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The Stratigraphy, Petrology, and Depositional Environments of the Maryville Limestone (Middle Cambrian) in the Vicinity of Powell and Oak Ridge, Tennessee

The Stratigraphy, Petrology, and Depositional Environments of the Maryville Limestone (Middle Cambrian) in the Vicinity of Powell and Oak Ridge, Tennessee

University of Tennessee, Knoxville TRACE: Tennessee Research and Creative Exchange

Masters Theses Graduate School

12-1986

The , , and Depositional Environments of the Maryville (Middle Cambrian) in the Vicinity of Powell and Oak Ridge, Tennessee

Michael Glenn Kozar University of Tennessee - Knoxville

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Recommended Citation Kozar, Michael Glenn, "The Stratigraphy, Petrology, and Depositional Environments of the Maryville Limestone (Middle Cambrian) in the Vicinity of Powell and Oak Ridge, Tennessee. " Master's Thesis, University of Tennessee, 1986. https://trace.tennessee.edu/utk_gradthes/1232

This Thesis is brought to you for free and open access by the Graduate School at TRACE: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Masters Theses by an authorized administrator of TRACE: Tennessee Research and Creative Exchange. For more information, please [email protected]. To the Graduate Council:

I am submitting herewith a thesis written by Michael Glenn Kozar entitled "The Stratigraphy, Petrology, and Depositional Environments of the Maryville Limestone (Middle Cambrian) in the Vicinity of Powell and Oak Ridge, Tennessee." I have examined the final electronic copy of this thesis for form and content and recommend that it be accepted in partial fulfillment of the requirements for the degree of Master of Science, with a major in Geology.

Kenneth R. Walker, Major Professor

We have read this thesis and recommend its acceptance:

Steven G. Driese, Thomas W. Broadhead

Accepted for the Council: Carolyn R. Hodges

Vice Provost and Dean of the Graduate School

(Original signatures are on file with official studentecor r ds.) To the Graduate Council:

I am submitting here with a thesis written by Mi chael Glenn Kozar entitled "The Stratigraphy , Petrology , and Depositional Environments of the Maryville Limestone (Middle Cambrian) in the Vicinity of Powell and Oak Ridge , Tennessee. " I have examined the final copy of this thesis for form and content and recommend that it be accepted for the degree of Master of Science , with a major in Geology.

We have read this thesis and recommend its acceptance:

Accepted for the Council:

Vice Provost and Dean of The Graduate School STATEMENT OF PERMISSION TO USE

In presenting this thesi s in partial fulfillment of the requirements for a Master's degree at The University of

Tennessee , Knoxville , I agree that the Library shall make it available to the borrowers under rules of the Library.

Brief quotations from this thesis are allowable without spe cial permission, provided that accurate acknowledgment of the source is made .

Permission for extensive quotation from or reproduction of this thesis may be granted by my major professor , or in his absence , by the Head of Interlibrary

Services when, in the opinion of either , the proposed use of the material is for scholarly purposes. Any copying or use of the material in this thesis for financial gain sh all not be allowed without my permission.

Signature AJlir:..hcuJ b}e-i'tf'l J{tJ6,aV

Date II - .2s--8'b THE STRATIGRAPHY, PETROLOGY , AND DEPOSITIONAL ENVIRONMENTS

OF THE MARYVILLE LIMESTONE (MIDDLE CAMBRIAN) IN THE

VICINITY OF POWELL AND OAK RIDGE, TENNESSEE

A Thesis

Presented for the

Master of Science

Degree

The University of Tennessee

Mi chael Glenn Ko zar

December 1986 DEDICATION

This thesi s is dedicated to my Mom and Dad whose constant

support made this research possible. iii

ACKNOWLEDGMENTS

I wish to express my sincere appreciation to Dr .

Kenneth R. Walker, Carden Professor and Head of the

Department of Geological Sciences, for his close supe rvision and encouragement during my tenure at The

University of Tennessee , Knoxville .

I would also like to thank the other members of my committee, Dr . Steven G. Driese and Dr . Thomas w. Broadhead of the University of Tennessee , Knoxville for their patience during the various stages of this thesis and for their many helpful cr iticisms in the final draft.

I am grateful for the many constructive and stimulating discussions with my fellow members of "The

Carbonate Bank" as well as other fellow students at the

Department . Special thanks go to Jim Weber and Eric Johnson for numerous discussions concerning carbonate se dimentology and diageneis, which aided in the completion of this thesis, and in my knowledge of carbonates in general.

Finally , I would like to thank Dr . Steve Haase at Oak Ridge

National Laboratories for allowing acce ss to the two drill cores.

This research has been supported by grants from the

Mobi l Carbonate Fund and the Appalachian Basin Industrial

Associates to Dr. Kenneth R. Walker and by the following grants to me : 1) a grant from Sun Exploration and iv

Production Company (85); 2) two Grants-in-Aid of Research from Sigma Xi (85-86) ; 3) a grant from the American

Association of Petroleum (85); and 4) monies from the Don Jones Fund of the Department of Geological

Sciences , The University of Tennessee . v

ABSTRACT

The Maryville Limestone (Middle Cambrian) is part of the nearly 600 meter thick Conasauga Group, which crops out along a series of northeasterly trending strike belts in the Valley and Ridge Province of the southern Appalachians.

The interlayered limestone, , and dolostone comprising the conasauga result from the interfingering of the

Conasauga Shale to the west and northwest and the Honaker

Dolomite to the east and southeast. Apart from detailed lithologic and paleoenvironmental work concerning Conasauga strata in southwestern Virginia and northeasternmost

Tennessee, few studies have examined the Maryville in detail in east Tennessee.

In the study area, a total of 330 m of section were measured and described at three localities (Clinton

Highway, Joy 2,and GW 129). Although the base of the

Maryville is unexposed at Clinton Highway (77.24 m), both the Joy 2 (142.48 m) and the GW 129 (107.23 m) localities record a complete Maryville sequence. These sections were analyzed in order to establish a paleoevnvironmental model for the Maryville near the transition of this interval into the Conasauga Shale. The 12 recognized within the stratigraphic sections reflect the interaction between contemporaneous shallo�-water carbonate ramp environments and a siliciclastic-dominated intrashelf basin. Deposition vi

on the carbonate ramp was in the form of lime mudstone and

wackestone and oolitic and oncolitic packstone and

grainstone . In these shallow-water areas, wave and storm

influence were at a maximum as evidenced by the abundance

of wave-rippled , planar , and microhummocky cross-laminated

calcareous . To the west and southwest,

deeper-water conditions were more common . on

the deeper-water margin of the ramp and within the

intrashelf basin occurred near or below mean storm

wave-base . Deposition was mainly in the form of

discontinuous , wave-rippled (linsen-bedded ), quartz-rich

pe loidal packstone ; very thin-bedded , planar and low-angle

cross-laminated pe loidal packstone/grainstone ;

carbonate-streaked mudstone ; and shale . There,

sedimentation was governed by fairweather waves and storms

that winnowed fine-grained carbonate in shallow-water and

transported it off-ramp . In some instances , bottom-hugging

geostrophic (?) currents were capable of redistributing

, thereby modifying the earlier hemipelagically

deposited carbonate . Where they were not winnowed by

currents, rhythmic interbeds of lime mud and shale were

preserved .

Throughout these sections limestone-clast conglomerate beds also were deposited . Evidence from clast fabrics , type , geometries , and associated lithologies

indicate that conglome rate deposits owe their origin to two vii

related end-member processes , storms and

mas�-sediment-gravity movement . Storm-derived conglomerate

beds occur more commonly in shallower-water ramp areas .

Debris-flow derived conglomerate deposits underwent a more

complex history and occur in more basinward areas .

A modified Markov-chain analysis was applied to the

nearly 1100 lithologic transitions recorded at the three

localities to objectively test for cyclicity. Although

statistical analysis supports the presence of rare and

subtle cycles , longer-term 10 , 000-100 ,000 year Milankovitch

cycles, similar to those proposed for coeval deposits in

southwestern Virginia, are not recognized within the

Maryville sequence . The near absence of statistically

verifiable cycles is believed to be related to the heterogenous nature of the ramp depositional , as well as the prevalence of storm related processes . Storms were sporadic in time and space and capable of reworking

the sediment , thus modifying the stratigraphic record.

Analysis of the three Maryville sections reveals a

sequential alternation of lithologies which collectively

indicate progradational events . Progradational patterns are

asymmetric and record the increasing inf luence of

shallow-water carbonate environments which extended

southwestward into the intrashelf basin. These sequences are common elsewhere in the Maryville along structural

strike . Progradational events we re superimposed on an viii overall transgressive sequence and may have been triggered by stillstands in regional sea-level and/or a lull in . ix

TABLE OF CONTENTS

CHAPTER PAGE

1. INTRODUCTION ...... 1

Stratigraphic Setting and Previous

Work . . • • . . . • • • • . . . . • • • • . . . • • • • ...... • • • • . . . • • • 2

Biostratigraphy of the Maryville ..••••.••...•••. 5

Purpose of the Study . • • • • • • • . • • . • • • . . . • • • • • • . • • • 8 Lac a tion ...... 9

2. PETROLOGY AND DEPOSITIONAL ENVIRONMENTS

OF THE MARYVILLE LIMESTONE ••.•.•••••...•••.....••• 12

Introduction ...... 12

Methods . . . . . • • ...... • • ...... • • ...... • • . • 15

Format of The Chapter •.....••••...••••••...•••••. 20

Lithology 1-Shale ..••••••.•••••••.•.••••••.••• 21

Lithology 2 - Planar and Low-Angle Cross-laminated , Carbonate-Streaked

Muds tone . . . . • • • • • . . . . • • • • . . . • . • • • • • . . . • . . • • . . . 2 9 Lithology 3 - Very Thin-Bedded , Quartz-rich

Peloidal Packstone/Grainstone and Shale •••.••• 33 Lithology 4 - Wave-rippled and Linsen-bedded Quartz-rich , Peloidal Grainstone

and Interbedded Shale • . . . . • • • • . • . • . . • • • . • • . . . • 45 Lithology 5 - Nodular Mudstone/Wackestone

and Interbedded Shale . • • . • . . . . • • . . • • . . . . • • . • • . . 50

Lithology 6-Calcareous Quartz Siltstone •••..•. 57

Lithology 7-Thin-bedded Mudstone/Wackestone •..• 67 Lithology 8 - Oncolitic Packstone and

Interbedded Wackestone/Mudstone •••...•••••.•.. 70 Lithology 9 - Very Thin to Thin-bedded

Oolitic Grainstone Caps .•••••...... •••.....•.. 82 Lithology 10 - Medium- to Thick-Bedded,

Oolitic (Intrashelf ) Packstone •...•••..•...••. 86 Lithology 11 - Medium- to Thick-Bedded

Oolitic Packstone and Grainstone •.•....••••.•• 88 Lithology 12 - Medium-Bedded , Laminated

Mudstone/Wackestone . • ...... • • • • . . . • • • • • • . . . . • . 9 3

3. LIMESTON E-CLAST CONGLOMERATE BEDS

Introduction ...... 98

General Geology ...... 99 Problematic Shale Matrix Conglomerate Beds

(Debris-Flows/Storms? ) ...••••.....••...•..•••.. 100

Debris-Flow Derived Conglome rate Beds ••...•..••.. 102

Storm-Derived Conglomerate Beds ..•••••..••••...•• 110 X

CHAPTER PAGE

Vertical Sequence Analysis of Maryville

Limestone-Clast Conglomerate Beds ••••••••.•••• 118 Controlling Factors and Geologic

Implications ...... 120 Conc lusions ...... 127

4. CYCLICITY AND THE HYDRODYNAMIC REGIME ALONG A RAMP -TO-BASIN PROFILE

Introduction ...... 130

Facies Sequences ...... 131

Stratigraphic Analysis . • • • • • • • • • . . . . • • . • • • . • . . • . 140

Cyclicity ...... 146

Carbonate Ramp Dynamics- A Hypothesis .•••••••.•. 151

Conclusions ...... 158

5. PALEOENVIRONMENTAL SYNTHESIS

Introduction ...... 160

Paleoenvironmental Model ....•..•••••.....•••••.• 162

General Trends ...... 168

causes of •••••••.....•••••...... ••• 175

Conclusions ...... 179

6. SUMMARY AND CONCLUSIONS .....•...•••....••••••.... 181

LIST OF REFERENCES ...... • • • • • • . . . . • • • . . . . . • . . • • • . . • . . . 18 5

APPENDICES . . . • ...... • ...... • • • ...... 203

A. DESCRIPTION OF STRATIGRAPHIC SECTIONS ...•••••..... 204

B. PETROGRAPHIC CONSTITUENT ANALYSIS .••••.•....•.•••• 239

VITA ...... • ...... • • ...... • • ...... • . • . . 242 xi

LIST OF TABLES

TABLE PAGE

2.1. Distinguishing Features of the 12 Lithologies

Recognized in the Maryville Limestone •••••••••• 22

B.l. Petrographic Constituent Analysis for Selected Thin-sections of the

Maryville Limestone ••••.•..•••••••••...••••••. 240 xii

LIST OF FIGURES

FIGURE PAGE

1. 1. Stratigraphic Relationships of the Formations Within the Conasauga Group ...... 4

1. 2. Generalized Temporal Relationship of Cambrian

Units in East Tennessee ••••••••••••••••••••••• 7

1. 3. Location Map of the Study Area Within the Copper Creek and Hunter Valley Allocthons

in East Tennessee ••••••••••••••••••••••••••••• 10

2. 1. Generalized Stratigraphic Section of the

Maryville Limestone at Clinton Highway •••••••• 17

2. 2. Generalized Stratigraphic Section of the

Maryville Limestone at Joy 2 •••••••••••••••••• 18

2. 3. Generalized Stratigraphic Section of the

Maryville Limestone at GW 129 ••••••••••••••••• 19

2. 4. Characteristics of Lithology 1 - Shale 24

2. 5. Field Photographs of Lithologies 2 and 3 ...... 30

2. 6. Types of Laminations Found Within Lithology 3 ...... 3 5

2. 7. Features Indicative of Probable Suspension Settling and current-Related Sedimentation ...... 37

2. 8. Soft-Sediment Deformation Features and

Burrow Types Found Withi Lithology 3 ••••••••• 39

2. 9. Wave-generated Structures Found Within Lithology 4 ...... 46

2. 10. Characteristics of Lithology 5 51

2. 11. Characteristics of Lithology 6 58

2. 12. Characteristics of Lithology 7 ...... 68

2. 13. Characteristics of Lithology 8 ...... 72

2. 14. Characteristics of Lithology 8 75 xiii FIGURE PAGE

2 o 15 o Abundance of Ooids , Oncoids , and Algal

Grains in Lithologies 8, 9, and 11 000000000000 79

2 o l6 o Characteristics of Lithology 9 oooooooooooooooo 83

2 o 17 o Characteristics of Lithology 11 ...... 89

2 o l8 o Characteristics of Lithology 12 ...... 94

3 o l o Characteristics of Shale Martrix

Conglomerate Beds oooooooooooo••••ooo•o•••o•o•• 101

3.20 Problematic Shale Matrix Conglomerate and Debris-Flow Derived Limestone-Clast

Conglomerate Beds ••••. o .. o o ••.o. • • • • • . • • • • • • • . 103

3o 3. Characteristics of Debris-Flow Derived

Conglomerate Beds .....••••..••••..••••••...o.. 107

3.4. Storm-derived Limestone-clast Conglomerate

Beds ...... 112

3.5. Characteristics of Storm-derived

Conglomerate Beds ··············o••········••o• 115

3o 6. Upward-thickening Sequences at

Clinton Highway ...... 121

3.7. Upward-thickening and Thinning Sequences at Joy 2 ...... 12 2

3.8. Upward-thickening and Thinning Sequences

at GW 12 9 • • • . . • • . . . . . • • • • . . • • • • • . • • • • . • • • . . • • • 12 3

3o9. Distribution of Limestone-Clast Conglomerate

Types ...... • • . . . • ...... • . . 129

4ol . Generalized Siliciclastic Dominated

Basin-to-carbonate Ramp Profile •...••••...•••• 133

4.2. Lithologic Thickness Trends as Observed

in Stratigraphic Sections •••...•••...•...... • 138

4o 3. Tally Matrix of Lithologic Contacts at Thorn Hi ll ...... 141

4.4. Tally Matrix of Lithologic Contacts

at Clinton Highway ········•••••o••············ 142 xiv FIGURE PAGE

4.5. Tally Matrix of Lithologic Contacts

at Joy 2 . • . . • ...... 143

4.6. Tally Matrix of Lithologic Contacts

at GW 129 • • ...... • . • • • ...... • • • ...... 14 4

4.7. Flow-Chart Summary Showing Lithologic Transition Based On Vertical

Contact Analysis ...... • • • • • . • . . • • • • • • • • • • • . . . • 145

4. 8. Cyclicity ...... 148

4.9. Current and Wave Trends Plotted

Palinspastic Base Map •.•••••...•.•••••••.•.... 152

4.10. Hydrodynamic Regime ...••••.•••..•.••••••••.••• 155

5 .1. Palinspastic Map of Middle and Upper Cambrian Age in East Tennessee 161

5.2. Generalized Schematic Block Diagram of the Ramp-To-Basin Profile During

Maryville Time ...... 163

5.3. Vertical Distribution of Skeletal and Nonskeletal Allochems as well as Matrix Type

at the Clinton Highway Section ...••.••••••••.. 172

5.4. Stratigraphic Distribution of Conglomerate ,

Oo litic , and Oncolitic Units at Joy 2 .•...•••• 173

5.5. Stratigraphic Distribution of Conglomerate

and Oolitic Units at GW 129 .•••••• ...... ••••.• 174 1

CHAPTER 1

INTRODUCTION

Mu ch of the literature concerning Cambrian strata in

North Ame rica has focused on the platform-to-basin transitions of the western United States, Texas , and

Alberta (e.g. , Aitken, 1966, 1978 ; Ahr , 1971 ; Palmer, 1971 ;

Sepkoski, 1975) . Deeper-water , off-platform sequences of limes tone and shale have been described from the northern and north-central Appalachians and Newfoundland (e.g. ,

Hubert et al. , 1977 ; Ke ith and Friedman , 1977).

Paleoenvironmental studies of exposed Middle and Upper

Cambrian strata in the central and southern Appalachians have been restricted to those rocks which crop out in extreme northeastern Tennessee and southwestern Virginia

(D erby , 1965; Pfiel and Read, 1980; Erwin 1981; Markello and Read , 1981, 1982 ; Simmons, 1984). Few studies have examined Midd le to Upper Cambrian strata in east Tennessee

(Conasauga Group ) occurring within the transition from platform carbonates to off-platform as described by

Rod ge rs (1953) . Much of the literature (e.g. , Bu tts , 19 40;

Raymond, 1959) pertaining to this transitional, or mixed carbonate and fine-grained siliciclastic phase was published prior to 1970 and consists of generalized stratigraphic, lithologic, and paleontologic descriptions . 2

Although these older stud ies are important , techniques available today allow for more detailed analysis . As a

result , Middle to Upper Cambrian strata that crop out in east Tennessee provide a unique opportunity for regional paleoenvironmental study .

Stratigraphic Setting and Previous Work

During Cambrian time deposition along the eastern margin of North Ame rica wa s dominated by a broad , shallow ,

carbonate shelf (Bird and Dewey , 1970; Palmer , 1971 ).

Ly ing adj acent to this shelf was a complex of nearshore

siliciclastic environments to the northwest, and a

subsiding marine basin to the southeast . It has been

suggested that the regional tectonic setting was that of an

is land-arc complex separated from the eastern margin of the

North Ame rican craton by a marginal or back-arc basin

(Hatcher , 1978 ). The Cambrian lithologies representing these ••tectonic provinces" roughly parallel the present-day eastern margin of North Ame rica .

The Maryville Lime stone (Middle Cambrian ) of east

Tennessee formed as a part of this complex and is the subje ct of this thesis . The Maryville is a formation within the Conasauga Group wh ich crops out in a series of northeasterly-trending , im bricate thrust sheets within the

Va lley and Ridge Province of the southern Appalachians . The 3

Conasauga (Fig . 1.1) consists of an interbedded package of

shale , limestone , and dolostone , that result from an

interfingering between the Conasauga Shale to the west and

northwest and the Honaker Dolomite to the east and

southeast. The lowermost bed of the Conasauga occurs above

the highest prominent bed of the Rome Formation , whereas the uppermost Conasauga lies just beneath the

Copper Ridge Dolomite (Knox Group ), a dark gray , chert-bearing dolostone (Rodgers , 1953 ). Based on the po sition of the eastern limestone and western shale margins within the Conasauga , depositional strike of these formations is oblique to the northeasterly trending thrust be lts in the southern Va lley and Ridge (Rodgers , 1953;

Palme r, 1971; Markello and Read , 1981; Woodward et al .,

1983 ). An imaginary line trending north-northeast through

Tazewell, Knoxville, and Madisonville , Tennessee separates the western phase from the central phase of sedimentation and roughly parallels depositional strike (see Fig . 1.1).

The Maryville Limestone was originally included in the

Knox Shale by Safford (1 8 69 ) and in the Connasauga

(original spelling ) by Hayes (1871). Since then , the

Ma ryville has been named by Ke ith (1 895) for exposures of heavy-bedded , massive , blue limestone which crop out in the vicinity of Maryville , in Blount County , Tennessee .

Although no type section has been proposed for the

Maryville , a generally accepted informal type section crops 4

KENTUCKY

TENNESSEE NORTH I

GEORGIA

. NORTHWESTERN CENTRAL SOUTHEASTERN PHASE PHASE PHASE

Copper Ridge Dolomite

500 � • -; E

Ill ..J c u 2!10 "' ..J c � ... a: Ill > 0

Figure 1.1. Stratigraphic relationships of the formations within the Conasauga Group (modified from Rodgers , 1953) . Approximate position of the formations within the study area lie within the central phase of sedimentation . Map of east Tennessee shows the imaginary line which separates the western phase from the central phase of sedimentation and roughly parallels deposit ional strike . 5 out just northwest of Maryville (Bridge , 1956). A summary of-the stratigraphic nomenclature (i.e. , formational names ) whi ch has been used for the Lower to Upper Cambrian is presented by Simmons (1984, p. 39) .

Since its first description , few studies have examined the Ma ryville in any great detail. Detailed paleoenvironmental analysis of the Maryville was not conducted until Simmons (1984) proposed that deposition of the Maryville in the vicinity of Thorn Hill, Tennessee occurred within a "d istal" ca rbonate ramp to intrashelf basin setting broadly similar to that proposed by Markello and Read (1981, 1982 ) for co eval strata in southwestern

Virginia. This paleoenvironmental setting was composed of five , broadly contemporaneous lithofacies which , from we st to east, include: 1) a mixed carbonate and fine-grained siliciclastic intrashelf basin; 2) an oolitic and oncolitic deposited within the active zone of the oolitic shoal and lagoonward of them ; 3) a stabilized oolitic shoal ; 4) a Renalcis boundstone deposited in a protected environment shelfward of the stabilized oolitic shoal; and

5) a restricted , carbonate-dominated shelf lagoon .

Biostratigraphy of the Maryville

Compared with the do lomite-dominated and faunally impoverished strata of the overlying Knox Group , the 6 dolostone , limestone , and shale strata that comprise the

Conasauga Group contain faunas of greater variety and abundance (McLaughlin, 1973). This fauna briefly includes: , phosphatic brachiopods , pelmatozoans , acritarchs, conodonts , and various taxa of unknown affinity

(e.g. , Resser , 1938; Bridge , 1956; Derby , 1965; Rassetti,

1965; Clendening , 1978). Although Cambrian acritarchs and conodonts may be useful biostratigraphic tools, to date , co rrelation has been based on trilobites.

In the Conasauga , zonations parallel the upper Middle to lower Upper Cambrian (Dresbachian ) trilobite in the midcontinent region

(McLaughlin, 1973). The Cedaria Zo ne is restricted to the

Nolichucky Shale , whereas the overlying Crepicephallus and

Aphelaspis zones occu r in the Maynardville Limestone and are above the Middle-Upper Cambrian boundary (Fig . 1.2) .

From the work of Derby (1965 ) and Rasseti (1965) the top of the Maryville is generally thought to range in age from from the Bolaspide lla Zone (Albertan ) to the older Cedaria

Zone (Dresbachian ). McLaughlin documented that the base of the Cedaria Zo ne is approximately 4.6 m above the top of the Maryville at Thorn Hill, the area of Simmons study . In the vicinity of Knoxville , near the area of the present study , McLaughlin reported the base of the Cedaria Zone to be more than 24.4 m above the Maryville/Nolichucky contact .

Although there may be some disagreement about the age of 0 0 NORTH AMERICAN TRILOBITE CA MBRIAN OF SOUTHERN � ZONES APPALACHIANS .... (Rodvers,I9S3l CL sw. �EPOCH �E C McLouvhlin,l973) EAST TENNESSEE VA.

.... CL ::I ::::�.., TREMPEALEAUAN 0 "z a: COPPER ""o UPPER C) ...... AND l:en z )( RIDGE (.)1&.1 "" 0 DOLOMITE 02 FRANCONIAN z z- )( ¥ o.J 0 (.) a: (.) ? - APHEL ASPIS - MAYNARDVILLE LATE LIMESTONE z CREPlCEPHALUS .... "" DRESBACHIAN ------1- � CL .... :i CD CEDAR/A ::I _, NOLICHUCKY SHALE 0 2 0 "" _, ...... "" ------a: l: 0 (.) C!) en MARYVILLE 0

"" "" LIMESTONE a:IIJ C) C!) ¥ ::I ::I 1&.1!: 0 "" "" ROGERSVILLE lo:::f 0 MIDDLE en en ""o a: "" "" SHALE z_, CD ALBERTAN BOLASPIDEUA z z oo _, 0 0 RUTLEDGE l:o .... (.) (.) MEDIAL LIMESTONE

PUMPKIN VA LLEY SHALE ------WAUCOBAN ROME FORMATION �y

Figure 1.2. Ge neralized temporal relationship of Cambrian units in east Tennessee . 8

the Maryville /Nolichucky contact , it is evident that the

datum becomes progressively older towards the southwest and

into the shale (intrashelf ) basin.

Collectively , the Maynardville and Nolichucky are

believed to be late Middle Cambrian (?) to early Late

Cambrian (Dresbachian) in age . Although the precise age of

the lower part of the conasauga is uncertain, the Maryville

is thought to be late Middle Cambrian in age .

Purpose of the Study

The primary purpose of this study is to synthesize a

stratigraphic , sedimentologic , and depositional framework

for the Maryville Limestone in east Tennessee , near the

transition of this interval westward into the shale of the

intrashelf basin. Related sequences to the northeast wi ll also be considered so that a complete history of the ramp

and intrashelf basin can be synthesized .

This study wi ll address the following major problems:

1) What type of sedimentary deposits characterize the

Ma ryville within its transitional phase of

sedimentation?

2) What were the primary transportational processes

responsible for the deposition of the limestone-clast

conglomerate beds which are so prominent in the

Maryville? 9

3) What types of processes are responsible for the

deposition of mixed carbonate and fine-grained

siliciclastics?

4) Many of the within the

Maryville are current- and wave-induced . Do these

structures show a preferred orientation? If so, how can

we explain these orientations?

5) Do these deposits show evidence of cyclicity? If so ,

are these cycles allocyclic or autocyclic in nature?

6) Finally, recent literature suffers from lack of data

pe rtaining to the depositional framework of east

Tennessee during Maryville time , particularly within its

southern transitional phase of sedimentation . Therefore ,

this study will have as its pr imary goal the recognition

of lateral facies re lationships and basin morphology .

Lo cation

In this study attention will be focused on those

Maryville outcrops and drill core which are located within the vicinity of Powe ll and Oak Ridge , Tennessee . This study area lies within the ce ntral phase of sedimentation as described by Rodgers (1 953) . All sections lie within the Copper Creek and Hu nter Valley thrust sheets (Fig.

1.3). The following is a list of these localities (see

Appendix A for a more detailed description ): TENNESSEE c 7 N

,..... 0 .- KM

EXPLANATION

\} MEASURED SECTION

Q MEASURED DRILL CORE

MIDDLE a UPPER m CAMBRIAN

Figure 1.3. Location map of the study area within the Copper Creek and Hu nter Valley Allocthons in east Tennessee . 11

1) Section along Clinton Highway U.S. Highway 25W located within the Copper Creek thrust sheet approximately 15 kilometers north-northwest of

Knoxville , Tennessee, Powell 7 1/2' Quadrangle.

2) Subsurface drill core (ORNL Joy 2) located within the Copper Creek thrust sheet ju st east of the Roane

County line ; approximate ly 15 kilometers southeast of the city of Oak Ridge , Tennessee and approximately 20 kilometers southwest of Loc ality 1. Bethel Valley 7

1/2' Quadrangle . Boxed core is currently housed at the

Oak Ri dge National Laboratory.

3) Subsurface drill core (ORNL GW 129) within the

Hunter Valley thrust sheet located at the east end of the Y-12 Plant , Scarboro Road area and approximate ly 9 kilometers northwest of Locality 2. Lovell 7 1/2'

Quadrangle . Boxed core is currently housed at the Oak

Ridge Ridge National Laboratory. 12

CHAPTER 2

PETROLOGY AND DEPOSITIONAL

ENVIRONMENTS OF THE MARYVILLE LIMESTONE

Introduction

The interbedded package of limestone, shale, and siltstone that comprises the Maryville Limestone wa s deposited within a carbonate ramp-to-intrashelf basin transition (Markello and Read , 1981, 1982; Simmo ns , 1983 ).

Carbonate ramps are gently sloping platforms that show no marked change in slope (Ahr, 1973; Wilson, 1975 ). In contrast, carbonate shelves typically contain a flat platform and a we ll-defined shelf slope break . This difference in physiography produces depositional facies patterns which are inherently unique to either carbonate ramps or shelves . In a ge neral sense , carbonate ramp facies patterns tend be distributed in bands which are roughly parallel to the strandline, reflecting greater wave and current activity in an upramp direction (Ahr , 1973) .

The relatively uniform and gently sloping sea-floor topography of carbonate ramps favors the predominance and widespread distribution of depositional facies with monotonous, wedge-shaped geometries wh ich thicken seaward .

Excluding shelf marginal environments such as reefs or 13 skeletal banks wh ich occur as shore parallel accumulations , carbonate shelf facies patterns are typically more complex . Shelf facies patterns often appear mosaic-like in areal distribution, with rapid changes in sediment type laterally (Laporte , 1967).

Based on slope angle, Read (1 980; 1985) divided carbonate ramps into two basic types; homoclinal and distally steepened. The latter is characterized by a marked increase in slope at the seaward edge of the deep ramp and may contain slumps , slope-derived breccias , sediment gravity-flow deposits , and turbidites. Ramps quite often develop initially on passive margins , and with time may evolve into rimmed shelves as a result of increased carbonate production on the developing shelf-edge and/or downwarping of the basin (o pe n ocean side) . The early stages of developme nt of the Middle Ordovician basin

(Whitesburg time ) documents such an example (Shanmugam and

Walker , 1980) . In some cases , such as that of the

Maryville , a gently sloping carbonate ramp may separate an intrashelf basin from shelf and shelf-edge (r im ) environments . In such instances , it is generally thought that carbonate ramps develop as a result of a relative sea-level rise which allows for rapid upbuilding of the carbonate rim, wh ile the floor of the shelf interior lags behind .

