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Alcohols Combined 1405
ALCOHOLS COMBINED 1405 Formulas: Table 1 MW: Table 1 CAS: Table 2 RTECS: Table 2 METHOD: 1405, Issue 1 EVALUATION: PARTIAL Issue 1: 15 March 2003 OSHA : Table 2 PROPERTIES: Table 1 NIOSH: Table 2 ACGIH: Table 2 COMPOUNDS: (1) n-butyl alcohol (4) n-propyl alcohol (7) cyclohexanol (2) sec-butyl alcohol (5) allyl alcohol (8) isoamyl alcohol (3) isobutyl alcohol (6) diacetone alcohol (9) methyl isobutyl carbinol SYNONYMS: See Table 3. SAMPLING MEASUREMENT SAMPLER: SOLID SORBENT TUBE TECHNIQUE: GAS CHROMATOGRAPHY, FID (Coconut shell charcoal, 100 mg/50 mg) ANALYTE: Compounds above FLOW RATE: 0.01 to 0.2 L/min DESORPTION: 1 mL 5% 2-propanol in CS2 Compounds: (1-3 ) (4-9) VOL-MIN: 2 L 1 L INJECTION -MAX: 10 L 10 L VOLUME: 1 µL SHIPMENT: Routine TEMPERATURE -INJECTION: 220 °C SAMPLE -DETECTOR: 250 - 300 °C STABILITY: See Evaluation of Method. -COLUMN: 35 °C (7 minutes), to 60 °C at 5 °C/minute, hold 5 minutes, up to BLANKS: 2 to 10 field blanks per set 120 °C at 10 °C /minute, hold 3 minutes. CARRIER GAS: He, 4 mL/min ACCURACY COLUMN: Capillary, fused silica, 30 m x 0.32-mm RANGE STUDIED: Not studied [1, 2]. ID; 0.5 µm film polyethylene glycol, DB- wax or equivalent BIAS: Not determined CALIBRATION: Solutions of analyte in eluent (internal OVERALL standard optional) PRECISION (Ö ): Not determined rT RANGE: See EVALUATION OF METHOD. ACCURACY: Not determined ESTIMATED LOD: 1 µg each analyte per sample PRECISION: See EVALUATION OF METHOD. APPLICABILITY: This method may be used to determine two or more of the specified analytes simultaneously. -
The PO Production Chain and Possibilities for Energy Saving
The PO production chain and possibilities for energy saving Public Summary Report Delft, January 2012 Author(s): Ewout Dönszelmann Ab de Buck Harry Croezen Lonneke Wielders Publication Data Bibliographical data: Ewout Dönszelmann, Ab de Buck, Harry Croezen, Lonneke Wielders The PO production chain and possibilities for energy saving Public Summary Delft, CE Delft, January 2012 Energy saving / Chain Management / Products / Chemical industry / Propylene Oxide / Styrene / Iso-butylene FT: Tert-butyl alcohol (TBA) Publication code: 12.2232.12 CE publications are available from www.cedelft.eu. Commissioned by: Agentschap NL Further information on this study can be obtained from the contact person, Ewout Dönszelmann. © copyright, CE Delft, Delft CE Delft Committed to the Environment CE Delft is an independent research and consultancy organisation specialised in developing structural and innovative solutions to environmental problems. CE Delft’s solutions are characterised in being politically feasible, technologically sound, economically prudent and socially equitable. 2 January 2012 2.232.3 – The PO production chain and possibilities for energy saving Contents 1 Introduction 5 1.1 General background 5 1.2 The project 5 1.3 Approach 6 1.4 Reading guide 6 2 The production chains 7 2.1 The two processes 7 2.2 Expanded polystyrene 9 2.3 Polyols 11 2.4 TBA/iso-butylene applications 13 3 Conclusions, recommendations 17 3.1 Conclusions 17 3.2 Recommendations 17 4 Background of the Long-term Agreement Energy Efficiency ETS enterprises (LEE) 19 References 21 3 January 2012 2.232.3 – The PO production chain and possibilities for energy saving 4 January 2012 2.232.3 – The PO production chain and possibilities for energy saving 1 Introduction 1.1 General background The Dutch Industry and the Dutch government have made long term agreements on energy efficiency (LEE) for companies that are under the European Trading Scheme (ETS). -
Lyondellbasell Supervisory Board of Directors for Final Approval (A Necessary Internal B
