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THE AND HISTORY OF THE HOLOCENE OF ,

TILOTTAMA BASA

Thesis submitted for the degree of Ph D at the Department of Geological Sciences, University College London, University of London. March 1992 ProQuest Number: 10609844

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ProQuest LLC. 789 East Eisenhower Parkway P.O. Box 1346 Ann Arbor, Ml 48106- 1346 In memory of my Father ABSTRACT

The drilling of several deep boreholes through the 40 m thick marine Holocene succession of the Dungeness foreland on the site of the proposed Dungeness "C" Nuclear Power Station provides an opportunity to examine the nature and composition of its sediments. Selected unaltered mollusc shells were used to date the succession at -34.3 m, -32.9 m, -32.4 m and -20.5 m OD to supplement the existing 14C determinations on both wood and shells. The 14C dates obtained showed that the sediments at these depths were deposited between 560±95 and 2755±175 cal. yr BP. Study of borehole cores and logs showed that these deposits consist of three distinct divisions: Basal Gravels, Middle and Top Gravels. analyses indicated that the bulk of the Middle Sands succession (99% - 76%) below the Top Gravels comprised fine and , the rest being medium sand, and a sprinkling of fine to medium gravel. The silt fraction has a predominant peak at 5 to 6 § typical of loess. The detrital mineralogy as a whole consists of 90% quartz, the remainder being feldspar, chert, glauconite and heavy minerals, mainly zircon, tourmaline, garnet, rutile with a variable amount of staurolite, kyanite, amphibole and the epidote group of minerals. The garnets are predominantly Fe-rich with variable amounts of Mn, Ca and Mg. The clay minerals include illite, kaolinite and mixed-clay minerals with a little chlorite and smectite, similar to that reported from brickearths in Kent. The surface of the sand grains have characteristic subaqueous, aeolian and subaerial microtextures and in a few grains there is evidence of high energy glacial features. Most of the in the Basal Gravels are subangular to subrounded and consist predominantly of flint from the local rocks, with some , siltstones and limestones. A few exotic pebbles such as granitic angular rock fragments are also present in the Basal Gravels. The sediment constituents are of mixed provenance. The local Cretaceous bedrocks supplied the more resistant heavy minerals and the bulk of the quartz, feldspar, chert and glauconite whereas the less stable heavy minerals along with some quartz and other light minerals were derived from relatively younger Quaternary sources. The surface texture, the size distribution of the , the presence of unstable heavy minerals and the clay mineral types indicate an admixture of aeolian loessic sediments which may have been reworked a number of times before they were finally deposited at Dungeness.

3 The Quaternary sediments of the southern North Sea, which contain a large proportion of semistable to unstable heavy minerals, may have supplied sediment to the offshore area near Dungeness at a time when, as the molluscan fauna suggests, Dungeness was evolving under the influence of heavy storms.

4 TABLE OF CONTENTS PAGE Title page 1 Dedication 2 Abstract 3 Table of Contents 5 List of Tables 8 List of Figures 9 List of Plates 12 Acknowledgements 18

CHAPTER 1: INTRODUCTION 19 Introduction A review of pre-existing information on Dungeness Holocene deposits Pleistocene deposits in southeast Sea level CHAPTER 2: THE SEDIMENTS OF DUNGENESS 38 Introduction Sampling and analytical methods Results of the detailed sedimentological analyses CHAPTER 3: MOLLUSC STUDIES 111 Introduction Mollusc shells found in Dungeness Results and Interpretation CHAPTER 4: RADIOCARBON DATING 120 Introduction Holocene deposits at Dungeness First-Order 14C dating 14C dates in the area Dating of the barrier Implication of the recent dates at Dungeness

5 CHAPTER 5: PROVENANCE 136 Introduction Texture Detrital mineralogy Provenance Summary CHAPTER 6: ENVIRONMENTS OF DEPOSITION 167 Introduction Barrier environments Reconstruction of the depositional environments at Dungeness Evolution of a barrier under the influence of storms at Dungeness Evidence of probable storm activities in the surrounding areas Evolution of Dungeness CHAPTER 7: WIDER IMPLICATIONS 194 Introduction Coastal Holocene sea-level changes Holocene crustal movements and sea-level changes CHAPTER 8: SUMMARY OF FINDINGS 206 AND FUTURE WORK

REFERENCES CITED 209

APPENDICES 231 APPENDIX 1 Borehole logs APPENDIX 2 Grain size frequency distributions APPENDIX 3 Grain-size distributions: cumulative curves APPENDIX 4 SEM surface microfeatures on quartz grains APPENDIX 5 Detrital mineralogy in thin section APPENDIX 6 Heavy mineralogy of Midley Sand and Modern Sand sediments APPENDIX 7 Heavy mineralogy of sea bed sediments near Dungeness APPENDIX 8 Distribution of tourmaline varieties

6 APPENDIX 9 Electron microprobe analysis of detrital garnets APPENDIX 10 Electron microprobe analysis of selected heavy minerals APPENDIX 11 Glauconite analyses APPENDIX 12 Semiquantitative clay determination

7 LIST OF TABLES

2.1 % of sand and silt+clay 2.2 % of silt and clay in < 4 <}> fraction of Dungeness sediments 2.3 Grain-size parameters of Dungeness sediments, Midley Sand and Modern Sand from -on-Sea 2.4 SEM surface microtextures of quartz grains 2.5 Representative electron microprobe analysis of detrital garnets 2.6 Garnet analysis according to 24 Oxygens 2.7 Mole % of different types of garnet 2.8 Representative electron microprobe analysis of glauconite from Dungeness 2.9 XRD analysis of clay

3.1 Shells from Dungeness

4.1 First-Order 14C dates from Dungeness 4.2 14C dates from Dungeness 4.3 Radiocarbon dates from Romney Marsh

5.1 Detrital mineral suites characteristic of source rock types 5.2 Comparison of grain-size parameters of Holocene sediments and of local lower Cretaceous bedrocks 5.3 Comparison of heavy mineralogy of Dungeness sediments and of lower Cretaceous bedrocks 5.4 Comparison of heavy mineralogy of coarse silt fraction of Dungeness sediments and of the Rother Valley fill sediments 5.5 Comparison of glauconite analysis of Dungeness sediments with McRae and Lambert’s (1968) glauconite analysis of Cretaceous and Tertiary sediments of southeast England.

8 LIST OF FIGURES

Fig. 1.1 Location map of Dungeness Fig. 1.2 Evolution of shorelines at Dungeness Fig. 1.3 Surface deposits at and near Dungeness

Fig. 2.1.1.a Borehole and sample location sites Fig. 2.l.l.b Representative lithological logs of Holocene sequence at Dungeness Fig. 2.1.1 Representative grain size frequency curves of Dungeness sediments Fig. 2.1.2 Grain size frequency curves of Midley Sand sediments Fig. 2.1.3 Grain size frequency curves of Modem Sand sediments from Lydd-on-Sea Fig. 2.2.1 Grain size distribution of representative Dungeness samples Fig. 2.2.2 Grain size distribution of Midley Sand samples Fig. 2.2.2 Grain size distribution of Modem Sand samples Fig. 2.3.a Grain size frequency distribution curves of silt and clay fraction of Dungeness sediments Fig. 2.3.b Grain size frequency distribution curves of silt and clay fraction of Dungeness sediments Fig. 2.4 Surface texture of quartz grains observed under SEM Fig. 2.5 Detrital mineralogy of Dungeness sediments in thin sections Fig. 2.6.1.a Heavy mineralogy of fine sand (2-3 ) fraction of Dungeness sediments Fig. 2.6.l.b Heavy mineralogy of fine sand (2-3 ) fractions of Dungeness sediments Fig. 2.6.2.a Heavy mineralogy of very fine sand (3-4 $) fraction of Dungeness sediments Fig. 2.6.2.b Heavy mineralogy of very fine sand (3-4 <)>) fraction of Dungeness sediments Fig. 2.6.3 Heavy mineralogy of coarse silt (<4 ) fraction of Dungeness sediments Fig. 2.6.4 Heavy mineralogy of Midley Sand Fig. 2.6.5 Heavy mineralogy of Modem Sand from Lydd-on-Sea Fig. 2.6.5.a Heavy mineralogy of coarse silt (<4 $) fraction of Modem Sand sediments Fig. 2.7 Distribution of tourmaline varieties Fig. 2.8 Garnet composition of sand from Dungeness Fig. 2.9 Garnet composition of sand from Midley Sand and Modem Sand at Lydd-on-Sea

9 Fig. 2.10 X-ray diffractograms of glauconite from Dungeness sediments Fig. 2.11 X-ray diffractogram of typical clay sample from Dungeness sediment Fig. 2.12 Diffractometer traces of a typical clay sample from Dungeness sediments and component clay minerals

Fig. 4.1 X-ray diffractograms of aragonitic shells from Dungeness Fig. 4.2 First-Order 14C dating rig at UCL

Fig. 5.1 Simplified map of solid of the English Fig. 5.2 Typical relative frequency distribution of valley fill and floodplain sediments of the southern England rivers Fig. 5.3 Deeps and infilled channels of the English Channel Fig. 5.4 Outline map of mean spring near-surface tidal strength on the around the British Isles. Fig. 5.5 Net sand transport direction on the continental shelf around the British Isles Fig. 5.6 Distribution of sediment types off the southern of England Fig. 5.7 Generalised palaeogeography of Dungeness c.3000 yr BP and direction of

Fig. 6.1 Sketch map of coast of south and southeast England showing various shingle barriers Fig. 6.2 Worldwide Holocene eustatic sea-level interpretations Fig. 6.3 Holocene relative sea-level curve and new First-order 14C dates from Dungeness Fig. 6.4 Schematic diagram of a barrier system illustrating the six interactive sedimentary environments Fig. 6.5 Beach face subenvironments, processes and Fig. 6.6 Wave-induced nearshore circulation system of longshore currents and seaward-directed rip currents Fig. 6.7 Models of transgressive and regressive barrier stratigraphic sequence illustrating the concepts of Walther’s Law. Fig. 6.8 Offshore storm deposits from contrasting settings

10 Fig. 6.9 Generalised sequence of modem storm deposits Fig. 6.10 Mechanisms of storm erosion and deposition by storm processes

Fig. 7.1 Holocene relative sea-level curve for the North Sea

11 LIST OF PLATES

Plate 2.1. Photomicrographs of thin sections of sands and gravels from Dungeness. All photographs enlarged X40. a: Moderately well sorted silty sand showing angular and rounded quartz, glauconite, chert and other shell fragments b: Detrital flint gravel c: Limestone from the Basal Gravels d: Granitic rock fragment from the Basal Gravels

Plates 2.2 ■ 2.7 SEM micrographs showing characteristic surface microtextures observed on quartz grains.

Plate 2.2 a: Assemblage of quartz sand grains from Dungeness b: Rounded grain c: Angular grain d: Grain with high relief e: Grain with medium relief f: Grain with low relief and partly smooth surface

Plate 2.3 a: Conchoidal fracture with convex up surface b: Conchoidal fracture with concave up surface c: Dish shaped fracture d: Large conchoidal fracture with arcuate steps e: Conchoidal fracture with radiating steps f: Small conchoidal fracture

Plate 2.4 a: Edge abrasion and cracks b: Large irregular blocky depression

12 c: Isolated large V-shaped blocks d: Large blocks e: Large flat areas f: Parallel straight scratches

Plate 2.5 a: Curved scratches b: Upturned plates c: Mechanical V on projected areas d: Mechanical V on depressed areas e: Irregular pits f: Sickle pits

Plate 2.6 a: Smooth capping layers of silica on grain surface b: Smooth capping of silica on upturned plates c: Irregular solution and precipitation d: Chemical etching e: Chemically oriented V ’s

Plate 2.7 a: Topographically negative areas with medium relief b: Topographically negative areas with low relief c: Edge abrasion in grains with authigenic overgrowth and solution d: Edge abrasion and irregular blocky fracture e: Elongate grain

Plate 2.8 Comparison of SEM surface textures of quartz sand grains from the Hastings Beds and from Dungeness. a: Assemblage of quartz grains from the Hastings Beds b: Single sand grain from the Hastings Beds c: Magnification of the above grain (2.8.b) showing crystalline overgrowth

13 d: Another type of quartz sand grain from the Hastings Beds showing chemical etching e: Magnification of the above grain showing details of the etched surface f: A quartz sand grain from Dungeness with crystalline overgrowth g: Quartz sand grain from Dungeness with crystalline overgrowth and later partially altered by solution h: Magnification of the grain (2.8.f) showing partially altered surface of authigenic overgrowth

Plate 2.9 SEM surface microtextures of quartz silt grains from Dungeness and from the Hastings Beds. a: Angular quartz silt grain from Dungeness with fresh breakage surface b: Blocky quartz silt grain from Dungeness with conchoidal fracture, flat surface and surface particle adhering c: Angular quartz silt grain from Dungeness with upturned plates d: Freshly broken silt with flat surface and platy surface e: Quartz silt grain from the Hastings Beds f: Magnification of the above silt grain (2.9.e) showing authigenic overgrowth

Plate 2.10 SEM micrographs of glauconite grains from Dungeness. a: Elongate rounded glauconite grain with smooth surface b: Scaly structure on surface of the above grain (2.10.a) c: Details of the scaly structure in higher magnification d: Pellet shaped rounded smooth glauconite grain e: Scaly structure on the surface of the above grain f: Magnification of the above grain showing thin plate like structure

Plates 2.11 - 2.12 Photomicrographs of different varieties of heavy minerals seen under microscope. Photograph No. 2.12.e and 2.12.i are enlaged to X350. The rest are enlarged to X175.

Plate 2.11 a: Euhedral colourless zircon in ordinary light

14 b: Euhedral zoned brownish zircon, in ordinary light c: Zircon with authigenic overgrowth, in ordinary light d: Prismatic brown tourmaline in ordinary light e: Prismatic brown tourmaline with abraded metasomatic or sedimentary overgrowth in ordinary light f: Angular, flaky green tourmaline in ordinary light g: Euhedral yellowish green tourmaline, in ordinary light h: Prismatic blue coloured tourmaline in ordinary light i: Angular flaky multicoloured tourmaline, in ordinary light j: Angular colourless to very light pink garnet with fresh conchoidal fracture, in ordinary light k: Etched garnet with intense corrosion in ordinary light j: Subrounded light pink garnet in ordinary light

Plate 2.12 a: Rutile with characteristic twinning, in polarized light b: Well rounded apatite, in polarized light c: Straw yellow colour and saw tooth structure of corroded staurolite, in ordinary light d: Green amphibole, in ordinary light e: Brown amphibole, in ordinary light f: Bluish green amphibole, in ordinary light g: Rounded epidote grain with characteristic greenish colour, in ordinary light h. Rounded epidote group mineral with characteristic interference colour, in polarized light i: Andalusite with characteristic patchy red colour pleochroism under ordinary light

Plates 2.13 -2.16 SEM micrographs of heavy minerals from Dungeness sediments.

Plate 2.13 a: Euhedral zircon grain with mild pitting on the edge b: Angular zircon grain with conchoidal fractures c: Garnet with impact pits on the edge

15 d: Garnet with mamilliary features, formed by corrosion or chemical dissolution e: Angular garnet grain with irregular fracture and edge abrasion f: Garnet with rhomb-shaped cavities indicating an advance stage of corrosion

Plate 2.14 a: Euhedral tourmaline with mild edge abrasion b: Acicular fresh tourmaline c: Well rounded tourmaline d: Chemically corroded tourmaline e: Well rounded sphene with pock-marked pitted surface

Plate 2.15 a: Relatively fresh amphibole b: Rounded amphibole c: Chemically altered amphibole d: Highly corroded amphibole e: Rounded pyroxene f: Well rounded epidote

Plate 2.16 a: Angular staurolite with fresh fracture b: Chemically corroded staurolite c: Edge pitting in staurolite d: Relatively fresh kyanite e: Slightly corroded kyanite f: Severely corroded kyanite

Plate 3.1 Examples of fresh and worn shells of both offshore and shallow water species identified in sediments of Dungeness. a: Cerastoderma edule , Thracia convexa, Spisula subtruncata, Tellina fabula, Scrobicularia plana b: Nucula turgida

16 c: Worn shell of Corbula gibba

Plate 4.1 Unaltered shell ultrastructure seen under SEM

Plate 6.1 Fine sand with thin dark silty-clayey lamination

17 ACKNOWLEDGEMENTS

First of all I would like to thank my supervisors Prof. Claudio Vita-Finzi and Dr J.T.Greensmith for not only introducing the project to me but also for constant guidance and direction over the last few years. My thanks are due to the Government of India for funding my study in London and the Central Electricity Generating Board (CEGB, now Nuclear Electric pic) for giving me access to their material. During the course of my research I have received much help from many persons on different occasions, among them Mr Don Monteith, Mr Stuart Phethean (Geography Department, UCL) for help in the laboratory in the first two years, Mr J. Davy and Mr A.T. Osborn for help during the final years, and Mr S. Houlding for preparing the thin sections. Mr Osborn helped me with the chemical analyses. Dr I.Wood and Mr Osborn helped me with XRD analysis of clay and glauconite, Dr A. Hurford, Dr A. Morton of the British Geological Survey and Dr M. Mange-Rajetzky of Oxford made many suggestions on heavy mineral analysis, Mr Andy Carter helped me in heavy mineral separation and Mr Andy Beard kindly allowed me to do all of my microprobe analyses in his laboratory. I studied some surface textures of heavy minerals at the SEM laboratory of the Geology Department, Imperial College and did my silt and clay analysis with Prof. I. McCave at Cambridge University. Dr M. Tooley and his collegue Mr Ian Sproxton took me around the Romney Marsh area and helped in sample collection from the Midley Sand and I am greatly indebted to them. During my several visits to the area I stayed with Mrs B. Coatts; my sincere thanks go to her. Mr C. Cromarty of the Geography Department and Mr M. Gray from the Geology Department helped me in SEM and other photography and I thank them both. My thanks also go to Mr Stuart Laidlow, Institute of Archaeology who kindly prepared the final plates for me. Last but not least, my husband Kishor gave me moral support throughout my work. I owe a lot to him.

