Lakshmi Pharmachem Form I Annexures Location Map of Pharmachem

LAKSHMI PHARMACHEM SY.NO. 219/1(PART), 219/2(PART) AND 221(PART), RAMANNAPALEM VILLAGE, TIRUVURU MANDAL, KRISHNA DISTRICT, ANDHRA PRADESH

FORM I

Project No. 0218-21-02 February 2018

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants M/s. Lakshmi Pharmachem B-115-117 AND 509, Annapurna 64-9-5A, Flat No 303, Sree Bhaskara Residency, Block, Chennupati Ramakotaiah Street, Patamata Lanka, Aditya Enclave, Ameerpet, Vijayawada, Andhra Pradesh – 520 010 Hyderabad-500 038. Phone No: +91 98491 72280 Phone: 040-23748 555/23748616, E-mail: [email protected] Telefax: 040-23748666 SUBMITTED TO MINISTRY OF ENVIRONMENT, FOREST AND CLIMATE CHANGE GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI Lakshmi Pharmachem

APPENDIX – I (See Paragraph – 6) FORM I I) Basic Information S.No. Item Details 1 Name of the Project/s Lakshmi Pharmachem 2 S. No in the Schedule 5 (f) – A category - Synthetic Organic Chemicals (Bulk Drugs and Intermediates) 3 Proposed capacity/area/length/tonnage to Production Capacity: 4.75 TPD be handled/command area/lease Site Area: 10 acres area/number of wells to be drilled Capital Cost: Rs. 25 crores 4 New/Expansion/Modernization New 5 Existing Capacity/Area etc. Not Applicable 6 Category of Project i.e 'A' or 'B' “A” 7 Does it attract the general condition? If yes, NA please specify 8 Does it attract the Specific condition? If yes, No please specify. 9 Location Plot/Survey/Khasra No. Sy. No. 219/1(Part), 219/2(Part) and 221(Part), Village Ramannapalem Village Tehsil Tirvuru Mandal District Krishna District State Andhra Pradesh 10 Nearest railway station/airport along with Madhira Railway station – 34.8 km distance in km. Gannavarm airport (Vijayawada) - 61 km 11 Nearest Town, City, District Headquarters Tiruvuru - 5.2 km along with distance in kms. 12 Village Panchayats, Zilla Parishad, Municipal Kakarla Corporation, Local body (complete postal address with telephone nos. to be given) 13 Name of the Applicant N. Rama Krishna 14 Registered Address Lakshmi Pharmachem Sy. No. 219/1(Part), 219/2(Part) and 221(Part), Ramannapalem Village, Tiruvuru Mandal, Krishna District, Andhra Pradesh – 521227. 15 Address for Correspondence: Name N. Rama Krishna Designation(Owner/Partner/CEO) Proprietor Address Lakshmi Pharmachem 64-9-5A, Flat No 303, Sree Bhaskara Residency, Chennupati Ramakotaiah Street, Patamata Lanka, Vijayawada Pin Code 520 010 E-mail [email protected] Telephone Number 09849172280 Fax No.

Form I Page 1 Lakshmi Pharmachem

16 Details of alternative Sites examined, if any. Not Applicable Location of these sites should be shown on a topo sheet. 17 Interlinked Projects Not applicable 18 Whether separate application of interlinked -NA- project has been submitted? 19 If yes, date of submission -NA- 20 If no, reason 21 Whether the proposal involves -NA- approval/clearance under: if yes, details of the same and their status to be given. (a) The Forest (Conservation) Act, 1980? (b) The Wildlife (Protection) Act, 1972? (c) The C.R.Z Notification, 1991? 22 Whether there is any Government No Order/Policy relevant/relating to the site? 23 Forest land involved (hectares) No 24 Whether there is any location pending No against the project and /or land in which the project is propose to be set up? (a) Name of the Court (b) Case No (c) Orders/directions of the Court, if any and its relevance with the proposed project.

