Isotopes of Iodine 1 Isotopes of Iodine
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A Low Cost Supercritical Nuclear + Coal 3.0 Gwe Power Plant
n. 461 August 2012 A low cost supercritical Nuclear + Coal 3.0 Gwe power plant Pedro Cosme Costa Vieira 1 1 FEP-UP, School of Economics and Management, University of Porto A low cost supercritical Nuclear + Coal 3.0 Gwe power plant. Pedro Cosme Costa Vieira, [email protected] Faculdade de Economia do Porto, R. Dr. Roberto Frias, 80, 4200-464 Porto, Portugal Abstract: The rapid growth in the consumption of electricity in China and India has been covered at 80% by coal, which has the side effect of emitting CO2 to the atmosphere. The alternative is the use of nuclear energy that, to become unquestionably competitive, must use supercritical water as coolant. The problem is that the inflow temperature of a supercritical turbine must be at least 500 ºC that is impossible to attain using the mainstream PWR and it is uneconomical to accomplish in a pressure tubes similar to the CANDU and the RBMK reactors. In this paper, I propose a simple but important innovation that is the coupling of the nuclear reactor to a coal fired heater. With this apparently small improvement, it becomes feasible to build a multi-tube slightly supercritical pressure light water reactor where the outflow low temperature of the nuclear reactor, ≤ 400 ºC, results in a simple nuclear reactor. The design I propose will originate a 50% decrease in the cost of the electricity produced using nuclear energy. Keywords: Electricity production, Supercritical water reactor, Nuclear energy, Coal fired plant, Multi-tube reactor, SCWR. 1. Introduction. Every candidate to the Miss Universe Contest whishes to contribute for the end of war and starvation all over the World, above all, when child are the victims. -
Implications for the Solar Protoplanetary Disk from Short-Lived Radionuclides
From Dust to Planetesimals: Implications for the Solar Protoplanetary Disk from Short-lived Radionuclides M. Wadhwa The Field Museum Y. Amelin Geological Survey of Canada A. M. Davis The University of Chicago G. W. Lugmair University of California at San Diego B. Meyer Clemson University M. Gounelle Muséum National d’Histoire Naturelle S. J. Desch Arizona State University ________________________________________________________________ Since the publication of the Protostars and Planets IV volume in 2000, there have been signifi- cant advances in our understanding of the potential sources and distributions of short-lived, now ex- tinct, radionuclides in the early Solar System. Based on recent data, there is definitive evidence for the presence of two new short-lived radionuclides (10Be and 36Cl) and a compelling case can be made for revising the estimates of the initial Solar System abundances of several others (e.g., 26Al, 60Fe and 182Hf). The presence of 10Be, which is produced only by spallation reactions, is either the result of irradiation within the solar nebula (a process that possibly also resulted in the production of some of the other short-lived radionuclides) or of trapping of Galactic Cosmic Rays in the protosolar mo- lecular cloud. On the other hand, the latest estimates for the initial Solar System abundance of 60Fe, which is produced only by stellar nucleosynthesis, indicate that this short-lived radionuclide (and possibly significant proportions of others with mean lives ≤10 My) was injected into the solar nebula from a nearby stellar source. As such, at least two distinct sources (e.g., irradiation and stellar nu- cleosynthesis) are required to account for the abundances of the short-lived radionuclides estimated to be present in the early Solar System. -
Table 2.Iii.1. Fissionable Isotopes1
