Hydrostatics
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On Entropy, Information, and Conservation of Information
entropy Article On Entropy, Information, and Conservation of Information Yunus A. Çengel Department of Mechanical Engineering, University of Nevada, Reno, NV 89557, USA; [email protected] Abstract: The term entropy is used in different meanings in different contexts, sometimes in contradic- tory ways, resulting in misunderstandings and confusion. The root cause of the problem is the close resemblance of the defining mathematical expressions of entropy in statistical thermodynamics and information in the communications field, also called entropy, differing only by a constant factor with the unit ‘J/K’ in thermodynamics and ‘bits’ in the information theory. The thermodynamic property entropy is closely associated with the physical quantities of thermal energy and temperature, while the entropy used in the communications field is a mathematical abstraction based on probabilities of messages. The terms information and entropy are often used interchangeably in several branches of sciences. This practice gives rise to the phrase conservation of entropy in the sense of conservation of information, which is in contradiction to the fundamental increase of entropy principle in thermody- namics as an expression of the second law. The aim of this paper is to clarify matters and eliminate confusion by putting things into their rightful places within their domains. The notion of conservation of information is also put into a proper perspective. Keywords: entropy; information; conservation of information; creation of information; destruction of information; Boltzmann relation Citation: Çengel, Y.A. On Entropy, 1. Introduction Information, and Conservation of One needs to be cautious when dealing with information since it is defined differently Information. Entropy 2021, 23, 779. -
Lecture 5: Saturn, Neptune, … A. P. Ingersoll [email protected] 1
Lecture 5: Saturn, Neptune, … A. P. Ingersoll [email protected] 1. A lot a new material from the Cassini spacecraft, which has been in orbit around Saturn for four years. This talk will have a lot of pictures, not so much models. 2. Uranus on the left, Neptune on the right. Uranus spins on its side. The obliquity is 98 degrees, which means the poles receive more sunlight than the equator. It also means the sun is almost overhead at the pole during summer solstice. Despite these extreme changes in the distribution of sunlight, Uranus is a banded planet. The rotation dominates the winds and cloud structure. 3. Saturn is covered by a layer of clouds and haze, so it is hard to see the features. Storms are less frequent on Saturn than on Jupiter; it is not just that clouds and haze makes the storms less visible. Saturn is a less active planet. Nevertheless the winds are stronger than the winds of Jupiter. 4. The thickness of the atmosphere is inversely proportional to gravity. The zero of altitude is where the pressure is 100 mbar. Uranus and Neptune are so cold that CH forms clouds. The clouds of NH3 , NH4SH, and H2O form at much deeper levels and have not been detected. 5. Surprising fact: The winds increase as you move outward in the solar system. Why? My theory is that power/area is smaller, small‐scale turbulence is weaker, dissipation is less, and the winds are stronger. Jupiter looks more turbulent, and it has the smallest winds. -
Thermodynamics Notes
Thermodynamics Notes Steven K. Krueger Department of Atmospheric Sciences, University of Utah August 2020 Contents 1 Introduction 1 1.1 What is thermodynamics? . .1 1.2 The atmosphere . .1 2 The Equation of State 1 2.1 State variables . .1 2.2 Charles' Law and absolute temperature . .2 2.3 Boyle's Law . .3 2.4 Equation of state of an ideal gas . .3 2.5 Mixtures of gases . .4 2.6 Ideal gas law: molecular viewpoint . .6 3 Conservation of Energy 8 3.1 Conservation of energy in mechanics . .8 3.2 Conservation of energy: A system of point masses . .8 3.3 Kinetic energy exchange in molecular collisions . .9 3.4 Working and Heating . .9 4 The Principles of Thermodynamics 11 4.1 Conservation of energy and the first law of thermodynamics . 11 4.1.1 Conservation of energy . 11 4.1.2 The first law of thermodynamics . 11 4.1.3 Work . 12 4.1.4 Energy transferred by heating . 13 4.2 Quantity of energy transferred by heating . 14 4.3 The first law of thermodynamics for an ideal gas . 15 4.4 Applications of the first law . 16 4.4.1 Isothermal process . 16 4.4.2 Isobaric process . 17 4.4.3 Isosteric process . 18 4.5 Adiabatic processes . 18 5 The Thermodynamics of Water Vapor and Moist Air 21 5.1 Thermal properties of water substance . 21 5.2 Equation of state of moist air . 21 5.3 Mixing ratio . 22 5.4 Moisture variables . 22 5.5 Changes of phase and latent heats . -
Practice Problems from Chapter 1-3 Problem 1 One Mole of a Monatomic Ideal Gas Goes Through a Quasistatic Three-Stage Cycle (1-2, 2-3, 3-1) Shown in V 3 the Figure
