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Soda Sanayii A.Ş 1 SODA SANAYİİ A.Ş. Date : 19.09.2011 SAFETY DATA SHEET Chromium Trioxide According to Rev. Date : 06.05.2014 EU Regulation No (EC) Page: 1/14 Revision No : 06 453/2010 1. Identification of Substance and of the Company 1.1. Product Identifier Substance Name : Chromium Trioxide Molecular Formula : CrO3 EC No : 215-607-8 REACH Registration No : 01-2119458868-17-0001 CAS No : 1333-82-0 1.2. Relevant Identified Uses of the Substance and Uses Advised Against Relevant identified uses; (see SECTION 16 for a complete list of uses) Industrial use [SU 3]; Uses of substances as such or in preparations at industrial sites. Manufacture of fine chemicals [SU 9]; Intermediate in manufacture of other chromium substances. Manufacture of fabricated metal products [SU 15]; Metal surface treatment. No uses advised against. ONLY FOR PROFESSIONAL USAGE! 1.3. Details of the Supplier of the Safety Data Sheet REACH Only Representative : CROMITAL S.P.A. soggetta all'attività di direzione e coordinamento di Soda Sanayii A.Ş. Strada Quattro, palazzo A7, 20090 Assago (MI) Italy Phone : + 39 02 576 06 070 Fax : + 39 02 576 09 175 E-mail : [email protected] Manufacturer : Soda Sanayii A.Ş. Address : Soda Sanayii A.Ş. Kazanli Bucagi Yani 33004 Mersin/Turkey Phone : +90 324 241 6600 Fax : +90 324 451 2850 E-mail of SDS Responsible : [email protected] 1.4. Emergency Tel. Number: +90 324 241 6600 Opening Hours : Only available during office hours (07:00-17:00 CET) 2. Hazards Identification 2.1. Classification of the Substance 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] See SECTION 16 FORM NO: KYS-KF-24-07 1 SODA SANAYİİ A.Ş. Date : 19.09.2011 SAFETY DATA SHEET Chromium Trioxide According to Rev. Date : 06.05.2014 EU Regulation No (EC) Page: 2/14 Revision No : 06 453/2010 2.1.2 Classification according to Directive 67/548/EEC Oxidising; O; R9, Category 1 carcinogens; Carc.Cat.1; R45, Category 2 mutagens; Muta. Cat. 2; R46, Category 3 reproductive toxins; Repr. Cat.3; R62, Very toxic; T+; R26, Toxic; T; R24/25-48/23, Corrosive; C; R35, Sensitising; R42/43, Dangerous for the environment; N; R50-53 , 2.1.3 Additional Information For full text of R-phrases and Hazard- and EU Hazard-statements; see SECTION 16. 2.2. Label Elements Labelling according to Regulation (EC) No 1272/2008 [CLP] Hazard Pictograms: Signal Word: Danger Hazard Statements: H271 May intensify fire or explosion; strong oxidizer H301Toxic if swallowed H310 Fatal in contact with skin H314 Causes severe skin burns and eye damage H330 Fatal if inhaled H340 May cause genetic defects H350 May cause cancer H361 Suspected of damaging fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects FORM NO: KYS-KF-24-07 1 SODA SANAYİİ A.Ş. Date : 19.09.2011 SAFETY DATA SHEET Chromium Trioxide According to Rev. Date : 06.05.2014 EU Regulation No (EC) Page: 3/14 Revision No : 06 453/2010 Precautionary Statements: P201: Obtain special instructions before use P280: Wear protective gloves/protective clothing/eye protection/face protection P302+350: IF ON SKIN: Gently wash with soap and water P304+341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing P307+311: IF EXPOSED: Call a POISON CENTER or doctor/physician P405: Store locked up 2.3. Other Hazards The substance does not contain any PBT or vPvB. 3. Composition / Information on Ingredients 3.1 Substances Name Index Number in CLP Annex VI Weight, % content Chromium Trioxide 024-001-00-0 99.7 (CrO3) 4. First Aid Measures Skin Exposure : Irrigate affected area with copious quantities of water. After contact, wash immediately with plenty of water and soap. Seek immediate medical attention. Eye Exposure : Irrigate with copious quantities of water. Seek immediate medical attention. Inhalation : Remove to fresh air. Irrigate mouth and nasal passages with water. Seek immediate medical attention. Ingestion : Never give anything by mouth to an unconscious person. If swallowed, do not induce vomiting. If conscious, give several glasses of water to drink. Seek immediate medical attention. Accident victims should be given 5 – 10 g ascorbic acid (non-effervescent form) dissolved in water. Repeated doses of 5 –10 g ascorbic acid per day may be given whilst features of toxicity are present. The quantity and length of treatment will be dependent on the severity of the poisoning. 5. Fire Fighting Measures Non-flammable Contact with combustible material may cause fire. Incompatibility : This product may act as an oxidizing agent to initiate or sustain a fire involving organic matter or other easily oxidizable material. FORM NO: KYS-KF-24-07 1 SODA SANAYİİ A.Ş. Date : 19.09.2011 SAFETY DATA SHEET Chromium Trioxide According to Rev. Date : 06.05.2014 EU Regulation No (EC) Page: 4/14 Revision No : 06 453/2010 Decomposition : Decomposition begins at 196 °C liberating oxygen, no hazardous decomposition products observed under normal conditions of use. Measures : All extinguisher types can be used; select on the basis of other materials present. Use water fog – in the absence of a fog fine spray may be used. Equipment : Use self-contained breathing apparatus. Full protective clothing. 