processes Article Chemical Composition and Low-Temperature Fluidity Properties of Jet Fuels Alirio Benavides 1, Pedro Benjumea 1,* , Farid B. Cortés 2,* and Marco A. Ruiz 1 1 Grupo de Yacimientos de Hidrocarburos, Departamento de Procesos y Energía, Facultad de Minas, Universidad Nacional de Colombia, Sede Medellín, Medellín 050034, Colombia;
[email protected] (A.B.);
[email protected] (M.A.R.) 2 Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Departamento de Procesos y Energía, Facultad de Minas, Universidad Nacional de Colombia, Sede Medellín, Medellín 050034, Colombia * Correspondence:
[email protected] (P.B.);
[email protected] (F.B.C.) Abstract: The physicochemical properties of petroleum-derived jet fuels mainly depend on their chemical composition, which can vary from sample to sample as a result of the diversity of the crude diet processed by the refinery. Jet fuels are exposed to very low temperatures both at altitude and on the ground in places subject to extreme climates and must be able to maintain their fluidity at these low temperatures otherwise the flow of fuel to turbine engines will be reduced or even stopped. In this work, an experimental evaluation of the effect of chemical composition on low-temperature fluidity properties of jet fuels (freezing point, crystallization onset temperature and viscosity at −20 ◦C) was carried out. Initially, a methodology based on gas chromatography coupled to mass spectrometry (GC–MS) was adapted to determine the composition of 70 samples of Jet A1 and Jet A fuels. This methodology allowed quantifying the content, in weight percentage, of five main families of hydrocarbons: paraffinic, naphthenic, aromatic, naphthalene derivatives, and tetralin- and indane-derived compounds.