DOCSLIB.ORG

Synthesis of Fullerene Derivatives G

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Synthesis of Fullerene Derivatives G Physics of the Solid State, Vol. 44, No. 4, 2002, pp. 601–602. Translated from Fizika Tverdogo Tela, Vol. 44, No. 4, 2002, pp. 579–580. Original Russian Text Copyright © 2002 by Churilov, Isakova, Weisman, Bulina, Bachilo, Cybulski, Glushchenko, Vnukova. PROCEEDINGS OF THE V INTERNATIONAL WORKSHOP “FULLERENES AND ATOMIC CLUSTERS” (St. Petersburg, Russia, July 2–6, 2001) Synthesis of Fullerene Derivatives G. N. Churilov*, V. G. Isakova*, R. B. Weisman**, N. V. Bulina*, S. M. Bachilo**, D. Cybulski**, G. A. Glushchenko*, and N. G. Vnukova* * Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russia e-mail: [email protected] ** Rice University, Houston, TX 77005 USA e-mail: [email protected] Received April 1, 1999 Abstract—This paper presents the results of plasmochemical synthesis of fullerene derivatives with hydrogen, iodine, iridium, platinum, and scandium. The synthesis is carried out under atmospheric pressure in a carbon– helium plasma stream formed by an ac arc in the rf range. © 2002 MAIK “Nauka/Interperiodica”. The synthesis of fullerene derivatives with H2, I2, changes (as compared to the spectrum for a fullerene Sc, Ir, and Pt was carried out in a plasmochemical reac- mixture): a new band appeared at 434 nm and the band tor developed earlier in [1, 2]. The reactor differs con- at 334 nm was displaced to the UV region by 17 nm. siderably from the widely used Kretschmer reactor in This variation is usually attributed to fullerene com- that the synthesis occurs under atmospheric pressure in plexes with hydrogen of the C60H2 type [4, 5]. a stream of carbon–helium plasma generated by an ac Emission spectroscopy revealed the presence of Sc arc in the rf range. The reactor makes it possible for par- at a content of the order of 10–3% in the fullerene-con- ticles of the introduced substance to stay for a long time taining extract. in the carbon plasma jet and, hence, become atomized Highly effective chromatographic separation of the completely. Consequently, this reactor can be used for fullerene mixture prepared by extraction from Ir- and the synthesis of fullerenes both with light elements and Pt-containing soots was carried out in a Cosmosil with refractory metals. Buckyprep column. The mass spectra of the separated In accordance with the concept of the effect of the fractions were measured. It was found that the given electron concentration on the formation of fullerenes extract contains 55% C60, 25% C70, 15% higher and fullerene derivatives in a carbon plasma, which was fullerenes (mainly, C76, C78, C82, C84, and C86), and 5% developed in our earlier work [3], we synthesized oxidized fullerenes C and C . fullerene derivatives by adding both donors and accep- 60 70 tors of electrons (hydrogen, iodine, scandium, iridium, Mass spectrometry did not reveal the presence of and platinum). The initial metallic powder or metal any platinum or iridium derivatives in the extracts sep- wire was placed in a hole (d = 1.2 mm) made in one of arated from Ir- and Pt-containing soots. This can be due the electrodes between which the plasma jet of carbon to poor volatility of the formed metal compounds. with a metal was formed. Hydrogen and iodine were Moreover, Pt- and Ir-containing derivatives involved in introduced into the reactor in the form of a gas flow and soots may be insoluble in organic solvents. In this con- vapor, respectively, in different temperature regions of nection, we made an attempt to convert them into vola- the plasma. We tested fullerene-containing soot and tile chelate complexes of metals, which are soluble in fullerenes extracted from it. organic solvents and similar to those described in [6]. Fullerene-containing soots with Pt and Ir (samples I An analysis of the x-ray spectra revealed that Ir, Pt, and II, respectively) were treated with acetylacetone and Sc metals are present in a fullerene-containing soot (Hacac) in solutions of HF (a) and HCl (b) acids during only in the