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Sodium Chlorate Process Liquor De-Chromed SN
SAFETY DATA SHEET This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries. 1. Identification Product identifier Sodium Chlorate Process Liquor De-chromed SN Other means of identification De-chromed blend of Crystallizer Feed Liquor and Mother Liquor, NaClO3 Recommended use For internal transfer between ERCO Worldwide sodium chlorate manufacturing facilities for process purposes Recommended restrictions None known Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name ERCO Worldwide Address 335 Carlingview Drive Unit 1 Etobicoke, M9W 5G8 Canada Telephone Information #: (416) 239-7111 (M- F: 8:00 am – 5:00pm EST) Website http://www.ercoworldwide.com E-mail [email protected] Emergency phone number Canada & USA: 1-800-424-9300 (CHEMTREC) Supplier Refer to Manufacturer 2. Hazard(s) Identification Physical hazards Oxidizing liquids Category 2 Health hazards Acute toxicity, oral Category 4 Environmental hazards Not currently regulated by OSHA, refer to Section 12 for additional information. OSHA defined hazards This mixture does not meet the classification criteria according to OSHA HazCom 2012. Label elements Signal word Danger Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Page 1 of 15 Issue Date: 11/18/2020 Sodium Chlorate Process Liquor De-chromed SN Precautionary statement Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from clothing and other combustible materials. Wear protective gloves, protective clothing, eye protection, face protection. Response IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. In case of fire: Use water to extinguish. -
Production of Hexavalent Chromium for Use in Chlorate Cells
Europaisches Patentamt J European Patent Office © Publication number: 0 266 128 A2 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 87309335.5 © Int. CIA C25B 1/26 @ Date of filing: 22.10.87 ® Priority: 29.10.86 CA 521737 © Applicant: Tenneco Canada Inc. 2 Gibbs Road © Date of publication of application: Islington OntarioM9B 1R1(CA) 04.05.88 Bulletin 88/18 0 Inventor: Dobosz, Leszek Michal © Designated Contracting States: 68 MacDonald Street CH ES FR LI SE Toronto Ontario M8V 1Y4(CA) © Representative: Hamilton, Raymond et al c/o Albright & Wilson Limited 1 Knightsbridge Green London SW1X 7QD(GB) © Production of hexavalent chromium for use in chlorate cells. © By-product hypochlorite from the electrolytic production of chlorates, notably sodium chlorate, is used to form hexavalent chromium for use in the electrolysis process by oxidation of trivalent chromium compounds by the hypochlorite. The hypochlorite maybe the condensate produced by treatment of the chlorate cell by-product gas stream and/or present in the cell liquor. < 00 CO CO (VI a. UJ Xerox Copy Centre 0 266 128 PRODUCTION OF HEXAVALENT CHROMIUM FOR USE IN CHLORATE CELLLS The present invention relates to the fomation of hexavalent chromium useful in the electrolytic production of aqueous chlorate solutions. An aqueous solution of sodium chlorate and sodium chloride is conventionally produced by the electrolysis of aqueous sodium chloride in diaphragmless electrolytic cells. The extent of electrolysis is 5 controlled to produce an effluent from the cell in which the sodium chlorate and sodium chloride have the desired ratio, usually in the range (expressed as a weight ratio) of about 1 :1 to about 20:1 and preferably in the range of about 2:1 to about 15:1. -
Sodium Chlorite Neutralization
® Basic Chemicals Sodium Chlorite Neutralization Introduction that this reaction is exothermic and liberates a If sodium chlorite is spilled or becomes a waste, significant amount of heat (H). it must be disposed of in accordance with local, state, and Federal regulations by a NPDES NaClO2 + 2Na2SO3 2Na2SO4 + NaCl permitted out-fall or in a permitted hazardous 90.45g + 2(126.04g) 2(142.04g) + 58.44g waste treatment, storage, and disposal facility. H = -168 kcal/mole NaClO2 Due to the reactivity of sodium chlorite, neutralization for disposal purposes should be For example, when starting with a 5% NaClO2 avoided whenever possible. Where permitted, solution, the heat generated from this reaction the preferred method for handling sodium could theoretically raise the temperature of the chlorite spills and waste is by dilution, as solution by 81C (146F). Adequate dilution, discussed in the OxyChem Safety Data Sheet thorough mixing and a slow rate of reaction are (SDS) for sodium chlorite in Section 6, important factors in controlling the temperature (Accidental Release Measures). Sodium chlorite increase (T). neutralization procedures must be carried out only by properly trained personnel wearing Procedure appropriate protective equipment. The complete neutralization procedure involves three sequential steps: dilution, chlorite Reaction Considerations reduction, and alkali neutralization. The dilution If a specific situation requires sodium chlorite to step lowers the strength of the sodium chlorite be neutralized, the chlorite must first be reduced solution to 5% or less; the reduction step reacts by a reaction with sodium sulfite. The use of the diluted chlorite solution with sodium sulfite to sodium sulfite is recommended over other produce a sulfate solution, and the neutralization reducing agents such as sodium thiosulfate step reduces the pH of the alkaline sulfate (Na2S2O3), sodium bisulfite (NaHSO3), and solution from approximately 12 to 4-5. -
