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INCT Annual Report 2019 ANNUAL REPORT 2019 INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY Editors Prof. Jacek Michalik, Ph.D., D.Sc. Ewa Godlewska-Para, M.Sc. Cover designer Sylwester Wojtas © Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 2020 CONTENTS GENERAL INFORMATION 7 MANAGEMENT OF THE INSTITUTE 9 MANAGING STAFF OF THE INSTITUTE 9 HEADS OF THE INCT DEPARTMENTS 9 SCIENTIFIC COUNCIL (2017-2021) 9 ORGANIZATION SCHEME 11 SCIENTIFIC STAFF 12 PROFESSORS 12 SENIOR SCIENTISTS (Ph.D.) 12 CENTRE FOR RADIATION RESEARCH AND TECHNOLOGY 15 IAEA Collaborating Centre 17 RAPID Centre 18 THE SPECIFICS OF DOSIMETRY MEASUREMENT METHODS APPLIED TO LOW ENERGY ELECTRON BEAM S. Bułka, U. Gryczka, W. Migdał 19 POSTRADIATION DEGRADATION OF PAPER W. Głuszewski 20 CENTRE FOR RADIOCHEMISTRY AND NUCLEAR CHEMISTRY 23 Radiopharmaceutical studies 25 Radioactive waste management 27 GOSPOSTRATEG Programme 28 RECEPTOR RADIOPHARMACEUTICAL BASED ON DUAL-ACTING DRUG METHOTREXATE E. Gniazdowska, P. Koźmiński, P. Halik 29 ENDOHEDRAL ISOMERISM IN HETEROFULLERENES S. Ostrowski, P. Garnuszek, J.Cz. Dobrowolski 32 ANALYSIS OF URANIUM CONTENT IN SECONDARY RAW MATERIALS USING ALFA SPECTROMETRY K. Kiegiel, D. Gajda, P. Kalbarczyk, G. Zakrzewska-Kołtuniewicz 35 FABRICATION OF ThO2 MICROSPHERES WITH DIAMETER BELOW 50 m BY INCT METHODS M. Brykała, M. Rogowski, T. Olczak, D. Wawszczak, R. Laskowska 37 APPLICATION OF BIO-MATERIALS FOR WATER PURIFICATION: POWDERED ROOTS OF DRIED CARROTS L. Fuks, I. Herdzik-Koniecko, P. Kalbarczyk 40 CENTRE FOR RADIOBIOLOGY AND BIOLOGICAL DOSIMETRY 45 Biological dosimetry 46 TOXICITY OF SILVER NANOPARTICLES IN COMBINATION WITH TITANIUM DIOXIDE NANOPARTICLES S. Męczyńska-Wielgosz, H. Lewandowska-Siwkiewicz, S. Sommer, A. Lankoff, I. Buraczewska 47 IMPACT OF SILVER NANOPARTICLES ON ROS GENERATION IN 4T1 AND A2780 CELL LINES S. Męczyńska-Wielgosz, H. Lewandowska-Siwkiewicz, M. Wojewódzka, K. Sikorska, K. Brzóska, M. Kruszewski 48 LABORATORY OF NUCLEAR ANALYTICAL METHODS 51 DETERMINATION OF RESIDUES OF ANTIDEPRESSANT DRUGS IN WATERS AND THEIR REMOVAL BY THE USE OF IONIZING RADIATION A. Bojanowska-Czajka, S. Górska, E. Poboży, M. Trojanowicz, P. Kalbarczyk 52 PRELIMINARY RESULTS ON DETERMINATION OF HEAVY METALS IN THE SOIL OF THE POLISH SIDE OF THE BIAŁOWIEŻA FOREST P. Kalbarczyk, E. Buśko, L. Fuks, E. Shavalda, H. Polkowska-Motrenko 57 LABORATORY OF MATERIAL RESEARCH 61 Chemical and nuclear techniques in heritage science 63 STUDIES ON URANYL ION SORPTION FROM WATER USING UiO-66 TYPE METAL-ORGANIC FRAMEWORK MATERIALS SYNTHESIZED WITH AMINO OR NITROGEN FUNCTIONALIZED MONOCARBOXYLIC ACID MODULATORS W. Starosta, P. Kalbarczyk 64 MULTIELEMENTAL COATINGS ON ZIRCONIUM ALLOY – OXIDATION EXPERIMENTS B. Sartowska, W. Starosta, L. Waliś, J. Smolik, V.K. Semina 66 LEAD ISOTOPE COMPOSITIONS OF DOROGICHIN SMALL LEAD SEALS – PRELIMINARY RESULTS E. Pańczyk, J. Dudek, M. Wołoszyn, A. Garbacz–Klempka 70 POLLUTION CONTROL TECHNOLOGIES LABORATORY 75 COMPUTER SIMULATION OF MICROWAVE GENERATED PLASMA TO REMOVE NO FROM SHIP EMISSION Y. Sun, A.G. Chmielewski 77 STABLE ISOTOPE LABORATORY 81 THE STUDY OF MEDICINAL HERBS ORIGIN BY CARBON AND NITROGEN ISOTOPE