Form I Page 2 Lakshmi Pharmachem

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which will cause physical changes in the locality (topography, land use, changes in water bodies, etc.) S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities /rates, wherever possible) with source of information data 1.1 Permanent or temporary change in NO The proposal is a green field project. The total site area land use, land cover or topography of 10 acres. including increase in intensity of land use (with respect to local land use plan) 1.2 Clearance of existing land, NO The proposal is a green field project. The total site area vegetation and buildings? of 10 acres. 1.3 Creation of new land uses? NO 1.4 Pre-construction investigations e.g. YES Soil test done and soil load bearing capacity bore houses, soil testing? established 1.5 Construction works? YES Construction activity involves creation of production blocks, Utilities, ZLD system. 1.6 Demolition works? NO 1.7 Temporary sites used for NO Construction labor from local villages shall be construction works or housing of employed. construction workers? 1.8 Above ground buildings, structures YES Storage facilities shall be constructed. No major cut or earthworks including linear and fill or excavation is anticipated. structures, cut and fill or excavations 1.9 Underground works including mining NO No underground works like mining and tunneling. or tunneling? 1.10 Reclamation works? NO 1.11 Dredging? NO 1.12 Offshore structures? NO 1.13 Production and manufacturing YES Enclosed in Annexure – I processes? 1.14 Facilities for storage of goods or NO Raw materials and solvents shall be stored with in materials? factory premises. Materials in bags and drums will be stored in flame proof ware houses. 1.15 Facilities for treatment or disposal of YES Effluents are treated in ZLD system. solid waste or liquid effluents? Solid waste is sent to TSDF or authorized recyclers. Details of waste treatment facilities presented in Annexure II 1.16 Facilities for long term housing of NO Operational workers stay in surrounding villages. operational workers? 1.17 New road, rail or sea traffic during YES Construction materials shall be transported to the site. construction or operation? The traffic density of the existing connecting road is negligible. 1.18 New road, rail, air waterborne or NO other transport infrastructure including new or altered routes and stations, ports, airports etc? 1.19 Closure or diversion of existing NO

Form I Page 3 Lakshmi Pharmachem

transport routes or infrastructure leading to changes in traffic movements? 1.20 New or diverted transmission lines or NO pipelines? 1.21 Impoundment, damming, culverting, NO realignment or other changes to the hydrology of watercourses or aquifers? 1.22 Stream crossings? NO All raw materials, solvents and waste streams are pumped through pipe lines above ground level. 1.23 Abstraction or transfers of water YES Total water required shall be met from ground water form ground or surface waters? using bore- wells.

Total water required shall be 330 KLD out of which 211 KLD shall be drawn from bore well and the balance shall be recycled water. 1.24 Changes in water bodies or the land NO surface affecting drainage or run-off? 1.25 Transport of personnel or materials YES The construction material shall be drawn from local for construction, operation or sources within 10 km. There is no transport of decommissioning? personnel, as the construction workers shall be drawn from local villages. 1.26 Long-term dismantling or NO decommissioning or restoration works? 1.27 Ongoing activity during NO decommissioning which could have an impact on the environment? 1.28 Influx of people to an area in either YES The proposed project shall increase the employment temporarily or permanently? potential. 1.29 Introduction of alien species? NO 1.30 Loss of native species or genetic NO There are no major losses of tree/shrub species. diversity? 1.31 Any other actions? NO

Form I Page 4 Lakshmi Pharmachem

2. Use of Natural resources for construction or operation of the Project (such as land, water, materials or energy, especially any resources which are non-renewable or in short supply): S.No. Information/checklist Yes/No Details thereof (with approximate quantities /rates, confirmation wherever possible) with source of information data 2.1 Land especially undeveloped or YES The proposal is a green field project. The total site area of 10 agricultural land (ha) acres.

2.2 Water (expected source & YES Total water required shall be met from ground water. competing users) unit: KLD Total water required shall be 330 KLD out of which 211 KLD shall be drawn from bore well and the balance shall be recycled water. (Water Balance Enclosed in Annexure III) 2.3 Minerals (MT) NA 2.4 Construction material – stone, YES Shall be sourced from the local villages. aggregates, sand / soil (expected source – MT) 2.5 Forests and timber (source – NO MT) 2.6 Energy including electricity and YES The required energy shall be drawn from AP Transco. fuels (source, competing users) Standby DG sets of 2 X 1010 kVA and 2 x 500 kVA is Unit: fuel (T), energy (MW) proposed. It is proposed to establish 2 X 8 TPH coal fired boilers to meet the steam requirement for process. It is proposed to keep 1 x 8 TPH coal fired boiler as standby. It is proposed to establish coal based Thermic fluid heater of capacity 2 x 2 lac K.cal. Coal consumption is 31.8 TPD. 2.7 Any other natural resources NA (use appropriate standard units)

