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The Atomic Number Revolution in Chemistry: a Kuhnian Analysis
Found Chem https://doi.org/10.1007/s10698-017-9303-6 The atomic number revolution in chemistry: a Kuhnian analysis K. Brad Wray1 Ó Springer Science+Business Media B.V., part of Springer Nature 2017 Abstract This paper argues that the field of chemistry underwent a significant change of theory in the early twentieth century, when atomic number replaced atomic weight as the principle for ordering and identifying the chemical elements. It is a classic case of a Kuhnian revolution. In the process of addressing anomalies, chemists who were trained to see elements as defined by their atomic weight discovered that their theoretical assump- tions were impediments to understanding the chemical world. The only way to normalize the anomalies was to introduce new concepts, and a new conceptual understanding of what it is to be an element. In the process of making these changes, a new scientific lexicon emerged, one that took atomic number to be the defining feature of a chemical element. Keywords Atomic number Á Atomic weight Á Revolutionary theory change Á Isotope Á Kuhn Á Lexical change The aim of this paper is to provide an analysis of the discovery of atomic number and its effects on chemistry. The paper aims to show that this is a classic textbook case of a Kuhnian scientific revolution. The analysis serves two purposes. First, it provides another case of a Kuhnian revolution, thus offering support for Thomas Kuhn’s theory of scientific change, which has been subjected to criticism on an ongoing basis (see, most recently, Scerri 2016). Second, it provides a compelling unifying narrative of some of the most important research in chemistry in the early twentieth century. -
The Van Den Broek Hypothesis
The van den Broek Hypothesis Tetu Hirosige* 1. Introductioii In the development of the study of the atomic structure during the 1910's, the foundation of models of the atom was provided by van den Broek's hypothesis. The van den Broek hypothesis states that the electric charge of the nucleus or the number of intra-atomic electrons of a chemical element is equal to its ordinal number in the periodic system. Once the hypothesis was proposed by A. van den Broek in 1913, it exerted considerable influence upon N. Bohr, H. G. J. Moseley, and F. Soddy and was soon accepted by most of those who were interested in the atomic physics. This rapid acceptance may presumably be accounted for by the fact that it was just the time when various inquiries into the number of intra-atomic electrons were converging to a nearly correct conclusion. No settled conclusion, however, had yet been pronounced. The van den Broek hypothesis gave a clear and definite expression to this vaguely felt conclusion, and thus greatly advanced the atomic physics. To attach an essential significance to the atomic number was van den Broek's most original idea, which had occurred to no one before him. E. Whittaker, in his History of the Theories of Aether and Electricity If wrote about the van den Broek hypothesis as though it were originated in an examination of experimental results of a-particle scattering.^ According to the Rutherford for mula, the number of particles scattered by an atomic nucleus to a given angle is proportional to the square of the nuclear charge. -
The Relation of Particle Sequence to Atomic Sequence
The Relation of Particle Sequence to Atomic Sequence J. Yee,1,2 Y. Zhu,1,3 G.F. Zhou1 1 Electronic Paper Display Institute, South China Academy of Advanced Optoelectronics, South China Normal University, Higher Education Mega Center, Guangzhou 510006 CHINA 2 ZTE USA Inc, Milpitas, California, 95035 USA 3 China Telecom Imusic Ltd, Guangzhou, Guangdong, 510081 CHINA In this paper, we take the first steps of simplifying particles into a linear function that organizes particles based on their particle number, similar to how atoms are arranged by atomic number. This repeats the method that was used to organize atomic elements and create the Periodic Table of Elements in the 1800s. The solution to linearize particles into a predictable function is not as simple as atomic elements, but it does exist. We will introduce an equation that fits known particles into a linear function and enables the prediction of future particles based on missing energy levels. It also predicts an exact mass of the neutrino. To accomplish this, particles are first organized by particle numbers, similar to atomic numbers in the Periodic Table of Elements and then charted against their known Particle Data Group energy levels. The results show similarities between particles and atomic elements – in both total numbers in formation and also in numbers where both are known to be more stable. Key words: neutrino, atomic numbers, periodic table, leptons, Mendeleev. 1. BACKGROUND – ATOMIC NUMBERS In 1869, Dmitri Mendeleev presented The Dependence Between the Properties of the Atomic Weights of the Elements to the Russian Chemical Society [1], which included the first version of the Periodic Table of Elements. -
