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1 Identification Page 1/11 Printing date 09/28/2015 acc. to OSHA HCS Reviewed on 06/01/2015 1 Identification · Product identifier · Trade name: Resorcinol · CAS Number: 108-46-3 · EC number: 203-585-2 · Index number: 604-010-00-1 · Relevant identified uses of the substance or mixture and uses advised against 1. Rubber compounding of resorcinol 2. Rubber compounding of resin containing free resorcinol 3. Rubber dipping of resorcinol 4. Rubber dipping of resin containing free resorcinol 5. Intermediate applications 6. Manufacture of PRF resins 7. Manufacture of RF resins 8. Wood adhesive use of PRF resins containing free resorcinol 9. Hair dye formulation 10. Hair dye application by consumers 11. Manufacture of other resins 12. Formulation and (re)packing of preparations 13. Use in coatings 14. Use in other adhesives and sealants 15. Processing of Resins · Sector of Use SU6a Manufacture of wood and wood products SU8 Manufacture of bulk, large scale chemicals (including petroleum products) SU9 Manufacture of fine chemicals SU10 Formulation [mixing] of preparations and/or re-packaging (excluding alloys) SU11 Manufacture of rubber products SU12 Manufacture of plastics products, including compounding and conversion SU15 Manufacture of fabricated metal products, except machinery and equipment SU17 General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment SU20 Health services · Product category PC39 Cosmetics, personal care products · Process category PROC1 Use in closed process, no likelihood of exposure PROC2 Use in closed, continuous process with occasional controlled exposure PROC3 Use in closed batch process (synthesis or formulation) PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) PROC6 Calendering operations PROC7 Industrial spraying PROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities PROC8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC10 Roller application or brushing PROC13 Treatment of articles by dipping andpouring PROC14 Production of preparations or articles by tabletting, compression, extrusion, pelletisation PROC15 Use as laboratory reagent (Contd. on page 2) USA 40.0 Page 2/11 Safety Data Sheet acc. to OSHA HCS Printing date 09/28/2015 Reviewed on 06/01/2015 (Contd. of page 1) PROC19 Hand-mixing with intimate contact and only PPE available PROC21 Low energy manipulation of substances bound in materials and/or articles PROC24 High (mechanical) energy work-up of substances bound in materials and/or articles · Environmental release category ERC1 Manufacture of substances ERC2 Formulation of preparations ERC3 Formulation in materials ERC5 Industrial use resulting in inclusion into or onto a matrix ERC6a Industrial use resulting in manufacture of another substance (use of intermediates) ERC6c Industrial use of monomers for manufacture of thermo-plastics ERC6d Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers ERC8a Wide dispersive indoor use of processing aids in open systems · Application of the substance / the mixture 1. Rubber compounding of resorcinol 2. Rubber compounding of resin containing free resorcinol 3. Rubber dipping of resorcinol 4. Rubber dipping of resin containing free resorcinol 5. Intermediate applications 6. Manufacture of PRF resins 7. Manufacture of RF resins 8. Wood adhesive use of PRF resins containing free resorcinol 9. Hair dye formulation 10. Hair dye application by consumers 11. Manufacture of other resins 12. Formulation and (re)packing of preparations 13. Use in coatings 14. Use in other adhesives and sealants 15. Processing of Resins · Details of the supplier of the safety data sheet Charkit Chemical Company, LLC. 32 Haviland Street, Unit 1 Norwalk, CT 06854 USA Landline telephone:+1 203-299-3220 · Manufacturer/Supplier: Charkit Chemical Company, LLC. 32 Haviland Street, Unit 1 Norwalk, CT 06854 USA Phone No : +1 203-299-3220 Fax No : +1 203-299-1355 · Emergency telephone number: Chemtrec: 800-424-9300 (US) / +1-703-527-3887 (Int' l) USA (Contd. on page 3) 40.0 Page 3/11 Safety Data Sheet acc. to OSHA HCS Printing date 09/28/2015 Reviewed on 06/01/2015 (Contd. of page 2) 2 Hazard(s) identification · Classification of the substance or mixture GHS08 Health hazard STOT SE 2 H371 May cause damage to organs. GHS05 Corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. · Label elements · GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS05 GHS07 GHS08 · Signal word Danger · Hazard statements H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H371 May cause damage to organs. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray. P280 Wear protective gloves. P280 Wear eye protection / face protection. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing must not be allowed out of the workplace. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P321 Specific treatment (see on this label). P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P363 Wash contaminated clothing before reuse. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P330 Rinse mouth. P302+P352 If on skin: Wash with plenty of water. P308+P311 IF exposed or concerned: Call a poison center/doctor. (Contd. on page 4) USA 40.0 Page 4/11 Safety Data Sheet acc. to OSHA HCS Printing date 09/28/2015 Reviewed on 06/01/2015 (Contd. of page 3) P362+P364 Take off contaminated clothing and wash it before reuse. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Classification system: · NFPA ratings (scale 0 - 4) 1 Health = 2 Fire = 1 2 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH 2 Health = 2 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0 · Other hazards · Results of PBT and vPvB assessment · PBT: The substance is not PBT · vPvB: The substance is not vPvB 3 Composition/information on ingredients · Chemical characterization: Substances · CAS No. Description 108-46-3 resorcinol · Identification number(s) · EC number: 203-585-2 · Index number: 604-010-00-1 · SVHC Does not fall under SVHC substance 4 First-aid measures · Description of first aid measures · General information: Take affected persons out into the fresh air. Seek immediate medical advice. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Immediately call a doctor. · Most important symptoms and effects, both acute and delayed Causes damage CNS effects and blood effects - methemoglobin via oral bolus dosing May cause damage to the respiratory system, via oral bolus dosing · Information for doctor: Treat symptomatically. (Contd. on page 5) USA 40.0 Page 5/11 Safety Data Sheet acc. to OSHA HCS Printing date 09/28/2015 Reviewed on 06/01/2015 (Contd. of page 4) · Indication of any immediate medical attention and special treatment needed NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Have patient drink several glasses of water or milk. DO NOT induce vomiting. Keep airway clear. GET MEDICAL ATTENTION IMMEDIATELY. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Carbon dioxide, Dry chemical, Foam, Water spray · Special hazards arising from the substance or mixture Carbon oxides · Advice for firefighters Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. · Protective equipment: No special measures required. A self-contained breathing apparatus NOSH, MSHA or EN149 (approved or equivalent) and suitable protective clothing and protective gloves should be worn if involved in fire with other materials. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Inhalation: Remove person to fresh air, if not breathing give artificial respiration. If breathing is difficult give oxygen and call a physician. Skin contact: Wash affected area with soap and plenty of water, Remove contaminated clothing.If any irritation seek immediate medical aid. Eye contact: Immediately flush eyes with a plenty of water for 15 minutes. Seek immediate medical aid. Ingestion:Induce omitting immediately as directed by physician.Never give anything by mouth
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