August 18, 2017 Greg Ollis Superintendent Channelview Independent School District 828 Sheldon Road Channelview, Texas 77530 Re: Certificate for Limitation on Appraised Value of Property for School District Maintenance and Operations Taxes by and between Channelview Independent School District and Lyondell Chemical Company, Application 1199 Dear Superintendent Ollis: On July 20, 2017, the Comptroller issued written notice that Lyondell Chemical Company (applicant) submitted a completed application (Application 1199) for a limitation on appraised value under the provisions of Tax Code Chapter 313.1 This application was originally submitted on June 20, 2017, to the Channelview Independent School District (school district) by the applicant. This presents the results of the Comptroller’s review of the application and determinations required: 1) under Section 313.025(h) to determine if the property meets the requirements of Section 313.024 for eligibility for a limitation on appraised value under Chapter 313, Subchapter B; and 2) under Section 313.025(d), to issue a certificate for a limitation on appraised value of the property and provide the certificate to the governing body of the school district or provide the governing body a written explanation of the Comptroller’s decision not to issue a certificate, using the criteria set out in Section 313.026. Determination required by 313.025(h) Sec. 313.024(a) Applicant is subject to tax imposed by Chapter 171. Sec. 313.024(b) Applicant is proposing to use the property for an eligible project. Sec. 313.024(d) Applicant has committed to create the required number of new qualifying jobs and pay all jobs created that are not qualifying jobs a wage that exceeds the county average weekly wage for all jobs in the county where the jobs are located. -
Long-Term Prospects for Northwest European Refining
LONG-TERM PROSPECTS FOR NORTHWEST EUROPEAN REFINING ASYMMETRIC CHANGE: A LOOMING GOVERNMENT DILEMMA? ROBBERT VAN DEN BERGH MICHIEL NIVARD MAURITS KREIJKES CIEP PAPER 2016 | 01 CIEP is affiliated to the Netherlands Institute of International Relations ‘Clingendael’. CIEP acts as an independent forum for governments, non-governmental organizations, the private sector, media, politicians and all others interested in changes and developments in the energy sector. CIEP organizes lectures, seminars, conferences and roundtable discussions. In addition, CIEP members of staff lecture in a variety of courses and training programmes. CIEP’s research, training and activities focus on two themes: • European energy market developments and policy-making; • Geopolitics of energy policy-making and energy markets CIEP is endorsed by the Dutch Ministry of Economic Affairs, the Dutch Ministry of Foreign Affairs, the Dutch Ministry of Infrastructure and the Environment, BP Europe SE- BP Nederland, Coöperatieve Centrale Raiffeisen-Boerenleenbank B.A. ('Rabobank'), Delta N.V., ENGIE Energie Nederland N.V., ENGIE E&P Nederland B.V., Eneco Holding N.V., EBN B.V., Essent N.V., Esso Nederland B.V., GasTerra B.V., N.V. Nederlandse Gasunie, Heerema Marine Contractors Nederland B.V., ING Commercial Banking, Nederlandse Aardolie Maatschappij B.V., N.V. NUON Energy, TenneT TSO B.V., Oranje-Nassau Energie B.V., Havenbedrijf Rotterdam N.V., Shell Nederland B.V., TAQA Energy B.V.,Total E&P Nederland B.V., Koninklijke Vopak N.V. and Wintershall Nederland B.V. CIEP Energy -
Chapter 13.Pptx
Chapter 13: Alcohols and Phenols 13.1 Structure and Properties of Alcohols C C Alkanes Carbon - Carbon Multiple Bonds Carbon-heteroatom single bonds basic O C C C N C N C X O nitro alkane X= F, Cl, Br, I amines Alkenes Alkyl Halide Chapter 23 OH C C H O C O C C O C C Alkynes phenol alcohols ethers epoxide acidic Chapter 14 H H H C S C C C C S S C C S C C H C C sulfides thiols disulfide H H (thioethers) Arenes 253 Nomenclature of alcohols 1. In general, alcohols are named in the same manner as alkanes; replace the -ane suffix for alkanes with an -ol for alcohols CH3CH2CH2CH3 CH3CH2CH2CH2OH OH butane 1-butanol 2-butanol butan-1-ol butan-2-ol 2. Number the carbon chain so that the hydroxyl group gets the lowest number 3. Number the substituents and write the name listing the substituents in alphabetical order. Many alcohols are named using non-systematic nomenclature H C OH 3 OH OH C OH OH HO OH H3C HO H3C benzyl alcohol allyl alcohol tert-butyl alcohol ethylene glycol glycerol (phenylmethanol) (2-propen-1-ol) (2-methyl-2-propanol) (1,2-ethanediol) (1,2,3-propanetriol) 254 127 Alcohols are classified according to the H R C OH C OH H H degree of substitution of the carbon bearing H H 1° carbon the -OH group methanol primary alcohol primary (1°) : one alkyl substituent R R C OH C OH R R secondary (2°) : two alkyl substituents H R 2° carbon 3° carbon tertiary (3°) : three alkyl substituents secondary alcohol tertiary alcohol Physical properties of alcohols – the C-OH bond of alcohols has a significant dipole moment. -