Guidelines for Drinking-Water Quality, Fourth Edition
12. CHEMICAL FACT SHEETS Assessment date 1993 Principal reference WHO (2003) Chlorine in drinking-water In humans and experimental animals exposed to chlorine in drinking-water, no specific adverse treatment-related effects have been observed. IARC has classified h ypochlorite in Group 3 (not classifiable as to its carcinogenicity to humans). Chlorite and chlorate Chlorite and chlorate are disinfection by-products resulting from the use of chlorine dioxide as a disinfectant and for odour and taste control in water. Chlorine dioxide is also used as a bleaching agent for cellulose, paper pulp, flour and oils. Sodium chlorite and sodium chlorate are both used in the production of chlorine dioxide as well as for other commercial purposes. Chlorine dioxide rapidly decomposes into chlorite, chlorate and chloride ions in treated water, chlorite being the predominant species; this reaction is favoured by alkaline conditions. The major route of environmental ex- posure to chlorine dioxide, sodium chlorite and sodium chlorate is through drinking- water. Chlorate is also formed in sodium hypochlorite solution that is stored for long periods, particularly at high ambient temperatures. Provisional guideline values Chlorite: 0.7 mg/l (700 µg/l) Chlorate: 0.7 mg/l (700 µg/l) The guideline values for chlorite and chlorate are designated as provisional because use of chlorine dioxide as a disinfectant may result in the chlorite and chlorate guideline values being exceeded, and difficulties in meeting the guideline value must never be a reason for compromising adequate disinfection. Occurrence Levels of chlorite in water reported in one study ranged from 3.2 to 7.0 mg/l; however, the combined levels will not exceed the dose of chlorine dioxide applied. -
Dangers of Unspent Aircraft Oxygen Generators
Safety Advisory Dangers of Unspent Aircraft Oxygen Generators U.S. Chemical Safety and Hazard Investigation Board No. 2007-I-NC-01-SA | June 2007 Key Message This Safety Advisory is issued to alert aircraft maintenance and hazardous waste facility personnel to the hazards associated with the transportation and storage of expired, unspent aircraft chemical oxygen generators. Aircraft oxygen generators are dangerous devices that, if mishandled, can cause fires, property damage, and personal injury. Aircraft oxygen generators that have exceeded their service life should be expended before shipping by any transport mode. Introduction On October 5, 2006, at about 10 pm, a fire occurred at the EQ Industrial Services (EQ) hazardous waste treatment, storage, and disposal facility in Apex, North Carolina. The fire resulted in the evacuation of thousands of Apex residents and the complete destruction of the hazardous waste building at EQ’s Apex facility. The U.S. Chemical Safety and Hazard Investigation Board (CSB) investigation concluded that aircraft oxygen generators most likely contributed to the rapid spread of the fire to other areas in the EQ facility. The CSB issues this Safety Advisory to focus attention on the need for aircraft maintenance facilities to expend chemical oxygen generators that have exceeded their service life, and for hazardous waste facility operators and shippers to exercise due care when handling unspent chemical oxygen generators. Incident Description At about 10 pm on October 5, 2006, a citizen driving past the EQ facility in Apex, North Carolina, called 911 when he saw a plume of smoke and smelled a strong chlorine odor coming from the facility. -
Six-Year Review 3 Technical Support Document for Chlorate
Six-Year Review 3 Technical Support Document for Chlorate Office of Water (4607M) EPA-810-R-16-013 December 2016 Disclaimer This document is not a regulation. It is not legally enforceable, and does not confer legal rights or impose legal obligations on any party, including EPA, states, or the regulated community. While EPA has made every effort to ensure the accuracy of any references to statutory or regulatory requirements, the obligations of the interested stakeholders are determined by statutes, regulations or other legally binding requirements, not this document. In the event of a conflict between the information in this document and any statute or regulation, this document would not be controlling. This page intentionally left blank. Table of Contents 1 Introduction ................................................................................................................. 1-1 2 Contaminant Background .......................................................................................... 2-1 2.1 Chemical and Physical Properties ................................................................................. 2-1 2.2 Production, Use and Release ......................................................................................... 2-2 2.2.1 Commercial Production and Use in Industry and Agriculture ........................... 2-2 2.2.2 Incidental Production and Release ...................................................................... 2-6 2.3 Environmental Fate ...................................................................................................... -