COMPOSITIONS R. Wierzchnicki 82 ISOTOPIC STUDY OF EDIBLE MUSHROOM ORIGIN R. Wierzchnicki 83 LABORATORY FOR MEASUREMENTS OF TECHNOLOGICAL DOSES 87 LABORATORY FOR DETECTION OF IRRADIATED FOOD 89 THERMOLUMINESCENCE METHOD FOR THE DETECTION OF RADIATION TREATED TABLETS, CAPSULES AND DRAGEES OF DIET SUPPLEMENTS CONTAINING VEGETAL EXTRACTS M. Miłkowska, G. Liśkiewicz, G.P. Guzik 91 LABORATORY OF NUCLEAR CONTROL SYSTEMS AND METHODS 97 New biogas installation 98 Leakage control of pipelines and industrial columns 99 PUBLICATIONS IN 2019 100 ARTICLES 100 BOOKS 104 CHAPTERS IN BOOKS 105 THE INCT PUBLICATIONS 106 CONFERENCE PROCEEDINGS 106 CONFERENCE ABSTRACTS 108 SUPPLEMENT LIST OF THE PUBLICATIONS IN 2018 112 NUKLEONIKA 114 POSTĘPY TECHNIKI JĄDROWEJ 116 THE INCT PATENTS AND PATENT APPLICATIONS IN 2019 118 PATENTS 118 PATENT APPLICATIONS 118 CONFERENCES ORGANIZED AND CO-ORGANIZED BY THE INCT IN 2019 120 Ph.D./D.Sc. THESES IN 2019 121 Ph.D. THESES 121 D.Sc. THESES 121 EDUCATION 123 Ph.D. PROGRAMME IN CHEMISTRY 123 TRAINING OF STUDENTS 123 MASTER’S, BACHELOR’S AND ENGINEER’S THESES 124 Erasmus+ Programme 126 RESEARCH PROJECTS AND CONTRACTS 127 RESEARCH PROJECTS GRANTED BY THE NATIONAL SCIENCE CENTRE IN 2019 127 PROJECTS GRANTED BY THE NATIONAL CENTRE FOR RESEARCH AND DEVELOPMENT IN 2019 127 IAEA RESEARCH CONTRACTS IN 2019 128 PROJECTS WITHIN THE FRAME OF EUROPEAN UNION PROGRAMME HORIZON 2020 129 OTHER INTERNATIONAL RESEARCH PROGRAMMES IN 2019 129 ERASMUS+ PROGRAMME 130 PARTICIPATION IN IAEA REGIONAL TECHNICAL COOPERATION PROJECTS 130 H2020 Programme – Euratom-Fission 131 LIST OF VISITORS TO THE INCT IN 2019 132 THE INCT SEMINARS IN 2019 133 LECTURES AND SEMINARS DELIVERED OUT OF THE INCT IN 2019 135 LECTURES 135 SEMINARS 136 AWARDS IN 2019 138 INDEX OF THE AUTHORS 140 GENERAL INFORMATION 7 GENERAL INFORMATION The Institute of Nuclear Chemistry and Technology (INCT) is Poland’s leading research institution in the fi elds of nuclear and radiation chemistry, and radiobiology. Scientifi c activities of the INCT are dedicated to a wide range of nuclear topics, involving basic and applied research. Basic research is focused on separation processes of actinides and lan- thanides, novel radiopharmaceuticals, radiation effects in molecules of biological import- ance, cells and polymers. With its six electron accelerators, the Institute is one of the most advanced centres in the fi eld of electron beam applications. The various types of accel- erators are used for radiation sterilization of medical devices and transplantation grafts, modifi cation of polymers, removal of SO2 and NOx from fl ue gases, and for food irradia- tion. The INCT Scientifi c Council has the right to confer D.Sc. and Ph.D. degrees in the fi eld of chemistry. In 2019, six Ph.D. and three D.Sc. theses were defended in the INCT. The Institute’s expertise and infrastructure made possible the participation in nu- merous international and domestic projects. In 2019, the INCT continued research activ- ity in fi ve projects of the EU programme Horizon 2020, in which leading European insti- tutes and industrial companies participate: • ARIES: Accelerator research and innovation for European science and society. In the framework of this project the