FISSIONABLE ISOTOPES Charles P. Blair Last revised: 2012 “While several isotopes are theoretically fissionable, RANNSAD defines fissionable isotopes as either uranium-233 or 235; plutonium 238, 239, 240, 241, or 242, or Americium-241. See, Ackerman, Asal, Bale, Blair and Rethemeyer, Anatomizing Radiological and Nuclear Non-State Adversaries: Identifying the Adversary, p. 99-101, footnote #10, TABLE 2.III.1. FISSIONABLE ISOTOPES1 Isotope Availability Possible Fission Bare Critical Weapon-types mass2 Uranium-233 MEDIUM: DOE reportedly stores Gun-type or implosion-type 15 kg more than one metric ton of U- 233.3 Uranium-235 HIGH: As of 2007, 1700 metric Gun-type or implosion-type 50 kg tons of HEU existed globally, in both civilian and military stocks.4 Plutonium- HIGH: A separated global stock of Implosion 10 kg 238 plutonium, both civilian and military, of over 500 tons.5 Implosion 10 kg Plutonium- Produced in military and civilian 239 reactor fuels. Typically, reactor Plutonium- grade plutonium (RGP) consists Implosion 40 kg 240 of roughly 60 percent plutonium- Plutonium- 239, 25 percent plutonium-240, Implosion 10-13 kg nine percent plutonium-241, five 241 percent plutonium-242 and one Plutonium- percent plutonium-2386 (these Implosion 89 -100 kg 242 percentages are influenced by how long the fuel is irradiated in the reactor).7 1 This table is drawn, in part, from Charles P. Blair, “Jihadists and Nuclear Weapons,” in Gary A. Ackerman and Jeremy Tamsett, ed., Jihadists and Weapons of Mass Destruction: A Growing Threat (New York: Taylor and Francis, 2009), pp. 196-197. See also, David Albright N 2 “Bare critical mass” refers to the absence of an initiator or a reflector. -
An Introduction to Isotopic Calculations John M
An Introduction to Isotopic Calculations John M. Hayes ([email protected]) Woods Hole Oceanographic Institution, Woods Hole, MA 02543, USA, 30 September 2004 Abstract. These notes provide an introduction to: termed isotope effects. As a result of such effects, the • Methods for the expression of isotopic abundances, natural abundances of the stable isotopes of practically • Isotopic mass balances, and all elements involved in low-temperature geochemical • Isotope effects and their consequences in open and (< 200°C) and biological processes are not precisely con- closed systems. stant. Taking carbon as an example, the range of interest is roughly 0.00998 ≤ 13F ≤ 0.01121. Within that range, Notation. Absolute abundances of isotopes are com- differences as small as 0.00001 can provide information monly reported in terms of atom percent. For example, about the source of the carbon and about processes in 13 13 12 13 atom percent C = [ C/( C + C)]100 (1) which the carbon has participated. A closely related term is the fractional abundance The delta notation. Because the interesting isotopic 13 13 fractional abundance of C ≡ F differences between natural samples usually occur at and 13F = 13C/(12C + 13C) (2) beyond the third significant figure of the isotope ratio, it has become conventional to express isotopic abundances These variables deserve attention because they provide using a differential notation. To provide a concrete the only basis for perfectly accurate mass balances. example, it is far easier to say – and to remember – that Isotope ratios are also measures of the absolute abun- the isotope ratios of samples A and B differ by one part dance of isotopes; they are usually arranged so that the per thousand than to say that sample A has 0.3663 %15N more abundant isotope appears in the denominator and sample B has 0.3659 %15N. -
Dr. A.A. El-Mohty Dr. Shoukar T.M. Atwa
Benha University Faculty of Science Chemistry Department RADIOCHEMICAL STUDIES ON THE SEPARATION OF IODINE- 131 AND RADIOIODINATION OF SOME ORGANIC COMPOUNDS A Thesis Submitted by MAHMOUD ABBAS ISMAIL MOHAMED Isotopes and Radioactive Generators Dep., Hot Labs. Center Atomic Energy Authority To Faculty of Science – Benha University Presented as partial fulfillment of The Degree of M.Sc In chemistry Supervised by Prof .Dr .H .A. Dessouki Prof . Dr .S .A .El -Bayoumy Prof. of Inorganic and Prof. of Radiochemistry Analytical Chemistry Isot. and Radio Generators.Dept, Faculty of Science Benha Univ. Atomic Energy Authority Dr. Shoukar T.M. Atwa Dr. A.A. El-Mohty Lect. of Physical Chemistry Pro Ass it. Prof.of Radiochemistry Faculty of Science Benha Univ. Isot. and Radio Generators.Dept, Atomic Energy Authority 2010 آ ام اء درات آ إ اد- ١٣١و اآت ا د ا ر ــــد س ا ا واات ا – آ ا ارة ه ا ار ا آــ اــــ ــم – ــ ل در ا اء اـــــــــاف أ.د/ ا ا أ.د/ د اذ اء ا و ا أذ اــء اـــ آ ام - ـــ ا واات ا هــــ اـــ ارــــــــ د/ ر أ.م.د / أ ا رس اء ا أذ اــء اـــ آ ام - ـــ ا واات ا هــــ اـــ ارــــــــ ٢٠١٠ List of abbreviations Abbr. Referent CAT Chloramine-T H2O2 Hydrogen peroxide HPLC High performance liquid chromatography TLC Thin layer chromatography Temp. Temperature Conc. Concentration min Minute NCA No Carrier Added Rf Relative front Rt Retention time CNS Central nervous system Y-indole 4-[2-hydroxy-3- (isopentylamino)propoxy] indole Epidepride N-[(1-ethyl-2- pyrrolidyl)methyl]-2,3- dimethoxy-5-(tributylstannyl) benzamide -