A New Approach to Prepare Polyethylene Glycol Allyl Glycidyl Ether
E3S Web of Conferences 267, 02004 (2021) https://doi.org/10.1051/e3sconf/202126702004 ICESCE 2021 A new approach to prepare Polyethylene Glycol Allyl Glycidyl Ether Huizhen Wang1*, Ruiyang Xie1, Mingjun Chen1*, Weihao Deng1, Kaixin Zhang2, Jiaqin Liu1 1School of Science, Xihua University, Chengdu 610039, China; 2Chengdu Jingyiqiang Environmental Protection Technology Co., Ltd. Abstract. The polyethylene glycol allyl glycidyl ether (PGAGE) is an important intermediate for preparing silicone softener that can be synthesized from allyl alcohol polyoxyethylene ether and epichlorohydrin (ECH). The performance parameters including the concentration of ECH, initial boron trifluoride diethyl etherate (BFEE) as well as CaCl2 quality were investigated respectively. The optimum process parameters which can get high capping and low by-product rate are as follows: the ECH concentration is 2.0 M, the initial BFEE concentration is 1.65mM, and the CaCl2 dosage is 1.65g/L. Under these conditions, the maximal yield can be improved to 91.36%, the percent of capping rate is higher than 98.16%, the residual concentration of F- is only 0.63 mg/L. concentrated basic solution, in which the total yield was between 90%~91% by Matsuoka et al. [10] also use the 1 Introduction two-step reaction to synthesize AGE based on the reaction Polyethylene glycol allyl glycidyl ether (PGAGE) and the of allyl alcohol with ECH using BFEE as the catalyst. allyl polyoxyethylene ether (APEG), tethering with both Their results demonstrated that the yield reaches 82% alkene and epoxy groups, are widely used as fabric under the following condition: n (ECH) : n (allyl alcohol): finishing agent [1-2] , reactive diluent [3] , cross-linking (catalysis) = 1: (1~3) : (0.01~0.002). -
Title Selective Reduction of Acrolein to Allyl Alcohol by a Vapor Phase
Selective Reduction of Acrolein to Allyl Alcohol by a Vapor Title Phase Hydrogen Transfer Reaction Author(s) Kunichika, Sango; Oka, Shinzaburo; Sakai, Mutsuji Bulletin of the Institute for Chemical Research, Kyoto Citation University (1966), 44(3): 215-220 Issue Date 1966-10-31 URL http://hdl.handle.net/2433/76125 Right Type Departmental Bulletin Paper Textversion publisher Kyoto University Selective Reduction of Acrolein to Allyl Alcohol by a Vapor Phase Hydrogen Transfer Reaction Sango KUNICHIKA,Shinzaburo OKA and Mutsuji SAKAI* (KunichikaLaboratory) (ReceivedJune 15, 1966) Selectivereduction of acroleinto ally! alcoholhas been achievedby a vapor phase hydrogen transferreaction using isopropyl alcohol as a hydrogendonor. It was foundthat the preferredcatalyst was 50 weight% zinc oxide-magnesiumoxide catalyst prepared by calcininga mixtureof zincnitrate and magnesiumoxide at 500°C. The optimumconditions were found to be as follows;reaction tem- perature,near 200°C,total feed rate, 45 moles/1.of catalyst/hr.,feed ratio of isopropylalcohol per acrolein,10 moles. Under theseconditions, the yieldsof allyl alcoholof 80-65% at 80-90% conversion of acroleinwere obtained. INTRODUCTION Acrolein has two reactive functional groups, one is carbonyl group and the other is carbon-carbon double bond. Selective reduction of acrolein to allyl alcohol has been studied by several investigators. The reaction was generally carried out by the following two methods: (1) the Meerwein-Ponndorf-Verley reduction1-3), (2) vapor phase hydrogen transfer reaction with various metal oxide catalysts using an alcohol as a hydrogen donor4-11> The liquid phase reaction has some technical difficulties owing to the polymeri- zation of acrolein especially at high conversion. Therefore, in the present work, the more promising vapor phase reaction has been studied to find an effective catalyst and favorable reaction conditions. -
T-Hydro Tert-Butyl Hydroperoxide (TBHP) Product Safety Bulletin
