Towards an Improved Test of the Standard Model's Most Precise Prediction
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Magnetism, Magnetic Properties, Magnetochemistry
Magnetism, Magnetic Properties, Magnetochemistry 1 Magnetism All matter is electronic Positive/negative charges - bound by Coulombic forces Result of electric field E between charges, electric dipole Electric and magnetic fields = the electromagnetic interaction (Oersted, Maxwell) Electric field = electric +/ charges, electric dipole Magnetic field ??No source?? No magnetic charges, N-S No magnetic monopole Magnetic field = motion of electric charges (electric current, atomic motions) Magnetic dipole – magnetic moment = i A [A m2] 2 Electromagnetic Fields 3 Magnetism Magnetic field = motion of electric charges • Macro - electric current • Micro - spin + orbital momentum Ampère 1822 Poisson model Magnetic dipole – magnetic (dipole) moment [A m2] i A 4 Ampere model Magnetism Microscopic explanation of source of magnetism = Fundamental quantum magnets Unpaired electrons = spins (Bohr 1913) Atomic building blocks (protons, neutrons and electrons = fermions) possess an intrinsic magnetic moment Relativistic quantum theory (P. Dirac 1928) SPIN (quantum property ~ rotation of charged particles) Spin (½ for all fermions) gives rise to a magnetic moment 5 Atomic Motions of Electric Charges The origins for the magnetic moment of a free atom Motions of Electric Charges: 1) The spins of the electrons S. Unpaired spins give a paramagnetic contribution. Paired spins give a diamagnetic contribution. 2) The orbital angular momentum L of the electrons about the nucleus, degenerate orbitals, paramagnetic contribution. The change in the orbital moment -
Magnetism, Angular Momentum, and Spin
Chapter 19 Magnetism, Angular Momentum, and Spin P. J. Grandinetti Chem. 4300 P. J. Grandinetti Chapter 19: Magnetism, Angular Momentum, and Spin In 1820 Hans Christian Ørsted discovered that electric current produces a magnetic field that deflects compass needle from magnetic north, establishing first direct connection between fields of electricity and magnetism. P. J. Grandinetti Chapter 19: Magnetism, Angular Momentum, and Spin Biot-Savart Law Jean-Baptiste Biot and Félix Savart worked out that magnetic field, B⃗, produced at distance r away from section of wire of length dl carrying steady current I is 휇 I d⃗l × ⃗r dB⃗ = 0 Biot-Savart law 4휋 r3 Direction of magnetic field vector is given by “right-hand” rule: if you point thumb of your right hand along direction of current then your fingers will curl in direction of magnetic field. current P. J. Grandinetti Chapter 19: Magnetism, Angular Momentum, and Spin Microscopic Origins of Magnetism Shortly after Biot and Savart, Ampére suggested that magnetism in matter arises from a multitude of ring currents circulating at atomic and molecular scale. André-Marie Ampére 1775 - 1836 P. J. Grandinetti Chapter 19: Magnetism, Angular Momentum, and Spin Magnetic dipole moment from current loop Current flowing in flat loop of wire with area A will generate magnetic field magnetic which, at distance much larger than radius, r, appears identical to field dipole produced by point magnetic dipole with strength of radius 휇 = | ⃗휇| = I ⋅ A current Example What is magnetic dipole moment induced by e* in circular orbit of radius r with linear velocity v? * 휋 Solution: For e with linear velocity of v the time for one orbit is torbit = 2 r_v. -
Lecture #4, Matter/Energy Interactions, Emissions Spectra, Quantum Numbers
