Neoproterozoic Glaciation in the Mid-Oceanic Realm: an Example from Hemi-Pelagic Mudstones on Llanddwyn Island, Anglesey, UK ⁎ T

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Neoproterozoic Glaciation in the Mid-Oceanic Realm: an Example from Hemi-Pelagic Mudstones on Llanddwyn Island, Anglesey, UK ⁎ T Available online at www.sciencedirect.com Gondwana Research 14 (2008) 105–114 www.elsevier.com/locate/gr Neoproterozoic glaciation in the mid-oceanic realm: An example from hemi-pelagic mudstones on Llanddwyn Island, Anglesey, UK ⁎ T. Kawai a, , B.F. Windley b, M. Terabayashi c, H. Yamamoto d, Y. Isozaki e, S. Maruyama a a Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Meguro, Tokyo 152-8551, Japan b Department of Geology, The University of Leicester, Leicester LE1 7RH, UK c Department of Safety Systems Construction Engineering, Kagawa University, Takamatsu, 761-0396, Japan d Department of Earth and Environmental Sciences, Kagoshima University, Kagoshima 890-0065, Japan e Department of Earth Science & Astronomy, The University of Tokyo, Meguro Tokyo 153-8902, Japan Received 24 August 2007; received in revised form 3 December 2007; accepted 7 December 2007 Available online 3 January 2008 Abstract We report the first occurrence of ice-rafted dropstones in mid-oceanic sediments belonging to an ocean plate stratigraphy within a Neoproterozoic accretionary complex on Llanddwyn Island, Wales, UK. Dropstones of sandstone, chert, and basalt occur as matrix-supported exotic clasts in a 1 m-thick, hemi-pelagic mafic mudstone; the largest clast is 20×25 cm across. These dropstones occur specifically in hemi- pelagic mafic mudstone that is located at the structural top of ocean plate stratigraphy that records a ridge-trench transition; they are supplementary to dropstones associated with extensive tillites reported in shallow marine sequences of continental shelf facies and in back-arc basins. © 2007 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved. Keywords: Dropstone; Pelagic sediment; Accretionary complex; Anglesey; Neoproterozoic 1. Introduction 2008). Associated glacial features include dropstones in deep- water sediments in the current oceans (e.g. Anderson et al., The periodic changes in climatic conditions on the Earth are 1991 in the Ross Sea, Antarctica; Bond and Lotti, 1995 in the responsible for the formation of ice sheets and glaciers near the North Atlantic), and from varved sediments in on-land glacial poles, some of which may migrate to lower latitudes. Such lakes, scratched glacial pavements, and glacial debris in glaciations occurred, most prominently, in the Quaternary, moraines (e.g. Starck and Papa, 2006; England, 1999). Carboniferous, Neoproterozoic and Paleoproterozoic (Evans, Evidence of former glaciations in the Neoproterozoic, is 2000). Neoproterozoic glaciations are the best known for their provided by tillites, scratched pavements, dropstones and widespread extent from high to low latitudes (Evans, 2000, moraines (e.g. Hoffman and Schrag, 2002). The bulk of such 2003; Trindade and Macouin, 2007; see also Maruyama and evidence comes from tillites that were deposited on shallow Santosh, 2008-this issue). marine continental shelves. Only rarely has evidence been found Evidence of glaciations and ambient glacial conditions from of dropstones that were deposited in Neoproterozoic compara- the modern Earth comes largely from extant polar ice sheets and tively deep-water continental slope basins (e.g. Frimmel et al., glaciers that are residual from the main Quaternary glaciation 2002). Least of all, there are no reports of dropstones that (e.g. England, 1999; Forman et al., 2002; see also, van Loon, were deposited in deep-water mid-oceanic sediments, which are likely only preserved in chert or pelagic mudstone accumulated on an ancient oceanic plate (forming the top of ocean plate stratigraphy (OPS) of ophiolites that were emplaced tectonically into accretionary and collisional orogens). Today about 70% of ⁎ Corresponding author. Fax: +81 3 5734 3538. the Earth's surface is covered by sea, thus pelagic environments E-mail address: [email protected] (T. Kawai). are most common. Hence, if global-scale glaciations occurred in 1342-937X/$ - see front matter © 2007 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved. doi:10.1016/j.gr.2007.12.008 106 T. Kawai et al. / Gondwana Research 14 (2008) 105–114 the Neoproterozoic with similar land-sea proportions as today, a considerable glacial record should be preserved in coeval pelagic sediments. The aim of this paper is to report the first occurrence of ice- rafted dropstones in Neoproterozoic hemi-pelagic sediments on Llanddwyn Island, Wales, UK, and to discuss their glacial origin, setting and significance. 