Homoclinal ramps commonly display slope angles of < 1 14 degree . As a result, slight sea-level and subsidence fluctuations may result in pronounced vertical and lateral facies changes .

Intrashelf basins in the are commonly bordered toward the craton by nearshore siliciclastics which may be locall y introduced into the basin via po int sources (delta systems ) or line sources (beaches ), only to be redistributed by marine currents (e.g. , Markello and

Read , 1981; Aitken , 1966). Although subordinant , it is po ssible that a portion of the and sized fraction may be introduced into the basin via eolian transport .

This would seem to be a plausible explanation for transport of fine-grained sediment prior to the appearance of higher level , terrestrial vegetation or in settings devoid of vegetation such as the Persian Gulf (e.g. , Purser, 197 3) .

Intrashe1f basins are dominantly subtidal in nature , and most commonly record deposition below fairweather wave-base and above storm wave-base .

Because of the general absence of wave-resistant, carbonate secreting organisms during the Middle and Late

Cambrian (Heckel , 1974; James , 1979), and because of low bottom gradients, carbonate ramps we re highly susceptible to wave and current activity. Organic buildups , if present , we re primarily constructed of the problematic blue-green (?) calcareous algae Epiphyton and Renalcis . These buildups were not continuous , but probably occurred as isolated 15

"patch reefs". It is therefore understandable that the

details of stratification and the overall facies

organi zations of carbonate ramps during Cambrian time we re

largely controlled by episodic high-energy events .

Consequently, many of the sedimentary structures found on

carbonate ramps are strikingly similar to those observed

within, fairweather wave , storm wave , and current-dominated

shallow, siliciclastic shelves . Thus , when studying

carbonate ramps we must employ techniques and terminology

of both carbonate and siliciclastic .

Methods

The stratigraphic sections forming the basis of this

study we re measured in the conventional manner. Each

lithologic change was measured centimeter by centime ter and

logged . A total of ne arly 330 meters of section was

measured and described from the three localities under

investigation. Although the base of the section at Clinton

Highway (77.24 m) is covered, both the Joy 2 (142.48 m) and

the GW 129 (107.23) localities record complete Maryville

sequences . Samples were collected from readily discernible

limestone units wh ich appeared conspicuous because of their

gross lithologic character . Thicker units were sampled at more than one level to afford better representation. The

average sampling interval wa s slightly less than 0.5 m at 16 the Clinton Highway section , whereas samples collected at the Joy 2 drill core were much wider spaced , approximately

1.50 m apart. Samples were not collected at the the GW 129 drill core , although each lithologic change was logged .

Field descriptions with stratigraphic thicknesses and sample positions are given in Appendix A. Generalized columnar sections of the Clinton Highway , Joy 2, and GW 129 localities are shown in Figures 2.1, 2.2, and 2.3, respectively.

Thin-sections were prepared from the rocks sampled .

Approximately, 180 thin-sections were examined and described from the Clinton Highway section . Nearly all thin-sections were etched in hydrochloric acid and stained with Alizarin Red-S and potassium ferricyanide according to the methods prescribed by Friedman (1959) and Dickson

(1966), respectively . This allowed for better identification of calcite and ferroan dolomite , as well as the identification of non-carbonate components such as quartz silt and clay. Acetate peals were prepared and examined from polished slabs . Special attention was reserved for any biogenic and sedimentary structures that were not apparent in thin-section.

Thin-sections were point-counted using the methods of

Chayes (1956); approximately 350 to 450 points per slide were counted . This number was varied depending upon the size and distribution of the particles in each 17

80 NOLICHUCKYSH MARYVILLE LS

CLINTON HIGHWAY {25W) SECTION solI . �·�m • SHALE PKST./WKSt IE5I ONCOLITIC (]] OOLITIC PKSt/GRNST. 30 � LIMESTONE ARGILLACEOUS PKST./ II GRNST. S SHALE 1±1 SILTSTONE 20

en a: � LLJ 10 ::E 0

BASE COVERED 0

Figure 2.1. Generalized stratigraphic section of the Maryville Limestone at Clinton Highway . 18

NOLICHUCKY SH. 140! MARYVILLE LS ! I SAMPLE � POSITIONS i 120. I JOY 2 DRILL CORE I STRUCTURALLY COMPLEX

. •

SHALE ONC./OOILITIC PKST./GRNST. ONC/OOLITIC PKST./GRNST.

OOLITIC PKST./GRNST.

LIMESTONE ARGILLACEOUS PKST/ GRNST. S SHALE

ffi .... w � 0 N

MARYVILLE lS. ROGERSVILLESH.

Figure 2.2. Generalized stratigraphic section of the Maryville Limestone at Joy 2. 19

- NOLICHUCKY SH. MARYVILLE LS. 100

80 IGW 129 DRILL COREl

60

SHALE

40 OOLITI C PKST./GRNST.

LIMESTONE

ARGILLACEOUS PKST./ GRNST. 6 SH. 20

MARYVILLE LS. ROGERSVILLE SH.

Figure 2.3. Generalized stratigraphic section of the Maryville Limestone at GW 129. 20 thin-section. Petrographic constituent analyses are tabulated in Appendix B.

The classification scheme used in this study is a combination of those described by Folk (1959,

19 62) and Dunham (1962). Because many of the lithologies of the Maryville are of mixed siliciclastic and carbonate composition, conventional terms such as argillaceous or silty were added to the classifications , accordingly. The standard stratigraphic and grain size nomenclature is outlined in Appendix A.

Thin-sections from the u.s. Highway 25 W (Clinton

Highway ) locality are housed at the Department of

Geological Science , The University of Tennessee , Knoxville .

Thin-sections of the Joy 2 drill core are housed at Oa k

Ridge National Laboratories , Environmental Science

Division , Oak Ridge , Tennessee and access to them may be arranged through communication with Dr . Steven Haase at

ORNL .

Format of the Chapter

This chapter discusses the petrology and depositional environments of the 12 lithologies which have been recognized in the stratigraphic sections under investigation (Chapter 3 discusses the abundant conglomerate units in detail ). Each lithology is 21

distinguished by a "suite" of macroscopic and microscopic

features (Table 2.1) which are the result of vario us

depositional and diagenetic processes . The fact that both

processes and responses (i.e. , facies ) form a continuum

necessarily complicates the formation of depositional

models . As a result, no "one" feature should be used to

discern a particular . Each

lithology repre sents a unique subenvironment which is part

of a more complex package of interrelated environments

comprising the Maryville carbonate ramp-to-intrashelf basin

sequence .

Lithology 1 - Shale

Description

Shale units within the Maryville range from a few

centimeters to slightly greater than a meter in thickness

(Fig . 2.4A; 2.4B) . The shale is fissile , black to green ,

and is devoid of any recognizable features suggestive of

either shallow-water deposition or "high-energy" aside from

thin , 1-2 em , interbedded quartz siltstone beds .

Calcareous , quartz siltstone interbeds are randomly

distributed throughout the shale units . Rare , ultra-thin quartz silt streaks occur throughout the shale sequences as well. Rarely , the shale is maroon , but this is restricted

to the base of the Maryville at Joy 2 and various positions Table 2.1. Distinguishing features of the 12 lithologies (i.e. , lithofacies ) recognized within the Maryville.

LmDLOCY - ID!IIIIIC

1 - Sh.olo L•hwu4 to veey thtn ..l>e44ed - llau fLto·arall>o4 okaloul delorl.t "--pelqlc bocqnNDII 4opoold.IID (baotaal); ....,....c- dopoottc- 0111 aballcv,..tar pena of ct.. ·- .t..rLta th.o -�.aa acaaoa of ator. &ct.lwltJ'i l_....I'IJ'

2 • flanar. low·anal• Lulnat:ed to very thtn•btddad, Thin, .,.rallal l•Jnattone to weak lara rLta-aratD04 aiLolaul 4abrl.t Ultrll

4 - Wavt•rlpple4 al\d UDII�m• Very thin• to thlo-be4ded; 2•) c:e Wave•rlppl&l � lluen•be4e � •lerohmaaoclt:r Abraded tr-llobbce. ecld..:Hler.. 110ft -tocl, 4opoa1tc- at b�dded, �lrta•rlch . thick 1tldlt aradattoul to tharp &:ncl planar laala&Uonaio burruva; Un&na• turtlculate bnchlopo.t. or DMI' MaD ttom veve bue� pelotdel aratutoce:l &od tODliCU upward eequancet lnta-.!Ltta doap• and aboll...,_ lhl111 ..... ·-: 1/kll)l·-- ...

� • llodular adltone/vacbltoh ¥117 thin• to thta-beddad 4•S c:11 Thb tamtutloui vert leal aad tr1lobltea. achlnad.a..-. tara HcatpetqtcallJ 4opoolta4 liM and t�terba•d•d abale thlck carbcn:.at.a lutarbW; CODt&ctl bort10o:tal burrwa• etrlolltal co.m� Chessllorta. lfiOD&I tplwt ...... S. aiMI •hale;e 4Mf-wal r lhal'p alaal delodo ....: �c�v---

6 C.lcarM\d qu4ona Vot'f thin• to thla-bo44ocl PlaneT and atcro'"-Kky eroaa bwl.tttculata bl'achlopo4a. Sto.. 4opootto, -Lta4 ..t- llllllOCM:I 2•) ca tl>lct ba4o lalaatton.; wa1ar laai.Mtlou; cU.tt&na trllobttu , �,_ 41nc:tl.llllal ....t bl41roctl.llllal vave·rtpplet; ••rtlcal etcapoe tK..nvw; fl... : 4opooltiOD bel... fait• btd•Slnz·plan. tracaa; eola ..rb aM ... the�- ..... \lue, bu1 abowa _. •roove calta •1om wva bu&i thaliGW-wtal' n.p

7 • Tbln·baddod ...!otonoa/ Yot'f thin- to thln·boddad Thin lutnattona, vert &cal and lllra ach'-4ar. Uld lla.tpolqlc dapooUica: 4aap- vacbatonal I·) .. thlct bodo hart:&ontal burrovt uUobltoo u4 •ba.llow411ttr r-.i l••eDtf'U'

I - OncoUt tc pacUt.ona• Tbla•bod4o4 Varttcal and horhontal burrav•i On.colda. achiDDCiar.a. cdlobltal. O..COlltlc a....t abooto • pertc41c and lnterbadded hardsRundat occatloDAl rtpplsd ..uuaca. b:rullt.hl.S.. apocaa rwodd.Aa b7 ....,.; ahallGW..,..tW Vltk&IIEOMI/-.dltOiDal r-.; co aurfaeea aplNlu. I.Dartlculata bl'•shtopob .adarate- lGW•-.f"'J bi!!WI Table 2.1. (continued ) .

LITRILOCY BEODING SF.D"Oa:lti'ARY nA'IVRES I'OSSD. AIID IOO!IrOSSD. DEFOSrfiOIW. DIY� AtLOCU!HS

9 • vuy thla• to-�- Vory thln• to ••u .. - �eddod; 'lanl&n>aola pecbtwn

11 • llocll- to thtck-�

Figure 2.4. Characteristics of Lithology 1 - Shale

A. Thick unit of shale . Note thin , calcareous quartz siltstone bed just above the scale . Scale is 10.0 em in height .

B. Thin unit of shale resulting from the suspension deposition of fine-grained siliciclastic sediment deposited in shallow-water positions on the ramp during the waning stages of storm activity . Associated with storm deposited limestone-clast conglomerate beds and planar to microhummocky cross-laminated calcareous quartz siltstone deposits. Lens cap is 5.5 em in A diameter .

FIGURE 2.4, p •. 25

---�- -�--- 26

throughout the GW 129 drill core . Shale sequences are

calcareous and contain various clay , quartz silt,

and fine-grained skeletal debris . Clay analysis of

the Maryville at the Joy 2 core reveals the presence of

illite + illite/vermiculite + chlorite + kaolinite ;

chlorite being more abundant and/or better crystalized in

the upper one-half of the formation (Haase , 1986). Clay mineral analysis was not conducted on samples from the

Clinton Highway or GW 12 9 localities .

Paleoenvironmental Interpretation

Although some of the shale may represent suspension

fallout associated with storm activity, much of the shale has been deposited under quiet-water conditions . Shale sequences deposited under quiet-water conditions are here referred to as hemipelagic background and form relative ly thick accumulations typically on the order of

1- 2 m. Shale sequences associated with the waning-stages of storm deposition typically do not exceed more than a 0.1 m in thickness , but more commonly are less than few em thick . These "muddy tails" of storm deposition occur interbedded with shallower-water lithologies and are considered to have been transported from basinal positions onto the carbonate-dominated ramp . Most of the shale in the study area is restricted to the most western and southwestern localities , the Joy 2 and GW 129 drill cores . 27

These shale sequences were deposited within a broad ,

intrashelf basin similar to that described by Aitken

(1966), and is the same intrashelf basin described by

Markello and Read (1981, 1982) in southwestern Virginia.

Shale facies are interpreted to have been dominantly

deposited below storm wave-base . Estimates of water depth

within the intrashe lf basin are difficult to quantify .

Based on palinspastic reconstruction, inferred water depths

of interfingering lithologies, and the low slope of the

ramp (<1.0 degree ), water depths within the basin in the

vicinity of Joy 2 and GW 129 are estimated to have been

between 35 and 45 me ters . This contrasts slightly with the

presumed water depth of coeval deposits within the basin in

southwestern Virginia which , according to Markello and Read

(1981 , 1982), were on the order of 20-30 meters .

Most of the quartz silt and clay particles comprising

the shale sequences were likely introduced into the basin

via rivers situated on the western margin of the intrashelf

basin and later redistributed by waves and currents .

Although the intrashe lf basin was sheltered from "oceanic

waves" by a wide carbonate shelf to the east, several lines / of evidence suggests that the intrashelf basin was periodically subjected to a moderate degree of

wave-activity.

The first line of evidence is the widespread

occurrence of quartz silt across the basin, which , based on 28 work in Virginia (Markello and Read , 1981, 1982), may have been as wide as 300-400 kilometers . Curray (1965) noted that in few places does shelf-floor mud (silt) introduced via deltas extend further than 30 to 40 km outward from the shoreline . Assuming a basin width of > 100 km (see Markello and Read , 1981) , how could such fine-grained sediment be distributed over such a wide area? On rare occasions , as during storm swells , silt within the basin could have been resuspended and redistributed by currents associated with surface and internal tides and winds . As a result, sediment was spread over a wide area by a continual process of resuspension and redeposition . This dynamic mechanism is a common occurrence in storm-dominated shelves (Drake , 1976). In addition , silt may be resuspended in situ during heavy storms to produce a di lute , non-erosive , low density turbid layer which moves under the influence of coastal currents and gravity

(Stanley , 1969; McCave , 1972; and Drake , 1976). Because of the gentle slopes within the Cambrian basin and the thickness and density of turbid layers , it is likely that such layers would have deposited their sediment load rapidly as soon as they reached the basin floor .

Another indication of episodic storm activity is the repeated occurrence of thin interbeds of Lithologies 2 and

3 which contain hemipelagically deposited carbonate interlayers . Thin interbeds of well-rounded , reworked , 29 limestone clasts and medium- to thick-bedded intervals of allocthonously deposited oolitic packstone add further support to the hypothesis that periodic storms played a major role in redistributing sediment within the intrashelf basin.

Based on paleogeographic position and associated lithologies it is concluded that the thick shale units within the Maryville intrashelf basin accumulated in waters dominantly below mean storm wave-base , approximately 35-45 me ters in depth . Although storm wave base can extend easily to greater depths , the limited fetch of the basin prohibited storm wave-base from being any deeper .

Lithology 2 Planar and Low-Angle Cross-laminated ,

Carbonate-Streaked Mudstone

Description

Aside from the shale of Lithology 1, Lithology 2 contains the lowest carbonate content . Lithology 2 is characterized by planar and low-angle (5-10 degrees) cross-laminated , silty, peloidal packstone and shale .

Carbonate layers occur as ultra-thin (<0.5 em ) "carbonate streaks'' (Fig . 2.5A) that are quite often laterally discontinuous , and are subject to minor pinching and swelling, imparting an undulatory appearance . Individual layers commonly exhibit sharp bases and irregular, diffuse 30

Figure 2.5. Field photographs of Lithologies 2 and 3.

A. Planar- and low-angle cross-laminated , carbonate streaked mudstone of Lithology 2. Thin carbonate interlayers, in effect , represent the ultradistal products of carbonate sediment swept off the shallower parts of the ramp and deposited in deeper-water areas on the ramp .

B. Very thin-bedded pe loidal packstone and shale of Lithology 3. Note the planar- and low-angle cross laminations within the carbonate interlayers, the discontinuous nature of many of carbonate interlayers , and the loading features . Small convolution occurs in the lower right hand corner of the picture . Penny is 2.0 em in diameter.

FIGURE .2.·-'·:i .p .•. 31

KOZAR, MICHAEL GLENN

------·· ---- 32

tops , forming ultra-thin fining-upward sequences. In some

cases , isolated skeletal layers are observed as thin

"laminae" . Typically , carbonate layers display load-cast

lower surfaces and micro-convolutions . Sedimentary

structures suggesting tractional transport are absent from

this lithology .

Paleoenvironmental Interpretation

This low-energy lithology occurs most commonly at Joy

2 and GW 129. Apart from its intimate association with the

shale of Lithology 1, this lithology is commonly

intercalated with Lithology 3. These beds are interpreted

to have been deposited from suspension fallout forming planar-laminations . During settling wave oscillation

(perhaps associated with storms of exceptional magnitude ) or currents reworked the sediment , mo lding the planar

laminations into very weak , low-angle , cross-laminations .

These thin "carbonate streaks" owe their origin to storm deposition , and to a lesser degree , the effects of waves related to the same storm . Thus , they represent the ultradistal products of storm and fairweather processes which swept carbonate sediment off the ramp and into the basin. Similar low-energy type deposits have been recognized by Reineck and Singh (1972) and DeRaaf et al . 33

(1977) from both recent and ancient , wave- and

storm-dominated, siliciclastic shelves .

Lithology 3 Very Thin-bedded, Quartz-rich, Peloidal

Packstone/Grainstone and Shale

Description

Very thin-bedded , quartz-rich (silt) , peloidal packstone/grainstone (micrograinstone , see Wilson, 1969 , particle size <1/16 mm) and shale beds are relatively uniform in thickness and do not pinch-out laterally , although , silty carbonate "layers" may pinch and swell

(Fig. 2.5B) . Carbonate layers within Lithology 3 range in thickness from 1-3 em . Sedimentary structures within this lithology are quite varied . Although some of these structures may be observed on outcrop , a majority are microscopic in scale , and as a result are only observable on polished slab and/or in thin-section. Individual structures include various types of laminations , soft-sediment deformation features, and burrows . Each internal carbonate layer within Lithology 3 is composed of internal laminations which are primarily attributable to variations in : 1) composition (e.g. , pe loidal/quartz silt ratios ) and 2) grain size . Micrograinstone layers are composed of 10 to 20 percent quartz silt , while the remainder is largely composed of peloids . Abraded 34

trilobites , echinoderms , and inarticulate brachiopods , as

well as glauconite particles, account for < 5.0 percent .

Three basic types of laminations are common to

Lithology 3. These include : parallel (Fig. 2.6A) ; irregular

(Fig. 2.6B) ; and low-angle cross-, whose angles

are commonly less than 5-10 degrees (Figs . 2.6C) . Rare ,

fading-ripple laminations (i.e. , fade vertically ) also

occur (Fig. 2.60) . Individual carbonate layers are

commonly discontinuous imparting a lenticular appearance .

Fining-upward sequences are quite common and are

characterized by sharp bases and gradational tops (Fig.

2.7A) . Micrograded sequences may contain a basal layer of

either quartz silt or very fine-grained skeletal debris

(Fig. 2.7B). Fining-upward sequences are subtle and exhibit whole size distribution shifts from 0.06 mm (4.05 phi ) at

the base to 0.01 (6.0 phi ) at the top of a sequence . In

rare cases , graded laminations are observed which are dominantly composed of quartz silt. Coarsening-upward

sequences are equally as rare . Micrograinstone layers with

sharp bases and tops are also observed (Fig 2.7C) . These

layers commonly contain individual laminae that are defined by opaque grains (Fig . 2.70) .

Soft-sediment deformation features are common and

include : micro-convolutions , loading , pseuodonodules, and micro-rotational load structures (Fig . 2.8A) . Possible micro-scale dish structures and micro-flame structures also 35

Figure 2.6. Types of laminations found within Lithology 3. Arrows indicate stratigraphic up .

A. Parallel-laminations . Note the horizontal burrow in the upper right hand corner . Bar scale is 1.0 em in length .

B. Irregular-laminations . Bar scale is 2.0 em in length .

c. Low-angle cross-laminations . Bar scale is 0.5 em in length .

D. Type c fading-ripple laminations of Jopling and Walker (1968). Ripple amplitudes decrease gradually upward and finally pass into horizontal laminations . Ripple morphology is asymmetrical and is representative of current transport . overall sequence indicates deceleration of the current during deposition . Also note loading features in the lower third of picture . Bar scale is 0.5 em in length .

. ,. --; -.. ..; . _. -

·, . 37

Figure 2.7. Features indicative of probable suspension settling and current-related sedimentation . Arrows indicate stratigraphic up.

A. Beds with sharp bases and diffuse tops . Suspension deposition . Also note loading features. Bar scale is 1.0 em in length . Note microhummocky top .

B. Beds with sharp bases and sharp tops . Current deposition. Note possible dewatering features in the upper third of the picture . Bar scale is 1.0 em in length.

c. Discontinuous lenticular laminations noted by the arrow . Current deposition . Bar scale is 1.0 em in length .

D. Concentrations of heavy minerals defining discrete laminae . Arrows denote heavy mineral laminae . Close up of Fig. 2.7A. Bar scale is 0.5 mm in length .

FIGURE �.7., p. 38

KOZAR, MICHAEL GLENN

'-----�---- ·------� --

39

Figure 2.8. Soft-sediment deformation features and burrow types found within Lithology 3. Arrows indicate stratigraphic up .

A. Micro-convolutions (M) , loading (L) , psudonodules (P) , and rotational load structures (R) caused by differential . Bar scale is 0.5 em in length .

B. Vertical (V) and inclined (I) burrows . Bar scale is 0.4 em in length .

c. Horizontal burrows . Bar scale is 1.0 em in length .

D. Burrow mottling . Bar scale is 1.0 em in length .

FIGURE: Z,.-8·.� , ·'P· 40 ' ..

KOZAR, MICHAEL GLENN 41 have been observed . In many cases , burrows disrupt or obscure internal laminae . Bioturbation structures inc lude vertical escape(?) burrows and inclined burrows (Fig.

2.8B) , as well as horizontal burrows (Fig. 2.8C) and burrow mottles (Fig . 2.80) .

Paleoenvironmental Interpretation

Based on the various types of sedimentary structures found in Lithology 3, no single mechanism can fully explain its origin. As a result, a multiple theory of origin is proposed ranging from suspension settling to deposition and/or reworking by bottom currents . Although its inf luence was minor in extent , wave-influenced oscillatory flow played a role in modifying the sediment . Many of the structures superficially resemble the ultradistal to distal turbidites described by Shanmugam (1978) for the Middle

Ordovician Sevier Shale basin in east Tennessee . However , lack of lateral continuity , alternations between quartz silt and peloidal carbonate within a single "layer" , and the absence of tractional transport features which are oriented in a downramp direction all preclude a turbiditic origin for these mixed carbonate and siliciclastic beds .

The sharp bases and gradational (diffuse ) tops of the fining-upward sequences suggest simple suspension settling of particles or an upward decrease in flow conditions .

This interpretation is supported by the size of the grains 42 within these layers . Bagnold (1966 ) and McCave (1971 ) have shown that grains (i.e. , quartz silt) finer than 170-200um

(approximately 0.10-0.20 mm) tend to go directly into suspension . Because the grains observed here are finer than 200um, most of the fine-grained material was probably transported in suspension and subsequently deposited.

Intervening clay layers , as we ll as thin (< 2.0 em ) lime mudstone interlayers, were most likely formed from hemipelagic settling . In cases where basal quartz silt or skeletal layers grade into peloidal-rich layers , layering could have been produced by resuspension and settling of particles with varying sizes and densities . The sharp bases of the fining-upward sequences resulted from minor scouring during storms , though because of water depth , sharp bases probably more often resulted from the rapid onset of deposition of storm suspended sediment . Burrows within these layers suggest an appreciable time lag which allowed for burrowing organisms to repopulate the sediment after storm-settling .

Alternating carbonate- and clay-rich layers show evidence of soft-sediment deformation . Soft-sediment deformation structures most commonly include load structures and pseudonodules and are similar to those described by Skipper and Middleton (1977) . Evidence for penecontemporaneous deformation is furnished by sub- and superjacent layers which show no indication of 43 soft-sediment deformation . Micro-convolutions , rare flame structures , and micro-rotational load structures (e.g. ,

Dzulynski and Kotlarczyk, 1962) occur as well . Similar structures are found in environments where episodic sedimentation results in the "instantaneous" deposition of coarser layers over a hydroplastic mud layer leading to unequal loading (Reineck and Singh , 1980) .

An alternative scenario for the deposition of graded laminae is that of bottom currents . Such currents , whether storm or tidally influenced , are capable of producing grading under waning-energy conditions (Davies , 1972).

Peloidal layers with sharp bases and tops indicate deposition and/or reworking by combined flows (i.e. , unidirectional currents interacting with oscillatory flow produced by overhead passing storm waves ). cannibalistic by bottom currents of carbonate layers deposited by a process of suspension fallout may also yield a sharp upper contact , thus imparting an amalgamated appearance to the bedding sequence . Amalgamations are commonly minor in vertical extent , suggesting that currents were either weak or relatively short-lived . Thicker peloidal layers typically show a succession of sedimentary structures which include we ll-developed planar-laminations at the base , followed by sinusoidal or low-angle cross-laminations .

Deviations may include fading-ripple lamination (fade ve rtically ) such as the Type c ripple-drift laminations 44 described by Jopling and Walker (1968). Collectively, this sequence of sedimentary structures suggests deposition under decelerating energy conditions (Banderjee , 1977).

Soft-sediment features are equally as abundant in the current-related layers .

Evidence to substantiate the presence of bottom currents includes : 1) concentrations of autochthonous skeletal debris as a basal lag or opaque minerals as individual laminae , indicating winnowing ; 2) a variable sequence of grain sizes and sedimentary structures , indicating a temporal variability in current flow ; 3) vertical burrowing , indirectly emphasizing a relative slow rate of deposition or reworking after storm flow; and 4) lenticular and discontinuous laminations . The randomness and thickness of these sedimentary features indicate deposition/reworking by lower flow-regime currents that were sporadic , local, and of a relatively short duration .

Collectively, these features suggest deposition within the intrashelf basin and deeper margins of the ramp where

"exceptional" storm waves were barely able to touch bottom and where currents were the dominant depositing and/or reworking mechanism . These deposits accumulated below mean storm wave-base in a low-energy environment in which the supply of allochthonous carbonate sediment was barely 45

sufficient to form recognizable wave- and current-generated

structures.

Lithology 4 - Wave-rippled and Linsen-bedded , Quartz-rich,

Peloidal Grainstone and Interbedded Shale

Descript ion

With increasing carbonate content , the thickness ,

lateral continuity , and mu ltiplicity of sedimentary

structures increases within a single carbonate layer .

Lithology 4 is characterized by intercalated quartz-rich ,

peloidal grainstone and shale , and is differentiated from

Lithology 3 by its increased carbonate content resulting in

thicker limestone interlayers (up to 6.0 em ). Peloidal

grainstone layers occur as either connected wave-rippled

lenses , (linsen beds of DeRaaf et al., 1977 , Fig. 2.9A) or

beds displaying wave-ripp le laminations (Fig . 2.9B) .

Flat-lenses have wavelengths ranging from 8-10 em and

amplitudes from 2-3 em . The internal ripp les are commonly

unidirectional, although variations may be observed along a

single , interconnected train of lenses . Lenses are more or

less symmetric in outline . In some cases , peloidal

grainstone layers occur as isolated lenses within the shale

(Fig . 2.9C) , and show internal laminae which exhibit a -like upbui lding . Microhummocky cross-laminated

intervals , which show both vertical upbuilding and lateral 46

Figure 2.9. Wave-generated structures found within Lithology 4. Note irregular and undulatory lower bounding surfaces , bundle-wise upbuilding of internal cross-laminae , and swollen and lenticular cross-sets .

A. Linsen beds of DeRaff et al . (1977), connected flat lenses .

B. Wave-ripple laminations . Note scour and fill structure indicated by the arrow.

c. Microhummocky cross-stratification showing both vertical upbuilding and migration .

D. Isolated lenses within a shale-rich unit .

FIGURE 2.9., p. 47

��AR,' "MICHAEL GLENN 48

migration, are also present (Fig. 2.9D) . Parallel and

low-angle cross-laminations commonly accompany these

structures .

Lithology 4 is composed predominantly of peloids with

lesser quartz silt and ske letal debris . Vertical (escape? )

burrows are also common (see Fig . 2.9C) .

Paleoenvironmental Interpretation

These observations suggest that this lithology was

deposited under conditions of moderate wave activity .

Isolated lenses represent periods when either the supply of

sediment was barely adequate to form diminutive linsen deposits , or limited wave activity precluded the molding of

sediment into a complete train of lenses. Conversely , if wave activity persisted long enough and there was an

adequate supply of carbonate sediment , peloidal grainstone

layers could be reworked into a train of flat lenses containing well-developed wave-ripple laminations . Thicker bedded , carbonate layers which exhibit wave-ripple structures (see M-2, 7-8 of DeRaaf et al ., 1977) point to the increased influence of wave activity .

Sedimentary structures found within Lithology 4 are

strikingly similar to those found in both modern and ancient wave-dominated, shallow-marine siliciclastic shelves (Reineck, 1972, 1975; DeRaaf et al . , 1977, Aigner ,

1985 ). Such structures have also been described from 49 shallow subtidal and intertidal carbonate sand and mud flats from the Upper Cambrian of western Maryland (e.g. ,

Demicco , 1983). The absence of intertidal indicators, such as fenestrae , mudcracks , etc. , within the study area precludes an intertidal setting for these wave-related deposits . Microhummocky peloidal grainstone beds within the same lithology suggest deposition at or above mean storm wave-base (Dott and Bourgeois , 1982) . There is, however, current disagreement as to whether HCS forms by suspension mantling of scours or is a bed form that migrates ; and whether it forms under purely oscillatory or by combined flow (see Dott and Bourgeois , 1982; Duke , 1985; Swift et al . , 1983 ). The vertical upbuilding and lateral migration of the HCS within this lithology suggest that combined unidirectional and oscillatory flows were responsible .

The of low- and high-energy lithologies within Lithology 4 is be lieved to result from alternating storm and fairweather conditions . The main arguments for interpreting these deposits as wave-dominated are : 1) most beds display irregular and undulatory lower bounding surfaces , 2) internal laminae show bundle-wise upbuilding , and 3) most beds contain swollen and lenticular cross-laminae sets . Form discordant or combined flow wave-ripple foresets (foresets are asymetrically dipping , but are symmetrical in profile ) are directed obliquely onramp . Deposition of Lithology 4 is thought to have been 50 at or near mean storm wave-base in an intermediate position on the ramp .