Formation of Perchlorate from Chlorine Species Under Simulated Mars Conditions
Eighth International Conference on Mars (2014) 1020.pdf FORMATION OF PERCHLORATE FROM CHLORINE SPECIES UNDER SIMULATED MARS CONDITIONS. B. L. Carrier* and S. P. Kounaves, Department of Chemistry, Tufts University, Medford, MA, 02155, USA. ([email protected]). Introduction: an ongoing mechanism for perchlorate formation from - Perchlorate (ClO4 ) was first discovered on Mars at chloride, and likely indicates the probable presence of the Phoenix landing site in 2008 at concentrations of other oxychlorine intermediates and radicals such as - - ● ● 0.4 to 0.6 wt % [1]. More recently results from Mars OCl , ClO2 , ClO2(g), OCl, Cl and others. The pres- Science Laboratory (MSL) pyrolysis experiments per- ence of these intermediates has serious implications for formed by the Sample Analysis at Mars (SAM) in- the survival and detection of organics as most of these strument suite indicate the presence of an oxychlorine intermediates, unlike perchlorate, are strong oxidizing species in samples collected at Rocknest, Cumberland agents at Mars ambient conditions. All of this seems and John Klein sites, with calcium perchlorate being to indicate the presence of a complex chlorine cycle on the most likely candidate [2,3]. Perchlorate has also the martian surface. been identified in martian meteorite EETA79001 [4] Our current reseach aims to investigate factors that and has been proposed as a possible explanation for the may influence the rate of perchlorate formation such as detection of chlorinated hydrocarbons at the Viking UV dosage, exposure time, relative humidity, concen- landing sites [5]. Taken together this seems to indicate tration of atmospheric oxidants and effects of direct a global distribution of perchlorate on the martian sur- exposure to UV photons vs. -
Toxicological Profile for Chlorine Dioxide and Chlorite
TOXICOLOGICAL PROFILE FOR CHLORINE DIOXIDE AND CHLORITE U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES Public Health Service Agency for Toxic Substances and Disease Registry September 2004 CHLORINE DIOXIDE AND CHLORITE ii DISCLAIMER The use of company or product name(s) is for identification only and does not imply endorsement by the Agency for Toxic Substances and Disease Registry. CHLORINE DIOXIDE AND CHLORITE iii UPDATE STATEMENT Toxicological Profile for Chlorine Dioxide and Chlorite, Draft for Public Comment was released in September 2002. This edition supersedes any previously released draft or final profile. Toxicological profiles are revised and republished as necessary. For information regarding the update status of previously released profiles, contact ATSDR at: Agency for Toxic Substances and Disease Registry Division of Toxicology/Toxicology Information Branch 1600 Clifton Road NE, Mailstop F-32 Atlanta, Georgia 30333 CHLORINE DIOXIDE AND CHLORITE vi *Legislative Background The toxicological profiles are developed in response to the Superfund Amendments and Reauthorization Act (SARA) of 1986 (Public law 99-499) which amended the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA or Superfund). This public law directed ATSDR to prepare toxicological profiles for hazardous substances most commonly found at facilities on the CERCLA National Priorities List and that pose the most significant potential threat to human health, as determined by ATSDR and the EPA. The availability of the revised priority list of 275 hazardous substances was announced in the Federal Register on November 17, 1997 (62 FR 61332). For prior versions of the list of substances, see Federal Register notices dated April 29, 1996 (61 FR 18744); April 17, 1987 (52 FR 12866); October 20, 1988 (53 FR 41280); October 26, 1989 (54 FR 43619); October 17, 1990 (55 FR 42067); October 17, 1991 (56 FR 52166); October 28, 1992 (57 FR 48801); and February 28, 1994 (59 FR 9486). -
Occurrence of Chlorite, Chlorate and Bromate in Disinfected Swimming Pool Water
Polish J. of Environ. Stud. Vol. 16, No. 2 (2007), 237-241 Original Research Occurrence of Chlorite, Chlorate and Bromate in Disinfected Swimming Pool Water R. Michalski*, B. Mathews institute of environmental engineering of Polish Academy of science, 34 sklodowska-curie str., 41-819 zabrze, Poland Received: June 29, 2006 Accepted: November 10, 2006 Abstract Swimming pool water treatment in general includes flocculation, sand filtration and subsequent dis- infection. Chlorite, chlorate and bromate are disinfection by-products of swimming pool water treated by chlorine species or ozone. They are responsible for adverse effects on human health and their analyses in swimming pool water are necessary. The simply and fast suppressed ion chromatography simultaneous separation and conductivity deter- mination of chlorite, chlorate, bromate, fluoride, chloride, nitrate, bromide, phosphate and sulfate in dis- infected swimming pool water has been described. The separation was performed on an anion-exchange column with 1.0 mm na2CO3 + 3.2 mm naHco3 as eluent, and determination by suppressed conductivity detection. chlorite has been found in 5 analyzed samples, chlorate in all of them, and bromate in the 2 samples originated from ozonated swimming pool water. ions were analyzed in the wide concentrations range from 0.05 mg l-1 (bromate) up to 300 mg l-1 (chloride, sulfate). Linearity of disinfection by-products was checked up to 2.0 mg/l (chlorite), 30 mg l-1 (chlorate) and 0.5 mg l-1 (bromate) with a 50 µl injection loop (r2= 0.9966 – 0.9985), respectively. Fluoride, chloride, nitrate, bromide, phosphate, and sulfate did not interfere with target anions. -
