Depleted Uranium Hexafluoride Management Program
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140. Sulphuric, Hydrochloric, Nitric and Phosphoric Acids
nr 2009;43(7) The Nordic Expert Group for Criteria Documentation of Health Risks from Chemicals 140. Sulphuric, hydrochloric, nitric and phosphoric acids Marianne van der Hagen Jill Järnberg arbete och hälsa | vetenskaplig skriftserie isbn 978-91-85971-14-5 issn 0346-7821 Arbete och Hälsa Arbete och Hälsa (Work and Health) is a scientific report series published by Occupational and Enviromental Medicine at Sahlgrenska Academy, University of Gothenburg. The series publishes scientific original work, review articles, criteria documents and dissertations. All articles are peer-reviewed. Arbete och Hälsa has a broad target group and welcomes articles in different areas. Instructions and templates for manuscript editing are available at http://www.amm.se/aoh Summaries in Swedish and English as well as the complete original texts from 1997 are also available online. Arbete och Hälsa Editorial Board: Editor-in-chief: Kjell Torén Tor Aasen, Bergen Kristina Alexanderson, Stockholm Co-editors: Maria Albin, Ewa Wigaeus Berit Bakke, Oslo Tornqvist, Marianne Törner, Wijnand Lars Barregård, Göteborg Eduard, Lotta Dellve och Roger Persson Jens Peter Bonde, Köpenhamn Managing editor: Cina Holmer Jörgen Eklund, Linköping Mats Eklöf, Göteborg © University of Gothenburg & authors 2009 Mats Hagberg, Göteborg Kari Heldal, Oslo Arbete och Hälsa, University of Gothenburg Kristina Jakobsson, Lund SE 405 30 Gothenburg, Sweden Malin Josephson, Uppsala Bengt Järvholm, Umeå ISBN 978-91-85971-14-5 Anette Kærgaard, Herning ISSN 0346–7821 Ann Kryger, Köpenhamn http://www.amm.se/aoh -
Efficiency of Chemical Desiccants Fred Charles Trusell Iowa State University
Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1961 Efficiency of chemical desiccants Fred Charles Trusell Iowa State University Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Analytical Chemistry Commons Recommended Citation Trusell, Fred Charles, "Efficiency of chemical desiccants " (1961). Retrospective Theses and Dissertations. 2422. https://lib.dr.iastate.edu/rtd/2422 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. This dissertation has been Mic 61—2276 microfilmed exactly as received TRUSELL, Fred Charles. EFFICIENCY OF CHEMICAL DESICCANTS. Iowa State University of Science and Technology Ph.D., 1961 Chemistry, analytical University Microfilms, Inc., Ann Arbor, Michigan iii-i-i -vx l-SaSi»!.*. VA1» 1ZDO-LV Wi-TVi.a by Fred Charles Truseli A Dissertation Submitted to the Graduate Faculty in Partial Fulfillment of The Requirements for the Degree of DOCTOR OF PHILOSOPHY Major Subject: Analytical Chemistry Approved Signature was redacted for privacy. In Charge of Major Work Signature was redacted for privacy. Head of Major Department Signature was redacted for privacy. Iowa State University Of Science and Technology Ames, Iowa -
The Radiochemistry of Cesium NUCLEAR SCIENCE SERIES: MONOGRAPHS on RADIOCHEMISTRY and RADIOCHEMICAL TECHNIQUES
National Academy Sciences National Research Council I NUCLEAR SCIENCE SERIES The Radiochemistry of Cesium NUCLEAR SCIENCE SERIES: MONOGRAPHS ON RADIOCHEMISTRY AND RADIOCHEMICAL TECHNIQUES AvailablefromtheNationalTechnicalInformationService, U.S.DepartmentofCommerca.Springfield,Virginia22161 ELEMENTS Selenlum, NAS-NS-3030 (Rev. ) [ 19651, $4.50 Silicon, NAS-NS-3049 (Rev.) [ 1968], $5.00 Recent Radiochemlcal Seoaratlon Procedures Silver, NAS-NS-3047 [19611 , $4,50 for As, At, Be, Mg, Ni, hu, and Se, NAS-NS- Sodium, NAS-NS-3055 [1962], $4.00 3059 [19741 , $5.00 Sulfur, NAS-NS-3054 [ 1961] , $6.00 Alumlnum and G.sllium, NAS-NS-3032 [1961] , Technetium, NAS-NS-3021 [ 1960], $4.50 $4.50 Tellurlum, NAS-NS-303E [ 19601,$4,00 Americium and Curium, NAS-NS-3006 [ 1960] , Thorium, NAS-NS-3004 [19601 , $4.50 $4.50 Tin, NAS-NS-3023 [1960] , $4.50 Antimonv, NAS-NS-3033 [ 1961] , $4.60 Titenium, NAS-NS-3034 (Rev. ) [ 1971] .