Lithology 5 - Nodular Mudstone/Wackestone and Interbedded

Shale

Description

Nodular lime mudstone and wackestone is common within the Maryville , and in many cases is interbedded with various proportions of shale (Fig . 2.10A) . As a result , a continuous spectrum of intergradational rock fabrics is observed . Mudstone and wackestone layers commonly occur as

2-3 em beds (Fig . 2.10B) . Thin mudstone and wackestone lithologies may be compacted to such a degree as to form discrete "nodules". In some instances , thin laminations that reflect primary layering can be traced from nodule to nodule . Gradational upper and lower boundaries within carbonate beds are common along with various states of stylolitization (microstylolites , microstylolite swarms , and rare stylobrecciated fabrics ). Skeletal debris within wackestone beds is rare (< 5.0 %) , and consists of abraded , very fine-grained trilobite and echinoderm debris . Equally as rare are Chancelloria fragments, sponge spicules , and fragmented algal (i.e. , Girvanella) remains . Quartz silt and very small peloids define laminations . Burrowing structures are common, particularly within wackestone 51

Figure 2.10. Characteristics of Lithology 5 .

. A. Field photograph of nodular mudstone and shale . Lens cap is 5.5 em in diame ter.

B. Polished slab of nodular mudstone and shale . Note the discontinuous and nodular nature of lime stone interbeds . Also note horizontal burrows to the right of the scale .

c. Vertical burrows . Note ultrathin carbonate-streaks within the intevening shales . Bar scale 0.5 em in length .

FIGURE:�. �f(h-,. .p . 52 • ·' - • ' ' • # • • .�. '.

KO ZAR, MICHAEL GLENN

,_, ______,. ------·-- �--- 53

lithologies . These typically consist of 3-10 nun long vertical burrows (Fig . 2.10C) . Horizontal burrows are also present . Burrows possess discrete walls , and may be filled with ske letal debris and peloids .

Paleoenvironemental Interpretation

Nodular lime mudstone/wackestone and interbedded shale have been described from a number of different carbonate environments . Most authors have attributed their distinct bedding fabric to differential compaction and/or bioturbation (e.g. , Bogacz et al., 1968; Fursich , 1973;

Jenkyns , 1974; Wilson, 1975; Baud , 1976; Logan and

Semenuik, 1976; Kennedy and Garrison , 1977; Wanless , 1979 ;

Jones et al. , 1979; and Mullins et al., 1980) . In the

Maryville , differential compaction and accompanying pressure solution appear to have been the primary mechanism that produced this bedding style . Evidence for pressure solution inc ludes: microstylolitization , microstylolitic seams , and gradational upper and lower bed boundaries

(Wanless , 1979). Nodular , mudstone/wackestone and shale were probably continuous limestone and shale layers prior to postdepostional compaction. Extreme cases of pressure solution resulted in a stylobrecciated fabric (e.g. , Logan and Semeniuk , 1976 ).

Lime mudstone/wackestone and interbedded shale sequences were deposited in the more basinal positions or 54

deeper-water positions on the ramp . Lime mud and

fine-grained skeletal debris were hemipelagically deposited

from upramp positions . The alternating , uniformly bedded , mudstone/wackestone and shale layers suggest a rhythmic or episodic mode of deposition . This pattern of sedimentation

is very simi lar to several examples known in the geologic record , in which lime mud accumulations occur basinward of high-energy shelf deposits (Wilson, 1969; James, 1984).

Given that modern lime mud forms dominantly in shallow-water environments commonly less than 10 m deep

(Stockman et . al ., 1967 ) and the absence in the Cambrian of calcareous pelagic organisms (i.e. , forams and coccoliths ), downramp environments were probably too deep to "produce"

lime mud size sediment . Thus , the probable mechanisms for suspending and supplying sediment to this position on the ramp were storm or wind-driven currents . Typically, in modern-settings , storms stir up the wide , shallow mud-f loored areas of the carbonate shelf and stream across the shelf only to redeposit fine-grained lime mud in more basinward (shale-dominated) settings (James , 1984). In carbonate-dominated shelves such as the Campeche Bank

(Logan et al. , 1969 ; Ahr , 1973) lime mud accumulations commonly form aprons located downslope from the shelf margin, and in many cases are peripheral to a deeper-water shale basin. Normally , in the "distal" or "deeper-ramp " areas limestone and shale layers are more evenly 55

distributed and are not sporadically intercalated with the

carbonate layers (Wilson , 1969). This also appears to be

the case in the Maryville .

Although the nodular appearance of this lithology is

commonly accepted as a compactional effect, this

interpretation does not explain the cyclic origin of the

limestone/shale alternations . Einsele (1982) stated that

the most likely means of producing this style of bedding :

1) , and 2) variations in the siliciclastic and

carbonate sediment supply. Because diagenesis has already

been discounted as a primary means of producing such

alternations , I will focus here on mechanisms which may

cause a cyclic variation in sediment supply . These include

climatic and tectonic controls .

Climatic control (e.g. , Milankovitch effect, storms ,

etc. ) of sedimentary cycles is usually associated with

eustatic sea-level fluctuations (glaciation ). Cycles

associated with sea-level variations commonly have

periodicities of more than 10, 000 years and generally

create moderately thick , cyclic sequences (Duff et al .,

1967). Considering the small-scale of the Maryville

carbonate and shale "cyc le" (ems in scale) , changes in

eustatic sea-level are not a reasonable explanation . There

is, however, one climatic effect that could yield a

periodicity of appropriate magnitude and that is storms .

It is conceivable that large storms occurring every 102 to 56

103 years could produce the observed cyclicity. Analysis of the preserved evidence of storm frequency (number of large storms per stratigraphic section ) by Kreisa (1981 ) in the upper Ordovician Martinsburg of southwe stern Virginia yielded a minimum storm frequency of 1200 to 3100 years .

Brenchley et al. (1979) estimated a preserved storm frequency for the Ordovician of Norway of approximately 1 every 10, 000 years . During the Middle Cambrian the intrashe lf basin lay approximately 200 south of the paleoequator and was oriented in an approximate east-west direction (Scotese et al ., 1979). In such a tropical location, storm activity and occasional hurricanes would be the norm (Marsaglia and Klein, 1983). Such events could easily stir-up fine-grained sediment in the shallow-water regions of the ramp and transport the suspended load into deeper-water. Sedimentary structures suggestive of storm activity are quite common within the study area (see

Lithology 6).

Variations in sediment supply might also be tectonically induced by several mechanisms such as periodic uplift , local or regional subsidence, and variable seismicity related to regional tectonism . All of these mechanism produce variations in the sediment supply of rather long periodicity , commonly greater than 105 years

(Duff et al. , 1967). Again, the long periodicity and large scale of these cyc les are inconsistent with the observed 57

data.

Based on the magnitude of the cyclic alternations

between limestone and shale , it is postulated that storm

activity was the primary mechanism responsible for these

rhythms . However , it is remarkable that storms , which are

stochastic in nature , could have acted so uniformly in

depositing these limestone and shale deposits .

Lithology 6 - Calcareous Quartz Siltstone

Description

Lithology 6 is composed of calcareous quartz

siltstone . Siltstone beds range from 2-5 em in thickness

and commonly display sharp bases and tops . In some cases ,

lower bedding surfaces display sharp, erosional bases .

Shale partings are common between many beds as are 3-5 em

lime mudstone interbeds (Lithology 7). Siltstone beds

typically contain planar and microhummocky laminations (Fig

2.11A) . Microhummocky cross-laminations display median wavelengths of 10.0 em and amplitudes of 2.0 em . swaley

laminations , an intermediate ripple-form between parallel

and microhummocky cross-laminations (see Duke , 1980; Leckie

and Walker , 1982), occur as we ll. Commonly , planar

laminations comprise a single bed (Fig . 2.11B ) or may form the basal part of a planar laminated to microhummocky cross-laminated sequence . The underside of many of the 58

Figure 2.11 . Characteristics of Lithology 6.

A Gradation from planar to microhummocky cross-laminations .

B. Planar laminations . Scale bar is 1.0 em in length.

c. Vertical sequence of sedimentary structures which include planar-laminations , climbing-ripple laminations , laminated mudstone cap . Bar scale is 0.7 em in length .

D. Sole marks shown on the underside of planar laminated calcareous siltstone bed . Quarter for scale .

E. Groove casts shown on the underside of planar laminated calcareous siltstone bed . Quarter for scale .

F. Bedding plane traces (hypichnial burrows ). Penny for scale .

G. Vertical escape burrows . Note down-turned laminae . Scale is 2.0 em in length .

H. Close-up of Fig . 2.10B showing laminations which are defined by inarticulate brachiopods and opaque minerals . Scale bar is 0.5 em in length .

FIGUJ,tE � .11,. , . p:. 59 . .. .,,

KOZAR; MICHAEL GLENN

.. 60 planar-laminated beds show several types of scour marks including sole marks of unknown origin and groove casts

(Fig. 2.110; 2.11E) . These structures are aligned roughly parallel to depositional strike (parallel to the strike of the ramp ) in the study area . In rare cases , calcareous quartz siltstone beds show evidence of synsedimentary deformation (i.e. , micro-convolutions ).

Wave-ripple laminations are rare as are climbing wave-ripple laminations . Both of these structures are arranged in a gradual vertical succession which may build a microsequence of sedimentary structures (Fig. 2.11C) . A sequence usually commences with a planar-laminated interval, followed by a thin interval of low-angle cross-laminations , which grade upwards into wave-ripple laminations and eventually into a lime mud "cap" or clay drape . Very thin mudstone caps , which overlie climbing wave-ripple laminations , may contain an upper interval of planar-laminations . There may be modifications to this sequence , such as undulatory laminations and rare , micro-graded intervals . Size grading may not be conspicuous except where skeletal debris is present .

Although subtle , a single bed may show a progressive grain size change from base to top . Calcareous , quartz siltstone beds display a succession of sedimentary structures which is similar to the Bouma Tbce sequence , except that C-interval shows evidence of wave processes . 61

Although a single bed which displays a gradual,

vertical succession of sedimentary structures is striking ,

horizontal transitions along a single bed are equally as

interesting . Most common is the lateral mergence of

climbing wave-ripples into unidirectional form-discordant

wave-ripple cross-laminations . In some exposures ,

particularly in the case of thin beds that terminate

laterally, it can be seen that small-scale climbing

wave-ripple laminations , low-angle wave-ripple

cross-laminations , and planar-laminations pass laterally

into one another over <2.0 m of outcrop .

Calcareous , quartz siltstone beds also display an

abundance of trace . Traces (Planolites?) are

usually found on both the upper and lower surfaces of mo st beds (Fig. 2.11F) , and occur as meandering trails . Vertical

(escape? ) (Fig. 2.11G) and inclined , vertical burrows are

also abundant.

Calcareous quartz siltstone beds are dominantly

composed of angular-to-rounded grains of quartz silt

(45-89%) . Other grain types include peloids , clay minerals

and mica, feldspar silt , and rare glauconite (Fig . 2.11H) .

Silt-sized , dolomite rhombs are far less common .

Individual laminae are defined by both mica and clay minerals , as well as fragmented, phosphatic brachiopods .

Granular equant calcite is the cementing agent . 62

Paleoenvironmental Interpretation

The calcareous , quartz siltstone beds within the study

area are interpreted as shallow-water storm sheets that were deposited below fairweather wave-base , but above storm wave-base . Here , the frequency of storm layers and the number of beds displaying wave-ripple laminations are at a maximum . Very similar sequences have been recorded from ancient carbonate and siliciclastic shelves (e.g. , Goldring and Bridges , 1973; Ager , 1974; Brenchley et al. , 1979;

Nelson, 1981; Dott and Bourgeois , 1982; Einsele and

Seilacher , 1982) as well as modern shelves (Hayes , 1967;

Morton, 1981; Nelson, 1982; Aigner and Reineck , 1982;

Aigner , 1985) . The succession of sedimentary structures in these beds allows the dynamics of their formation to be reconstructed .

Calcareous , quartz siltstone beds are dominantly planar-laminated . Planar-laminations are produced in a wide range of current velocities and, if not associated with other features that give some indication of current strengths , can be difficult to interpret (Harms , 1982) .

Based on several lines of evidence, three separate processes are believed to be responsible for their formation : 1) lateral transport by unidirectional currents ,

2) settling (without traction ) by simple suspension fallout , and 3) high flow-regimes associated with oscillatory flow . 63

Deposition by unidirectional currents is evidenced by planar-laminated beds which display aligned sole marks

(sole marks have not been found on the underside of wave-rippled or microhummocky cross-laminated beds) . Sole marks align roughly parallel to depositional strike suggesting some type of flow component acting parallel to the ramp . Alongshore transport associated with storm activity is commonplace and has been documented in both modern (Swift et al ., 1983; Swift et al ., 1985) and ancient

(Aigner, 1985, Dreise et al ., 1986) settings . Escape burrows which pass undisturbed through the entire bed imply that the bed was deposited as a single event . The occurrence of Planolites-like burrows on the top of the bedding surfaces record the return to fairweather deposition . Collectively , burrows observed within this lithology reflect the activities of mobile epifaunal and shallow-burrowing epifaunal detritus feeders . Howard (1971) interpreted similar beds to have resulted from episodic deposition due to storms .

Some beds show no evidence of either unidirectional flow or epi sodic deposition . The origin of these beds is more problematic , but may have been attributed to suspension settling . This is based on the presence of : 1) crude grading , 2) rare , skeletal lags , and 3) associated microhummocky cross-laminated lithologies .

Gradation from planar to microhummocky 64

cross-laminations , without evidence of a progressive growth

of hummocks as bedforms , suggests suspension fallout and

molding into stationary hummocks by wave oscillations (Dott

and Bourgeois , 1982). Progressive upbuilding and lateral

migration of laminae , such as described by Hamblin and

Walker (1979), are not recogni zed within this lithology ,

but have been observed in other lithologies (e.g. ,

Lithology 4) within the Maryville . Although there is some

disagreement as to the mode of deposition of HCS (e.g. ,

Duke , 1985; Swift et al . , 1983), the occurrence of HCS is

thought to be most prevalent between fairweather and storm

wave-base (Dott and Bourgeois , 1982; Duke , 1985; Swift et

al. , 1983 ; Walker , 1983). Parallel and low-angle

cross-laminations and microhummocky cross-laminations grade

laterally into each other , possibly suggesting that their

association reflects changing hydrodynamic conditions

during a single event . Alternatively , this systematic

change in bedforms may be a function of the thickness of

the sediment sheet when it was deposited . In any case , it

is apparent that sediment put into suspension during storms was deposited after a lull in energy level, only to be

reworked by the oscillatory component of overhead passing

storm waves.

Beds which show a succession of bedforms (see Fig .

2.10C) indicate deposition during waning energy flow

(Allen , 1970). These beds occur randomly interbedded with 65

planar- laminated and microhummocky cross-laminated

deposits. superficially, they show similarities to the

Bouma Tbce interval, however, very low gradients on the Maryville ramp were probably insufficient enough to provide

the necessary gravitational force required to sustain a

dilute turbidity current (see Soegaard and Eriksson, 1985,

p. 681). On such a low-angle slope a turbidity current

would become weak and diffuse , thus producing an incomplete

Bouma sequence . Thin, planar- laminated intervals, which

may be equated with Tbd units , would be the norm . Additionally, lateral discontinuity of bedforms , bedding

thicknesses, and the absence of tractional features (i.e. ,

sole marks ) which align downramp argue against a turbiditic

origin for these siltstone beds . The vertical relationship

of these bedforms is probably the result of wave-generated

currents related to the same storm that provided the quartz

silt, perhaps after most of the coarser fraction had

settled from suspension ; or such a sequence may be due to

later reworking by storms of a lower magnitude . Very thin

(<2.0 em ) , laminated mudstone "caps" resulted from

suspension settling at current velocities below those

required to entrain sediment . It is possible that these

intervals were deposited by geostrophic flows running

roughly parallel to ramp strike .

The relationship between flow power and a succession of bedforms is not always so straight-forward , because in 66

some cases beds show a lateral change in bedforms . This is

particularly true in beds which thicken and thin laterally .

This lateral change in bedforms may be related either to

very rapid decline in depositional rate at the distal

margins of a sand sheet or to irregularities in sea-f loor

topography .

Reineck and Singh (1979) noted that offshore

storm-generated , planar- laminated sequences may pass into

shallower, wave-agitated sediments . Such transitions can

be found in Lithology 6, in which planar , microhummocky and

wave-ripple laminated beds pass up-section one into the

other . The presence of both wave-formed features and

features caused by storm currents suggests a complex

interaction of oscillatory and unidirectional flows .

Combined flows would be the typical response of ancient

epicontinental seas to storms (Swift et al . , 1985). The

relative absence of thick , highly amalgamated storm layers may suggest that water depths were great enough that the

effects of storms were dampened (compared to a shoreface

area where storm sequences tend to be several decimeters

thick), or that storms were of short duration. The

increased frequency of storm layers , percentage of wave-rippled laminations , and stratigraphic position

suggests that water depths in this transitional zone on the

ramp were approximately 15-25 m. Depths were probably greater than those associated with amalgamated sequences 67

found in more "proximal" storm deposits described in the

literature . Ama lgamated sequences may , however, form during intense storms of long duration . This paleobathymetric interpretation is based primarily on modern analogues (e.g. , North Sea , Aigner, 1985) .

Lithology 7 - Thin-bedded Mudstone/Wackestone

Description

Mudstone/wackestone beds range in thickness from 1-5 em . In more basinward settings , this lithology is commonly less than 2 em thick and occurs interbedded with Lithology

3 (Fig . 2.12A) . Upramp , this lithology is thicker bedded , typically between 2-5 em thick, and is intimately associated with the planar and microhummocky cross-laminated, calcareous quartz siltstone beds of

Lithology 6 (Fig . 2.12C) . Occasionally, this lithology occurs interbedded with lensoid bodies of limestone-clast conglomerate that resemble channels . Apart from extensive bioturbation (Fig . 2.11B) and rare skeletal lags , Lithology

7 is featureless . Bounding upper and lower surfaces are sharp to undulatory, commonly mimicking the topography of the underlying bed .

Paleoenvironmental Interpretation

Thin-bedded mudstone/wackestone beds represent 68

Figure 2.12. Characteristics of Lithology 7.

A. Thin-bedded distal lime mudstone (indicated by the arrow ) interlayered with Lithology 2. Bar scale is 0.8 em in length.

B. Vertical burrow within thin-bedded shallow-water mudstone . Commonly interbedded with calcareous quartz siltstone . Scale bar is 2.5 em in length .

c. Field photograph of thin-bedded shallow-water lime mudstone interbedded with thin shale and planar to microhummocky cross-laminated , calcareous quartz siltstone .

FIG� .. 2 • .12. , p. 69

. \ .� - '- ··KOZAR, ·M[CHAEL GLENN 70

suspended lime mud which settled during the waning stages

of storm deposition. Very thin-bedded mudstone/wackestone

beds associated with deeper-water lithologies represent the

very "fine-tails" of storm deposition , and hence , are the distal products of "mud-tempestites" which have bypassed

the more proximal portions of the ramp . Thicker-bedded mudstone/wackestone strata were deposited in a shal lower position, as evidenced by their association with storm- and wave-generated sequences of Lithology 6, and are analogous

to the burrowed mudstones interval of the idealized HCS

sequence described by Dott and Bourgeois (1982) .

Nearly instantaneous , post-storm deposition is

supported by the fact that burrowing always starts at the

tops of the beds (see Aigner , 1985, p. 82; Wetzel and

Aigner, 1986). The absence of interpenetrative infaunal

tiers precludes continuous sedimentation . Rare skeletal

lags also suggests episodic sedimentation (Kreisa, 1981).

Compared to the interbedded calcareous , quartz siltstone of

Lithology 6, these beds represent longer intervals of deposition .

Lithology 8 Oncolitic Packstone and Interbedded

Wackestone/Mudstone

Description

Lithology 8 is the most distinctive unit within the 71

Maryville owing to its massive appearance as well as the

abundance of dolornitized oncoids . In outcrop , this

lithology is composed of medium-bedded oncolitic packstone with thin, 4-6 ern wackestone/mudstone interlayers.

Weathered surfaces are generally medium gray , although wackestone/mudstone interlayers may be dolornitized, thereby

imparting an orange-brown weathered appearance . Dolornitized

oncoids have a similar orange-brown appearance .

The oncolitic packstone beds typically contain the most diverse assemblage of any lithology within the

Maryville . Aside from oncoids and various degrees of algal

comminution , this lithology contains variable amounts of

trilobites , inarticulate brachiopods , and echinoderm

fragments (Fig . 2.13A) . Sponge spicules , both calcitic

and siliceous varieties , are absent to common (Fig .

2.13B) . Although rare , bivalves, hyolithids ,

gastropods (?) , and the problematic fossil Chancelloria may

also be observed (Fig . 2.13C; 2.13D; 2.13E) . Matrix material typically consists of variable amounts of micrite

(0-46%) and spar (20-30%) , the latter taking the form of

fibrous/bladed and equant cements.

Ooids (0-14% ) contained within this lithology exhibit both preserved and spar-filled rnicrofabrics , and in some

instances are dolornitized . The nucleus of these ooids may be any skeletal grain, although echinoderms are by far the most common . 72

Figure 2.13. Characteristics of Lithology 8. Arrows indicate stratigraphic up .

A. Photomicrograph of echinoderm (E) and trilobite (T) debris . Scale bar is 0.3 mm in length .

B. Photomicrograph of a probable mollusc (M) forming the nucleus of an oncoid . Scale bar is 0.5 mm in length .

C. Photomicrographs of Chancelloria (C) generally noted by its calc ite walls and hollow centers , which are typically filled with micrite or void-filling cement . Scale bar is 0.5 mm in length .

D. Photomicrograph of a triaxon calcareous sponge (S) spicules. Calcareous sponge spicules are differentiated from their siliceous counterparts by the the absence of a central canal . Scale bar is 0.5 mm in length .

E. Photomicrograph of a single hyolithid (H) cone and a variety of nested hyolithid cones , each shell of which is now a mold filled by granular equant cement . Scale bar is 0.2 mm in length .

FIGURE 2.13., p. 73

KOZAR; MICHAEL GLENN

------74

The most distinctive feature of this lithology is the

abundance of calcified algae . Girvanella-formed oncoids are

relatively common grains (22-35% ) and range from .20 to 1.0 rnm in size (Fig. 2.14A) . Using the classification of Logan

et al . (1964), the oncoid morphotypes commonly found are

the I- and R-types . c-type oncoids occur as well, but are

far less abundant . In all cases , layers of intertwined

Girvanella tubules are concentrically disposed around an elliptical skeletal nucleus . Although echinoderm and

trilobite debris typically serve as nuclei, Renalcis may also serve as the nuclei upon which Girvanella tubules encrust . Aside from Girvanella-formed oncoids , this

lithology contains various other types of Girvanella-formed particles . These include isolated Girvanella-tubules ,

-peloids , and -intraclasts (Fig. 2.14B; 2.14C) .

Collectively , these algal grains comprise from 3-18% by volume of a single thin-section. Individual Girvanella tubules are typically uniform in size and may range up to several micrometers in length (i.e. , apparent length). The sharpness of the boundary between the algal peloids and the surrounding matrix is variable , however, in most cases the transition is sharp . Spheroidal algal particles exceeding

2.0 mm are here termed algal intraclasts (sensu stricto ,

Folk , 1959) . These grains are similar in composition to the algally derived peloids , except that their microstructure is commonly obscured by either micritization 75

Figure 2.14. Characteristics of Lithology 8. Arrows indicate stratigraphic up .

A. Oncoids , Mode I-, R- , and C-types. Scale bar is 1.0 em in length .

B. Algal intraclasts (Girvanella ). Scale bar is 2.0 mm in length .

c. Algal peloids (>2.0 em in length ) containing vague , filamentous forms interpreted as Girvanella tubules. Scale bar is 0.2 mm in length .

D. Strands of intertwined algal tubules (Girvanella) appeared to be spalled off from adj acent Girvanella forming oncoids . Scale bar is 0.2 mm in length .

E. Anastomosing and planar hardgrounds . Contact with underlying intraclastic unit . Scale is 0.8 em in length .

F. Renalcis, a probable blue-green alga . Note mu lticellular shape (lunules ) with thin micritic walls and clear crystalline calcite center . scale is 0.3 mm in length .

G. Renalcis intraclasts . Note clear sponge spicules within the center of the clasts . Scale bar is 0.2 mm in length .

H. Burrows within lime mudstone and wackestone interbeds . Note rippled upper surface of the mudstone/wackestone layer . Scale bar is 1.5 em in length .

·,:.;,��tfRE·2.. 1 4. ' p . 76 :.. . ·"" . .. ·KOZAR',: MICHAEL GLENN 77

(not micrite infilling ) of the algal tubules or . As a result, difficulties arise in recognizing individual tubules. Strands of intertwined

Girvanella tubules are elongate and range up to 1 mm in length . In contrast to the algally-derived peloids and intraclasts , the transition between Girvanella tubules comprising the strands and the surrounding matrix is gradational, suggesting that the Girvanella tubules were loosely intertwined .

The problematic alga Renalcis is also present . Thalli have a multicellular shape consisting of small clusters or lunules which have a clear calcite spar center and a micritic periphery (Fig . 2.14E ) . Renalcis-formed intraclasts are also observed (Fig. 2.14F) , although these are rare compared to the Girvanella-formed intrac lasts .

Such intraclasts are commonly rounded to subrounded, elongate (typically 3.0 mm in lenght ), and are neomorphosed to some degree . Renalcis has not been observed forming arborescent or "head-like" bodies within the study area .

Hardgrounds and scoured surfaces within this lithology are restricted exclusively to one unit at Clinton Highway .

Hardground surfaces are planar-to-undulatory (Fig. 2.14G) , and are distinguished by the presence of either truncated grains or ultra-thin, iron-stained or pyritized(?) crusts .

Commonly, closely spaced hardgrounds cut down through previously cemented hardgrounds resulting in an 78 anastomosing sequence . In some cases , hardground surfaces are bored (i.e. , skeletal grains are truncated ); the borings filled with peloidal sediment . Hardground surfaces are locally overlain by a thin layer of quartz silt .

Wackestone/mudstone layers are typically laminated and may be dolomitized to a variable degree . Laminations are defined by fine-grained quartz silt , and are commonly disrupted by vertical burrows (Fig . 2.13H) . Burrows range in length from 1-2 em and are attributed to deposit-feeding organisms (e.g. , Cruziana- and Zoophycus- type) .

Wackestone/mudstone interlayers are devoid of megafossils, but may contain rare , unidentifiable skeletal debris observable only in thin-section . Lithology 8 may be differentiated from Lithology 9 and 11 by its allochem abundances (Fig . 2.15) .

Paleoenvironmental Interpretation

Oncolitic packstone and interbedded wackestones/mudstone sequences were deposited as subtidal carbonate sand and mud . These deposits commonly "cap" upward-thickening progradational sequences . Scoured erosional surfaces and rotated asymmetric oncoids (I- and

R-types) mixed with concentrically coated varieties

(C-type ) suggest that sediment was deposited under quiet-water conditions that were interrupted periodically by higher-energy events . The absence of highly abraded OOIDS

eLITHOLOGY 8 •LITHOLOGY 9 .LITHOLOGY II STORM-DEPOSITED UNITS • (Shallow-water Romp)

...... \0

ONCOIDS ALGAL PELOIDS, INTRACLAST. AND ALGAL DEBRIS

Figure 2.15. Abundance of ooids , oncoids , and algal grains in Lithologies 8, 9, and 11. 80 oncoids indicates that these grains were not transported a considerable distance from an upramp position, although the presence of comminuted algal grains (e.g. , algal peloids , algal intraclasts) suggests some degree of lateral transport. Hence , these deposits probably represent the periodic influx of migrating oncolitic sand sheets into the study area.

The abundance of calcified algae suggests that the contribution of algal particles to the fine-grained fraction of the original sediment was quite significant .

The spalling-off of the peripheral parts of

Girvanella-formed oncoids is thought to be the primary mechanism by which these particles were generated .

Alternatively, mechanical fragmentation of Girvanella mats

("sheets") by high-energy events may have produced algal peloids and/or algal intraclasts . Minor calcification or micritization of intertwined algal tubules may also yield pe loids . Algal peloids may be indistinguishable from pe loids which have a fecal origin , or those resulting from the breakdown of micritic intraclasts or skeletal grains , particulary in cases where they have been neomorphosed .

For these reasons , "algal peloids" or "algal intraclasts" are only distinguishable by the recognition of internal

Girvanella tubules or Renalcis clusters . In spite of this problem , the role of calcified algae as sediment producers within this lithology should not be underestimated. 81

The role of calcified algae as important sediment producers has been suggested in many Phanerozoic

. Coniglio and James (1985) documented the breakdown of Girvanella to form peloids and intraclasts in the Middle and Upper Cambrian of Newfoundland . Other studies which have described the breakdown products of

similar types of algae include Aitken (1966), Ahr (1971),

Markello and Read (1981, 1982) and Wolf (1965) . In modern carbonate environments , calcified algae , particularly the chlorophytes Halimeda and Penicillus , are found to be a dominant sediment contributor in shallow-shelf environments . The importance of algae as sediment producers has been documented repeatedly in the Florida

Keys and the Bahamas (e.g. , Stockman et al . 1967; Neuman and Land , 1975; Wray , 1977 ; Mullins and Van Buren, 1979;

Crevelo and Schlager , 1980; Mullins et al. 1980) .

Girvanella also appears to have played a role in binding and possibly "cementing" grains in place . Af ter death, algal tubules may become calcified to produce an intertwined network of calcified filaments on which later micrite and microspar cements may precipitate (modern blue-green algae simi lar to Girvanella produce a microcrystalline calcite sheath during their lifetime ).

Promotion of the precipitation of low-magnesium meniscus

(micritic? ) cement by binding algal filaments has been described from both modern and ancient , shallow-water, 82 carbonate environments (Kobluk and Risk, 1977).

Lithology 8 is believed to have been deposited as a subtidal sand sheet in waters which were intermittently reworked by currents and/or storms . Water depths were approximately 5-10 meters or slightly deeper and were comparable to the deeper margins of oncoid-forming environments in the modern (e.g. , Logan et al. , 1964 ).

Lithology 9 - Very Thin to Thin-bedded Oolitic Grainstone

Caps

Description

Oolitic grainstone beds ranging in thickness from 3-15 em occur as 11caps11 on several conglomerate beds . These

11caps11 punctuate upward-thickening sequences and occur at both Clinton Highway and Joy 2, but are particularly common at the former. Caps do not occur at GW 129. Oolitic caps display a scoured lower surface and a sharp megarippled upper surface (Fig . 2.16A) . Caps with well developed megarippled upper surfaces can be observed at other localities within the region approximately 15 km to the northeast along strike (e.g. , Beech Grove) . In rare cases , intraclasts of the underlying conglomerate beds project into the oolitic cap. Oo litic grainstone caps consist dominantly of ooids 0.3-0 .6 mm in diameter. Other allochems inc lude : echinoderm and trilobite fragments ; 83

Figure 2.16. Characteristics of Lithology 9.

A. Field photograph of oolitic grainstone capping a thick intraclastic grainstone bed . Note megarippled upper bedding surface.

B. Photomicrograph of a hardground with marine , fibrous cement growing on it. Also note algal strands and truncated allochem at the lefthand side of the picture . Scale bar is 0.4 em in length .

