A SYSTEM of NOMENCLATURE for RARE-EARTH MINERALS In
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A Crystal.Chemical Investigation of Alpine Gadolinite 135
LN Canadian Mineralogist Vol. 30, pp. 1n-136 (1993) A CRYSTAL.CHEMICALINVESTIGATION OFALPINE GADOLINITE FRANCESCODEMARTIN Istinto di ChimicaStrumtristica Inorganica" Universit degli Studi, Via G. Venezian21, I-20133 Milan' Italy TULLIOPILATI CentroCNR per Io Studiodelle Relazioni fra Strunurae ReattivitChimica, via Golgi 19,I-20133 Milan' Italy VALERIADIELLA Centro CNRdi Sndio per la Stratigrafia e Petrografiadelle AIpi Centrali, via Bonicelli 23, I-20133Milan' Italy PAOLO GENTILE AND CARLO M. GRAMACCIOLI Dipanimentodi ScienzedellaTerra, Ilniversit degli Studi,via Bonicelli 23, I-20133Milnn' Italy ABSTRACI Gadolinite-(Y) specimensfrom variouslocalities in the Alps havebeen examined by electronmicroprobe and single-crystal X-ray diffraction. tn generat,dysprosium is the most abundantrare-earth, although a few samplescontain approximately equal ulnount,of Dy undYb-,andin oneinstance, Gdpredominates.Incontrasttomanynon-Alpineoccunences, mostof these specimens show only lirnited amountsof the lighter REE.There is an almostconstant presence of calcium (up to 4 wt7o.CaO' and.possibly twice thai amountfor morequestiorible samples;;iron is often markedlydeficient with respectto the tleqretlcal formula, and in ar leastone case (Glogstafelberg), the materialshould more properly be ialled hingganite-(Y)(4.0 wrToFeO). In somespecimens, a silnificant substituiionof S fJi Be (up to about4 .Z wtUoUrOll canbededuced-from crystal-structure data, on the basisof linear inteipolation of the measuredBe-O''6ond lengfhswith reip".t to other gadolinite-groupminerals. This substitutionis more exteisive for specimenshigh in Ca and low in Fe, and which thereforegrade toward datolite. No evidencefor replacementof Si by B hasbeen iound. Minor amountsof thorium (up to 0.4 wtToThO2)commonly are present' and uranium(0.3 wtVoUO) was found in one specimen.As for xenotimeand monazite,the behaviorbf Y is not uniquely determinedby the ionic radius,some specimensbeing especiallyemiched in this elementwith respectto the middle-heavyrare earths(up to 4 I .5 wt%oY 2O) . -
CM37 1239.Pdf
1239 TheCanaclian Mineralogist Vol. 37, pp.1239-1253(1999) CRYSTALLIZATIONAND ALTERATION HISTORY OF BRITHOLITE IN RARE.EARTH.ELEMENT.ENRICHEDPEGMATITIC SEGREGATIONS ASSOCIATED WITHTHE EDEN LAKE COMPLEX. MANITOBA. CANADA KYLA M. ARDEN ANDNORMAN M. HALDENS Departmentof GeologicalSciences, University of Manitoba,Winnipeg, Manitoba R3T 2N2,Canada ABSTRACT Pegmatitic segregationsand quartzofeldspathic veins associatedwith the Eden Lake Complex, Manitoba, Canada, contain significant abundancesof rare-earth elements (REE),U and Th, concentrated in minerais such as titanite, apatite, allanite and bdtholite. Titanite and apatite are typically found as discrete,zoned, and locally euhedral crystals. Allanite occurs both as discrete crystals as well as irregular segregations,whereas britholite occurs only as irregular masses.The allanite and britholite typically share sharp but irregular contacts with the host silicate minerals (aegirine-augite, K-feldspar and quartz). Allanite normally occurs between britholite and the silicate minerals, suggestingthat it formed as the result ofreaction between aREE-bearing fluid rich in P and F and the silicate minerals. Within the irregular massesof britholite, one sees an unusual polygonal mosaiclike texture with polygons ranging from 20 to 200 pm. Polygon boundariesare straight to slightly curved, intersect at triplejunctions, and converge at angles from 60 to 180'. This texture is likely the product ofreheating and annealing ofthe britholite However, as a result of metamictization, the britholite retains little -