Form I Page 5 Lakshmi Pharmachem

3. Use, storage, transport, handling or production of substances or materials, which could be harmful to human health or the environment or raise concerns about actual or perceived risks to human health. S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 3.1 Use of substances or materials, which YES Hazardous chemicals shall be used for manufacturing are hazardous (as per MSIHC rules) to of CMC. MSIHC rules shall be followed during human health or the environment storage, transportation and handling of raw (flora, fauna, and water supplies) materials. Hazardous chemicals and solvent shall be stored and handled in closed systems. 3.2 Changes in occurrence of disease or NO affect disease vectors (e.g. insect or water borne diseases). 3.3 Affect the welfare of people e.g. by YES Shall increase the employment potential for locals changing living conditions? and affect the living conditions for betterment. 3.4 Vulnerable groups of people who could NO No sensitive receptors are present in the immediate be affected by the project e.g. hospital vicinity of the site. The project shall not have any patients, children, the elderly etc., significant impact on vulnerable groups of people. 3.5 Any other causes NO

4. Production of solid wastes during construction or operation or decommissioning (MT/month) S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 4.1 Spoil, overburden or mine wastes NO 4.2 Municipal waste (domestic and or NO Wastes from canteen, other commercial wastes like commercial wastes) paper, empty containers etc. 4.3 Hazardous wastes (as per Hazardous YES Hazardous waste generation during construction shall Waste Management Rules) be limited to waste oils, batteries and containers of paints etc. The quantity of hazardous wastes generated during operation contain used oil, ETP sludge etc. 4.4 Other industrial process wastes YES Enclosed at Annexure IV 4.5 Surplus product NO 4.6 Sewage sludge or other sludge from YES Sludge from STP and Effluent treatment plant shall be effluent treatment sent to TSDF. 4.7 Construction or demolition wastes NO Construction activities involve creation of production blocks, Utilities and ZLD system. 4.8 Redundant machinery or equipment NO 4.9 Contaminated soils or other materials NO All pipe lines including pipe lines of waste streams are above ground level to eliminate the possibility of any contamination due to seepage and for ease of maintenance. 4.10 Agricultural wastes NO 4.11 Other solid wastes YES Enclosed at Annexure IV

Form I Page 6 Lakshmi Pharmachem

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr) S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 5.1 Emissions from combustion of fossil fuels YES Coal Shall be used as fuel. Emissions details are from stationary or mobile sources enclosed in Annexure V

5.2 Emissions from production processes YES Gaseous emissions from process are HCl, SO2, are scrubbed in scrubber and. Hydrogen gas sent to atmosphere through water column. 5.3 Emissions from materials handling NO Material transfer takes place in closed pipeline including storage or transport systems using pumps with mechanical seals. 5.4 Emissions from construction activities YES Dust may rise during transport of material and including plant and equipment construction activity. The dust emissions shall be mitigated by water spraying on the roads within the premises. 5.5 Dust or odors from handling of materials NO Domestic wastewater sent to STP. Treated including construction materials, sewage wastewater reused for gardening. and waste 5.6 Emissions from incineration of waste NO 5.7 Emissions from burning of waste in open NO air (e.g. slash materials, construction debris) 5.8 Emissions from any other sources NO

Form I Page 7 Lakshmi Pharmachem

6. Generation of Noise and Vibration, and Emissions of Light and Heat: S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data with source of information data 6.1 From operation of equipment e.g. YES Material transport and construction equipment shall be engines, ventilation plant, crushers source of noise, while transfer pumps, DG sets are the sources of noise during operation. 6.2 From industrial or similar processes YES DG sets controlled by providing Acoustic Enclosures. 6.3 From construction or demolition YES Noise during construction shall be due to construction equipment and emergency DG sets. 6.4 From blasting or piling NO 6.5 From construction or operational NO The increased traffic shall not have any significant traffic impact. 6.6 From lighting or cooling systems NO 6.7 From any other sources NO

7.Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea: S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 7.1 From handling, storage, use or NO All the hazardous materials will be stored in MS drums, spillage of hazardous materials in a covered shed and no contamination of soil is expected. Same philosophy will be followed for the after expansion 7.2 From discharge of sewage or other NO Sludge from ETP shall be sent to TSDF. effluents to water or the land (expected mode and place of discharge) 7.3 By deposition of pollutants emitted NO Vents of reactors are connected to common scrubber to air into the land or into water 7.4 From any other sources NO 7.5 Is there a risk of long term build up NO of pollutants in environment from these sources?