book ‘Electron accelerators for research, industry and en- vironment – the INCT perspective’ was edited in 2019, presenting the INCT achieve- ments in the fi eld of electron beam applications. • GENIORS: GEN IV integrated oxide fuels recycling strategies. • TeamCABLES: European tools and methodologies for an effi cient ageing management of nuclear power plant cables. • CHANCE: Characterization of conditioned nuclear waste for its safe disposal in Europe. • EURAD: European Joint Programme on Radioactive Waste Management. The INCT cooperated also in DISCO project ‘Modern spent fuel dissolution and chemistry in failed container conditions’ as associated group member. According to recent publication of the National Contact Point for Research Programmes of the European Union, the Institute takes second place (after the National Centre for Nuclear Research) among Polish entities highly active in seeking and raising funds from H2020 Euratom-Fission Programme. Besides, six large projects of the National Centre for Research and Development (NCBR) and two projects in the frame of European operational programmes were carried out, im- portant for health, environmental protection and commercial use of nuclear techniques. There were also eight projects of the National Science Centre (NCN) led by the INCT researchers, majority of them dedicated to the development of new radiopharmaceuticals for medical diagnosis and therapy. The INCT Centre for Research and Radiation Technology (RAPID) was included to the Polish Roadmap for Scientfi c Infrastructures. The RAPID Centre is a research and im- plementation platform for innovative projects in radiation chemistry and technology with the use of electrom beams of energy in the range 0.2-10.0 MeV from different accelera- tors. It has a status of the IAEA Collaborating Centre and many collaborating and train- ing programmes are carried out jointly with the IAEA. In 2019, the RAPID Centre took part in the IAEA RER1019 and RER1020 programmes concerning standards in radiation technologies, quality control procedures and nuclear control systems. Under the frame- work of the IAEA Coordinated Research Programmes, the INCT researchers took part in 13 IAEA research contracts cooperating with scientists from numerous countries all over the world. The long-term INCT cooperation with industrial companies was very succesful in 2019. Two innovative projects were accepted by the NCBR. The fi rst one run jointly with REMONTOWA Shiprepair Yard S.A. concerns the design of pilot system for cleaning 8 GENERAL INFORMATION ballast waters and sludge from ships using ionizing radiation. The goal of the second one is to prepare together with Biopolinex the new technology of organic fertilizer production from sewage sladge with zero energy input. The interdisciplinary Ph.D. study project ‘Radiopharmaceuticals for molecularly tar- geted diagnostics and medical therapy’ (RadFarm) was granted to the INCT jointly with the National Centre for Nuclear Research, University of Warsaw (Faculty of Chemistry) and Medical University of Warsaw (Faculty of Pharmacy with the Laboratory Medicine Division). In 2019, the INCT scientists published 63
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