18 CHAPTER ONE INTRODUCTION

The forelands of Dungeness, Romney Marsh, and are situated mainly in Kent and partly in (Fig. 1.1). This triangular Holocene geomorphological complex is bounded on the south and east by the English Channel and on the north and west by old sea cliffs. The latter are broken by river valleys on the west. Located to the south and east of Lydd, the promontory of Dungeness is the largest of a group of interrelated storm beaches of shingle lying between the of Fairlight on the west and Folkstone on the east. The other beaches occur at Hythe, north-east of (a hummocky strip of mixed sand and gravel), and around Rye harbour. Their surfaces are marked by sequences of parallel to subparallel shingle ridges representing successive shorelines (Fig. 1.2). The ridges vary in height between 3.6 m to 6 m above OD. Dungeness itself is at the apex of the most recent and highest series of beaches known as Denge Beach, which projects well out into the sea. In addition to the gravels there are extensive marshlands reclaimed from the marine alluvium and peat known as Romney Marsh and Walland Marsh and small areas of sand . The latter are well developed at Camber and also occur near Greatstone-on-Sea (Fig. 1.3). The shingle ridges at Dungeness, which run parallel with or at an angle to the present coastline, were recognized long ago as beach formations (Lewis 1932, Hey 1967, Lake and Shephard-Thom 1987) covered at some places by later windblown and marsh deposits. Much less is known about the deeper deposits. In the course of the last few years more precise data about them have become available from a number of borings made by the CEGB which penetrate through the Holocene into the bedrocks of lower Cretaceous age. They have been recently studied by Greensmith and Gutmanis (1990), who put forward some stimulating suggestions about the origin of the coastal system. The objectives of the work presented in this thesis are (a) to collect and collate the considerable amount of new borehole data beneath and adjacent to the present Nuclear Power Station at Dungeness Point, very little of which has been available in the public domain until now, (b) to describe and identify the lithologies which constitute the full Holocene succession, discuss vertical and lateral variations within the borehole successions, and establish a "type succession" for that locality, (c) to describe the detailed

19 c f LINE Hythe r l ' >rTmrrm7rrrTTT>^tn____ n iu w

LONDON © ROMNEY

MARSH

Midley Sand

WALLAND New j | Romney Kc ? MARSH Beach gravels

Broomhili^0rMy R.Ti'lling

^^DUNGENESS — ______I 5>p Winchelsea

CLIFF END

Fig. 1.1 Location map o f Dungeness (from Greensmith and Gutmanis 1990 ) The box is the site of borehole data used in this thesis.

20 21 ^999999999999999999114^ 999999939999

CT> 0)C k_a> U >_ o C ^ cnco a> c c TJC CO ♦-» CO

22 petrology of the sediments, more especially the sands comprising the middle division of the succession about which little previous published information exists, (d) to establish on the basis of the petrology of the sediments, particularly the sands and silts, the possible sources of their constituents, (e) to identify the surprisingly scanty shelly fauna distributed throughout the core samples and date them with First-Order 14C dating method, (f) to compare the First-Order 14C dates with available conventional 14C dates in the area, (g) to establish the styles of sedimentation adjacent to Dungeness Point during Late Holocene times from the borehole data, placing that into a wider context of Dungeness as a whole, utilising pre-existing published information, especially that emanating from recent work of members of the Romney Marsh Research Trust, and (h) to attempt to place the sedimentation of Dungeness Point into a regional setting, taking into account changes in sediment dispersal paths, sea level and climate through the last few thousand years.

A REVIEW OF PRE-EXISTING INFORMATION ON DUNGENESS In order to establish the context for the research at Dungeness Point it is fitting to review some of the significant and relevant scientific contributions of the past and more recent years. The findings of many of the workers have a direct bearing on the interpretation of the Dungeness cores. Early writers suggested that the shingle at Dungeness was deposited in an area of slack water produced by the meeting of the tides (Drew 1864, White 1928). Drew suggested that banks of sand were first formed as a result of the meeting of the North Sea tides and the English Channel tides onto which shingle was later cast up. Redman (1854) believed the area extending from Lydd to the Ness was built from the shingle held up by the old mouth of the Rother at New Romney. Gulliver (1897) first put forward the theory of a migrating which formed the basis of most of the later explanations. He explained the transition of the shingle deposits from a bar to a cuspate foreland as the product of eddies, but this view was later refuted by Lewis (1932). Lewis reviewed all the early literature up to that date and went on to give the most comprehensive account of the formation of the foreland. According to him rapid erosion of Fairlight Head, enhanced by the higher sea level, caused a bend in an already existing bay bar, and the presence of the of the Brede and the Tillingham running out through Winchelsea accentuated the bend by obstructing the movement of shingle from

23 the west to the east of this point. As a result the tended to swing round to face more nearly the dominant southerly and south-westerly waves. In swinging round the Ness, the refracting waves were weakened and unable to drift material northward so that a large amount of shingle accumulated on the point. East-north-easterly waves, originating in the North Sea, formed ridges parallel to the eastern shore. Thus the Ness was formed by two dominant sets of waves from two directions, the sharpness being caused by the absence of large powerful waves coming in from the south-east of the point owing to the proximity of the French coast. The evolution of the shingle barrier beaches between Fairlight and Hythe was further reviewed by Eddison (1983a). Later, Lake and Shephard- Thom (1987) summarised the stages of development of Dungeness and Romney Marsh. Hey (1967) described sections in the beach gravels and Greensmith and Gutmanis studied the deep boreholes at Power Station site. Cunliffe (1980) described the evolution of the Romney Marsh. The surface shingle ridges were formed at the highest point during spring flood- tide by gravels being driven up the beach by the waves. Lower and weaker ridges were destroyed during higher tides and storms. On certain combinations of stormy weather and flood-tide the ridge escaped destruction by the accumulation of shingle in front of it on the seaward side. This protecting shingle was moulded into a ridge which dissipated the power of the waves, and the earlier ridge was untouched thus forming the storm gravel beach deposits. When the supply of shingle was high, the beach accreted seaward as well as vertically by the addition of sub-parallel ridges. The ridges extended for several kilometres forming spits and barriers and curved inland when they approached an estuary; losing height they gradually tapered out and were buried in the sands and clays of the marshland. When the supply of shingle was low, a small storm ridge was formed which was resorted and replenished during the subsequent arrival of storm waves. Johnson (1919) considered that the heights of the ridges were largely dependent on the rate at which they were built. With a rapid supply of material he believed that the shoreline might be prograded so fast that a given ridge had little opportunity to grow to a great height before the shore-face zone is shallowed and a new ridge is formed in front of it. The maximum height as opposed to the average depended largely on the size of the storm waves, for a great ridge could be the product of a single storm given sufficient material. At Dungeness, the average heights of the storm beaches recorded were as

24 follows: west of The Midrips, 4.1 m above OD; west of The Wicks, 4.2 m above OD; Holmestone Beach, 4.3 m above OD; Lydd Beach, 4.7 m above OD; Denge Beach, 5.3 to 6.3 m above OD. The Midrips-Holmstone-Lydd beaches (Fig. 1.3) are the old series shingle ridges truncated at high singles near their southern end. Apart from their trend, which is NE-SW, they are more weathered, and the fulls are low, flat, often ill-defined and partly grass- grown. The Denge series is the most recent series of beaches and shows all the characteristics of the present beaches. On the assumption that each shingle ridge was an ancient shoreline, Lewis and Balchin (1940) deduced oscillations of sea level from the height of the ridges: in historic times at Dungeness, sea level was approximately at 1.65 m below present during the fifteenth century; approximately the same level as today during the thirteenth century; 0.3 m or so lower during the eighth century; and 1.5 m to 1.8 m below the present level in Roman times. According to them the low ridges south of Denge marsh, and the deposit underlying this area, probably date from the low sea level of the Roman-Bronze Age period. Successive beaches and marshes westward of the above beaches were shown as representing several oscillations of level from the late Neolithic (c.4000 yr BP) times to the Bronze Age (c.3000 yr BP). Before this sea level was low and allowed the growth of "forests" which were later submerged. The rate of growth of Dungeness was not uniform as its development depended upon several variable factors. Moreover the rate of growth was much higher at the Ness Point in comparison to the whole foreland. Redman (1854) summarized the evidence up to his time and assumed an average growth of 5.4 m per year from 1617 to 1844. Drew (1864) measured an advance of 324 m since the mapping by the Ordnance Survey (c.1794). Drew (1864) found that from 1794 to 1860 the annual increase was about 4.95 m. Gulliver (1897) noted that the Ness was advancing at a rate of 2.7 m per year. According to Johnson (1919) one ridge was constructed every 20 to 40 years. A table drawn up by Lewis and Balchin (1940) showed that between 1878-1938 growth at the Ness was much higher with an average of 4.05 m per year than further north. They pointed out that, since 1914-19, the southern shore of the Ness has retreated whereas an amount varying between 0 and 90 m had been added to the eastern shore.

25 HOLOCENE DEPOSITS

SURFACE Surface deposits in the area include storm gravels, marsh deposits consisting of fine grained sands, clays and peat and blown sand (Fig. 1.3). The storm gravels consist of beach shingle arranged in a pattern of ridges and troughs. These have been thrown up above mean high water mark by storm waves, where they form semi-permanent ridges and build up into complex spits and barriers. According to Lewis and Balchin (1940) the series of storm beaches at Dungeness covers over 4000 years and the first well-developed shore-line probably dates from late Neolithic times (Gilbert 1933, Lewis and Balchin 1940). Some of the later storm beaches are dated by historical events and cartographic evidence. The alignment of the early shingle (SW-NE) has led to the suggestion that a may have extended from Fairlight to Hythe forming as a result of the predominant eastward (Lewis 1932, Lewis and Balchin 1940). Eddison (1983a,b) argued that shingle barrier beaches are responsible for providing sheltered environments for the formation of peat. As peat was forming by c.5300 yr BP at Pett Level (Welin et al. 1972), Eddison suggested that shingle has accumulated significantly by this period. Lake and Shephard-Thom (1987) suggested that the early barrier was of sandy nature and represented partly by the Midley Sand, which is comparable to Jennings and Smyth’s assertion (1982a) about the sediment of the early barrier on the east Sussex coast. The supply of flint gravel gradually increased to this part of this coast; the earliest unequivocal evidence for shingle barrier formation consists of a series of relatively low shingle beaches west of Lydd. Tooley and Switsur (1988) have dated some of them near Broomhill level to be older than 3410±60 yr BP. Along the east coast of Dungeness the base of the shingle is exposed on the foreshore (Lydd-on-Sea), and can be seen to rest upon sand, but near the Point it is permanently submerged. However there is no shingle below the level of spring low tides (Hey 1967). These surface shingle deposits are generally matrix free; sand lenses and seams are comparatively rare. They consist almost entirely of well-worn flint pebbles (about 98%) presumably derived by erosion of the Chalk and Tertiary beds, with accessions from superficial deposits to the west of the Hastings district. Although there is considerable

26 agreement that most of the flint pebbles originated in the Chalk, it is probable that part of the gravel has a polycyclic history extending through at least the Quaternary Period (Greensmith and Gutmanis 1990, Jennings and Smyth 1990). There is also a small percentage of vein quartz, reddish, grey and liver coloured quartzites (like those of the Lower Trias at Budleigh Salterton in Devonshire), dark coloured quartz tourmaline grit similar to that occurring in south Devon and cherty from the Upper Greensand. A variety of fine grained sandstones including some from Wealden sandstone are also present (White 1928:88). Some of these components have been explained as ships’ ballast, the product of longshore transport from the far west, ice rafted and transported material. However, White (1928) noted that the risk of contamination by ships’ ballast at Dungeness was negligible. The lithological nature of the exotic pebbles, mainly of southwesterly provenance, suggests that longshore drift was probably the dominant factor in their introduction into the Dungeness area. The surface marsh deposits comprise fine grained sands and clays (Green 1968, Shephard-Thom et al. 1966, Smart et al. 1966, Lake and Shephard-Thom 1987, Waller et al. 1988). The sands and clays are associated with creeks and channels and divided by Green (1968) into older decalcified and younger calcified marshland. Their fauna consists mainly of Cardium, and the creek-dwelling Hydrobia and Scrobicularia. The above have been used by many authors to interpret the deposits as the product of tidal flat and environments (Smart et al. 1966). A 14C age determination on Scrobicularia plana from 1 to 2 m below the surface of a creek ridge 450 m S 10 E of Wheelsgate gave a date of 15501120 yr BP (Smart et al. 1966). According to Smart et al. (1966) quartz and micaceous minerals are dominant in the sands and silts, and montmorillonite and micas in the clays, but calcite and glauconite are also found. They concluded that except for the calcites, the finer mineral particles, have been derived from the sedimentary rocks of the Weald. Blown sand has been identified in several places (White 1928, Green 1968, Lake and Shephard-Thom 1987). Remnants of old dunes fringing and overlapping the shingle and providing much of the interstitial sand in it are present at Lydd and at New Romney. It overlaps the northeast end of the shingle underlying the town of Lydd and appears to have been deposited later than the old series of beaches in Denge. The sand here is fine grained, stained with humus and disturbed with roots to a depth of 0.6 m beneath the

27 surface. Well developed dunes of varying age partly overlie shingle at or near The Wanren, and are related to some of the shallow sands capping the shingle hereabouts, as at Lydd. The other relatively old dunes occur at and, mostly overlying shingle between New Romney and St. Mary’s Bay. More recently developed and still currently accumulating ones are at Camber and near Greatstone-on-Sea. The former is about 15 m high and formed between 1617 and 1816 AD (Poker’s map and the Tithe Survey of 1816 in Green 1968:22). The sand contains the comminuted shells of Tellina tenuis and Donax vittatus, valves of which strew the adjacent foreshore, and is speckled with granules of limonite and of an olive green glauconite. The proportion of angular to rounded quartz grains is larger than the Lydd deposit. On the windward side of these dunes low shingle ridges are occasionally visible. The dunes at Greatstone-on-Sea are more recent. These dunes have been shown to have resulted mainly from the deflation of adjacent intertidal sand flats.

SUB-SURFACE There has been very little reported investigation of the sub-surface Holocene deposits. The spread of deep boreholes passing through the succession and into the bedrock of Hastings Beds is uneven. Up to 30 m of alluvial sediments, including peats, are known to overlie a platform of Hastings Beds and Weald Clay (Smart et al. 1966) at Romney Marsh. Drew (1864), Shephard-Thom et al. (1966) and Smart et al. (1966) described the deposits as seen in a few boreholes available at that time. The boreholes recorded thick sequences of gravels, sand and clays as well as peat underneath the variable surface deposits. A water bore near Poplar Hall showed 28.01 m of Holocene deposits consisting of 7.31 m of vegetable debris and 20.7 m of soft blue clay with dark green sand beds. About 20 m of marsh sediments have been described in a borehole at Langdon resting upon the Hastings Beds. In descending sequence they are as follows: turf and mould, 0.15 m, clayey, 0.9 m, sand and mud with bands of peat, 0.6 m, soft light blue clay (grey sandy clay), 1.67 m, grey sand with a few shells, 9.1 m, soft light blue clay with bands of peat, 2.74 m, and brown sand mixed with pebbles and stones of various kinds, 3.2 m (Smart et al. 1966). The deepest of several trial boreholes (Smart et al. 1966) near church proved soil 0.3 m, firm mottled clay 0.9 m, silty clay 1.06 m, sand 10.2 m, loose clayey grey silt with clay lumps and shells 11.8 m. A borehole made in

28 1935 on the Road, just west of Hythe, proved made ground 1.82 m on 1.82 m of light blue clay, then shingle continued until it entered Weald Clay at a depth of 14.6 m. Another borehole at Brookland Bog penetrated tree roots from the surface until a depth of 5.48 m, light blue sand 9.14 m, and dark blue clay 18.2 m. Two boreholes recorded bedrock at c. -20 m (Langdon) and c. -28 m (Guldeford Lane Comer) respectively. Two deep boreholes in the valley alluvium of the lower Tillingham and lower Rother also recorded bedrock at -24.5 m OD (Tilling Green, Rye) and c. 28 m OD (Wittersham Bridge). The deepest deposits at Tilling Green, consisting of peat, have been dated to 9565±120 yr BP (Welin et al. 1974). Green (1968) established the basic stratigraphic sequence of the marshland except for the gravels. The deepest deposit identified by Green is the Midley Sand which is overlain by the Blue Clay. Blue Clay contains shells of estuarine bivalve Scrobicularia. Above this deposit is an extensive peat bed which is thickest at the Dowel and wedges out into the Midley Sand. Two radiocarbon dates are available from the main peat bed in the marsh: 3020±94 yr BP at Appledore Dowels and 3340±92 yr BP from Walland Marsh (Callow et al. 1964). Subsequent deposits referred to as Young Alluvium by Green (1968) include the surface deposits. Waller et al. (1988) described the detailed lithostratigraphy of Walland Marsh, the lower river valleys of the Rother, the Brede, and Pett level and studied the detailed environments of deposition by systematic augering. The stratigraphic sequence described by them broadly compares with that of Green (1968). Tooley and Switsur (1988) also described the subsurface deposits at two localities by shallow depth augering. These deposits are dated by both 14C and pollen assemblages. The deepest deposit noted by Waller et al. (1988) in this area is the bluish grey sand and is of estuarine origin. It is found over a wide area including Pett Level, the lower Brede, the Rother Levels (at Blackwall Bridge), the Royal Military Canal, and on the marshland along the Stone Bridge to section. Texturally it ranges from fine sand to coarse silt and contains marine foraminiferal and bivalve fossils. Overlying bluish grey clay is thickest and most widespread in those lower valley sequences where there is a degree of protection. It occurs only intermittently across the marshland as shown in the sections in Pett Level and that between Stone Bridge and Snargate. This is overlain by thick peat deposits.