.FIGURE 2. 16 ., p. 84

KOZAR; MICHAEL GLENN 85

peloids ; hyolithids ; fragmented algal grains displaying

faint , tubular (Girvanella? ) structures ; and rare oncoids

(see Fig . 2.15 for a comparison with Lithology 8 and 11).

Ooids exhibit radial and concentric micro-fabrics, and may

be partially to completely dolomitized . Commonly , oolitic

caps contain anastomosing hardgrounds or pyritized(?)

nondepositiona l surfaces , which have relief on the order of

a few mm. Although rare , hardgrounds may have fibrous

marine cement on them (Fig . 2.16B ) imparting an "oolitic"

appearance . Glauconite occurs in association with many

hardgrounds and surfaces of nondeposition.

Paleoenvironmental Interpretation

Very thin- to thin-bedded oolitic grainstone caps

punctuate small-scale upward-thickening sequences .

Collectively, the occurrence of hardgrounds , glauconite ,

and corrosional surfaces suggest periods of slow deposition

or nondeposition (Wilson,1975) . Proximality to

shallow-water oolitic sand bodies is indicated by the

abundance of ooids , and rare algal grains .

All patterns of progressive change prior to the occurrence of this lithology indicate a shallowing and the increasing influence of shallower-water carbonate sand bodies as they prograded out onto the deeper margins of the ramp . These caps are interpreted to represent the initial 86 outbuilding or progradation of the shallow-water oolitic

sand sheets .

Lithology 10 Medium- to Thick-bedded , Oolitic

(Intrashelf ) Packstone

Description

Oolitic packstone beds , 30-40 em thick, occur interbedded with the shale and interbedded shale and

limestone lithologies (Lithology 1, 2, and 3) at Joy 2.

Slightly thinner bedded (5-28 em ) oolitic packstone beds occur at the base of the GW 129 core . Basal contacts are erosional, whereas upper contacts are typically sharp and undulatory. Oolitic packstones beds consist of well-sorted , medium sand-size ooids that display a wide array of microfabrics similar to those observed in other ooid-bearing lithologies . Rare intraclasts and abundant glauconite occur as we ll.

Paleoenvironmental Interpretation

Medium- to thick-bedded oolitic packstone deposits are interpreted as subtidal sand bodies that accumulated within the intrashelf basin . These deposits differ from other oolitic lithologies in that they are underlain and overlain by argillaceous , peloidal packstone and shale lithologies .

The dominantly quiet-water stratigraphic associations 87

present quite an interpretational dilemma , because ooids

are most often viewed as indicating shallow, turbulent water settings . Oolitic packstone beds contained within the

lower part of the Joy 2 core occur more than 20 km from the presumed acid-producing environments . Basinward transport

of shoal-derived ooids across depositional strike into a

shale basin approximately 35-45 m deep is enigmatic . An

alternative scenario , however, is to generate the ooids within a muddy , shale basin. Sufficient shallowing , either by sea-level lowering or epeirogenic uplift, to allow for

ooid formation would cause a vast maj ority of the carbonate

ramp to the east to become subaerially exposed. If this was the case , formation (caliche assuming proper

climatic conditions ), karstification , and abundant

sedimentary features suggestive of peritidal sedimentation would most likely result. However, none of these features

are observed . Likewise , basinwide shallowing to depths

requisite for ooid formation would likely bring about widespread damping of both wave and tidal energy .

Localities within a short distance of Joy 2 (e.g. , Clinton

Highway ) and , likewise Joy 2 and GW 129, however, show

abundant evidence of wave- and current-induced

sedimentation .

Based on paleogeographic and stratigraphic consideration, an allochthonous origin for the ooids in

Lithology 10 is proposed . It is possible that storms were 88 capable of entraining and transporting ooids across depositional strike and into the deeper margins of the ramp and into the basin. Lareau and Purser (1973) described similar oolitic accumulations within the axial parts of the

Persian Gulf between water depths of 80 and 120 m.

Transported , deep-water (50-80 m) ooids have similarly been described from the Yucatan Shelf (Logan et al., 1969).

Ancient examples of oolitic accumulations which occupy a basinal position include the Mesozoic of Canada (Eluik,

1978), and the Cambrian intrashelf basins of Alberta

(Aitken , 1978). Markello and Read (1981, 1982) described similar deep-water oolite accumulations within coeval sediments in southwestern Virginia.

Lithology 11 - Medium- to Thick-bedded Oolitic Packstone and Grainstone

Descript ion

Oolitic packstone and grainstone beds ranging from

23-40 em in thickness occur sparingly at Clinton Highway

(Fig . 2.17A) and are rare at Joy 2. These beds are internally homogeneous or faintly parallel bedded ; rarely are they cross-bedded . Apart from the oolitic beds at Joy 2 and the oolitic caps at Clinton Highway , this lithology occurs intimately associated with the calcareous quartz siltstone deposits of Lithology 6. Oolitic packstone and 89

Figure 2.17. Characteristics of Lithology 11.

A. Field photograph of oolitic packstone/grainstone unit at the Clinton Highway section.

B. Field photograph of thick oolitic unit 2 km northeast of the Clinton Highway along the northeast side of Heiskell Rd . Jacob staff increments equal 10.0 em .

c. Different varieties of ooids within oolitic sand sheets of Lithology 6. Bar scale is 0.2 mm in length . 1) radial (R) . 2) concentric (C) . 3) dolomitized (D) .

D. Intraclasts within oolitic packstone/grainstone bed that has superficial oolitic coatings (coatings of 2 to 3 laminae . Bar scale is 0.25 em in length .

':FIG�/2.. 17 ., p. 90

KOZAR, MICHAEL GLENN 91 grainstone beds occur as extensive sheets which retain a constant thickness, and may be traced along strike in field exposures. Thicker (approximately 0.5 -1 .5 m) beds with megarippled tops show similar associations and crop out approximately 2.0 km along structural strike to the northeast (Fig. 2.17B) at the intersection of Heiskell

Road and Bull Run Creek .

Oolitic packstone and grainstone beds contain ooids

(30-60%) which are approximately 0.3-1.0 mm in diameter and display concentric and radial microfabrics (Fig . 2.17C) .

Dolomitization of ooids may be partial or complete and is commonly random within a single bed . Skeletal debris is rare , but includes : trilobites , echinoderms , sponge spicules , and Chancelloria . Algally coated grains and peloids are also present . Rounded intraclasts composed of micritic , oolitic , and pe loidal lithologies are common within this lithology . In many cases , clasts display superficial, oolitic coatings (Fig . 2.17D) . Matrix consists of admixtures of early marine fibrous/bladed cements (20-30%) , and micrite (0-24%) . Micrite usually occurs trapped between grains suggesting incomplete winnowing . Quartz silt occurs disseminated throughout .

Hardgrounds are generally absent . Figure 2.15 illustrates the difference between Lithology 11 and Lithologies 8 and 9 based on ooid , oncoid and algal debris abundances . 92

Paleoenvironmental Interpretation

The medium- to thick-bedded oolitic packstone and

grainstone beds within the study area are interpreted to

have been deposited as subtidal sand blankets or sheets . In

contrast to thicker, oolitic beds observed approximately

2.0 km to the northeast , these oolitic packstone/grainstone

sequences were deposited as relatively thin veneers . The

presence of micritic matrix within some portions of the

oolite suggests weak current activity and/or incomplete

winnowing by waves . The intimate association of this

lithology with storm-deposited calcareous quartz siltstone

beds suggests that such events may have played a key role

in the wholesale movement of these sand sheets . Ball (1967 )

and Hine (1977 ) noted that although tidal currents are

important in maintaining modern oolitic , large

hurricanes we re the primary mechanism responsible for net

sand body movement . Alongshore paleocurrents associated with storm activity may have caused migration of the

Cambrian subtidal sand sheets in a manner simi lar to that

described by Sternbach and Friedman (1984) .

Unlike the oolite bodies described by Simmons (1984)

and Markello and Read (1981, 1982) , the oolitic packstone

and grainstone deposits within the study area are typically much thinner and lack tabular and/or herringbone cross-bedding . Oolitic lithologies are not believed to

have formed barrier-type shoals (0-5 m water depth ) such as 93

those described by Harris (1979) in the Bahamas and the

"oolitic shoal" environments described by Markello and Read

and Simmons . However, rare clasts of adjacent lithologies

contained within the oolite exhibit superficial oolitic

coatings (2-3 laminae ) suggesting that agitation was

sufficient to produce such coatings .

Lithology 12 - Medium-bedded , Laminated Mudstone/Wackestone

Description

Medium-bedded , laminated mudstone/wackestone sequences

occur as 0.25-1.5 m thick units (Fig . 2.18A) . This

lithology is restricted almost exclusively to the Clinton

Highway section . Quartz silt, peloids , and unidentifiable

skeletal debris often define laminations (mm-scale ) .

Primary stratification may be obscured by burrowing .

Fossil allochems (generally < 20%) include trilobites ,

sponge spicules, echinoderms , and Chancelloria . Girvanella

occurs as intertwined tubules , and is commonly disseminated

randomly throughout the lithology . Discrete vertical and horizontal burrows are quite extensive (Fig. 2.18B) and

typically display interpenetrative tiering . Burrows may be

filled with either skeletal debris , peloids , or equant calcite cement . Pervasive stylolitization imparts a nodular appearance to this lithology . Various styles of stylolitization range from anastomosing swarms of fine clay 94

Figure 2.18. Characteristics of Lithology 12.

A. Field photograph of medium-bedded , laminated lime mudstone/wackestone showing the nodular bedding character of the lithology . Arrow indicates thin intervals containing planar and ripple laminations . Lens cap is 5.5 em in diameter .

B. Mudstone/wackestone showing faint laminae defined by quartz silt and skeletal debris (arrow) . Also note vertical burrows and anastomosing seams which impart a nodular appearance to the lithology. Scale bar is 1.0 em in length .

FIGURE 2.18., p. 95

KOZAR, MICHAEL GLENN 96 seams (microstylolites ) to stylobrecciated fabrics (see

Fig . 2.18B) .

Paleoenvironmental Interpretation

Medium-bedded , laminated mudstone/wackestone beds are interpreted as subtidal lime mud accumulations . Such deposits formed apron-like veneers which mantled the ramp and were the likely source of fine-grained carbonate for the rhythmic lime mud and shale units that occur downramp as well as the very thin carbonate layers that occur in the basin. This lithology is commonly interbedded with the oncolitic packstone and wackestone/mudstone beds of

Lithology 8. Interpenetrative tiering of burrows suggests relatively slow, continuous sedimentation (Aigner, 1985,

Wetzel and Aigner , 1986) . The abundance of well-preserved infaunal burrows with we ll-defined walls also indicates that the sediment was relatively firm (Rhoads , 1964 ; Walker and Diehl, 1986) . Interlayers containing mm-scale , planar and wave-ripple laminations reflect minor wave and/or current activity .

The nodular bedding of the lime mudstone/wackestone lithologies share so many characteristics with nodular limestones described by Wanless (1979 ) that the interpretation seems to be warranted that their bedding character is a product of pressure solution rather than extensive bioturbation (an origin of nodular bedding 97 suggested by Byers , 1982).

Laminated mudstone/wackestone deposits of Lithology 12 are interpreted as lime mud accumulations which were deposited in quiet water, dominately below normal wave base . Such accumulations were , to a variable degree , disturbed by minor wave and/or current activity . Water depths were comparable to those in which the interbedded oncolitic packstone and wackestone/mudstone beds of

Lithology 8 were deposited (approximately 10 m) , but may have been as much as 15-30 m. such deposits are common in the geologic record (Wilson , 1975), and typically form on carbonate ramps as widespread mud blankets basinward of shoal-water complexes. 98

CHAPTER 3

LIMESTONE-CLAST CONGLOMERATE BEDS

Introduction

Limestone-clast conglomerate beds are a common feature of most Cambrian sequences, and have been described from a wide array of depositional environments . Many of these conglomerate deposits are thought to have formed from the erosion and redeposition of partially lithified sediments by storm waves and currents in shallow subtidal and intertidal environments (e.g. , Sepkoski , 1982; Markello and

Read , 1981 , 1982; Demicco , 1983 ). Analysis of conglomerate beds from the Maryville Limestone suggests that in addition to storm transport , other processes such as mass-sediment-gravity movement we re also responsible for the transport of lime stone clasts . It should be noted , however, that mass-gravity deposited conglomerate beds within the Maryville differ from those described from similar age rocks in the western u.s. and Canada (e.g. ,

Cook , 1977; Hiscott and James , 1985) in that they lack obvious slumps , slump scars and/or rotational and translationa l slides . Within the Maryville , debris-flow derived conglomerates have undergone a more complex history. 99

In this chapter , attention is focused on the nature and distribution of the Maryville limestone-clast conglomerate beds with the following obj ectives in mind :

1) To characterize the textures , fabrics , and geometries

of the conglomerate beds .

2) To differentiate between storm and mass-gravity

transported conglomerate deposits .

3) To examine systematic vertical variations in bed

thickness up sections .

4) To construct a model for the transport and genesis of

the limestone-clast conglomerate beds within the

Maryville .

General Geology

During latest Middle Cambrian time the region of east

Tennessee contained parts of three major depositional settings . Briefly , these included: 1) a western intrashelf basin ; 2 ) a carbonate ramp with a westward dipping slope ; and 3) a shallow carbonate platform . This study wi ll pay particular attention to the intrashelf basin-to-carbonate ramp transition . Limestone-clast conglomerate beds are common within this transition and may comprise nearly 20% of a stratigraphic section . Most clasts were derived from nearby positions on the ramp based on the occurrence of similar lithologies within the stratigraphic sections 100 examined . Shal low-water (i.e. , peritidal-intertidal) clasts , which include stromatolitic, and fenestrae-bearing lithologies are absent from these conglomerate deposits .

Thus , all clasts originated in subtidal environments .

Although a definitive mechanism by which all clasts were entrained, transported, and subsequently deposited may be unclear in all cases; two separate end-member processes are believed to have been operable : storm transport , and local, mass-sediment-gravity movement . Previous workers have characterized sedimentary structures associated with both of these modes of transport; however , only those characteristics unique to the lime stone-clast conglomerate beds within the Maryville will be discussed here .

Problematic Shale-Matrix Conglomerate Beds

(Debris-Flows /Storms?)

Limestone-clast conglomerate beds which have a dominantly shale matrix are a more problematic variety and occur in more basinward settings within the Maryville .

Judging by the lack of any definitive evidence concerning their origin, no single mechanism can fully explain these conglomerate beds . Hence, based on limited characteristics

(Fig. 3.1) a mu ltiple theory of origin is proposed. 101

SHALE MATRIX CONGLOMERATES

FEATURES CHARACTERISTICS

ASSOCIATED LITHOLOGIES • THICK UNDER-AND OVERLYING SH.

THIN-BEDDED CM) BED THICKNESS (3.0-6.0 NATURE OF BEDDING SHARP LOWER BEDDING SURFACE CONTACT IRREGULAR UPPER BEDDING SURFACE

BED GEOMETRY • LATERALLY DISCONTINUOUS CHANNELS OR LENSES

GRADING ABSENT

SORTING (CLASTS) POOR; GRANULE-PEBBLE

CLAST ORIENTATION • RANDOM TO SUBPARALLEL

MATRIX • SHALE

CLAST SHAPE, TA BULAR, ROUNDED; RARE ROUNDED IRREGULAR VARIETIES

MECHANISM= DEBRIS FLOW/STORM

Figure 3.1. Characteristics of shale matrix conglomerate beds (* denotes characteristics most diagnostic of the problematic shale ma trix conglomerate beds ). 102

Description

In outcrop , shale matrix conglomerate beds are typically interbedded with shale . Bed thickness ranges from 3-6 em . Lateral continuity is inferred, based on small bed thickness , to be not as great as the other conglomerate types , usually on the order of centimeters to meters in scale . Similar shale matrix conglomerates observed within the Nolichucky (Kozar et al. , 1986 ) also are discontinuous .

In all the beds examined clasts are oriented random to subparallel to bedding (Fig. 3.2A) . Clasts are commonly tabular and have rounded edges . Larger clasts typically have a very irregular shape and may be of debris-flow origin . Extremely small clasts , on the other hand , may have been entrained during storms . Clasts are composed of deeper-water lithologies , name ly silty peloidal packstone/grainstone .

Debris -Flow Derived Conglomerate Beds

Description

In outcrop , debris-flow derived conglomerate beds are interstratified with shale and very thin- to thin-bedded lime stone intercalated with shale (Fig. 3.2B) . The thickness of these conglomerate beds ranges from 4-12 em , and in rare cases can be as thick as 29 em . The beds are 103

Figure 3.2. Problematic shale matrix conglomerate and debris-flow derived limestone-clast conglomerate beds .

A. Shale matrix conglomerate (Joy 2 drill core) .

B. Field photograph of debris-flow derived conglomerate . Note lateral termination and slight topographic relief (i.e. , planar base and concave top. )

C. Polished slab of debris-flow derived conglomerate . Note small clasts that have been "rafted" along the top of the flow.

tt� :a ..• 2., p. 1o4

.. . . KOZAR, MICHAEL GLENN

--�------r------105 generally laterally continuous , although minor variation in thickness may be observed along the outcrop . Individual beds have planar bases which show no ev idence of scour and may have slightly irregular to hummocky tops .

In most of the beds examined, elongate clasts are subparallel to randomly oriented to bedding . Rarely , clasts display imbricated orientations . Normal grading is conspicuously absent, whereas crude inverse grading has been observed . Poor of the clasts is obvious as clasts typically range from 1-12 em in length .

Matrices of debris-flow derived conglomerate beds are nonlaminated and are typically composed of lime mud , peloids , quartz silt , and rare skeletal debris. Clasts are matrix-supported . Point-counts show clast/matrix ratios to average approximately 2.8/1.0.

Clasts are commonly subangular and may be very irregular in outline, although tabular and disc-shaped varieties also occur . Clasts range in length from 2-10 em and often proj ec t slightly (< 2 em ) above the upper bedding surface. In rare cases , small clasts appear to have been

"rafted" along the tops of the beds (Fig. 3.2C) . This feature is accentuated by of overlying shales .

Cl asts may be bent suggesting deposition as semi-lithified

"lumps "; however , most appear to be bored(?) and covered with traces suggesting that most clasts were well-lithified prior to deposition. Lime mudstone clasts 106

commonly display dark, corroded borders .

Evidence for Mass-Gravity Transport

Obvious, large-scale sedimentary features indicative

of catastrophic mass-sediment-gravity movement such as

slumping, rafted megablocks , and rotational and

translational sliding have not been observed within the

study area . However, thin- to medium-bedded debris flows

are believed to ex ist. Sedimentary features characteristic

of Maryville limestone-clast conglomerate beds deposited as debris-flows are summarized in Figure 3.3. Mass movement by grain-flow and modified grain-f low processes are here discounted because of the relatively steep slope required

for their initiation and sustained movement (gen erally gO or greater ; Middleton and Hampton, 1965; Lash, 1984).

Two types of debris flows have been discussed in the

literature (e.g., Lowe, 1979) . These are ''true debris-flows" in which larger grains are supported by the cohes ion of a clay water-matrix slurry and "rheological debris-flows " (Coulomb-viscous model of Johnson, 1970), which include mass gravity flows that exhibit plastic behavior . Th e accurate interpretation of both of thes e

types of flows is dependent upon : 1) the recognition of textures and structures characteristic of particle support mechanisms , and 2) the discrimination of compound textures and structures produced by the interaction of several 107

LIME-MUD AND COARSE-GRAINED MATRIX CONGLOMERATES

FEATURES CHARACTERISTICS

ASSOCIATED LITHOLOGIES • SHALE, THIN-BEDDED LI ME MOST. AR GILLACEOUS PKST./GRNST.

BED THICKNESS THIN TO MEOI UM-BEDDED CM) (4.0-12.0 NATURE OF BEDDING • PLANAR LOWER BEDDING SURFACE CONTACT IRREGULAR TO HUMMOCKY UPPER BEDDING SURFACE

BED GEOMETRY SHEETS,DOMAL BEDF ORMS •

GRADING RARE TO ABSENT

SORTING (CLASTS) POOR, GRANULE-COBBLE

CLAST ORIENTATION • SUBPARALLEL TO RANDOM

MATRIX • FINE-GRAINED LIME MUD TO COARSE-GRAINED SKEL. PKST.

CLAST SHAPE, IRREGULAR, TA BULAR TO ROUNDNESS DISCOID

OTHER • RAF TED AND PROJECTING CLASTS

• MONO- OR POLYMICTIC CLAST ASSOCIATIONS

MECHANISM= DEBRIS FLOW

Figure 3.3. Characteristics of debris-flow derived conglomerate beds (* denotes characteristics most diagnostic in determining conglomerate beds of debris-flow origin) . 108

support mechanisms which may have acted simultaneously or

periodically within a flow. Thus , any evidence for debris-flow origin is based on the final flow character of

the deposit (i.e. , when the flow "freezes11) .

The presence of a supportive fine-grained matrix

(Enos , 1977), along with little consistent preferred clast

fabric (Nardin et al. , 1977 ), is suggestive of debris flow transport . As mentioned earlier, fine -grained matrix and random to subparallel clast fabrics are common within those

Maryville conglomerates wh ich are interpreted to be of debris-flow origin . The relatively high proportion of matrix implies that most of the flow strength (i.e buoyant strength ) came from the cohesive strength of the matrix and not from frictional strength caused by clast-to-clast interactions . An unsupported clast framework , the lack of normal grading , and the absence of cement-filled shelter voids and/or perched-sediment rules out suspension settling of clasts .

Clasts which "lie" on the top of the beds imply that they were not jumbled about , but were actually "rafted" along by the flow. Hampton (1972) noted that such evidence is indicative of rigid, plug flow. Hummocky or concave upper bedding surfaces suggest that the debris-flows had minor topographic relief above the sea-floor . However, beds do not display appreciable topographic relief (i.e., "doma l tops11 ) such as observed in debris-flows found within the 109

Nolichucky Shale (Kozar et al. , 1986) . The absence of

basal scour implies that the flows lacked turbulence as

they moved downslope .

On rare occasion , clasts display an inclined fabric .

Such a fabric resulted from frictional shear at the base of

the flow. Although clasts in the study area are observed

dipping downflow, imbrication which occurs as a consequence

of basal shear can result in clasts which dip up- or down­

flow (Lindsay , 1966; Gorler and Reutter , 1968; Harms , 1974;

Hubert et al. , 197 7).

Any model concerned with the of sediment

gravity-flows should take into consideration all aspects of the flow, from entrainment of the clasts to their ultimate deposition . All too often consideration of the actual mechanism which lifts the particles (in this case , the

limestone clasts ) is not formally discussed . Matrix

strength alone cannot be responsible for li fting the grains

(Lowe , 1979 ). Actual lifting of the clasts can be

accomplished by three basic mechanisms : 1) flow turbulence;

2) dispersive pressure (grain-to-grain contact ); and 3) escaping pore-fluids (Middleton and Hampton , 1973 ). Flow

turbulence is discounted as a possible lift mechanism because of the minor scour observed at the base of the

flows . It is , therefore , �robable that dispersive pressures , acting in consort with escaping pore fluids , provided the necessary force to initially lift and entrain 110

clasts .

Based on paleoenviromental and palinspastic

reconstructions , these debris flows must have been able to

move over slopes wh ich we re <1 degree . Such low slopes are

only consistent with flows having excess pore-pressures

(Peirson , 1981). Excess pore-pressures can be caused by

several mechanisms , which include : 1) deposition upon a

semi-permeable layer, 2) overloading of the sediment , and

3) liquefaction caused by storm , tidal, and/or wave

activity (Nardin et al . , 1979 ). In the case of the

Maryville, it is thought that sediment overloading and/or

cyc lic waveloading was the probable mechanism initiating

failure and , hence , mass-movement . Maryville debris flows may be similar to modern subaqueous debris flow deposits described by Prior and Coleman (1982) wh ich have been observed moving on slopes of <1 degree .

Storm-Derived Conglomerate Beds

Description

Within the study area , storm-derived conglomerate beds

are characteristically interbedded with planar- and hummocky cross-laminated , calcareous siltstone sequences displaying sole marks , and may be covered by thin (<3 em ) shale layers . These storm-derived conglomerate beds take on several different forms , which include broad , low-relief 111 channels and lenses with planar tops and concave bottoms

(Fig. 3.4A) , and moderately thick conglomerate-filled channels (Fig. 3.4B) . Channel bases exhibit minor scouring of a few centimeters of the underlying beds . More commonly, however , storm-derived conglomerate beds occur as sheets which are continuous over the entire length of the outcrop (see also Fig . 3.4B) . Conglomerate-filled channels and sheet deposits may build upon each other to form "amalgamated" or "m ultistory" sequences (Fig 3.4C) .

Single beds commonly range in thickness from 3-30 em , and may form "multistory" sequences as thick as 0.5-1 m.

Clasts tend to be oriented subparallel to bedding .

Clasts may also lie at high angles to bedding , commonly occurring as "fanned" masses without any consistent orientation to bedding (Fig. 3.4D) . Clasts are poorly sorted and lack any recognizable s�ze grading .

Matrices within storm-derived conglomerate beds consist of we ll-washed skeletal grainstone . Skeletal and nonskeletal material consists largely of coarse-grained echinoderm and trilobite debris , as well as subordinate peloids , inarticulate brachiopods , and quartz silt . Lime mud , if present , is usually trapped between grains or is restricted to the upper portion of beds which contain clasts having fanned fabrics (see Fig. 3. 4D) •

Interparticle cement (i.e, between matrix grains ) occurs as either equant calcite , fibrous cement , or syntaxial 112

Figure 3.4. Storm-derived limestone-clast conglomerate beds .

A. Broad , low-relief conglomerate-filled channels.

B. Moderately thick conglomerate-filled channel. Also note conglomerate (sheet ) deposit located at the approximate position of the hammer. c. Amalgamated sequence of conglomerate beds .

D. Polished slab of storm-derived conglomerate beds exhibiting fanned-clast fabric. Lime mud within the upper part of the slab represents suspension settling of fine-grained sediment during the waning stages of storm activity .

FIGT]R]l: 3.4., p. 113 •:: a :toZAR, MICHAEL GLENN

---- ·· ------' 114 echinoderm overgrowths . Perched-micrite has been observed within a few beds , however , shelter-voids are much more common . Clast matrix ratios average approximately

1.15/1.00.

Clasts within storm-derived conglomerate beds are similar to bounding lithologies; most are derived from associated storm-deposited planar to hummocky cross-laminated siltstone beds . Homogeneous lime mudstone and silty fossiliferous packstone clasts also occur , but are far less common and are typically more well-rounded , as are multicyclic clasts . Clasts generally range in length from 1-12 em and vary in shape from tabular to discoid varieties that have rounded edges . Clasts rarely show evidence of plas tic deformation, but may be bored(?) and burrowed, suggesting prior lithification. In some cases , lime mudstone clasts display dark corroded and glauconitic rinds . However, the presence of borings and corroded rinds is not restricted exclusively to storm-derived conglomerate beds , but also occurs in those conglomerate beds which are be lieved to be of debris-flow origin.

Evidence for Storm-Induced Transport

Sedimentary structures used to discriminate Maryville storm-derived limestone-clast conglomerate beds from those of debris-flow origin are summarized in Figure 3.5. Close association with lithologies suggestive of storm deposition 115

COARSE-GRAINED MATRIX CONGLOMERATE

FEATURES CHARACTERISTICS

ASSOCIATED UTHOLOGIES •INTERBEDDED CALCAREOUS SILT STONE:.TYPI CAL LY OVERLAIN BY SHALE

BED THICKNESS THIN TO MEDIUM-BEDDED CM) (3.0-30.0 NATURE OF BEDDING SHARP PLANAR BOTTOM AND CONTACT TOP BED GEOMETRY •SHEETS; LOW-RELIEF CHANNELS; •THICK• CHANNELS

GRADING WEAK TO ABSENT SORTING (CLASTS) MODERATE TO POOR; PEBBLE­ COBBLE CLAST OR IENTATION •SUBPARALLEL; FANNED MATRIX •WELL-WASHED SKEL. GRNST. RARE TRAPPED LIME MUD

CLAST SHAPE, TABULAR TO DISCOID ROUNDNESS ROUNDED EDGES

OTHER •HCS; PLANAR LAMINATIONS; SOLE MARKS; WAVE-RIPPLE LAM.

•CEMENT -FILLED SHELTER VOIDS

• PERCHED-Ml CRITE •DOMINANTLY MONOMICTIC

MECHANISM: STORMS

Figure 3.5. Characteristics of storm-derived conglomerate beds . (* denotes characteristics believed most diagnostic in determining storm-derived conglomerate beds ). 116

and the dominance of we ll-washed , coarse-grained skeletal

matrix suggests that these conglomerate beds were emplaced

by a process of erosion, presumably during intense storms ,

and redeposition . The abundance of storm-derived

conglomerate deposits within the study area indicate a

location on the ramp that was highly susceptible to storm

processes . Clasts exhibiting "f anned" fabrics represent

re-orientation of clasts by the oscillatory component of

overhead passing storm waves . Lime mud within the upper

portion of these beds represents suspension-settling and

of fine-grained sediment during the waning

stages of storm activity . Unidirectional currents played a minor role in re-orienting clasts as is indicated by the absence of imbrication which is commonly observed in current-generated accumulations (e.g. , Futterer , 1981).

The fact that clasts were exposed for an appreciable time on the sea-floor is evidenced by iron-stained and dark , corroded and glauconitic rinds . Brett et al . (1983 ) noted similar rinds on clasts of Cambrian age in Wyoming and suggested that they were the result of submarine we athering . Glauconite as coatings on a number of the clasts is an excellent indicator of slow rates of deposition in quiet , slightly reducing environments .

Although continuous thin- to medium-bedded , conglomeratic storm-sheets are the norm , broad, low-relief channels and lenses , and moderately thick 117 conglomerate-filled channels also occur. Based on bed thickness and geometry, these beds show close similarities to subtidal storm-surge channels, rip-channels, and progradational lobes related to storm activity (e.g. ,

Brenner and Davis, 1973 ; Kazmeirzak and Goldring , 1978;

Seilacher , 1982; Markello and Read , 1981, 1982).

Storm-generated currents incised low-relief channels across the ramp and transported limestone clasts through the channels . Transportation of the clasts was related directly to the presence of high-energy conditions at the sediment-water interface, possibly by tractional bed load transport . Cessation of storm activity terminated the high-energy conditions , leaving the channels floored with limestone clasts . Suspension settling resulted in sediment infiltrating the deposit. Single , high-energy pulses resulted in "isolated" conglomerate-filled channels .

Conglomerate fill of minor topographic lows may , however , result in similar appearing deposits . Multiple , high­ energy events , on the otherhand, resulted in an amalgamated sequence of storm channels or caused prograding storm sheets to build upon each other as they migrated out over the ramp . The amalgamated bedding geometry suggests that episodic pulses , rather than continuous sedimentation, was the norm . Progradational storm sheets and amalgamated conglomerate sequences may be genetically related to conglomerate-filled channels . 118

In recent years , considerable attention and debate has

focused on the genesis and temporal distribution of

flat-pebble conglomerates with regards to the problems of

lithification and the presence and/or absence of infaunal burrowers. Sepkoski (1982) believed three conditions to have been primarily responsible for the unique abundance of flat-pebble conglomerates within the Cambrian : 1) preservation of beds near the sediment-water interface where they could be rapidly cemented ; 2) erosion and redeposition by storms or other erosional events ; and 3) the near absence of deep (> Smm) infaunal burrowers which inhibit cementation by continual churning and homogenization of the sediment . Although burrows are preserved (e.g. , vertical burrows which occur as discrete

"h oles" ), "swirled" fabrics indicating churning and homogenization by deep , infaunal burrowers is absent within the Maryville. Discontinuous early lithification may have played a role in allowing clasts to be readily eroded .