amorphous state. heating, and, then, reaction products (Ia, IIa, Ib, and The fullerene yield increased upon the introduction IIb) soluble in organic solvents were extracted from the of a metal from 4 to 12%. The introduction of iodine reaction systems. virtually nullifies the concentration of fullerenes in the The electronic absorption spectra of products Ia and soot. IIa are shifted to the UV region as compared to samples The electronic absorption spectra for the fullerene I and II. The x-ray diffraction pattern of the toluene extract from soots obtained during the synthesis with extract of the Ir-containing product IIa contains reflec- the introduction of hydrogen exhibited the following tions of fullerene (for small angles) and reflections of 1063-7834/02/4404-0601 $22.00 © 2002 MAIK “Nauka/Interperiodica” 602 CHURILOV et al. an unknown substance (for large angles); the latter the one hand, and the yield of the resulting fullerene reflections can be associated with Ir complexes. derivatives, on the other. This will be the next step Toluene extracts of the synthesis products contained toward the controlled synthesis of fullerene derivatives. fractions of greenish yellow and yellow color which were soluble in protogenic solvents (acetone and alco- hol). The electronic absorption spectra of compounds ACKNOWLEDGMENTS obtained from fullerene-containing soots and the spec- This work was supported by the American Founda- tra of halogenated iridium acetylacetonates contain tion CRDF, grant no. RE1-2231. The foundation is not bands at 270–280 nm, which are similar to the bands of responsible for the concepts, ideas, and results pre- iridium γ-fluoroacetylacetones but are displaced by 10– sented in this paper. This work was also partly sup- 15 nm toward the long-wavelength range. The presence ported by the Russian State Program “Fullerenes and of other bands can be associated with the presence of Atomic Clusters” (project no. 5-3-00) and the Program fullerenes in the metal complexes; in addition, the for- “University Research Work in Priority Trends of Sci- mation of carbon-bonded acetylacetonates and mixed ence and Technology,” the Ministry of Education of the halogenacetylacetonates of metals is also possible. Russian Federation (project nos. 201.05.01.001 and The results obtained demonstrate that, in the irid- 203.02.05.007). ium- and platinum-based fullerene-containing soots, iridium and platinum are in the chemically active form. This follows from the fact that the aforementioned reac- REFERENCES tions with acetylacetone do not occur with the familiar 1. G. H. Churilov, L. A. Soloviev, Ya. N. Churilova, et al., metallic forms of iridium and platinum (compact metal, Carbon 37, 427 (1999). metallic sponges, and powders). It can be assumed that 2. G. N. Churilov, Prib. Tekh. Éksp., No. 1, 5 (2000). the active form of Ir and Pt is their oxidized state in the 3. G. N. Churilov, P. V. Novikov, and N. G. Vnukova, in form of insoluble fullerides; however, the results of Proceedings of the XV International Winterschool on x-ray diffraction analysis indicate the presence of Electronic Properties of Novel Materials “Molecular amorphous particles of a metal in soots, which proba- Nanostructures,” Kirchberg, Austria, 2001. bly exhibit a high chemical activity. 4. D. Mandrus, M. Kele, R. L. Hettich, et al., J. Phys. The experiments described here indicate that the Chem. B 101, 123 (1997). synthesis of metallocomplexes of fullerenes in prepara- 5. C. C. Henderson and P. A. Cahill, Science 259, 1885 tion amounts is a complex problem associated with the (1993). donor and acceptor properties of the substances being 6. V. G. Isakova, I. A. Baidina, N. B. Morozova, and introduced. Further investigations are required for I. K. Igumenov, Polyhedron 19, 1097 (2000). determination of the relation between the magnitude and the variation of the electron concentration in a plasma upon the introduction of various elements, on Translated by N. Wadhwa PHYSICS OF THE SOLID STATE Vol. 44 No. 4 2002 Physics of the Solid State, Vol. 44, No. 4, 2002, pp. 603–606. From