29 The peat has been dated to 59701150 yr BP in the Brede, c.5300 yr BP on Pett Level (Welin et al. 1972) and c.5000 yr BP at Blackwall Bridge and c.5150 yr BP at Horsemarsh Sewer. This widespread growth of biogenic sediments lye between C.-5.35 and +0.2 m OD. Ulmus (elm) decline at Pannel Bridge has been dated to 5040180 yr BP. The decline in Tilia (lime) at Brede Bridge and Pannel Bridge has been dated to 3690170 yr BP and 3700190 yr BP respectively. The upper contact of the peat at Old Place has been dated to 1830180 yr BP at a depth of -1.16 m OD. In a few places here the high Tilia value persists until the contact of the peat and upper inorganic sediments and indicates erosion prior to the deposition of the upper inorganic sediments. The inorganic sediments overlying the peat have been found on Pett Level, the lower Brede and the southern part of the Royal Military Canal and shown to consist of black grey laminated sands, silts and clays which were deposited in low energy estuarine condition. They appear to have been brought from the south. At Horsemarsh sewer, these deposits are silty clays with iron concretions, which form two creek ridges trending NW-SE and rising 40 to 50 cm above the valley floor. A pollen diagram for the area immediately subjacent to the silty clay of a creek ridge at Horsemarsh Sewer yielded post-elm decline pollen assemblages. At Broomhill 1, a sample of organic silt from immediately above the flint cobbles on the floor of the low at an altitude of +0.8 m was dated to 3410±60 yr BP and another sample beneath the brackish water lagoonal clay at an altitude of +0.9 m OD yielded a date of 3160160 yr BP. At Broomhill A, the stratigraphic section is more characteristic of a tidal flat and lagoonal environment. Basal clayey silt with Cardium shells, indicating tidal flat sedimentation, ended at an altitude of +1.2 m OD and was replaced by biogenic sedimentation where a radiocarbon assay yielded a date of 3520160 yr BP. Within the biogenic strata the rise of the pollen of saltmarsh taxa has been dated to 3060160 yr BP. Immediately above the dated organic strata, the laminated sandy silts with iron concretions and containing a high marsh assemblage of foraminifera are recorded, and these pass up in a coarsening upwards sequence to a silty fine sand with occasional shell fragments of Cardium and no iron staining, to a fine sand conspicuously laminated and strongly iron stained, and then back to a laminated silty fine sand, with some iron staining. The cutting of a palaeocreek through this sequence with a floor altitude of +0.6 m OD, followed by infilling up to 2.4 m OD and postdating 3060160 yr BP, has been

30 shown to be associated with the establishment of a creek system draining into the Wain way Channel and with the continued of the shingle barriers eastward. The interpretation of the formation of these coastal sedimentary sequences at a number of sites after c. 3000 yr BP has been controversial. Barrier breaching, sea-level oscillations and climatic region, all have been proposed (Waller et al. 1988). The deposits underneath the shingle beaches have been described by Hey (1967), Lake and Shephard-Thom (1987) and more recently by Greensmith and Gutmanis (1990). Hey (1967) described two deep excavations located at the Dungeness "B" Power Station site with bottom levels at -7.5 m and -13.5 m OD. According to him the unimodal pebbles at the highest level pass into a mixture of sand and pebbles below a depth of 0.9 m to 1.5 m. The latter rest upon sand at about -3.9 m, -6.0 m and -7.2 m OD. The contact falls from north to south and is a plane surface with some local shallow channels (Hey 1967, pis. 18 and 19). Hey (1967) found that the individual beds in the sandy gravels were deposited as c.15 cm thick beds with strike of the bedding planes parallel to the strike of the beach ridges and dipping 8 to 10 degrees towards the south-south-east. They were interpreted as foreshore deposits laid down within the last 350 years. There was an abundance of sand, the supply of material was rapid and the average rate of deposition in the direction normal to the bedding was about 0.75 m a year. Permanent deposition was confined to half a dozen brief periods in each year during the time of spring tides. The sandy deposits underneath were uniform in lithology with a few scattered pebbles and some marine shells. The uppermost few feet were crossbedded, but otherwise the bedding was in the form of indistinct laminations, apparently horizontal (Hey 1967, plate 19). Lake and Shephard-Thom (1987) gave a summary log of these deposits broadly mentioning the top gravelly beach deposits and bottom sands and silts with gravels, shell fragments and occasional clay seams. Recently Greensmith and Gutmanis (1990) divided the Holocene succession into basal gravels, middle sands and top gravels and interpreted the succession as a prograding, coarsening-upwards, barred shoreline type, laid down under mixed wave-tidal conditions during predominantly rising sea-levels. According to them the sands were deposited as a lower shoreface-offshore apron on the surface of which rip-current channels occurred with intervals of storm-induced sedimentation and the gravels and sandy gravels were formed as storm beaches, foreshore and upper shoreface deposits.

31 Offshore the Holocene succession thins out rapidly as it approaches the 28 m isobath. The slope is steepest off the point of Dungeness. The sediment surface flattens towards the shoreline on reaching a depth of 1.0-1.5 m below the low water mark (Greensmith and Gutmanis 1990). Beyond the offshore margin of the succession anywhere up to 1.2 km further offshore, there is usually a narrow fringe of mobile sand and gravel some 100-150 m wide and up to 1.5 m thick (BGS 1989 1:250,000).

PLEISTOCENE DEPOSITS IN SOUTHEAST ENGLAND In view of the probability that the source for certain of the constituents within the Dungeness Holocene succession is material laid down peripherally to Pleistocene ice- sheets, especially loessic deposits, a brief summary of relevant published work is desirable. The Quaternary deposits of southeast England have been discussed by Kellaway et al. (1973). Although Destombes et al. (1975) and Kellaway et al. (1975) later proposed that the Dover and the English Channel were glaciated during the Pleistocene, there are alternative explanations for the evidence which they considered to be due to glaciation (Jones 1981). The Pleistocene is not clearly recorded in this region, except for the possibility that the solid rock surface beneath Dungeness at -32 m to -35 m OD, and its lateral equivalent offshore, is of Pleistocene age, reflecting a phase of lowered sea level (age indeterminate) (Lapierre 1975). The area south of the Thames is considered to be extraglacial. The glaciated area nearest to Dungeness is the London Basin north of the Thames valley. Direct evidence of glaciation has been reconstructed from the position of till sheets and fluvio-glacial outwash gravels and is restricted to north of the river Thames. This has been critically reviewed by Jones (1981: 176-96). General reviews of past periglacial environments are given by West (1968) and Williams (1968) and summarised by Jones (1981). Periglacial phenomena have been most widely identified and studied in East Anglia, where those of Devensian age are particularly well developed (West 1968), but they are also recognised in the Weald (Shephard-Thom 1975). Patterned ground, fossil soil structures, cambering, valley bulging, mass movement phenomena, and loess are all known to occur. Involution, frost wedges, frost polygons, patterned grounds are abundant in chalkland, and a lesser amount is

32 reported from other areas. Large structures such as gravel filled pipes, valley bulging and cambering are also found. Sheets of coombe rock or soliflucted chalk, flint gravel head, or other types of solifluction deposits, are widely reported. The products of earlier events were largely reworked during periods of periglacial, fluvial or marine activity, more so in case of head and other arenaceous and argillaceous soliflucted material, so that little has survived in place. Periglacial aeolian deposits known as loess and coversand occur widely in the area as thin, weathered units and have been mixed with other materials by cryoturbation or mass movement deposits. They have also been redeposited by water often thus departing from the strict definition of loess and coversand suggested by Russell (1944) and Van der Hammen (1951). Their ultimate aeolian origin is indicated by mineralogical and granulometric similarities with deposits that do fit the stricter definitions, and sometimes by field relationships indicating derivation from sediment that occurs in so many different physiographic situations that it could only have been deposited by wind (Catt 1977). These have been mapped extensively by the Soil Survey. Continuous deposits of unweathered calcareous loess, which has not been reworked by fluvial or colluvial processes occur over Chalk, Lower Tertiary sediments, and River gravels in areas adjacent to the Thames estuary (north Kent and south-east Essex). They are mapped as brickearth or head brickearth (Dines et al. 1954, Smart et al. 1966, Gruhn et al. 1974). Loess horizons have also been recognized in the coastal head deposits of south Devon (Mottershead 1971). Loess on the Tertiary deposits in south Hampshire was also mapped as brickearth by the Institute of Geological Sciences and by Fisher (1971). Catt et al. (1971) recognized widespread loess in soils over older glacial deposits in north-east Norfolk; a similar coverloam occurs in north-east Essex; in other parts of East Anglia, loess occurs mainly in the river valleys. Almost all the loess in Britain has been attributed to the earlier part of the Late Devensian, but only on indirect evidence. In Kent, solifluction deposits containing loess underlie pellety chalk muds of the Older Dryas period (Kemey 1963, 1965). As the mineralogical composition of the coarse silt in the loess is similar, especially in eastern England, to the same size fraction of Late Devensian glacial deposits, most of the loess has been suggested to have been derived from glacial outwash in the North Sea basin, and is therefore approximately contemporaneous with the late Devensian ice advance.

33 There is evidence of loess and loessic deposits of greater antiquity as well. They are the brickearths of Middle Devensian age in the valley of Kent (Kemey 1971), of Wolstonian age in the lower Thames valley (Wooldridge and Linton 1955), and of Anglian age (the Burham loess) (Rose et al. 1976). The modal size of the silt decreases westwards across southern England from 45 to 25 }im, and there is an increase in the same direction of flaky silt minerals (micas and chlorite). All these changes have been taken to suggest that the loess was transported westwards across the country from the North Sea source area by dominantly easterly winds (Catt 1977). This is also indicated by palaeoclimatic evidence (Catt 1977, Lill and Smalley 1978). Weir et al. (1971) suggested that Kentish loess is similar in mineralogy to glacial deposits to the north, with 10 to 20% originating from the Palaeogene outcrops, particularly the Thanet and Woolwich Beds.

SEA LEVEL Since Mesozoic times the region’s structural and tectonic history has been strongly influenced by the separation of the European and North American-Greenland crustal plates (Kent 1975, Ziegler 1975, Ziegler and Louwerens 1979) and has witnessed various phases of , particularly evident in the North Sea Basin. Continued subsidence in this Basin during the Quaternary is indicated by the accumulation of nearly 1000 m of sediment (Caston 1979) underlining the long term geological pattern of structural instability in the region. This has made the region susceptible to extreme sea-level changes. Apart from the influence of global tectonics, isostatic rebound following deglaciation (Wright 1914) has resulted in uplift in north-west Britain and subsidence in south-east Britain during the Holocene. This has been reinforced by analysis of tide gauge data by Jolly (1939) and Valentin (1953), the analysis of the displacement of deposits formed at sea-level 6,500 years ago by Churchill (1965), the analysis of the distribution of emerged and submerged shorelines of Late Pleistocene and Holocene Age by Stephens and Synge (1966), and the distribution of raised beaches and submerged forests around the of Britain by Dunham (1972). In the 1960s, Shepard (1964) and Curray (1965) grouped the diverse opinions concerning the Holocene or Flandrian rise of sea level into the following three categories.

34 1. Sea level has fluctuated repeatedly from about 1.5 m to 3 m above the present sea level. 2. Sea level has been constant during most of the past 5000 years. 3. Sea level has risen smoothly and not above the present sea level. As early as in 1920, Daly (1920) collated evidence of eustatic fall in sea level of 6 m at about 5000 yr BP and a higher sea level than the present during the preceding Atlantic period. Fairbridge (1961) cited evidence of more than one eustatic fall and rise of the ocean level during the Holocene, as did Tooley (1974) in Northwest England. Jelgersma (1961), Shepard (1963), Curray (1965), Kidson and Heyworth (1973) and others favour a steady Holocene sea-level rise without regressions and transgressions. Over the years there has been much work done on sea-level changes and their impact on coastal evolution (Tooley and Shennan 1987, Devoy 1987b). There is a flood of literature on different aspects of Quaternary sea-level studies as well as the present sea-level movement and potential problems involved in the study (National Research Council 1990, Doomkamp 1990). At the beginning of the Holocene, 10,000 years ago, the global sea level was still at about -45 m OD (West 1972). The rate of sea-level rise was high until 5000 yr BP causing shoreline transgression in southern Britain, where glacial rebound was negligible (Jardine 1979). Possible positions of the Holocene shoreline in the outer estuary of the River Thames at 9600, 9300, 9000, 8600, 8300 and 8000 yr BP have been published by D’Olier (1972, figs. 4 to 9). During the time concerned the mean high water mark level appears to have risen from c. -45 m OD to -17 m OD, and in broad terms the shoreline has moved westwards. More detailed investigation of the inner Thames estuary and of areas in Essex adjacent to the outer Thames estuary covering the period since 8500 yr BP illustrates the variety of depositional environments that resulted from and regression (Greensmith and Tucker 1973, Devoy 1979, 1982). The southeast England is the subject of a thorough review by Devoy (1982), who presents evidence of sea-level rise from -30 m OD at about 9300 yr BP to a still-stand or a reduction in the rate of sea-level rise between about 4500 and 3000 yr BP followed by possible highstand at +0.5 m OD around 1700 yr BP. Historical indicators of relative sea- level changes are recorded from many places by Akeroyd (1972).

35 In the Broadland, Norfolk, MHWS at -19.3 to -19.5 m OD dated to 7500±90 yr BP rose to about -6.0 m OD at 4500 yr BP. About -0.5 m OD sea level has been dated to 1609±50 yr BP (Coles and Funnel 1981). The values for subsidence since 7580 yr BP, and since 4500 yr BP, were shown 1.77 mm/ yr and 1.33 mm/ yr respectively and since 1600 yr BP it is 1.72mm/ yr. In coastal zone of SE Essex marine inundation began between 8900 and 7500 yr BP. Faunal and lithological changes within the 36 m thick succession of Holocene sediments indicate three major transgressive cycles, and five marine incursions the last of which occurred at 300 yr BP (Greensmith and Tucker 1973, 1976). The first and second cycles are confined to the basal infill of preexisting Pleistocene channels and the third, possibly initiated c.7500 yr BP, extends across the whole coastal zone. Each cycle consists of a lower division of clays and silts with thin coarser-grained deposits towards the base and an upper division of sand and sandy gravels. The main environments represented are salt marsh-, beach-chenier-barrier-spit, intertidal flat and channel (Greensmith and Tucker 1973,1975,1976). At Tilbury four fully developed organic layers, representing regressive phases within a rising sea level, occur at depths of -13.0, -10.0, -6.0 and -2.0 m OD and have been dated to 7830±110, 6575±95, 3850±80 and 3020±65 yrs BP. The apparent rapid rate of coastal change in the Boreal and early Atlantic, 8500 to 7500 yr BP, seems to be the result of differential subsidence (Devoy 1979). Akeroyd (1972) noted that in the Thames estuary sea level was not above -1.0 m OD in the Roman Period and could have been as low as -3 m OD. Sea level data on southern England coast are relatively scarce. Akeroyd (1972) reported that southern England underwent continuous submergence with some local interruptions during the Holocene. The highstands are generally higher in the west and lowest in the east. After 4000 BC (5950 yr BP) there is less divergence between these regions. According to her sea level rose 11 m since the Neolithic period, 5000 BC (6950 yr BP) and 1.6-2.6 m since the Roman period (1950 yr BP).

