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Material Safety Data Sheet Ethanol SDA1, Anhydrous MSDS# 88067 Section 1

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Material Safety Data Sheet Ethanol SDA1, Anhydrous MSDS# 88067 Section 1 - Chemical Product and Company Identification MSDS Name: Ethanol SDA1, Anhydrous Catalog Numbers: A405-20, A405P-4 Synonyms: Ethyl alcohol, denatured; Grain alcohol, denatured; Ethyl hydroxide, denatured. Fisher Scientific Company Identification: One Reagent Lane Fair Lawn, NJ 07410 For information in the US, call: 201-796-7100 Emergency Number US: 201-796-7100 CHEMTREC Phone Number, US: 800-424-9300 Section 2 - Composition, Information on Ingredients ---------------------------------------- Risk Phrases: 11 CAS#: 64-17-5 Chemical Name: Ethyl alcohol %: 92-93 EINECS#: 200-578-6 Hazard Symbols: F ---------------------------------------- ---------------------------------------- Risk Phrases: 11 23/24/25 39/23/24/25 CAS#: 67-56-1 Chemical Name: Methyl alcohol %: 3.7 EINECS#: 200-659-6 Hazard Symbols: F T ---------------------------------------- ---------------------------------------- Risk Phrases: CAS#: 108-10-1 Chemical Name: Methyl iso-butyl ketone %: 1.0-2.0 EINECS#: 203-550-1 Hazard Symbols: ---------------------------------------- ---------------------------------------- Risk Phrases: 11 20 CAS#: 108-88-3 Chemical Name: Toluene %: 0.07 EINECS#: 203-625-9 Hazard Symbols: F XN ---------------------------------------- ---------------------------------------- Risk Phrases: 11 36 66 67 CAS#: 141-78-6 Chemical Name: Ethyl acetate %: <1.0 EINECS#: 205-500-4 Hazard Symbols: F XI ---------------------------------------- Text for R-phrases: see Section 16 Hazard Symbols: XN F Risk Phrases: 11 20/21/22 68/20/21/22 Section 3 - Hazards Identification EMERGENCY OVERVIEW Warning! Flammable liquid and vapor. Causes respiratory tract irritation. May cause central nervous system depression. Causes severe eye irritation. This substance has caused adverse reproductive and fetal effects in humans. Causes moderate skin irritation. May cause liver, kidney and heart damage. Target Organs: Kidneys, heart, central nervous system, liver, eyes, optic nerve. Potential Health Effects Causes severe eye irritation. May cause painful sensitization to light. May cause chemical conjunctivitis and Eye: corneal damage. Inhalation, ingestion or skin absorption of methanol can cause significant disturbances in vision, including blindness. Causes moderate skin irritation. May cause cyanosis of the extremities. Methanol can be absorbed through the Skin: skin, producing systemic effects that include visual disturbances. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, Ingestion: dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, Inhalation: dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Animal Chronic: studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage. Section 4 - First Aid Measures Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower Eyes: eyelids. Get medical aid. Skin: Get medical aid. Wash clothing before reuse. Flush skin with plenty of soap and water. Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give Ingestion: anything by mouth to an unconscious person. Get medical aid. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If Inhalation: breathing is difficult, give oxygen. Get medical aid. Notes to Treat symptomatically and supportively. Physician: Section 5 - Fire Fighting Measures Treat symptomatically and supportively. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an General explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a Information: fire. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use Extinguishing water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may Media: be ineffective. Do NOT use straight streams of water. Autoignition 362.8 deg C (Ethano Temperature: Flash Point: 13.9 deg C ( 57.02 deg F) Explosion 3.3 (Ethanol) Limits: Lower: Explosion 18.0 (Ethanol) Limits: Upper: NFPA Rating: health: 2; flammability: 3; instability: 0; Section 6 - Accidental Release Measures General Use proper personal protective equipment as indicated in Section 8. Information: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all Spills/Leaks: sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - Handling and Storage Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Handling: Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Storage: Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Do not store near perchlorates, peroxides, chromic acid or nitric acid. Section 8 - Exposure Controls, Personal Protection +-------------------- +------------------- +------------------- +----------------- + | Chemical Name | ACGIH | NIOSH |OSHA - Final PELs| |-------------------- |------------------- |------------------- |----------------- | | Ethyl alcohol |1000 ppm |1000 ppm TWA; |1000 ppm TWA; | | | |1900 mg/m3 TWA | 1900 mg/m3 TWA | | | |3300 ppm IDLH | | |-------------------- |------------------- |------------------- |----------------- | | Methyl alcohol |200 ppm; 250 ppm |200 ppm TWA; 260 |200 ppm TWA; 260 | | | STEL; Skin - | mg/m3 TWA 6000 |mg/m3 TWA | | |potential | ppm IDLH | | | |significant | | | | |contribution to | | | | |overall exposure | | | | | by the cutaneous | | | | |r oute | | | |-------------------- |------------------- |------------------- |----------------- | | Methyl iso-butyl ke|50 ppm; 75 ppm |50 ppm TWA; 205 |100 ppm TWA; 410 | | tone | STEL |mg/m3 TWA 500 |mg/m3 TWA | | | | ppm IDLH | | |-------------------- |------------------- |------------------- |----------------- | | Toluene |20 ppm |100 ppm TWA; 375 |200 ppm TWA; 300 | | | | mg/m3 TWA 500 |ppm Ceiling | | | |ppm IDLH | | |-------------------- |------------------- |------------------- |----------------- | | Ethyl acetate |400 ppm |400 ppm TWA; 1400 |400 ppm TWA; | | | |mg/m3 TWA 2000 |1400 mg/m3 TWA | | | |ppm IDLH | | +-------------------- +------------------- +------------------- +----------------- + OSHA Vacated PELs: Ethyl alcohol: 1000 ppm TWA; 1900 mg/m3 TWA Methyl alcohol: 200 ppm TWA; 260 mg/m3 TWA Methyl iso-butyl ketone: 50 ppm TWA; 205 mg/m3 TWA Toluene: 100 ppm TWA; 375 mg/m3 TWA Ethyl acetate: 400 ppm TWA; 1400 mg/m3 TWA Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Personal Protective Equipment Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face Eyes: protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or Respirators: European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - Physical and Chemical Properties Physical State: Liquid Color: clear, colorless Odor: alcohol-like pH: Not available Vapor Pressure: 48 mm Hg Vapor Density: 1.5 Evaporation Rate: 3.6 (Butyl Acetate=1) Viscosity: Not available Boiling Point: 77.1 deg C ( 170.78F) Freezing/Melting Point: <-90 deg C Decomposition Temperature: Not available Solubility in water: 100% at 20C Specific Gravity/Density: .785-.792 Molecular Formula: Mixture Molecular Weight: Not Available Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Incompatible materials, ignition
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