Phenol Resorcinol Formaldehyde Resin Validation Date : 01/19/2015 Print Date : 07/08/2015 Manufacturer/Supplier/Impor : Hexion Canada, Inc
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Page:1/14 Material Safety Data Sheet FOR INDUSTRIAL USE ONLY Cascophen(TM) LT-5210Q 1. Product and company identification Product name : Cascophen(TM) LT-5210Q MSDS Number : 000000104568 Material uses : Wood Adhesives, Composites, Laminates or Related Board Products Product type : Phenol Resorcinol Formaldehyde Resin Validation date : 01/19/2015 Print date : 07/08/2015 Manufacturer/Supplier/Impor : Hexion Canada, Inc. ter 180 East Broad Street Columbus, Ohio 43215 USA Contact person : [email protected] Telephone : For additional health and safety or regulatory information, call 1 888 443 9466. Emergency telephone number : For Emergency Medical Assistance Call Health & Safety Information Services 1-866-303-6949 For Emergency Transportation Information CHEMTREC US Domestic (800) 424-9300 CHEMTREC International (703) 527-3887 CANUTEC CA Domestic (613) 996-6666 Part of the CASCO® Brand of Adhesives and Resins from Hexion Inc. 2. Hazards identification –Emergency overview Physical state : Liquid Color : Clear, reddish-brown Odor : Slight alcoholic Signal word : WARNING! Hazard statements : COMBUSTIBLE LIQUID AND VAPOR. MAY FORM EXPLOSIVE MIXTURES WITH AIR. INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE Version: 9.1 Date of issue/Date of revision: 01/19/2015 Date of previous issue: 12/28/2011 Cascophen(TM) LT-5210Q Page:2/14 CANCER. Precautionary measures : Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe vapor or mist. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep away from heat and flame. Keep container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling. Potential acute health effects Inhalation : Can cause central nervous system (CNS) depression. Slightly irritating to the respiratory system. Ingestion : Can cause central nervous system (CNS) depression. Skin : Slightly irritating to the skin. Eyes : Severely irritating to eyes. Risk of serious damage to eyes. Potential chronic health effects Chronic effects : Contains material that can cause target organ damage. Signs and symptoms of chronic phenol poisoning may include vomiting, difficulty in swallowing, diarrhea, lack of appetite, jaundice, fatigue, bleeding or easy bruising and sometimes pain and swelling in the upper right abdomen, changes in urine output or dark urine, pain upon urination or in the lower back, or general edema. Can also cause cardiac damage evidenced by shortness of breath and in severe cases cardiac arrest. Preexisting medical conditions of the heart, kidney, liver, lung, eyes and skin may be aggravated by exposure. Carcinogenicity : Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Target organs : Contains material which causes damage to the following organs: blood kidneys lungs the nervous system liver heart spleen gastrointestinal tract cardiovascular system upper respiratory tract immune system skin central nervous system (CNS) eye, lens or cornea pancreas thyroid Over-exposure signs/symptoms Inhalation : Adverse symptoms may include the following: nausea or vomiting Version: 9.1 Date of issue/Date of revision: 01/19/2015 Date of previous issue: 12/28/2011 Cascophen(TM) LT-5210Q Page:3/14 respiratory tract irritation coughing headache drowsiness/fatigue dizziness/vertigo unconsciousness Ingestion : No specific data. Skin : Adverse symptoms may include the following: irritation redness Eyes : Adverse symptoms may include the following: pain or irritation watering redness Medical conditions aggravated : Pre-existing disorders involving any target organs mentioned in this MSDS by over-exposure as being at risk may be aggravated by over-exposure to this product. See toxicological information (Section 11) 3. Composition/information on ingredients Name CAS number % by weight Resorcinol 108-46-3 >=5 - <10 Phenol 108-95-2 >=5 - <10 Sodium Hydroxide 1310-73-2 >=1 - <5 Ethanol 64-17-5 >=1 - <5 Methanol 67-56-1 >=0.1 - <1 Ethyl Acetate 141-78-6 >=0.1 - <1 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Protection of first aid : No action shall be taken involving any personal risk or without suitable personnel training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before Version: 9.1 Date of issue/Date of revision: 01/19/2015 Date of previous issue: 12/28/2011 Cascophen(TM) LT-5210Q Page:4/14 removing it, or wear gloves. Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. 5. Fire-fighting measures Flammability of the product : Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Extinguishing media Suitable : Use dry chemical, CO2, water spray (fog) or foam. Not suitable : Do not use water jet. Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide metal oxide/oxides Special protective equipment : Fire-fighters should wear appropriate protective equipment and self- for fire-fighters contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8 of SDS). Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13 of SDS). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 of SDS for Version: 9.1 Date of issue/Date of revision: 01/19/2015 Date of previous issue: 12/28/2011 Cascophen(TM) LT-5210Q Page:5/14 emergency contact information and section