Form I Page 8 Lakshmi Pharmachem

8.Risk of accidents during construction or operation of the Project, which could affect human health or the environment S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 8.1 From explosions, spillages, fires etc from YES All Inbuilt Safety precautions will be storage, handling, use or production of adopted and there will not be any hazardous substances damage to environment or human health 8.2 From any other causes NA 8.3 Could the project be affected by natural disasters NO causing environmental damage (e.g. Floods, earthquakes, landslides, cloudburst etc)?

9.Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts with other existing or planned activities in the locality S. No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 9.1 Lead to development of supporting. YES The project shall enhance the socio facilities, ancillary development or development economic status of the area by stimulated by the project which could have impact increasing the demand for housing, on the environment e.g.: improving the employment. • Supporting infrastructure (roads, power supply, waste or waste water treatment, etc.) • housing development • extractive industries • supply industries • other 9.2 Lead to after-use of the site, which could haven NO impact on the environment 9.3 Set a precedent for later developments NO 9.4 Have cumulative effects due to proximity to other NO The baseline environmental status of existing or planned projects with similar effects the surrounding areas is within the prescribed limits as observed from the Secondary data.

Form I Page 9 Lakshmi Pharmachem

(III) Environmental Sensitivity S.No. Areas Name/ Aerial distance (within 15 km.) Identity Proposed project location boundary 1 Areas protected under international conventions, NA national or local legislation for their ecological, landscape, cultural or other related value 2 Areas which are important or sensitive for YES Kakarla RF – W – 50 m ecological reasons - Wetlands, watercourses or Edulla Vagu – S – 4.5 km other water bodies, coastal zone, biospheres, Kattaleru River Stream – W – 5.2 km mountains, forests 3 Areas used by protected, important or sensitive NA species of flora or fauna for breeding, nesting, foraging, resting, over wintering, migration 4 Inland, coastal, marine or underground waters NO 5 State, National boundaries NO 6 Routes or facilities used by the public for access to NO recreation or other tourist, pilgrim areas 7 Defense installations NO 8 Densely populated or built-up area YES Nearest habitation from the site is Ramannapalem at a distance of 3.5 Km in SE direction 9 Areas occupied by sensitive man-made land uses NA (hospitals, schools, places of worship, community facilities) 10 Areas containing important, high quality or scarce NO resources (ground water resources, surface resources, forestry, agriculture, fisheries, tourism, minerals) 11 Areas already subjected to pollution or NO environmental damage. (those where existing legal environmental standards are exceeded) 12 Areas susceptible to natural hazard which could NO cause the project to present environmental problems (earthquakes, subsidence, landslides, erosion, flooding or extreme or adverse climatic conditions)

(IV) Proposed Terms of Reference for EIA studies

Form I Page 10

LAKSHMI PHARMACHEM SY.NO. 219/1(PART), 219/2(PART) AND 221(PART), RAMANNAPALEM VILLAGE, TIRUVURU MANDAL, KRISHNA DISTRICT, ANDHRA PRADESH

