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Greement with the Original Manufacturer YSI sells this product under agreement with the original manufacturer. YSI assumes no legal liability or responsibility for the accuracy, completeness or usefulness of any information set forth in this MSDS. Page 1/8 Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/08/2014 Reviewed on 04/08/2014 * 1 Identification · Product identifier · Trade name: Vario Sodium periodate F 10 ml · Catalogue number: 251406Y · Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available. · Application of the substance / the mixture: Reagent for water analysis · Manufacturer/Supplier: Tintometer Inc. Distributor/Supplier: YSI, Inc 6456 Parkland Drive Address 1700/1725 Brannum Lane Sarasota, FL 34243 Yellow Springs, Ohio 45387 USA Telephone (937) 767-7241 phone: (941) 756-6410 E-mail [email protected] fax: (941) 727-9654 www.lovibond.us Made in Germany · Emergency telephone number: Chemtrec® : (US & Canada) 800-424-9300 (International) +1 (703) 527-3887 * 2 Hazard(s) identification · Classification of the substance or mixture US-GHS ~ GHS03 Flame over circle Ox. Sol. 2 H272 May intensify fire; oxidizer. ~ GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H335 May cause respiratory irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC ?@G Xn; Harmful R22: Harmful if swallowed. ?@E O; Oxidizing R8: Contact with combustible material may cause fire. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS03, GHS07 · Signal word Danger · Hazard-determining components of labeling: sodium periodate · Hazard statements H272 May intensify fire; oxidizer. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. (Contd. on page 2) USA 38.0.3 Page 2/8 Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/08/2014 Reviewed on 04/08/2014 Trade name: Vario Sodium periodate F 10 ml (Contd. of page 1) · Precautionary statements P221 Take any precaution to avoid mixing with combustibles. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P261 Avoid breathing dust. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. · Canadian Hazard Symbols: ;= · WHMIS classification: C Oxidizing materials D2B Toxic material causing other toxic effects · NFPA ratings (scale 0 - 4) 0 Health = 2 2 0 Fire = 0 Reactivity = 0 OX The substance possesses oxidizing properties. * 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: mixture of inorganic compounds · Composition and Information on Ingredients: CAS: 7790-28-5 sodium periodate 40-50% EINECS: 232-197-6 ?@G Xn R22; ?@E O R8 RTECS: SD4550000 ~ Ox. Sol. 1, H271; ~ Acute Tox. 3, H301; ~ Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335 · REACH - pre-registered substances All components are REACH pre-registered. · Additional information: For the wording of the listed risk phrases refer to section 16. 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes (15 min) under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink 1-2 glasses of water. Call a doctor immediately. · Most important symptoms and effects, both acute and delayed after swallowing: diarrhoea sickness vomiting · Indication of any immediate medical attention and special treatment needed: No further relevant information available. USA (Contd. on page 3) 38.0.3 Page 3/8 Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/08/2014 Reviewed on 04/08/2014 Trade name: Vario Sodium periodate F 10 ml (Contd. of page 2) 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Water spray Foam Carbon dioxide or dry chemical Fire-extinguishing powder · Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. Sulfur oxides (SOx) Sodium monoxide Iodine compounds · Advice for firefighters · Protective equipment: Wear fully protective suit. Wear self-contained respiratory protective device. · Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Avoid formation of dust. Ensure adequate ventilation Keep away from ignition sources · Environmental precautions: Do not allow product to reach sewage system or any water course. · Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Pick up mechanically. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Precautions for safe handling Keep away from heat and direct sunlight. Keep receptacles tightly sealed. Prevent formation of dust. Ensure good ventilation/exhaustion at the workplace. · Information about protection against explosions and fires: Substance/product is oxidizing when dry. Protect from heat. Keep ignition sources away - Do not smoke. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Store away from oxidizing agents. Store away from flammable substances. · Further information about storage conditions: Store in dry conditions. Protect from exposure to the light. Protect from humidity and water. · Recommended storage temperature: 20 °C +/- 5 °C (approx. 68°F) · Storage class: 5.1 A (Contd. on page 4) USA 38.0.3 Page 4/8 Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/08/2014 Reviewed on 04/08/2014 Trade name: Vario Sodium periodate F 10 ml (Contd. of page 3) · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. · Breathing equipment: Use respiratory protective device against the effects of fumes/dust/aerosol. · Recommended filter device for short term use: Filter P2 · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. After use of gloves apply skin-cleaning agents and skin cosmetics. · Material of gloves Nitrile rubber, NBR Recommended thickness of the material: ≥ 0.11 mm · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Value for the permeation: Level ≤ 1 (10 min) · Eye protection: Tightly sealed goggles · Body protection: Protective work clothing 9 Physical and chemical properties · Information on basic physical and chemical properties Odor Threshold: Not applicable. · Appearance: Form: Powder Color: White · Odor: Odorless · pH-value (8.9 g/l) at 20 °C (68 °F): 4.7 · Melting point/Melting range: 175 °C (347 °F) · Boiling point/Boiling range: 300 °C (572 °F) · Freezing Point: Not applicable. · Flash point: Not applicable. · Flammability (solid, gaseous): Contact with combustible material may cause fire. · Ignition temperature: Undetermined. · Auto igniting: Product is not selfigniting. · Specific Gravity: Not applicable. · Density at 20 °C (68 °F): 3.194 g/cm³ (26.654 lbs/gal) · Vapour density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with Water: Soluble. · Coefficient of Water / Oil Distribution: Not applicable. · Solvent content: Organic solvents: 0.0 % Solids content: 100.0 % (Contd. on page 5) USA 38.0.3 Page 5/8 Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/08/2014 Reviewed on 04/08/2014 Trade name: Vario Sodium periodate F 10 ml (Contd. of page 4) · Other information No further relevant information available. 10 Stability and reactivity · Possibility of hazardous reactions Reacts with powdered metals. · Conditions to avoid No further relevant information available. · Incompatible materials: organic
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