Vertical Sequence Analysis of Maryville

Limestone-Clast Conglomerate Beds

Vertical sequence analysis of a sedimentary package can reveal two basic types of vertical trends : 1) upward-thickening and coarsening and 2) upward-thinning and fining. The study of different types of thickening or 119 thinning sequences has large ly been restricted to siliciclastic sand and conglomerate divisions of flysch and turbiditic sequences (see Walker , 1984b for a review). such an approach has been referred to as "rhythmic analysis" , the general principles of which have been discussed by

Ksiazkiewicz (1960) and Walker (1970) . Although study of rhythms have been conducted on a number of carbonate sequences (e .g. , Aigner , 1985; Handford , 1986 ), no such study has been applied exclusively to limestone-clast conglomerate beds . Recognition of rhythms within sedimentary sequences can be a useful tool in predicting orderly facies patterns and , thus , may be an important means of understanding the sedimentary evolution of a stratigraphic sequence (Shanmugam , 1980). Explaining the origin of the rhythms may , however, be quite difficult .

Study of conglomerate rhythms within the Maryville sequence was performed in order to answer the following questions :

1) Do the conglomeratic beds show an orderly sequence?

If so , are these sequences represented as

upward-thickening or thinning trends .

2) What is the origin of these sequences?

3) What is the geologic importance of these sequences

(i.e., Do they shed any light on the origin of the

limestone-clast conglomerate beds ?)

In order to accurately check for rhythmic sequences 120

outcrops and core were examined for thickness variations .

Each lithologic change was measured

centimeter-by-centimeter . A continuous log was made for the

sections under study . A total of nearly 37 0 conglome rate beds were encountered and measured at the three localities .

Rhythmograms were constructed by plotting stratigraphic position on the ordinate and lithologic thickness on the abscissa. Rather than selecting only certain stratigraphic intervals , entire stratigraphic sections were considered in detail.

Th e term "rhythm" is here considered in the same relative sense as that used by Shanmugam (1 9 78), and represents a couplet of thick and thin lithologic units , in this case conglomerate beds . The resulting patterns are shown in Figures 3.6, 3.7, and 3.8.

Controlling Factors

And Geologic Implications

Analysis of conglomerate beds using the criteria outlined in the previous section for distinction between debris-flow and storm-derived conglomerate beds indicate that a majority of the conglomerate beds of storm origin.

Th is is particularly true for the Clinton Highway section .

Vertical sequence analysis reveals upward-thickening and coarsening sequences to be common within the study area . 121

FIRST ORDER SEC OND ORDER

60 � ... � N=l44 � e: AVE. THKN.= 13.88 "' � i:::: 40 � \.)

a..� � Co:) i::: ":t� 20 Cl)

CGL. THKN. (em.)

Figure 3.6. Upward-thickening sequences at Clinton Highway . First-order sequences are greater than 10 m and are capped by moderately thick oncolitic , oolitic , and/Qr lime mud accumulations . Second-order sequences mimic the overall sequence and are less than 5 m. Second order sequences are punctuated by thin-bedded , oolitic packstone/grainstone caps .

* N = Number of conglomerate beds . 122

150

120

N=l55 "iii' ... AVE.THKN.= 14.65 � .... � � 90 ...... � i::: � 60 a:� � <.5 t:::: � .,;;: Cl) 30

0 0._...... _....._.&.....I 100 CGL. THKN. (em.)

Figure 3.7. Upward-thickening and thinning sequences at Joy 2.

* N = Number of conglomerate beds . 123

120

100

..... eo N=68 � ..... � AVE. THKN.= 10.70 ...,;.

� 60 i::: � �

Q::;t � 40 (:) i::: � lo.;;: Cl) 20

0 0�-'--L...I..� 30

CGL. THKN. (cm.J

Figure 3.8. Upward-thickening and th inning sequences at GW 129.

* N = Number of conglomerate beds . 124

Upward-thickening sequences , composite sequences of

Ricci-Lucci (1975 ), are asymmetric and reflect the accretionary outbuilding of the ramp via prograding storm sheets and channels . Successive progradation and loss of depositional slope may lead to the aggradation of channel-form deposits , followed by subsequent avulsion and lateral growth of new channels , and finally deposition of non-channelized storm sheets . Such a progression is simi lar to the outbuilding of submarine fan systems within siliciclastic sequences (e . g. , Walker, 1984b) .

A complete progradational sequence is capped by a relatively thick ( 0.5-3.5 m) oolitic , oncolitc , and/or lime mudstone accumulation . Sequences of a lower order mimic the 1st order sequence and are punctuated by very-thin to thin-bedded , oolitic grainstone caps . These gr ainstone caps contain numerous hardgrounds , corrosional surfaces , and glauconite suggesting an extended period of nondeposition or , at least , relatively slow deposition

(B athurst , 1975; Wilson, 1975) . The pattern of the lower order sequences implies that the overall progradational sequence occurred episodically, rather than continuous ly .

Complete progradational sequences are best observed at

Clinton Highway . Here , these sequences are capped by shallow-water deposited oolitic , oncolitic , and lime mud accumulations . At Joy 2 and GW 129, progradational sequences are not readily discernable , although 125 upward-thickening sequences within the conglomerate beds are clearly recognizable . Both of these localities exhibit a thickening and increased conglomerate abundance toward the top of the formation , but are not capped by thick oncolitic and oolitic accumulations . Asymmetric , progradational sequences have been documented within the

Maryville at localities further to the northeast along structural strike (e.g. , Erwin, 1981; Simmons , 1984 ) suggesting that such phenomena may have been common on the ramp . Both of these workers recognized two well-developed progradational sequences accompanied by three intrabasinal onlapping sequences, the final phase extending into the overlying Nolichucky .

The three factors which most notably influence sediment accumulation are eustatic sea-level changes, tectonic subsidence , and sediment supply . Whether a sequence is transgressive/regressive or progradational is dependent on these three factors and their interaction .

De positional topography and sedimentational processes are thought to have played a major role in the progradation .

These progradational sequences may , in part , correspond to sea-level and/or subsidence stillstands .

Although shallowing sequences are commonly associated with regressive sequences , shallowing can also occur during periods of rising sea-level (Miall, 1984) . Asymmetric progradational sequences within the Maryville occurred 126

during a broadly transgressive sequence . Regional sea-level

rises for the Middle to middle Upper Cambrian sequence have

been recorded in carbonate deposits in southwestern

Virginia (Markello and Read , 1981 ; Read , 1985 ). Kendall

and Schlager (1981 ) noted that the upper parts of

transgressive "cycles" may be dominated by a series of

upward-shal lowing carbonate sequences , particularly in the

late stages of regional transgressive events . Clear

evidence for the mechanism responsible for these

shallowing , progradational phases is absent . If regional

sea-level and subsidence stillstands are , in fact,

responsible , these sequences should be correlative in

similar positions on the ramp and within the basin. The

nature and extent of these progradational/retrogradational

phases and a plausible mechanism for their initiation wi ll be discussed more thoroughly in Chapter 5.

Conglomerate beds owing their origin to debris-flow

transport are not reflected as upward-thickening or upward-thinning sequences, but are typically randomly distributed. Based on their relatively small bed thickness

and their variable stratigraphic occurrence , debris-flows were local and probably traveled relative ly short distances. Because of the absence of slumps or slump scars within the study area, it is difficult to reason that these

flows (clasts included ) originated as transformed slumps .

Thus , in contrast to debris flows described by Cook (1977), 127

Maryville de bris-flows had a more complex origin.

Limestone clasts are thought to have originated in a shallow position on the ramp as semi-lithified sediment , were eroded by storms , and were transported downramp , incorporating a variety of material during their basinward transport. Oversteepening (along with overloading) of the sediment pile or liquefaction by storm current , and/or wave activity is be lieved to have initiated failure and , he nce mass movement .

Conclusions

Although a definitive mechanism by which clasts were entrained , transported , and subsequently deposited may be unc lear in all cases , clast fabrics , matrix type , bed geometries , and associated lithologies indicate that limestone-clast conglomerat.e beds within the Maryville owe the ir origin to two related end-member processes ; storms and mass-sediment-gravity movement . Based on field and petrographic evidence , the following conclusions can be made :

1) Limestone-clast conglomerate beds of debris flow origin are characterized by sharp bases, with minor evidence of scour , poorly developed clast fabrics , floating and projecting clasts , and irregular to occasionally mounded flow tops . 128

2) Storm-derived limestone-clast conglomerate beds , in

contrast , are characterized by parallel and fanned-clast

fabrics , well-washed skeletal grainstone matrix, sheet and

channel- like geometries , and associated storm deposited

lithologies .

3) Upward-thickening sequences developed within storm-derived conglomerate sequences show close analogies

with upward-thickening trends in turbiditic , fluvial, and

deltaic progradational sequences. Mass-gravity transported

conglomerate beds , however, are randomly distributed and

show little , if any, systematic variation in thickness .

4) Conglomerate types show a lateral variation . In general, conglomerate beds of storm origin occur in more

shallow-water positions on the ramp , whereas conglomerate

beds of debris-flow origin are found in more basinward

pos itions . Shale matrix conglomerates are found in more

basinward positions as well. Figure 3.9 schematically

summarizes the positions of these various conglomerate

types .

5) Upward-thickening sequences represented, in part , by the conglomerate beds are be lieved to be progradational in origin. cGl..� 1VE�D :EE!l- sf()fl� -- - �o cGL.· - ERIVv� o ENE 'II � OOLITIC/ONCOLITIC 1�!P �- oEB!! L.· SANDS ,..- RIX cG �t1 ­ - /l��� � -�aLE� � - - CH.�:.

.... N \0

SUBWAVE BASE ARGILLA'CEOUS PELOIDAL.

- PKST./GRNST. _a SHAL�. ,�·:; · · ·

Figure 3.9. Distribution of limestone-clast conglomerate types. 130

CHAPTER 4

CYCLICITY AND THE HY DRODYNAMIC REGIME

ALONG A RAMP-TO-BASIN PROFILE

Introduction

As stated in Chapter 2, carbonate ramps are gently sloping surfaces containing agitated shallow-water grainstone deposits , which pass gradually downramp into progressively deeper-water, low-energy mudstone and wackestone , and finally into more basinal argillaceous limestone and shale (cf. , Ahr , 1973 ). The dynamics of ramp systems differ markedly from rimmed-carbonate shelves in that they lack a protective barrier , making them highly susceptible to the effects of waves . As a result , facies organizations are , to a large degree , controlled by episodic high-energy events such as storms .

Within the study area , deposition took place at the transition between a carbonate ramp and a shale-dominated intrashelf basin. Textures and compositions were governed by the type of sediment supplied to the ramp and basin via the interaction of fairweather waves and currents, overhead passing storm waves , and continuous hemipelagic , background deposition . The transfer of sediment between these two contrasting depositional regimes resulted in a 131 heterolithic package of limestone and shale lithologies within the intervening area .

The obj ectives of this chapter are as follows :

1) To document the various lithologies that were

deposited in the Maryville along a ramp-to-basin

profile . In the absence of a variety of modern analogues

for carbonate ramps , th is study will provide detail of

facies types and associations which should be useful in

analysis of vertical facies transitions along similar

carbonate ramp-to-basin sequences .

2) To te st for the presence or absence of cyclicity in

the sequence .

3) To te st the applicability of various shelf transport

mechanisms norma lly applied to siliciclastic shelves and

infer a model by which carbo nate sediment from

shal low-water positions on the ramp was transported out

and deposited in deeper-water.

Facies Sequences

The strata of the Maryville Limestone have been assigned to various lithofacies based on the ir overall lithologic composition, as well as their sedimentary structures . Lithologies may be grouped into two major categories : 1) carbonate-dominated and siltstone lithologies which we re deposited in shallow-water positions 132 on the ramp and 2) heterolithic units of limestone and

shale which were deposited in the deeper margins of the ramp and within the intrashelf basin itself . These heterolithic packages are , volumetrically , the most

important lithologies at Joy 2 and GW 129. Because these

lithologies were extensively discussed in Chapter 2, detailed descriptions are omitted here .

Although distinguishable in outcrop and in polished slab , some of the lithologies exhibit gradational contacts with each other reflecting diffuse paleoenvironmental boundar ies . Figure 4.1 illustrates the proposed lateral relationship of these lithologies . Lithologies which are gradational to each other are grouped together for the sake of simplicity .

Shallow-Water Ramp Sequences

The shallow-water zone on the ramp is considered to be that zone most strongly influenced by storm and fairweather wave activity. Consequently, the frequency of storm layers is at a maximum within this zone . Lithologies attributable to this zone consist dominantly of planar and microhummocky cross-laminated beds , the latter probably being deposited below fairwe ather wave-base , but above mean storm wave-base

(cf., Dott and Bourgeois , 1982) . Some of these shallow-ramp deposits also contain wave-ripple laminations .

Nearly all of these beds are overlain by thin (up to a few 133

Figure 4.1. Generalized siliciclastic dominated basin-to-carbonate ramp profile. Note that the carbonate ramp , in effect , acts as a "clastic" source of for the carbonate interlayers found within the deeper portions of the ramp and within the basin. Limestone-clast conglomerate beds , deep-water oolitic deposits (Lithology 10) , and oolitic caps (Lithology 9) are omitted he re . Lateral scale is tens of kilometers.

A) Shale and ultradistal carbonate-streaked mudstone deposits . Lithologies 1 and 2.

B) Very thin-bedded , silty peloidal packstone/grainstone . Planar and low-angle cross-laminations , undulatory laminations, and micro-graded fining-upward layers are common . Bioturbation and soft-sediment deformation features are also common . Lithology 3.

C) Rhythmically interbedded nodular lime mudstone and shale. Lithology 5.

D) Planar and hummocky cross-stratified siltstone . Note burrowed lime mudstone interval overlying HCS . Also isolated lenses of silty, wave-rippled peloidal packstone/grainstone at the base . Lithologies 4, 6, and 7.

E) Lime mudstone containing stylolitic seams and ve rtical burrows . Rare , laminations defined by quartz silt and peloids . Lithology 12.

F) Oncolitic packstone and interbedded lime mudstone/wackestone . Most oncoids are Type-R and -I of Logan et al . (1974 ), although Type-C varieties also occur . Algal intraclasts , alga l peloids , and rare clusters of Renalcis also occur . Note that within the interbedded lime mudstone/wackestone layers ve rtical burrows disrupt thin laminae . Lithology 8.

G) Oolitic packstone/grainstone . Note marine fibrous fringe and late , equant pore-filling cement , dolomitized ooids , and intraclasts with superficial oolitic coatings . Lithology 11.. I-DEEP-WATERRAMP-BASIN SHALLOW-WATER RAMP ------.1

...... · .. . . .

HCS

...... w � 2

LESS CARBONATE MORE CARBONATE DEEPER SHALLOWER WAVES LESS FREQUENT WAVES MORE FREQUENT LOW ENERGY HIGHER ENERGY 135

em thick) bioturbated mudstone and shale which were

deposited as suspension fallout during the waning stages of

storm activity . Locally, the upper bedding surfaces record

the feeding activities of epifaunal organisms , thus ,

demonstrating the return to fairweather conditions .

Amalgamated , microhummocky cross-laminated beds are absent,

suggesting that either storm waves were short-lived and

relatively weak, or that water depths were too great to

allow waves to continually rework the sediment into an

amalgamated hummocky sequence . However, thin, swaley and rnicrohurnmocky cross-laminated siltstone beds are found

rarely within the deeper parts of the ramp and represent

the effects of exceptionally strong storms that molded the

sediment into a diminutive hummocky deposit .

Oolitic and oncolitic sand sheets were deposited in

slightly shallower parts of this zone . Wholesale movement

of these sands was the consequence of varying hydraulic

regimes associated with storm waves and currents which, based on limited paleocurrent data , acted both parallel to

the strike of the ramp as we ll as onramp (i .e. , oblique to

the ramp) . Relatively thick accumulations of lime mudstone

and wackestone were also deposited within this zone as

ve neers or aprons .

Deep-water Ramp and Intrashelf Basin Sequences

Deposition within this zone was largely below mean 136 storm wave-base, although occasional storms were capable of reworking the sediment . Towards the deeper-water margins of this zone the effects of storms decreased . Lithologies found within this zone characteristically consist of heterolithic packages of limestone and shale reflecting the interaction of two contrasting source areas . Carbonate layers are much thinner , generally less than 2 em . The oscillatory component of overhead-passing waves associated with exceptionally strong storms were barely able to rework the sediment into wavy and lenticular carbonate interlayers . The base of these layers are commonly nonerosional, although in some instances they appear to be erosional . Internally, carbonate layers are planar and low-angle cross-laminated. Thin, fining-upward sequences are the norm and reflect deposition from suspension fallout . Carbonate-streaked mudstone layers and thin, lime mud inter layers effectively represent deeper-water deposition of carbonate sediment that was earlier winnowed in shallower-water positions and then transported basinward . Where they were not reworked , rhythmically interbedded hemipelagic lime mud and interbedded shale we re preserved. In effect , it could be said that the ramp acted as a clastic source of carbonate sediment . Within this zone , currents were the dominant reworking and/or depositing mechanism. 137

Ramp-To-Basin Lithologic Trends

The systematic change in many of the sedimentary

sequences from shallower-to-deeper margins on the ramp

are documented by means of a ramp-to-basin transect (Fig .

4.2). A statistical approach has been used in order to

eliminate the bias caused by the fact that strong storms may leave the same sedimentary record in deeper areas as

weaker storms do in shallower ones . In the absence of such

an approach (use of only "one" stratigraphic section) , a

ve rtical sequence may only be used as a rough "energy

index" and may not have any implications concerning paleobathymetry . In general , the following patterns are

found to be characteristic in the histograms . Towards the basin (i.e. , southwestward ), the percentage of storm layers

(planar and microhummocky cross-laminated lithologies) decreases continually , whereas , the proportion of shale and thin carbonate interlayers progressively increases .

Additionally , in situ accumulations of "shallow-water"

lithologies are absent in most basinward positions , howe ver , allocthonous oo litic packstone deposits have been observed . Such deposits are thought to have been entrained during storms and transported downramp .

Two main factors appear to be responsible for these ramp-to-basin trends: 1) distance from the carbonate source area , and 2) local water depth; because wave effects 138

Figure 4.2. Lithologic thickness trends as observed in stratigrahic sections . Sections A, B, and c, are part of this study . Section D is that of Simmons (1984) near Thorn Hill, Tennessee . Note the decrease in carbonate-dominated units towards the southwest, particularly between section A and sections B and c. Carbonate-dominated lithologies are denoted by diagonal lines .

Abbreviations :

Shale (Ll) SWrareXEP (L2)= Shale with rare planar and cross-laminated packstone SWXEP (L3)= Shale with planar and cross-laminated packstone XEPWS (L4)= Planar and cross-laminated packstone with shale IPG= Intraclastic packstone/grainstone Strx . Camp .= Structurally complex MWS (L7)= Lime Mudstone with shale ONPG (L8)= Oolitic and oncolitic packstone/grainstone OPG (L9, LlO , Lll )= Oolitic packstone/grainstone Sltst. (LG)= Calcareous Siltstone EP (L4)= Silty Pe loidal packstone LMW (L12)= Laminated mudstone /wackestone ARG (Ll-L3)= Argillaceous Limestone NodMWS (L5)= Nodular mudstone with shale NP (L8)= Oncolitic packstone NRPWM (L8)= Oncolitic/Renalcis packstone with wackestone/mudstone Calc .= Calcarenite (oolitic/oncolitic grainstone , see Simmons , 1984 ) Ren . Bdst.= Renalcis boundstone Ren . Grnst .= Renalcis grainstone Mottled Ls . Ribbon Ls . Covered= Covered Interval 139

0 .,

:z: 0�� 0'-t u @ �::Pl0'� lt(.:o !)�'I'( .r., ...... , 0 0 0 0 : .., N 2 �,t O'f ., >.r � � q&O'., @ it. � � � 0'� ,"':0', .,���:., , """...0 """ 0 � 0 0'-�_;:" N "..,0'��

N - 0 l' � � @ �0'� .ei�l>�+o�" ""'co·..,.. =--�lJ, .r 0 � 0 '2. ., .., N .,.,�� SS3NX:JIH.J. " 140 decrease with depth, erosion and resultant suspension deposition should decrease in deeper water .

Stratigraphic Analysis

Walther's Law states that sediment types deposited in adjacent environments will be found more commonly in vertical contact than sediment types deposited in laterally separated environments . Consequently , recurrent vertical contacts should exist between lithologies representing laterally contemporaneous environments. To evaluate this, the frequency of vertical contacts for all the sections examined in this study , in addition to that compiled by

Simmons (1984 ) for the Maryville sequence at Thorn Hill, were recorded and tabulated as two-way frequency tables

(Figs . 4.3, 4.4, 4.5, and 4.6).

Figure 4.7 is a flow-chart summary of the lithologic transitions based on percent frequency of contacts with respect to the total number of contacts. Note that transitions among the deeper-water lithologies are more common at Joy 2 and GW 129, whereas transitions between lithologies found in intermediate or shallower-water positions are more common at Clinton Highway . In addition , transitions between shallower-water lithologies (lime mudstone , oolitic packstone/grainstone , Renalcis boundstone etc. ) are far more common at Thorn Hill. These results are 141

.... � . � � ! row totals -...,.--T-r--r---,-...,.----r-r---r---,-- 3 0 3 35 14 1 2 0 1 77 MOTTLED IS. 0 2 0 0 0 0 0 2 24 Sltst.

5 1 2 0 0 0 4 70 IPG

5 1 0 0 0 0 0 0 11 RIBBON LS.

0 0 4 0 0 0 7 35 UND. LS.

0 NodMWS 5 0 0 14

32 0 2 0 OPG

16 1 3 4 Calc.

0 0 0 0 0 0 Ren. Grnst.

2 0 010001 NP

0 0 0 0 0002 Ren. Bdst.

2 3 2 0 520 3 0 0 SHALE

column 77 24 70 11 35 14 38 31 7 totals total number ot transitions

Figure 4.3. Tally ma trix of lithologic contacts at Thorn Hill. 142

tl) . lzl . � .u tl) � (I) e,:, e,:, "C � e,:, .u � if � � � � 0 p.. p.. .-I z lzl row tl) < ..... z � z z 0 0 tl) X totals

SHALE 0 0 0 0 1 3 0 0 21

ARG 0 0 0 0 1 1 0 0 6

IPG 17 9 3 0 8 63 1 1 0 113

NodM\.JS 0 0 0 0 1 2 0 0 3

U1W 1 0 6 0 1 4 0 1 16

NP 0 0 1 0 0 2 0 0 6

NPRt.J}I 1 0 0 0 0 0 0 0 1

OPG 2 1 0 2 0 0 0 3 14

S 1 tst. 1 0 71 1 3 1 1 2 83

ONPG 0 0 0 0 0 0 0 0 1

XEPWS 0 0 14 6 1 0 0 0 0 column totals 22 6 112 3 16 6 1 14 total number of transitions

Figure 4.4. Tally matrix of lithologic contacts at Clinton Highway 143

� �:a) . � $of � Cll .u as � iE (,!) II) � $of � (,!) Cll p.. (,!) .u � � p.. p.. z p.. .-I Cll Cll Cll :< f:;l H � 0 0 tf) row totals

SHALE 5 6 4 15 0 0 0 0 30

SWrareXEP 7 2 4 0 0 1 0 16

0 8 0 0 1 SWXEP 37 1 57

XEPWS 11 5 97 0 0 1 0 122

EP 3 1 5 1 0 0 0 17

IPG 16 4 30 1 3 0 157

N\vS 0 0 0 2 1 0 0 4

ONPG 0 0 1 0 0 0 0 1

OPG 1 1 1 3 0 0 0 6

0 0 1 0 0 0 0 0 S 1 ts t. column totals 31 14 50 j 20 24 16 0 4 1 total number of transitions

Figure 4.5. Tally matrix of lithologic contacts at Joy 2 144

c... f:,:l :>a1 . $.1 c... (/) ""' � as f:,:l (ll (!) 1-1 � (!) (.!) ""' c... � � � fa.:! c... c... c... c... .-I z tl) (/) (/) � f:,:l H 0 z (/) 0 row totals

3 SHALE 1 2 28 2 7 1 0 1 1 4

SWrareXEP 19 2 0 0 0 1 0 24

SWXEP 0 0 19 0 0 0 0 26 3 XEPWS 26 15 40 1 0 0 94

EP 5 2 0 0 0 0 0 9 3 33 IPG 7 20 1 1 0 67 3 OPG 1 0 0 0 0 0 4

NP 0 0 0 1 0 0 1

S ltst. 1 1 0 2 0 2 0 6

ONPG 0 0 0 1 0 0 0 0 column 3 totals 4 25 27 91 9 68 4 1 total number of transitions

Figure 4.6. Tally matrix of lithologic conatcts at GW 129 145

THORN HILL

10.45 MOTTLED OOLITIC LIMESTONE LS !1.55 5.07 !l �·7 INTRA.CLASTIC

:n:,SILTSTONE

2536 INTRACLASTIC 6.07 SHALE SILTSTONE PKSr./6RNST. "22.50 • 5.71

23.60 po INTRACLASTIC !1.00 XEPWS SWXEP KS • 22.87 P T./6R NST. • 7.30

SWXEP

5.� 690 NTRACLA 7 15 �XEPWS ! ST/C 7.2 • SWXEP g-50..00 PKST./6RNST ... 6 .90 9.'#"45 AXJ./8

SHALE

Figure 4.7. Flow-chart summary showing lithologic transitions based on vertical contact analysis . Numbers refer to the percent frequency of contacts with respect to the total number of contacts . Arbitrary cut-off point was put at 5 %. The reciprocal nature of the I pairs between lithologies attest to the randomness of the sequence. 146

to be expected, because deeper-water lithologies are vo�umetrically more abundant at Joy 2 and GW 129 than they

are at either the Clinton Highway or Thorn Hill sections .

Nonetheless , this demonstrates that towards the southwest

along structural strike the Maryville sequence was deposited in progressively deeper water .

Cyclicity

A cyc le refers to a series of observations (i.e. , rock types , bed-thickness measurements) that tend to occur in certain order (cf., American Geological Institute , ) . The idea that cyc les are a common motif within carbonate sequences has become increasingly popular recently ; however, identification of such cycles has been based on either descriptive data which lacks statistical verification , flawed Markov-chain analyses , or synthetic computer-generated mode ls (see Weber et al ., 1986, for a review) . Few studies have applied rigorous statistical methods to carbonate sequences in order to objectively test for cyclicity .

In order to evaluate cyclicity in an obj ective manner , a Markov-chain analysis procedure initially proposed by

Carr (1982) was used to evaluate the presence and extent of any "cyclic" tendencies within the Maryville . Transitions from one lithology to an overlying lithology (i.e. , contact 147 analysis data ) are compiled as two-way frequency tables .

Because the transition from one lithology to an overlying identical lithology never occurs the transition frequency matrix contains a priori zeros along the main diagonal. To test transition-frequency matrices for embedded Markov chains a Pearson 's chi-square statistic was used . By doing this we can identify vertical transitions from one lithology to another that are more frequent than would be expected in a random sequence . That is to say, if the observed chi-square value is greater than the expected chi-square value the lithologic sequence displays nonrandomness or Markovian behavior . The BMDP- 2F computer program was used in this stepwise procedure (Brown , 1979 ).

At this point in time , substitutability analysis has not been conducted in order to objectively combine lithologies and test for cyclicity .

Preferred Transitions

For all of the transitions examined , except for a few selected transitions at GW 129, the observed frequency was not greater than the expected value (see Fig. 4.8). Even the cyc lic trends at GW 129 are not very significant as evidenced by the small differences between the observed and expected frequency values . This small difference may not correspond to a true cycle , but may , in fact, be a statistical artifact . Matrices emphasizing transitions that 148

Figure 4.8. Cyclicity . Facies transitions selected as signif icant after analysis . Selection was made using a log-linear , quasi-independent model and stepwise procedure proposed by Carr (1982). Stepping terminated when probability of chi-square for matrix exceeded .20 alpha (80% confidence interval) . Note that most transitions had observed frequencies less than that expected under random depositional conditions . Thus , cycles in the sense of a repeating l�thologic succession do not exist within the study area except for a few selected transitions at GW 129. BMDP-2F computer program was used for the stepwise procedure (see Brown , 1979). JOY 2 DRILL CORE CLINTON HIGHWAY 0 0 11 X11 MATRIX 1 X 1 MATRIX

Step Tra nsition Observed Expected Chi Probability no. type frequency frequency Square Step Tra nsition Observed Expected Chi Probability EP no. type frequency frequency Square 1 6 24.1 2 127.64 0.0000 IP t 1 0 27 69 191 .90 0.0000 IP OPGt S'HXEP 2 5 19.77 110.37 0.0120 NP 2 3 0.08 151.50 0.0000 XEPtWS t M XEPWS 3 7 26.42 94.80 0.0176 M 3 3 0.07 110.09 0.041 1 S'HXEPt NPt EP 4 3 24.37 81 .61 0.1 080 4 s 1 0.00 87.31 0.4103 XEPtWS NPt XEPWS 5 1 8.90 70.47 0.3307 ARG LS 5 2 0.14 74.86 0.751 9 EPt t s 6 IP 3.90 t 0 64.31 0.5008 � Totl l nllllber ottransltions-N• 279 SILT ST \.0

Totll nl.lnberot Ira nsltlons•N- 411 GW1 29 1 0 X 1 0 MATRIX

Step Tra nsition Observed Expected Chi Probability no. type fre quency frequencv Square S'HXEP 1 20 1.55 114.12 0.0007 t IPGIIP IPG IIP 2 19 1.35 78.1 6 0.2106 S'HXEPt XEPWS 3 0 5.60 68.66 0.4548 OPGt XEPWS 4 2 11.43 59.14 0.7420 E t P PIME · -

Totll numberor lransltlons•N• 275 150

do not occur as often as would be expected (i.e., expected

frequencies which are much greater than observed

frequencies ) probably do not correspond to the unlikelihood

that such lithologies were adj acent , but most likely attest

to the high degree of randomness within the sequence . Thus ,

collectively , the analysis demonstrates that the

lithologies recognized in the Maryville are randomly

stacked , occurring enough times out of order to

statistically negate cyclic order . Although subtle evidence for cyc licity does occur within one of the

stratigraphic sequence , lithologies within the Maryville

sequence as a whole are randomly stacked and do not show evidence for longer-term Milankovitch (10,000-100,000 year cycles ) cyclic packages such as those proposed by Read , et al. (1986) for coeval carbonate sequences in southwestern

Virginia . However , Reads ' cyclic packages have never been rigorously tested via Markov-chain analysis. Po ssible explanations for the absence of cyclicity within the

Maryville are as follows :

1) Many of the lithologies found within the Maryville

sequence are directly or indirectly related to storm

processes . Such storm processes are sporadic in nature

and capable of reworking the sediment , thus modifying

the stratigraphic record .