ANNEXURES

Project No. 0218-21-02 February 2018

Page 1

M/s. Lakshmi Pharmachem Form I Annexures

ANNEXURE - I M/s. Lakshmi Pharmachem proposes to set up a Synthetic Organic Chemicals (Bulk Drugs & Intermediates) Unit in an area of 10 acres in at Sy. No. 219/1(Part), 219/2(Part) and 221(Part), Ramanapalam Revenue village, Kakarla Gramapanchayati, Tiruvuru Mandal, Krishna District, Andhra Pradesh. The proposed list of products and manufacturing capacity is presented in Table A-1. Table A-1 Manufacturing Capacity S.No Name Of the Product Cas No Capacity Kg/Day TPM 1 Cis-Bromo Benzoate 61397-56-6 1000 30 2 2,3-Dimethyl-4--nitropyridine-N-oxide 37699-43-7 750 22.5 3 Lansoprazole 103577-45-3 300 9 4 Rabeprazole Sodium 117976-90-6 300 9 5 Omeprazole 73590-58-6 300 9 6 3,5-Dimethyl-4-nitropyridine-N-oxide 14248-66-9 500 15 7 Cis-[[2-(2-(2,4-Dichlorophenyl)-2-(1H-1,2,4-triazol-1-yl- 67914-86-7 500 15 methyl)-1,3-dioxolan-4-yl]methyl]methane sulfonate 8 Cis-Tosylate 154003-23-3 500 15 9 Pantaprazole Sodium Sesquihydrate 138786-67-1 300 9 10 Itraconazole 84625-61-6 200 6 11 Esomeprazole Magnesium Trihydrate 217087-09-7 200 6 12 Ketaconazole 65277-42-1 200 6 13 1-[2-(2-Hydroxy ethoxy)Ethyl]Piperazine 13349-82-1 200 6 14 2-Hydroxy methyl-3-methyl-4-(3-mothoxy propoxy) 118175-10-3 300 9 pyridine. Hydrochloride 15 2-Chloromethyl-3-methyl-4-(3-methoxy 153259-31-5 600 18 propoxy)Pyridine. 16 2-[[[4-(3-methoxy propoxy)-3-methyl-2- 117977-21-6 450 13.5 pyridinyl]methyl] thio]-1H-benzimidazole 17 2-(Hydroxy methyl)-3-methyl-4-(2,2,2-triflouroethoxy) 103577-66-8 450 13.5 Pyridine. Hydrochloride 18 2-(Chloro methyl)-3-methyl-4-(2,2,2-triflouroethoxy) 127337-60-4 400 12 pyridine Hydrochloride 19 2-[[[3-methyl-4-(2,2,2-triflouro ethoxy)-2- 103577-40-8 400 12 pyrdinyl]methyl] sulfanyl]-1H-benzimidazole 20 2-[[[3-methyl-4-(nitro)-2-pyridinyl]methyl] sulfanyl]-1H- 152402-98-7 400 12 benzimidazole 21 4-[4-[4-(4-Hydroxy Phenyl) -1-Piperazinyl]phenyl] 2,4- 400 12 dihydro-2-(1-Methyl Propyl)-3H-1,2,4-Triazole-3-One Total (Worst Case 8 Product on Campaign Product) 4750 142.5

Page 3 M/s. Lakshmi Pharmachem Form I Annexures

Process Description of Itraconazole Reaction Scheme N N Hydrogen bromide N CH 3 O M .W t: 8 1 O H C 3 N Dimethyl formamide N N N O M e N + O H 3C O 2S O H 2 C Formic acid C l M e th a n o l 2,4-Dihydro-4-[4-[4-4-methoxyphenyl]1-piperazinyl] C l phenyl]-2-(1-methlpropyl)-3H-1,2,4-triazol-3-one Cis-[2-(2-,4-dichlorophenyl)-2-1H-1,2,4- M .W t: 4 0 7 Trazol-1-yl]methyl1,3-dioxalan-4-yl] methyl sulfonate

M .W t: 4 0 8

C H 3 O N H C N 3 N O M e th a n e Methyl Bromide N N N O sulfonic acid N + + M .W t: 9 5 O M .W t: 9 6 H C l C l Itraconazole (Pharma) M .W t: 7 0 5

Process Description: 2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-piperazinyl]phenyl]-2-(1-methoxy propyl)-3H- 1,2,4-triazol-3-one compound react with cis-[2-(2,4-dichlorophenyl)-2-(1H-1,2,4-triazol-1- ylmethyl)-1,3-dioxolan-4-yl] methyl-p-toluenesulfonate in the prensence of Dimethyl formamide, Formic Acid, and Methanol Solvent to gives the Itraconazole. Schematic diagram of Itraconazole is shown in Fig A.3 and material balance for Itraconazole is presented in Table A.2.

