Tin. Tungsten. and Molybdenum Geochemistry of Parts of Stevens and Spokane Counties, Washington

Total Page:16

File Type:pdf, Size:1020Kb

Tin. Tungsten. and Molybdenum Geochemistry of Parts of Stevens and Spokane Counties, Washington STATE OF WASHINGTON DEPARTMENT OF NATURAL RESOURCES BRIAN J. BOYLE, Commissioner of Public Lands ART STEARNS, Supervisor DIVISION OF GEOLOGY AND EARTH RESOURCES RAYMOND LASMANIS, State Geologist REPORT OF INVESTIGATIONS 28 TIN. TUNGSTEN. AND MOLYBDENUM GEOCHEMISTRY OF PARTS OF STEVENS AND SPOKANE COUNTIES, WASHINGTON by Bonnie B. Bunning 1986 STATE OF WASHINGTON DEPARTMENT OF NATURAL RESOURCES BRIAN J. BOYLE, Commissioner of Public Lands ART STEARNS, Supervisor DIVISION OF GEOLOGY AND EARTH RESOURCES RAYMOND LASMANIS, State Geologist REPORT OF INVESTIGATIONS 28 TIN, TUNGSTEN, AND MOLYBDENUM GEOCHEMISTRY OF PARTS OF STEVENS AND SPOKANE COUNTIES, WASHINGTON by Bonnie B. Bunning 1985 Printed in the United States of America For sale by Department of Natural Resources, Olympia, Washington Price $ 1.39 . 11 tax 1 .50 COVER PHOTO The Germania mill in Stevens County, Washington. During the 1930's and 1940's, the Germania mine and mill supplied tungsten concentrate to General Electric Company, for use in manufacturing light bulbs. Today the tungsten vein system at Germania is worked out, but the old mine still holds high potential as an exploration target for porphyry molybdenum minerali­ zation. II TABLE OF CONTENTS Page Abstract . 1 Introduction. 1 Location and geographic setting . 1 General geology . 1 Objectives and scope of study . 2 Study methods . 2 Acknowledgments . 3 Geologic models . 3 Tin deposits . 3 Molybdenum deposits . 4 Tungsten deposits . 5 Past production in the study area . 6 Tin (Silver Hill mine) . 6 Production . 6 Geology and mineralization . 6 Tungsten (Germania and Germania Consolidated mines) . 7 History and production . 7 Geology . 8 Mineralization . 8 Alteration . 8 Molybdenum [Deer Trail Monitor (Monitor) mine) . 8 Production . 8 Geology . 8 Mineralization . 8 Favorable prospects . 9 Tin... ... .... ..... .. ...... ...... ................ .... .... .. 9 Spokane County . 9 Freeman clay pit . 9 Stevens County . 10 Huckleberry Mountain area . 10 Read prospect . 10 Deer Trail Monitor (Monitor) mine . 11 Cleveland mine . 12 Togo mine . 12 Daisy and Tempest mines . 13 Young America mine . 13 McMillan prospect . 14 U.S. Forest Service sample G-6/25 llR . 15 U.S. Forest Service sample G-6/27 20R . .. 15 U.S. Forest Service sample K-7 /12 lOR . 16 Tungsten . 16 Stevens County . 16 Regal Serpentine quarries . 16 Molybdenum . 17 Stevens County . 1 7 Germania and Germania Consolidated mines . 17 Blue Grouse Mountain area . 17 Geology . 18 III TABLE OF CONTENTS - Continued Page Alteration . 18 Geochemistry . 18 Silver Summit (Summit) mine . 19 Summary . 20 Recommendations . 20 Tin . 20 Tungsten . 21 Molybdenum . 21 References cited . 23 Appendix A - Sample descriptions and analytical results . 27 Appendix B - Sample location and geochemical maps . 45 IV ILLUSTRATIONS Page Figure 1. Location map of the study area, Stevens and Spokane Counties, Washington .... 2 2. Relationship of tin, tungsten, molybdenum, and copper deposits in granitic rocks .... 4 3. Location map of past producers of tin, tungsten, and molybdenum .............. 6 4. Sample location map - Freeman clay pit ................................ 9 5. Sample location map - Read prospect ......................... .. .......... 10 6. Sample location map - Deer Trail Monitor (Monitor) mine ........... ......... 11 7. Sample location map - Cleveland mine .................................... 12 8. Sample location map - Togo mine .............................. ......... 12 9. Sample location map - Daisy and Tempest mines ............... ...... ... ..