2) "Cannibalistic" scour of sediment due to shifts in

environments may create nonrandomness by producing 151

facies transitions which appear to be noncharacteristic.

3) Normalization of carbonate sequences to small-scale

cycles involves oversimplification of a complex and

heterogeneous depositional system . Thus , it is

questionable whether "pronounced" statistically valid

cycles should occur in a carbonate ramp system.

Carbonate Ramp Dynamics- A Hypothesis

Although shallow-water oolitic sand bodies were

invariably agitated , the overall facies organizations and details of stratification were controlled by episodic , high-energy storm events . Re latively low-energy conditions

found within the more basinward settings were only

interrupted by occasional high-energy events of exceptional magnitude . Here , currents were more efficient in modifying

the sediment . In the shallow-water zone , sediment was deposited within the realm of fairweather wave-base , but above mean storm wave-base . This zone was strongly storm-influenced and contains microhummocky cross-laminated and wave-rippled beds . Or ientation of sole marks within this zone indicate flow parallel to the strike of the ramp

(Fig . 4.9A) . Although the absence of available bedding surfaces precluded the accurate measurement of wave-ripple orientations , it is apparent from crude measurements of wave-ripple crests , as well as the inclination of internal 152

Figure 4.9. current and wave trends plotted on palinspastic base map of Roeder and Witherspoon (1978). Solid black line is believed to be the outline of the ·carbonate platform during Maryville time . Rectangle refers to study area.

A) Orientation of sole marks .

B) Direction of wave approach based on trends (southeast quadrant ) of ripple crests and internal fore-sets as well as megaripple crests of oolitic sand sheets . Absence of available outcrop surfaces precluded accurate orientation measurements .

/ 153

· · :' .· · · ------

� · · · · ·· . . . ·

··· . . · . · · · . · · · ...... · ·· ...... · , . · · .. · .. ·· · - . . ·· : ,, . · -- � · . •• · � · : ·· : 1..:.. · ..,/ · • . · · · � . ·· · '--. / / . .. o....J .

..···· : · ·· . . · · ...... · : .: ::: :::.:: :::: . .. : . .. ·...... 154

cross sets , that onramp-directed waves were responsible for

the formation of such structures (Fig. 4.9B) . The

orientation of megaripple crests within oolitic beds is ,

likewise , onramp . Figure 4.10A is a schematic block

diagram illustrating the probable hydrodynamic regime on

the carbonate ramp . Onramp-directed storm waves likely

entrained quartz silt within the intrashelf basin and deposited it in shallower positions on the ramp once the high-energy conditions dissipated . This, in part, explains the high percentage of siltstone beds within the

shallow-water zone as well as the thin shale beds which overly them .

Fine-grained carbonate sediment suspended by wave turbulence in the shallow-water zone was transported away

from it, and hemipelagically deposited downramp . The mechanism responsible for this is not entirely clear ,

although a mechanism employing storm-surge-ebb flow may be

responsible . Rampward pile-up of water by storm waves

(coastal set-up ) may have been compensated for by offramp

return flow in the way of storm-surge ebb flow or relaxation (i.e. , compensation for higher pressure gradient onramp) . Figure 4.10B is a simplified illustration of this mechanism. Such a mechanism may have also been responsible for forming the conglomerate-filled channels , which have been observed in a number of the Maryville sequences in the area of study . In any case , it is apparent that the 155

Figure 4.10. Hydrodynamic Regime .

A) Model for the hydrodynamic regime on the ramp . Overhead passing waves moved obliquely onramp producing wave-ripple laminations and megaripples. A flow component acting roughly parallel to the strike of the ramp is indicated by the orientation of the sole marks .

B) Theoretical model of depositional processes responsible for the transfer of carbonate and siliciclastic sediment on the ramp . Rampward pile -up of water (coastal set-up ) is compensated for by offramp directed return flows (storm-surge ebb-flow , gradient currents? ) causing erosion of channels (i.e. , conglomerate-filled channels) and transport of carbonate sediment out into the distal and intrabasinal portion of the study area . At some finite distance from shallower areas Coriolis forces def lects gradient flow to become isobath parallel geostrophic flow . 156

A

B

�------101 KM------��

WSW WAVE S@ �SET-UP ENE

, , . ...._ HEMIPELAGIC FA LLOUT

'P-WATERRAMP-BASIN • 1,. SHALLOW-WATER RA MP 157 oscillatory component of overhead-passing storm waves was capable of mixing carbonate sediment with siliciclastic sediment by a recurring process of suspension and redeposition. Although more paleocurrent data is needed to make any conclusive statements, deposition by combined-f lows (i.e. , wave oscillation plus a mean geostrphic flow component ) seems a highly probable mechanism for mixing and redistributing sediment within the basin and the ramp . Southern hemisphere paleolatitudes plus available paleocurrent data would predict southward directed geostrphic flow . Although highly speculative at this point , it may be possible that off-platform transport and southerly directed circulation patterns played a major role in allowing the carbonate ramp to prograde in a southwestward direction . Mullins and Neuman (1979) noted that the direction and magnitude of off-bank sediment transport , along with oceanic circulation, had the greatest effect in controlling the progradation of the northwestern margins of the Little and Great Bahama Banks .

Fairweather conditions were likely dominated by off-ramp transport of carbonate sediment similar to the leeward margin of th� Little Bahama Bank (cf.,Mullins and

Neuman, 1979). Wind stress acting southwestward along and across the carbonate (fairweather winds ) platform and ramp would have entrained carbonate sediment and deposited it 158 within the deeper margins of the ramp and in the intrashelf basin.

Conclusions

1) From the stratigraphic sequences examined in this study it is apparent that lithologies show a systematic change from northeast-to-southwest reflecting a decrease in carbonate and a concomitant increase in shale and siltstone lithologies . Two main factors appear to be responsible for this change : A) distance from the carbonate source areas and B) local water depth .

2) A modified Markov Chain analysis procedure applied to the Maryville sequence reveals almost comp lete absence of statistically verifiable cyclicity in the sense of a repeating succession of lithologies . Where cycles do exist

(GW 129 ) they are both rare and subtle .

3) Limited paleocurrent data suggests that sole marks owe their origin to a flow component which acted parallel to ramp strike , whereas , onramp-directed waves acting obliquely to the ramp were responsible for many of the wave-ripple laminations as well as the megarippled crests of some of the oolitic beds . Storms were responsible for deposition of microhummocky beds within the realm of fairweather wave-base , but not below storm wave-base .

Fairweather conditions were dominated by modification of 159 storm-deposited siltstone beds by overhead-passing waves and off-ramp transport of shallow-water carbonate sediment due to wind stress acting southwestward across the platform and ramp . 160

CHAPTER 5

PALEOENVIRONMENTAL SYNTHESIS

Introduction

During Middle and Upper Cambrian time the region of east Tennessee contained parts of three major depositional settings . Briefly, these inc luded: 1) a western intrashelf basin , 2) a westward-dipping carbonate ramp , and 3) a shallow carbonate platform . Figure 5.1 displays the location of the three stratigraphic sections referred to in this study and those of other workers (e.g. , Erwin , 1981 ;

Simmons , 1984) .

Development of the westward-dipping carbonate ramp began in latest Early Cambrian to earliest Middle Cambrian time when a major transgressive event resulted in the drowning of the mixed carbonate and siliciclastic sediment of the Rome Formation (Palmer , 1971). Lithologies contained within the Rome were periodically subaerially exposed , as suggested by local development of mud cracks , salt hopper casts , and fenestrae (Samman, 1975 ). Other environments recogni zed by Samman (1975) include mud flats , sand flats , mixed flats and lagoons ; collectively represented by a series of shale , siltstone and sandstone lithologies . East of this broad carbonate- and PALINSPASTIC RECONSTRUCTION

...._. '

· · ·· · -·'" ----;- -, .. ./ ··- ····- .,�·· ··· · ··· •"' · ·· ..:�· V..//::·� /: �� /' . . . ,·�� . (.. .. . - . ���--· . �--­ · /::-·· ...... ,., ...... / . 0\ , . · ...... = . . - -- , � .. .. . ,... � .. · ·, J ,..- r'·· ·

.·"""" ··- .,. _ .. ��. .._ _/_. .... -,(<) · ::.- l/ . � �: . ,:::-:;�_·.·;:::: ...... 100 KM . .. . ) ...... /? .- ...... •··•• 'l•'.l . . . . ( ...... J . ,.-.�·::::::.� .

• " .• . ' - ,r ... -· ...: ::�:/ Figure 5.1. Palinspastic base map of Middle and Upper Cambrian age rock in east Tennessee . Localities A, B, and C are part of th is paper . Locality D refers to the Thorn Hill section of Simmons (1984) . Locality E refers to the DC section of Erwin (1981). Palinspastic base of Roeder and Witherspoon (1978) . 162 siliciclastic-dominated, supra- and subtidal comp lex was a carbonate bank (Shady Dolomite ) that was developing along the western margin of a slowly subsiding Appalachian basin.

Continued transgression and/or subsidence throughout

Cambrian time is manifest by the overlying Conasauga Group .

The lower part of the Conasauga Group , Pumpkin Valley through early lower Nolichucky , depicts this transgressive phase . The final phase of transgression resulted in basinal shale and argillaceous limestone extending over the whole province (i.e. , establishment of the Nolichucky basin) . Brief shoaling occurred at various intervals throughout middle to late No lichucky time , becoming much more widespread during late Maynardville time (see Weber , in progress ).

Paleoenvironmental Mode l

Careful analys is of lithologies found within the study area has led to the development of a paleoenvironmental mode l (Fig . 5.2) for the Maryville (upper Bolaspidella

Zone ) within the vicinity of Powe ll and Oak Ridge ,

Tennessee . Deposition occurred at the transition between a carbonate ramp and a shale-dominated intrashelf basin.

Deposition on the carbonate ramp was in the form of lime mudstone and wackestone , as well as oolitic and oncolitic packstone/grainstone sand sheets . Within this ENE OOLITIC/ONCOLITIC SANDS

- _:.. : . ;- CH .

.... 0\ 1,.1.)

SUBWAVE BASE ARGILL(CEOUS PELOIDAL .

PKST./GRNST. _ SHAL>:; 6 ... ·I/

Figure 5.2. Generalized schematic block diagram of the ramp-to-basin profile during Maryville time . 164 shallow-water setting wave and storm influence was at a maximum , as evidenced by the abundance of planar , wave-rippled and hummocky cross-laminated calcareous siltstone deposits. Storm-derived lime stone-clast conglomerate beds are also common . To the west and southwest , deeper-water conditions became increasingly more common. There , sedimentation was largely be low mean storm wave-base . Deposition consisted of shale , carbonate-streaked mudstone as well as other interbedded shale and lime stone lithologies (see Chapters 2 and 4) .

Many of these rocks exhibit fining-upward sequences .

The type and character of sedimentation within the basinward margins of the ramp and within the shale dominated basin was governed , to a large degree , by off-ramp transport of carbonate sediment winnowed by fairwe ather waves and storm-currents in more upra mp positions . In some instances , bottom currents were able to redistribute sediment , modfifying the once hemipelagically deposited carbonate . In the deeper margins of the ramp where they we re not winnowed by currents , rhythmically interbedded lime mud and shale sequences were preserved .

Thin, calcareous quartz siltstone occasionally occur interbedded with the basinal shale deposits .

As in the study area , farther to the east and northeast (i.e. , farther on-ramp) , much of the carbonate ramp lay be low sea-level (e.g. , Erwin , 1981, Simmons , 165

1984). Sedimentation consisted of relatively thick

accumulations of lime mudstone and wackestone , oolitic and

oncolitic sand sheets and shoals , algal "biostromes" and

lime mudstone deposited in restricted lagoonal

environments. To date , peritidal deposits have only been

recognized in the easternmost equivalent of the Maryville ,

the Honaker Dolomite.

Based on the presence of open-marine biotas (i.e. ,

echinoderms , hyolithids , sponges , etc. ), the intrashelf basin is thought to have been open-marine throughout

Maryville time . It is possible that surface-to-bottom mixing conditions caused by waves and currents inhibited development of euxinic conditions within the basin, allowing for the proliferation of an open-marine fauna .

Pervasive evidence of bioturbation within the basinal deposits attests to the absence of dysaerobic conditions .

It may be possible that the intrashelf basin was "open" to the seaward side of the shelf at its southernmost margin in

Tennessee and Georgia . Whether the shelf was breached at any point along its extent is not known .

Arid , or at least semi-arid conditions (indicated by the presence of gypsum and evaporate psuedomorphs within the Honaker, see Erwin, 1981 ), may have caused oxygenated surface waters from the shallow margins of the ramp and shelf to move downramp as they became denser due to evaporation, replenishing -deficient waters contained 166

within the basin.

Although paleo-water depths are difficult to

estimate , based on paleoenvironmental and palinspastic

reconstructions , water depths within the basin in the study

area were on the order of 35-45 m. Locally , however, water depths may have been slightly greater . This estimate

deviates slightly from 20 to 30 m water depths postulated

by Markello and Read (1981; 1982) for coeval basinal

sediment in southwestern Virginia. Simmons (1984 ) concluded that depths for the Maryville sequence at Thorn

Hill, Tennessee (approximately 50-60 km to the northeast

along structural strike ) were no greater than 30 m.

Comparison of depth estimates for these three wide ly spaced

study areas implies that the intrashelf basin deepened

slightly toward the southwest in east Tennessee . On a regional scale , this may , in part , be related to differential sedimentation or subsidence rates . Increased subsidence in the southern margin of the basin is suggested by the fact that rocks are slightly older within the study area than they are near Thorn Hill (i.e. ,

Maryville/Nolichucky contact , see McLaughlin, 1973; see also Chapter 1). Nevertheless , the lack of observed slumps , slump scars , and turbidites , along with the absence of shelf-edge buildups , implies that the basin-to-shelf transition retained its ramp-like profile throughout

Maryville time . 167

Initial development of the Conasauga intrashelf basin was not related to flexural bending or down-to-basin normal faulting , but may have been related to high carbonate production on the developing carbonate shelf while sedimentation rates within the shale-dominated intrashelf basin lagged behind (i.e. , bipolar sedimentation rates , see

Walker , Shanmugam , and Ruppel, 1983). Once established , local siliciclastic influx from the basin suppressed carbonate production , further maintaining basinal conditions . To date , evidence for structural control of the basin is lacking .

Although the recognition of carbonate ramps has become increasingly common with the inception of Ahrs '

(1973 ) ramp model (e.g, Read , 1980; Markello and Read ,

1981, 1982; Aigner, 1984), there is an absence of a variety of modern analogues for carbonate ramps . The Arabian

Gulf-Trucial Coast region (Purser , 1973) may be the only widely recognized modern example of a carbonate ramp , although Shark Bay, Australia has been regarded by some

(Logan et al., 1974 ) to be an example of a homoc linal carbonate ramp . The width of the ramp in east Tennessee is not precisely known because the study area does not extend far enough across depositional strike to trace the entire transition along a single horizon . Markello and Read (1982) estimated the intrashelf basin to have been 300-400 km wide . Because of the lack of data , estimates of the width 168

of the basin in east Tennessee are speculative, at present .

Based on work by Markello and Read (1981; 1982), Erwin,

(1981), Simmons (1984), and the present study , it is

obvious , however, that the carbonate ramp extended much

more than 100 km along depositional strike .

General Trends

Vertical stacking of upward shallowing sequences is a

common motif within many shallow-water carbonate complexes

(Wilson , 1975; James , 1984). Analysis of three Maryville

stratigraphic sections along a ramp-to-basin profile

reveals a sequential alternation of lithologies which collectively indicate progradational events .

Progradational sequences identified within the Maryville are asymmetric. Ideally , asymmetric sequences commence with shale and/or interbedded shale and limestone and calcareous quartz siltstone , grade into lime mudstone and wackestone , and in turn are finally capped by either

relatively thick (0.5-3.5 m) oolitic and/or oncolitic packstone and grainstone . Throughout this sequence are

interbedded limestone-clast conglomerate beds . These asymme tric progradational sequences represent the increasing influence of shallow-water carbonate environments, which extended westward and southwestward into the intrashelf basin. Progradational sequences are 169 believed to have been superimposed upon a gradual, transgressive sequence . Progradational (shallowing )

sequences within broadly transgressive successions have , likewise , been documented in carbonate environments throughout the geologic record (e.g. , Bebout , 1977; Wright ,

1986). These sequences are common elsewhere in the

Maryville and have been described by other workers (Erwin ,

1981; Simmons , 1984) in areas further to the northeast along structural strike . Both of these workers recognized two well-developed prograding carbonate sequences (minor progradations may also occur , see Simmons , 1984) accompanied by three intrabasinal onlapping sequence , the latter extending into the Nolichucky Shale .

Although the boundary between progradational

(shallowing ) and retrogradational (deepening ) pairs may , in some cases, be arbitrary , lithologies which are inherent to each phase still can be recognized. Lithologies representing progradational phases within the study area inc lude lime mudstone and wackestone along with oolitic and oncolitc grainstone and packstone . Within the latter lithofacies , algal debris , in the form of Renalcis intrac lasts and intertwinned Girvanella tubules , is quite common . Tri lobite and echinoderm debris is ubiquitous throughout these progradational lithologies; sponge spicule , mollusc, and hyolithid debris are not quite as common . Various forms of algal debris and oncoids , along 170 with associated oolitic grainstone and packstone , attest to the shallow-water environment of deposition for these progradational lithologies .

In contrast to the Maryville sequence near Thorn Hill,

Renalcis algal boundstone has not been observed within the progradational facies observed in the study area. Based on their dimensions , (single "microbioherms" grew to a height of 10 em ; see p. 163, Simmons , 1984 ) these algal boundstone beds are different from the algal bui ldups described by

Weber et al. (1985) in the Nolichucky in that they probably did not display any appreciable relief . Consequently , the

Renalcis boundstone deposits described by Simmons probably did not form wave-resistant barriers , but played a major role by locally stabilizing and binding sediment much like algae do in modern carbonate environments. The absence of algal boundstone within the study area may , in part , be due to slightly deeper-water conditions or increased siliciclastic influx into the area .

Retrogradational (deepening ) facies , on the other hand , characteristically have a higher siliciclastic content . Fining-upward sequences of storm and fairweather origin are common within this sequence of facies . Common lithologies include shale , carbonate-streaked mudstone , and peloidal packstone/grainstone and shale , as well as other lithologies commonly found in distal positions on the ramp .

Thin , interbedded quartz siltstone deposits occur among the 171 basinal shale . Intraclastic beds are equally common, but are not as thick-bedded as those found within the progradational phase . Collectively , conglomerate beds show a characteristic upward-thickening from the base of the retrogradational phase to the top of the progradational phase .

In the study area, progradational sequences are most pronounced at Clinton Highway where two major progradational (shallowing ) sequences exist (Fig. 5.3).

Accompanying this are three intrabasinal onlapping sequences , the final phase extending into the overlying

Nolichucky Shale. Overall, sequences are asymmetric , with the progradational phase being thicker than its retrogradational counterpart .

In a transect from shallower-to-deeper parts of the ramp , and into the basin itself , it is apparent that the progradational patterns become less recognizable . At Joy

2, only one such , and possibly two , progradational sequences are readily identifiable (Fig. 5.4). Although conglomerate beds do show a characteristic upward-thickening at GW 129, clear evidence for progradational sequences is absent (Fig. 5.5) . In these more basinward areas lime mudstone , as well as oolitic and oncolitic units , are rare to absent . Conversely , carbonate layers displaying thin, fining-upward sequences , the distal � r1-e ;'!'£. ,.,. � \J\.Es rfoO ,t�� , .. 1 " , r �· I • ,.. I .... - 60 1 � • r -- � =� � ,. � � � , ,...... ,. I � ...... IL r- 40 I .... � .... ,. ,.. � ,.... � � � ...... :r r � I l � N 20 1 � I � I • � • F •

I I 0 0 I 0 I"'I I 0 I 0 .-: I I I I t I I I I I I I I 0 P"l

0 60 a-- 10 0 100 P•�.,I(SJ P•rt:•n i(SJ f»�MII (SJ

e• POSITION OF POINT- COUNTED SAMPI..ES

Figure 5.3. Vertical distribution of skeletal and nonskeletal allochems as well as matrix type at the Clinton Highway section . Also included is the stratigraphic distribution of the conglomerate beds . Measurements of the conglomertaic beds are in centimeters. Some of the "spikes" represent thin strom layers which contain ooids , omcoids , algal debris etc . or thin oolitic caps and , thus , may not seem to fit we ll into the progradational pattern. 173

meters 150

120

90

60

30

100 0 50

LITHOLOGY THICKNESS (CtJnfimtJftJrs)

Figure 5.4. Stratigraphic distribution of conglomerate , oolitic, and , oncolitic units at Joy 2. Measurements are of unit thickness and are in centimeters . Oolitic unit at the base of the section represents deep-water oolitic accumulations . 174

meters 120

100

80

60

40

' ' 20 ' ' '

50 0 50 LITHOLOGY THICKN�SS (csnfimtJftJrs)

Figure 5.5. Stratigraphic distribution of conglomerate and oolitic units at GW 129 . Measurements are of unit thickness and are in centimeters. 175

products of carbonate sediment transported off the shallow

margins of the ramp , are much more common .

Causes of Progradation

Although some workers may consider the

progradational/retrogradational pairs found within the

Maryville to represent small-scale , eustatically controlled

transgressive/ regressive sequences , such sequences can

result from an interplay of a wide variety of mechanisms

(see Wilson, 1975, p.5 1) . Even though it is indeed

possible that smaller-scale progradational sequences

(second order sequences of <5 m thick ) may be intrinsically controlled , in part , the generally wide distribution of

larger scale ( > 10 m thick ) progradational sequences

excludes local , self-regulating mechanisms . The

alternative extrinsic controls responsible for such

sequences can include : 1) absolute (eustatic ) rises and

falls in sea-level, 2) changes in relative sea-level caused by differential subsidence within the basin, or 3) a combination of 1 and 2 acting in tandem or simultaneously .

Minor changes in sediment production or supply may be attributable to changes in sea-level or subsidence .

During Middle Cambrian time much of the southern margin of North America is considered to have been a passive margin (Rodgers , 1968; Bird and Dewey , 1970 ). 176

Tectonically related subsidence rates on modern day passive margins are typically on the order of 2-4 cm/ 1000 years

(Pittman , 1978; Steckler and Watts , 1978; Keen, 1979 ;

Heller , et al. , 1982), but may be as high as 20-25 em /1000 years early in the history of the passive margin when subsidence is not entirely controlled by thermal cooling

(Steckler and Watts , 1980) . From study in Virginia and adj acent states, Read (1985) inferred subsidence rates to be on the order of 4 cm/ 1000 years . Goldhammer, et al. ,

(1985) calculated subsidence rates to range from 1.25-6.8 cm/1000 years for coeval deposits in the central and northern Appalachians . Although subsidence rates have not been estimated for east Tennessee , it is likely that minimum rates were also compatable with those predicted for passive margins (note subsidence rates calculated for the

Appalachian depocenter are calculated over long time periods and ignore shorter-term speed-ups and slow-downs , diastemic hiatuses , as we ll as solutional removal ).

Bipolar loading due to overburdern (i.e. , the effects of both water and sediment load ) is thought to have played a minor role in establishment of the intrashelf basin because isopach maps (see Hasson and Haase , in prep ) constructed for the Maryville sequence reveal that the basin center and depocenter do not coincide . It would be expected that the area containing the thickest sediment cover should undergo the greater subsidence due to overburden . Nonetheless, it 177

is evident that the basin neither underwent considerable

subsidence, nor was it sediment-starved , because

considerable basin-to-shelf relief does not exist .

Consequently, some other mechanism must be responsible for

allowing the Maryville to remain subtidal over its entire

extent . A gradual rise in regional sea-level for the

Middle to middle Upper Cambrian sequence has been

documented in coeva l carbonate deposits in southwestern

Virginia and , likewise , is thought to have been responsible

for maintaining subtidal conditions in east Tennessee .

Although glacio-eustatic changes in sea-level are

debatable in the Cambrian , it is still conceivable that

climatically induced fluctuations of global sea-level did

occur . Such sequences would be on the order of

10, 000-100,000 yrs . and are comparable to Milankovitch

climatic cycles (e.g. , Schwarzacher and Fisher, 1982)

Climatically induced sea-level changes should be

correlative over the entire basin.

The fact that progradational sequences are best developed in the shallower positions on the ramp and are more variab le (and in some cases non-existent ) within deeper water areas implies that differential sedimentation rates were the primary control on the position of the carbonate/silicic lastic interface . Progradation (i.e. , times when carbonate production outpaced siliciclastic

sedimentation rates ) may have been triggered by pulsed 178 standstills in sea-level and/or lulls in subsidence .

An idealized four- mode l for the asymmetrical progradational sequences found within the Maryville and elsewhere to the northeast consists of :

Phase 1. Sea-level rose slowly. Carbonate production

kept up with sea-level or may have outpaced relative

sea-level rise, initially producing shallowing-upward

sequences . Eventually , the rate of carbonate production

decreased because of increased water depth and the

concomitant increase in siliciclastic input, which

inhibited carbonate production .

Phase 2. Sea-level continued to rise , subsidence was

ongoing . "Deep-water" subtidal conditions were

maintained over the ramp . Depending on the rates of

each , either subtidal conditions developed and

persisted , or , if both were slow , minor

shallowing-upward sequences occurred . This phase lasted

for a pronounced period of time in comparison to the

other phases and resulted in thick,"deep-water" subtidal

accumulations .

Phase 3. Sea-level rise dropped slowly and subsidence

decreased at the same rate so that sea-level and

subsidence rates equaled each other . Shallow-water

carbonate environments extended basinward , culminating

in relatively thick oncolitic and oolitic accumulations.

Stillstands of short duration resulted in thin 179

progradational sequences accompanied by numerous

hardgrounds or nondepositional surfaces (i.e. oolitic

caps ). Phosphatic crusts(?) , iron-staining, and

glauconite zones are associated with these minor

outbuildings . Collectively, these features indicate

short stillstands in sedimentation .

Phase 4. Progradational wedge reached its limit, and

approached a state of dynamic equilibrium . Relative

sea-level continued to rise. Whole sequence started

again.

Conclusions

The following conclusions can be drawn from the above discussion :

1) Within the study area, complete progradational sequences are best developed in shallower positions on the ramp and are indistinguishable , if ever, observed in more distal and basinal positions .

2) Smaller-scale progradational ( shallowing ) sequences (<5 m) may be intrinsicallly controlled in part; however, larger-scale (<10 m) sequences are be lieved to be extrinsically controlled.

3) Progradation was probably superimposed on an overall transgressive sequence and may have been triggered by a standstill in regional sea-level rise and/or a lull in 180

subsidence .

4) If, in fact, progradation was a basinwide phenomena ,

correlation of the tops of the sequences among sections

within the same paleogeographic position may provide an

empirical time scale with finer resolution than is possible

through current biostratigraphic techniques . Such an

approach has been referred to as "kickback stratigraphy"

(Irwin , 1965) or "event corre lation" (Ager , 1981; Cant ,

1984). In transects marginal to the more central parts of

the basin correlation of sequences may be impossible .

5) Using the lithologies recognized within the study area

and taking into consideration the variations that exist

during a pro- or retrogradational phase, an overall

depositional model has been derived for the Maryville near

the transition of this unit we stward and southwestward into

the shale sequences of the intrashelf basin. Further work

in east Tennessee may discover sequences not easily fitted

into the model. These deviations may reveal local differences due to subsidence fluctuations , differences in basin physiography , etc . such departures should be expected , and will allow greater detail to be added to the model. 181

CHAPTER 6

SUMMARY AND CONCLUSIONS

1. The late Middle Cambrian age Maryville Limestone of the Conasauga Group within the study near Powell and Oak

Ridge , Tennessee represent deposition that occurred at the transition between a carbonate ramp and a shale-dominated intrashelf basin.

2. In the study area, a total of nearly 330 m of section were measured and described at three localities ,

(Clinton Highway , Joy 2, and GW 129) . Although the base of the section is covered at the Clinton Highway section near

Powell, approximately 77 .24 m of section were measured .

Toward the west and southwest in the vicinity of Oak Ridge complete sections of the Maryville were measured and described . These sections include the Joy 2 (142 . 485 m) and

GW 129 (107 .23 m) drill cores .

3. Detailed stratigraphic and petrologic analysis of the three localities revealed that 12 lithologies can be recognized in the Maryville within the study area . These lithologies have been grouped into two "broad" interrelated environments, a shallow-ramp zone where sediment was mainly 182

deposited near or below fairweather wave-base and a

deeper-ramp and intrashelf basin zone in which deposition

occurred below mean storm wave-base . The type and

character of sedimentation within this area on the ramp was

governed by off-ramp transport of carbonate sediment winnowed by winds , waves , and storm activity in more upramp

positions .

4. Limestone-clast conglomerate beds are a common

feature within the stratigraphic sections examined, in some

instances comprising nearly 20 % of a stratigraphic

section . Based on field and petrographic evidence Maryville conglomerate beds are thought to owe their origin to two

related end-member processes , storms and mass-sediment-gravity movement . In general, conglomerate beds of storm origin occur in shallower positions on the ramp , whereas those of debris-flow origin occur in deeper , more basinward positions . Because of the absence of obvious slump features, it is probable that debris-flow derived conglomerate beds had a more complex origin. Limestone clasts originated on the ramp in shallow positions as semi-lithified sediment , were eroded by storms , and transported downramp . Oversteepening of the sediment pile due to periods of increased sedimentation or liquefaction by fairweather wave- or storm-currents initiated failure and , hence , mass movement . 183

5. Comparison of lithologic thicknesses among the

three Maryville sections reveals an increase in

deeper-water , shale-rich lithologies toward the west and

southwest (Joy 2 and GW 129). Conversely, shallower-water

lithologies are more dominant toward the northeast (Clinton

Highway ). Progradational patterns reflecting the

influence of shallow-water carbonate environments , which

extended westward and southwestward into the

shale-dominated intrashelf basin , are best developed at

Clinton Highway . Evidence of progradational outbuilding of

the carbonate ramp is rarely , if ever , distinguishable in

the more western and southwestern localities toward the

basin. Progradational/retrogradational pairs are

asymmetric , with the retrogradational phase being less

thick than its progradational counterpart . Progradation was

superimposed upon a overall transgressive sequence and may

have been triggered by a standstill in regional sea-level

and/or a lull in subsidence .

6. Modified Markov-chain analysis applied to the

lithologic transitions recorded at the three localities

reveals the almost complete absence of a statistically

verifiable cyc lic pattern . Where cycles do exist they are both rare and subtle . This is to be expected because many

of the lithologies recognized within the Maryville are 184 directly or indirectly related to storm processes . Coupled with the fact that carbonate depositional environments are heterogenous in their aerial extent , it is unlikely that statistically strong evidence for cyclicity should exist .

7. Further work in east Tennessee may reveal lithologic sequences not easily fitted into the depositional model proposed here . These deviations may be due to local subsidence fluctuations or differences in basin physiography . Such departures from the model are indeed we lcomed and should add important detail in the establishment of a regional paleoenvironmental framework for the Maryville . Study of Maryville strata in areas further to the southeast of the study area (e.g. ,

Saltville , Knoxvi lle , Chestuee , and Dumplin Valley thrust sheets) is needed in order to determine the southern extent of the carbonate platform during Maryville time . . ·- ·..,_.:;:_JI'

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DESCRIPTION OF STRATIGRAPHIC SECTIONS

' 205

MEASUREMENT CONVENTIONS

Bed thicknesses used in the descriptions of the measured sections follows those used by McKee and Weir

(1953) and are supplemented by Weir (1953). Grain size descriptions are based on the standardized terminology of

Wentworth (1922) .