ROMNEY MARSH The whole area was inundated in the early Holocene to form an embayment. The deepest dated peat at -24.5 m (Tilling Green, Rye) has been dated to 95651120 yr BP

36 (Welin et al. 1974). While the relationship of the Tilling Green peat to sea level is unclear, a rise in relative sea level in the Romney Marsh area by a minimum of 17 m has been suggested between c.9500 yr BP and c. 6000 yr BP for the Brede valley by Waller et al. (1988), i.e. about 4.85 mm/yr. Peat at a depth of -5.35 m at the Brede Bridge has been dated to 5970±150 yr BP and at -3.42 at Horsemarsh sewer to 5150±70 yr BP (Tooley and Switsur 1988). Submerged forests accumulated during this time near Pett (Welin et al. 1972). The development of peat has been ascribed to one of the following reasons: the growth of coastal barriers, a fall in sea level, the seaward extension of freshwater and brackish facies as a result of a reduction in the rate of sea level recovery, or an increase in sediment supply resulting in coastward progradation of the beach system. There is still no conclusive evidence concerning the early stages in the development of the barrier system and the age, location, composition and processes which led to barrier formation have yet to be clearly defined. However, the high rate of peat accumulation in the lower valley areas has been attributed to rising sea level situation, although the rate may have been much reduced, until the Tilia decline period which has been dated to 3690±70 yr BP at Brede Bridge (Waller 1987). The earliest date for the arrival of coarse littoral deposits has been determined to over 3410±60 yr BP (Tooley and Switsur 1988). Tooley and Switsur (1988) found a positive tendency of sea level affecting an extensive area including Walland Marsh, Appledore Dowels, Broomhill and Blackwall Bridge during 3340-3020 yr BP. The terminology was introduced by Shennan (1982) in order to avoid confusion between eustatic sea-level changes and local environmental effects. However the post peat deposits in Walland Marsh has also been correlated with a major gap in the coastal barrier during later part of the Holocene, which was a product of changing coastal dynamics (Waller et al. 1988). These deposits are not confined to one period. Such incursions may be the result of the barrier breaching as a result of variations in sediment supply, storminess and other coastal changes.

37 CHAPTER TWO THE SEDIMENTS OF DUNGENESS

INTRODUCTION Three important features of siliciclastic sediments are mineralogical composition, sedimentary structure and texture. In a broad sense, the detrital mineralogical composition of clastic sediments is a reflection of the source petrology. The commonest components present in sediments are quartz, feldspar, rock fragments, micaceous minerals and variable amount of clay, and some accessory heavy minerals. To determine the precise detrital composition of a group of sediments and to distinguish them from other similar sediments, it is necessary to separate and identify the heavy minerals, light minerals and clays. Different varieties of minerals are recorded by point counting under a microscope. Clay minerals are usually identified by XRD analysis. A wide range of depositional agents including wind, flowing water and gravity acting through turbidity currents and debris flow, operate during transportation and deposition of sediments. The depositional processes leave their record in the form of and textures. Some depositional processes are typical of a particular environment, whereas others operate in several environments. The structures and textures in Dungeness sediments are identified here and used in the reconstruction of the environments of sediment deposition at Dungeness later. The logs and cores of the boreholes, drilled in 1983 by the CEGB at the Dungeness "C" power station site, together with more recent three boreholes named the "eastern group", constituted the main data base for the present investigation. The boreholes were sunk by percussion methods through the surface gravels, with frequent sampling, and extended by mud flush rotary core drilling through the underlying sands and silts (information obtained from the borehole log report by CEGB). Most of the boreholes penetrated into the solid rock; some of which were cored down to depths of between 120 and 250 m below the surface and penetrated the Lower Cretaceous-Upper Jurassic sequence (Lake and Shephard-Thom 1987) (for location of boreholes, see Fig. 2.1.1.a). The solid rocks are everywhere overlain by about 40 m of Flandrian marine sediments and shingle deposits, the latter providing a fairly complete stratigraphic record of the Holocene in the locality (see Appendix 1 for detailed logs of borehole).

38 — .— T ----- t / I— Midley ros LI(c*H.'KC'« /’ / / / Midley Sand i f I / / / / LI LYDD tydd on-Sea / j ; /

Dungeness

0 km

1______— Scale

20*"' 0's s' roo B I__ I

Samples were collected from Dungeness boreholes, Midley Sand (near Old Midley Church) and Lydd-on-Sea. Inset 1 0 2 8 • 2 3 8 37 4 3 5 ° t f 9 4 O

& O 6 6 27 0 3 3 O If O

Inset 2 "Eastern group’ 10: 250 M

Boreholes sampled i * „ for present study. ^

H

Fig. 2.1.1 ji Borehole and sample location sites

39 The bottom levels reached by the boreholes were as follows: 1 =-38.87m, 2=-35.15m, 3=-l 14.54m, 4=-39.45m, 5=-37.74m, 6=-36.60m, 7=-38.65m, 8= -33.70m,9=-112.8m, 10=-114.75m, ll=-114.87m, 12=-39.22m, 13=-37.15m, 14=-37.40m, 15=-37.36m, 16=-37.89m, 17=-36.06m, 18=-34.36m, 19=-37.65m, 20A=-37.61m, 20= -9.74m, 21=-37.50m, 22=-l 15m, 23=-34.50m, 24=-38.50m, 25=-33.6m, 26=-37.45m, 27= -36.30m, 28=-36.00m, 29A=-114.65m, 31=-114.60m, 32=-115.04m, 33=-34.15m, 34=- 144.25m, 35=-34.4m, 36=-36.00m, 37=-37.77m, 38=-37.45m, 39=-l 14.5m, 40=-175.2m, 50=-10.2, 51=-177.8m, 52=more than 214.34m, A=-37.35m, B=-36.53m, C=-37.64m, D= -37.08m, E=-37.25m.F=-36.45m, G=-36.97m, H=-37.01m. The Holocene succession of Dungeness can be divided into three subdivisions following analysis of the borehole logs (see Appendix 1). The unit at the base is the Basal Gravels, this is overlain by largely a thick sand succession named the Middle Sands and the upper layers of gravels on the top of the Middle Sands are named as the Top Gravels. In boreholes 101, 12 and 28, the whole succession is dominated by relatively coarse facies and gravels. The Basal Gravels deposits are essentially sandy, clayey gravel lags and up to about 2.8 m thick. The deposits are mainly fine to coarse gravels dominated by flint pebbles with a matrix of clay, silt and medium to coarse quartz sand and shells. Although flint pebbles are dominant, sandstone, limestone, siltstone, ironstone and a few granitic exotic pebbles are also present (Plate 2.1). The Middle Sands consist mainly of greenish-grey, brown, grey and green fine sands and silty sands. These are interbedded with occasional lenses and lamina of dark grey organic clayey silt, soft dark grey silty organic clay and thinly laminated green-grey and grey silty fine sand and fine to medium shelly sandy lag-gravels (Fig. 2.1.1.b). Grey- green and greenish sand and silty sand dominate at Dungeness. The origin and significance of colours in sediments in general has been reviewed by van Straaten (1965), McBride (1974) and Allen (1986). There are three main colours in the sediments of Dungeness, brown, green and grey. Brownish or yellowish colours are produced by the oxidation of ferric minerals. This colour is usually caused by thin coatings of iron hydroxides on grain surfaces. The coatings normally develop more on coarser grains than finer grains and in well oxygenated environments such as at or near the surface of the sediment. The adsorption of ferrous and chlorophyll-related compounds can cause a green

4 0 Basal Gravels

Simplified lence diagram showing lire broad llthologlcal divisions at the main borehole location site

Chonnel Sequence

Top KEY

prove/? grovel? Witf> sond rngtnj to n d i '■vitfi grovel

line !o medium jond? wilh thell?

lom ino*ed ?or>d? o nd ?«!•» •c * ^ «- M.dHI* tUayxjca *ond$

B o io I grovel? ■ s M l

Fig. 2.1.1 b Representative lithological logs of Holocene sequence at Dungeness (from Greensmith and Gutmanis 1990). coloration. Greens are due to iron reduction and ion exchange in relatively impermeable media such as muddy sediments. In the case of the Dungeness sediments part of the green colour can be attributed to the presence of glauconites and glauconitic clay films on detrital grains which escaped oxidation due to the relatively impermeable nature of the sediments at certain levels. Grey sediments may reflect colour transitional between brown and green. Grey deposits are commonly due to masking pigments of organic material. With the presence of abundant plant organic material, black-coloured, colloidal iron- monosulphides also develop because of anaerobic, anoxic conditions. These conditions develop far more rapidly and to a much higher degree in fine-grained, muddy sediments than in the coarse sands. Fine-grained deposits imply lower current velocities and slow depositional rates allowing organic matter to accumulate. In muddy sediments lying on the seafloor the water table must be practically stagnant and reducing in character allowing the production of a black colour. The intermittent thin layers of clayey silts are black probably because of the presence of black iron mono-sulphide. The Middle Sands succession was deposited as low angle dipping (about 1°) beds, as determined in the cores and similar to the present day surface slope offshore to the northeast and west-south-west of Dungeness Point. The sands are flat-bedded and occasionally laminated. They alternate with beds and laminated layers of silty sands and are interbedded with clayey silty sands and silty clays (Plate 6.1). The clayey silty sand and silty clay units are dominantly parallel- and lenticularly-laminated. Individual laminae in these units are up to 2 cm thick and show an occasional micro cross-lamination. Cross­ bedding was noted in the uppermost few metres of the succession in excavations (Hey 1967) but in the borehole cores only indistinct microcross-laminations were found. They sometimes grade upwards from silty sand into silty clay. There are also layers of more massive, unlaminated clayey silty sand. Colour and textural mottling probably due to bioturbation are also visible at some levels distorting the structures. Drifted peat material is incorporated as lenses and pockets found at several levels in the Middle Sands succession. The Top Gravels layer can be subdivided into two subdivisions in keeping with Greensmith and Gutmanis (1990) and Hey (1967). The lower section is a 3.1 m to 8.7 m thick layer of fine to coarse gravels with variable amounts of sand as matrix. It occurs immediately above the Middle Sands succession in a coarsening-upward sequence. This

42 succession has been studied in great detail by Hey (1967) in the excavations and have been described in chapter 1. These sandy gravels have been deposited as parallel to subparallel seaward dipping beds. The largest average diameter of the pebbles in these sandy gravel according to Hey (1967) was about 3.81 cm, the smallest about 0.76 cm. Interbedded sands here are mostly brown and greyish brown in colour and occur as lenses and seams up to 1.5 m thick. Silty clay seams and pockets are very rare. Fragmented and worn bivalves occur sporadically, mainly in the interbedded sands and silty clays, and are similar in type to those in the underlying superficials. The boreholes show that the contact with the underlying Middle Sands is usually sharp and uneven, varying in altitude between -3.45 m and -15 m OD. This second subdivision of the Top Gravels is the storm beach gravels. They are clean, loose, matrix-free flint gravels mainly, 5.2-10.3 m thick and have a base which fluctuates between -7.0 m and +1.4 m OD, suggesting a certain degree of scour and channelling. This does not show any distinct sedimentary structures and are interpreted as backshore deposits by Hey (1967) and storm beach gravels by Greensmith and Gutmanis (1990). The Top Gravels are dominantly flint gravels. The Middle Sands in the middle of the succession are about 30 m thick. Relatively little is known about the details of these deposits. Hence these were investigated in detail in the present study and the results are described in this chapter.

SAMPLING AND ANALYTICAL METHODS Cores of a small number of high recovery boreholes were made available by the CEGB. They were examined and sampled for detailed analysis. Comparison with detailed lithological logs for the 56 boreholes (Appendix 1) indicated that the boreholes studied were representative of the regional sequence. Samples were taken at intervals through the cores, the sampling points being determined by apparent changes in lithology, texture or structure within the sedimentary succession. The colour of the sediments was studied in fresh core material from Borehole No. 39, from 18.25 m to 19.25 m in the lab. They were mainly light grey (10YR 7/2 in the Munsell colour chart) in colour with intermittent thin pale olive colour silty clayey bands (5Y 6/4). These colours were distinct when the sediment was wet, but gradually disappeared after two to three days of exposure. Hence comparison of sediment colours

43 with the Munsell colour chart was not done for subsequent analyses. In some cases, because of the disintegration of the cores, loose material was also sampled on the grounds that the cause of this looseness might have had a petrological basis, for example lack of cohesion due to lack of very fine silt and clay matrix. Despite core waxing during extraction, most of the cores had been opened-up by commercial interests and by the BGS, so that oxidation of the sediments was widespread. Additional surface sand samples were collected from old inland sand banks known as Midley Sand outcropping near the old Midley Church and from the modern beach at Lydd-on-Sea for comparison. Midley Sand (MSI and MS2) samples were collected from the floor of a freshly excavated ditch section which was about 90 cm below the present surface, as well as from about 60 cm below the ditch floor by augering. At Lydd-on-Sea, surface samples (N1 to N3) were collected from the modem intertidal sand at 30 m intervals starting from the nearest landward side of the sand zone adjacent to the shingle. Grain size analyses was done on 62 samples including three samples from the modem intertidal sand at Lydd-on-Sea and two samples from the Midley Sand. Dry sieving was done for all the samples. Representative samples containing more than 8% silt and clay (residue in the lower pan in sieve analysis) were chosen for pipette and sedigraph analyses. As the sediments are unconsolidated in nature, the representative split samples were embedded in resin and then thin sections were prepared. In the laboratory they were studied for mineral identification and distribution. The salient features were recorded and samples were chosen for further examination. The percentage distribution of different components such as quartz, feldspar, glauconite and rock fragments such as chert and sandstone were determined by point counting. A total of 200 grains were counted by the ribbon method (Galehouse 1971). Fifteen samples - ten from boreholes at Dungeness, three from the modern beach sands at Lydd-on-Sea (N1,N2 and N3) and two from the Midley Sand (MSI, MS2), were selected for heavy mineral study. Each of them was first wet sieved in a 7<|) sieve and the fraction finer than 77<}> was dried and sieved into four different size fractions, i.e. 72(J). The first three fractions were taken for heavy mineral analysis. The silt fraction was studied in three selected borehole samples and in the Modern Sand (at Lydd-on-Sea) samples where there were enough

44 material in this size fraction for the heavy mineral separation. Heavy minerals could not be separated from the silt fraction of the Midley Sand as the samples had an inadequate amount of silt. Heavy minerals (>2.8 specific gravity) were extracted from each size fraction separately by the settling or gravity method using bromoform (Carver 1971b). The minerals having specific gravity more than 2.8 sank to the bottom of the funnel. When the downward movement of the minerals stopped the heavy residues were carefully recovered by opening the bottom lid slowly. The bromoform was filtered away and the heavy minerals were washed several times with acetone to remove any bromoform attached to the surface of the heavy mineral grains. Glazed filter paper was used to avoid the fine heavy minerals sticking to the fibres of the filter paper. All the heavy minerals were treated with acetic acid to eliminate carbonates and other impurities. Acetic acid was used instead of hydrochloric acid so that apatite would not dissolve. A representative proportion of each sample was then mounted on glass slides by embedding the grains in Canada balsam and optically examined. The non-opaque detrital heavy mineral proportions were estimated by counting 200 grains by the ribbon method of Galehouse (1971). The coloured varieties of tourmalines were counted. Polished grains of garnets from 7 samples were analyzed by using EDS X-ray analysis system (JEOL Superprobe 733 combined with a link AN 10000-55S). The chemical composition of the garnets were determined. The chemical composition of some of the heavy mineral groups, particularly of tourmalines, amphiboles and garnets, were investigated by this method. Chemistry of the garnets was considered for further study. Fifty polished grains each from the five selected samples (BH samples 38/24, 26/18 and 24/35.5 and Midley Sand (MSI, MS2) and Modem Sand (N2)) were analysed for garnet composition. Thirty five grains were analysed from sample MSI. Microprobe analysis of the garnets did not reveal any chromium, thereby eliminating uvarovite as a potential variable. Similarly, titanium was not detected in significant quantities. Andradite contents are also insignificant, because Al-filled trivalent sites are virtually absent, indicating a lack of substantial Fe+3 substitution except for a very few number of grains in each sample. Hence the andradite content has been calculated, but not considered for plotting in triangular diagram. Therefore all the garnets plotted in the diagram contain the four end members, almandine, spessartine, pyrope and grossular. The content of pyrope, grossular and almandine+spessartine molecules in each

45 garnet was calculated by taking the ratios of Fe (almandine), Mn (spessartine), Mg (pyrope) and Ca (grossular). The compositions then derived have been plotted on triangular diagrams with poles of Almandine+Spessartine, Pyrope and Grossular following Morton (1985b). To distinguish Mn-rich garnet from Mn-poor garnet, those with >5% Spessartine are plotted as x and those with <5% as open circles. Each ternary plot represents one sample with analysis of 50 grains. Scanning electron microscopy was carried out by using a Hitachi S-450, JEOL Superprobe 733 and a Cambridge Scanning Electron Microscope at different times. The samples were mounted on aluminium stubs and were coated with carbon and gold. Carbon coating was used to enable X-ray spectra to be analysed using an EDS system combined with a Link system capable of producing ZAF correction for 14 elements. But carbon coated samples failed to give good resolution photographs because of incomplete conductive contact. Therefore where good photographs were necessary the samples were coated with another layer of gold. In this study the SEM was used for several purposes : a. Study of surface morphology of quartz, heavy minerals and glauconite. b. Study of internal structure and diagenetic changes of the shells. c. EDS analysis of heavy minerals and glauconite. The methodology followed for the study of surface morphology of quartz is as follows. The samples were wet sieved and the fraction finer than 7()> were discarded. The rest were then separated into two fractions: coarser than 4