$5.00 Arsenic, NAS-NS-3002 (Rev. ) [1965] , $3.60 Tranwurium Elements, NAS-NS-3031 [1960] , Astatlne, NAS-NS-3012 [ 1960] , $4.00 $4.00 B.srlum. Calclum. and Strontium. Tungsten, NAS-NS-3042 [1 961] , $4.00 NAS-NS-301O [19601 ,$5.50 Urenlum, NAS-NS-3050 [19611 , $10.60 BarVllium, NAS-NS-3013 [19601 , $4.50 Venadlum, NAS-NS-3022 [ 1960] , $5.00 Blamuth. NAS-NS-3061 [19771 . $4.75 Zinc, NAS-NS-3015 [1960] ,$4.50 Cadmium, NAS-NS-3001 [ 1960] , $4.50 Zi:40;&m and Hafnium, NAS.NS.3011 [ 19601, Carbon, Nitrogen, and OxV#en, NAS-NS-3019 [ 1960] , $3.60 Cesium, NAS-NS-3035 [ 1961] , $4.50 Chromium. -
The Example of Sulfuric Acid
life Article Evaluating Alternatives to Water as Solvents for Life: The Example of Sulfuric Acid William Bains 1,2,*, Janusz Jurand Petkowski 1 , Zhuchang Zhan 1 and Sara Seager 1,3,4 1 Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139, USA; [email protected] (J.J.P.); [email protected] (Z.Z.); [email protected] (S.S.) 2 School of Physics & Astronomy, Cardiff University, 4 The Parade, Cardiff CF24 3AA, UK 3 Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139, USA 4 Department of Aeronautics and Astronautics, Massachusetts Institute of Technology, Cambridge, MA 02139, USA * Correspondence: [email protected] Abstract: The chemistry of life requires a solvent, which for life on Earth is water. Several alternative solvents have been suggested, but there is little quantitative analysis of their suitability as solvents for life. To support a novel (non-terrestrial) biochemistry, a solvent must be able to form a stable solution of a diverse set of small molecules and polymers, but must not dissolve all molecules. Here, we analyze the potential of concentrated sulfuric acid (CSA) as a solvent for biochemistry. As CSA is a highly effective solvent but a reactive substance, we focused our analysis on the stability of chemicals in sulfuric acid, using a model built from a database of kinetics of reaction of molecules with CSA. We consider the sulfuric acid clouds of Venus as a test case for this approach. The large majority of terrestrial biochemicals have half-lives of less than a second at any altitude in Venus’s clouds, but three sets of human-synthesized chemicals are more stable, with average half-lives of days to weeks at the conditions around 60 km altitude on Venus. -
Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants
pubs.acs.org/joc Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants D. Bradley G. Williams* and Michelle Lawton Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, P.O. Box 524, Auckland Park 2006, South Africa [email protected] Received August 12, 2010 Various commonly used organic solvents were dried with several different drying agents. A glovebox- bound coulometric Karl Fischer apparatus with a two-compartment measuring cell was used to determine the efficiency of the drying process. Recommendations are made relating to optimum drying agents/conditions that can be used to rapidly and reliably generate solvents with low residual water content by means of commonly available materials found in most synthesis laboratories. The practical method provides for safer handling and drying of solvents than methods calling for the use of reactive metals, metal hydrides, or solvent distillation. Introduction facilities. Accordingly, users of the published drying methods rely upon procedures that generally have little or no quanti- Laboratories involved with synthesis require efficient methods fied basis of application and generate samples of unknown with which to dry organic solvents. Typically, prescribed water content. In a rather elegant exception, Burfield and co- methods1 are taken from the literature where little or no workers published a series of papers3 some three decades ago quantitative analysis accompanies the recommended drying in which the efficacy of several drying agents was investi- method. Frequently, such methods call for the use of highly gated making use of tritiated water-doped solvents. The reactive metals (such as sodium) or metal hydrides, which drying process was followed by scintillation readings, and increases the risk of fires or explosions in the laboratory. -