Fizika Tverdogo Tela, Vol. 44, No. 4, 2002, pp. 581–584. Original English Text Copyright © 2002 by Mordkovich, Shiratori, Hiraoka, Takeuchi. PROCEEDINGS OF THE V INTERNATIONAL WORKSHOP “FULLERENES AND ATOMIC CLUSTERS” (St. Petersburg, Russia, July 2–6, 2001) Synthesis of Multishell Fullerenes by Laser Vaporization of Composite Carbon Targets1 V. Z. Mordkovich, Yosuke Shiratori, H. Hiraoka, and Yoshimasa Takeuchi International Center for Materials Research, East 601, KSP, Takatsuku, Kawasaki, 213-0012 Japan e-mail: [email protected] Abstract—Multishell fullerenes are the smallest among multishell carbon clusters, such as the larger graphitic onions or multishell nanotubes. Unlike classical fullerenes, which have a cage structure and are known to have been synthesized in a variety of sizes (C60, C70, C84, C102, etc.), multishell fullerenes have a cage-inside-cage concentric structure, such as double-shell C60@C240 or triple-shell C60@C240@C560. We report on the synthesis of multishell fullerenes by laser vaporization of C60-containing composite carbon targets. Transmission elec- tron microscopy, Raman scattering spectroscopy, and other methods were used for characterization of the prod- uct. The yield of the process reaches up to 40%, which permits production in gram amounts even in laboratory conditions. © 2002 MAIK “Nauka/Interperiodica”. 1 Multishell fullerenes are the smallest among multi- Also, it seems reasonable to suggest that the actual shell carbon clusters, such as the larger graphitic onions growth of additional shells around C60 cores takes place [1, 2] or multiwall nanotubes [2, 3]. Unlike classical not during 3000°C treatment but during the cooldown fullerenes, which have a cage structure and are known after the heat treatment. If this suggestion is correct, the to have been synthesized in a variety of sizes (C60, C70, successful synthetic route should be comprised of at C84, etc.), multishell fullerenes have a cage-inside-cage least two steps: (1) the formation of carbon vapor con- concentric structure, such as double-shell C60@C240 or taining many C60 molecules and (2) cooling down at the triple-shell C60@C240@C560.
Load more

Recommended publications
  • (SAM) Alloy Parts Using X-Ray CT
    Research Article ISSN 2639-9466 Nanotechnology & Applications Porosity Determination and Characterization of Binder Jet Printed Structural Amorphous Metal (SAM) Alloy Parts Using X-Ray CT Amamchukwu B. Ilogebe1*, Benedict Uzochukwu2, and Amy M. Elliot3 1North Carolina A&T State University, US. *Correspondence: Amamchukwu B. Ilogebe, North Carolina A&T State University, 2Virginia State University, US. US. 3Oak Ridge National Laboratory, US. Received: 04 November 2019; Accepted: 29 November 2019 Citation: Amamchukwu B. Ilogebe, Benedict Uzochukwu, Amy M. Elliot. Porosity Determination and Characterization of Binder Jet Printed Structural Amorphous Metal (SAM) Alloy Parts Using X-Ray CT. Nano Tech Appl. 2019; 2(1): 1-6. ABSTRACT The advent of Binder jet additive manufacturing continued to a revelation in the manufacture of intricate metal parts. This technology has been utilized in medical, aerospace and automotive industries, not much has been reported in the printing of parts from amorphous metal powders, which have found numerous applications in engineering because of their special properties. In this research, special emphasis was placed on two different manufacturing methods for structural amorphous metal alloy (SAM alloy); Die compaction and Binder jet printing. Samples of SAM alloy was created from these two-manufacturing methods and were subsequently, sintered, analyzed and compared. Previous studies show that as much as up to 50% porosity could be recorded in binder jet printing [1,2]. In this regard, different techniques were used to determine the percentage porosity from both manufacturing methods. The Archimedes method was used to determine the density and percentage porosity of the parts from the two methods. Similarly, percentage porosity was also determined using different tools in computed tomography (CT) analysis.
