Article Predominantly Ferruginous Conditions in South China during the Marinoan Glaciation: Insight from REE Geochemistry of the Syn‐glacial Dolostone from the Nantuo Formation in Guizhou Province, China Shangyi Gu 1,*, Yong Fu 1 and Jianxi Long 2 1 College of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, China;
[email protected] 2 Guizhou Geological Survey, Bureau of Geology and Mineral Exploration and Development of Guizhou Province, Guiyang 550081, China; with‐
[email protected] * Correspondence:
[email protected]; Tel.: +86‐0851‐83627126 Received: 23 April 2019; Accepted: 3 June 2019; Published: 5 June 2019 Abstract: The Neoproterozoic Era witnessed two low‐latitude glaciations, which exerted a fundamental influence on ocean‒atmosphere redox conditions and biogeochemical cycling. Climate models and palaeobiological evidence support the belief that open waters provided oases for life that survived snowball Earth glaciations, yet independent geochemical evidence for marine redox conditions during the Marinoan glaciation remains scarce owing to the apparent lack of primary marine precipitates. In this study, we explore variability in rare earth elements (REEs) and trace metal concentrations in dolostone samples of the Cryogenian Nantuo Formation taken from a drill core in South China. Petrological evidence suggests that the dolostone in the Nantuo Formation was formed in near‐shore waters. All the examined dolostone samples featured significant enrichment of manganese (345‒10,890 ppm, average 3488 ppm) and middle rare earth elements (MREEs) (Bell Shape Index: 1.43‒2.16, average 1.76) after being normalized to Post‐Archean Australian Shale (PAAS). Most dolostone samples showed slight to no negative Ce anomalies (Ce*/Ce 0.53‒1.30, average 0.95), as well as positive Eu anomalies (Eu*/Eu 1.77‒3.28, average 1.95).