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The 17Th International Conference on Molecule-Based Magnets Online The 17th International Conference on Molecule-based Magnets Online via The University of Manchester 14 - 18 June 2021 Sponsors 2 Knowledge for your next step forward Volume 9 Number 1 7 January 2018 C h e m i c a l Pages 1-268 C h e m i c a l S c i e n c e S c i e n c e rsc.li/chemical-science Open and free, for authors and readers The Royal Society of Chemistry’s flagship journal introduces primary research in all fields to a global readership Editor-in-chief ISSN 2041-6539 EDGE ARTICLE Andrew Cooper University of Liverpool, UK Xinjing Tang et al. Caged circular siRNAs for photomodulation of gene expression in cells and mice Submit your work rsc.li/chemical-science @ChemicalScience Volume 46 Number 10 14 March 2017 D a l t o n Pages 3073-3412 Dalton Transactions T r a n s a c t i o n s An international journal of inorganic chemistry rsc.li/dalton The international journal for high quality, original research in inorganic and organometallic chemistry Fast times to publication mean rapid visibility for your work Editorial Board Chair Russell Morris University of St Andrews, UK ISSN 0306-0012 COMMUNICATION Douglas W. Stephen et al. Submit your work N-Heterocyclic carbene stabilized parent sulfenyl, selenenyl, and tellurenyl cations (XH+, X = S, Se, Te) rsc.li/dalton @DaltonTrans Get journal updates: rsc.li/alerts Registered charity number: 207890 Contents Sponsors ..................................................................................................................................... 2 Contents ..................................................................................................................................... 3 Programme ................................................................................................................................. 4 Prof. Keith Murray: Olivier Kahn Lecture ..................................................................................... 5 Prof. Ania Bleszynski Jayich: Plenary Lecture............................................................................... 6 Prof. Daniella Goldfarb: Plenary Lecture ..................................................................................... 7 Prof. David Leigh: Plenary Lecture .............................................................................................. 8 Prof. Hiroki Oshio: Quantum Design Lecture ............................................................................... 9 Invited and Contributed Talks ................................................................................................... 10 Poster Timetable ...................................................................................................................... 66 Posters ..................................................................................................................................... 72 3 Programme UK Japan USA Monday 14th June Tuesday 15th June Wednesday 16th June Thursday 17th June Friday 18th June (UTC+1) (UTC+9) (UTC-7) Zoom Webinar link zoom.us/j/91924643361 zoom.us/j/91924643361 zoom.us/j/91924643361 zoom.us/j/91924643361 zoom.us/j/91924643361 Session chair Winpenny/Chilton Takeji Takui Eugenio Coronado Euan Brechin Malcolm Halcrow 09.00 17.00 01.00 Olivier Kahn Lecture: Plenary: Quantum Design Lecture: Shinya Hayami Annie Powell 09.30 17.30 01.30 Prof. Keith Murray Prof. Daniella Goldfarb Prof. Hiroki Oshio Colette Boskovic Matteo Briganti 09.50 17.50 01.50 Shin-ichi Ohkoshi Osamu Sato Elizaveta Suturina Rodolphe Clérac José Real 10.20 18.20 02.20 Elena Garlatti Yan-Zhen Zheng Yoji Horii Shang-Da Jiang Zhongyue Zhang 10.40 18.40 02.40 Coffee Coffee Coffee Coffee Session chair Li-Min Zheng Jürgen Schnack Victor Ovcharenko Gopalan Rajaraman Richard Winpenny 11.00 19.00 03.00 Qi Zhang Tao Liu Ramasamy Murugavel Ming-Liang Tong Hitoshi Miyasaka 11.30 19.30 03.30 Vadapalli Chandrasekhar Yasunao Otsuki Kasper Pedersen Salvador Cardona-Serra Abhishake Mondal 11.50 19.50 03.50 Lorenzo Sorace POSTER SESSION 2 POSTER SESSION 3 Shu-Qi Wu Zhilin Guo Rm 1-10: Rm 1-10: 12.10 20.10 04.10 Matvey Fedin zoom.us/j/93234805108 zoom.us/j/93234805108 Matteo Mannini Sergey Veber Rm 11-20: Rm 11-20: zoom.us/j/93990174843 zoom.us/j/93990174843 RSC journal pres. 12.40 20.40 04.40 Lunch Lunch Lunch Lunch CLOSE: POSTER PRIZES BREAK Zoom Webinar link zoom.us/j/91924643361 zoom.us/j/91924643361 zoom.us/j/91924643361 zoom.us/j/91924643361 Session chair Joel Miller Roberta Sessoli Talal Mallah Tatiana Guidi 16.30 00.30 08.30 Plenary: Plenary: Miguel Novak Theodore Betley 17.00 01.00 09.00 Prof. Ania Jayich Prof. David Leigh Selvan Demir Lucie Norel 17.20 01.20 09.20 Randall McClain Kathryn Preuss Danna Freedman Mark Murrie 17.50 01.50 09.50 Magdalena Owczarek Carolina Sañudo George