    [Show full text]
  • Process, Structure, Property and Applications of Metallic Glasses
    AIMS Materials Science, 3(3): 1022-1053. DOI: 10.3934/matersci.2016.3.1022 Received: 15 March 2016 Accepted: 07 July 2016 Published: 26 July 2016 http://www.aimspress.com/journal/Materials Short review Process, structure, property and applications of metallic glasses Bindusri Nair and B. Geetha Priyadarshini * Nanotech Research Innovation and Incubation Centre, PSG Institute of Advanced Studies, Coimbatore, Tamil Nadu, India-641004 * Correspondence: Email: [email protected]. Abstract: Metallic glasses (MGs) are gaining immense technological significance due to their unique structure-property relationship with renewed interest in diverse field of applications including biomedical implants, commercial products, machinery parts, and micro-electro-mechanical systems (MEMS). Various processing routes have been adopted to fabricate MGs with short-range ordering which is believed to be the genesis of unique structure. Understanding the structure of these unique materials is a long-standing unsolved mystery. Unlike crystalline counterpart, the outstanding properties of metallic glasses owing to the absence of grain boundaries is reported to exhibit high hardness, excellent strength, high elastic strain, and anti-corrosion properties. The combination of these remarkable properties would significantly contribute to improvement of performance and reliability of these materials when incorporated as bio-implants. The nucleation and growth of metallic glasses is driven by thermodynamics and kinetics in non-equilibrium conditions. This comprehensive review article discusses the various attributes of metallic glasses with an aim to understand the fundamentals of relationship process-structure-property existing in such unique class of material. Keywords: metallic glasses; glass transition; amorphous; mechanical properties 1. Introduction Metallic Glasses (MG) are a class of materials which has caught the eye of many researchers since Klement et al’s [1] first work on Au-Si alloys in early 1960’s.
    [Show full text]
  • Mechanical Behavior of Amorphous Alloys
    Acta Materialia 55 (2007) 4067–4109 www.elsevier.com/locate/actamat Overview No. 144 Mechanical behavior of amorphous alloys Christopher A. Schuh a,*, Todd C. Hufnagel b, Upadrasta Ramamurty c a Department of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, M.I.T., Cambridge, MA 02139, USA b Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218, USA c Department of Materials Engineering, Indian Institute of Science, Bangalore-560 012, India Received 14 August 2006; received in revised form 29 January 2007; accepted 31 January 2007 Available online 19 April 2007 Abstract The mechanical properties of amorphous alloys have proven both scientifically unique and of potential practical interest, although the underlying deformation physics of these materials remain less firmly established as compared with crystalline alloys. In this article, we review recent advances in understanding the mechanical behavior of metallic glasses, with particular emphasis on the deformation and fracture mechanisms. Atomistic as well as continuum modeling and experimental work on elasticity, plastic flow and localization, frac- ture and fatigue are all discussed, and theoretical developments are connected, where possible, with macroscopic experimental responses. The role of glass structure on mechanical properties, and conversely, the effect of deformation upon glass structure, are also described. The mechanical properties of metallic glass-derivative materials – including in situ and ex situ composites, foams and nanocrystal- reinforced glasses – are reviewed as well. Finally, we identify a number of important unresolved issues for the field. Ó 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. Keywords: Metallic glass; Amorphous metal; Mechanical properties 1.