46 and broad shape and features were noted. Five of them were from the boreholes, two from the Midley Sand, two from the Modem beach sand and one from the Wealden Beds. Only four, one each from Dungeness sediments, Midley Sand sediments, Modem Sand sediments and the Wealden Sand were studied in detail and presence or absence of 38 surface textural features were examined. This data was plotted in a histogram of surface variability plot. Surface textures of whole grains of heavy minerals were examined under a Hitachi SEM attached to an EDS X-ray analyser. Ten grains from the ubiquitous mineral species were hand picked and mounted on aluminium stubs with double-sided adhesive tape and photographs were taken showing details of their surface morphology under scanning electron microscope. Microprobe analyses of garnets, amphiboles, tourmalines and other heavy minerals using the EDS system have been mentioned above, under heavy mineral analysis. Five polished glauconite samples were analysed using the same JEOL superprobe. Glauconite grains were counted along with other minerals from the thin sections and percentage distributions were calculated. Approximately 50 g of unconsolidated samples were taken and sieved through the 4 sieve. The fractions coarser than 40 were passed through a magnetic separator and the glauconites were separated. The process was repeated several times until they were almost completely free from impurities. The glauconites were put into an ultrasonic bath for about 5 to 10 seconds and cleaned by washing with water several times in order to get rid of clayey surface contaminants. A representative part of each glauconite sample was analysed by ICP for bulk chemistry especially the K20 %. Another part was used for determination of cation exchange capacity. A number of polished grains from each sample were analysed in the microprobe in order to get the individual grain analysis. Cation exchange capacity was determined by saturating the glauconite with magnesium solution and measuring the Mg replacements in the solution using an Atomic Absorption Spectrophotometer. Oriented slides were prepared from the Mg saturated glauconite and X-ray diffraction peaks were obtained in order to examine the micaceous mineralogical nature of these glauconites following McRae and Lambert (1968). The XRD technique was used primarily to identify the clay minerals using a Co- Ka X-Ray diffractometer. The procedures for the preparation of oriented samples are as

47 follows: Approximately 3 g of samples from relatively clayey sediments were taken in a 250 ml beaker. 150 ml of 2% calgon was added. The solution was then desegregated in an ultrasonic bath for 15 to 30 minutes. When all the clays had been dispersed, the solution was poured into a 150 ml measuring cylinder and left for 1 hour to settle. After 1 hour, 25 ml of liquid was siphoned out from 10 cm below the top surface and slowly decanted into the centrifuge tube filled with water. Four slides: three glass slides and one ceramic slide, were kept inside four separate centrifuge tubes before dropping the samples into it. Four sub-samples were drawn by the above method and centrifuged for 5 minutes at 2500 revolutions per minute. The clay from the suspension was deposited on the slides in an oriented manner. The slides were carefully taken out of the centrifuge tube, kept on a filter paper and dried in room temperature. Extra oriented acid-treated slides were prepared from three samples in order to identify chlorite.

RESULTS OF THE DETAILED SEDIMENTOLOGICAL ANALYSES

GRAIN SIZE ANALYSES The results obtained from the above analyses are presented in four different ways. 1. Sand and silt+clay fractions were indicated (Tables 2.1 and 2.2). 2. The frequency curves for all the samples were drawn which indicated the presence of dominant modes (Figs. 2.1.1-2.1.3; Appendix 2). 3. Cumulative curves were drawn to determine the nature of these sediments (Figs. 2.2.1- 2.2.3; Appendix 3). 4. Statistical grain size parameters such as median, sorting, skewness and kurtosis were calculated (Table 2.3). 5. Frequency curves for silt and clay samples were obtained and important modes were noted (Figs. 2.3.a and 2.3.b). The sediments are similar in their grain-size distribution. Most of the samples are well sorted and symmetrically skewed, and have slightly variable kurtosis. They are predominantly fine sand (99% to 76%) with a little silt and clay and occasionally contain some coarse material. The modes are mainly at 2.5 and 3 <}) (Figs. 2.1.1-2.1.3). The sediments at certain levels in the Dungeness borehole samples are comparatively fine­ grained. For example, for sample No. 26/15.5 (named for BH no.26 and at a depth of 15.5

48 Table 2.1: % of sand and slit ♦ clay found In grain size analysis.

Locality Borehole/Sample Depth In m Sand % Slit ♦ clay % Dungeness 12 18.50 97.33 2.70 12 19.50 97.31 2.68 12 25.50 94.76 5.24 12 30.60 99.54 0.50 12 35.50 98.07 1.93 13 16.80 99.14 0.86 13 19.50 97.08 2.92 13 28.00 98.43 1.57 13 30.00 98.79 1.21 13 33.50 99.68 0.32 13 37.00 97.23 2.77 16 24.00 80.08 19.92 16 25.60 88.85 11.15 16 26.50 87.76 12.24 16 27.80 92.37 7.63 23 11.00 97.99 2.10 23 13.00 99.26 0.73 23 16.50 86.95 13.05 23 17.30 97.63 2.37 23 18.00 98.45 1.55 23 18.80 97.70 2.30 23 19.40 97.60 2.40 23 21.35 99.08 0.92 23 23.00 96.47 1.53 23 23.75 98.61 1.39 23 24.50 98.71 1.29 23 26.00 98.51 1.49 24 14.50 91.34 8.66 24 17.50 97.74 2.26 24 18.50 91.47 8.53 24 20.00 97.14 2.87 24 22.50 68.82 31.19 24 23.00 95.27 4.73 24 30.00 95.87 4.13 24 32.00 98.02 1.97 24 32.50 93.79 6.20 24 34.00 98.88 1.12 24 34.60 98.15 1.85 24 35.00 98.13 1.87 24 35.50 97.92 2.07 24 37.50 99.37 0.63 26 15.50 55.25 44.75 26 17.50 91.31 8.70 26 18.00 96.44 3.56 26 18.50 91.07 8.93 38 15.00 96.10 3.90 38 16.50 89.66 10.34 38 18.00 89.31 10.69 38 19.50 77.10 22.90 38 21.00 98.19 1.81 38 25.50 94.84 5.16 38 28.00 93.27 6.03 38 30.00 87.99 12.01 38 36.00 80.28 19.72 38 37.50 92.21 7.80 near Old MS1 0.90 98.71 1.29 Midley Church MS2 1.50 99.28 0.72 Lydd-on-Sea N1 surface 99.67 0.33 N2 surface 96.65 3.35 N3 surface 98.85 1.15

MS 1 and MS 2 are samples taken at 0.9m and 1.5m depth from surface respectively from a sand bank near Okf Midley Church.

49 Table 2.2: % of silt and clay in < 4 0 fraction of Dungeness sediments.

Borehole Depth in m Silt % Clay % 16 25.60 86.07 13.75 16 26.50 99.92 0.10 16 27.80 62.61 37.39 24 22.50 50.77 49.03 26 15.50 71.66 28.00 26 17.50 66.95 32.49 26 18.50 29.42 70.17 38 18.00 84.76 14.41 38 36.00 78.49 21.45

50 Fig. 2.1.1 Representative grain size frequency curves of Dungeness sediments

% 100

38/18

—f— 38/21

38/25.5

-B- 38/28

-X- 38/30

- 0 - 38/36

-A- 38/37.5

0.5 1 1.5 . 2 2.5 3 3.5 4 4.5

Size in phi units

Note the important modes at 2.5 and 3phi In a few samples, minor modes also occur both at finer and coarser ends of curves

51 Fig. 2.1.2 Grain size frequency curves of Midley Sand sediments

% 100

90

80

70

60

* MSI 50 e - MS2 40

30

20

10

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units

52 Fig. 2.1.3 Grain size frequency curves of Modem Sand sediment from Lydd-on-Sea

% 100

N1

~ ^ r - N2

-X- N3

0 * 1 1------1— ^ — * 0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units

53 Fig. 2.2.1 Grain size distribution of representative Dungeness samples. u r—H s P a p >

cumulative % 100

90

80

70

60

50

40

30

20

10

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Fig. 2.2.3 Grain size distribution of Modern Sand sediment from Lydd-on-Sea

cumulative % 100

—t— N1

-B- N2

N3

O H ------1------1------1------1------0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units

56 Table 2.3: Grain size parameters of Dungeness sediments, Midley Sand and modern sand from Lydd-on-Sea.

L ocality Borehole/Sample Depth in m Median Sorting Skewness Kurtosls Dungeness 12 18.50 2.53 0.41 -0.06 0.98 12 19.50 2.72 0.27 -0.03 1.32 12 25.50 2.60 0.43 -0.01 1.00 12 30.60 2.40 0.38 0.06 0.83 12 35.50 2.40 0.36 0.06 0.86 13 16.80 2.42 0.37 0.07 0.84 13 19.50 2.55 0.41 -0.03 1.00 13 28.00 2.61 0.37 -0.04 1.02 13 30.00 2.58 0.37 0.04 0.84 13 33.50 2.60 0.36 -0.06 0.99 13 37.00 2.60 0.39 -0.06 1.1 16 24.00 2.88 0.84 0.45 1.36 16 25.60 2.72 0.49 -0.03 1.95 16 26. €5 2.80 0.44 0.05 1.10 16 27.50 2.58 0.50 0.05 0.95 23 11.00 2.50 0.40 0.07 0.88 23 13.00 2.50 0.47 -0.08 2.04 23 16.50 2.65 0.60 0.16 1.64 23 17.30 2.55 0.38 -0.30 1.38 23 18.00 2.50 0.37 -0.04 1.05 23 18.80 2.50 0.38 -0.05 1.16 23 19.40 2.60 0.43 -0.07 1.15 23 21.35 2.50 0.37 -0.04 1.14 23 23.00 2.50 0.36 -0.03 1.28 23 23.75 2.55 0.38 -0.04 0.95 23 24.50 2.55 0.38 -0.05 0.95 23 26.00 2.55 0.38 -0.03 0.95 24 14.75 3.00 0.56 0.10 1.00 24 17.50 2.40 0.65 -0.12 2.02 24 18.50 2.70 1.5? 0.04 2.20 24 20.00 2.60 O.J.'i -0.04 1.08 24 22.50 3.30 0.85 0.26 0.80 24 23.00 2.60 0.41 -0.03 1.08 24 30.00 2.70 0.47 0.03 1.27 24 32.00 2.60 0.40 0.10 1.30 24 32.50 2.80 0.44 -0.03 1.14 24 34.00 2.60 0.37 -0.04 1.00 24 35.00 2.80 0.34 -0.04 1.33 24 35.50 2.60 0.38 -0.08 1.02 24 37.50 2.60 0.37 -0.07 1.20 26 15.50 3.65 0.78 -0.01 0.88 26 17.50 2.83 0.54 0.10 1.26 26 18.00 2.60 0.44 0.00 1.00 26 18.75 2.70 0.55 -0.30 1.62 38 15.00 2.66 0.44 0.00 1.08 38 16.50 2.75 0.50 0.03 0.99 38 18.00 2.72 0.51 0.04 1.08 38 21.00 2.50 0.39 0.00 0.83 38 25.50 2.83 0.41 0.08 1.00 38 27.00 2.66 0.56 0.04 0.87 38 28.00 2.75 0.51 0.04 0.99 38 30.00 2.72 0.43 0.01 1.27 38 31.50 2.61 0.59 0.15 1.49 38 33.00 2.75 0.50 0.08 1.35 38 36.00 2.53 1.06 0.59 1.25 38 37.50 2.55 0.40 -0.01 0.96 near Old MS1 0.90 2.30 0.26 0.06 1.16 Midley Church MS2 1.50 2.30 0.26 0.06 1.13 Lydd-on-Sea N1 surface 2.70 0.26 -0.04 1.23 N2 surface 3.00 0.5 -0.03 1.05 N3 surface 2.80 0.41 0.05 1.05

57 Fig. 2.3.a Grain size frequency distribution curves of silt and clay fraction of Dungeness sediments.

16/25.6 16/26.5

%

4 6 8 10 Size in phi units Size in phi units

26/15.5 24/22.5

% %

4 10

Size in phi units Size in phi units

58 Fig. 2.3.b Grain size frequency distribution curves of silt and clay fraction of Dungeness sediments. 26/18.75 26/17.5

%

1

10 4 6 8 10 Size in phi units ^ '2e in unlts

38/36 38/18

% %

4 104 6 10

Size in phi units Size in phi units

59 m, a form of abbreviation applied to all sample names), the silt+clay content is 44.75% whereas in 13/33.5 the same is only 0.3%. The samples from the Midley Sand (namely MSI and MS2) and the Modem Sand at Lydd-on-Sea (Nl, N2 and N3) contain mainly sand with very little silt and clay. Statistical grain size parameters were calculated using a computer package named "geomorph" in which values derived directly from plotted cumulative curves were entered into established formulae. Four different graphic parameters were calculated: (a) the Median (50%), that is the grain size at 50% in the cumulative curve, taken here as the average size because most samples have one prominent mode; (b) sorting, or the spread around the average size, calculated from the formulae,(84%-(|)16%)/2, by computer in the same package; (c) skewness, that is the symmetry or preferential spread to one side of the average [<}>16%+16%)]; and (d) kurtosis, the degree of concentration of the grains in the central size band [(90%-10%)/1.6(75%-<})25%)]. All these parameters are tabulated in Table 2.3. The medians are mainly between 2.3 and 3.0 <}>; in one of the samples (26/15.5), it is 3.85. Following McManus (1988:78, table 3.5(b)), samples are generally well to moderately well sorted (42 borehole samples and two Modem Sand samples are well sorted; seven borehole samples are moderately well sorted) and are characteristic of beach and near shore zone (Davis 1985b). Two borehole samples, all the Midley Sand samples and one Modem Sand sample are very well sorted. Only three samples from the boreholes are moderately sorted and two samples from the borehole samples are poorly sorted. The sediments are essentially symmetrical in their skewness (48 samples from the boreholes, all the samples from the Midley Sand and from the Modem Sand). Four samples are positively skewed, one sample is very positively skewed, two samples are negatively skewed, one very negatively skewed. Kurtosis is more variable. Forty-seven samples are either mesokurtic or lepto and very lepto-kurtic. Nine samples are platy-kurtic (the sediments were distributed over wider spectrum of grain size than other samples). In the silt and clay size analysis by sedigraph method, the sediment contains mainly silt with very little clay. They contain prominent modes at the coarse silt range (Figs. 2.3.a and 2.3.b). There are, however a few samples which are more clayey in nature

6 0 (24/22.5, 26/18.75). Discussion There is an unusual lack of variation in these Holocene deposits and they are predominantly of fine sand and silt-sized material. The good sorting of these sediments can be attributed to the nature of the depositional environment and the nature of the sediments supplied to the area. The sorting of the sediments at Midley Sand and Modern Sand indicates the action of waves and tides in a beach and nearshore region. Most of the samples from Dungeness also showed good sorting and symmetrical skewness, thus are probably either affected by wave activity or are derived from well sorted sand from nearshore region. The relatively poor sorting and fineness of sediments at certain levels at Dungeness suggest that these were deposited further away from the foreshore zone, that is in the shoreface and offshore zone where wave action was only intermittently effective. These are described in detail in chapter 5, 6 and 7. The silt fraction contains dominant modes at coarse silt range, typical of loessic sediment described in the region.

SCANNING ELECTRON MICROSCOPY OF QUARTZ Scanning electron microscopic analysis of surface features on detrital monocrystalline quartz sand grains was used in conjunction with other information about grain size, mineralogy and depositional environment in an attempt to discover more about the history of the Holocene deposits at Dungeness. Samples coarser than 4 (coarse silt fraction) were examined separately. Their general shape and textures were also noted (Plate 2.9). Samples examined from the Holocene sediments showed various mechanical and chemical textural features (Appendix 4). Typical features and grains of the sand fraction are shown in Plate 2.2 to 2.7. The surface features from the samples of the Hastings Beds showed an abundance of diagenetic modification, such as secondary growth of silica and etching and paucity of mechanical features. Typical grains of these are shown in Plate 2.8 and are compared with similar grains from Holocene sediments for provenance studies. With regard to the silt grains, these are very angular with different breakage and

6 1 Table 2.4: List of SEM surface microtextures of quartz (after Williams and Thomas 1989).