2. Geological background The geology of the island of Anglesey was first described comprehensively and in detail by Greenly (1919). Anglesey and the adjacent Lleyn peninsula (Index map of Fig. 2) make up the Mona Complex (Gibbons, 1983), which is a fragment of a Neoproterozoic accretionary orogen that developed from an Avalonian subduction system (Gibbons and Horák, 1996; Horák et al., 1996). The geological map of Anglesey (British Geological Survey, 1980) shows that Anglesey consists of several NE-trending, parallel schist belts ranging in meta- morphic grade from the zeolite through greenschist and amphibolite to blueschist facies. The Gwna Group belts, the subject of this paper, contain a collage of pillow lavas with OPS, mélanges, greenschists, blueschists, and minor quartzites and limestones. Using new metamorphic isograds and structure Kawai et al. (2006) demonstrated that a shallow-dipping slab (nappe) of blueschists is tectonically sandwiched between high- grade gneisses above and low-grade or unmetamorphosed rocks below; these rocks have the structure of an anticlinal nappe, which Kawai et al. (2007) concluded was exhumed from an Avalonian subduction zone. These relations demonstrate that the Mona Complex is an accretionary collage or complex that has similar lithology, structure and evolution to that of a western Pacific-type orogen, best exemplified by the Mesozoic– Cenozoic, accretionary Japanese Islands (Isozaki, 1996; Maruyama, 1997). The dropstone-bearing mudstones and associated cherts of the Gwna Group are unfossiliferous and have not been dated by isotopic techniques, but they form an important part of the accretionary collage of the Mona complex, Anglesey, some parts of which have isotopic ages. The amphibolite facies Coedana gneisses have a U–Pb zircon metamorphic age of 666±7 Ma (Strachan et al., 2007), a c. 1 metre-size clast of muscovite- garnet granite in the Gwna mélange has Rb–Sr ages on Fig. 1. Modified paleomagnetically-constrained reconstruction in latest Neoproter- muscovite of 621±6 Ma and 619±6 Ma (Horák et al., 1996), ozoic time (~565 Ma) after Meert and Lieberman (2008). We interpolate the position the crustal melt Coedana muscovite-garnet granite has a U–Pb of Avalonia, which includes southern Britain, based on paleomagnetic data of zircon crystallization age of 614±4 Ma (Tucker and Pharaoh, 603 Ma Chaldecote volcanic rocks in Southern UK (Vizan et al., 2003) and on 580– 1991), Holland Arms gneisses have a Rb–Sr whole rock iso- 570 Ma Marystown Group in Newfoundland, Canada (McNamara et al., 2001). We chron age of 595±12 Ma (Beckinsale and Thorpe, 1979), also place the position of the Tarim craton according to Zhan et al. (2007).The 40 39 – approximate locations of Gaskiers glacial deposits are also marked: Eg: Egan blueschists have Ar/ Ar phengite ages of 580 590 Ma on Formation in northern Australia (Corkeron and George, 2001), Et: Elatina Formation actinolite concentrates and 560–550 Ma on barroisite/crossie- in southern Australia (Calver et al., 2004), Gs: Gaskiers Formation in Newfoundland rich concentrates (Dallmeyer and Gibbons, 1987), and the South (Bowring et al., 2003), Hk: Hankalchough Formation in NW China (Xiao et al., Stack Group, the last Group to be accreted, has a U–Pb zircon 2004; Condon et al., 2005), JG: Jibalah Group (Kusky and Matsah, 2003; Stern et al., age of 501±10 Ma (Collins and Buchan, 2004). This gamut of 2006), Jh: Jhonson Formation in California (Corsetti and Kaufman, 2003), LC: Loch na Cille Boulder Bed in Scotland (Condon and Prave, 2000; Dempster et al., 2002), isotopic ages demonstrates that the Mona Complex as a whole Mt: Mortensnes Formation in northern Norway (Halverson et al., 2005), Mv: Moelv formed in the Neoproterozoic to Cambrian between 666 Ma FormationinsouthernNorway(Bingen et al., 2005), SA: Serra Azul Formation in and 501 Ma. The best age of the Gwna Group is estimated to be Brazil (Alvarenga et al., 2007), Sq: Squantum Formation in Boston basin 595–550 Ma (see later). (Thompson and Bowring, 2000), ANS; Arabian-Nybian Shield. T. Kawai et al. / Gondwana Research 14 (2008) 105–114 107 3. Tectonic setting created not only the volcanic arc of Avalonia, but also the accretionary Mona Complex of Anglesey in the southern UK Fig. 1 shows a modified paleomagnetically-constrained (Kawaietal.,2007). The paleogeographic position of the southern reconstruction of continental blocks in latest Neoproterozoic time UK within the framework of the Avalonian subduction system (~565 Ma) after Meert and Lieberman, 2008. We interpolate the along the margin of Gondwana has been much discussed (e.g. position of Avalonia (Paleo-southern UK and Newfoundland, Gibbons and Horák, 1996; Torsvik et al., 1996), and constrained Canada) based on the paleomagnetic data from 603 Ma Chaldecote with isotopic (Horák et al., 1996; Strachan et al., 2007)and volcanic rocks in southern England (Vizan et al., 2003) and from paleomagnetic (Vizan et al., 2003) data. 580–570 Ma Marystown Group in Newfoundland, Canada (McNamara et al., 2001). Note that Eastern Avalonia was posi- 4. The Gwna Group on Llanddwyn Island tioned at about 30°S when the Anglesey sediments were deposited. Avalonia that includes present-day southern UK was situated close Part of the Gwna Group (Greenly, 1919)ofaccretionaryorigin to South America and Africa in western Gondwana with a paleo- (Kawai et al., 2007) crops out on Llanddwyn Island (300×700 m), subduction zone and open ocean facing towards it. Subduction had which is off the southwestern coast of Anglesey Island, Wales, UK Fig. 2. A: Geological map of Llanddwyn Island showing the distribution of main lithologies, and the principal structural relations.
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