Stillwellite-(Ce) (Ce, La, Ca)Bsio
Stillwellite-(Ce) (Ce; La; Ca)BSiO5 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Hexagonal. Point Group: 3: As °at rhombohedral crystals, to 4 cm, and massive. Twinning: Observed about [100]. Physical Properties: Cleavage: One imperfect. Fracture: Conchoidal. Hardness = 6.5 D(meas.) = 4.57{4.60 D(calc.) = 4.67 » Optical Properties: Transparent to translucent. Color: Red-brown to pale pink; colorless in thin section. Streak: White. Optical Class: Uniaxial (+) to biaxial (+). ! = 1.765{1.784 ² = 1.780{1.787 2V(meas.) = 0±{6± Cell Data: Space Group: P 31: a = 6.841{6.844 c = 6.700{6.702 Z = 3 X-ray Powder Pattern: Mary Kathleen mine, Australia. 3.43 (s), 2.96 (s), 2.13 (ms), 4.44 (m), 1.864 (m), 2.71 (mw), 2.24 (mw) Chemistry: (1) (2) (1) (2) (1) (2) SiO2 22.40 22.06 La2O3 27.95 19.12 MgO 0.06 UO2 0.22 Ce2O3 33.15 30.82 CaO 0.95 0.34 ThO2 5.41 Pr2O3 1.82 F 0.30 + B2O3 12.23 [13.46] Nd2O3 5.36 H2O 0.85 Al2O3 0.42 Sm2O3 0.34 H2O¡ 0.10 Y2O3 0.74 0.28 Fe2O3 0.18 P2O5 0.67 Total [100.00] [99.26] (1) Mary Kathleen mine, Australia; recalculated to 100.00% after removal of very small amounts of uraninite and apatite determined by separate analysis. (2) Vico volcano, near Vetralla, Italy; by electron microprobe, B2O3 calculated from stoichiometry, original total given as 99.23%; corresponds to (Ce0:50La0:31Nd0:08Th0:05Pr0:03Ca0:02Sm0:01)§=1:00B1:02Si0:97O5: Occurrence: Locally abundant as a metasomatic replacement of metamorphosed calcareous sediments (Mary Kathleen mine, Australia); in alkalic pegmatites in syenite in an alkalic massif (Dara-i-Pioz massif, Tajikistan). -
GLOBAL RARE-EARTH PRODUCTION: HISTORY and OUTLOOK History – the Discovery
Center for Strategic and International Studies Rare Earth Elements: Geology, Geography, and Geopolitics James B. Hedrick Hedrick Consultants, Inc. U.S. Rare Earths, Inc. Burke, Virginia December 15, 2010 Washington, DC GLOBAL RARE-EARTH PRODUCTION: HISTORY AND OUTLOOK History – The Discovery . The rare earths were discovered in 1787 by Swedish Army Lieutenant Carl Axel Arrhenius . Carl, an amateur mineralogist collected the black mineral ytterbite, later renamed gadolinite, from a small feldspar and quartz mine at Ytterby, Sweden . With similar chemical structures the rare earths proved difficult to separate . It was not until 1794 that Finnish chemist Johann Gadolin separated the first impure yttrium oxide from the mineral ytterbite History – The Discovery History – The Commercialization . The rare earths were commercialized when the incandescent lamp mantle industry was established in 1884 with mantles of zirconium, lanthanum, and yttrium oxides with later improvements requiring only the oxides of thorium and cerium. The lamp mantle was discovered by Baron Carl Auer von Welsbach . The mantles also used small amounts of neodymium and praseodymium as an indelible brand name Welsbach label History – The Early Mining . Rare earths were first produced commercially in the 1880s with the mining in Sweden and Norway of the rare-earth thorium phosphate mineral monazite . Foreign Production Brazil produced monazite as early as 1887 India produced monazite starting in 1911 . Domestic Production Monazite production in the United States was first recorded in 1893 in North Carolina - a small tonnage of monazite was reportedly mined in 1887 Monazite mining in South Carolina began in 1903 History – The Processing . Three main methods for separating and refining the rare- earth elements since they were discovered . -