6. Accidental Release Measures After Spillage/Leakage/Dust leakage : Collect spilled material in a closed metal container for reclamation or disposal, preferably using vacuum equipment. Avoid heat, smoking, oils/greases when handling. Personal Precaution : Operatives to use Personal Protective Equipment, i.e. eye protection, appropriate respiratory equipment and gloves, overalls and safety footwear. Environmental Precautions : Do not empty into drains, sewers/watercourses i.e. contain. If spillage does enter watercourses or sewers, inform the appropriate local water authority or National Regulatory body immediately. Small areas of contamination, which cannot be removed, may be treated with ferrous sulphate solution or sodium metabisulphite solution to reduce hexavalent chromium to the trivalent form and the pH adjusted to 8.5 with sodium carbonate or sodium hydroxide solution to precipitate chromium hydroxide. Use personal protective equipment. 7. Handling and Storage Oxidizer 7.1. Precautions for Safe Handling Wear personal protective equipment to avoid contact with skin, eyes or clothing. Remove any contaminated clothing and launder before re-use. Wear respiratory protection where there is a risk of exposure to the product. 7.2. Conditions for Safe Storage, Including Any Incompabilities Store in a cool & dry place away from foodstuffs and easily oxidizable/combustible material. Keep product away from heat and sun. Keep container closed when it is not in use. Container may only be opened under local exhaust ventilation. Segragation as for class 5.1 however, “Seperated from” classes 4.1 and 7. FORM NO: KYS-KF-24-07 1 SODA SANAYİİ A.Ş. Date : 19.09.2011 SAFETY DATA SHEET Chromium Trioxide According to Rev. Date : 06.05.2014 EU Regulation No (EC) Page: 5/14 Revision No : 06 453/2010 8. Exposure Controls / Personal Protection Derivation of DNEL(s) /DMELs Endpoint Quantitative dose descriptor Associated relevant Remarks on study (appropriate unit) or effect qualitative assessment Local Systemic Acute toxicity oral - LDlo: 32 mg/kg Death Acute oral toxicity study bw dermal 35 mg/kg bw 35 mg/kg bw Local irritation; Acute dermal toxicity (LOAEL) (LOAEL) signs of toxicity study inhalation 0.19 mg/L 0.19 mg/L Death, local Acute inhalation toxicity LOAEC LOAEC irritation study Irritation/Corrosivity skin - NA Corrosivity Substance found to be corrosive in vitro and in vivo eye - NA Severe irritation Substance found to be a severe eye irritant resp. tract - NA No data: irritation No data: irritation likely likely Sensitisation skin - NA Skin sensitisation Based on human data and experience resp. tract - NA Respiratory Based on human sensitisation experience Repeated dose toxicity oral - LOAEL 1.7 Haematological Read-across from mg/kg bw/d effects related compounds sub-acute/ sub-chronic/ dermal - - Irritation / - chronic corrosivity likely inhalation LOAEC 1.81 NOAEC 1.81 Local irritation Mouse inhalation mg/m3 mg/m3 toxicity studies Mutagenicity in vitro Not - Mutagenicity Consistent positive quantifiable effects seen in various studies in vivo Not Not Mutagenicity Consistent positive quantifiable quantifiable effects seen in various studies Carcinogenicity oral No relevant No relevant - - data data dermal No relevant No relevant - - data data inhalation 0.1 mg/m3 No effects Lung cancer Review of published (Cr VI) predicted epidemiology studies Additional risk 1-6/1000 Reproductive toxicity oral NA NOAEL 40 None Continuous breeding mg/kg bw/d study with potassium fertility impairment dichromate dermal NA - - - inhalation NA - - - Reproductive toxicity oral NA LOAEL 20 Significant Read-across from mg/kg bw/d (Cr developmental potassium dichromate developmental toxicity (VI) effects dermal NA - - - inhalation NA - - - FORM NO: KYS-KF-24-07 1 SODA SANAYİİ A.Ş. Date : 19.09.2011 SAFETY DATA SHEET Chromium Trioxide According to Rev. Date : 06.05.2014 EU Regulation No (EC) Page: 6/14 Revision No : 06 453/2010 PNEC Values PNEC aquatic PNEC Value Assessment Remarks/Justification factor PNEC aqua – The PNEC value for 10 Extract from EU RAR (2005, Section 3.2.1.7.1): freshwater (mg/L) Cr (VI) is 3.4 µg/L, According to the standard assessment factor approach, the PNEC equivalent to 6.5 µg/l is derived from the lowest CrO3 NOEC available for Cr (III). The lowest NOEC is 4.7 μg/l, for The PNEC value for reproduction of the cladoceran Ceriodaphnia dubia. As there is a Cr (III) is large amount of long-term effect data on a wide range of aquatic 4.7 µg/L, equivalent organisms, an assessment factor of 10 is used, giving a PNEC by to 9.0 µg/L CrO3 this method of 0.47 μg/l.
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