Recommended publications
  • Evolution and Understanding of the D-Block Elements in the Periodic Table Cite This: Dalton Trans., 2019, 48, 9408 Edwin C
    Dalton Transactions View Article Online PERSPECTIVE View Journal | View Issue Evolution and understanding of the d-block elements in the periodic table Cite this: Dalton Trans., 2019, 48, 9408 Edwin C. Constable Received 20th February 2019, The d-block elements have played an essential role in the development of our present understanding of Accepted 6th March 2019 chemistry and in the evolution of the periodic table. On the occasion of the sesquicentenniel of the dis- DOI: 10.1039/c9dt00765b covery of the periodic table by Mendeleev, it is appropriate to look at how these metals have influenced rsc.li/dalton our understanding of periodicity and the relationships between elements. Introduction and periodic tables concerning objects as diverse as fruit, veg- etables, beer, cartoon characters, and superheroes abound in In the year 2019 we celebrate the sesquicentennial of the publi- our connected world.7 Creative Commons Attribution-NonCommercial 3.0 Unported Licence. cation of the first modern form of the periodic table by In the commonly encountered medium or long forms of Mendeleev (alternatively transliterated as Mendelejew, the periodic table, the central portion is occupied by the Mendelejeff, Mendeléeff, and Mendeléyev from the Cyrillic d-block elements, commonly known as the transition elements ).1 The periodic table lies at the core of our under- or transition metals. These elements have played a critical rôle standing of the properties of, and the relationships between, in our understanding of modern chemistry and have proved to the 118 elements currently known (Fig. 1).2 A chemist can look be the touchstones for many theories of valence and bonding.
    [Show full text]
  • A Review of Flotation Separation of Mg Carbonates (Dolomite and Magnesite)
    minerals Review A Review of Flotation Separation of Mg Carbonates (Dolomite and Magnesite) Darius G. Wonyen 1,†, Varney Kromah 1,†, Borbor Gibson 1,† ID , Solomon Nah 1,† and Saeed Chehreh Chelgani 1,2,* ID 1 Department of Geology and Mining Engineering, Faculty of Engineering, University of Liberia, P.O. Box 9020 Monrovia, Liberia; [email protected] (D.G.W.); [email protected] (Y.K.); [email protected] (B.G.); [email protected] (S.N.) 2 Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, MI 48109, USA * Correspondence: [email protected]; Tel.: +1-41-6830-9356 † These authors contributed equally to the study. Received: 24 July 2018; Accepted: 13 August 2018; Published: 15 August 2018 Abstract: It is well documented that flotation has high economic viability for the beneficiation of valuable minerals when their main ore bodies contain magnesium (Mg) carbonates such as dolomite and magnesite. Flotation separation of Mg carbonates from their associated valuable minerals (AVMs) presents several challenges, and Mg carbonates have high levels of adverse effects on separation efficiency. These complexities can be attributed to various reasons: Mg carbonates are naturally hydrophilic, soluble, and exhibit similar surface characteristics as their AVMs. This study presents a compilation of various parameters, including zeta potential, pH, particle size, reagents (collectors, depressant, and modifiers), and bio-flotation, which were examined in several investigations into separating Mg carbonates from their AVMs by froth flotation. Keywords: dolomite; magnesite; flotation; bio-flotation 1. Introduction Magnesium (Mg) carbonates (salt-type minerals) are typical gangue phases associated with several valuable minerals, and have complicated processing [1,2].
    [Show full text]
  • Download PDF About Minerals Sorted by Mineral Name
    MINERALS SORTED BY NAME Here is an alphabetical list of minerals discussed on this site. More information on and photographs of these minerals in Kentucky is available in the book “Rocks and Minerals of Kentucky” (Anderson, 1994). APATITE Crystal system: hexagonal. Fracture: conchoidal. Color: red, brown, white. Hardness: 5.0. Luster: opaque or semitransparent. Specific gravity: 3.1. Apatite, also called cellophane, occurs in peridotites in eastern and western Kentucky. A microcrystalline variety of collophane found in northern Woodford County is dark reddish brown, porous, and occurs in phosphatic beds, lenses, and nodules in the Tanglewood Member of the Lexington Limestone. Some fossils in the Tanglewood Member are coated with phosphate. Beds are generally very thin, but occasionally several feet thick. The Woodford County phosphate beds were mined during the early 1900s near Wallace, Ky. BARITE Crystal system: orthorhombic. Cleavage: often in groups of platy or tabular crystals. Color: usually white, but may be light shades of blue, brown, yellow, or red. Hardness: 3.0 to 3.5. Streak: white. Luster: vitreous to pearly. Specific gravity: 4.5. Tenacity: brittle. Uses: in heavy muds in oil-well drilling, to increase brilliance in the glass-making industry, as filler for paper, cosmetics, textiles, linoleum, rubber goods, paints. Barite generally occurs in a white massive variety (often appearing earthy when weathered), although some clear to bluish, bladed barite crystals have been observed in several vein deposits in central Kentucky, and commonly occurs as a solid solution series with celestite where barium and strontium can substitute for each other. Various nodular zones have been observed in Silurian–Devonian rocks in east-central Kentucky.