Bed Thickness

Very thick-bedded ...... 1.0 m

Thick-bedded ...... 0.3-1 .0 m

Medi'Ulll-bedded ...•••.....•••...... •...•... 0.1-0.3 m

Thin-bedded ...... 0.03-0.1 m

Very thin-bedded •....•••.....•••....••••... 0.01-0 .03 m

Laminated ...... 0.003-0.01 m

Thinly laminated . . • • . . . . . • . • . . . . • . • • ...... • • • . . • 0. 003 m

Grain Size

Coarse-grained grains visible to the unaided eye and readily identifiable (approx.>l.O mm) Medium-grained grains visible only with hand lens (approx . 0.25-1.0 mm)

Fine-grained •....• grains visible only with hand lens (approx . 0.10-0.25 mm) Very fine-grained . grains not visible even with hand lens (approx . < 0.25 mm) 206

CLINTON HIGHWAY SECTION AND SAMPLES

Outcrop is located on the northeast side of Clinton Highway between Stradler Road (Brushy Valley Road ) and the bridge over Bull Run Creek . Lower formational contact with the Rutledge Limestone is covered . Measurements are in meters and begin at the first observable intraclastic unit . Strike = N 35 E and Dip = 24 SE . Thin-sectioned samples are underlined .

CUM . UNIT THKN . THKN . DESCRIPTION

A 2.8 2.8 LIMESTONE , Medium-bedded intraclastic grainstone and oolitic packstone/grainstone ; medium-bedded ; weathers orange-brown ; coarse-grained ; poorly to moderately exposed; clasts are dominantly planar to cross-laminated ; clasts range in length 2-5 em ; clasts are randomly oriented ; most clasts appear to be well rounded ; thin-bedded mudstone interbedded with intraclastic grainstone at top of the unit ; contacts sharp . SAMPLES : A-1, 0.0 m; A-2 , 0.20 m; A-3, 2.0 m; A- 4, 2.40 m; A-5, 2.70m.

B 2.2 5.0 CALCAREOUS SILTSTONE AND SHALE , Thin-bedded calcareous siltstone and shale ; medium gray; weathers brown ; poorly to moderately exposed ; some beds show planar-laminations as well as low-angle cross-laminations and microhummocky cross-laminations ; rare beds show transition from planar to climbing wave-ripp les ; tracks and trails ; contacts sharp ; upper contact is denoted by a medium-bedded intraclastic grainstone . SAMPLES : B-1, 3.40 m; B-2, 3.90 m.

c 1.5 6.5 LIMESTONE AND SHALE , Medium-bedded intraclastic grainstone at base of the unit ; medium gray , weathers 207

brown ; moderately to well exposed ; clasts are randomly oriented ; most clasts planar to low-angle cross-laminated; upper part of the unit consists of interbedded nodular lime mudstone and calcareous shale, thin-bedded ; medium gray ; weathers brown ; moderately to well exposed ; tracks and trails ; top of the unit is marked by massive intraclastic grainstone ; contacts sharp. SAMPLES C-1, 5.10 m; C-2, 5.35 m; C-3, 6.05 m

D 8.4 14.9 LIMESTONE AND CALCAREOUS SILTSTONE , Base is a thick-bedded intraclastic grainstone ; medium gray ; moderately to well exposed ; clast are randomly oriented ; ooids (?) at the top of the bed ; remainder of the unit consists of interbedded calcareous siltstone and shale and medium-bedded intraclastic grainstone ; siltstone beds are thin-bedded; planar to low-angle cross-laminated ; rare wavy-laminated packstone/grainstone and lime mudstone interbeds ; clasts within intraclastic grainstone are planar to cross-laminated ; some clasts project above bedding surface ; well to moderately exposed ; tracks and trails are apparent on the upper surfaces of most thin-bedded siltstone interbeds ; top of the unit is marked by a thick-bedded intraclastic grainstone (unit E) ; contact sharp . SAMPLES D-1, 6.50 m; D-2, 7.50 m; D-3, 8.10 m; D-4, 10.80 m; D-5, 10.85 m; D-6 , 10.90 m; D-7 , 12.0 m; D-8, 12.30 m; D-9 13.25 m; D-10, 13.50 m; D-11, 13.90 m; D-12, 14.90 m.

E 2.7 17 .6 LIMESTONE AND CALCAREOUS SILTSTONE AND SHALE , Base is a medium-bedded intraclastic grainstone ; medium gray ; weathers orange-brown ; most clasts appear to be planar to cross-laminated; clast are oriented 208

parallel-to-subparallel to bedding ; randomly oriented clasts; some intrac lastic beds are lense-shaped , remainder of the unit divided into two subunits ; the lower subunit is a thin-bedded nodular wackestone/mudstone and interbedded shale ; medium gray ; limestone nodules exhibit planar-laminae ; lower contact with underlying intraclastic grainstone is sharp and is marked by a 1 to 3 em thick shale ; contact with the upper subunit is sharp ; upper subunit is a interbedded calcareous siltstone and shale ; rare intraclastic grainstone interbeds ; calcareous thin-bedded ; occasionally wavy bedded; planar and low-angle cross-laminations ; rare undulatory laminations ; abundant tracks and trails ; possible scour ; sole marks ; shales range from few mm to 2 em in thickness ; intraclastic grainstones are medium-bedded ; medium gray ; clast are oriented parallel to subparallel to bedding ; randomly oriented clasts ; clast planar to low-angle cross-laminated ; moderately to well exposed ; contact with the overlying unit is sharp . SAMPLES (*note numbers are not in numerical order ) E-1, 15.0 m; E-6, 15.10 m; E-2, 15. 35 m; E-7 , 15.50 m; E-B(also E-3 ), 15.80 m; E-4, 16.0 m; E-9, 16 .10 m; E-12 , 16 .90 m; E-13, 17 .30 m; E-5, 17 . 50 m

F 0.65 18.25 LIMESTONE Medium- to thick-bedded oolitic grainstone , medium gray ; weathers orange-brown , subtle cross-bedding ; small (1-2 em ) clasts appear within the oolitic grainstone ; rare , laminated siltstone interbeds ; no apparent tracks and trails ; differing lithologies are separated by a very "l thin shale (few mm to 1 em ) ; moderately exposed ; contacts sharp ; upper contact marked by thin-bedded 209

shale . SAMPLES F-1 , 18.10 m; F-2, 18.0 m; F-3, 17 .80 m; F-4� 17 .65 m

G 3.90 22 .15 LIMESTONE AND CALCAREOUS SILTSTONE AND SHALE Base of the unit (approximately 1.0 m) is poorly exposed; lower half of the unit is a thin-bedded calcareous siltstone and interbedded shale ; medium gray , weathers orange-brown ; planar to low-angle cross-laminations ; planar upper surfaces and scoured bases ; rare highly-abraded fossil debris; tracks and trails ; thin-bedded intraclastic grainstone interbeds ; clasts are parallel to randomly oriented ; upper half of the unit intraclastic beds become thicker and are interbedded with planar to low-angle cross-laminated calcareous siltstone and shale ; intraclastic beds are commonly discontinuous and may be lense- or channel-shaped ; moderate exposure ; contacts sharp ; upper contact is marked by a moderately thick silty shale interval. SAMPLES G-1 , 18.30 m; G-2 , 18 .70 m; G-3 , 19. 10 m; G-4, 19.80 rn; G-5 , 20.10 m; G-6, 20 .30 rn; G-7 20. 55 m; G-8, 20.80 rn; G-9 , 21. 95 m

H 5.35 27 .50 LIMESTONE AND CALCAREOUS SILTSTONE AND SHALE Unit H is similar to underlying ; differentiated by higher shale content , particularly at upper margin ; Base of the unit is a sequence of thin-bedded calcareous siltstone and interbedded shale ; medium gray ; weathers orange-brown ; planar to low-angle cross-laminated ; tracks and trails ; remainder of the unit is interbedded thin-bedded calcareous siltstones and shales ; medium-bedded intraclastic grainstone interbeds ; clasts are planar to cross laminated; clast are dominantly oriented parallel to subparallel to bedding ; rare , 210

discontinuous thin-bedded intraclastic beds ; planar to cross-laminated calcareous siltstone show evidence of scour and are wavy bedded ; moderate exposure ; sharp contacts . SAMPLES H-1, 22.70 m; H-2, 22.80 m; H-3, 23.0 m; H-4, 23.55 m; H-5, 23.80 m; H-6, 25.40 m; H-7 , 25.75 m; H-8, 26.05 m; H-9, 26.35 m; H-10, 26.65 m; H-11, 26.70 m; H-12, 27 .0 m; H-13, 27 .15 m

I 2.80 30. 30 LIMESTONE AND SILTY LIMESTONE AND SHALE Base of the unit is a 25.4 em thick calcareous shale subunit; above is a medium-bedded intrac lastic grainstone ; uneven bedding ; discontinuous in part ; medium gray ; clasts are parallel to randomly oriented ; polymictic clast associations ; some clasts appear to sit on top of the bed and do not project into the overlying bed ; remainder of the unit is a medium­ to thin-bedded argillaceous peloidal packstone/grainstone , rare calcareous siltstones , medium-bedded intraclastic grainstone interbeds ; medium gray , weathers tan; microhummocky cross-laminations ; wave-ripp le laminations ; tracks and trails ; top of the unit is a thick interval of thick-bedded intraclastic grainstone and thin- to very thin-bedded , wavy-laminated, calcareous siltstone ; clasts are parallel to subparallel oriented; fanned and randomly oriented clasts at top of the interval ; clasts 5-10 em in length ; lense-shaped intrac lastic bed at top ; moderately to we ll exposed ; contacts sharp . SAMPLES I-1 , 27 .7 m; I-2, 27 .9 m; I-3, 28 .2 m; I-4, 28.3 m; I-5, 28.55 �; I-6, 28 .75 m; I-7, 29.05 m; I-9, 29 .65 m

J 3.50 33.80 LIMESTONE Massive, medium- to thick-bedded oncolitic packstone and 211

interbedded wackestone/mudstone ; medium gray ; bands of dolostone (wackestone/mudstone ) weather orange-brown ; abundant oncoids ; oncoids are dolomitized ; common ; Renalcis occurs as small clusters ; common in the upper part of the unit; planar laminations are present within the wackestone/mudstone interbeds ; laminae disrupted by vertical burrows ; well exposed; contacts sharp . SAMPLES J-1, 31.0 m; J-2, 32.0 5 m; J-3, 33.25 m; J-4, 33.5 m

K 3.30 37 .10 SILTY LIMESTONE AND SHALE Thin to very thin-bedded argillaceous peloidal packstone/grainstone and interbedded shale ; medium gray ; weathers brown ; planar and low-angle cross-laminations , wave-ripple laminations ; evidence of scour ; micro-convolutions ; loading ; vertical burrows ; loading ; small-scale dishing( ?); tracks and trails ; contact with the underlying unit is a 10 em calcareous shale subunit ; upper contact with overlying unit is gradational and is a nodular wackestone /mudstone and a very thin, discontinuous oolitic layer . moderately to well exposed . SAMPLES K-b, 34.20 m; K-1, 34.55 m; K-2, 34.85 m; K-3, 36.6 m; K-4, 36.9 m

L 2.15 39.25 LIMESTONE AND SHALE Thin-bedded nodular wackestone/mudstone and interbedded shale ; beds thicker bedded toward the top of the unit; medium gray ; weathers brown ; planar , wavy , and possible wave-ripple laminations ; tracks and trails ; moderately to well exposed; lower and upper contacts are gradational and are marked by a thin, oolitic layer and a thin-bedded intraclastic bed , respectively . SAMPLES L-1, 37.3 m; L-2, 37 .55 m; L- 3, 38.70 m; 212

L-4 39 .0 m

M 2.55 41 .80 LIMESTONE AND CALCAREOUS SILTSTONE AND SHALE Thin- to medium-bedded calcareous siltstone and shale ; medium-bedded intraclastic grainstone interbeds , intraclastic beds thicker-bedded (.25 to .30 m) and more common toward the top of the unit; calcareous siltstone beds medium gray; weathered orange-brown ; planar , low-angle , undulatory , and microhummocky cross-laminations ; some individual beds show a transition from conglomerate to planar to microhummocky laminated lithologies, particularly at the base ; tracks and trails ; intrac lastic beds show polymictic clast associations and have planar bases and hummocky tops ; clasts larger toward the top of the unit; clasts slightly more imbricated toward the top of the unit , whereas before they were oriented parallel to subparallel to bedding ; top of the unit is a intraclastic bed capped by a .10 to .20 m oolitic grainstone ; clasts project into the overlying oolite ; lower contact gradational, upper contact sharp ; moderately to well exposed . SAMPLES M-1, 39.4 m; M-2, 40.35 m; M-3, 41 . 70m

N 1.50 43.30 CALCAREOUS SILTSTONE AND SHALE Very thin- to thin-bedded calcareous siltstone and shale ; thicker bedded and more carbonate-rich toward the top of the unit ; gray; planar , wavy , and low-angle cross-laminations ; tracks and trails ; lower contact is sharp and is marked by a calcareous shale ; upper contact is sharp and is marked by a .10-.20 m thick intraclastic grainstone bed (unit O) ; moderately to well exposed.

SAMPLES N-1 , 43.15 m 213

0 1.20 44.50 LIMESTONE AND SILTY LIMESTONE AND SHALE Thin-bedded intraclastic grainstone and interbedded calcareous siltstone and shale ; lower 0.55 m of the unit is a sequence of intraclastic grainstone , thin-bedded oolitic grainstone , and argillaceous peloidal packstone/grainstone ; medium gray , clasts oriented parallel to subparallel to bedding ; beds become thinner bedded and more shale-rich toward top of the unit; toward top of the unit limestone beds exhibit a nodular appearance; moderately to well exposed; contacts sharp . SAMPLES 0-1, 43.40 m; 0-2, 43.70 m; o-3, 44 .25 m p 2.95 47 .45 LIMESTONE AND SHALE Medium- to thin-bedded peloidal packstone /grainstone interbedded with shale ; intraclastic beds interbedded throughout ; at base of unit occurs an intraclastic grainstone bed with an oolitic grainstone cap ; gray ; limestone beds planar to low-angle cross-laminations ; rare , thin bedded oolitic grainstone interlayers ; rare oncoids ; hardgrounds (?); tracks and trails ; unit thinner-bedded toward the top ; moderately to well exposed ; contacts sharp . SAMPLES P-1 , 44 .80 ffi; P-2, 45 .00 m; P-3, 45.15 m; P-4 , 45.20 m; P-5, 46.20 m; P-6 , 46.80 m; P-8, 47 .45 m

Q 1.35 48.88 LIMESTONE Lower part of unit contains medium- to thin-bedded oncolitic packstone/grainstone beds ; remainder of unit is intrac lastic grainstone and interbedded laminated to low-angle , cross-laminated peloidal packstone/grainstone ; rare , wackestone interbeds (unit is very heterogeneous lithologically ); medium gray ; weathers orange-brown ; 214

tracks and trails ; moderately to well exposed ; contact·s sharp . SAMPLES Q-1 , 47 .41 m; Q-2, 48.05 m; Q-3, 48.60 m

R 0.85 49.65 LIMESTONE AND SHALE Thin to very thin , wavy-bedded peloidal packstone/grainstone and interbedded shale ; planar and rare wave-ripp le laminations ; rare low-angle, cross-laminations ; some beds show evidence of grading ; tracks and trails ; moderately to we ll exposed ; contacts sharp . SAMPLES R-1 , 49 .35 m s 1.45 51.10 LIMESTONE AND SHALE Medium-bedded, rare , oncolitic packstone/grainstone beds ; dominantly medium-bedded intraclastic grainstone interbedded with silty peloidal packstone and shale ; gray ; clasts oriented parallel to subparallel to bedding ; beds thinner bedded toward the top of the unit; planar-laminated peloidal packstone more dominant toward the top of the unit and more silt-rich ; tracks and trails ; moderately to well exposed ; contact with the lower unit is sharp, whereas contact with overlying unit is gradational; unit complicated by minor faulting . SAMPLES S-1 , 49.90

�; �-2, 50.30 m; S - 3, 50 .40 m; S-4 , 50.85 m

T 11 .95 63.05 LIMESTONE AND CLACLAREOUS SILTSTONE AND SHALE Lower one third of the unit dominated by thin- to medium-bedded calcareous siltstone and interbedded shale ; gray ; weathers orange-brown ; moderately to we ll exposed ; irregular bedding ; planar to wavy laminations ; tracks and trails ; thin shale partings separate beds ; interbedded , but less dominant , are medium bedded intraclastic grainstone beds ; clasts parallel to randomly oriented ; some 215

clasts project into overlying beds ; intraclastic beds much thicker half-way through the unit; thin-bedded oolitic and skeletal packstone interbeds occur in the upper half of the unit; lower contact gradational and noted by medium-bedded , planar laminated calcareous siltstone ; upper contact sharp and is noted by a medium-bedded intraclastic grainstone bed with a hummocky upper contact. SAMPLES T-1, 51 .40 m; T-2, 52.30 m; T-3, 52.40 m; T-4, 52 .65 m; T- 5, 53.75 m; T-6, 55 .00 m; T-7 , 55 .50 m; T-8 58 .10 m; T-9, 58.20 m; T-10, 58.30 m; T-11, 58 .40 m; T-12, 58.80 m; T-13, 58.95 m; T-14, 59 .75 m; T-15, 59 .87 m; T-16, 60.35 m; T- 17 , 61.15 m; T-18, 62.08 m u 0.49 63.54 LIMESTONE Thin-bedded wackestone /mudstone ; light gray ; stylolites common ; planar laminations ; possible wave-ripple laminations ; nodular in appearance ; vertical burrows ; scattered skeletal debris ; underlying contact undulatory ; upper contact sharp; moderate exposure . SAMPLES U-1, 63 .20 m; U-2, 63.40 m v 0.43 63.97 LIMESTONE AND CALCAREOUS SILTSTONE Base of the unit is a thin-bedded , wavy to planar-laminated calcareous siltstone ; gray ; weathers orange -brown ; track and trails ; remainder of unit is an intraclastic grainstone ; most clasts planar-laminated ; clasts are highly disorganized; some clasts are imbricated ; polymictic clast associations ; intraclastic beds vary in thickness laterally ; moderate exposure ; lower contact planar ; upper contact undulatory. SAMPLES None 216 w 0.65 64 .62 LIMESTONE Very thin- to thin-bedded wackestone /mudstone ; irregular bedding ; nodular appearance; stylolites common; gray ; planar- to wavy-laminations ; minor scattered ske letal debris ; vertical burrows ; rare , burrow mottling ; beds thicker bedded toward the top of the unit lower contact undulatory ; upper contact sharp ; moderately to well exposed , similar to unit u. SAMPLES W-1, 64 .00 m; W-2, 64.40 m

X 2.95 67 .57 LIMESTONE AND CALCAREOUS SILTSTONE AND SHALE Very thin- to thin-bedded calcareous siltstone and shale ; thin- to medium-bedded intraclastic grainstone interbeds ; intraclastic grainstone beds thicker bedded toward top of the unit; rare , argillaceous peloidal packstone/grainstone interbeds ; gray ; calcareous siltstone beds contain planar to low-angle cross-laminations ; microhummocky cross-laminations ; rare evidence of scour , sole marks ; tracks and trails ; polymictic clast associations ; clast oriented parallel to random ; thin shale interval approx . 0.95 m from base of the unit ; moderate exposure ; upper and lower contacts are sharp . SAMPLES X-1, 64 .70 m; X-2, 64 .82 m; X-3, 65 .12 m; X-4, 65.62 m; X-5, 65 .97; X-6; 67 .02 m y 1.98 69 .55 LIMESTONE AND CALCAREOUS SILTSTONE AND SHALE Interbedded medium- to thick-bedded intrac lastic grainstone and thin-bedded calcareous siltstone and shale ; moderately exposed ; polymictic clast associations ; clasts dominantly parallel to subparallel oriented to bedding ; few randomly oriented clasts occur ; siltstone display planar- to low-angle cross-laminations ; tracks and trails ; sole marks ; oo litic 217

grainstone cap occurs approximately 1/2 to 2/3 of the way through unit; top of the unit is noted by a sequence of thin- to medium-bedded calcareous siltstone and shale ; moderate exposure; contacts sharp . SAMPLES Y-1, 67 .92 m; Y-2, 68.47 m; Y-3 , 68.57 m; Y-4, 68.82 m z 3.05 72.60 LIMESTONE Thin- to medium-bedded intraclastic grainstone , oncolitic packstone , and wackestone/mudstone ; massive appearance ; base of the unit noted by intraclastic grainstone ; clasts are dominantly oriented parallel to subparallel to bedding , randomly oriented varieties also occur ; intraclastic beds less abundant to nonexistent in the remainder of unit ; remainder of unit is an oncolitic packstone and wackestone/mudstone ; oncoids are preferentially dolomitized imparting an orange-brown appearance ; scattered skeletal debris ; vertical burrows ; rare , burrow mottling ; toward the top unit beds become thinner bedded ; rare planar-laminations ; stylolites common; moderately to well exposed ; lower contact sharp ; upper contact gradational . SAMPLES Z-1, 69 .60 m; Z-2; 70.05 m; Z-3 , 70.55 m; Z-4, 70.70 m; z-5, 71.40 m; Z-6, 72.05 m; Z-7 , 72.50 m

AA 2.78 75.38 LIMESTONE AND CALCAREOUS SILTSTONE Lower part of the unit is a thin-bedded wackestone/mudstone and thin- to medium-bedded intraclastic grainstone ; gray ; wackestone/mudstone contains planar-laminations and scattered skeletal debris ; burrows ; clasts are parallel to randomly oriented ; remainder of unit is a thin- to medium-bedded , calcareous siltstone and interbedded intraclastic grainstone ; siltstone contains 218

planar- laminations and low-angle cross-laminations ; glauconite ; tracks and trails; moderate exposure ; contacts sharp. SAMPLES AA-1, 72.70 m; AA-2, 72.85 m; AA-3, 73.00; AA-4, 73.40 m; AA- 5, 73.70 m; AA-6, 73 .85 m; AA-7, 73.95 m; AA7-1, 74 .00 m; AA-8, 74.61 m; AA-9, 75.08 m

BB 0.72 76.10 LIMESTONE Medium- to thick-bedded wackestone/mudstone and rare oncolitic packstone ; gray ; wackestone contains skeletal interlayers; rare , burrow mottling ; oncoids are preferentially dolomitized ; unit capped by intraclastic grainstone bed ; clasts are dominantly oriented parallel to subparallel to bedding ; stylolites common; poor to moderate exposure ; contacts sharp . SAMPLES BB-1, 75.42 m; BB- 2, 76 .10 m

cc 0.87 76 .97 CALCAREOUS SILTSTONE AND SHALE Very thin- to thin-bedded calcareous siltstone and interbedded shale ; gray ; weathers orange-brown ; planar­ and wavy-laminations ; tracks and trails ; poorly exposed ; contacts sharp . SAMPLES None

DD 0.27 77 .24 LIMESTONE Massive , thin- to medium-bedded wackestone/mudstone ; gray ; subtle planar-laminations ; rare skeletal interlayers ; burrowing(?); stylobreccia (?); stylolites common ; unit capped by intraclastic grainstone bed ; clasts oriented parallel to subparallel to bedding ; moderately to poorly exposed ; contacts sharp . SAMPLES None

NOLICHUCKY SHALE 219

ORNL JOY 2

Subsurface drill core (ORNL Joy 2) located east of the Anderson-Roane County line , approximately 5 km southwest of the ORNL plant site and 15 km southwest of the city of Oak Ridge , Tennessee (currently located at Oak Ridge National Laboratories) . Joy 2 locality approximately 20 km southwest of the Clinton Highway locality along structural strike . The borehole was collared on the crest of Copper Ridge . The abbreviation TS refers to thin-sections housed at ORNL (Block# =cumulative drill core depth in feet) . Measurements are in centimeters

CUM . UNIT THKN . THKN . DESCRIPTION

1 191.0 191.0 SHALE AND LIMESTONE Shale with rare discontinuous 1-2 em carbonate interlayers at base of section ; limestone interlayers have planar­ to undulatory-laminations ; rare skeletal layers , particularly at the base of carbonate layers ; shale black; in middle of unit carbonate layers more common ; planar- to low-angle cross-laminated packstone/grainstone interbedded with shale ; rare intraclasts ; glauconite abundant; scattered skeletal debris; more shale-rich towards top of unit . BLOCK 1475

2 117.0 308.0 SHALE Shale ; black to maroon .

3 51 .0 359.0 SHALE AND LIMESTONE Green/gray shale interbedded with planar- to low-angle cross-laminated packstone/grainstone ; glauconite ; top of unit shale more dominant ; limestone interlayers are discontinuous ; shale black to maroon .

4 46.0 405.0 LIMESTONE AND SHALE Planar-laminated "massive" peloidal/fossiliferous packstone/grainstone interbedded with shale ; abundant trilobites ; very fine- to coarse-grained . BLOCK 1470; TS-1470 220

5 93.0 498.0 SHALE Shale interbedded with rare , discontinuous planar-laminated limestone interlayers ; shale maroon to gray ; very fine- to medium-grained .

6 51.0 549.0 SHALE AND LIMESTONE Planar- to low-angle cross-laminated packstone/grainstone interbedded with shale , lower 17 .0 em ; shale green/gray ; fining-upward sequences common ; limestone interlayers commonly discontinuous ; more shale-rich in upper 34.0 em ; shale gray/green to maroon .

7 40.0 589.0 SHALE Rare , planar-laminated limestone interlayers ; shale maroon .

8 29.0 618.0 SHALE AND LIMESTONE Shale interbedded with limestone ; discontinuous packstone/grainstone interlayers; fining-upward sequences common ; shale green/gray ; very fine­ to medium-grained . TS-1463 .5

9 64.0 682.0 SHALE Featureless , gray to maroon ; very fine- to fine-grained .

10 72.0 754.0 SHALE AND LIMESTONE Shale with interbedded laminated to low-angle cross-laminated packstone/grainstone ; limestone interlayers more dominant towards top of unit ; limestone layers discontinuous and appear to pinch and swell; loading ; rare , skeletal interlayers; glauconite ; shale black to maroon ; very fine- to medium-grained . BLOCK 1460 , TS-1460; TS-1459.5

11 35.0 789.0 SHALE Rare , discontinuous , laminated to low-angle cross-laminated packstone/grainstone interlayers ; shale maroon to black; very fine-to fine-grained.

12 716.5 1505.5 SHALE AND LIMESTONE Sha le interbedded with planar- to 221

low-angle cross-laminated packstone/grainstone ; limestone more dominant in lower 46 .0 em · of unit; upper 6-7 m of unit shale more dominant ; limestone layers discontinuous ; fining-upward sequences common ; rare , thin intraclastic beds ; gluaconite ; shale gray/black ; fine- to medium-grained . BLOCK 1453 , 1443, 1434; TS- 1447 .5, TS-1446, TS-1435

13 22.0 1527 .5 SILTY LIMESTONE Planar- to low-angle cross-laminated siltstone ; shale partings ; loading ; glauconite ; brown-gray , fine- to medium-grained .

14 352.0 1879.5 SHALE AND LIMESTONE Shale interbedded with planar- to low-angle cross-laminated packstone/grainstone ; limestone layers discontinuous ; loading ; glauconite ; shale black/green; very fine- to medium-grained. BLOCK 1424; TS-1430, TS-1423, TS-1419

15 40.5 1920 .0 LIMESTONE Oolitic packstone/grainstone ; stylolites common ; irregular upper bedding surface ; thin shale drapes ; scoured base ; hardgrounds (?); intraclasts at base ; random clast orientation; abundant glauconite ; shale green/gray ; medium- to coarse-grained.

16 101.0 2021.0 LIMESTONE AND SHALE Interbedded intraclastic packstone /grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts are subparallel to randomly oriented to bedding ; clast may project above bedding ; clast range from 2.0 to 9.5 em in length ; coarse-grained and mud matrix within intraclastic beds ; planar- to low-angle cross-laminated interlayers discontinuous; irregular tops ; planar bases ; fining-upward sequences common; loading ; glauconite ; burrows . TS-1417 222

17 56 .0 2077.0 SHALE AND LIMESTONE Shale with rare planar- to low-angle cross-laminated packstone/grainstone ; limestone layers discontinuous ; very fine- to fine-grained ; shale black .

18 74.0 2151.0 LIMESTONE AND SHALE Interbedded intraclastic packstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel to bedding ; some clasts project above beds ; mud matrix within intraclastic beds ; monomictic; planar- to low-angle cross-laminated packstone/grainstone layers discontinuous ; rare mudstone interlayers ; burrows ; loading ; very fine- to coarse-grained . TS-1412.5

19 58 .0 2209 .0 SHALE Featureless ; dark gray to black ; very fine-grained

20 1101.0 3310.0 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clast oriented random to subparalle l to bedding ; dominantly coarse-grained skeletal matrix; subordinant mud matrix; monomictic and polymictic clast associations ; planar- to low-angle cross-laminated packstone/grainstone layers discontinuous ; loading ; possible convolute bedding ; fining-upward sequences common ; limestone layers have sharp bases and diffuse tops ; rarely limestone layers have sharp upper surfaces; glauconite ; rare , ske letal interlayers ; rare , coarsening-upward (?) sequences; very fine- to coarse-grained . BLOCKS 1405, 1395, 1385, 1375; TS-1405, TS-1405.5, TS-1401, TS-1395, TS-1392, TS-1386, TS-1383, TS-1375

21 61.0 337 1.0 SHALE Featureless; black , very fine-grained . TS- 1368.5 223

22 490.0 3861.0 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts subparallel to randomly oriented; dominantly coarse-grained skeletal matrix, mud matrix subordinant ; some clasts proj ect above the upper bedding surface ; shale commonly drapes projecting clasts ; polymictic clast associations ; intraclastic beds have planar bases and undulatory upper surfaces ; planar- and low-angle cross-laminated packstone/grainstone layers discontinuous ; sharp bases and diffuse tops ; rare evidence of scour ; loading; convolut ions ; burrowing ; rare skeletal interlayers ; limestone layers undulatory; shale black; very fine­ to coarse-grained. BLOCKS 1365; TS-1360

23 40 .0 3901 .0 LIMESTONE Oolitic packstone/grainstone ; abundant glauconite ; rare intraclasts ; medium-grained . TS-1353

24 179.0 4080 .0 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar to low-angle cross-laminated packstone/grainstone and shale ; clast oriented subparallel to parallel to bedding ; coarse-grained skeletal and mud matrix within conglomerate beds ; clast range from 2-4 em in length ; planar bases and undulatory tops ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; fining-upward sequences common ; planar bases , occasionally scoured ; loading , burrowing ; rare skeletal interlayers ; some limestone beds are nodular ; very fine- to coarse-grained . TS- 1349

25 15.0 4095.0 LIMESTONE Oolitic grainstone ; rare intraclasts ; peloids ; glauconite ; 224

lower surfaces planar ; upper surface undulatory ; medium- to coarse-grained .