~Ui&£R5itt! of J\Rij!Oua
Minerals and metals of increasing interest, rare and radioactive minerals Authors Moore, R.T. Rights Arizona Geological Survey. All rights reserved. Download date 06/10/2021 17:57:35 Link to Item http://hdl.handle.net/10150/629904 Vol. XXIV, No.4 October, 1953 ~ui&£r5itt! of J\rij!oua ~ul1etiu ARIZONA BUREAU OF MINES MINERALS AND METALS OF INCREASING INTEREST RARE AND RADIOACTIVE MINERALS By RICHARD T. MOORE ARIZONA BUREAU OF MINES MINERAL TECHNOLOGY SERIES No. 47 BULLETIN No. 163 THIRTY CENTS (Free to Residents of Arizona) PUBLISHED BY ~tti£ll~r5itt! of ~rh!Omt TUCSON, ARIZONA TABLE OF CONTENTS INTRODUCTION 5 Acknowledgments 5 General Features 5 BERYLLIUM 7 General Features 7 Beryllium Minerals 7 Beryl 7 Phenacite 8 Gadolinite 8 Helvite 8 Occurrence 8 Prices and Possible Buyers ,........................................ 8 LITHIUM 9 General Features 9 Lithium Minerals 9 Amblygonite 9 Spodumene 10 Lepidolite 10 Triphylite 10 Zinnwaldite 10 Occurrence 10 Prices and Possible Buyers 10 CESIUM AND RUBIDIUM 11 General Features 11 Cesium and Rubidium Minerals 11 Pollucite ..................•.........................................................................., 11 Occurrence 12 Prices and Producers 12 TITANIUM 12 General Features 12 Titanium Minerals 13 Rutile 13 Ilmenite 13 Sphene 13 Occurrence 13 Prices and Buyers 14 GALLIUM, GERMANIUM, INDIUM, AND THALLIUM 14 General Features 14 Gallium, Germanium, Indium and Thallium Minerals 15 Germanite 15 Lorandite 15 Hutchinsonite : 15 Vrbaite 15 Occurrence 15 Prices and Producers ~ 16 RHENIUM 16 -
Study on Extraction of Lanthanum Oxide from Monazite Concentrate
World Academy of Science, Engineering and Technology International Journal of Materials and Metallurgical Engineering Vol:2, No:10, 2008 Study on Extraction of Lanthanum Oxide from Monazite Concentrate Nwe Nwe Soe, Lwin Thuzar Shwe, and Kay Thi Lwin La2O3 has more extensive applications. It is a white Abstract—Lanthanum oxide is to be recovered from monazite, amorphous powder; insoluble in water improves the alkali which contains about 13.44% lanthanum oxide. The principal resistance of glass. The Kodak's camera objectives contain objective of this study is to be able to extract lanthanum oxide from from 20 to 40% La2O3. Lanthanum oxide can also be used in monazite of Moemeik Myitsone Area. The treatment of monazite in optical glasses where it imparts improved alkali resistance, this study involves three main steps; extraction of lanthanum La-Ce-Tb phosphors for fluorescent lamps, dielectric and hydroxide from monazite by using caustic soda, digestion with nitric conductive ceramics, Barium titanate capacitors, X-Ray acid and precipitation with ammonium hydroxide and calcination of lanthanum oxalate to lanthanum oxide. intensifying screens and lanthanum metal production [1]. Keywords—Calcination, Digestion, Precipitation. II. EXPERIMENTAL PROCEDURE Monazite from Moemeik Myitsone Area was used as raw I. INTRODUCTION material for the experiments. Monazite was ground to obtain - ANTHANUM was discovered in 1839 by Swedish 325 mesh. It has beach color. The flow diagram of the L Chemist Carl Gustav Mosandar when he partially extraction of lanthanum oxide is shown in Fig. 1. decomposed a sample of cerium nitrate by heating and treating Monazite the resulting salt with nitric acid. -
