Symposium A Advanced Materials: From Fundamentals to Applications INVITED LECTURES 1. Potassium hydroxide 2. Potassium hydride 3. Potassium carbonate 4. Sodium hydroxide 5. Sodium hydride 6. Sodium carbonate 7. Calcium hydroxide 8. Calcium carbonate 9. Calcium sulphate 10. Calcium nitrate 11. Calcium chloride 12. Barium hydroxide 13. Barium carbonate 14. Barium sulphate 15. Barium nitrate 16. Barium chloride 17. Aluminium sulphate 18. Aluminium nitrate 19. Aluminium chloride 20. Alum 21. Potassium silicate 22. Potassium silicate 23. Potassium calcium silicate 24. Potassium barium silicate 25. Silicon fluoride 26. Ammonium potassium 27. Ethylene chloride compound Chemical symbols used by Dalton, 19th century ← Previous page: Distilling apparatus from John French’s The art of distillation, London 1651 Symposium A: Advanced Materials A - IL 1 Binuclear Complexes as Tectons in Designing Supramolecular Solid-State Architectures Marius Andruh University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory Str. Dumbrava Rosie nr. 23, 020464-Bucharest, Romania
[email protected] We are currently developing a research project on the use of homo- and heterobinuclear complexes as building-blocks in designing both oligonuclear species and high-dimensionality coordination polymers with interesting magnetic properties. The building-blocks are stable binuclear complexes, where the metal ions are held together by compartmental ligands, or alkoxo- bridged copper(II) complexes. The binuclear nodes are connected through appropriate exo- - 3- III bidentate ligands, or through metal-containing anions (e. g. [Cr(NH3)2(NCS)4] , [M(CN)6] , M = Fe , CrIII). A rich variety of 3d-3d and 3d-4f heterometallic complexes, with interesting architectures and topologies of the spin carriers, has been obtained1.