Angular/rounded Topographically Positive Areas Very High Relief High Relief Medium Relief Low Relief Smooth Topographically Negative Areas Very High Relief High Relief Medium Relief Low Relief Smooth Conchoidal Fractures Concave Up Convex Up Dish Shaped Conchoidal Fracture and Arcurate Steps Radiating Steps Edge Abrasion Cracks Severe Edge Abrasion Moderate Edge Abrasion Mild Edge Abrasion Large Irregular Blocky Depression Isolated Large "V'shaped Blocks Large Blocks Large Flat Areas Parallel Straight Scratches Curved Scratches Mechanical "V"s Projecting Surface Depressed Areas Irregular Pits Sickle Pits Small Conchoidal Fractures Smooth Capping Layer Irregular Solution/Precipitation Surface Chemical Oriented "V"s Large Isolated Chemical "V s Upturned Plates ICrystallographlc Overgrowths ______

62 patterns. When these were compared with silts from the Hastings Beds samples (Plate 2.9), they were found to be very different. The microfeatures observed were plotted in a surface feature variability plot (Fig. 2.4). The quartz grains from the Hastings Beds are not shown in these surface variability plots as they showed only diagenetic features, such as crystalline overgrowths and chemical etching. Discussion It can be seen from the general observations and the surface feature variability plots (Fig. 2.4) that the mechanical features, such as the development of mechanical "V"s, small conchoidal fractures and blocky breakage, and chemical features, such as irregular solution and precipitation, constitute the main surface microfeature. These features broadly compare with sediments from nearshore barrier environments (Williams and Thomas 1989). A few grains still display very high relief and mechanical failure textures characteristic of sediments modified by high energy nearshore wave action or glacial processes (Whalley and Krinsley 1974). These more or less angular grains from Dungeness show high relief, scratches, and various blocky topographies. The subaqueous littoral processes are shown to be responsible for the production of blocky topography by intermittent grain-grain collision. However, scratches are formed by prolonged contact between grains. This is not often possible in subaqueous environment. Roundness achieved by some of the grains suggest reworking of these sediments during the Pleistocene period on several occasions. Reworking could have taken place both by marine processes during interglacials and by . On the whole the presence of a mixture of very well rounded grains along with very angular grains with contrasting surface microtextures on them indicate that these sediments were derived from multiple sources. High percentage of the grains in the borehole sediments also show a second phase of fracturing with fresh large flat surfaces which is typical of recent littoral deposits. Qualitative differences between environments with distinctive textural patterns have been successfully identified by SEM microtexture analysis (Krinsley and Doornkamp 1973, Margolis and Krinsley 1974). Surface texture resolution of subenvironments and within large scale interactive environmental systems has also been attempted with variable success (Whalley and Krinsley 1974, Middleton and Davis 1979, Prusak and Mazzullo

63 1. Rounded 2. Angular 3. Topographically Positive areas with very high relief 4. Topographically positive areas with high relief 5. Topographically positive areas with medium relief 6. Topographically positive areas with low relief 7. Topographically positive areas with smooth surface 8. Topographically negative areas with very high relief 9. Topographically negative areas with high relief 10. Topographically negative areas with medium relief 11. Topographically negative areas with low relief 12. Topographically negative areas with smooth surface 13. Conchoidal fractures with concave up surface 14. Conchoidal fractures with convex up surface 15. Conchoidal fractures with dish shaped fractures 16. Conchoidal fractures and arcuate steps 17. Conchoidal fractures and radiating steps 18. Edge abrasion with cracks 19. Severe edge abrasion 20. Moderate edge abrasion 21. Mild edge abrasion 22. Large irregular blocky depression 23. Isolated large V shaped blocks 24. Large blocks 25. Large Flat areas 26. Parallel straight scratches 27. Curved scratches 28. Mechanical V s on the projecting surface 29. Mechanical V s on the depressed areas 30. Irregular pits 31. Sickle pits 32. Small conchoidal fractures 33. Smooth capping layer 34. Irregular solution/precipitation surface 35. Chemical oriented V s 36. Large isolated chemical V s 37. Upturned pits 38. Crystallographic overgrowths. VO

On CN 00 CN oo C » ■g £ § ^ t-H # 5 u VO 3 s VO & ^ 00 £21 00 CD X5 & m 8 <1 ° 3 00 cS CO 3 ,

Ov

VO

CN

O O. O o o o o o O Ov 00 lO cn CN

64 1987). Surfaces of relict origin have also been identified (Middleton and Davis 1979). Quartz grain surface texture analysis from coastal sediments has been undertaken in various regions. Margolis and Krinsley (1971) noted that mechanical V s were a common feature on grains transported by littoral processes. Higgs (1979) observed that V s developed best on grain-surface projections rather than in depressions. Analysis of aeolian grains (Margolis and Krinsley 1974) indicated that a combination of chemical solution and silica redeposition, and abrasion created frosting and grain rounding. Upturned plates are also quite distinctive in aeolian grains (Krinsley and Doomkamp 1973). Angular grains with high relief, scratches and various blocky topographies characterise glacially derived shape and surface textures.

DETRITAL LIGHT MINERALOGY At Dungeness, all the sandy samples were examined in thin section and the percentage distribution of different detrital components were determined by point counting (Fig. 2.5). Thin sections studied from Modem Sand and Midley Sand were also found to be of similar detrital mineralogy. In detail, angular to rounded quartz is the major component (89 to 96.5 %), the rest includes glauconites (2 to 6 %), feldspars (traces to about 2.5 %) and chert (about 4.5 %).

HEAVY MINERAL ANALYSES Heavy mineral analyses have been used for sediment provenance determination, sand body correlation and in the interpretation of diagenetic events. Boswell (1933) was among the first to report that heavy minerals are useful clues to the nature of the source rock. Milner (1962) outlined the principles for correlation by heavy mineral techniques. Later, when the problems of dissolution of unstable minerals (intrastratal solution) and hydraulic influence on heavy mineral distribution were detected (Morton 1985a), the technique became less popular. In these cases varietal studies of different minerals such as amphiboles on the basis of colour (van Andel and Poole 1960), and zircon, tourmaline and garnet on the basis of colour, form and inclusion (Brammali 1928, Krynine 1946, Dreimanis et al. 1957, Connally 1964), have been used. This method later was found to

65 F ig . 2 .5 Detrital mineralogy of Dungeness sediments in thin section

Quartz

Glauconite

Chert

m Feldspar

i_. 0 10 20 30 40 50 60 70 80 90 100

frequency %

W m 24/14.75 ' 24/18 Iw 24/19.5 ! ...... J 24/22.5

P. ’ 1 24/23 24/26 iH l 24/30 EiJl 24/32.5

24/14.75 means BH 24 and 14.75 m depth 66 be misleading as colour is not a very distinctive indicator of the petrology (McDonald 1968). More recently microanalysis of minerals and the assessment of compositional variation of a particular species in heavy mineral assemblages have gained wide use. Detrital pyroxenes, amphiboles, tourmalines and garnets (Morton 1984,1985b, Mange- Rajetzky and Oberhansli 1982) are used for the purpose. Garnet has been found to be the most suitable group among all these minerals because of its relatively stable nature and limited density range. Despite some of the limitations of the method, heavy mineral analysis has been regarded as a satisfactory provenance and correlation tool (Gibbard et al. 1991), especially in Quaternary sediments. A few heavy mineral studies of the Holocene sediments in the area have concentrated on river valley deposits (Chartres 1981, Millar 1984, Burrin and Scaife 1988). They revealed major windblown loessic components in the Holocene river valley sediments. Zircon, tourmaline, garnet, rutile, the epidote group (allanite, zoisite and clino- zoisite), the amphibole group (hornblende, actinolite, tremolite, glaucophane), the pyroxene group (enstatite, hypersthene, diopside, augite and aegirine), kyanite, sillimanite, andalusite, sphene, spinel, apatite, chloritoid, corundum, topaz and pumpellyite were all identified in all the samples. Examples of some are shown in Plates 2.11 and 2.12. The abundances of major minerals are shown in Figs. 2.6.1.a to 2.6.6 and Appendix 6. Amphiboles and tourmalines are concentrated more in the 2(J)-3(j) fraction and zircon in the 3

67 Fig. 2.6.l.a Heavy mineralogy of fine sand (2-3 phi) fraction of Dungeness sediments

Zircon

Tourmaline

Rutile

Garnet -US

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 30 40 50 60 70 80 90 100

frequency %

m 12/19.5 L _ J 12/35.5 13/19.5

24/22.5 LZ] 24/35.5

68 Fig. 2.6. l.b Heavy mineralogy of fine sand (2-3 phi) fraction of Dungeness sediments

Zircon

Tourmaline

Rutile

Garnet

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 40 60 80 90 100

frequency % • i m i 26/18 38/15 L.:J 38/24

■H 38/36 mm 38/37.5

69 Fig. 2.6.2.a Heavy mineralogy of very fine sand (3-4phi)fraction of Dungeness sediments

Zircon

Tourmaline

Rutile

Garnet

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 30 40 50 60 70 80 90 100

frequency %

13/19.512/19.5 W m 12/35.5 13/19.512/19.5

24/22.5 24/35.5

70 Fig. 2.6.2.b Heavy mineralogy of very fine sand (3-4phi) fraction of Dungeness sediments

Zircon

Tourmaline

Rutile

Garnet

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 30 40 50 60 70 80 90 100

frequency %

I M 26/18 ETj 38/15 I H 38/24 ! ■ 38/36 CTJ 38/37.5

71 Fig. 2.6.3 Heavy mineralogy of coarse silt (<4phi) fraction of Dungeness sediments

Zircon

Tourmaline

Rutile

Garnet n

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 30 40 50 60 70 80 90 100

frequency %

m 12/19.5 CIZ3 38/36

SHI 38/37.5

<4phi = finer than 4 phi 72 Fig. 2.6.4 Heavy mineralogy of Midley Sand

Zircon

Tourmaline

Rutile

Garnet

Amphibole 1

Epidote

Staurolite

Kyanite

Others/Unknown

0 10 20 30 40 50 60 70 80

frequency %

(2-3 phi) (3-4phi)

The sample studied is MSI. This has been collected at 0.9 m below surface of a sand bank near Old Midley Church. 73 Fig. 2.6.5 Heavy mineralogy of Modem Sand from Lydd-on-Sea

Zircon

Tourmaline

Rutile

Garnet

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 30 40 50 60 70 80 90 100

frequency %

U N l(2-3phi^B N 2(2-3phiJH N3(2-3phi) III N l(3-4phijM N2(3-4phi^H N3(3-4phi)

Nl, N2 and N3 are surface sand samples from of the modem shore at Lydd-on-Sea

7 4 Fig. 2.6.6 Heavy mineralogy of coarse silt (<4phi) fraction of Modem Sand sediment

Zircon

Tourmaline

Rutile

Garnet

Amphibole

Epidote

Staurolite

Kyanite

Apatite

Others/Unknown

0 10 20 30 40 50 60 70 80 90 100

frequency %

75 Fig. 2.7 Distribution of tourmaline varieties

Tourmaline variety

Brown

Green

Blue

Yellow

Pink

Multicoloured

Fibrous

I L 0 10 20 30 40 50 60 70 80 90 100

frequency %

12/19.5 38/15

38/37.5

76 Table 2.5: Representative electron microprobe analysis results of detrital garnets Loca Bore Depth SiO, A1A TiO, F e A MnO MgO CaO tion hole/ in m sample Dunge BH 24 35.5 37.6 21.8 ND 32.7 0.4 3.5 3.6 ness 38.3 22.1 ND 22.7 0.4 55 10.7 38.6 20.1 0.4 4.6 0.8 ND 35.1 36.5 20.6 ND 20.0 19.9 0.15 2.2 39.1 22.7 ND 2825 0.8 7.5 1.4 BH 26 18 37.8 21.9 ND 34.4 ND 4.4 0.9 37.0 21.4 0.18 19.5 15.7 0.8 5.1 38.9 22.5 ND 24.7 0.6 8.5 4.5 38.0 21.6 0.2 25.9 0.6 2.8 10.8 BH 38 15 38.2 21.9 ND 34.3 1.1 2.0 2.1 37.6 21.3 ND 14.9 11.4 0.3 14.1 38.4 22.3 ND 29.8 0.9 7.0 1.2 Midley MSI 0.9 36.7 21.0 ND 28.1 2.1 1.9 7.1 Sand 38.3 26.97 ND 3.6 0.1 1.9 23.0 37.8 21.1 ND 23.5 13.6 0.6 4.7 38.4 21.8 ND 19.0 0.4 8.9 8.3 MS2 1.5 36.1 13.1 1.9 10.0 0.3 0.1 35.8 38.3 20.6 0.5 3.1 0.2 0.1 36.2 36.1 21.3 ND 37.0 ND 2.6 0.5 36.7 21.8 ND 12.8 27.5 0.2 2.7 35.9 21.6 ND 21.6 16.7 0.9 1.6 39.2 23.5 ND 19.7 0.3 11.2 5.7 Lydd- N1 surface 36.9 21.0 ND 25.3 0.3 4.7 3.4 on-Sea 38.1 22.1 ND 36.0 1.4 2.7 1.4 - 37.1 21.5 0.2 24.9 17.1 0.7 0.3 37.2 22.2 ND 28.5 0.4 6.6 3.2 38.7 22.6 ND 24.2 0.6 2.8 13.1

77 Table 2.6: Garnet analysis according to 24 Oxygens of samples described In Table 2.5.

Loca Bore Depth SiO, A1203 TiOj Fe,0, MnO MgO CaO tion hole/ In m sample Dunge 24 35.5 5.97 4.09 0.00 4.35 0.06 0.84 0.62 ness 5.92 4.03 0.01 2.94 0.05 1.26 1.77 5.94 3.64 0.05 0.59 0.11 0.04 5.78 5.98 3.98 0.00 2.74 2.77 0.04 0.39 6.04 4.12 0.00 3.64 0.11 1.74 0.23 26 18 6.00 4.10 0.00 4.57 0.00 1.03 0.16 5.97 4.06 0.00 2.64 2.15 0.19 0.9 5.96 4.07 0.00 3.17 0.08 1.94 0.73 5.98 4.00 0.03 3.41 0.07 0.66 1.82 38 15 6.08 4.12 0.00 4.58 0.14 0.47 0.37 5.98 3.98 0.00 1.98 1.54 0.06 2.41 5.98 4.09 0.00 3.89 0.12 1.62 0.2 Midley MSI 5.99 4.05 0.02 3.84 0.29 0.47 1.25 Sand 5.92 4.91 0.00 0.47 0.02 0.44 3.81 6.03 3.97 0.00 3.14 1.84 0.15 0.81 5.97 4.0 0.00 2.48 0.05 2.06 1.38 Midley MS2 1.5 5.94 2.54 0.24 1.38 0.04 0.02 6.31 Sand 5.9 3.74 0.05 0.4 0.03 0.02 5.98 5.96 4.15 0.00 5.11 0.00 0.63 0.09 5.89 4.12 0.00 1.72 3.73 0.06 0.47 5.93 4.2 0.00 2.98 2.33 0.22 0.28 5.89 4.16 0.00 2.48 0.04 2.5 0.92 Lydd- N1 surface 6.16 4.13 0.00 3.54 0.05 1.18 0.61 on-Sea • 6.00 4.10 0.01 4.75 0.19 0.63 0.23 5.95 4.05 0.02 3.33 2.32 0.17 0.06 5.88 4.14 0.02 3.76 0.05 1.55 0.54 5.91 4.07 0.00 3.12 0.08 0.64 2.15

78 Table 2.7: Mole % of different types of garnets in the samples described in Table 2.5.

Loca- Bore Depth Almandine Spessartine Pyrope Grossular Andradite -tion hole/ in m sample

D u n g e 24 35.5 74.11 0.94 14.23 10.55 0 n e s s 48.84 0.87 20.93 29.34 0 3.57 1.78 0.65 83.74 10.24 45.76 46.95 0.67 5.54 1.0 63.78 1.84 30.37 3.99 0 26 18 79.26 0.04 17.9 2.74 0 44.87 36.61 3.26 15.24 0 53.48 1.29 32.82 12.35 0 57.07 1.24 11.06 30.49 0 38 15 82.3 2.5 8.4 6.65 0 32.6 25.88 1.0 39.49 1.0 66.65 2.04 27.78 3.48 0

M i d l e y MSI 0.9 65.6 4.92 7.95 21.28 0 S a n d 9.85 0.4 9.24 80.25 0 52.6 30.97 2.58 13.63 0 41.35 0.88 34.46 23.04 0

M S 2 1.5 1.5 0.6 0.3 62 35.3 1.7 0.46 0.31 84.6 8.39 87.61 0 10.86 1.52 0 28.77 62.31 0.93 7.89 0 51.32 40.09 3.8 4.79 0

L y d d - N 1 s u r f a c e 65.76 0.89 21.88 11.34 0 o n - S e a 81.82 3.26 10.91 3.97 0 * 56.59 39.45 2.94 1.02 0 62.77 0.83 25.8 9.01 0 52.00 1.33 10.6 35.89 0

79 Pyrope O < 5% Spessartine X > 5% Spessartine

Sample No. 24/35.5

Almandine + Spessartine Grossular

Pyrope O < 5% Spessartine X > 5% Spessartine

Sample No. 26/18

Almandine + Spessartine Grossular

Pyrope O < 5% Spessartine X > 5% Spessartine

Sample No. 38/15

Almandine + Spessartine Grossular

Fig. 2.8 Garnet composition of sand from Dungeness. 80 Pyrope O < 5% Spessartine X > 5% Spessartine

MS1

Almandine + Spessartine Grossular

Pyrope O < 5% Spessartine X > 5 % Spessartine

MS2

Almandine + Spessartine Grossular

Pyrope O <5% Spessartine X >5% spessartine

Almandine + Spessartine Grossular

Fig. 2.9 Garnet composition of sand from Midlev Sand and Modern Sand from Lydd-on-Sea. 81 Shephard-Thom (1987) Midley Sand is part of an old barrier deposit laid down as a result of a slight reduction in the rate of sea-level rise and is older than the present shingle foreland. The samples from Lydd-on-Sea are modem intertidal shallow water coastal deposits. The sediments at Dungeness have been dated as late Holocene deposits (Chapter 4) presumably younger than the Midley Sand but older than the modem intertidal sand. The similar heavy mineral composition of these three different units are clearly demonstrated by three independent provenance sensitive criteria, namely the gross heavy mineral distribution, tourmaline colour varieties and garnet geochemistry. Hence the implication is that these units share the same or similar source. The heavy fraction in the sediments have a varied heavy mineral suite. The presence of a large amount of stable minerals such as zircon, rutile, tourmaline and garnet along with some semi-stable species such as kyanite, staurolite and some unstable species such as the epidote group, the amphibole group, and some pyroxenes, is consistent with derivation from multiple sources.