Material Science Notes
Monograph on Material Engineering By Dr. Jayanta Kumar Mahato Assistant Professor Mechanical Engineering Department Shobhit Institute of Engineering & Technology (Deemed to-be University) NH-58, Modipuram, Meerut – 250 110, India Contact: 9051020788 Introduction Materials science, also commonly known as materials science and engineering, is an interdisciplinary field which deals with the discovery and design of new materials. This relatively new scientific field involves studying materials through the materials paradigm (synthesis, structure, properties and performance). It incorporates elements of physics and chemistry, and is at the forefront of nano science and nanotechnology research. In recent years, materials science has become more widely known as a specific field of science and engineering. Importance of Materials A material is defined as a substance (most often a solid, but other condensed phases can be included) that is intended to be used for certain applications. There are a myriad of materials around us—they can be found in anything from buildings to spacecrafts. Materials can generally be divided into two classes: crystalline and non-crystalline. The traditional examples of materials are metals, ceramics and polymers. New and advanced materials that are being developed include semiconductors, nanomaterials, biomaterials etc. The material of choice of a given era is often a defining point. Phrases such as Stone Age, Bronze Age, Iron Age, and Steel Age are great examples. Originally deriving from the manufacture of ceramics and its putative derivative metallurgy, materials science is one of the oldest forms of engineering and applied science. Modern materials science evolved directly from metallurgy, which itself evolved from mining and (likely) ceramics and the use of fire. -
Nuclear Physics My First Ebook Using Wikipedia by Billy Merchant
Nuclear Physics My first eBook using Wikipedia by Billy Merchant PDF generated using the open source mwlib toolkit. See http://code.pediapress.com/ for more information. PDF generated at: Mon, 02 Dec 2013 01:40:24 UTC Contents Articles Atom 1 Atomic nucleus 19 Electron 24 Nuclear physics 41 Particle physics 46 Photon 52 Physics 68 Quantum mechanics 81 References Article Sources and Contributors 100 Image Sources, Licenses and Contributors 105 Article Licenses License 107 Atom 1 Atom Helium atom An illustration of the helium atom, depicting the nucleus (pink) and the electron cloud distribution (black). The nucleus (upper right) in helium-4 is in reality spherically symmetric and closely resembles the electron cloud, although for more complicated nuclei this is not always the case. The black bar is one angstrom (10−10 m or 100 pm). Classification Smallest recognized division of a chemical element Properties Mass range: 1.67×10−27 to 4.52×10−25 kg Electric charge: zero (neutral), or ion charge Diameter range: 62 pm (He) to 520 pm (Cs) (data page) Components: Electrons and a compact nucleus of protons and neutrons The atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons (except in the case of hydrogen-1, which is the only stable nuclide with no neutrons). The electrons of an atom are bound to the nucleus by the electromagnetic force. Likewise, a group of atoms can remain bound to each other by chemical bonds based on the same force, forming a molecule. -
The Newsletter, Program, and Abstracts
American Chemical Society DIVISION OF THE HISTORY OF CHEMISTRY NEWSLETTER, PROGRAM AND ABSTRACTS 246th ACS National Meeting Indianapolis, IN September 8-12, 2013 S. C. Rasmussen, Program Chair DIVISION OF THE HISTORY OF CHEMISTRY Chair: Ned D. Heindel Councilor: Mary Virginia Orna Lehigh University Department of Chemistry Department of Chemistry College of New Rochelle Seeley G. Mudd Lab New Rochelle, NY 10805 Bethlehem, PA. 18015 Phone: (914) 654-5302 Phone: (610) 758-3464 Fax: (914) 654-5387 Fax: (610) 758-3461 Email: [email protected] Email: [email protected] Councilor: Roger A. Egolf Chair-Elect: Gary Patterson Pennsylvania State University - Lehigh Valley Department of Chemistry Campus, 2809 Saucon Valley Road Carnegie Mellon University Center Valley, PA 18034 Pittsburgh, PA 15213 Phone: (610) 285-5110 Phone: (412) 268-3324 Fax: (610) 285-5220 Fax: (412) 268-1061 Email: [email protected] Email: [email protected] Alternate Councilor: Joe Jeffers Past Chair: E. Thomas Strom Ouachita Baptist University Department of Chemistry and Biochemistry 410 Ouachita Street, Box 3786 University of Texas at Arlington Arkadelphia, AR 71998-0001 P. O. Box 19065 Phone: (870) 245-5216 Arlington, TX 76019-0065 Fax: (870) 245-5241 Phone: (817) 272-5441 Email: [email protected] Fax: (817) 272-3808 Alternate Councilor: Arthur Greenberg Email: [email protected] Department of Chemistry Secretary-Treasurer: Vera V. Mainz University of New Hampshire 2709 Holcomb Drive Parsons Hall Urbana, IL 61802 Durham, New Hampshire 03824 Phone: (217) 328-6158 Phone: 603 862-1180 Email: [email protected] Fax: 603 862-4278 Email: [email protected] Program Chair: Seth C. -
