1387 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 57, 2017 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Sauro Pierucci, Jiří Jaromír Klemeš, Laura Piazza, Serafim Bakalis Copyright © 2017, AIDIC Servizi S.r.l. DOI: 10.3303/CET1757232 ISBN 978-88-95608- 48-8; ISSN 2283-9216 Evaluation of Anticorrosive Effect of Niobium Carbide Coating Applied on Carbon Steel b a b a Luisa Novoa , Luis E. Cortes , Eliana Gonzalez , Arnaldo Jimenez , Luis G. a a a Cortes , Mario Ojeda , Aida L. Barbosa* a Laboratory of Research of Catalysis and New materials (LICATUC), Science Faculty, Chemistry Program, University of Cartagena, Campus of Zaragocilla, Kra 50 Nº 30-40, Cartagena, Colombia b Dept of Civil Engineering, Civil Enginering programm, University of Cartagena, Campus of Piedra de Bolivar, Av. El Consulado Calle 30. No. 48 - 152, Cartagena, Colombia
[email protected] South America and particularly Colombia, has niobium and tantalum deposits, which can be used as a carbon steel protective agent. A preliminary step is the raw material characterization. Fresh and calcinated samples of niobium mineral in ores and sand were analyzed through optic microscopy, laser-Raman spectroscopy, DRX and textural aspects. The main components of the ore and alluvial sand were Ferrotapiolite and ferrocolumbite with chemical formula (Fe,Mn)•(Ta,Nb)2O6 and associated oxides like Fe2O3, SiO2. In the shape of Tectosilicates, Mn-Tantalite, Nb=O terminal and polyatomic octahedral structures of NbO6, highly distorted, susceptible to form carbides. Ferrocolumbite synthetic (FeNb50) was used as precursor of NbC coating for the surfaces protection of AISI 1020 steel samples having dimensions of 3/8 inch diameter and 1/2 inch length.