0.04 0.00 0.00 0.00 0.03 27.49 0.00 0.00 0.16 0.01 96.70 -0.07 96.63 0.99 0.03 0.00 0.00 0.00 0.04 27.91 0.00 0.01 0.06 0.00 97.90 -0.03 97.88 0.99 0.03 0.00 0.00 0.01 0.03 28.21 0.00 0.01 0.47 0.01 101.02 -0.20 100.83 0.98 0.03 0.00 0.00 0.00 0.01 28.42 0.02 0.01 0.54 0.00 101.26 -0.23 101.03 0.97 0.04 0.00 0.87 0.04 0.12 0.00 0.01 0.00 0.01 0.01 102.86 -0.01 102.85 0.00 1.89 0.02 41.08 0.02 4.48 0.01 0.02 0.00 0.02 0.00 102.97 -0.01 102.96 0.00 0.07 0.84 1.32 0.00 0.20 0.00 0.01 0.00 0.00 0.00 102.43 0.00 102.43 0.00 1.89 0.03 1.26 0.02 0.17 0.00 0.03 0.00 0.01 0.00 102.87 0.00 102.87 0.00 1.89 0.03 40.21 0.11 3.57 0.00 0.03 0.00 0.06 0.00 101.98 -0.03 101.95 0.00 0.12 0.83 1.18 0.00 0.12 0.00 0.00 0.00 0.00 0.00 102.17 0.00 102.17 0.00 1.91 0.03 3.05 0.05 0.04 0.04 0.09 0.04 0.00 0.05 104.51 -0.01 104.50 0.01 1.83 0.06 0.00 0.00 0.04 0.06 0.00 0.01 0.00 0.04 104.21 -0.01 104.20 0.00 0.02 0.00 0.00 0.02 3.60 6.39 0.01 0.00 0.31 0.02 104.82 -0.14 104.68 0.08 0.17 0.00 0.00 0.00 0.00 0.03 0.00 0.01 0.04 0.00 103.54 -0.02 103.52 0.00 0.01 0.00 0.00 0.00 0.03 0.11 0.01 0.00 0.04 0.02 103.20 -0.02 103.17 0.00 0.01 0.00 33.69 0.00 11.36 0.06 0.00 0.00 0.04 0.00 102.29 -0.02 102.28 0.00 0.09 0.70 33.11 0.00 11.52 0.00 0.00 0.04 0.01 0.00 101.72 0.00 101.72 0.00 0.09 0.69 0.00 0.00 0.04 0.06 0.01 0.00 0.00 0.00 104.09 0.00 104.09 0.00 0.01 0.00 22.80 6.60 7.89 0.64 0.00 0.00 0.02 0.03 102.52 -0.02 102.51 0.20 0.14 0.42 0.00 0.00 1.54 0.13 0.04 0.02 0.01 0.06 103.52 -0.02 103.50 0.00 0.05 0.00 0.44 0.06 0.04 0.19 0.05 0.13 0.00 0.00 101.99 0.00 101.99 0.03 1.93 0.01 0.00 0.01 0.10 0.03 0.01 0.10 0.01 0.21 101.60 -0.05 101.55 0.01 1.98 0.00 0.24 0.02 0.05 0.04 0.04 0.04 0.00 0.00 103.30 0.00 103.30 0.01 1.96 0.01 0.45 0.00 0.00 0.01 0.00 0.00 0.00 0.00 102.92 0.00 102.92 0.01 1.97 0.01 0.00 0.00 0.00 0.24 0.01 0.00 0.00 0.01 100.03 0.00 100.02 0.00 1.99 0.00 0.27 0.05 0.04 0.29 0.07 0.04 0.00 0.03 102.59 -0.01 102.59 0.02 1.94 0.01 0.14 0.00 0.01 0.00 0.00 0.01 0.00 0.00 100.75 0.00 100.75 0.00 1.99 0.00 0.06 0.00 0.05 0.08 0.00 0.00 0.00 0.01 102.21 0.00 102.20 0.00 1.99 0.00 3.51 0.03 0.00 0.00 0.00 0.00 0.01 0.00 98.97 0.00 98.97 0.08 1.84 0.08 0.00 0.00 0.01 28.31 0.00 0.05 0.28 0.00 99.59 -0.12 99.47 0.99 0.03 0.00 O Ti Mg Mn Ca Al Na K Cr Sum F Cl O Total 0.87 0.00 0.00 1.00 0.11 0.00 0.00 0.00 3.00 0.06 0.00 5.94 6.00 0.99 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.02 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.18 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.96 0.00 0.00 0.97 0.03 0.00 0.01 0.00 3.00 0.02 0.00 5.98 6.00 0.91 0.01 0.07 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.01 0.00 0.00 0.00 0.02 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.89 0.00 0.00 0.98 0.08 0.00 0.00 0.00 3.00 0.03 0.00 5.97 6.00 0.92 0.00 0.00 0.98 0.05 0.00 0.00 0.00 3.00 0.01 0.00 5.99 6.00 0.00 0.02 0.00 0.01 0.01 0.00 0.00 0.00 2.00 0.00 0.00 5.99 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 5.99 6.00 0.93 0.00 0.11 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.20 0.00 0.00 0.00 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.17 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.31 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.09 0.00 0.00 0.00 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.92 0.00 0.04 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.69 0.00 0.00 0.97 0.29 0.00 0.00 0.00 3.00 0.15 0.00 5.85 6.00 0.00 0.00 0.00 0.01 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.94 0.00 0.00 1.00 0.04 0.00 0.00 0.00 3.00 0.02 0.00 5.98 6.00 0.93 0.00 0.00 0.99 0.04 0.00 0.00 0.00 3.00 0.02 0.00 5.98 6.00 0.95 0.00 0.00 0.99 0.04 0.00 0.00 0.00 3.00 0.02 0.00 5.98 6.00 0.94 0.00 0.00 0.99 0.04 0.00 0.00 0.00 3.00 0.01 0.00 5.99 6.00 0.91 0.00 0.00 0.98 0.05 0.00 0.00 0.00 3.00 0.05 0.00 5.95 6.00 0.89 0.00 0.00 0.98 0.08 0.00 0.00 0.00 3.00 0.06 0.00 5.94 6.00 0.03 0.00 0.00 0.00 0.04 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.94 0.00 0.09 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.03 0.00 0.00 0.00 0.02 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.03 0.00 0.00 0.00 0.02 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.92 0.00 0.08 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.03 0.00 0.00 0.00 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.07 0.00 0.00 0.00 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.93 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.61 0.00 0.04 0.08 0.00 0.00 0.00 0.00 1.00 0.01 0.00 5.99 6.00 0.95 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.95 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.94 0.00 0.24 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.93 0.00 0.24 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.94 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.60 0.22 0.15 0.02 0.22 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.88 0.00 0.02 0.00 0.00 0.00 0.00 0.00 1.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.01 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.01 5.99 6.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 0.01 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.01 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.01 0.01 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 0.00 6.00 6.00 0.94 0.00 0.00 0.99 0.05 0.00 0.00 0.00 3.00 0.03 0.00 5.97 6.00