Welcome to 3.091 Lecture 4 September 16, 2009 Matter/Energy Interactions: Atomic Spectra 3.091 Periodic Table Quiz 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 Name Grade /10 Image by MIT OpenCourseWare. Rutherford-Geiger-Marsden experiment Image by MIT OpenCourseWare. Bohr Postulates for the Hydrogen Atom 1. Rutherford atom is correct 2. Classical EM theory not applicable to orbiting e- 3. Newtonian mechanics applicable to orbiting e- 4. Eelectron = Ekinetic + Epotential 5. e- energy quantized through its angular momentum: L = mvr = nh/2π, n = 1, 2, 3,… 6. Planck-Einstein relation applies to e- transitions: ΔE = Ef - Ei = hν = hc/λ c = νλ _ _ 24 1 18 Bohr magneton µΒ = eh/2me 9.274 015 4(31) X 10 J T 0.34 _ _ 27 1 19 Nuclear magneton µΝ = eh/2mp 5.050 786 6(17) X 10 J T 0.34 _ 2 3 20 Fine structure constant α = µ0ce /2h 7.297 353 08(33) X 10 0.045 21 Inverse fine structure constant 1/α 137.035 989 5(61) 0.045 _ 2 1 22 Rydberg constant R¥ = mecα /2h 10 973 731.534(13) m 0.0012 23 Rydberg constant in eV R¥ hc/{e} 13.605 698 1(40) eV 0.30 _ 10 24 Bohr radius a0 = a/4πR¥ 0.529 177 249(24) X 10 m 0.045 _ _ 4 2 1 25 Quantum of circulation h/2me 3.636 948 07(33) X 10 m s 0.089 _ 11 1 26 Electron specific charge -e/me -1.758 819 62(53) X 10 C kg 0.30 _ 12 27 Electron Compton wavelength λC = h/mec 2.426 310 58(22) X 10 m 0.089 _ 2 15 28 Electron classical radius re = α a0 2.817 940 92(38) X 10 m 0.13 _ _ 26 1 29 Electron magnetic moment` µe 928.477 01(31) X 10 J T 0.34 _ _ 3 30 Electron mag. -
New Measurements of the Electron Magnetic Moment and the Fine Structure Constant
S´eminaire Poincar´eXI (2007) 109 – 146 S´eminaire Poincar´e Probing a Single Isolated Electron: New Measurements of the Electron Magnetic Moment and the Fine Structure Constant Gerald Gabrielse Leverett Professor of Physics Harvard University Cambridge, MA 02138 1 Introduction For these measurements one electron is suspended for months at a time within a cylindrical Penning trap [1], a device that was invented long ago just for this purpose. The cylindrical Penning trap provides an electrostatic quadrupole potential for trapping and detecting a single electron [2]. At the same time, it provides a right, circular microwave cavity that controls the radiation field and density of states for the electron’s cyclotron motion [3]. Quantum jumps between Fock states of the one-electron cyclotron oscillator reveal the quantum limit of a cyclotron [4]. With a surrounding cavity inhibiting synchrotron radiation 140-fold, the jumps show as long as a 13 s Fock state lifetime, and a cyclotron in thermal equilibrium with 1.6 to 4.2 K blackbody photons. These disappear by 80 mK, a temperature 50 times lower than previously achieved with an isolated elementary particle. The cyclotron stays in its ground state until a resonant photon is injected. A quantum cyclotron offers a new route to measuring the electron magnetic moment and the fine structure constant. The use of electronic feedback is a key element in working with the one-electron quantum cyclotron. A one-electron oscillator is cooled from 5.2 K to 850 mK us- ing electronic feedback [5]. Novel quantum jump thermometry reveals a Boltzmann distribution of oscillator energies and directly measures the corresponding temper- ature. -
The G Factor of Proton
The g factor of proton Savely G. Karshenboim a,b and Vladimir G. Ivanov c,a aD. I. Mendeleev Institute for Metrology (VNIIM), St. Petersburg 198005, Russia bMax-Planck-Institut f¨ur Quantenoptik, 85748 Garching, Germany cPulkovo Observatory, 196140, St. Petersburg, Russia Abstract We consider higher order corrections to the g factor of a bound proton in hydrogen atom and their consequences for a magnetic moment of free and bound proton and deuteron as well as some other objects. Key words: Nuclear magnetic moments, Quantum electrodynamics, g factor, Two-body atoms PACS: 12.20.Ds, 14.20.Dh, 31.30.Jv, 32.10.Dk Investigation of electromagnetic properties of particles and nuclei provides important information on fundamental constants. In addition, one can also learn about interactions of bound particles within atoms and interactions of atomic (molecular) composites with the media where the atom (molecule) is located. Since the magnetic interaction is weak, it can be used as a probe to arXiv:hep-ph/0306015v1 2 Jun 2003 learn about atomic and molecular composites without destroying the atom or molecule. In particular, an important quantity to study is a magnetic moment for either a bare nucleus or a nucleus surrounded by electrons. The Hamiltonian for the interaction of a magnetic moment µ with a homoge- neous magnetic field B has a well known form Hmagn = −µ · B , (1) which corresponds to a spin precession frequency µ hν = B , (2) spin I Email address: [email protected] (Savely G. Karshenboim). Preprint submitted to Elsevier Science 1 February 2008 where I is the related spin equal to either 1/2 or 1 for particles and nuclei under consideration in this paper. -
