DTPA 5Na Safety Data Sheet According to Regulation (EU) 2015/830 Date of Issue: 7/15/2019 Revision Date: 7/15/2019 Version: 1.0
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DTPA 5Na Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 7/15/2019 Revision date: 7/15/2019 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : DTPA 5Na 40%-50% 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category : Chelating agent, household and industrial cleaning, detergents, pulp and paper bleaching, etc 1.2.2. Uses advised against Restrictions on use : No information available 1.3. Details of the supplier of the safety data sheet Manufacturer Importer Shijiazhuang Jackchem Co., Ltd. Address: Douyu Industrial Park,Luancheng County, Shijiazhuang City, Hebei Province, P. R. China Postal Code: [email protected] Phone: +86 -311-84631641 Only Representative Hangzhou REACH Technology Group Co., Ltd. (CIRS Group) 11F Building 1, Dongguan Hi-Tech Park, 288 Qiuyi Road, Binjiang District, Hangzhou 310052, China T 0571-87206529 [email protected] 1.4. Emergency telephone number Emergency number : +86 -311-84631641 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Corrosive to metals, Category 1 H290 Acute toxicity (inhalation:dust,mist) Category 4 H332 Serious eye damage/eye irritation, Category 2 H319 Reproductive toxicity, Category 2 H361 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. Causes serious eye irritation. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) : GHS05 GHS07 GHS08 Signal word (CLP) : Warning Hazard statements (CLP) : H290 - May be corrosive to metals. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H361 - Suspected of damaging fertility or the unborn child. 7/15/2019 (Version: 1.0) EN (English) 1/8 DTPA 5Na 40%-50% Safety Data Sheet according to Regulation (EU) 2015/830 Precautionary statements (CLP) : P234 - Keep only in original packaging. P264 - Wash hands, forearms and face thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Pentasodium (CAS-No.) 140-01-2 38 - 52 Met. Corr. 1, H290 (carboxylatomethyl)iminobis(ethylenenitrilo)tetraacetate (EC-No.) 205-391-3 Acute Tox. 4 (Inhalation:dust,mist), H332 Eye Irrit. 2, H319 Repr. 2, H361 Nitrilotriacetic acid trisodium salt (CAS-No.) 5064-31-3 <= 2 Acute Tox. 4 (Oral), H302 (EC-No.) 225-768-6 Eye Irrit. 2, H319 (EC Index-No.) 607-620-00-6 Carc. 2, H351 Water (CAS-No.) 7732-18-5 Balance Not classified (EC-No.) 231-791-2 Specific concentration limits: Name Product identifier Specific concentration limits Nitrilotriacetic acid trisodium salt (CAS-No.) 5064-31-3 ( 5 =<C < 100) Carc. 2, H351 (EC-No.) 225-768-6 (EC Index-No.) 607-620-00-6 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : Take off contaminated clothing. Wash skin with mild soap and water. And wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Ensure adequate flushing of eyes by separating eyelids with the fingers. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Never give anything by mouth to an unconscious person. Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after eye contact : Causes serious eye irritation.Harmful if inhaled.Suspected of damaging fertility or the unborn child. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide (CO2). Unsuitable extinguishing media : No information available. 5.2. Special hazards arising from the substance or mixture Fire hazard : Thermal decomposition may produce : Carbon oxides (CO, CO2). Hazardous decomposition products in case of fire : Toxic fumes may be released. 7/15/2019 (Version: 1.0) EN (English) 2/8 DTPA 5Na 40%-50% Safety Data Sheet according to Regulation (EU) 2015/830 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Ventilate spillage area. Use personal protective equipment as required. Do not touch or walk on the spilled product. Avoid contact with skin and eyes. Remove all sources of ignition. Do not breathe vapour/aerosol. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. Do not discharge into drains or rivers. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Stop leak if safe to do so. Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Do not handle until all safety precautions have been read and understood. Ensure good ventilation of the work station. Wear personal protective equipment. Obtain special instructions before use. Do not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in accordance with local, regional, national or international regulation. Keep container tightly closed in a cool, well-ventilated place. Protect from moisture. Store locked up. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters Nitrilotriacetic acid trisodium salt (5064-31-3) Austria - Occupational Exposure Limits OEL chemical category (AT) Group B Carcinogen 8.2. Exposure controls Appropriate engineering controls: Showers. Eyewash stations. Use with local exhaust ventilation. Hand protection: PPE18 - Wear chemically resistant gloves (tested to EN374) in combination with intensive management supervision controls. Eye protection: Wear safety glasses with side shields (or goggles). Skin and body protection: Wear suitable protective clothing. Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Environmental exposure controls: Avoid release to the environment. 7/15/2019 (Version: 1.0) EN (English) 3/8 DTPA 5Na 40%-50% Safety Data Sheet according to Regulation (EU) 2015/830 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : No data available. Colour : Clear Light yellow liquid Odour : Slight Ammonia Odour threshold : No data available pH : 10 - 12 Relative evaporation rate (butylacetate=1) : No data available Melting point : < -15 °C Freezing point : No data available Boiling point : 106 °C Flash point : No data available Critical temperature : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available No data available