Suppression Mechanisms of Alkali Metal Compounds
SUPPRESSION MECHANISMS OF ALKALI METAL COMPOUNDS Bradley A. Williams and James W. Fleming Chemistry Division, Code 61x5 US Naval Research Lnhoratory Washington, DC 20375-5342, USA INTRODUCTION Alkali metal compounds, particularly those of sodium and potassium, are widely used as fire suppressants. Of particular note is that small NuHCOi particles have been found to be 2-4 times more effective by mass than Halon 1301 in extinguishing both eountertlow flames [ I] and cup- burner flames [?]. Furthermore, studies in our laboratory have found that potassium bicarbonate is some 2.5 times more efficient by weight at suppression than sodium bicarhonatc. The primary limitation associated with the use of alkali metal compounds is dispersal. since all known compounds have very low volatility and must he delivered to the fire either as powders or in (usually aqueous) solution. Although powders based on alkali metals have been used for many years, their mode of effective- ness has not generally been agreed upon. Thermal effects [3],namely, the vaporization of the particles as well as radiative energy transfer out of the flame. and both homogeneous (gas phase) and heterogeneous (surface) chemistry have been postulated as mechanisms by which alkali metals suppress fires [4]. Complicating these issues is the fact that for powders, particle size and morphology have been found to affect the suppression properties significantly [I]. In addition to sodium and potassium, other alkali metals have been studied, albeit to a consider- ably lesser extent. The general finding is that the suppression effectiveness increases with atomic weight: potassium is more effective than sodium, which is in turn more effective than lithium [4]. -
NUREG-1350, Vol. 31, Information
NRC Figure 31. Moisture Density Guage Bioshield Gauge Surface Detectors Depth Radiation Source GLOSSARY 159 GLOSSARY Glossary (Abbreviations, Definitions, and Illustrations) Advanced reactors Reactors that differ from today’s reactors primarily by their use of inert gases, molten salt mixtures, or liquid metals to cool the reactor core. Advanced reactors can also consider fuel materials and designs that differ radically from today’s enriched-uranium dioxide pellets within zirconium cladding. Agreement State A U.S. State that has signed an agreement with the U.S. Nuclear Regulatory Commission (NRC) authorizing the State to regulate certain uses of radioactive materials within the State. Atomic energy The energy that is released through a nuclear reaction or radioactive decay process. One kind of nuclear reaction is fission, which occurs in a nuclear reactor and releases energy, usually in the form of heat and radiation. In a nuclear power plant, this heat is used to boil water to produce steam that can be used to drive large turbines. The turbines drive generators to produce electrical power. NUCLEUS FRAGMENT Nuclear Reaction NUCLEUS NEW NEUTRON NEUTRON Background radiation The natural radiation that is always present in the environment. It includes cosmic radiation that comes from the sun and stars, terrestrial radiation that comes from the Earth, and internal radiation that exists in all living things and enters organisms by ingestion or inhalation. The typical average individual exposure in the United States from natural background sources is about 310 millirem (3.1 millisievert) per year. 160 8 GLOSSARY 8 Boiling-water reactor (BWR) A nuclear reactor in which water is boiled using heat released from fission. -
EXTRACTION of BERYLLIUM-10 from SOIL by FUSION Summary
