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International Symposium Relations Between Homogeneous and Heterogeneous Catalysis LBNL-62755 Abs. Abstracts International Symposium on Relations between Homogeneous and Heterogeneous Catalysis July 16-20, 2007 Gabor Somorjai, Ed. University of California, Berkeley, CA Preface The International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC) has a long and distinguished history. Since 1974, in Brussels, this event has been held in Lyon, France (1977), Gr¨oningen, The Netherlands (1981); Asilomar, California (1983); Novosibirsk, Russia (1986); Pisa, Italy (1989); Tokyo, Japan (1992); Balatonf¨ured, Hungary (1995); Southampton, United Kingdom (1999); Lyon, France (2001); Evanston, Illinois (2001) and Florence, Italy (2005). The aim of this international conference in Berkeley is to bring together practitioners in the three fields of catalysis, heterogeneous, homogeneous and enzyme, which utilize mostly nanosize particles. Recent advances in instrumentation, synthesis and reaction studies permit the nanoscale characterization of the catalyst systems, often for the same reaction, under similar experimental conditions. It is hoped that this circumstance will permit the development of correlations of these three different fields of catalysis on the molecular level. To further this goal we aim to uncover and focus on common concepts that emerge from nanoscale studies of structures and dynamics of the three types of catalysts. Another area of focus that will be addressed is the impact on and correlation of nanosciences with catal- ysis. There is information on the electronic and atomic structures of nanoparticles and their dynamics that should have importance in catalyst design and catalytic activity and selectivity. There are over 300 attendees registered for this meeting attesting to the vitality of these fields of sci- ence. We look forward to making your visit in Berkeley enjoyable as well as scientifically rewarding. Gabor A. Somorjai Chair, ISHHC XIII 2 Advisory Board Baiker, A., Switzerland Koningsberger, D.C., The Netherlands Bao, X., China Li, C., China Basset, J.-M., France Marks, T., US Beller, M., Germany Mason, R., UK Bianchini, C., Italy Psaro, R., Italy Corma, A., Spain Schmid, G., Germany Ertl, G., Germany Schwab, E., Germany Evans, J., UK Somorjai, G.A., US Freund, H.-J., Germany Stevens, J., US Giambastiani, G., Italy Thomas, J.M., UK Ichikawa, M, Japan Tilley, T. D., US Ikariya, T., Japan Ugo. R., Italy Iwasawa, Y., Japan Joyner, R., UK van Leeuwen, P.W., The Netherlands Kaneda, K., Japan van Santen, R. A., The Netherlands Kiricsi, I., Hungary Zecchina, A., Italy Kn¨ozinger, H., Germany Ziolkowski, J., Poland 3 Program Lecture Hall A – 105 Stanley Hall Lecture Hall B – 106 Stanley Hall Sunday, July 15 4:00-6:00 p.m. Reception and Registration Faculty Club, University of California, Berkeley Monday, July 16 7:30-8:30 Registration Stanley Hall Atrium Lecture Hall A Morning Chair: Gabor Somorjai 8:30-9:00 Opening Gabor A. Somorjai 9:00-9:45 (PL1) – Jan-E. B¨ackvall 9:45-10:30 (PL2) – Hans-Joachim Freund Break 10:50-11:35 (PL3) – Jens Nørskov 11:35-12:20 (PL4) – Bruno Chaudret Lunch Lecture Hall A Lecture Hall B Afternoon Chair: Francisco Zaera Chair: Bruce Gates 2:00-2:35 (KN1) – Jean-Marie Basset 2:00-2:20 (O1) – Nicola Scott 2:35-3:10 (KN2) – Norbert Kruse 2:20-2:40 (O2) – Eric L. Margelefsky 