Physical Origin of Chemical Periodicities in the System of Elements
Pure Appl. Chem. 2019; 91(12): 1969–1999 Conference paper Chang-Su Cao, Han-Shi Hu, Jun Li* and W. H. Eugen Schwarz* Physical origin of chemical periodicities in the system of elements https://doi.org/10.1515/pac-2019-0901 Abstract: The Periodic Law, one of the great discoveries in human history, is magnificent in the art of chemistry. Different arrangements of chemical elements in differently shaped Periodic Tables serve for different purposes. “Can this Periodic Table be derived from quantum chemistry or physics?” can only be answered positively, if the internal structure of the Periodic Table is explicitly connected to facts and data from chemistry. Quantum chemi- cal rationalization of such a Periodic Tables is achieved by explaining the details of energies and radii of atomic core and valence orbitals in the leading electron configurations of chemically bonded atoms. The coarse horizon- tal pseudo-periodicity in seven rows of 2, 8, 8, 18, 18, 32, 32 members is triggered by the low energy of and large gap above the 1s and nsp valence shells (2 ≤ n ≤ 6 !). The pseudo-periodicity, in particular the wavy variation of the elemental properties in the four longer rows, is due to the different behaviors of the s and p vs. d and f pairs of atomic valence shells along the ordered array of elements. The so-called secondary or vertical periodicity is related to pseudo-periodic changes of the atomic core shells. The Periodic Law of the naturally given System of Elements describes the trends of the many chemical properties displayed inside the Chemical Periodic Tables. -
246Th National ACS Meeting, Fall 2013, Indianapolis, IN, HIST Program
American Chemical Society DIVISION OF THE HISTORY OF CHEMISTRY PROGRAM AND ABSTRACTS 246th ACS National Meeting Indianapolis, IN September 8-12, 2013 S. C. Rasmussen, Program Chair DIVISION OF THE HISTORY OF CHEMISTRY Chair: Ned D. Heindel Councilor: Mary Virginia Orna Lehigh University Department of Chemistry Department of Chemistry College of New Rochelle Seeley G. Mudd Lab New Rochelle, NY 10805 Bethlehem, PA. 18015 Phone: (914) 654-5302 Phone: (610) 758-3464 Fax: (914) 654-5387 Fax: (610) 758-3461 Email: [email protected] Email: [email protected] Councilor: Roger A. Egolf Chair-Elect: Gary Patterson Pennsylvania State University - Lehigh Valley Department of Chemistry Campus, 2809 Saucon Valley Road Carnegie Mellon University Center Valley, PA 18034 Pittsburgh, PA 15213 Phone: (610) 285-5110 Phone: (412) 268-3324 Fax: (610) 285-5220 Fax: (412) 268-1061 Email: [email protected] Email: [email protected] Alternate Councilor: Joe Jeffers Past Chair: E. Thomas Strom Ouachita Baptist University Department of Chemistry and Biochemistry 410 Ouachita Street, Box 3786 University of Texas at Arlington Arkadelphia, AR 71998-0001 P. O. Box 19065 Phone: (870) 245-5216 Arlington, TX 76019-0065 Fax: (870) 245-5241 Phone: (817) 272-5441 Email: [email protected] Fax: (817) 272-3808 Alternate Councilor: Arthur Greenberg Email: [email protected] Department of Chemistry Secretary-Treasurer: Vera V. Mainz University of New Hampshire 2709 Holcomb Drive Parsons Hall Urbana, IL 61802 Durham, New Hampshire 03824 Phone: (217) 328-6158 Phone: 603 862-1180 Email: [email protected] Fax: 603 862-4278 Email: [email protected] Program Chair: Seth C. -
Bohr Shell Model of the Atom
Shell model of the atom Mr. Nderitu In 1922, Nobel prize winner Niels Bohr revised Rutherford's model by suggesting that • The electrons were confined into clearly defined orbits. • They could jump between these orbits, but could not freely spiral inward or outward in intermediate states. • An electron must absorb or emit specific amounts of energy for transition between these fixed orbits. Bohr extended the model of Hydrogen to give an approximate model for heavier atoms. This gave a physical picture which reproduced many known atomic properties for the first time. 1 Heavier atoms have more protons in the nucleus, and more electrons to cancel the charge. Bohr's idea was that each discrete orbit could only hold a certain number of electrons. After that orbit is full, the next level would have to be used. This gives the atom a shell structure , in which each shell corresponds to a Bohr orbit. This model is even more approximate than the model of hydrogen, because it treats the electrons in each shell as non-interacting. But the repulsions of electrons are taken into account somewhat by the phenomenon of screening . The electrons in outer orbits do not only orbit the nucleus, but they also orbit the inner electrons, so the effective charge Z that they feel is reduced by the number of the electrons in the inner orbit. For example, the lithium atom has two electrons in the lowest 1S orbit, and these 2 orbit at Z=2. Each one sees the nuclear charge of Z=3 minus the screening effect of the other, which crudely reduces the nuclear charge by 1 unit. -
Reposs #17: the Periodic Table in a National Context: Denmark, 1880-1923