T-Hydro Tert-Butyl Hydroperoxide (TBHP) Product Safety Bulletin lyondellbasell.com Foreword Lyondell Chemical Company (“Lyondell”), a LyondellBasell company, This Product Safety Bulletin should be evaluated to determine applicability is dedicated to continuous improvement in product health, safety and to your specific requirements. Please make sure you review the environmental performance. Included in this effort is a commitment to government regulations, industry standards and guidelines cited in this support our customers by providing guidance and information on the safe bulletin that might have an impact on your operations. use of our products. For Lyondell, environmentally sound operations, like Lyondell is ready to support our customers’ safe use of our products. For environmentally sound products, make good business sense. additional information and assistance, please contact your LyondellBasell Lyondell Product Safety Bulletins are prepared by our Environmental, customer representative. Health and Safety Department with the help of experts from our LyondellBasell is a member of SPI’s Organic Peroxide Producers Safety manufacturing and research facilities. The data reflect the best Division (OPPSD). information available from public and industry sources. This document is provided to support the safe handling, use, storage, transportation and March 2016 ultimate disposal of our chemical products. Telephone numbers for transportation emergencies: CHEMTREC +1-800-424-9300 International (call collect) +1-703-527-3887 or CANUTEC (in Canada) -
Conversion of Glycerol Into Allyl Alcohol Over Potassium-Supported Zirconia-Iron Oxide Catalyst
Title Conversion of glycerol into allyl alcohol over potassium-supported zirconia-iron oxide catalyst Author(s) Konaka, Aya; Tago, Teruoki; Yoshikawa, Takuya; Nakamura, Ayaka; Masuda, Takao Applied catalysis b-environmental, 146, 267-273 Citation https://doi.org/10.1016/j.apcatb.2013.03.007 Issue Date 2014-03 Doc URL http://hdl.handle.net/2115/54715 Type article (author version) File Information Manuscript_Glycerol to Allyl Alcohol .pdf Instructions for use Hokkaido University Collection of Scholarly and Academic Papers : HUSCAP Conversion of Glycerol into Allyl Alcohol over Potassium-Supported Zirconia-Iron Oxide Catalyst Aya Konaka, Teruoki Tago*, Takuya Yoshikawa, Ayaka Nakamura, and Takao Masuda Research Group of Chemical Engineering, Division of Chemical Process Engineering, Faculty of Engineering, Hokkaido University, N13W8, Kita-ku, Sapporo, Hokkaido, Japan 060-8628 * Corresponding author should be addressed E-mail: [email protected] Tel: +81-11-706-6551 Fax: +81-11-706-6552 1 Abstract The catalytic conversion of glycerol was performed with iron oxide-based catalysts for production of allyl alcohol using a fixed-bed flow reactor at 623 K under atmospheric pressure. The glycerol dehydration proceeds on acid sites of catalysts while the allyl alcohol production is assumed to be catalyzed by non-acidic sites of catalysts through a hydrogen transfer mechanism. Different alkali metals, including Na, K, Rb, and Cs were supported on ZrO2-FeOX and all of them gave impressively higher allyl alcohol yield and suppressed glycerol dehydration due to the reduced catalyst acidic property. K-supported ZrO2-FeOX (K/ZrO2-FeOX) was chosen for further studies, and allyl alcohol yield remarkably increased up to 27 mol%-C at the K content of 3-5 mol%. -
United States Patent (19) (11) Patent Number: 4,968,451 Scheibel Et Al
United States Patent (19) (11) Patent Number: 4,968,451 Scheibel et al. 45) Date of Patent: Nov. 6, 1990 (54) SOIL RELEASE AGENTS HAVING ALLYL-DERVED SULFONATED END CAPS FOREIGN PATENT DOCUMENTS 155710 9/1985 European Pat. Off. (75) Inventors: Jeffrey J. Scheibel; Eugene P. 180356 5/1986 European Pat. Off. Gosselink, both of Cincinnati, Ohio 1475798 6/1977 United Kingdom . (73) Assignee: The Procter & Gamble Company, OTHER PUBLICATIONS Cincinnati, Ohio S. C. Bright, C. E. Stubbs and L. Thompson, J. Appl. (21) Appl. No.: 474,709 Chem. Biotechnol, 1975, vol. 25, pp. 901-912. 22) Filed: Jan. 29, 1990 Norton et al., J. Org. Chem, vol. 33, No. 11, pp. 4158-4165 (1967). Related U.S. Application Data Primary Examiner-A. Lionel Clingman (63) Continuation of Ser. No. 237,598, Aug. 26, 1988, aban Attorney, Agent, or Firm-Leonard W. Lewis; Jerry J. doned. Yetter (51 Int, C. .................... CO7C 309/05; C08G 63/68; 57 ABSTRACT C11D 3/37 (52) U.S. C. ............................... 