2:40-3:00 (O3) – Christopher W. Jones 3:00-3:20 (O4) – Imre Kirisci Break 3:30-4:05 (KN3) – Walter Kaminsky 3:30-3:50 (O5) – Ive Hermans 4:05-4:40 (KN4) – Georg Held 3:50-4:10 (O6) – Harold H. Kung 4:40-5:00 (O9) – Alex Bell 4:10-4:30 (O7) – Jie Fan 4:30-4:50 (O8) – Richard Joyner 4 Program Tuesday, July 17 Lecture Hall A Morning Chair: Ron Mason 8:30-9:15 (PL5) – Sunney Xie 9:15-10:00 (PL6) – Per Siegbahn Break 10:20-11:05 (PL7) – Francisco Zaera 11:05-11:50 (PL8) – Carolyn Bertozzi 11:50-12:25 (KN5) – Paul Alivisatos Lunch Lecture Hall A Lecture Hall B Afternoon Chair: Tobin Marks Chair: Richard Joyner 2:00-2:35 (KN6) – Istv´anHorv´ath 2:00-2:20 (O10) – Devis Di Tommaso 2:35-3:10 (KN7) – Anders Holmen 2:20-2:40 (O11) – Xinhe Bao 2:40-3:00 (O12) – Hans Schulz 3:00-3:20 (O13) – Heinz Frei Break 3:30-4:05 (KN8) – Malgorzata Witko 3:30-3:50 (O14) – Gerd Buntkowsky 4:05-4:25 (O15) – Peter Maitlis 3:50-4:10 (O16) – Philippe Sautet 4:25-4:45 (O17) – Peter Stair 4:10-4:30 (O18) – Randall Meyer 4:45-5:05 (O19) – Thomas Maschmeyer 4:30-4:50 (O20) – Alex Katz 6:30-9:00 Banquet and Cruise, San Francisco Bay Wednesday, July 18 Lecture Hall A Morning Chair: Peter Stair 8:30-9:15 (PL9) – Avelino Corma 9:15-10:00 (PL10) – Tobin Marks Break 10:20-11:05 (PL12) – Mostafa El-Sayed 11:05-11:40 (KN9) – Graham Hutchings 11:40-12:15 (KN10) – Neville Richardson Lunch Stanley Hall Atrium 2:00-5:00 Poster Session Wine and Cheese Reception 5 Program Thursday, July 19 Lecture Hall A Morning Chair: Heinz Frei 8:30-9:15 (PL12) – Yasuhiro Iwasawa 9:15-10:00 (PL13) – T. Don Tilley Break 10:20-11:05 (PL14) – Peidong Yang 11:05-11:50 (PL15) – Thomas Colacot 11:50-12:25 (KN11) – Riitta Keiski Lunch Lecture Hall A Lecture Hall B Afternoon Chair: Graham Hutchings Chair: Steve Overbury 2:00-2:20 (O21) – Wolfgang E. Hoelderich (O22) – Esther Sulman 2:20-2:40 (O23) – Song Ihl Woo (O24) – Atsushi Fukuoki 2:40-3:00 (O25) – Giuliano Giambastiani (O26) – Carlos F. Sanz-Navarro 3:00-3:20 (O26) – I.V. Kozhevnikov (O28) – Agnes´ Mastalir Break 3:40-4:00 (O29) – Thomas F. Jaramillo (O30) – Mohd Ambar Yarmo 4:00-4:20 (O31) – Bruce Gates (O32) – Yunjie Ding 4:20-4:40 (O33) – Robert M. Rioux (O34) – Gabor Laurenczy 4:40-5:00 (O35) – Sven Oscarsson (O36) – Yousung Jung Friday, July 20 Lecture Hall A Morning Chair: Georg Held 8:30-9:15 (PL16) – Chris Hardacre 9:15-9:50 (KN12) – Michael Bowker Break Lecture Hall A Lecture Hall B Chair: Georg Held Chair: Imre Kiricsi 10:10-10:30 (O37) – Mizuki Tada (O38) – Matthias Koebel 10:30-10:50 (O39) – Miquel Salmeron (O40) – Thomas Bligaard 10:50-11:10 (O41) – Steven H. Overbury (O42) – Hongbo Li Lecture Hall A 11:10-11:25 Poster Awards 11:30-12:00 Conclusion and Summary Sir Ronald Mason 6 Plenary Lectures PL1. Jan-E. B¨ackvall, Stockholm University, Sweden ”Combination of Enzymes and Homogeneous Metal Catalysts. A Powerful Approach in Asymmetric Catalysis” PL2. Hans-Joachin Freund, Fritz-Haber-Institute, Germany ”Model Systems in Heterogeneous Catalysis: Selectivity Studied at the Atomic Level” PL3. Jens K. Nørskov, Technical University of Denmark ”Structural Effects in Reactivity of Metal Surface and Nanoparticles” PL4. Bruno Chaudret, CNRS, Toulouse, France ”Organometallic Nanoparticles: A Link between Molecular Organometallic Complexes and Hetero- geneous Catalysts” PL5. Sunney Xie, Harvard University, USA ”Single Molecule Enzymology” PL6. Per Siegbahn, University of