    [Show full text]
  • The R3-Carbon Allotrope
    The R3-carbon allotrope: a pathway towards glassy carbon under high SUBJECT AREAS: MECHANICAL pressure PROPERTIES ELECTRONIC MATERIALS Xue Jiang1,2, Cecilia A˚ rhammar3, Peng Liu1, Jijun Zhao2 & Rajeev Ahuja1,4 STRUCTURE OF SOLIDS AND LIQUIDS 1Department of Materials and Engineering, Royal Institute of Technology, 10044 Stockholm, Sweden, 2Key Laboratory of Materials ELECTRONIC STRUCTURE Modification by Laser, Ion and Electron Beams Dalian University of Technology, Ministry of Education, Dalian 116024, China, 3Sandvik Coromant, Lerkrogsv. 13, S-126 80 Stockholm, Sweden, 4Department of Physics and Astronomy, Box 516, Uppsala University, 75120, Uppsala, Sweden. Received 8 November 2012 Pressure-induced bond type switching and phase transformation in glassy carbon (GC) has been simulated Accepted by means of Density Functional Theory (DFT) calculations and the Stochastic Quenching method (SQ) in a 25 April 2013 wide range of pressures (0–79 GPa). Under pressure, the GC experiences a hardening transition from sp- and sp2-type to sp3-type bonding, in agreement with previous experimental results. Moreover, a new Published crystalline carbon allotrope possessing R3 symmetry (R3-carbon) is predicted using the stochastic SQ 23 May 2013 method. The results indicate that R3-carbon can be regarded as an allotrope similar to that of amorphous GC. A very small difference in the heat of formation and the coherence of the radial and angular distribution functions of GC and the R3-carbon structure imply that small perturbations to this crystalline carbon Correspondence and allotrope may provide another possible amorphization pathway of carbon besides that of quenching the liquid melt or gas by ultra-fast cooling. requests for materials should be addressed to J.Z.
    [Show full text]
  • Atomistic Modelling of CVD Synthesis of Carbon Nanotubes and Graphene Cite This: Nanoscale, 2013, 5, 6662 James A
    Nanoscale View Article Online FEATURE ARTICLE View Journal | View Issue Atomistic modelling of CVD synthesis of carbon nanotubes and graphene Cite this: Nanoscale, 2013, 5, 6662 James A. Elliott,*a Yasushi Shibuta,b Hakim Amara,c Christophe Bicharad and Erik C. Neytse We discuss the synthesis of carbon nanotubes (CNTs) and graphene by catalytic chemical vapour deposition (CCVD) and plasma-enhanced CVD (PECVD), summarising the state-of-the-art understanding of mechanisms controlling their growth rate, chiral angle, number of layers (walls), diameter, length and quality (defects), before presenting a new model for 2D nucleation of a graphene sheet from amorphous carbon on a nickel surface. Although many groups have modelled this process using a variety of techniques, we ask whether there are any complementary ideas emerging from the different proposed growth mechanisms, and whether different modelling techniques can give the same answers for a given mechanism. Subsequently, by comparing the results of tight-binding, semi-empirical fi Creative Commons Attribution 3.0 Unported Licence. molecular orbital theory and reactive bond order force eld calculations, we demonstrate that graphene on crystalline Ni(111) is thermodynamically stable with respect to the corresponding amorphous metal and carbon structures. Finally, we show in principle how a complementary heterogeneous nucleation Received 17th April 2013 step may play a key role in the transformation from amorphous carbon to graphene on the metal Accepted 5th June 2013 surface. We conclude that achieving the conditions under which this complementary crystallisation DOI: 10.1039/c3nr01925j process can occur may be a promising method to gain better control over the growth processes of both www.rsc.org/nanoscale graphene from flat metal surfaces and CNTs from catalyst nanoparticles.
    [Show full text]
  • Laser Additive Manufacturing of Fe-Based Magnetic Amorphous Alloys
    magnetochemistry Review Laser Additive Manufacturing of Fe-Based Magnetic Amorphous Alloys Merve G. Ozden * and Nicola A. Morley Department of Material Science and Engineering, University of Sheffield, Sheffield S1 3JD, UK; n.a.morley@sheffield.ac.uk * Correspondence: mgozden1@sheffield.ac.uk Abstract: Fe-based amorphous materials offer new opportunities for magnetic sensors, actuators, and magnetostrictive transducers due to their high saturation magnetostriction (ls = 20–40 ppm) and low coercive field compared with polycrystalline Fe-based alloys, which have high magne- tostriction but large coercive fields and Co-based amorphous alloys with small magnetostriction (ls = −3 to −5 ppm). Additive layer manufacturing (ALM) offers a new fabrication technique for more complex net-shaping designs. This paper reviews the two different ALM techniques that have been used to fabricate Fe-based amorphous magnetic materials, including the structural and magnetic properties. Selective laser melting (SLM)—a powder-bed fusion technique—and laser- engineered net shaping (LENS)—a directed energy deposition method—have both been utilised to fabricate amorphous alloys, owing to their high availability and low cost within the literature. Two different scanning strategies have been introduced by using the SLM technique. The first strategy is a double-scanning strategy, which gives rise to maximum relative density of 96% and corresponding magnetic saturation of 1.22 T. It also improved the glassy phase content by an order of magnitude of 47%, as well as improving magnetic properties (decreasing coercivity to 1591.5 A/m and increasing magnetic permeability to around 100 at 100 Hz). The second is a novel scanning strategy, which Citation: Ozden, M.G.; Morley, N.A.