252/549; 252/174.19; The present invention relates to novel soil release 252/539; 252/558; 252/DIG. 15 agents, which are particular sulfonated linear tere (58) Field of Search ......................................... 252/549 phthalate ester oligomers (S.T.E. oligomers). The S.T.E. oligomers are especially suitable for formulation (56 References Cited into laundry products such as laundry detergents or U.S. PATENT DOCUMENTS fabric conditioners. Thus formulated, they provide ef. 3,821,169 6/1974 Duddey et al. ..................... 528/293 fective soil release treatments for fabrics laundered in 4,156,073 5/1979 Login ............. -
Tcc/Acit Spring Meeting
Association of Chemical Industry of Texas 2020 TCC-ACIT Industry Awards 2020 has been a remarkable year that has disrupted our lives in so many ways. One of these disruptions is the forced cancellation of our 2020 EHS Seminar and our 2020 Awards Banquet. While we were forced to cancel our Awards Banquet, we are not thwarted in our efforts to recognize our members for excellent safety performance, caring for Texas, and support for our industry. Our award committees have completed their judging and we are honored to recognize the winners of our 2020 TCC-ACIT Awards. Our winners have been notified and will be receiving their awards soon. Our top award winners will also be recognized in BIC Magazine and on BIC’s social media. CARING FOR TEXAS AWARDS The Caring for Texas Awards were adopted by the TCC Board of Directors in 1998, and the awards program is administered by our TCC Outreach Committee. The Outreach Committee is made up of member company volunteers who are dedicated to community outreach and educating the public about the importance of the chemical industry, and our industry’s commitment to our communities and environmental stewardship. The objective of the TCC Caring for Texas awards program is to promote continuous improvement by the chemical industry relative to their performance in community awareness, emergency response, security and pollution prevention. The program provides recognition for member facilities that, during the previous calendar year, have achieved exemplary results and demonstrated a strong commitment to their employees and their community. We also invite members from our local Community Advisory Panels to serve as judges for the Caring for Texas Awards. -
Annual Report 2020
EMERGING STRONGER Annual Report 2020 Hyperzone HDPE Plant Houston, Texas, U.S. www.lyondellbasell.com 2 LyondellBasell Message from the CEO To the owners of our company, continues to serve us well allowing us to deliver on our three priorities. Without a doubt, the past year has been one of the most challenging periods in recent memory: In addition to leveraging these historical a global pandemic; a dramatic decline in oil strengths, we have been further expanding our prices; a rapidly accelerating energy transition; core competencies to include M&A execution civil unrest around the world; and a weakened and a focus on extracting value from integration global economy that continues to impact activities. Altogether, our asset base, existing millions of individuals and families. As I write, operational models and expanded skillsets the seasons have changed and the calendar has position us well to benefit from an economic turned, yet many of the challenges that began recovery. in 2020 remain in front of us in 2021. Like our industry peers, in 2020 we were not Early in 2020, as the virus became more immune to the challenges of the macro- widespread, our leadership team established environment. Yet, because of our very deliberate three principles to guide our company’s actions approach, we were able to deliver $1.4 billion Bhavesh V. (Bob) Patel in the short term. These were to: of net income, $3.9 billion of EBITDA excluding LCM and impairment1, $5.61 diluted earnings Chief Executive Officer ❙ Protect our employees, both from the virus per share excluding LCM and impairment1 and in the workplace and also from widespread $3.4 billion of cash from operating activities.