Practice Problems from Chapter 1-3 Problem 1 One mole of a monatomic ideal gas goes through a quasistatic three-stage cycle (1-2, 2-3, 3-1) shown in V 3 the Figure. T1 and T2 are given. V 2 2 (a) (10) Calculate the work done by the gas. Is it positive or negative? V 1 1 (b) (20) Using two methods (Sackur-Tetrode eq. and dQ/T), calculate the entropy change for each stage and ∆ for the whole cycle, Stotal. Did you get the expected ∆ result for Stotal? Explain. T1 T2 T (c) (5) What is the heat capacity (in units R) for each stage? Problem 1 (cont.) ∝ → (a) 1 – 2 V T P = const (isobaric process) δW 12=P ( V 2−V 1 )=R (T 2−T 1)>0 V = const (isochoric process) 2 – 3 δW 23 =0 V 1 V 1 dV V 1 T1 3 – 1 T = const (isothermal process) δW 31=∫ PdV =R T1 ∫ =R T 1 ln =R T1 ln ¿ 0 V V V 2 T 2 V 2 2 T1 T 2 T 2 δW total=δW 12+δW 31=R (T 2−T 1)+R T 1 ln =R T 1 −1−ln >0 T 2 [ T 1 T 1 ] Problem 1 (cont.) Sackur-Tetrode equation: V (b) 3 V 3 U S ( U ,V ,N )=R ln + R ln +kB ln f ( N ,m ) V2 2 N 2 N V f 3 T f V f 3 T f ΔS =R ln + R ln =R ln + ln V V 2 T V 2 T 1 1 i i ( i i ) 1 – 2 V ∝ T → P = const (isobaric process) T1 T2 T 5 T 2 ΔS12 = R ln 2 T 1 T T V = const (isochoric process) 3 1 3 2 2 – 3 ΔS 23 = R ln =− R ln 2 T 2 2 T 1 V 1 T 2 3 – 1 T = const (isothermal process) ΔS 31 =R ln =−R ln V 2 T 1 5 T 2 T 2 3 T 2 as it should be for a quasistatic cyclic process ΔS = R ln −R ln − R ln =0 cycle 2 T T 2 T (quasistatic – reversible), 1 1 1 because S is a state function. -
Introduction to Hydrostatics
Introduction to Hydrostatics Hydrostatics Equation The simplified Navier Stokes equation for hydrostatics is a vector equation, which can be split into three components. The convention will be adopted that gravity always acts in the negative z direction. Thus, and the three components of the hydrostatics equation reduce to Since pressure is now only a function of z, total derivatives can be used for the z-component instead of partial derivatives. In fact, this equation can be integrated directly from some point 1 to some point 2. Assuming both density and gravity remain nearly constant from 1 to 2 (a reasonable approximation unless there is a huge elevation difference between points 1 and 2), the z- component becomes Another form of this equation, which is much easier to remember is This is the only hydrostatics equation needed. It is easily remembered by thinking about scuba diving. As a diver goes down, the pressure on his ears increases. So, the pressure "below" is greater than the pressure "above." Some "rules" to remember about hydrostatics Recall, for hydrostatics, pressure can be found from the simple equation, There are several "rules" or comments which directly result from the above equation: If you can draw a continuous line through the same fluid from point 1 to point 2, then p1 = p2 if z1 = z2. For example, consider the oddly shaped container below: By this rule, p1 = p2 and p4 = p5 since these points are at the same elevation in the same fluid. However, p2 does not equal p3 even though they are at the same elevation, because one cannot draw a line connecting these points through the same fluid. -
Lecture 4: 09.16.05 Temperature, Heat, and Entropy
3.012 Fundamentals of Materials Science Fall 2005 Lecture 4: 09.16.05 Temperature, heat, and entropy Today: LAST TIME .........................................................................................................................................................................................2� State functions ..............................................................................................................................................................................2� Path dependent variables: heat and work..................................................................................................................................2� DEFINING TEMPERATURE ...................................................................................................................................................................4� The zeroth law of thermodynamics .............................................................................................................................................4� The absolute temperature scale ..................................................................................................................................................5� CONSEQUENCES OF THE RELATION BETWEEN TEMPERATURE, HEAT, AND ENTROPY: HEAT CAPACITY .......................................6� The difference between heat and temperature ...........................................................................................................................6� Defining heat capacity.................................................................................................................................................................6� -