Mineralogy and Geological Setting of Allanite-(Ce)-Pegmatites 341
NORWEGIAN JOURNAL OF GEOLOGY Mineralogy and geological setting of allanite-(Ce)-pegmatites 341 Mineralogy and geological setting of allanite-(Ce)- pegmatites in western Hurrungane, Jotun Nappe Complex, Norway: an EMP and ID-TIMS study Simon Spürgin, Rune S. Selbekk and Anders Mattias Lundmark Spürgin, S., Selbekk, R. & Lundmark, M. 2009: Mineralogy and geological setting of allanite-(Ce)- pegmatites in western Hurrungane, Jotun Nappe Complex, Norway: an EMP and ID-TIMS study. Norwegian Journal of Geology, vol. 89, pp 341-356, Trondheim 2009, ISSN 029-196X. The 950 ± 1 Ma Berdalsbandet Pegmatite Swarm (BPS) in Hurrungane, in the Jotun Nappe Complex, SW Norway, consists of ≤2 m wide subpa- rallel granitic dykes emplaced in a sinistral non-coaxial shear zone, constraining the age of local Sveconorwegian deformation. The abyssal class dyke swarm is interpreted to be related to local Sveconorwegian anatexis; mineralogy and REE characteristics indicate low degree partial melting. The pegmatites are symmetrically zoned and typically consist of an outer zone of feldspar + allanite-(Ce) + biotite, a transitional zone of feldspar + quartz + schorl + Fe-Ti-oxides, an inner zone of quartz + schorl + garnet + beryl and a core of hydrothermal quartz. A metasomatic rim of biotite is locally developed along contacts to the amphibolite wallrock. Secondary zeolites are suggested to relate to late- to post-Caledonian altera- tion. The dykes contain various rare-earth minerals, predominantly allanite-(Ce). Its composition, determined by electron microprobe (EMP) and 2+ expressed by representative analyses from three samples, is: (Ca0.86REE0.80Mn0.09Th0.01Na0.03)Σ1.79(Al1.79Fe 0.99Mg0.16Ti0.10)Σ3.04(Si3.17P0.01)O12(OH), (Ca1 2+ 3+ 2+ 3+ 0.30 .12REE0.72Mn0.03Th0.01Na0.02)Σ1.90(Al1.73Fe 0.66Fe 0.33Mg0.26Ti0.03)Σ3.01Si3.07O12(OH) and (Ca1.10REE0.74Mn0.02Th0.01Na0.01)Σ1.88(Al1.75Fe 0.69Fe 0.26Mg Ti0.04) 3+ 3+ 2+ 2+ 3+ 3+ 2+ 2+ 3+ Σ3.04Si3.08O12(OH). -
Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals
metals Review Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals Adrián Carrillo García 1, Mohammad Latifi 1,2, Ahmadreza Amini 1 and Jamal Chaouki 1,* 1 Process Development Advanced Research Lab (PEARL), Chemical Engineering Department, Ecole Polytechnique de Montreal, C.P. 6079, Succ. Centre-ville, Montreal, QC H3C 3A7, Canada; [email protected] (A.C.G.); mohammad.latifi@polymtl.ca (M.L.); [email protected] (A.A.) 2 NeoCtech Corp., Montreal, QC H3G 2N7, Canada * Correspondence: [email protected] Received: 8 October 2020; Accepted: 13 November 2020; Published: 17 November 2020 Abstract: Rare earth elements (REE), originally found in various low-grade deposits in the form of different minerals, are associated with gangues that have similar physicochemical properties. However, the production of REE is attractive due to their numerous applications in advanced materials and new technologies. The presence of the radioactive elements, thorium and uranium, in the REE deposits, is a production challenge. Their separation is crucial to gaining a product with minimum radioactivity in the downstream processes, and to mitigate the environmental and safety issues. In the present study, different techniques for separation of the radioactive elements from REE are reviewed, including leaching, precipitation, solvent extraction, and ion chromatography. In addition, the waste management of the separated radioactive elements is discussed with a particular conclusion that such a waste stream can be -