Christou Daniel Reta 18.10 02.10 10.10 Coffee Coffee Coffee Coffee Session chair Miguel Novak Rodolphe Clérac Stephen Hill Eric McInnes 18.30 02.30 10.30 Oscar Cespedes Mark Pederson Nathalie Guihéry Stefano Carretta 19.00 03.00 11.00 Silas Hoffman Eufemio Moreno-Pineda Mario Piedrahita-Bello Daphné Lubert-Perquel 19.20 03.20 11.20 Quantum Design pres. Natia Frank Hélène Bolvin Alessandro Lunghi POSTER SESSION 1 19.40 03.40 11.40 Rm 1-7 + Quant. Des.: PhiliP Willke Eric Switzer Laura Cañadillas-Delgado zoom.us/j/93870750691 CLOSE: POSTER PRIZES Rm 8-14: zoom.us/j/97439940767 Rm 15-20: zoom.us/j/91766287448 20.20 04.20 12.20 CLOSE 4 Prof. Keith Murray: Olivier Kahn Lecture New examples of lanthanide containing single molecule toroics (SMTs) and of d- f heterometallics Keith Murray1, Ivana Borilovic1, Stuart Langley2, Kuduva Vignesh3, Gopalan Rajaraman4, Jared Ashtree5, Alessandro Soncini5, Wolfgang Wernsdorfer6 1Monash University, Clayton, Australia. 2Manchester Metropolitan University, Manchester, United Kingdom. 3Institute of Molecular Science, Okazaki, Japan. 4IITB, Mumbai, India. 5University of Melbourne, Melbourne, Australia. 6Karlsruhe Institute of Technology, Karlsruhe, Germany Abstract Single molecule toroics (SMTs) are a sub topic of single molecule magnets. They generally consist of molecular rings (triangles, squares, hexagons) of lanthanide(III) ions, particularly of dysprosium, but there are recent examples of non-ring systems. The pioneering work by Powell, Chibotaru, et al. on µ3-OH bridged Dy3 triangles revealed the requisite molecular geometry, the directions of the magnetic moments on each Dy, the nature of magnetisation vs. field plots (often S-shaped) and relevant theory.1 From a more applied perspective, SMTs offer possible uses in quantum information processing, high-density data storage and as nanoscale devices such as molecular spin valves and spin transistors. III III III A novel class of “double triangles” of type [Dy 6M (OH)8(o-tol)12(MeOH)5(NO3)]·4MeOH, where M = 2 III Cr, Mn, Fe, Co, Al, o-tol = o-toluate, in which the M ion bridges the two Dy3 triangles in a MO6 coordination environment (see Fig.). The parent CrIII system2a showed a rare ferrotoroidal arrangement of the toroidal moments on each triangle. Comparisons will be made2b to the new MIII-bridged materials which include paramagnetic MnIII and FeIII and diamagnetic CoIII and p-block AlIII. New theory has allowed simulation of their microSquid hysteresis loops. 1. (a) J. Tang, I. Hewitt, N. T. Madhu, G. Chastanet, W. Wernsdorfer, C. E. Anson, C. Benelli, R. Sessoli, A. K. Powell, Angew. Chem. Int. Ed., 2006, 45, 1729-1733. (b) L. F. Chibotaru, L. Ungur, A. Soncini, Angew. Chem. Int. Ed., 2008, 47, 4126-4129. 2. (a) K. R. Vignesh, A. Soncini, S. K. Langley, W. Wernsdorfer, K. S. Murray, G. Rajaraman, Nat. Commun., 2017, 8, 1023. (b) J. M. Ashtree, I. Borilović, K. R. Vignesh, A. Swain, S. H. Hamilton, Y. L. Whyatt, S. L. Benjamin, W. Phonsri, C. M. Forsyth, W. Wernsdorfer, A. Soncini, G. Rajaraman, S. K. Langley, K. S. Murray, Eur. J. Inorg. Chem. 2021, 435-444. 5 Prof. Ania Jayich: Plenary Lecture Quantum sensing and imaging with diamond spins Ania Bleszynski Jayich1, Maxime Joos1, Simon Meynell1, Daipeng Yang1, Dolev Bluvstein1,2, Alec Jenkins1,3, Susanne Baumann4, Zhiran Zhang1 1UC Santa Barbara, Santa Barbara, USA. 2Harvard University, Boston, USA. 3University of Colorado, Boulder, USA. 4Max Planck Institute, Stuttgart, Germany Abstract Solid state spin qubits, in particular the nitrogen vacancy (NV) center in diamond, offer a path towards truly nanoscale imaging of condensed matter and biological systems with sensitivity to single nuclear spins. Here I discuss our NV-based magnetic imaging experiments as applied to condensed matter systems, where we have imaged current flow patterns in graphene as well as skyrmions, nanoscale spin textures. A grand challenge to improving the spatial resolution and magnetic sensitivity of the NV is mitigating surface-induced quantum decoherence, which I will discuss in the second part of this talk. Decoherence at interfaces is a universal problem that affects many quantum technologies, but the microscopic origins are as yet unclear. Our studies guide the ongoing development of quantum control and materials control, pushing towards the ultimate goal of NV-based single nuclear spin imaging. 6 Prof. Daniella Goldfarb: Plenary Lecture Characteristics of Gd(III) spin labels for the study of protein conformations Daniella Goldfarb Weizmann Institute of Science, Rehovot, Israel Abstract Gd(III) complexes are currently established as spin labels for structural studies of proteins using pulse dipolar electron paramagnetic resonance (PD-EPR) techniques. This has been achieved by the availability of medium- and high-field spectrometers,
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