    [Show full text]
  • Functionalized Graphene Sheets As Molecular Templates for Controlled Nucleation and Self-Assembly of Metal Oxide-Graphene Nanocomposites
    www.advmat.de www.MaterialsViews.com COMMUNICATION Functionalized Graphene Sheets as Molecular Templates for Controlled Nucleation and Self-Assembly of Metal Oxide-Graphene Nanocomposites Xiaolin Li , Wen Qi , Donghai Mei , Maria L. Sushko , Ilhan Aksay , and Jun Liu* [1] Since its discovery, graphene has been widely studied for of how graphene surface controls nucleation of metal oxides; [1–4] [5–12] [13–16] electronics, energy, catalysis, and sensing applica- and ii) to explore novel synthesis methods to control nucleation [17,18] tions. Functionalized graphene sheets (FGS) (or chemically during self-assembly processes. For the fi rst objective, we syn- [19–21] derived graphene sheets), along with other graphene mate- thesized FGS-SnO2 and FGS-TiO2 and demonstrated that the rials including pristine graphene and graphene oxide (GO),[ 4 , 22 ] , functional groups on FGS surface determine the nucleation have been explored extensively because of their good electrical energy, and thus control the nucleation sites and nucleation conductivity and tunable functional groups that are either density. We also demonstrated that FGS can tune the nucleation retained after the chemical/physical reduction of graphene energies for different crystalline structures and thereby control oxide or introduced during the exfoliation of graphite/expand- the crystalline phases. For the second objective, we use FGS as [19–25] able graphite. Recently, FGS-metal oxide composites such a molecular template to direct the self-assembly of surfactant as FGS-SnO2 , FGS-TiO2 , FGS-Co3 O4 , GO-mesoporous SiO2 , etc. micellar structures and produce ordered, mesoporous arrays of have been prepared either by direct deposition or surfactant- crystalline metal oxide composites (FGS-mesoporous TiO2 and [6,7,10–12,15,26] mediated synthesis.
    [Show full text]
  • Dispersion of Fullerenes in Natural Water and Their
    DISPERSION OF FULLERENES IN NATURAL WATER AND THEIR BEHAVIOR IN WATER TREATMENT PROCESS A Thesis Presented to The Academic Faculty by Hoon Hyung In Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the School of Civil and Environmental Engineering Georgia Institute of Technology August 2008 DISPERSION OF FULLERENES IN NATURAL WATER AND THEIR BEHAVIOR IN WATER TREATMENT PROCESS Approved by: Dr. Jae-Hong Kim, Advisor Dr. Seung Soon, Jang School of Civil and Environmental School of Material Science and Engineering Engineering Georgia Institute of Technology Georgia Institute of Technology Dr. Joseph B. Hughes Dr. Vernon L. Snoeyink School of Civil and Environmental School of Civil and Environmental Engineering Engineering Georgia Institute of Technology University of Illinois Dr. Michael H. Bergin School of Civil and Environmental Engineering Georgia Institute of Technology Date Approved: June 11, 2008 [To Se-Eun and Juhee] ACKNOWLEDGEMENTS Firstly, I would like to thank my advisor, Dr. Jae-Hong Kim. He not only provided me a chance to become a piece of this great legacy of Georgia Tech., but also showed me the example of a great advisor with extensive knowledge, creative mind, and friendliness. I acknowledge my thesis committee, Dr. Joseph Hughes, Dr. Vernon Snoeyink, Dr. Michael Bergin, and Dr. Seung Soon Jang for agreeing to be my committee and providing invaluable comments and advices on my research. All the members of Dr. Kim and Dr. Huang’s groups and Korean graduate students in the environmental engineering program are greatly appreciated. It was very nice to share friendship with them in and out of the campus and discussions and advices from them brought me valuable idea on my research.