RePoSS: Research Publications on Science Studies RePoSS #17: The Periodic Table in a National Context: Denmark, 1880-1923 Helge Kragh December 2011 Centre for Science Studies, University of Aarhus, Denmark Research group: History and philosophy of science Please cite this work as: Helge Kragh (Dec. 2011). The Periodic Table in a National Con- text: Denmark, 1880-1923. RePoSS: Research Publications on Sci- ence Studies 17. Aarhus: Centre for Science Studies, University of Aarhus. url: http://www.css.au.dk/reposs. Copyright c Helge Kragh, 2011 1 The Periodic Table in a National Context: Denmark, 1880-1923 HELGE KRAGH* In this essay I examine how the periodic system or table was introduced in Denmark in the late nineteenth century, how it was used in chemical textbooks, and the way it was developed by a few of the country’s scientists. Which were the reasons that many Danish chemists felt attracted to Mendeleev’s system? It turns out that the most important reason was the predictive force of the system, in particular Mendeleev’s predictions of new elements. I pay particular attention to the work of H.P.J. Julius Thomsen, which is an important example of “neo- Proutean” attempts to understand the periodic system in terms of internally structured atoms. Moreover, I direct attention to Mendeleev’s connection to Danish science by way of his membership of the Royal Danish Academy of Sciences and Letters. Thomson’s speculations of composite atoms as the ultimate cause of the periodicity of the elements were vindicated by the new developments in atomic theory. A semi-quantitative explanation was offered by Niels Bohr in 1913, and in subsequent refinements of his atomic model he came close to an explanation of the entire periodic system. -
X-Ray Spectroscopy and Moseley's
Henry Gwyn Jeffreys Moseley 1887 - 1915 X-Ray Spectroscopy and Moseley’s Law X-Ray Spectroscopy and Moseley’s Law X-ray spectroscopy is used to study inner shell phenomena of atoms, states of highly ionized atoms produced by accelerators or to determine material properties. There are two principal methods: Using a semiconductor detector or a Bragg-type spectrometer (see expt. Nr. 17). Semiconductor detectors have the advantage to be simple, portable and yielding sufficient resolution to distinguish adjacent elements. They have a good intrinsic efficiency and an acceptable energy resolution in the range of a few percent, whereas the Bragg method yields much higher resolution but very poor detection efficiency. In our experiment a high resolution silicon detector is used to measure the K-lines (or also L-lines) of several elements to verify Moseley’s law. The excitation of inner shell vacancies is performed by using the 59.5 keV γ-line of a strong 241Am source (best range 30 < Z < 65) or by using a small special X-ray tube with a rhodium anode which has its maximum of emission near 14 keV which is preferable for the lower Z elements (10 < Z < 30). By observing the characteristic L - lines one gets access to the elements with Z up to 92, but the L –spectra are yielding more lines and are more complicated. Moseley’s relation has also a broad field of application in material analysis – see experiment Nr. 18. Henry Gwyn Jeffreys Moseley (November 23, 1887 -– August 10, 1915) was an English physicist and a graduate of Trinity College Oxford. -
The Periodic Table and Its Iconicity: an Essay
Firenze University Press www.fupress.com/substantia The Periodic Table and its Iconicity: an Essay Citation: J. H. Maar, A. Maar (2019) The Periodic Table and its Iconicity: an Juergen Heinrich Maar1, Alexander Maar2 Essay. Substantia 3(2) Suppl. 5: 29-48. 1 doi: 10.13128/Substantia-582 Retired, Chemistry Department, Federal University of Santa Catarina 2 Department of Philosophy, State University of Londrina, Paraná Copyright: © 2019 J. H. Maar, A. E-mail: [email protected], [email protected] Maar. This is an open access, peer- reviewed article published by Firenze University Press (http://www.fupress. Abstract. In this essay, we aim to provide an overview of the periodic table’s origins com/substantia) and distributed under and history, and of the elements which conspired to make it chemistry’s most rec- the terms of the Creative Commons ognisable icon. We pay attention to Mendeleev’s role in the development of a system Attribution License, which permits for organising the elements and chemical knowledge while facilitating the teaching of unrestricted use, distribution, and chemistry. We look at how the reception of the table in different chemical communities reproduction in any medium, provided the original author and source are was dependent on the local scientific, cultural and political context, but argue that its credited. eventual universal acceptance is due to its unique ability to accommodate possessed knowledge while enabling novel predictions. Furthermore, we argue that its capacity Data Availability Statement: All rel- to unify apparently disconnected phenomena under a simple framework facilitates our evant data are within the paper and its understanding of periodicity, making the table an icon of aesthetic value, and an object Supporting Information files.