EXTRACTION OF BERYLLIUM-10 FROM SOIL BY FUSION Summary This method is used to separate Be from soil and sediment samples, for AMS analysis. After adding Be carrier, the sample is fused with KHF2. Be is extracted from the fusion cake with hot water. K is removed by precipitation, the sample is dried to expel fluoride, and Be is recovered as Be(OH)2. Yields are typically 70-80 %, but can be increased by additional leaching of the fusion cake. Version Written by John Stone, 1996-2002. This version revised May 2004 by Greg Balco. Available at: http://depts.washington.edu/cosmolab/chem.html References If you use this method, please cite: Stone, J.O.H. (1998). A rapid fusion method for the extraction of Be-10 from soils and silicates. Geochimica et Cosmochimica Acta (Scientific comment) 62, 555-561. Sampling and grinding Mix and grind an unbiased ∼ 50-100 g sample of the material. If possible, mix the original sample bag before opening and take representative proportions of coarse and fine material. Fine soil, carbonate nodules, clay lumps, rock fragments, etc., all have different 10Be concentrations. Grinding homogenises the sample and ensures that these components are evenly represented in the small subsample used for the analysis. If the sample is wet, you will need to dry it before grinding. Initial sample drying Samples are best run in batches of four. This is because we currently have four Pt crucibles. Given more crucibles and sufficient hotplate space, batches of 8 or even 12 are equally feasible. ————————————————— UW Cosmogenic Nuclide Lab – 10Be fusion process 1 – Label and tare four disposable aluminum foil drying dishes and transfer a few grams of ground sediment to each with a steel spatula. -
Isotopegeochemistry Chapter4
Isotope Geochemistry W. M. White Chapter 4 GEOCHRONOLOGY III: OTHER DATING METHODS 4.1 COSMOGENIC NUCLIDES 4.1.1 Cosmic Rays in the Atmosphere As the name implies, cosmogenic nuclides are produced by cosmic rays colliding with atoms in the atmosphere and the surface of the solid Earth. Nuclides so created may be stable or radioactive. Radio- active cosmogenic nuclides, like the U decay series nuclides, have half-lives sufficiently short that they would not exist in the Earth if they were not continually produced. Assuming that the production rate is constant through time, then the abundance of a cosmogenic nuclide in a reservoir isolated from cos- mic ray production is simply given by: −λt N = N0e 4.1 Hence if we know N0 and measure N, we can calculate t. Table 4.1 lists the radioactive cosmogenic nu- clides of principal interest. As we shall, cosmic ray interactions can also produce rare stable nuclides, and their abundance can also be used to measure geologic time. A number of different nuclear reactions create cosmogenic nuclides. “Cosmic rays” are high-energy (several GeV up to 1019 eV!) atomic nuclei, mainly of H and He (because these constitute most of the matter in the universe), but nuclei of all the elements have been recognized. To put these kinds of ener- gies in perspective, the previous gen- eration of accelerators for physics ex- Table 4.1. Data on Cosmogenic Nuclides periments, such as the Cornell Elec- -1 tron Storage Ring produce energies in Nuclide Half-life, years Decay constant, yr the 10’s of GeV (1010 eV); while 14C 5730 1.209x 10-4 CERN’s Large Hadron Collider, 3H 12.33 5.62 x 10-2 mankind’s most powerful accelerator, 10Be 1.500 × 106 4.62 x 10-7 located on the Franco-Swiss border 26Al 7.16 × 105 9.68x 10-5 near Geneva produces energies of 36Cl 3.08 × 105 2.25x 10-6 ~10 TeV range (1013 eV). -
Review of Outpatient Brachytherapy Medicare Payments to Carolinas Medical Center
DEPARTMENT OF HEALTH & HUMAN SERVICES OFFICE OF INSPECTOR GENERAL Office of Audit Services, Region IV 61 Forsyth Street, SW, Suite 3T41 Atlanta, GA 30303 February 6, 2012 Report Number: A-04-11-06135 Ms. Suzanne Freeman Divisional President Carolinas Medical Center P.O. Box 32861 Charlotte, NC 28232-2861 Dear Ms. Freeman: Enclosed is the U.S. Department of Health and Human Services (HHS), Office of Inspector General (OIG), final report entitled Review of Outpatient Brachytherapy Medicare Payments to Carolinas Medical Center. We will forward a copy of this report to the HHS action official noted on the following page for review and any action deemed necessary. The HHS action official will make final determination as to actions taken on all matters reported. We request that you respond to this official within 30 days from the date of this letter. Your response should present any comments or additional information that you believe may have a bearing on the final determination. Section 8L of the Inspector General Act, 5 U.S.C. App., requires that OIG