2,4-Dihydro-4-[4-[4-4-m ethoxyphenyl] 1-piperazinyl]phenyl]-2-(1-m ethlpropyl) -3H -1,2,4-triazol-3-one M ethyl brom ide Cis-[2-(2,4-dichlorophenyl)-2-1H - 1,2,4-Triazol-1-yl]m ethyl1,3- M ethanesulphonic acid dioxalan-4-yl]m ethyl sulfonate Dimethylformamide Hydrobrom ic acid Caustic potash flakes Sodium bicarbonate W a s t e w a t e r Condensation Dimethylformamide M e t h a n o l Caustic potash flakes Form ic acid W a t e r M ethylene chloride M e t h a n o l Form ic acid Activated carbon M ethylene chloride Activated carbon

Itraconazole ( P h a r m a ) Fig A.3 Process Flow Diagram of Itraconazole

Page 4 M/s. Lakshmi Pharmachem Form I Annexures

Table A-2 Material Balance of Itraconazole Input Quantity Output Quantity Remarks (Kg/day) (Kg/day) 2,4-Dihydro-4-[4-[4-(4- 201.4 Itraconazole 200 Final product methoxyphenyl)-1- piperazinyl]phenyl]-2-(1- methoxy propyl)-3H-1,2,4- triazol-3-one cis-[2-(2,4-dichlorophenyl)- 202.2 Methane Sulfonic acid 30 Organic residue 2-(1H-1,2,4-triazol-1- ylmethyl)-1,3-dioxolan-4-yl] methyl-p-toluenesulfonate Formic acid 90 Methyl Bromide 29 Organic residue Sodium hydroxide 48 MDC recovered 1152 Recovered and reused Sodium bicarbonate 70 MDC loss 9.6 Fugitive loss Activate carbon 12 MDC residue 38.4 Residue Water 2000 Methanol recovered 1425 Recovered and reused Methanol 1500 Methanol loss 12 Fugitive loss Methylene chloride (MDC) 1200 Methanol to 15 To Wastewater wastewater Dimethylformamide (DMF) 500 Methanol residue 48 Residue Hydrochloric Acid 43.8 DMF recovered 480 Recovered and reused DMF loss 2.5 Fugitive loss DMF residue 17.5 Residue Organic Residue 144.7 Organic residue Formic acid 90 Recovered and reused Sodium bicarbonate 70 To Wastewater Activate carbon 12 Organic residue Sodium Chloride 70.1 To Wastewater Water 2021.6 To Wastewater Total Input 5867.4 Total Output 5867.4

Page 5 M/s. Lakshmi Pharmachem Form I Annexures

ANNEXURE – II: Wastewater Treatment Facilities

The main sources of effluent generation from the plant are from process, floor washings, blowing downs from boiler and cooling tower, and domestic effluents. The effluents generated in the process, separation techniques and during purification contain organic residues of raw materials, solvents, and products. Some of the raw materials used in the process are also inorganic in nature. Hence the effluents contain both organics and in- organics in various quantities leading to high COD and TDS levels respectively. The quantity of effluents generated and mode of treatment is presented in Table A-3.

Table A-3 Quantity of Effluent Generated and Mode of Treatment Description Quantity Mode of Treatment (KLD) HTDS Effluents Process 77 Sent to Stripper followed by MEE and ATFD. Washings 5 Stripper Condensate sent to Cement Plants for Co- Scrubber Effluent 5 Incineration. MEE and ATFD Condensate sent to RO/DM rejects 10 Biological treatment plant followed by RO. RO rejects sent to MEE and permeate is reused in cooling towers, boilers make-up and scrubbers. Total - I 97 LTDS Effluents R & D 1 Sent to Biological Treatment System followed by RO. Boiler Blow downs 6 RO permeate reused for cooling towers, boilers make-up Cooling Tower Blow 20 and scrubbers. RO rejects sent to MEE. downs Domestic 8 Sent to Sewage Treatment Plant and treated wastewater reused for gardening.. Total - II 35 Grand Total (I+II) 132