Stockholm, Sweden ”Reaction Mechanisms of Redox-Active Enzymes” PL7. Francisco Zaera, Univ. of California, Riverside, USA ”Mechanistic Details of Chiral Modification in Catalysis” PL8. Carolyn Bertozzi, Univ. of California, Berkeley, USA ”Catalysis at the Interface of Chemistry and Biology” PL9. Avelino Corma, Univ. Politecnica de Valencia, Spain ”Well Defined Active Sites Help to Relate Homogeneous and Heterogeneous Catalysis” PL10. Tobin J. Marks, Northwestern University, USA ”Synthesis of New Polymeric Materials Using Highly Electrophilic Homogeneous and Heterogeneous Catalysts” PL11. Mostafa El-Sayed, Georgia Institute of Technology, USA ”On Colloidal Nano-Catalysis” PL12. Yasuhiro Iwasawa, The University of Tokyo, Japan ”Conceptual Integration of Homogeneous and Heterogeneous Catalyses for New Sustainable Green Processes on Catalyst Surfaces” PL13. T. Don Tilley, University of California, Berkeley, USA ”Well-defined, Surface-Bound Catalytic Centers: Relationships between Homogeneous and Hetero- geneous Catalysis” PL14. Peidong Yang, University of California, Berkeley, USA ”Metal Nanocrystals: Shape Control, Assembly, Surface Chemistry and Catalysis” PL15. Thomas Colacot, Johnson Matthey, USA ”Highly Active Supported and Unsupported Homogeneous Tunable Catalysts for Challenging Cou- pling Reactions” PL16. Christopher Hardacre, Queens University, Belfast, UK ”Ionic Liquid Mediated Homogeneously and Heterogeneously Catalysed Reactions” 7 Keynote Lectures KN1. Jean-Marie Basset, CNRS, Villeurbanne, France ”Where are We Today in the Overlap between Homogeneous and Heterogeneous Catalysis?” KN2. Norbert Kruse, Universite Libre de Bruxelles, Belgium ”Catalytic CO Hydrogenation: Mechanisms and Kinetics from Studies on the Nano- and Macroscale” KN3. Walter Kaminsky, University of Hamburg, Germany ”In-situ Polymerization of Olefins on Nanoparticles or Fibers by Metallocene Catalysis” KN4. Georg Held, Reading University, UK ”The Chemistry of Intrinsically Chiral Surfaces – Enzymes in Two dimensions” KN5. Paul Alivisatos, University of California, Berkeley, USA ”Hollow, Nested, Striped and Segmented Colloidal Inorganic Nanocrystals as Potential New Cata- lysts” KN6. Istv´anHorv´ath, E¨otv¨osUniversity, Budapest, Hungary ”Integration of Homogeneous and Heterogeneous Catalytic Processes for Sustainable Biomass Con- version” KN7. Anders Holmen, Norwegian University of Science and Technology, Norway ”The Relation between Structure and Composition of Supported Nanoparticles on Catalyst Perfor- mance” KN8. Malgorzata Witko, Polish Academy of Sciences, Poland ”Molybdenum Active Centers in Hetero- and Homogeneous Catalytic Systems – Description from First Principles” KN9. Graham Hutchings, Cardiff University, UK ”Gold Catalysis using Heterogeneous and Homogeneous Catalysts” KN10. Neville V. Richardson, University of St. Andrews, UK ”The Quest for Enantioselectivity in Heterogeneous Catalysis KN11. Riitta Keiski, University of Oulu, Finland ”Combining the Best Features of Heterogeneous and Homogeneous Catalysis – The Importance of Catalyst Nanoparticles in Microreactors Design” KN12. Michael Bowker, Cardiff University, UK ”The Role of Mo in Selective Oxidation Catalysis” 8 Oral Lectures O1. Nicola Scott, Cambridge University, UK ”Enantiospecific Interaction at an Intrinsically Chiral Surface: A RAIRS Study of Alanine on CU {531}” O2.
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