1. Physical Constants 1 1
1. Physical constants 1 1. PHYSICAL CONSTANTS Table 1.1. Reviewed 1998 by B.N. Taylor (NIST). Based mainly on the “1986 Adjustment of the Fundamental Physical Constants” by E.R. Cohen and B.N. Taylor, Rev. Mod. Phys. 59, 1121 (1987). The last group of constants (beginning with the Fermi coupling constant) comes from the Particle Data Group. The figures in parentheses after the values give the 1-standard- deviation uncertainties in the last digits; the corresponding uncertainties in parts per million (ppm) are given in the last column. This set of constants (aside from the last group) is recommended for international use by CODATA (the Committee on Data for Science and Technology). Since the 1986 adjustment, new experiments have yielded improved values for a number of constants, including the Rydberg constant R∞, the Planck constant h, the fine- structure constant α, and the molar gas constant R,and hence also for constants directly derived from these, such as the Boltzmann constant k and Stefan-Boltzmann constant σ. The new results and their impact on the 1986 recommended values are discussed extensively in “Recommended Values of the Fundamental Physical Constants: A Status Report,” B.N. Taylor and E.R. Cohen, J. Res. Natl. Inst. Stand. Technol. 95, 497 (1990); see also E.R. Cohen and B.N. Taylor, “The Fundamental Physical Constants,” Phys. Today, August 1997 Part 2, BG7. In general, the new results give uncertainties for the affected constants that are 5 to 7 times smaller than the 1986 uncertainties, but the changes in the values themselves are smaller than twice the 1986 uncertainties. -
Magnetism in Transition Metal Complexes
Magnetism for Chemists I. Introduction to Magnetism II. Survey of Magnetic Behavior III. Van Vleck’s Equation III. Applications A. Complexed ions and SOC B. Inter-Atomic Magnetic “Exchange” Interactions © 2012, K.S. Suslick Magnetism Intro 1. Magnetic properties depend on # of unpaired e- and how they interact with one another. 2. Magnetic susceptibility measures ease of alignment of electron spins in an external magnetic field . 3. Magnetic response of e- to an external magnetic field ~ 1000 times that of even the most magnetic nuclei. 4. Best definition of a magnet: a solid in which more electrons point in one direction than in any other direction © 2012, K.S. Suslick 1 Uses of Magnetic Susceptibility 1. Determine # of unpaired e- 2. Magnitude of Spin-Orbit Coupling. 3. Thermal populations of low lying excited states (e.g., spin-crossover complexes). 4. Intra- and Inter- Molecular magnetic exchange interactions. © 2012, K.S. Suslick Response to a Magnetic Field • For a given Hexternal, the magnetic field in the material is B B = Magnetic Induction (tesla) inside the material current I • Magnetic susceptibility, (dimensionless) B > 0 measures the vacuum = 0 material response < 0 relative to a vacuum. H © 2012, K.S. Suslick 2 Magnetic field definitions B – magnetic induction Two quantities H – magnetic intensity describing a magnetic field (Système Internationale, SI) In vacuum: B = µ0H -7 -2 µ0 = 4π · 10 N A - the permeability of free space (the permeability constant) B = H (cgs: centimeter, gram, second) © 2012, K.S. Suslick Magnetism: Definitions The magnetic field inside a substance differs from the free- space value of the applied field: → → → H = H0 + ∆H inside sample applied field shielding/deshielding due to induced internal field Usually, this equation is rewritten as (physicists use B for H): → → → B = H0 + 4 π M magnetic induction magnetization (mag. -
Class 35: Magnetic Moments and Intrinsic Spin