Page 6 M/s. Lakshmi Pharmachem Form I Annexures

ANNEXURE – III: Water Balance

Water is required for process, scrubbers, washing, R&D, cooling tower makeup, steam generation and domestic purposes. The required water shall be drawn from ground water sources in addition to reuse of treated wastewater. The total water requirement is in the order of 330 KLD consisting of 211 KLD fresh water and the remaining of recycled water. Total water balance is presented in Table A-4. Table A-4 Total Water Balance (Tentative) Purpose INPUT(KLD) OUTPUT (KLD) Fresh Water Recycled Water Loss Effluent Process 70 77* Washings 5 5 R&D Lab 1 1 Scrubber 2 3 5 Boiler Feed 42 36 6 Cooling Tower 70 108 158 20 DM Rejects 10 10 Domestic 9 1 8 Gardening 2 8 10 Gross Total 211 119 205 132 Total 330 337 * Process effluents contain soluble raw materials, byproducts, solvents etc.

Page 7 M/s. Lakshmi Pharmachem Form I Annexures

ANNEXURE – IV: Solid Waste

Solid wastes are generated from the process shall be sent to TSDF/ Cement Industries for Co-incineration. The inorganic residue, evaporation salts from MEE and ATFD and ETP Sludge shall be sent to TSDF. Total solid waste generated and mode of disposal is presented in Table A-5.

Table A-5 Total Solid Waste Generated and Mode of Disposal (Tentative) S.No Description Units Quantity Mode of Treatment/Disposal

1 Ash from Boiler TPD 18 Sold to Brick manufactures and cement plants 2 Organic residue TPD 2.5 Sent to TDSF/Cement Plants for Co- incineration 3 Solvent Residue TPD 4 Sent to TSDF/Cement Industries 4 Spent Solvent KLD 50 Recovered within plant premises and reused 5 Mixed Solvent KLD 10 Sent to authorized recovery units/Cement plants for co-incineration 6 Stripper Distillate KLD 2 Sent to Cement Industries for Co- incineration. 7 Spent Carbon Kg/day 60 Sent to Cement Industries for Co- incineration. 8 Inorganic Residue TPD 1 Sent to TSDF 9 Evaporation salts TPD 7 Sent to TSDF 10 ETP Sludge TPD 1.2 Sent to TSDF/ Cement plants for co- incineration 11 Detoxified containers No.s/Yr 10000 Sold to authorized vendors 12 Waste oil KLPA 10 Sent to Authorized Recyclers 13 Used batteries No.s/Yr 300 Sent to Authorized Recyclers

Page 8 M/s. Lakshmi Pharmachem Form I Annexures

ANNEXURE – V: Stack Emissions Details

The sources of air pollution from the plant are proposed 2 x 8 TPH Coal fired boilers, 2 x 2 lac k.cal theric fluid heaters and proposed DG sets of 2 x 1010 KVA and 2 x 500 KVA. The proposed air pollution control equipment for coal fired boiler is Bag filters. DG sets shall be provided with stack heights based on the CPCB formula for effective stack height. The emission rates of SO2, NOx and PM from each stack are presented in Table A-6.

Table A-6 Stack Emission Details S. No Stack Connected to Stack Dia of Temp. of Exit Pollutant Emission Ht (m) stack at exhaust Velocity Rate (g/sec) 0 top(m) gases ( C) (m/sec) PM SO2 NOx 1 2 x 8 TPH Coal 40 1.2 180 10 0.3 1.2 1.88 Fired Boiler* 2 2 x 2 Lakh Kcal 15.2 0.4 180 6.5 0.04 0.08 0.12 Thermic Fluid Heaters 3 2 X 1010 KVA DG 10 0.4 200 11 0.037 0.13 0.19 set# 4 2 x 500 KVA DG 7 0.2 170 10.9 0.01 0.035 0.05 set# * 1 x 8 TPH boiler shall be kept as Standby #DG sets will be used during load shut down by .

Page 9 LAKSHMI PHARMACHEM SY.NO. 219/1(PART), 219/2(PART) AND 221(PART), RAMANNAPALEM VILLAGE, TIRUVURU MANDAL, KRISHNA DISTRICT, ANDHRA PRADESH

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants QCI: MoEANDF OM, List A-1, S.No.25. (An ISO 9001:2008, ISO 14001:2004 AND OHSAS 18001:2007 Certified Organization) B-115, Annapurna Block, Aditya Enclave Ameerpet, Hyderabad-500 038. Phone: 040-23748 555/616, Telefax: 040-23748666 Email: [email protected]