Active Chlorine Released from Sodium Hypochlorite Product-Type 5 (Drinking Water)
Regulation (EU) No 528/2012 concerning the making available on the market and use of biocidal products Evaluation of active substances Assessment Report Active chlorine released from sodium hypochlorite Product-type 5 (Drinking water) January 2017 IT Active chlorine released Product-type 5 January 2017 from sodium hypochlorite CONTENTS 1. STATEMENT OF SUBJECT MATTER AND PURPOSE ............................................... 3 1.1. Procedure followed .............................................................................................................................. 3 1.2. Purpose of the assessment report ................................................................................................ 3 2. OVERALL SUMMARY AND CONCLUSIONS ................................................................... 4 2.1. Presentation of the Active Substance ......................................................................................... 4 2.1.1. Identity, Physico-Chemical Properties & Methods of Analysis ................................................... 4 2.1.2. Intended Uses and Efficacy ..................................................................................................................... 9 2.1.3. Classification and Labelling ................................................................................................................... 12 2.2. Summary of the Risk Assessment ............................................................................................... 14 2.2.1. Human Health Risk Assessment -
Sodium Hydroxide (Caustic Soda)
SODIUM HYDROXIDE odium hydroxide (caustic soda) is a co-product from the manufacture of chlorine using a Ssolution of the readily available raw material, rock salt (sodium chloride). These factors contribute to it being the cheapest and most widely used strong alkali. Uses 48 The biggest single use for sodium hydroxide in making organic chemicals is in the manufacture of epoxypropane, used in turn to make polyurethanes (Unit 67). Figure Sodium hydroxide is used in the purification of the ore, bauxite, prior to it being used to make aluminium (Unit 69). This picture shows stockpiling of recently mined bauxite ore at the Gove refinery in the Northern Territory, Australia. Figure 2 Purified bauxite being unloaded from a ship in Iceland, on its way to an aluminium extraction plant. Much sodium hydroxide is used to scrub gases to remove acids. One example is in the purification of flue gases in the manufacture of sulfuric acid, where the alkali removes sulfur dioxide and sulfur trioxide from gases that are being emitted into the atmosphere (Unit 50). Similarly it is used to treat the effluent in the manufacture of titanium dioxide (Unit 51). Another major use of sodium hydroxide is in the manufacture of paper from wood. In the most used process, the Kraft process, wood is treated with a Figure 3 Uses of sodium hydroxide. solution containing a mixture of sodium sulfide and SODIUM HYDROXIDE sodium hydroxide. Most of the unwanted material in the caustic soda produced from each of the processes wood, such as the lignins, dissolve in the liquor, leaving varies: relatively pure cellulose which is filtered off. -
Chlorine Dioxide and Chlorite
CHLORINE DIOXIDE AND CHLORITE What are CHLORINE DIOXIDE AND CHLORITE? Chlorine dioxide is a man-made gas that is yellow to reddish-yellow in color, with an unpleasant odor similar to chlorine. When chlorine dioxide is added to water, it forms chlorite. Where can chlorine dioxide and chlorite be found and how are they used? Paper plants use chlorine dioxide to bleach paper. Public drinking water suppliers use low levels of chlorine dioxide to kill harmful bacteria and organisms. How can people be exposed to chlorine dioxide and chlorite? You could be exposed to chlorine dioxide and chlorite through: Drinking water purified with chlorine dioxide and chlorite. Touching chlorine dioxide and chlorite by being in the air they have contaminated. Both chemicals are gases that break down in air. Eye Contact by being in the air that chlorine dioxide and chlorite have contaminated. Employees of pulp and paper mills or water treatment plants can have a high exposure if they work where chlorine dioxide and chlorite are used as disinfectants. How do chlorine dioxide and chlorite work? Both chlorine dioxide and chlorite break down quickly when they enter the body. Chlorine dioxide changes to chlorite ions, small groups of atoms with an electric charge. These ions further break down into chloride ions that leave the body within hours or days through the urine. How can chlorine dioxide and chlorite affect my health? Breathing air containing chlorine dioxide gas can irritate your nose, throat and lungs. There is no evidence that chlorine dioxide or chlorite affects reproduction in humans. Most people will not be exposed to enough chlorine dioxide or chlorite to suffer significant and long-lasting damage.