ANRV284-AA44-09 ARI 28 July 2006 14:14 Diffuse Atomic and Molecular Clouds Theodore P. Snow1 and Benjamin J. McCall2 1Center for Astrophysics and Space Astronomy, University of Colorado, Boulder, Colorado 80309; email:
[email protected] 2Departments of Chemistry and Astronomy, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801; email:
[email protected] Annu. Rev. Astron. Astrophys. Key Words 2006. 44:367–414 interstellar medium, interstellar molecules, spectroscopy First published online as a Review in Advance on June 5, 2006 Abstract by UNIVERSITY OF ILLINOIS on 09/05/06. For personal use only. The Annual Review of Diffuse interstellar clouds have long been thought to be relatively devoid of molecules, Astrophysics is online at because of their low densities and high radiation fields. However, in the past ten years astro.annualreviews.org or so, a plethora of polyatomic molecules have been observed in diffuse clouds, via doi: 10.1146/ their rotational, vibrational, and electronic transitions. In this review, we propose Annu. Rev. Astro. Astrophys. 2006.44:367-414. Downloaded from arjournals.annualreviews.org annurev.astro.43.072103.150624 a new systematic classification method for the different types of interstellar clouds: Copyright c 2006 by diffuse atomic, diffuse molecular, translucent, and dense. We review the observa- Annual Reviews. All rights tions of molecules (both diatomic and polyatomic) in diffuse clouds and discuss how reserved molecules can be utilized as indicators of the physical and chemical conditions within 0066-4146/06/0922- these clouds. We review the progress made in the modeling of the chemistry in these 0367$20.00 clouds, and the (significant) challenges that remain in this endeavor.