Identifying dominant recombination mechanisms in perovskite solar cells by measuring the transient ideality factor Phil Calado1†*, Dan Burkitt2†, Jizhong Yao1†, Joel Troughton2, Trystan M. Watson2, Matt J. Carnie2, Andrew M. Telford1, Brian C. O’Regan3, Jenny Nelson1, Piers R. F. Barnes*1 1. Department of Physics, Blackett Laboratory, Imperial College London SW7 2AZ London, UK 2. SPECIFIC, College of Engineering, Swansea University, Baglan Bay Innovation and Knowledge Centre, Central Avenue, Baglan, SA12 7AX, UK. 3. Sunlight Scientific, Berkeley, CA, USA †These authors contributed equally to this work *
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[email protected] Abstract The ideality factor determined by measuring the open circuit voltage (VOC) as function of light intensity is often used as a means to identify the dominant recombination mechanism in solar cells. However, applying this ‘Suns-VOC’ technique to perovskite cells is problematic since the VOC evolves with time in a way which depends on the previously applied bias (Vpre), the light intensity, and the device architecture/processing. Here we show that the dominant recombination mechanism in two structurally similar CH3NH3PbI3 devices containing either mesoporous Al2O3 or TiO2 layers can be identified from the signature of the transient ideality factor following application of a forward bias, Vpre, to the device in the dark. The transient ideality factor, is measured by monitoring the evolution of VOC as a function of time at different light intensities. The initial values of ideality found using this technique were consistent with corresponding photoluminescence vs intensity as well as electroluminescence vs current density measurements. Time-dependent simulations of the measurement on modelled devices, which include the effects of mobile ionic charge, show that Shockley Read Hall (SRH) recombination through deep traps at the charge collection interfaces is dominant in both devices.