    [Show full text]
  • A Dissertation Entitled by Miaomiao Zhang
    A Dissertation entitled Design of Hinge-Line Geometry to Facilitate Non-Plastic Folding In Thin Metallic Origami- Inspired Devices by Miaomiao Zhang Submitted to the Graduate Faculty as partial fulfillment of the requirements for the Doctor of Philosophy Degree in Engineering ___________________________________________ Dr. Brian Trease, Committee Chair ___________________________________________ Dr. Halim Ayan, Committee Member ___________________________________________ Dr. Lesley Berhan, Committee Member ___________________________________________ Dr. Sarit Bhaduri, Committee Member ___________________________________________ Dr. Azadeh Parvin, Committee Member ___________________________________________ Cyndee Gruden, PhD, Dean College of Graduate Studies The University of Toledo May 2019 Copyright 2019 Miaomiao Zhang This document is copyrighted material. Under copyright law, no parts of this document may be reproduced without the expressed permission of the author. An Abstract of Design of Hinge-Line Geometry to Facilitate Non-Plastic Folding In Thin Metallic Origami- Inspired Devices by Miaomiao Zhang Submitted to the Graduate Faculty as partial fulfillment of the requirements for the Doctor of Philosophy Degree in Engineering The University of Toledo May 2019 Origami is the traditional art of paper folding, which yields objects that can be considered, in engineering terms, as mechanisms with relative motion between panels (paper) constrained by hinges (folds). Non-paper materials are often studied for origami- inspired applications
    [Show full text]
  • Download;Jsessionid=C84383C5 BB2BBA983BF41F08CE6476D6?Doi=10.1.1.578.7746&Rep=Rep1&Type=Pdf (Accessed on 19 March 2021)
    polymers Review From Amorphous Silicones to Si-Containing Highly Ordered Polymers: Some Romanian Contributions in the Field † Maria Cazacu * , Carmen Racles, Mirela-Fernanda Zaltariov, Mihaela Dascalu, Adrian Bele , Codrin Tugui, Alexandra Bargan and George Stiubianu Department of Inorganic Polymers, “Petru Poni” Institute of Macromolecular Chemistry, Aleea Gr. Ghica, Voda 41A, 700487 Iasi, Romania; [email protected] (C.R.); [email protected] (M.-F.Z.); [email protected] (M.D.); [email protected] (A.B.); [email protected] (C.T.); [email protected] (A.B.); [email protected] (G.S.) * Correspondence: [email protected]; Tel.: +40-232-217-454; Fax: +40-232-211-299 † Dedicated to 100 years from the birth of Professor Cristofor I. Simionescu (1920–2007). Tribute to the Memory of Dr. Mihai Marcu, recently passed away (1933–2020). Abstract: Polydimethylsiloxane (PDMS), in spite of its well-defined helical structure, is an amorphous fluid even at extremely high molecular weights. The cause of this behavior is the high flexibility of the siloxane backbone and the lack of intermolecular interactions attributed to the presence of methyl groups. These make PDMS incompatible with almost any organic or inorganic component leading to phase separation in siloxane-siloxane copolymers containing blocks with polar organic groups and in siloxane-organic copolymers, where dimethylsiloxane segments co-exist with organic ones. Self-assembly at the micro- or nanometric scale is common in certain mixed structures, including micelles, vesicles, et cetera, manifesting reversibly in response to an external stimulus. Polymers Citation: Cazacu, M.; Racles, C.; with a very high degree of ordering in the form of high-quality crystals were obtained when silox- Zaltariov, M.-F.; Dascalu, M.; Bele, A.; ane/silane segments co-exist with coordinated metal blocks in the polymer chain.