GLAUCONITE STUDY Green and yellow peloids resembling glauconites are present in the Holocene sediments of the area. Glauconites are usually considered to be authigenic although they may occur as detrital glauconite in a wide range of sedimentary rocks, particularly if calcareous since they are highly stable in alkaline conditions (Fairbridge 1967). The detrital origin of the glauconites occurring in Wealden Beds has been shown by Allen et al. (1964) by K-Ar dating. In view of their presence in up to about 6% of the sample in Dungeness sediments as calculated by point counting of the thin sections (Fig. 2.5; Appendix 5), information on the exact nature of these grains were thought to be of help in the interpretation of the sediment source. Description and mineralogy When viewed with the binocular microscope, the peloids appeared spherical to elongate, sometimes with polylobate and lamellar structures. The grains are of fine sand size usually in the range of 4<|)-2.5, and display a variety of colours, from dark green to olive green and from yellow to brownish yellow. Sectioned grains examined with the petrographic microscope were found to be fine grained and contained microcrystalline aggregates (Plate 2.1 (a)). No oolitic structure or nuclei were observed. There were no

82 shells or other organic coatings attached to the exterior surface. A SEM study of 25 representative grains was made by selecting different varieties of green and yellow peloids. Micrographs were made showing whole grains as well as details of surface features. The grains are variable in shape from spherical to elongate to lobate in shape. The detail surface features showed (Plate 2.10) 1. Smooth surfaces in relatively low magnification 2. Surfaces characterized by a scaly structure in high magnification. Most grains from boreholes and modem beaches are green in colour with some brownish grains which were formed due to weathering and oxidation (McRae 1972). The SEM study shows that with respect to morphology they resemble the evolved and highly evolved glauconites described by Odin and Matter (1981). Green and brownish grains were hand picked from a number of samples for X-ray diffraction analysis. Two random samples and five oriented air-dried samples showed distinct peaks at lOA indicating glauconitic mica (Fig. 2.10). Ten samples were analysed by the ICP (Inductively-coupled plasma spectrometry) method and the results indicated iron oxide 24.57-32.13%, A120 3 6.6-7.8%, MgO 2.66- 3.17% and K20 3.99-5.51%. Cation exchange capacity (C.E.C) was determined for 7 glauconite samples and was found to be 12.68-24.45 meq/lOOg. These results (Appendix 11) point to glauconite (McRae 1972). A microprobe study was made of 10 grains each from 5 samples (Table 2.8 and Appendix 11). Most of the grains gave comparable result. Overall the high K20 (up to 9%), relatively high Si02 and high Fe-oxide, and low A120 3 and MgO content suggest that these are primarily glauconitic minerals (McRae 1972, Odin and Matter 1981). It is of note that, in general, brownish peloids have a somewhat higher content of iron than the green ones. Differences in iron content probably reflect the effect of oxidation on the grains. Discussion McRae and Lambert (1968) have studied in detail the mineralogy of the glauconites present in the Tertiary and Mesozoic rocks of southeast England. According to their studies Tertiary glauconites have a low K20 content ( up to 5.8%), but Mesozoic glauconites have high K20 (up to 7.9). They determined the K20 by flame photometry following an HF-HC104-H2S04 digestion. Bulk analysis of glauconites from the Holocene

83 COUNTS 20000 25000. 30000. 10000 15000. 3000. 000 2 4000. 5000. 5000. 6000. 7000 1000 g. .0| rydfrcormso luoie rm nees edi t. n e im d se ungeness D from glauconite of s diffractogram -ray 2.10.|X . ig F . . . . 0. 0. 10 10. . Oriented air dried air Oriented 0 2 20 . . Random air dried air Random 2 Co K„ o C 20 ° •2 0 Co Ka Co 0 •2 0 40. 30. 40.30. 50. 50. 60. 60. Table 2.8: Representative electron microprobe analysis results for glauconite from Dungeness sediments.

Si02 ai 2o 3 FeO MgO CaO k 2o Na20 52.83 5.98 21.44 5.28 0.16 9.53 0.35 49.84 8.93 21.03 2.65 0.11 8.6 0.15

52.93 4.26 23.78 2.08 0.14 7.12 0.23 44.22 8.47 22.69 2.84 0.89 5.56 0.13

35 sediments of Dungeness by the ICP method showed up to 5.51% K20. Many grains here are oxidized and weathered and are therefore not likely to give reliable mineralogical results. Microprobe analysis of the polished individual grains avoided this surface problem. The analysis was made in the interior of the grains and the results proved that the glauconites have up to 9% K20 (Table 2.8, Appendix 11). However some grains contain 5% or less K20. Although direct comparison with the results of McRae and Lambert (1968) is not possible because of the different methods followed for analysis, the microprobe results indicate a mixed Tertiary and Cretaceous provenance for the glauconites.

CLAY MINERALOGY The clay fractions were separated and oriented samples were prepared for XRD analysis following the soil survey methods of Avery and Bascomb (1974). A cobalt X-Ray Diffractometer was used, and the samples included air dried, glycolated, heat treated material, the last after heating for 4 hours at 330°C and 4 hours at 550°C and acid treated. Clay minerals were identified by their characteristic basal reflection maxima. An approximate estimate of the proportion of different clay minerals was determined using the procedure of Weir et al. (1975) (Appendix 12). Results The clay fraction (finer than 7) contains mainly illite, kaolinite, and a small amount of mixed clay of degraded illite, montmorillonite, vermiculite and chlorite. The peaks in the XRD spectra are shown in Table 2.9. In Figs. 2.11 and 2.12, representative XRD profiles are shown. Illite is generally the dominant clay component of the group and may include a glauconitic component. It is recognised by peaks at about 10.06A, 5.006A and 3.3A. Some of the 3.3A peaks may include quartz as indicated by their relatively high intensity. Kaolinite is subordinate to illite in abundance, none the less it is present in conspicuous amounts in all the samples. The 7.1 A, 3.58A are the diagnostic kaolinite peaks, and they remain intact at 330°C but collapse completely after heating at 550°C for 4 hours. In some samples these peaks include the chlorite {(002) and (004)} reflections. The latter is identified by the presence of a small but significant peak at 14.255A, which diminishes in intensity but persists even at 550°C. This is further proved on treating the samples with 50% HC1. On treatment by acid the peak at 14.25A

8 6 Table 2.9! Paaka Idantlflad In XRD analysia of clay.

Locality Borehole/Sample Depth In m. Oriented Air dried 330* C 550° C G lycolated Acid treated Dungeness 1 34.40 14.30 14.30 17.3-14.3 10.05 10.05 10.05 17.3-14.3 7.14 7.14 4.98 4.98 4.98 4.72 4.25 4.25 4.25 3.58 3.58 3.58 3.35 3.35 3.35 1 35.85 14.50 17.7-14.3 10.05 10.05 10.05 7.14 7.14 7.14 4.98 4.98 4.98 4.72 4.25 4.25 4.25 3.58 3.58 3.58 3.35 3.35 3.35 16 24.00 14.26 14.26 14.26 21.375-17.103-14.255 14.50 peak became subdued and irregular 10.07 10.07 10.07 10.07 7.14 7.14 7.14 5.01 5.01 5.01 5.01 4.73 4.73 4.73 4.29 4.29 4.29 4.29 3.59 3.59 3.59 3.34 3.34 3.34 3.34 2.01 2.01 2.01 2.01 16 27.80 14.00 14.00 14.25 sweling of 14.25 peak 9.90 9.90 9.90 7.14 7.14 4.98 4.98 4.98 3.58 3.58 3.58 3.34 3.34 3.34 26 15.50 14.30 14.73-17.3 10.00 10.00 10.00 7.20 7.20 5.02 5.00 5.00 3.59 3.59 3.59 3.35 3.35 3.35 26 22.50 14.26 14.26 14.26 20.1-17.103 10.07 9.97 9.97 9.97 7.14 7.14 7.14 5.01 5.01 5.01 5.01 4.73 4.73 4.73 4.29 4.29 4.29 4.29 3.59 3.59 3.59 3.34 3.34 3.34 3.34 2.01 2.01 2.01 2.01 26 24.00 14.50 10.05 10.05 10.05 7.14 7.14 5.00 5.45 4.27 4 27 4.27 3.35 3.35 3.35 28 30.CO 14 30 10.05 10.05 10.05 7.14 7.14 5.00 5.00 5.00 4.25 3.58 3.58 3.58 3.35 3.35 3.35 near Old MS 2 (Midley Sand) 1.50 14.26 14.26 14.26 21.375-17 103-14.255 14.25 peak became subdued and irregular Midley Church 10.07 10.07 10.07 10.07 7.14 7.14 7.14 5.01 5.01 5.01 5.01 4.73 4.73 4.73 4.29 4.29 4.29 4.29 - 3.59 3.59 3.59 3.34 3.34 3.34 3.339-3.329 2.01 2.01 2.01 2.01 Lydd-on-Sea N2 (modem sand) surface 14.26 14.40 14.40 14.4 & 15.2-25.648 14.40 peak became subdued and irregular 10.06 10.06 10.06 7.14 7.14 5.00 5.00 5.00 4.30 4.30 3.59 3.59 3.59 3.36 3.36 3.36 Fig. 2.11 X-ray diffractogram of typical clay sample : Oriented air dried e ai +eiuomo paxiw Aep O O U W f + l!JoiHO 88 siNnoo n

5 0 0 . o 20 20 Co K,

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89 breaks into a broad peak. In such a situation kaolinite can be distinguished from chlorite, for chlorite tends to dissolve in acid whereas kaolinite does not. The break of the peak at 14.2A, the disappearance of the peak at 4.7A and absence of change at 7.1 A and 3.58A after treatment with acid, show that substantial amounts of kaolinite are present in the clay and that chlorite is very limited in amount. Chlorite occurs with smectite and vermiculite as mixed clays. As the amount of chlorite is low, it is difficult to distinguish within these mixed clays. The mixed layer clay shows broad reflections at 12-14.2A and swells to a series of peaks at 17.13-20.lA, sometimes leaving a small relict peak at 14.2A after glycolation. It collapses partly to 9.97A after heating at 330°C for 4 hours and leaves a peak at 14.255A which may be chlorite or vermiculite. Although weak, the 14.2A peak is a reference for the presence of chlorite within it. Smectite, which has a peak at 12.4A and swells to 17.1 A after glycolation is also present in this mixed clay. Moreover this whole peak is the more or less continuation of the left shoulder of the illite characteristic of degraded illite or glauconite. Following Weaver (1960) the degree of illite crystallinity or the sharpness ratio is measured from the ratio of the height of the illite (001) peak at 10A to the height above the base line at 10.5A. The illite sharpness ratio was found to be less than 2 (Gill et al. 1977) and is therefore considered a detrital effect. The amount of each clay fraction was determined for sample 16/24 by the semiquantitative method proposed by Weir et al. (1975) (Appendix 12). The calculation shows that illite represents about 64.17%, mixed clay about 20.18% and kaolinite about 14.4%. Chlorite is no more than 0.67%. Discussion The samples from three different areas have a similar clay mineralogy. Similar clay fractions were reported by Smart et al. (1966) from six samples of head brickearth from Kent. According to them these brickearth samples compare well with loess (Pitcher et al. 1954, Smart et al. 1966, Catt 1978). Wealden sediments also contain a large proportion of illite and kaolinite (Lake and Shephard-Thorn 1987).

90 KEY TO PLATES Plate 2.1 Photomicrographs of thin sections of sands and gravels from Dungeness in polarized light. All photographs enlarged X40. a: Moderately well sorted silty sand showing angular and rounded quartz, glauconite, chert and other shell fragments. b: Detrital flint gravel. There is some weathering indicated by the brownish colour, c: Limestone from the Basal Gravels d: Granitic rock fragment from the Basal Gravels

Plates 2.2 - 2.7 SEM micrographs showing characteristic surface microtextures observed on quartz grains.

Plate 2.2 a: Assemblage of quartz sand grains from Dungeness showing overall shape of the grains. Note angular, rounded and chemically altered grains. b: Rounded grain c: Angular grain d: Grain with high relief e: Grain with medium relief f: Grain with low relief and partly smooth surface

Plate 2.3 a: Conchoidal fracture with convex up surface b: Conchoidal fracture with concave up surface c: Dish shaped fracture d: Large conchoidal fracture with arcuate steps e: Conchoidal fracture with radiating steps (see lower part of the grain) f: Small conchoidal fracture (see left bottom centre of the photograph)

Plate 2.4 a: Edge abrasion and cracks b: Large irregular blocky depression c: Isolated large V-shaped blocks d: Large blocks e: Large flat areas f: Parallel straight scratches

Plate 2.5 a: Curved scratches b: Upturned plates c: Mechanical V on projected areas d: Mechanical V on depressed areas e: Irregular pits f: Sickle pits

91 Plate 2.6 a: Smooth capping layers of silica on grain surface b: Smooth capping of silica on upturned plates c: Irregular solution and precipitation d: Chemical etching e: Chemically oriented V ’s

Plate 2.7 a: Topographically negative areas with medium relief b: Topographically negative areas with low relief c: Edge abrasion in grains with authigenic overgrowth and solution d: Edge abrasion and irregular blocky fracture e: Elongate grain

Plate 2.8 Comparison of SEM surface textures of quartz sand grains from the Hastings Beds and from Dungeness. a: Assemblage of quartz grains from the Hastings Beds. Note the irregular shape of the grains. b: Single sand grain from the Hastings Beds showing detail angular shape of the grain c: Magnification of the above grain (2.8.b) showing crystalline overgrowth d: Another type of quartz sand grain from the Hastings Beds showing chemical etching e: Magnification of the above grain showing details of the etched surface f: A quartz sand grain from Dungeness with crystalline overgrowth, most probably derived from the local Hastings Beds. g: Quartz sand grain from Dungeness with crystalline overgrowth and later partially altered by solution h: Magnification of the grain (2.8.f) showing partially altered surface of authigenic overgrowth

Plate 2.9 SEM surface microtextures of quartz silt grains from Dungeness and from the Hastings Beds. a: Angular quartz silt grain from Dungeness with fresh breakage surface b: Blocky quartz silt grain from Dungeness with conchoidal fracture, flat surface and surface particle adhering c: Angular quartz silt grain from Dungeness with upturned plates d: Freshly broken silt with flat surface and platy surface e: Quartz silt grain from the Hastings Beds f: Magnification of the above silt grain (2.9.e) showing authigenic overgrowth

Plate 2.10 SEM micrographs of glauconite grains from Dungeness. a: Elongate rounded glauconite grain with smooth surface b: Scaly structure on surface of the above grain (2.10.a) c: Details of the scaly structure in higher magnification d: Pellet shaped rounded smooth glauconite grain e: Scaly structure on the surface of the above grain f: Magnification of the above grain showing thin plate like structure

92 Plates 2.11 - 2.12 Photomicrographs of different varieties of heavy minerals seen under microscope. Plate 2.12.e and 2.12.i are enlarged to X350. The rest are enlarged to X175.

Plate 2.11 a: Euhedral colourless zircon in ordinary light b: Euhedral zoned brownish zircon, in ordinary light c: Zircon with authigenic overgrowth, in ordinary light d: Prismatic brown tourmaline in ordinary light e: Prismatic brown tourmaline with abraded metasomatic or sedimentary overgrowth in ordinary light f: Angular, flaky green tourmaline in ordinary light g: Euhedral yellowish green tourmaline, in ordinary light h: Prismatic blue coloured tourmaline in ordinary light i: Angular flaky multicoloured tourmaline, in ordinary light j: Angular colourless to very light pink garnet with fresh conchoidal fracture, in ordinary light k: Etched garnet with intense corrosion in ordinary light j: Subrounded light pink garnet in ordinary light

Plate 2.12 a: Rutile with characteristic twinning, in polarized light b: Well rounded apatite, in polarized light c: Straw yellow colour and saw tooth structure of corroded staurolite, in ordinary light

d: Green amphibole, in ordinary light e: Brown amphibole, in ordinary light f: Bluish green amphibole, in ordinary light g: Rounded epidote grain with characteristic greenish colour, in ordinary light h. Rounded epidote group mineral with characteristic interference colour, in polarized light i: Andalusite with characteristic patchy red colour pleochroism under ordinary light

Plates 2.13 -2.16 SEM micrographs of heavy minerals from Dungeness sediments.