26 429.0 4524.0 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers discontinuous ; rare wavy-laminations ; rare skeletal interlayers ; planar bases and diffuse tops ; loading ; burrows ; very fine- to medium-grained . BLOCK 1335, TS- 1342.5, TS-1338.5, TS-1332.5

27 44 .0 4568.0 SHALE Rare , planar- to low-angle cross-laminated packstone/grainstone ; very fine- to fine-grained .

28 1564.0 6132.0 LIMESTONE AND SHALE Interbedded intrac lastic packstone/grainstone and planar- to low-angle cross-laminated packstone /grainstone ; clasts oriented parallel to subparallel to bedding ; dominately coarse grained skeletal matrix; subordinant mud and shale matrix; clasts range from 1.0 to 6.0 em in length ; some clasts appear to sit on beds or project into overlying shale ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; rare fossiliferous interlayers ; planar bases and diffuse tops common ; planar bases and tops rare , loading ; burrowing ; very fine- to coarse-grained . BLOCKS 1315, 1304 , 1295; TS-1326 .0, TS-1322.5, TS- 1319.5, TS-1309 , TS-1306, TS-1303.5, TS- 1299, TS-1292.5, TS-1285.5, TS-1284 , TS- 1281 .5, TS-1280

29 40 .0 6172.0 SHALE Rare , thin discontinuous planar- to low-angle cross-laminated packstone/grainstone interlayers ; shale black ; very fine-grained . 225

30 582.0 6754 .0 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented random to subparallel to bedding ; some conglomerate beds show a coarsening-upward; clasts range from 1-6 em in length ; rarely clast project above upper bedding surface and into overlying shale ; dominantly coarse grained skeletal (oolitic? ) matrix; rare shale and mud matrix; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; some limestone layers are nodular in appearance ; loading ; planar bases and diffuse tops ; rare evidence of scour ; some limestone layers have planar bases and tops ; burrows ; very fine- to coarse-grained . BLOCKS 1268 ; TS-1275, TS- 1268 .5, TS-1265.5

31 380.5 7134.5 STRUCTURALLY COMPLEX BLOCK 1258, 1258.5, 1252; TS- 1250

32 720.0 7854 .5 LIMESTONE AND SHALE Interbedded intraclastic packstone /grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel to bedding ; rare random orientations ; dominantly monomictic and polymictic clast associations ; rare multigeneration clasts ; dominantly coarse-grained skeletal matrix ; rare lime mud and shale matrix; clast tabular in shape ; rarely clasts project into overlying beds ; clast range in size from 1-6 em in length ; planar- and low-angle cross-laminated packstone /grainstone layers commonly discontinuous ; planar bases and diffuse tops common ; rare evidence of scour ; rarely , upper surfaces sharp ; loading ; burrowing ; convolute laminations ; very fine- to coarse-grained. TS-1244, TS-1241, TS-1240, TS-1237 , TS-1234, TS-1232.5 226

33 107.0 7961.5 LIMESTONE Oolitic/oncolitic packstone ; upper portion of the unit is glauconite-rich; coarsening- and fining-upward sequences ; oncoids randomly disposed ; clasts randomly oriented ; rare mudstone interlayers ; oncoids and ooids dolomitized ; oncoids elongate in shape ; hardgrounds (?); trilobites; peloids ; medium- to coarse-grained . BLOCK 1224, TS-1224

34 51.0 8012.5 LIMESTONE AND SHALE Interbedded intrac lastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel to bedding ; coarse-grained skeletal matrix; clasts range in size from 1.0 3.0 em in length ; planar- and low-angle cross-laminated limestone interlayers continuous ; loading ; rare glauconite ; rare evidence of scour ; planar bases and diffuse tops common ; very fine- to coarse-grained .

35 43.0 8055.5 LIMESTONE Oolitic packstone ; rare shale drapes ; rare intraclasts, oo litic clasts ; rare oncoids ; peloids ; general coarsening-upward sequence ; planar base and irregular top ; medium- to coarse-grained .

36 844 .5 8900 .5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clast oriented parallel to subparallel to bedding ; rnonornictic and polymictic clasts associations ; some clast project into overlying bed ; dominantly coarse-grained skeletal matrix; subdorninant mud and shale matrix; clasts range from 1-5 ern in length ; irregular upper and lower surfaces ; planar- and low-angle cross-laminated packstone/grainstone 227

interlayers discontinuous ; planar bases and diffuse tops common ; loading ; burrowing ; rare evidence of scour ; very fine- to coarse-grained. BLOCKS 1214, 1205, 1195; TS-1215.5, TS-1212, TS- 1209.5, 1203, TS- 1197 , TS-1193.

37 39.5 8939 .5 LIMESTONE Oolitic packstone ; clasts at base ; coarsening-upward sequence; oncoids occur in upper portion of unit ; clasts rare in upper part of unit ; abundant glauconite ; hardgrounds (?); planar base and irregular upper surface ; upper surface scoured, in part; medium-grained.

38 87 .0 9026.5 SHALE Shale interbedded with rare planar- to low-angle cross-laminated peloidal packstone interlayers ; loading ; limestone interlayers discontinuous ; rare clasts; very fine- to coarse-grained . TS-1191.

39 553.0 9579 .5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented subparallel to parallel to bedding ; coarse-grained skeletal matrix ; minor shale matrix ; polymictic clasts associations ; clasts range from 1-5 ern in length ; planar- and low-angle cross-laminated packstone/grainstone interlayer often discontinuous ; loading ; burrows ; rare skeletal interlayers ; planar bases and diffuse tops ; pseudonodules ; undulatory laminations ; very fine­ to coarse-grained . BLOCK 1185; TS-1183.5, TS-1180.5, TS-1175

40 70.0 9649 .5 SHALE AND LIMESTONE Shale interbedded with rare , discontinuous planar- to low-angle cross-laminated packstone /grainstone interlayers ; burrows ; planar bases and diffuse tops ; evidence of scour ; limestone 228

interlayers more common in upper part of unit ; very fine- to fine­ grained. TS- 1168.5

41 455.0 10104.5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel to bedding ; coarse-grained ske letal matrix; clasts range from 1-7 em in length ; polymictic ; planar- and low-angle cross-laminated packstone/grainstone interlayers commonly discontinuous ; loading ; planar bases and diffuse tops common ; some limestone layers are nodular bedded ; rare skeletal interlayers ; rare evidence of scour ; very fine- to coarse-grained. BLOCKS 1165, 1158, 1154 ; TS-1164 , TS-1156 , TS-1153

42 63 .0 10167.5 SHALE AND LIMESTONE Shale interbedded with rare , discontinuous planar- to low-angle cross laminated packstone/grainstone ; limestone interlayers have scoured bases and diffuse tops ; loading common ; very fine- to fine-grained.

43 155.0 1145 .5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts parallel to subparalle l oriented; dominantly medium- to coarse-grained skeletal matrix; rare mud matrix ; clasts range in from 1-8 em in length ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; rare ske letal layers; loading common ; burrows ; very fine- to coarse-grained.

44 975 .0 11297 .5 STRUCTURALLY COMPLEX BLOCKS 1135, 1133, 1125, 1115; TS-1144, TS-1136, TS-1135, TS-1128 .5, TS-1126.5, TS-1122, TS- 1118, TS- 1116. 229

45 1060 .5 12358 .0 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts parallel to subparallel oriented ; dominantly medium- to coarse-grained skeletal matrix ; rare shale matrix; clasts range in from 1-6 em in length ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; rare skeletal interlayers ; undulatory laminations ; loading common; very fine- to coarse-grained. BLOCK 1105, TS-1108; TS-1105.5, TS-1098

46 20 .0 12378.0 SHALE Featureless , black

47 834.5 13212.5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone ; clasts oriented parallel to subparallel to bedding ; dominantly medium- to coarse-grained skeletal matrix; planar bases and irregular tops ; clast range from 1-5 em in length ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; planar bases and diffuse tops common ; loading common; pseudonodules ; burrows ; very fine- to coarse-grained . BLOCKS 1075, 1065, 1055, TS-1075, TS-1072, TS-1069, 1065,

48 20.5 13233.0 SHALE Featureless , black .

49 132.5 13365.5 LIMESTONE AND SHALE Interbedded intrac lastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel; clast range from 1-6 em in length; dominantly medium- to coarse-grained skeletal matrix ; rare shale matrix; clasts have dark 230

corroded borders ; sharp bases irregular tops ; planar- and low-angle cross laminated packstone grainstone layers discontinuous ; loading common ; sharp bases diffuse tops ; scour ; burrows ; unit shale-rich towards top ; very fine­ to coarse-grained . TS-1051, TS-1048

50 31.0 13396 .5 SHALE Featureless , black . TS-1047

51 222 .0 13618.5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel, clast range from 1-6 em in length ; medium- to coarse-grained skeletal matrix; planar bases and irregular tops ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; loading common; planar bases and diffuse tops ; very fine- to coarse-grained . BLOCK 1045; TS- 1044 .3.

52 40.0 13658.5 LIMESTONE AND SHALE Lime mudstone interbedded with shale ; limestone nodular bedded; sharp upper and lower surfaces; rare skeletal interlayers ; fine-grained. TS-1034.5

53 259.0 13917 .5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel; clast range from 1-5 em in length ; medium- to coarse-grained skeletal matrix; rare shale matrix; planar bases and irregular tops ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; loading common ; rare lime mudstone interlayers ; pseudonodules ; sharp bases diffuse tops ; very fine- to coarse-grained. TS-1037, TS-1034.5, TS-1033, TS-1030.5 231

54 31 .0 13948.5 STRUCTURALLY COMPLEX . TS- 1027 .5

55 171 .0 14119.5 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparalle l to bedding ; clast range from 1-6 em in length ; medium­ to coarse-grained skeletal matrix common ; rare shale matrix; planar bases and irregular tops ; planar­ and low-angle cross-laminated packstone /grainstone interlayers commonly discontinuous ; loading common ; rare pseudonodules ; sharp bases and diffuse tops common ; rare skeletal interlayers; very fine- to coarse-grained . BLOCK 1025

56 46.0 14165 .5 LIMESTONE Mudstone/wackestone ; rare shale partings ; shale-rich towards top of unit. fine-grained . TS-1020.

57 83.0 14248 .5 LIMESTONE AND SHALE Interbedded intrac lastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clast oriented parallel to subparallel ; clast range 1-5 em in length ; medium- to coarse-grained skeletal matrix common ; polymictic ; planar- and low-angle cross-laminated packstone/grainstone interlayers discontinuous ; loading common ; rare lime mudstone /wackestone interlayers ; glauconite common ; rare skeletal interlayers ; very fine- to coarse-grained . TS-1019

NOLICHUCKY SHALE 232

ORNL GW 129

Subsurface drill core (ORNL GW 129) located northeast of the Y-12 Plant , Scarboro Road . GW 129 is located within the Hunter Valley thrust sheet approximately 9 km northwest of the Joy 2 locality . Block #= cumulative drill core depth in feet. Measurements are in centimeters.

CUM . UNIT THKN . THKN . DESCRIPTION

1 126.84 126.84 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers discontinuous ; loading common; undulatory laminations ; sharp bases and diffuse tops ; rare skeletal inter layers ; very fine- to fine-grained.

2 40 .32 167 .16 LIMESTONE Oolitic packstone/grainstone ; thin shale drapes ; planar base and irregular top ; stylolites common ; medium-grained

3 43.68 210.84 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers discontinuous ; rare intraclastic bed ; loading common ; rare skeletal interlayers ; undulatory laminations ; sharp bases and diffuse tops common ; rare evidence of scour ; very fine- to fine-grained .

4 21 .0 231.84 LIMESTONE Oolitic packstone/grainstone ; thin shale drapes ; planar bases and irregular tops ; stylolites common ; medium-grained .

5 301 .56 533 .4 SHALE AND LIMESTONE Interbedded shale and planar­ to low-angle cross-laminated packstone/grainstone ; lime stone interlayers discontinuous ; loading common ; rare skeletal interlayers ; limestone layers have sharp bases 233

and diffuse tops ; very fine- to fine-grained .

6 105.84 639.24 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone layers discontinuous ; shale black; very fine- to fine-grained.

7 147.84 787 .08 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers discontinuous ; loading common; rare skeletal interlayers; sharp bases and diffuse tops ; very fine- to fine-grained .

8 94.08 881.16 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black; very fine- to fine-grained .

9 341 . 54 1222 .70 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers discontinuous ; loading common ; rare ske letal interlayers ; sharp bases and diffuse tops common ; very fine- to fine-grained .

10 178.08 1400.78 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black; very fine- to fine-grained .

11 281 .40 1682.18 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone ; lime stone interlayers commonly discontinuous; loading common rare skeletal interlayers ; sharp bases and diffuse tops common ; very fine- to fine-grained .

12 191.52 1873.70 SHALE AND LIMESTONE Interbedded 234

shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black; very fine- to fine-grained .

13 372.12 2245.82 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers commonly discontinuous ; loading common ; rare skeletal interlayers ; sharp bases and diffuse tops common ; very fine­ to fine-grained.

14 99 .96 2345.78 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black; very fine- to fine-grained .

15 379 .68 2725 .46 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers commonly discontinuous ; loading common ; rare skeletal interlayers ; sharp bases and diffuse tops common ; very fine­ to fine-grained .

16 73.92 2799 .38 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone /grainstone ; limestone interlayers discontinuous ; shale black ; very fine- to fine-grained .

17 54.60 2853 .98 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; lime stone interlayers discontinuous ; loading common ; rare skeletal interlayers ; sharp bases and diffuse tops common ; very fine- to fine-grained .

18 73.08 2927 .06 SHALE AND LIMESTONE Interbedded shale and rare planar­ to low-angle cross-laminated packstone /grainstone ; limestone 235

interlayers discontinuous ; shale black ; very fine- to fine�grained .

19 472 .92 3399 .98 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale; limestone interlayers commonly discontinuous ; rare intraclastic beds ; rare skeletal interlayers ; sharp bases and diffuse tops common ; very fine- to fine-grained .

20 577 .92 3977 .90 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black; very fine- to fine-grained .

21 51.24 4029.14 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers commonly discontinuous ; sharp bases and diffuse tops common ; loading common ; rare ske letal interlayers ; intraclastic bed at the base of the unit; clasts oriented parallel to subparallel to bedding ; clasts 1-5 em in length ; very fine­ to coarse-grained .

22 60.59 4089 .73 SHALE Featureless, black.

23 712.07 4801.80 LIMESTONE AND SHALE Interbedded planar- and low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers are commonly discontinuous ; sharp bases and diffuse tops common ; loading common ; rare skeletal interlayers; intraclastic beds interbedded at the base and the top of the unit ; clast oriented parallel to subparallel to bedding ; very fine- to coarse-grained .

24 149.81 4951 .61 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale 236

black; very fine- to fine-grained.

25 391.92 5343.53 LIMESTONE AND SHALE Interbedded planar- and low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers are commonly discontinuous sharp bases and diffuse tops common ; loading common ; rare skeletal interlayers ; very fine- to fine-grained .

26 537 .47 5881 .00 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black; very fine- to fine-grained.

27 643 .97 6524 .97 LIMESTONE AND SHALE Interbedded planar- and low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers are commonly discontinuous ; sharp bases and diffuse tops common ; loading common ; rare skeletal interlayers; intraclastic packstone/grainstone beds become more common towards the top of the unit ; clasts oriented parallel to subparallel to bedding ; medium- to coarse-grained skeletal matrix common ; shale and mud subordinate ; clasts 1-5 em in lenght ; very fine- to coarse-grained .

28 34.79 6559 .76 STRUCTURALLY COMPLEX

29 193.12 6752 .88 LIMESTONE AND SHALE Interbedded planar- and low-angle cross- laminated packstone/grainstone and shale ; limestone interlayers commonly discontinuous ; sharp bases and diffuse tops common ; loading common ; rare skeletal interlayers ; intrac lastic packstone/grainstone beds are becoming more common ; clasts oriented parallel to subparallel to bedding ; medium- to coarse-grained skeletal matrix common ; shale and lime mud ma trix subordinant ; clasts 1-5 em in 237

length; very fine- to coarse-grained .

30 77 .39 6830. 27 STRUCTURALLY COMPLEX

31 195.27 7025 .54 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clast oriented parallel to subparallel to bedding ; medium­ to coarse-grained skeletal matrix common ; shale and mud matrix subordinate ; clasts 1-5 em in length; planar to low-angle packstone/grainstone interlayers commonly discontinuous ; loading common ; sharp bases and diffuse tops common ; very fine- to coarse-grained .

32 53.96 7079.50 STRUCTURALLY COMPLEX

33 702 .76 7782 .26 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clast oriented parallel to subparallel to bedding ; medium­ and coarse-grained skeletal matrix common; shale and lime mud matrix subordinant ; clasts 1-5 em length ; planar to low-angle cross laminated packstone/grainstone interlayers commonly discontinuous ; loading common ; sharp bases and diffuse tops common ; very fine to coarse grained .

34 85.20 7867.46 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; lime stone interlayers discontinuous ; shale black ; very fine- to fine-grained .

35 75.26 7942.72 LIMESTONE AND SHALE Interbedded planar- to low-angle cross-laminated packstone/grainstone and shale ; limestone interlayers commonly discontinuous ; loading common ; sharp bases and diffuse tops common ; rare 238

skeletal interlayers ; intraclastic packstone/grainstone bed at the top of the unit ; clast oriented parallel to subparallel to bedding ; clasts 1-4 em ; medium- and coarse-grained ske letal matrix common ; very fine­ to coarse-grained .

36 150.52 8093 .24 STRUCTURALLY COMPLEX

37 190 .28 8283.52 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar­ to low-angle cross-laminated packstone/grainstone and shale ; clasts oriented parallel to subparallel to bedding ; medium- and coarse-grained skeletal matrix common ; planar and low-angle cross-laminated packstone/grainstone interlayers commonly discontinuous ; loading common ; sharp bases and diffuse tops common; rare skeletal interlayers ; very fine- to coarse-grained.

38 79.52 8363 .04 SHALE AND LIMESTONE Interbedded shale and rare planar- to low-angle cross-laminated packstone/grainstone ; limestone interlayers discontinuous ; shale black ; very fine- to fine-grained .

39 2360.30 10723 .34 LIMESTONE AND SHALE Interbedded intraclastic packstone/grainstone and planar- to low-angle cross-laminated packstone/grainstone and shale ; clast oriented parallel to subparallel to bedding; medium­ and coarse-grained skeletal matrix common; shale and lime mud matrix subordinate ; clasts 1-7 em in length ; planar- and low-angle cross-laminated packstone/grainstone interlayers commonly discontinuous ; loading common ; sharp bases and diffuse tops common ; rare skeletal interlayers ; very fine- to coarse-grained.

NOLICHUCKY SHALE APPENDIX B

PETROGRAPHIC CONSTITUENT ANALYSIS Table B.l. Petrographic constituent analysis of selected thin-section from the Maryville Limestone . . - - sampno stratpos ooids peloids intra one algal chanc tril ech sposp hyol dolom - fib/rad ·- - �. -·· ... -�--- ·------· ----- ·-·------·-· ·- . --·- -·- --- -·-· ------·------.A.-4 2.4 60 .00 2.00 3.00 0.00 2.00 o.oo o.oo o.oo o.oo o.oo 4.00 23 .00 .A. -) -4 2.45 44.00 o.oo 15.00 0.00 5.00 0.00 o.oo 0.25 o.oo o.oo 2.50 20 .25 3.9 B-2 o.oo o.oo o.oo 0.00 o.oo 0.00 o.oo o.oo o.oo o.oo o.oo 0.00 c-2 5.35 o.oo 6.25 o.oo o.oo 0.00 o.oo o.oo o.oo o.oo o.oo o.oo 0.00 0-10 13.5 o.oo 19.50 0.00 0.00 o.oo 0.00 o.oo 0.00 o.oo o.oo 0.00 o.oo E-2 15.35 o.oo 9.25 o.oo 0.00 0.00 0.00 0.25 0.00 o.oo o.oo 0.00 o.oo E-4 16 o.oo 14.50 o.oo 0.00 0.00 0.00 0.00 o.oo o.oo o.oo o.oo 0.00 F-4 17 .65 )1 .00 7.00 o.oo 0.00 0.25 2.00 0.25 1.00 0.25 o.oo 0.25 0.25 F-1 18 .1 60.00 o.oo o.oo 0.00 1.25 0.00 o.oo 3.00 o.oo o.oo 0.00 6.50 G 4 - 19 .8 o.oo 13.75 o.oo 0.00 o.oo 0.00 o.oo o.oo o.oo o.oo 19 .75 0.00 G-7 20 .55 0.00 o.oo o.oo 0.00 0.00 0.00 o.oo o.oo o.oo o.oo 0.00 o.oo G-7-1 20 .66 o.oo 63 .00 o.oo o.oo 0.00 o.oo o.oo o.oo o.oo o.oo 0.00 o.oo H-7 25.75 o.oo 29 .25 o.oo o.oo 0.00 0.00 0.50 0.75 o.oo o.oo o.oo o.oo H-9 26 .35 o.oo 16 .25 o.oo o.oo o.oo o.oo 0.50 o.oo o.oo o.oo o.oo 0.00 H- 13 27 .15 40.00 o.oo 21.00 0.00 0.00 0.00 2.00 9.00 o.oo o.oo 0.00 0.25 J-1 31 o.oo 5.00 o.oo 19.00 3.00 0.00 2.00 1.00 o.oo o.oo 0.25 0.25 I\) J-3 33 .25 o.oo 7.25 o.oo 24 .50 11.75 2.50 0.25 0.25 0.25 o.oo 9.50 29 .50 .j::o- 0 J-4 33 .5 14 .00 4.00 0.00 28 .00 7.00 2.00 1.50 2.50 o.oo o.oo 3.00 25.00 K-4 36.9 6.25 9.()0 o.oo o.oo 4.25 0.50 8.50 1.00 1.50 o.oo 5.00 o.oo L-2 37 .55 o.oo 15.50 o.oo o.oo 0.00 0.00 1.00 o.oo o.oo o.oo o.oo o.oo L-3 38.7 o.oo 26.75 o.oo 0.00 0.00 0.00 2.75 o.oo 1.00 o.oo o.oo 0.00 o-3 44.75 o.oo 36. 50 o.oo 0.00 0.00 0.00 o.oo o.oo o.oo o.oo o.oo 0.00 P-1 44 .8 49.00 2.00 o.oo 4.50 13.00 o.oo o.oo 0.25 o.oo o.oo o.oo 28.50 P-2 45 11.25 7.00 o.oo 9.00 6.75 0.00 0.25 0.25 0.50 o.oo 2.75 o.oo P-4 45 .2 20 .00 8.50 27 .00 0.50 4.00 1.00 3.00 3.50 0.25 o.oo o.oo 0.00 s-2 50 .3 o.oo 8.50 0.00 12.50 17 .50 2.50 8.00 6.50 o.oo o.oo 7.00 6.00 T-2 52 .3 2.25 25.00 6.25 1.00 6.00 0.25 2.25 7.50 o.oo o.oo 12.75 o.oo T-3 52.4 1.00 9.00 2.00 1.50 10.00 0.00 2.00 4.00 o.oo o.oo 22.00 0.00 T-11 58 .4 37 .25 17.00 0.00 o.oo 3.00 0.25 0.25 2.25 0.25 o.oo o.oo o.oo U-1 63.2 o.oo 0.00 o.oo o.oo o.oo 0.00 o.oo o.oo 0.25 o.oo o.oo o.oo U-2 63.4 o.oo 28.00 o.oo o.oo 0.00 0.00 5.00 2.00 o.oo o.oo o.oo 0.00 W- 1 64 o.oo 7.00 o.oo o.oo 0.00 0.00 o.oo o.oo o.oo o.oo o.oo o.oo Y- 4 65 .62 13.00 27 .00 5.00 0.50 10.00 0.00 3.00 7.00 0.50 o.oo a.oo o.oo Z-4-1 70.7 o.oo 15.00 o.oo 0.00 0.00 0.00 0.00 o.oo 1.00 o.oo o.oo o.oo Z-6 . 72.05 o.oo 13.00 0.00 17 .00 8.50 0.25 1.00 4.00 0.25 o.oo 4.00 o.oo Z-7 72 .5 o.oo 12 .00 o.oo o.oo 0.00 0.00 1.00 o.oo 0.25 o.oo o.oo o.oo AA- 7-1 74 o.oo 6.50 o.oo o.oo 2.00 1.00 8.00 25.00 o.oo 2.00 1.00 4.50 BB-1 75.42 o.oo 0.25 o.oo o.oo o.oo 0.00 0.00 o.oo 1.50 o.oo o.oo o.oo BB-2 76 .1 o.oo 3.00 o.oo o.oo o.oo 0.00 0.00 o.oo 1.00 o.oo o.oo o.oo Table B.l. (Continued ) . sampno stratpos pspar equant stylo qlauc qtzsil unident micrite echsyn Renal mollusk burrow inart .... -· - -- -· -·· --· -- --· ------.. ---· ·------· A-4 2.4 0.00 5.00 o.oo 0.00 0.25 3,00 0.00 o.oo o.oo 0.00 0.00 0.00 A- 4-3 2.45 0.00 5.00 0.00 o.oo 0.25 6.25 1.50 0.00 o.oo o.oo o.oo o.oo B-2 3.9 0.00 7.50 o.oo 3.00 89 .00 0.00 0.00 o.oo 0.00 0.00 0.00 1.00 C-2 5.35 0.00 o.oo 3.25 0.00 0.25 0.25 89.00 0.00 o.oo 0.00 0.50 0.50 0-10 13.5 0.00 o.oo 17 .25 0.25 33 .50 0.00 o.oo 0.00 o.oo o.oo 28.25 1.00 E-2 15.35 0.00 0.00 12.50 0.50 62 .25 0.00 10.50 0.00 0.00 0.00 4.50 0.25 E-4 16 0.00 0.00 19.00 0.00 45.75 1.00 15.50 0.00 o.oo 0.00 0.00 4.25 F-4 17 .65 20 .00 5 .00 6.00 o.oo 2.00 13.00 13.00 0.00 0.00 o.oo o.oo 0.00 F-1 18 .1 13.25 7.50 3.00 0.00 0.00 5.50 0.25 0.25 0.00 o.oo 0.00 0.00 G-4 19 .8 0.00 0.00 14.00 0.00 28 .50 0.00 24.00 o.oo 0.00 o.oo 0.00 o.oo G-7 20.55 0.00 0.00 1.00 0.00 o.oo 0.00 90.00 o.oo 0.00 0.00 9.00 0.00 G-7-51 20. 66 0.00 34.50 0.00 0.00 0.75 0.00 0.00 o.oo 0.00 0.00 0.00 1. 75 H-7 25.75 0.00 13.00 46.25 1.00 8.00 0.00 0.00 o.oo o.oo 0.00 0.50 0.75 H-9 26.35 0.00 30.35 24.00 1.50 17.75 0.00 0.00 0.00 o.oo 0.00 0.00 9.50 H-13 27 .15 o.oo 20.50 0.00 o.oo 0.25 3.00 4.00 0.00 o.oo o.oo 0.00 0.00 17.00 3.00 6.00 0.00 0.00 J-1 31 26.00 21 .00 o.oo 0.25 o.oo o.oo o.oo N J-3 33.25 o.oo 0.25 9.25 o.oo 0.00 4.75 o.oo 0.00 0.00 o.oo 0.00 0.00 � J-4 33.5 0.00 o.oo 6.00 o.oo 0.00 6.00 0.00 1.00 0.25 o.oo o.oo 0.00 .... K-4 36. 9 15.00 8.25 2.00 0.00 o.oo 6.00 29.00 o.oo 2.75 0.2S o.oo 0.00 L-2 37 .S5 10.75 0.00 14.00 0.25 4.2S o.oo 52.00 o.oo o.oo 0.00 2.2S o.oo L-3 38.7 0.00 20 .75 24.75 0.25 24.75 o.oo 0.00 0.00 0.00 o.oo 0.00 o.oo 0-3 44.75 0.00 11.50 27.50 1.00 14.00 0.00 6.00 0.00 0.00 o.oo 2.00 1.00 P-1 44.8 o.oo 0.00 0.25 o.oo o.oo 2.50 0.00 o.oo 0.00 o.oo 0.00 0.00 P-2 4S 2.2S 1.00 8.00 0.00 o.oo 4 .75 46 .50 o.oo o.oo 0.00 o.oo 0.00 P-4 45.2 7.50 12.00 2.00 0.00 0.00 5.00 6.00 0.00 o.oo 0.00 0.00 0.00 S-2 50 .3 8.00 10 .00 1.00 o.oo 0.50 5.50 6.00 0.50 0.00 o.oo 0.00 o.oo T-2 52.3 1.50 13.25 3.00 0.00 o.oo 7.00 12.00 o.oo 0.00 0.00 o.oo 0.00 T-3 52.4 1.00 8.00 9.00 0.00 o.oo 4.50 18.SO 0.00 o.oo 0.00 0.00 0.00 T-11 58.4 0.00 11.50 11.50 0.00 2.50 2.00 12.00 0.00 0.00 o.oo 0.00 0.00 U-1 63.2 1.00 0.50 s.oo o.oo 3.00 0.00 89.25 o.oo 0.00 o.oo 0.50 o.oo U-2 63.4 0.00 1.25 13.00 0.00 3.00 3.00 44.50 0.00 0.00 0.00 0.00 o.oo W-1 64 o.oo 0.00 10 .25 0.00 0.00 0.00 81 .75 0.00 0.00 o.oo 1.00 0.50 Y-4 65.62 0.25 5.00 4.00 o.oo 1.00 1.00 13.00 o.oo o.oo 0.00 1.00 0.00 Z-4-1 70.7 2.00 0.25 12.00 0.00 6.00 o.oo 61 .00 o.oo o.oo 0.00 1.50 1.00 Z-6 72.05 o.oo 13.00 7.00 0.00 o.oo 2.00 30.00 0.00 o.oo 0.00 1.00 0.00 1.00 0.00 Z-7 72.5 0.00 0.50 6.00 o.oo 0.00 4.00 75 .00 o.oo 0.00 0.00 AA-7-1 74 0.00 14.50 0.00 16.50 o.oo 8.50 7.50 2.50 o.oo 0.2S 0.00 o.oo BB-1 75. 42 0.00 o.oo 2.50 0.00 o.oo 0.25 9S.SO 0.00 o.oo 0.00 0.00 o.oo BB-2 76 .1 o.oo 0.00 12.SO 0.00 o.oo o.so 78.00 0.00 0.00 o.oo 5.00 o.oo 242

VITA

Michael Glenn Kozar was born on October 26, 1960 in

Cleveland , Ohio . He attended elementary and junior high school in Willowick , Ohio . He was graduated from Eastlake

North High School in the spring of 1979 . In the fall of that year , he entered The College of Wooster in Wooster ,

Ohio where he maj ored in geology and minored in economics .

He was graduated from that institution in June , 1983 with a

Bachelor of Arts degree . He continued his studies in geology at Kent State University, Kent , Ohio . After a semester of graduate study at Kent State he transferred to

The University of Tennessee in the winter of 1984. In the winter of 1985, Michael accepted a Teaching Assistantship at the Department of Geological Sciences , The University of

Tennessee . In December 1986, Michae l was awarded a Master of Science with a concentration in Geological Sciences from

The University of Tennessee .

Michael is a member of the Society of Economic

Paleontologists and Mineralogists and the Geological

Society of America.