    [Show full text]
  • Overview of Tungsten Indicator Minerals Scheelite and Wolframite with Examples from the Sisson W-Mo Deposit, Canada
    Overview of tungsten indicator minerals scheelite and wolframite with examples from the Sisson W-Mo deposit, Canada M. Beth McClenaghan1, M.A. Parkhill2, A.A. Seaman3, A.G. Pronk3, M. McCurdy1 & D.J. Kontak4 1Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario, Canada K1A 0E8 (e-mail: [email protected]) 2New Brunswick Department of Energy and Mines, Geological Surveys Branch, P.O. Box 50, Bathurst, New Brunswick, Canada E2A 3Z1 3New Brunswick Department of Energy and Mines, Geological Surveys Branch, P.O. Box 6000, Fredericton, New Brunswick, Canada E3B 5H1 4Department of Earth Sciences, Laurentian University, Sudbury, Ontario, Canada P3E 2C6 These short course notes provide an overview of published lit- Table 1. List of regional surveys and case studies conducted around erature on the use of scheelite and wolframite as indicator min- the world in which scheelite and/or wolframite in surficial sediments erals for W, Mo, and Au exploration. The use of scheelite and have been used as indicator minerals. wolframite in stream sediments is well documented for mineral Mineral Media Location Source of Information exploration but less so for using glacial sediments (Table 1). scheelite stream sediments Pakistan Asrarullah (1982) wolframite stream sediments Burma ESCAP Scretariat (1982) The Geological Survey of Canada has recently conducted a scheelite, wolframite stream sediments USA Theobald & Thompson (1960) glacial till and stream sediment indicator mineral case study scheelite stream sediments, soil Thailand Silakul (1986) around the Sisson W-Mo deposit in eastern Canada. scheelite stream sediments Greenland Hallenstein et al. (1981) Preliminary indicator mineral results from this ongoing study scheelite stream sediments Spain Fernández-Turiel et al.
    [Show full text]
  • Porphyry and Other Molybdenum Deposits of Idaho and Montana
    Porphyry and Other Molybdenum Deposits of Idaho and Montana Joseph E. Worthington Idaho Geological Survey University of Idaho Technical Report 07-3 Moscow, Idaho ISBN 1-55765-515-4 CONTENTS Introduction ................................................................................................ 1 Molybdenum Vein Deposits ...................................................................... 2 Tertiary Molybdenum Deposits ................................................................. 2 Little Falls—1 ............................................................................. 3 CUMO—2 .................................................................................. 3 Red Mountain Prospect—45 ...................................................... 3 Rocky Bar District—43 .............................................................. 3 West Eight Mile—37 .................................................................. 3 Devil’s Creek Prospect—46 ....................................................... 3 Walton—8 .................................................................................. 4 Ima—3 ........................................................................................ 4 Liver Peak (a.k.a. Goat Creek)—4 ............................................. 4 Bald Butte—5 ............................................................................. 5 Big Ben—6 ................................................................................. 6 Emigrant Gulch—7 ...................................................................