Entropy: Ideal Gas Processes
Chapter 19: The Kinec Theory of Gases Thermodynamics = macroscopic picture Gases micro -> macro picture One mole is the number of atoms in 12 g sample Avogadro’s Number of carbon-12 23 -1 C(12)—6 protrons, 6 neutrons and 6 electrons NA=6.02 x 10 mol 12 atomic units of mass assuming mP=mn Another way to do this is to know the mass of one molecule: then So the number of moles n is given by M n=N/N sample A N = N A mmole−mass € Ideal Gas Law Ideal Gases, Ideal Gas Law It was found experimentally that if 1 mole of any gas is placed in containers that have the same volume V and are kept at the same temperature T, approximately all have the same pressure p. The small differences in pressure disappear if lower gas densities are used. Further experiments showed that all low-density gases obey the equation pV = nRT. Here R = 8.31 K/mol ⋅ K and is known as the "gas constant." The equation itself is known as the "ideal gas law." The constant R can be expressed -23 as R = kNA . Here k is called the Boltzmann constant and is equal to 1.38 × 10 J/K. N If we substitute R as well as n = in the ideal gas law we get the equivalent form: NA pV = NkT. Here N is the number of molecules in the gas. The behavior of all real gases approaches that of an ideal gas at low enough densities. Low densitiens m= enumberans tha oft t hemoles gas molecul es are fa Nr e=nough number apa ofr tparticles that the y do not interact with one another, but only with the walls of the gas container. -
ATMOSPHERIC and OCEANIC FLUID DYNAMICS Fundamentals and Large-Scale Circulation
ATMOSPHERIC AND OCEANIC FLUID DYNAMICS Fundamentals and Large-Scale Circulation Geoffrey K. Vallis Contents Preface xi Part I FUNDAMENTALS OF GEOPHYSICAL FLUID DYNAMICS 1 1 Equations of Motion 3 1.1 Time Derivatives for Fluids 3 1.2 The Mass Continuity Equation 7 1.3 The Momentum Equation 11 1.4 The Equation of State 14 1.5 The Thermodynamic Equation 16 1.6 Sound Waves 29 1.7 Compressible and Incompressible Flow 31 1.8 * More Thermodynamics of Liquids 33 1.9 The Energy Budget 39 1.10 An Introduction to Non-Dimensionalization and Scaling 43 2 Effects of Rotation and Stratification 51 2.1 Equations in a Rotating Frame 51 2.2 Equations of Motion in Spherical Coordinates 55 2.3 Cartesian Approximations: The Tangent Plane 66 2.4 The Boussinesq Approximation 68 2.5 The Anelastic Approximation 74 2.6 Changing Vertical Coordinate 78 2.7 Hydrostatic Balance 80 2.8 Geostrophic and Thermal Wind Balance 85 2.9 Static Instability and the Parcel Method 92 2.10 Gravity Waves 98 v vi Contents 2.11 * Acoustic-Gravity Waves in an Ideal Gas 100 2.12 The Ekman Layer 104 3 Shallow Water Systems and Isentropic Coordinates 123 3.1 Dynamics of a Single, Shallow Layer 123 3.2 Reduced Gravity Equations 129 3.3 Multi-Layer Shallow Water Equations 131 3.4 Geostrophic Balance and Thermal wind 134 3.5 Form Drag 135 3.6 Conservation Properties of Shallow Water Systems 136 3.7 Shallow Water Waves 140 3.8 Geostrophic Adjustment 144 3.9 Isentropic Coordinates 152 3.10 Available Potential Energy 155 4 Vorticity and Potential Vorticity 165 4.1 Vorticity and Circulation 165 -
Module 2: Hydrostatics
Module 2: Hydrostatics . Hydrostatic pressure and devices: 2 lectures . Forces on surfaces: 2.5 lectures . Buoyancy, Archimedes, stability: 1.5 lectures Mech 280: Frigaard Lectures 1-2: Hydrostatic pressure . Should be able to: . Use common pressure terminology . Derive the general form for the pressure distribution in static fluid . Calculate the pressure within a constant density fluids . Calculate forces in a hydraulic press . Analyze manometers and barometers . Calculate pressure distribution in varying density fluid . Calculate pressure in fluids in rigid body motion in non-inertial frames of reference Mech 280: Frigaard Pressure . Pressure is defined as a normal force exerted by a fluid per unit area . SI Unit of pressure is N/m2, called a pascal (Pa). Since the unit Pa is too small for many pressures encountered in engineering practice, kilopascal (1 kPa = 103 Pa) and mega-pascal (1 MPa = 106 Pa) are commonly used . Other units include bar, atm, kgf/cm2, lbf/in2=psi . 1 psi = 6.695 x 103 Pa . 1 atm = 101.325 kPa = 14.696 psi . 1 bar = 100 kPa (close to atmospheric pressure) Mech 280: Frigaard Absolute, gage, and vacuum pressures . Actual pressure at a give point is called the absolute pressure . Most pressure-measuring devices are calibrated to read zero in the atmosphere. Pressure above atmospheric is called gage pressure: Pgage=Pabs - Patm . Pressure below atmospheric pressure is called vacuum pressure: Pvac=Patm - Pabs. Mech 280: Frigaard Pressure at a Point . Pressure at any point in a fluid is the same in all directions . Pressure has a magnitude, but not a specific direction, and thus it is a scalar quantity . -
Chapter 7 Balanced Flow