Class 35: Magnetic moments and intrinsic spin A small current loop produces a dipole magnetic field. The dipole moment, m, of the current loop is a vector with direction perpendicular to the plane of the loop and magnitude equal to the product of the area of the loop, A, and the current, I, i.e. m = AI . A magnetic dipole placed in a magnetic field, B, τ experiences a torque =m × B , which tends to align an initially stationary N dipole with the field, as shown in the figure on the right, where the dipole is represented as a bar magnetic with North and South poles. The work done by the torque in turning through a small angle dθ (> 0) is θ dW==−τθ dmBsin θθ d = mB d ( cos θ ) . (35.1) S Because the work done is equal to the change in kinetic energy, by applying conservation of mechanical energy, we see that the potential energy of a dipole in a magnetic field is V =−mBcosθ =−⋅ mB , (35.2) where the zero point is taken to be when the direction of the dipole is orthogonal to the magnetic field. The minimum potential occurs when the dipole is aligned with the magnetic field. An electron of mass me moving in a circle of radius r with speed v is equivalent to current loop where the current is the electron charge divided by the period of the motion. The magnetic moment has magnitude π r2 e1 1 e m = =rve = L , (35.3) 2π r v 2 2 m e where L is the magnitude of the angular momentum. -
Deuterium by Julia K
Progress Towards High Precision Measurements on Ultracold Metastable Hydrogen and Trapping Deuterium by Julia K. Steinberger Submitted to the Department of Physics in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the MASSACHUSETTS INSTITUTE OF TECHNOLOGY August 2004 - © Massachusetts Institute of Technology 2004. All rights reserved. Author .............. Department of Physics Augulst 26. 2004 Certifiedby......... .. .. .. .. .I- . .... Thom4. Greytak Prof or of Physics !-x. Thesis SuDervisor Certified by........................ Danil/Kleppner Lester Wolfe Professor of Physics Thesis Supervisor Accepted by... ...................... " . "- - .w . A. ....... MASSACHUSETTS INSTITUTE /Thom . Greytak OF TECHNOLOGY Chairman, Associate Department Head Vr Education SEP 14 2004 ARCHIVES LIBRARIES . *~~~~ Progress Towards High Precision Measurements on Ultracold Metastable Hydrogen and Trapping Deuterium by Julia K. Steinberger Submitted to the Department of Physics on August 26, 2004, in partial fulfillment of the requirements for the degree of Doctor of Philosophy Abstract Ultracold metastable trapped hydrogen can be used for precision measurements for comparison with QED calculations. In particular, Karshenboim and Ivanov [Eur. Phys. Jour. D 19, 13 (2002)] have proposed comparing the ground and first excited state hyperfine splittings of hydrogen as a high precision test of QED. An experiment to measure the 2S hyperfine splitting using a field-independent transition frequency in the 2S manifold of hydrogen is described. The relation between the transition frequency and the hyperfine splitting requires incorporating relativistic and bound state QED corrections to the electron and proton g-factors in the Breit-Rabi formula. Experimental methods for measuring the magnetic field of an ultracold hydrogen sample are developed for trap fields from 0 to 900 G. -
Antihydrogen and the Antiproton Magnetic Moment
Gabrielse ATRAP: Context and Status Antihydrogen and the Antiproton Magnetic Moment Gerald Gabrielse Spokesperson for TRAP and ATRAP at CERN Levere tt Pro fesso r o f Phys ics, Har var d Uni ver sit y Gabrielse Context CERN Pursues Fundamental Particle Physics at WWeveegySceseesghatever Energy Scale is Interesting A Long and Noble CERN Tradition 1981 – traveled to Fermilab “TEV or bust” 1985 – different response at CERN wh en I went th ere to try to get access to LEAR antiprotons for qqyg/m measurements and cold antihydrogen It is exciting that there is now • a dedicated storaggge ring for antih ygpydrogen experiments • four international collaborations • too few antiprotons for the demand Gabrielse Pursuing Fundamental Particle Physics atWhtt Whatever Energy Sca le is In teres ting A Long and Noble CERN Tradition 1986 – First trapped antiprotons (TRAP) 1989 – First electron-cooling of trapped antiprotons (TRAP) 1 cm