post its publicly available reports on the OIG Web site. Accordingly, this report will be posted at http://oig.hhs.gov. If you have any questions or comments about this report, please do not hesitate to call me, or contact Andrew Funtal, Audit Manager, at (404) 562-7762 or through email at [email protected]. Please refer to report number A-04-11-06135 in all correspondence. Sincerely, /Lori S. Pilcher/ Regional Inspector General for Audit Services Enclosure Page 2 – Ms. Suzanne Freeman Direct Reply to HHS Action Official: Nanette Foster Reilly Consortium Administrator Consortium for Financial Management & Fee for Service Operations Centers for Medicare & Medicaid Services 601 East 12th Street, Room 235 Kansas City, Missouri 64106 Department of Health and Human Services OFFICE OF INSPECTOR GENERAL REVIEW OF OUTPATIENT BRACHYTHERAPY MEDICARE PAYMENTS TO CAROLINAS MEDICAL CENTER Daniel R. -
Radiation Quick Reference Guide Recommend Contacting Your State Fusion Center
Domestic Nuclear Detection Office If you encounter something suspicious follow your specific local protocols. Radiation Quick Reference Guide Recommend contacting your state fusion center. DNDO is available 24/7 to assist at 1-877-DNDO-JAC / 1-877-363-6522 JAC Information Line 202-254-7179 Email: [email protected] Nuclear Concerns/ Threats 1. Nuclear Weapon - a device that releases nuclear energy in an ex- Isotopes of Concern for use in RDDs - with common uses plosive manner. Uses Highly Enriched Uranium (HEU) and/or 1. Cobalt-60 – cancer treatment, level/ Plutonium. density gauge, teletherapy, radiography, 2. Improvised Nuclear Device (IND) - a nuclear weapon fabricated food sterilization/irradiation, by a terrorist organization or rogue nation. brachytherapy 2. Iridium-192 – Radiography/non- destructive testing, flaw detection, brachy- therapy “cancer seed”, skin cancer Cobalt 60 sources Uranium “superficial” brachytherapy Plutonium 3. Uranium a. Uranium exists naturally in the earth’s crust. Of the different “isotopes” of uranium, U-235 is the one required to produce a Iridium sentinel and nuclear weapon. gamma camera b. Natural uranium contains a small amount of U-235 (<1%) which Cesium Seeds must be separated in complex extraction processes to create HEU. The predominant uranium isotope is U-238. 3. Cesium-137 - Gauge/level gauge, industrial radiography, brachyther- c. Highly Enriched Uranium (HEU) refers to uranium usable in weap- apy/teletherapy, well logging/density gauges ons due to its enrichment in U-235. 4. Strontium-90 – Radioisotope thermoelectric generator (RTG), fis- d. Approximately 25 kg of HEU is required for a nuclear weapon. sion product, industrial gauges, medical treatment e. -
Chemical Behavior of Iodine-131 During the SRE Fuel Element
Chemical Behavior of Iodine- 13 1 during SRE Fuel Element Damage in July 1959 Response to Plaintiffs Expert Witness Arjun Makhijani by Jerry D. Christian, Ph.D. Prepared for in re Boeing Litigation May 26,2005 Background of Jerry D. Christian Education: B. S. Chemistry, University of Oregon, 1959. Ph. D. Physical Chemistry, University of Washington, 1965 - Specialty in Chemical Thermodynamics and Vaporization Processes of Halogen Salts. (Iodine is a halogen.) Postdoctoral: National Research Council Senior Research Associate, NASA Ames Research Center, Moffett Field, CAY1972-1974. Career Summary: Scientific Fellow, Retired from Idaho National Engineering and Environmental Laboratory (INEEL), September 2001. Scientific Fellow is highest achievable technical ladder position at INEEL; charter member, appointed in January 1987. Consultant and President of Electrode Specialties Company since retirement. Affiliate Professor of Chemistry, University of Idaho; I teach a course in nuclear fuel reprocessing. Referee for Nuclear Technology and Talanta journals; I review submitted technical manuscripts for the editors for scientific and technical validity and accuracy.* I have thirty nine years experience in nuclear waste and fuel processing research and development. Included in my achievements is development of the highly successful classified Fluorine1 Dissolution Process for advanced naval fuels that was implemented in a new $250 million facility at the ICPP in the mid-1980s. Career interests and accomplishments have been in the areas of nuclear