Chapter 7 Balanced flow In Chapter 6 we derived the equations that govern the evolution of the at- mosphere and ocean, setting our discussion on a sound theoretical footing. However, these equations describe myriad phenomena, many of which are not central to our discussion of the large-scale circulation of the atmosphere and ocean. In this chapter, therefore, we focus on a subset of possible motions known as ‘balanced flows’ which are relevant to the general circulation. We have already seen that large-scale flow in the atmosphere and ocean is hydrostatically balanced in the vertical in the sense that gravitational and pressure gradient forces balance one another, rather than inducing accelera- tions. It turns out that the atmosphere and ocean are also close to balance in the horizontal, in the sense that Coriolis forces are balanced by horizon- tal pressure gradients in what is known as ‘geostrophic motion’ – from the Greek: ‘geo’ for ‘earth’, ‘strophe’ for ‘turning’. In this Chapter we describe how the rather peculiar and counter-intuitive properties of the geostrophic motion of a homogeneous fluid are encapsulated in the ‘Taylor-Proudman theorem’ which expresses in mathematical form the ‘stiffness’ imparted to a fluid by rotation. This stiffness property will be repeatedly applied in later chapters to come to some understanding of the large-scale circulation of the atmosphere and ocean. We go on to discuss how the Taylor-Proudman theo- rem is modified in a fluid in which the density is not homogeneous but varies from place to place, deriving the ‘thermal wind equation’. Finally we dis- cuss so-called ‘ageostrophic flow’ motion, which is not in geostrophic balance but is modified by friction in regions where the atmosphere and ocean rubs against solid boundaries or at the atmosphere-ocean interface. -
Lecture 6: Entropy
Matthew Schwartz Statistical Mechanics, Spring 2019 Lecture 6: Entropy 1 Introduction In this lecture, we discuss many ways to think about entropy. The most important and most famous property of entropy is that it never decreases Stot > 0 (1) Here, Stot means the change in entropy of a system plus the change in entropy of the surroundings. This is the second law of thermodynamics that we met in the previous lecture. There's a great quote from Sir Arthur Eddington from 1927 summarizing the importance of the second law: If someone points out to you that your pet theory of the universe is in disagreement with Maxwell's equationsthen so much the worse for Maxwell's equations. If it is found to be contradicted by observationwell these experimentalists do bungle things sometimes. But if your theory is found to be against the second law of ther- modynamics I can give you no hope; there is nothing for it but to collapse in deepest humiliation. Another possibly relevant quote, from the introduction to the statistical mechanics book by David Goodstein: Ludwig Boltzmann who spent much of his life studying statistical mechanics, died in 1906, by his own hand. Paul Ehrenfest, carrying on the work, died similarly in 1933. Now it is our turn to study statistical mechanics. There are many ways to dene entropy. All of them are equivalent, although it can be hard to see. In this lecture we will compare and contrast dierent denitions, building up intuition for how to think about entropy in dierent contexts. The original denition of entropy, due to Clausius, was thermodynamic. -
Hydrostatic Leveling Systems 19
© 1965 IEEE. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be obtained from the IEEE. 1965 PELISSIER: HYDROSTATIC LEVELING SYSTEMS 19 HYDROSTATIC LEVELING SYSTEMS” Pierre F. Pellissier Lawrence Radiation Laboratory University of California Berkeley, California March 5, 1965 Summarv is accurate to *0.002 in. in 50 ft when used with care. (It is worthy of note that “level” at the The 200-BeV proton synchrotron being pro- earth’s surface is in practice a fairly smooth posed by the Lawrence Radiation Laboratory is curve which deviates from a tangent by 0.003 in. about 1 mile in diameter. The tolerance for ac- in 100 ft. When leveling by any method one at- curacy in vertical placement of magnets is tempts to precisely locate this curved surface. ) *0.002 inches. Because conventional high-pre- cision optical leveling to this accuracy is very De sign time consuming, an alternative method using an extended mercury-filled system has been deve- The design of an extended hydrostatic level is loped at LRL. This permanently installed quite straightforward. The fundamental princi- reference system is expected to be accurate ple of hydrostatics which applies must be stated within +O.OOl in. across the l-mile diameter quite carefully at the outset: the free surface of machine, a liquid-or surfaces, if interconnected by liquid- filled tubes-will lie on a gravitational equipoten- Review of Commercial Devices tial if all forces and gradients except gravity are excluded from the system.