Baddeleyite Zro2 C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Monoclinic
Baddeleyite ZrO2 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals commonly tabular on {100} and somewhat elongated on [010], or short to long prismatic along [001], to 6 cm; rarely equant; prism faces striated k [001]; radially fibrous with concentric banding in botryoidal masses. Twinning: Ubiquitous; on {100} and {110}, both may be polysynthetic; rare on {201}. Physical Properties: Cleavage: {001} nearly perfect, {010} and {110} less perfect. Fracture: Subconchoidal to uneven. Tenacity: Brittle. Hardness = 6.5 D(meas.) = 5.40–6.02 D(calc.) = [5.83] Blue-green cathodoluminescence. Optical Properties: Transparent; in dark-colored specimens, only in thin fragments. Color: Colorless to yellow, green, greenish or reddish brown, brown, iron-black; colorless to brown in transmitted light. Streak: White to brownish white. Luster: Greasy to vitreous; nearly submetallic in black crystals. Optical Class: Biaxial (–). Pleochroism: X = yellow, reddish brown, oil-green; Y = oil-green, reddish brown; Z = brown, light brown. Orientation: X ∧ c =13◦; Y = b. Dispersion: r> v, rather strong. Absorption: X > Y > Z. α = 2.13(1) β = 2.19(1) γ = 2.20(1) 2V(meas.) = 30(1)◦ 2V(calc.) = 28◦ Cell Data: Space Group: P 21/c (synthetic). a = 5.1505(1) b = 5.2116(1) c = 5.3173(1) β =99.230(1)◦ Z=4 X-ray Powder Pattern: Phalaborwa, South Africa. 3.15 (10), 2.835 (9), 2.62 (5), 1.817 (5), 3.66 (4), 3.51 (4), 1.847 (4) Chemistry: (1) (2) (1) (2) (1) (2) SiO2 0.19 0.08 HfO2 0.93 CaO 0.06 TiO2 0.56 Fe2O3 0.82 LOI 0.28 ZrO2 98.90 97.8 FeO 1.3 Total 100.25 100.67 (1) Balangoda, Sri Lanka. -
Alphabetical List
LIST L - MINERALS - ALPHABETICAL LIST Specific mineral Group name Specific mineral Group name acanthite sulfides asbolite oxides accessory minerals astrophyllite chain silicates actinolite clinoamphibole atacamite chlorides adamite arsenates augite clinopyroxene adularia alkali feldspar austinite arsenates aegirine clinopyroxene autunite phosphates aegirine-augite clinopyroxene awaruite alloys aenigmatite aenigmatite group axinite group sorosilicates aeschynite niobates azurite carbonates agate silica minerals babingtonite rhodonite group aikinite sulfides baddeleyite oxides akaganeite oxides barbosalite phosphates akermanite melilite group barite sulfates alabandite sulfides barium feldspar feldspar group alabaster barium silicates silicates albite plagioclase barylite sorosilicates alexandrite oxides bassanite sulfates allanite epidote group bastnaesite carbonates and fluorides alloclasite sulfides bavenite chain silicates allophane clay minerals bayerite oxides almandine garnet group beidellite clay minerals alpha quartz silica minerals beraunite phosphates alstonite carbonates berndtite sulfides altaite tellurides berryite sulfosalts alum sulfates berthierine serpentine group aluminum hydroxides oxides bertrandite sorosilicates aluminum oxides oxides beryl ring silicates alumohydrocalcite carbonates betafite niobates and tantalates alunite sulfates betekhtinite sulfides amazonite alkali feldspar beudantite arsenates and sulfates amber organic minerals bideauxite chlorides and fluorides amblygonite phosphates biotite mica group amethyst -