    [Show full text]
  • The H/F Ratio As an Indicator of Contrasted Wolframite Deposition Mechanisms
    Ore Geology Reviews 104 (2019) 266–272 Contents lists available at ScienceDirect Ore Geology Reviews journal homepage: www.elsevier.com/locate/oregeorev Short communication The H/F ratio as an indicator of contrasted wolframite deposition T mechanisms ⁎ Julie Anne-Sophie Michaud , Michel Pichavant Université d'Orléans/CNRS/ISTO/BRGM, UMR 7327, 1A rue de la Férollerie, 45100 Orléans, France ARTICLE INFO ABSTRACT Keywords: Understanding wolframite deposition mechanisms is a key to develop reliable exploration guides for W. In quartz Wolframite veins from the Variscan belt of Europe and elsewhere, wolframites have a wide range of compositions, from Hübnerite hübnerite- (MnWO4) to ferberite-rich (FeWO4). Deposition style, source of Mn and Fe, distance from the heat/ W deposition fluid source and temperature have been proposed to govern the wolframite H/F (hübnerite/ferberite ratio) Magmatic control defined as 100 at. Mn/(Fe + Mn). The Argemela mineralized district, located near the world-class Panasqueira W ore deposit W mine in Portugal, exposes a quartz-wolframite vein system in close spatial and genetic association with a rare- Veins metal granite. Wolframite is absent as a magmatic phase, but W-rich whole-rock chemical data suggest that the granite magma is the source of W. Wolframite occurs as large homogeneous hübnerites (H/F = 64–75%) co- existing with montebrasite, K-feldspar and cassiterite in the latest generation of intragranitic veins corre- sponding to magmatic fluids exsolved from the granite. Locally, early hübnerites evolve to late more Fe-rich compositions (H/F = 45–55%). In a country rock vein, an early generation of Fe-rich hübnerites (H/ F = 50–63%) is followed by late ferberites (H/F = 6–23%).
    [Show full text]
  • Geology of Tungsten Deposits in North-Central Chile
    UNITED STATES DEPARTMENT OF THE INTERIOR J. A. Krug, Secretary GEOLOGICAL SURVEY W. E. Wrather, Director Bulletin 960-C GEOLOGY OF TUNGSTEN DEPOSITS IN NORTH-CENTRAL CHILE BY JAMES F. McALLISTER AND CARLOS RUIZ F. Prepared in cooperation with the DEPARTAMENTO DE MINAS Y PETROLED DE CHILE under the auspices of INTERDEPARTMENTAL COMMITTEE ON SCIENTIFIC AND CULTURAL COOPERATION, DEPARTMENT OF STATE Geologic Investigations in the American Republics, 1947 (Pages 89-108) UNITED STATES GOVERNMENT PRINTING OFFICE WASHINGTON : 1948 For sale by the Superintendent of Documents, U. S. Government Printing Office, Washington 25, D. C. Price $1.75 CONTENTS Page Abstract____..______________________________._ 89 Introduction___________________________-__________ __________-___ 89 Geology_________________________________..._ 92 Rocks.____________________________________ 92 Structure____________________________________ 92 Minerals. _.---_.----_..---_.------_- _- -- 92 Type, size, and grade of ore deposits.------------._-----_-_-_-_-_ 93 Descriptions of mining properties__________-___-_-_-_---__--_---____- 94 Salamanca region____________________________________________ 94 Castaneda de Llamuco mine--___----------_-------_------__ 94 Picbe prospect... ________.- _ . 97 Domeyko region_______________________________________________ 97 El Durazno district.-..__-___.___--_____-__________...___ 97 Boliviana mine-..._________-____-._--._._-__-_--__-__. 99 Minillas property......____________________________________ 99 Vallenar region______________________________________________ 101 San Antonio mining property.______________________________ 102 Zapallo de Chehuque mining property_________*____-______- 104 Metric equivalents____-____-_____-_______-----_-__--_-_-_-__--_-- 106 Index.--.___-____-_._______________._______________ 107 Page PLATE 21. Geologic map of the Castaneda de Llamuco tungsten deposit. In pocket 22. Plan of workings, Castafieda de Llamuco mine. _-____-___ In pocket 23.
    [Show full text]
  • Freeport-Mcmoran Copper & Gold Inc. Announces Molybdenum
    Financial Contacts: Media Contact: One North Central Avenue Phoenix, AZ 85004 Kathleen L. Quirk David P. Joint William L. Collier (602) 366-8016 (504) 582-4203 (504) 582-1750 Freeport-McMoRan Copper & Gold Inc. Announces Molybdenum Production Curtailment and Plans to Defer Restart of Climax Molybdenum Mine PHOENIX, AZ, November 10, 2008 – Freeport-McMoRan Copper & Gold Inc. (NYSE: FCX) announced today in response to the recent sharp decline in molybdenum prices plans to reduce production from its Henderson primary molybdenum mine and to defer the restart of the Climax molybdenum mine. Molybdenum markets have been strong in recent years, averaging $30 per pound in 2007 and $33 per pound in the nine months ended September 30, 2008. Slowing demand for molybdenum in the metallurgical and chemicals sectors during October 2008 combined with weak global economic conditions and turmoil in credit and financial markets has resulted in a sudden and sharp decline in molybdenum prices in recent weeks. The Metals Week Molybdenum Dealer Oxide price declined from approximately $30 per pound in mid-October 2008 to $12 per pound on November 10, 2008. In response to these conditions, FCX has revised its mine plans at its Henderson primary molybdenum mine near Empire, Colorado to operate at a reduced rate. This will result in a reduction in expected annual molybdenum production of approximately 10 million pounds, reflecting a 25 percent reduction in Henderson’s approximate annual production. FCX is also assessing the potential to curtail molybdenum production at its by-product mines. FCX also announced the suspension of construction activities associated with the restart of the Climax molybdenum mine near Leadville, Colorado.
