Elena HELEREA Marius Daniel CĂLIN
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Elena HELEREA Marius Daniel CĂLIN 2015 ISBN 978–606–19–0717–5 FOREWORD A necessity and support In the last few years, many Electrical Engineering, Science of Materials and Physics Departments looked for a manual about materials and devices at the undergraduate/ graduate level that covers a broad spectrum of electrical and electronic materials, including highly conductive materials, semiconductors, dielectrics and magnetic materials. It was necessary to have applications and extensive problems, to include elementary quantum mechanics, to satisfy various accreditation requirements across international borders. The present work answers this need, and since 2002, it has become a textbook in Transilvania University of Braşov and a number of higher schools from Braşov area. The text-book represents a first course in electrical engineering materials and devices – in English language - suitable for a one- or two-semester course in materials for electrical and electronic engineering at undergraduate level. It would also be useful as graduate introductory course in materials for electrical engineering and material scientists. The course intends to be a reference material for the teachers who approach electrical technologies and engineering issues. The present support of course is an improved text-book, which was developed in the frame of VIRTUAL-ELECTR_LAB project – a Leonardo Project, to sustain the innovative approach for improvement of the teaching-learning-evaluation methods using e-resources, in which the knowledge are gradually transferred, on three levels: beginner, intermediate and advanced, and the visualization and explanation of the phenomena through ICT tools allow a correct and deep understanding, consequently the obtaining of a high level knowledge for the trainees. Organization and Features The course, structured on three study-levels, has as main objective the acquisition of knowledge and the formation of skills concerning the handling of the multifunctional materials used in electrical engineering and technology. The quality and characteristics of the materials are presented in relation to the factors, which influence them, so that the user could adjust the matrix of demands imposed by the electrical or electronic systems and the matrix of the material parameters. For a better access to the structure of the text-book, at the beginning of each sub- chapter, the symbol for the study-level is marked: Beginner level Intermediate level Advanced level Beginner level On the basic level there are to be treated the following issues: the functions/the roles of different classes of materials (conductors, semi-conductors, electro- insulators, dielectrics, magnetic materials); testing methods; characteristic features; examples of specific applications. Intermediate level On the intermediate level are to be treated: functions of materials and justification by means of classic microscopic theories; the testing methods by specifying the particularities of the measuring cells and measuring devices used; justifying the characteristic features; examples of applications of the materials, also considering the technological and environmental implications. Advanced level On the advanced level are to be treated: the characteristic parameters and justification by means of appropriate theories; testing the materials and considering the measurement errors and the factors which influence them; simulating the behaviour of the materials under various circumstances of functioning; some applications which take into account the technical, technological and environmental implications. The textbook has 5 chapters which provide an overview on material laws in electrotechnics (Ch. 1), conductive materials (Ch. 2), semiconductive materials (Ch. 3), dielectrics (Ch. 4), magnetic materials (Ch. 5), a section of assessment with questions and solutions for each chapter, and reach references. The present textbook added new concepts and applications on this fascinate world of materials for electric and electronic engineering. Acknowledgments Our thanks to the graduate students, especially Dorian Popovici, who contributed to the designing the explicative figures, and to teachers Mariana Streza, Ana Maria Antal and Viviana Moldovan, who read various portions at the manuscript and provided valuable solutions for English translation of the text. The Authors, Braşov, Autumn, 2015. 4 Materials in Electrical Engineering 1.1. DEFINITIONS AND CLASSIFICATIONS 1.1.1. Definitions. Material Parameters A large number of substances and materials are used in electrical engineering. The notion substance includes the category of objects that are characterized by the homogeneity of the composition and of their constituent structure. Examples: water, paper, air, iron etc. The notion material is much wider and includes the objects of different or resembling nature and structure that are used in a certain domain. We may consider the material as a whole made up of one or more substances. Examples: plastics, stratified materials, composites, ferrites. Many branches of science study the materials. Thus, among these sciences, chemistry and physics give an image/explanation of the composition (the nature of constituent particles), of the structure (the way the constituent particles are arranged) and of the physical and chemical properties of substances. Among applied sciences, the science of materials studies the composition and the structure as well as the properties of materials used in certain domains (car industry, electrotechnics, wood industry etc.). The material engineering science studies the structure, the producing and processing of materials, their properties and performances. Before making any classifications, we need a distinction between the notions of material property and material parameter. A material property represents a common characteristic for the specific class of materials that characterize the response of the material to the action of external stresses. Examples: Electrical conductivity defines the way a material behaves when an electric field is applied (the material property of conducting the electric current); Magnetic susceptivity characterizes the behavior of the material when a magnetic field is applied etc. For every material property is associated a physical quantity (which can be scalar, vector, tensor) called material parameter, which characterizes the material state under external stress. Examples: Electrical conductivity σ is a material parameter that characterizes the property of electric conduction; 1..Parameters and Material Laws in Electrical Engineering 5 Electrical susceptivity ϰ is a material parameter that characterizes the property of electrical polarization of dielectrics; Melting temperature Ttop is a material parameter that characterizes the property of fusibility (the property of the material to melt); etc. 1.1.2. Classification of Materials Materials can be classified on different criteria. A. According to their composition, there are: Organic materials, which contain carbon, are obtained from the vegetal or animal kingdom (examples: paper, wood, resins, rubber, etc.); Inorganic materials, which don’t contain carbon, are obtained from the mineral kingdom (examples: salts, acids, bases, glass, asbestos, etc.). B. According to the character of the periodical properties of the chemical elements: metals, metalloids and non-metals. Their characteristics are presented in the Table 1.1. Table 1.1. The comparative properties of metals, metalloids and non-metals. Properties Metals Metalloids Non-metals Electronegativity 0.7 – 1.8 1.8 – 2.2 2.2 – 4.0 Electric conductivity High Medium Low Increases with Decreases with Is little influenced by Electric resistance the rise of the rise of the temperature temperature temperature Malleable, Neither malleable Mechanical properties Flawed Ductile nor ductile Notes: Electronegativity is the property and a criterion of appreciation of the capacity to attract electrons by an atom from a molecule or from a complex structure; Malleability is the property of a metal to be drawn into leaves; Ductility is the property of a metal to be drawn into wires. C. According to their state of aggregation and their structure, there are: Gaseous materials, which have no proper form or volume (examples: air, nitrogen, methane gas, etc.); Liquid materials, they have a proper form, but no proper volume (examples: oils, water in liquid state, etc.); Solid materials, which have proper form and volume and a specific structure, therefore we can be distinguished: 6 Materials in Electrical Engineering Crystalline materials, which present regularity at long distance of the constituent atoms (examples: metals, silicon, germanium, quartz, etc.); Amorphous materials, which present only regularity at short distance of the constituent atoms (examples: resins, plastics, rubber, porcelain, etc.); Mezomorphous materials, which present the crystalline state only at certain temperature and concentration conditions (examples: liquid crystals, etc.). D. According to a characteristic property, such as: The electrical conductivity: o Electrical conductive materials, which allow the passing of intense electric currents, of A - kA order (examples: silver, copper, gold, aluminum, graphite, etc.); o Semiconductive materials, which allow the passing of the low electric current, of µA – mA order (examples: germanium and silicon crystals with impurities, etc.); o Electroinsulating materials, where the electric currents of conduction