Zircon, Monazite and Other Minerals Used in the Production of Chemical Com- Pounds Employed in the Manufac- Ture of Lighting Apparatus
North Carolina State Library GIFT OF \*J.^. M «v* Digitized by the Internet Archive in 2013 http://archive.org/details/zirconmonaziteot25prat V C*> ttonh Carolina Stat© ^vtef <^ Raleigh NORTH CAROLINA GEOLOGICAL AND ECONOMIC SURVEY JOSEPH HYDE PRATT, State Geologist BULLETIN No. 25 Zircon, Monazite and Other Minerals Used in the Production of Chemical Com- pounds Employed in the Manufac- ture of Lighting Apparatus BY JOSEPH HYDE PRATT, Ph.D. Raleigh, N. 0. Edwards & Broughton Printing Co. State Printers and Binders 1916 GEOLOGICAL BOARD Governor Locke Craig, ex officio chairman Raleigh Frank R. Hewitt Asheville Hugh MacRae Wilmington Henry E. Fries ". Winston-Salem John Sprunt Hill Durham Joseph Hyde Pratt, State Geologist Chapel Hill ^5 LETTER OF TRANSMITTAL Chapel Hill, M". C, October 1, 1915. To His Excellency , Honorable Locke Craig, Governor of North Carolina. Sir :—I have the honor to submit herewith for publication as Bulletin 25 a report on Zircon, Monazite and other Minerals Used in the Pro- duction of Chemical Compounds Employed in the Manufacture of Light- ing Apparatus. There is a renewed interest in the deposits of these min- erals in North Carolina, and the present report takes up not only a description of the localities in which these minerals are found, but is a technical review of the development of the lighting industry. Very truly yours, Joseph Hyde Pratt, State Geologist. ±o 5 ,3 3 2 7 CONTENTS PAGE Introduction 7 Zircon 7 Sources of Zirconia 10 Zircon 10 Baddeleyite 10 Other Zirconia-bearing Minerals 11 Occurrences and localities of Zircon 13 Zircon from Henderson County, N. -
From Bedrock to Porcelain a Study Regarding The
Bachelor Thesis Degree Project in Geology 15 hp From Bedrock to Porcelain A study regarding the history of porcelain, Ytterby mine and the discovery of yttrium in Sweden Timmy Kärrström Stockholm 2017 Department of Geological Sciences Stockholm University SE-106 91 Stockholm Sweden Abstract Porcelain is a translucent vitreous material that consists of clay (kaolin), feldspar and quartz which has been mixed and heated together to cause a metamorphic reaction. In Sweden, the Porcelain industry was established in 1726 at Rörstrands castle in Stockholm and is today one of the oldest industries in Europe to produce porcelain. Around the 1790’s Rörstrand got its feldspars and quartz from the Ytterby mine that was located at Resarö in Stockholm’s archipelago making the raw material somewhat easy to access. Rörstrand owned the mine in the 1850’s to 1926. During the time Ytterby mine was active, an amateur geologist by the name of Carl Axel Arrhenius, discovered an unusual black mineral in the quarry ore in 1787 which later led to the discovery of 8 new rare earth elements (REE) with the help of several Swedish chemists throughout time. These elements are Yttrium, Ytterbium, Gadolinium, Terbium, Thulium, Erbium, Holmium and scandium. This study will focus on the Swedish porcelain industry and how it has evolved throughout history and Rörstrand’s role in the discovery of yttrium. PAGE 1 Contents Abstract ........................................................................................................................................... 1