Examples of Total Synthesis
1262 COMMUNICATIONSTO THE EDITOR Tol. i9 methylation,s was converted into the trans product followed by crystallization from acetone-water IV, m.p. 202-204", C, 78.9; H, 8.33, in 69%.yield. containing an equivalent of pyridine, led to 75q) Alkaline peroxide oxidation4 transformed IV into V of D-a-phenoxymethylpenicilloicacid hydrate (IV), (R = H) which was converted with diazomethane CI~HZONZO~S.H~O;m.p. 129" dec. [Found: C, into the ester V (R = CHa), and cyclized with 49.61; H, 5.77; N, 6.94; aZ5D + 94" (c, 1 in potassium t-butoxide in benzene. The resulting methanol)]. Identity with a sample prepared by keto ester was decarbomethoxylated with hydro- saponification of natural penicillin V5 was estab- chloric and acetic acid to give the dl-ketone VI, lished by comparison of m.p., infrared spectra m.p. 155.5-161.5". The infrared spectrum of this (KBr), optical rotation and mixed m.p. material was indistinguishable from that of Treatment with N,N'-dicyclohexylcarbodiimide authentic 3,B-hydroxy-9,1l-dehydroandrostane-17- in dioxane-water (20 min. at 25') cyclized Was the one.g monopotassium salt in l(rl27, yield. By partition (S) At this stage the 3-hydroxyl group was protected as the tetra. between methyl isobutyl ketone and pH 5.5 phos- hydropyranyl ether (cf. ref. 3). phate buffer (two funnels) the totally synthetic (9) C. W. Shoppee, J. Ckem. SOC.,1134 (1946). crystalline potassium salt of penicillin V was iso- DEPARTMENTOF CHEMISTRY lated. The natural and synthetic potassium salts UNIVERSITYOF WISCOXSIN WILLIAMS. -
ETHANOL, ANHYDROUS Draft Proposal for Revision for the International Pharmacopoeia
Working document QAS/21.873 January 2021 Draft for comments 1 ETHANOL, ANHYDROUS 2 (ETHANOLUM, ANHYDRICUM) 3 Draft proposal for revision for The International Pharmacopoeia 4 (January 2021) 5 DRAFT FOR COMMENTS Please send any comments you may have on this draft working document to Dr Herbert Schmidt, Technical Officer, Norms and Standards for Pharmaceuticals, Technical Standards and Specifications ([email protected]), with a copy to Ms Claire Vogel ([email protected]) by 31 March 2021. Our working documents are sent out electronically and they will also be placed on the WHO Medicines website (https://www.who.int/teams/health-product-and-policy-standards/standards-and- specifications/pharmaceuticals/current-projects) for comments under the “Working documents in public consultation” link. If you wish to receive our draft guidelines, please send your e-mail address to [email protected] and your name will be added to our electronic mailing list. 6 7 . 8 © World Health Organization 2021 9 10 All rights reserved. 11 12 This is a draft. The content of this document is not final, and the text may be subject to revisions before publication. The 13 document may not be reviewed, abstracted, quoted, reproduced, transmitted, distributed, translated or adapted, in part or in 14 whole, in any form or by any means without the permission of the World Health Organization. 15 Please send any request for permission to: Dr Sabine Kopp, Team Lead, Norms and Standards for Pharmaceuticals, Technical 16 Standards and Specifications, Department of Health Products Policy and Standards, World Health Organization, CH-1211 17 Geneva 27, Switzerland, email: [email protected].