    [Show full text]
  • The Development of the Periodic Table and Its Consequences Citation: J
    Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1.
    [Show full text]
  • Download the Scanned
    Tne AMBRrcAx M rNBRALocrsr JOURNAL OF THE MINERALOGICAL SOCIETY OF AMERICA Vol.20 NOVEMBER, 1935 No. 11 THE PEGMATITE MINERALS FROM NEAR AMELIA, VIRGINIA* Jnwrr.r. J. Gless, U. S. Geological'Suraey, Washington, D. C. CoNrnxrs 1' rntroduction 741 2. Rutherfordmine 743 3' Morefield mine ' ' 744 4. Minerals 745 Albite, bertrandite, beryl, biotite, calcite, cassiterite, cerussite, chalcopy- rite, fluorite, galena, manganotantalite, microcline, microlite, monazite, muscovite, phenacite, pyrite, pyrolusite, qtsartz, spessartite, topaz, tourmaline, triplite, zinnwaldite, zircon. 5. Rarer elements identified by spectrographic analyses 764 6. Luminescence of minerals 766 7. Selected bibliography 768 1. INTnooucrroN The first commercial mica mines near Amelia Court House, Virginia, were opened in the early seventies, and the remarkable size and quality of the mica early awakened a keen economic in- terest in the pegmatite dikes of the region, but the richnessof the locality in rare and beautiful mineral specimenshas promoted a scientific interest which has persisted for sixty years. Thirty-six mineral species have been reported from the Rutherford mine alone,and the variety and perfection of many of thesehave led to their inclusion in most of the museums of the world. The concen- tration of unusual minerals in an easily accessible deposit at- tracted various scientific investigators and mineral collectors to this locality for successivegenerations. Such intensive investiga- tion of a locality might suggest that little remains to be learned about its minerals, but the recent opening of a new mine near Amelia and the reopening of the Rutherford mine have given new * Published by permission of the Director, U. S. Geological Survey. 742 THE AMERICAN MINERALOGIST opportunities for study.
    [Show full text]
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • BUILDING on STRENGTH Annual Report on Sustainability
    BUILDING ON STRENGTH Annual Report on Sustainability 2019 Sustainability Report | 1 Cover Photo: Remote underground equipment operators at the Grasberg Block Cave, Indonesia. About Freeport-McMoRan Freeport-McMoRan Inc. (Freeport-McMoRan, FCX or the company) is a leading international mining company with headquarters in Phoenix, Arizona. FCX operates large, long-lived, geographically diverse assets with significant proven and probable reserves of copper, gold and molybdenum. FCX is one of the world’s largest publicly traded copper producers. Our portfolio of assets includes the Grasberg minerals district in Indonesia (PT Freeport Indonesia or PT-FI), one of the world’s largest copper and gold deposits; and significant mining operations in North America and South America (Freeport Minerals Corporation or FMC), including the large-scale Morenci minerals district in Arizona and the Cerro Verde operation in Peru. RECENT AWARDS & RECOGNITION Freeport-McMoRan was named to Forbes Magazine’s JUST 100 as one of America’s most JUST Companies for the 4th consecutive year (ranked 43rd nationally and 1st in Basic Resources). Freeport-McMoRan ranked 6th among 200 of the largest publicly traded companies in the world assessed by the Corporate Human Rights Benchmark (ranked 1st in North America and 3rd among 56 global extractive companies evaluated). Forbes Magazine ranked Freeport-McMoRan on its 2019 Best Employers List (2nd best employer in Arizona and 143rd nationally). Newsweek ranked Freeport-McMoRan as one of America’s 300 Most Responsible Companies (ranked 138th). 100 BEST Corporate Responsibility Magazine listed Freeport-McMoRan as one of the CORPORATE 100 Best Corporate Citizens for the 8th year for outstanding environmental, CITIZENS social and governance (ESG) transparency and performance.
    [Show full text]