magnetic field 21 MeV antiprotons slow in matter degrader _ + _ CERN’s AD, plus these cold methods make antihydrogen possible Gabrielse Pursuing Fundamental Particle Physics atWhtt Whatever Energy Sca le is In teres ting A Long and Noble CERN Tradition 1981 – traveled to Fermilab “TEV or bust” 1985 – different response at CERN when I went there to try to get access to LEAR antiprotons for q/m measurements and cold antihydrogen LHC: 7 TeV + 7 TeV AD: 5 MeV 100 times 5 x 1016 More trapped ELENA upgrade: 0.1 MeV antiprotons ATRAP: 0.3 milli-eV Gabrielse Physics With Low Energy Antiprotons First Physics: Compare q/m for antiproton -
Trapped Antihydrogen in Its Ground State
Trapped Antihydrogen in Its Ground State The Harvard community has made this article openly available. Please share how this access benefits you. Your story matters Citation Richerme, Philip. 2012. Trapped Antihydrogen in Its Ground State. Doctoral dissertation, Harvard University. Citable link http://nrs.harvard.edu/urn-3:HUL.InstRepos:10058466 Terms of Use This article was downloaded from Harvard University’s DASH repository, and is made available under the terms and conditions applicable to Other Posted Material, as set forth at http:// nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of- use#LAA ©2012 - Philip John Richerme All rights reserved. Thesis advisor Author Gerald Gabrielse Philip John Richerme Trapped Antihydrogen in Its Ground State Abstract Antihydrogen atoms (H) are confined in a magnetic quadrupole trap for 15 to 1000 s - long enough to ensure that they reach their ground state. This milestone brings us closer to the long-term goal of precise spectroscopic comparisons of H and H for tests of CPT and Lorentz invariance. Realizing trapped H requires charac- terization and control of the number, geometry, and temperature of the antiproton (p) and positron (e+) plasmas from which H is formed. An improved apparatus and implementation of plasma measurement and control techniques make available 107 p and 4 × 109 e+ for H experiments - an increase of over an order of magnitude. For the first time, p are observed to be centrifugally separated from the electrons that cool them, indicating a low-temperature, high-density p plasma. Determination of the p temperature is achieved through measurement of the p evaporation rate as their con- fining well is reduced, with corrections given by a particle-in-cell plasma simulation. -
Harvard University Department of Physics Newsletter
Harvard University Department of Physics Newsletter FALL 2014 COVER STORY Probing the Universe’s Earliest Moments FOCUS Early History of the Physics Department FEATURED Quantum Optics Where Physics Meets Biology Condensed Matter Physics NEWS A Reunion Across Generations and Disciplines 42475.indd 1 10/30/14 9:19 AM Detecting this signal is one of the most important goals in cosmology today. A lot of work by a lot of people has led to this point. JOHN KOVAC, HARVARD-SMITHSONIAN CENTER FOR ASTROPHYSICS LEADER OF THE BICEP2 COLLABORATION 42475.indd 2 10/24/14 12:38 PM CONTENTS ON THE COVER: Letter from the former Chair ........................................................................................................ 2 The BICEP2 telescope at Physics Department Highlights 4 twilight, which occurs only ........................................................................................................ twice a year at the South Pole. The MAPO observatory (home of the Keck Array COVER STORY telescope) and the South Pole Probing the Universe’s Earliest Moments ................................................................................. 8 station can be seen in the background. (Steffen Richter, Harvard University) FOCUS ACKNOWLEDGMENTS Early History of the Physics Department ................................................................................ 12 AND CREDITS: Newsletter Committee: FEATURED Professor Melissa Franklin Professor Gerald Holton Quantum Optics ..............................................................................................................................14