    [Show full text]
  • 1111111111111111111Inmumu
    1111111111111111111inmumu (12) United States Patent (10) Patent No.: US 8,571,615 B2 Hays (45) Date of Patent: Oct. 29, 2013 (54) SUPERCONDUCTING METALLIC GLASS OTHER PUBLICATIONS TRANSITION-EDGE-SENSORS Bauer et al., "Homogene mechanische Spannungen in (75) Inventor: Charles C. Hays, Pasadena, CA (US) aufgedampften Schichten", Zeitschrift Fur Physik, 220, 293-304 (1969) (73) Assignee: California Institute of Technology, V. Sushkov, "TES microcalorimeter readout via transformer", Nuc. Pasadena, CA (US) Instr. and Methods in Physics Research a vol. 530, 234-250 (2004). J.H. Mooij, "Electrical Conduction in Concentrated Disordered (*) Notice: Subject to any disclaimer, the term of this Transition Metal Alloys", Phys. Status Solidi A 17, 521-530 (1973). patent is extended or adjusted under 35 Ullom et al., "Suppression of excess noise in Transition-Edge Sen- U.S.C. 154(b) by 106 days. sors using magnetic field and geometry", Nuc. Instr. and Meth. A 520, 333-335 (2004). (21) Appl. No.: 13/230,653 Aslamazov et al., "The Influence of Fluctuation Pairing of Electrons on the Conductivity of Normal Metal", Phys. Letters 26A, No. 6, (22) Filed: Sep.12, 2011 238-239 (1968). Chervenak et al., "Fabrication of transition edge sensor X-ray (65) Prior Publication Data microcalorimeters for Constallation-X", Nuc. Instr. and Meth. A 520, 460-462 (2004). US 2012/0065072 Al Mar. 15, 2012 Howson et al., "The Electron Transport Properties of Metallic Glasses", Physics Reports (Review Section of Physics Letters) 170, Related U.S. Application Data No. 5, 265-324 (1988). Lindeman et al., "Characterization and reduction of noise in Mo/Au (60) Provisional application No.
    [Show full text]
  • Microwave Magnetic Materials: from Ferrites to Metamaterials
    Microwave magnetic materials: from ferrites to metamaterials Soft magnetic materials and ferromagnetic metals are widely used in microwave applications. The newly-developed metamaterials, instead of replacing them, can combine with them to extend their potential. Two other systems – thin layers and magnetic microwires – offer equally remarkable microwave properties Pyramidal radar-absorbent materials in the Aquitaine science and engineering research centre (CEA/Cesta) anechoic chamber at Le Barp, near Bordeaux. Ferrites, which absorb electromagnetic radiation in certain frequency ranges, can be fitted under the pyramid-shaped radiation-absorbent foams lining the walls of the anechoic chambers to further increase the absorbent capacities. Philippe Labèguerie/CEA agnetic materials have long been used for micro- antenna substrates, radar absorbents, tunable fil- Mwave applications. Inductors, antenna cores ters, etc. and ferrite filters are also widely employed. Finally, when these magnetic materials are magne- Microwave permeability µ(f) is a fundamental phy- tized, they become non-reciprocal, which means their sical unit when working with these inductive appli- characteristics depend on the direction of motion of cations, as it can be used to gauge the performance the wave crossing through them. This non-recipro- of the material. Permeability describes the response city is put to use to build circulators and isolators of induction b to a magnetic field h oscillating at a employed in radar systems, mobile telephone relay frequency f, as: b = µ(f).µ0.h, where µ0 is the vacuum stations, etc. Ferrites and garnets are still the first- permeability. Therefore, it is the materials with high choice materials for these applications. Ferrites have permeability µ(f) that are used, as they can generate a long history as microwave materials.
    [Show full text]