Plate 2.13 a: Euhedral zircon grain with mild pitting on the edge b: Angular zircon grain with conchoidal fractures c: Garnet with impact pits on the edge d: Garnet with mamilliary features, formed by corrosion or chemical dissolution e: Angular garnet grain with irregular fracture and edge abrasion f: Garnet with rhomb-shaped cavities indicating an advance stage of corrosion

Plate 2.14 a: Euhedral tourmaline with mild edge abrasion b: Acicular fresh tourmaline c: Well rounded tourmaline

93 d: Chemically corroded tourmaline e: Well rounded sphene with pock-marked pitted surface

Plate 2.15 a: Relatively fresh amphibole b: Rounded amphibole c: Chemically altered amphibole d: Highly corroded amphibole e: Rounded pyroxene f: Well rounded epidote

Plate 2.16 a: Angular staurolite with fresh fracture b: Chemically corroded staurolite c: Edge pitting in staurolite d: Relatively fresh kyanite e: Slightly corroded kyanite f: Severely corroded kyanite

94 Plate 2.1

C d 95 Plate 2.2

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98 Plate 2.5

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100 Plate 2.7

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11 0 CHAPTER THREE MOLLUSC STUDIES

INTRODUCTION This chapter deals with the mollusc remains of the Holocene sediments of Dungeness. The samples were obtained from the borehole cores at the Dungeness "C" Power Station site and from the "eastern group" of boreholes. In a sedimentary deposit, the kinds of fossils present, their state of preservation, and their mode of attachment and orientation are all guides to the relative water depth and the energy state at the time of deposition (Hallam 1967). Through the study of the of the present day species, the depth of other deposits containing these forms is estimated. These are an indirect guide to the depth: delicate articulated forms suggest growth and in situ burial in a current-free environment, hence probably relatively quiet deep water, whereas disarticulated, broken and sorted fossil debris indicate strong bottom currents and wave activities, hence shallow water. The interpretation of such evidence is, however, complicated by the mechanical transport of shallow water forms to deep waters and vice-versa. These have to be carefully looked at before reaching any conclusion. Such a situation is present in the case of the sediments at Dungeness. Mixed assemblages are created by the transportation of shells. Of the three main lithological units recognised in the Holocene succession of Dungeness (Chapter 2), only the Basal Gravels and Middle Sands are rich in organic remains. The bulk of this material is mollusc shells, largely comminuted shell debris with a few whole though worn shells. The mode of emplacement of these shells provides the most important criterion for distinguishing the characteristic style of sedimentation at Dungeness. Mollusc shells occur in a sandy gravelly matrix in many boreholes near the base of the sequence. Throughout the Middle Sands succession broken shells, predominantly of thin-shelled bivalves such as Tellina fabula, are present. In addition, layers of shell concentrations, both of whole as well as broken specimens, occur in the fine to medium shelly sandy lag-gravels within the Middle Sands succession. Shells were separated by sieving and hand picking from 10 selected samples from six boreholes for identification of species. Two of them are from the Basal Gravels and 8 from the Middle Sands. Two boreholes, BH 101 and BH 102 were from eastern group

111 of boreholes, and the remaining four boreholes were from the western group at the site of the proposed Dungeness "C" Power Station. Different species were identified and noted together with the lithology of the respective samples (Table 3.1). Some examples of whole, broken, fresh and worn shells of both offshore and onshore species are shown in Plate 3.1. Due to the worn and broken nature of these shell assemblages, it was difficult to identify all of them and so make any kind of quantitative analysis.

MOLLUSC SHELLS FOUND IN DUNGENESS The shells were identified and their ecology was determined by using Tebble (1966), British Caenozoic fossils by British Museum (Natural History) (1975), The Macdonald encyclopedia of shells (1982) and Campbell and Nicholls (1984).

OFFSHORE SPECIES Abra alba, A. nitida, A. longicallus, Tellina fabula, Spisula subtruncata, Spisula elliptical, Mactra corallina, Nassaridae, Thracea convexa, Nucula nucleus, Nucula turgida, Corbula gibba, Trivia sp., Natica sp., Searlesia costifera, Ocenebra erinacea, Emarginula reticulata, Mysella bidenta, Ensis sp., Area lactea, Donax vittatus, Pholadacea, Modiolus phaseonus.

ONSHORE SPECIES Acanthocardia tuberculata, Chlamys varia, Scrobicularia plana, Cerastoderma edule, Macoma balthica, Tellina tenuis.

The following mixed fauna has been reported by Greensmith and Gutmanis (1990) from the Basal Gravels.

Scrobicularia plana, Mactra corallina, Acanthocardia echinata, Ostrea edulis, Cerastoderma edule, Abra abra, A. longicallus, Area lactea, Tellina fabula, Thracea convexa, Nucula turgida, N.nucleus, Spisula subtruncata, Corbula gibba, Donax vittatus, Mya arenaria, Chlamys varia, Natica sp.

112 Table 3.1: Shells from Dungeness.

Borehole Depth in m jLithology Shells

Samples from Basal Gravels 39 38.20 Gravel in a Nassaridae adrlatica, Searlesla costifera, Nassa sandy matrix reticosa, Ocenebra erlnacea, Natica sp., Nucula with shell turgida, Corbula gibba. ' fragments along with broken shells of many other bivalves. 102 39.20-39.40 Gravel in a Nucula turgida, Area lactea, Donax vittatus, brown clayey Mactra corallina, Abra longicallus, Nucula matrix and nucleus, Mya arenaria, Cerastoderma edule, shell fragments Corbula gibba, Nassarius reticulatus, Spisula subtruncata, Chlamys Varia, Pholadacea sp., Modiolus phaseolinus.

Samples from Middle Sands 12 25.85-26.50 Grey green silty Macoma balthica, Mysella bidenta, Tellina sand with shells fabula, Tellina tenuis, Abra nitida, Scrobicularia plana, Ensis sp. 31 37.70-37.90 Laminated green Nucula turgida, N. nucleus, Corbula gibba, grey clayey Natica sp., Scorbicularia plana, Tellina fabula, silty sand with Mactra corallina. wood and shell fragments 31 37.90-38.25 Brown grey and Emarginula reticulata, Corbula gibba,Abra green grey alba, Tellina fabula, Spisula elliptica, Abra mottled sand nitida. 32 34.50-35.45 Green grey Corbula gibba, Carditacea sp., Natica sp., Tellina mottled sand fabula, Nucula turgida. with shells, and gravels with wood and peat fragments 39 24.50 Green grey sand Trivia sp. with shell and many broken bivalve fragments. fragments 39 25.25-25.50 Green grey sand Emarginula reticulata with wood and and many broken bivalve fragments. shell fragments 101 37.70-37.96 Grey sand with Abra alba, Tellina fabula, Thracia convexa, shell fragments Spisula subtruncata, Cerastoderma edule, Area lactea, Corbula gibba. Nucula turgida, Ostrea edulis. 102 37.35-37.55 Green grey Acanthocardia tuberculata, Natica sp., sand with shells fragments of other bivalve shells. ______

113 RESULTS AND INTERPRETATION The present depth of occurrence of these shells at Dungeness varies from over 39 m below the present surface to about 24 m below the present surface. According to their original habitat, however, this bivalve-dominated fauna typifies intertidal and subtidal zones to a water depth of 80 m or more in the present English Channel. For example Scrobicularia plana is essentially intertidal and generally occupies intertidal mud . Cerastoderma edule is another bivalve usually occupying intertidal to high sublittoral niches and Ostrea edulis and Acanthocardia echinata are often found just below low water mark, though they are known to live at depths of 30 m or more. Nucula nucleus and Donax vittatus are rarely found at depths much exceeding 20 m. Nucula nucleus is rather restricted in occurrence and occurs where the bottom is a coarse muddy gravel. Nucula turgida occurs on sands and sandy silts in water ranging in depth from 8 to 100 m, and very occasionally in muds at a maximum depth of 180 m. It is most abundant in sandy-mud with small amounts of gravel. Where N. turgida is most abundant it is found together with Abra alba and Corbula gibba. Corbula gibba is an inhabitant of muddy gravel substrata from below the Laminaria zone to depths of some 146 m. It is a typical member of the bottom fauna. Mactra corallina exists to depths of 80 m or more burrowing into clean sand and gravel substrata. Donax vittatus prefers to burrow into clean sands.

MODERN OFFSHORE MOLLUSC COMMUNITIES IN RELATION TO SUBSTRATUM AND CURRENTS IN THE ENGLISH CHANNEL AND THE SOUTHERN NORTH SEA In inshore waters on the north side of the English Channel, and in sandy bays and , species present include the bivalves Tellina tenuis and Donax vittatus and the polychaete Arenicola marina . The species present are in the Boreal Shallow-sand Association (Holme 1961, 1966). In estuaries and shallow subtidal waters where the sediments are finer grained, the bivalves Macoma balthica, Scrobicularia plana, Cerastoderma edule and Tellina tenuis occur (Holme 1949, 1961, 1966). These species comprise the Boreal Shallow-mud Association. Wilson (1982) described in detail the occurrence and distribution of different shell

114 species in different bedforms of offshore tidal deposits around the British Isles. These bedforms represent characteristic substratum and energy condition such as the current- strength. Particular areas in the English Channel, such as the Eddystone area 22 km south of Plymouth (Allen 1899, Ford 1923), the area off Looe (Vevers 1951, 1952), the continental shelf off Brittany and the Baie de la Seine (Auffret et al. 1972, Cabioch 1968, Glemarec 1969a, b, Larsonneur 1971, Lefort 1970) have been studied in detail. Donax vittatus, Spisula elliptica, Ensis minor , Tellina fabula, Mactra corallina, Ensis ensis, Spisula subtruncata, Natica alderi, Nucula tenuis, Thyasira flexuosa, Thracia phaseolina, Mysella bidenta, Tellina tenuis are all present in different bedform zones in the southern North Sea. The sand floor supports the bivalves Spisula solida, Abra alba and the gastropod Natica alderi. The Modiolus and Abra community is found in sand ribbon zones and gravel floors. The latter are considered to form in relatively high tidal current situations.

MARINE MOLLUSC COMMUNITIES FOUND IN HOLOCENE SEDIMENTS IN NEARBY AREAS While studying the coastal barrier sediments of south and north Holland, van Straaten (1965) grouped the mollusc fauna into several divisions; group I: rich in Spisula subtruncata, Spisula solida and possibly other Spisula species; these are open-water near­ shore species for that part of North Sea; group II: Polinices catena, Polinices poliana, Area lactea, Mysella bidenta, Venus gallina, Mactra corallina, Donax vittatus, Abra alba, Ensis ensis, Thracea papyracea ; these are more or less characteristic of the North Sea association along the coast of South and North Holland; group III: Macoma balthica, Barnea Candida live in coastal zones of the North Sea and in the estuaries and other tidal flat environments of the Netherlands; group IV: Mytilus edulis ; originally mainly restricted to tidal flat areas, estuaries and . At the present day it also lives in large numbers along the North Sea shore, where it inhabits artificial structures such as wrecks, harbour moles and ; group V: Cardium edule, the dominant species of intracoastal marine environments in the Netherlands, also lives in small numbers in North Sea beaches at depths of a few metres; group VI: Scrobicularia plana and Mya arenaria are chiefly restricted to estuaries, tidal flat areas and lagoons. During the study of the faunal content of the sediments in the vicinity of the River

115 Crouch, east Essex, Greensmith and Tucker (1971) identified Ostrea edulis, Scrobicularia plana, Cardium edule, and Nassarius sp., with fragments of Corbula sp., Cardita sp., and various other lamellibranchs and gastropods in sandy gravel deposits of shoreline origin. The fauna in a second group of sandy sediments attributed to marine type, and generally of intertidal and subtidal aspect, included Cardium edule, Mytilus edulis, Macoma balthica, Spisula elliptica, Nucula sp., Barnea Candida (Crustacea), occasional Scrobicularia plana, Parvicardium scabrum, Ostrea edulis, Hydrobiids, and Littorina sp. Here shells of subtidal origin were transported towards the shore during marine transgression. A sequence of silts and silty clays there yielded forms such as abundant Hydrobia ulvae, Littorina saxatilis, Planorbis-type gastropod, Spirorbis sp. (Polychaeta), Scrobicularia plana and Cardium lamarcki and have been interpreted as diagnostic of the upper zones of intertidal flats and of supratidal zones.

CONCENTRATION OF MIXED SHELL ASSEMBLAGES IN COASTAL SEDIMENTS The present evidence suggests that the shallow water intertidal bivalves, such as Cerastoderma edule and Scrobicularia plana, as well as deep water species at Dungeness, are mixed assemblages occurring mainly in lag-concentrates. The mixing of transported shells under the influence of wave and tidal activity and occurrence of mixed megafaunal assemblages (non-microfossil) have been reported in shoreface, beach and intertidal zones. Storms generally tend to concentrate large shell material in beach zones by winnowing away the beach sand. -sized shells, where these shells are mixed with sands, comprising as much as 70% of the beach sediment, occur in Padre Island, Texas. The shell concentration of Padre Island is the result of littoral processes (Watson 1971). Current patterns concentrate shell debris from the nearby inner shelf zone and it is then moved landward by wave action (Davis 1985b). Hoskin and Nelson (1971) found beaches composed of 66% biogenic carbonate debris on beaches in Sitka , Alaska. At some locations beaches contain shell material that is being reworked from older sediments. Estuarine deposits containing brackish-water oysters and clams are being eroded along parts of the Texas coast, as are marsh deposits on the eastern shore of Virginia and Delaware, where the shoreline is transgressing. As a result the present-day beach contains a significant percentage of these large shells, with the estuarine mud being washed away (Davis 1985b). Derived shells are reported to occur on the floor of the

116 English Channel (Curry 1989). On the Essex coast, Greensmith and Tucker (1980) identified many shell beds containing mixed marine/estuarine species such as Cerastoderma edule, Ostrea edulis, Scrobicularia plana, Macoma balthica, Littorina littorea, L. saxatilis, Nassarius reticulata, N. incrassatus, Nucula turgida, Parvicardium exiguum, Hydrobia ulvae, Buccinum sp. and Balanus sp. (Crustacea) as chenier storm ridge accumulations formed no lower than a level close to mean high water mark, and the majority of these shell bodies formed on the surface of a salt marsh in a supratidal position. Post-mortem transport is extensive in many current- and storm-swept shallow seas, thereby leading to shell abrasion and mixing of benthic communities. Basal lag deposits of mud clasts, shells, plant debris and rock fragments are commonplace in shoreface and offshore-transitional zones in high energy storm deposits (Johnson and Baldwin 1986:252). These lag deposits usually contain a mixed shell assemblage above an erosional surface and have been described from offshore storm sequences along the modem shelf. Elliott (1986) suggested that during storm conditions, high amplitude waves cause extensive erosion of the upper beach face, and sediment is redeposited as washover fans in lagoons and swept seaward to the lower beach face and offshore areas to produce storm-generated beds. Tidal and rip channels provide natural pathways for storm-generated current- driven sediments. Thus the shallow water species move along with drifted wood fragments from the onshore region into the deeper water. A considerable amount of transportation is evident as the shells from Dungeness sediments are broken, worn down, and some of them have brown colour coatings indicating oxidising conditions and exposure to air (Plate 3.1)). However, in contrast to the Essex coast cited above where the shells and their fragments are moved inshore, at Dungeness the shallow water species have probably moved offshore. Open-water marine species are relatively more common than intertidal and shallow water species.

117 KEY TO PLATE 3.1

Plate 3.1 Examples of fresh and worn shells of both offshore and shallow water species identified in sediments of Dungeness. a: Top row - (from left to right) Cerastoderma edule , Thracia convexa , Spisula subtruncata , Tellina fabula, Scrobicularia plana b: Nucula turgida c: Worn shell of Corbula gibba

118 Plate 3.1

LLI..IJ I I I I I I u u

mum CHAPTER FOUR RADIOCARBON DATING

INTRODUCTION The increasing demand for improved resolution of environmental chronologies necessitates quantitative dating. This is generally provided by radiometric dating and in the case of the Late Quaternary by means of 14C assay. At Dungeness Holocene sediments lie directly on the lower Cretaceous Hastings Beds. The sediments at -34.2 m OD resting directly on the bedrock have been dated earliest to 3270±90 yr BP (Greensmith and Gutmanis 1990), 3099±143 (cal. age) yr BP. Peat at -23.5 m OD in a borehole at Tilling Green near Rye has been dated to a much older Holocene date, 9565±120 yr BP (Welin et al. 1974). The general level of the base of the Holocene has been identified at -32 m to -35 m OD (Appendix 1). This is probably the continuation of the widespread surface of marine planation identified elsewhere in the eastern English Channel. The general bedrock immediately offshore and to the southeast of Dungeness shows deeper palaeovalleys and a number of faults with similar trend as the faults mapped further west (Greensmith and Gutmanis 1990). Five 14C dates including one on wood have been reported from Dungeness (Greensmith and Gutmanis 1990). The dates were obtained from mixed assemblages of shells and wood fragments in the Basal Gravels at a depth of -32.1 m to -34.2 m and ranged between 3270±90 and 1370±80 yr BP. Further dating of the Basal Gravels and the Middle Sands succession is the subject of this chapter.

HOLOCENE DEPOSITS AT DUNGENESS The event preceding the formation of the Dungeness complex in the area seems to have been the development of a series of SW-NE trending sandy banks or barriers parallel to the palaeoshoreline and represented mainly by the partly coarse-grained Midley Sand (Green 1968, Lake and Shephard-Thom 1987, Greensmith and Gutmanis 1990). Between 5000 and 3000 years BP, a period characterised by a relatively rapid decrease in the rate of sea-level rise affecting the English Channel, the Thames estuary and East Anglian coastal areas (Devoy 1982), coastal barriers were formed in many coastal areas

120 of this region, where sediment supply was high. In Holland, the formation of an early coastal barrier complex is related to a slowing down in the rise of sea level between 6000 yr BP and 4800 yr BP (van Straaten 1965). The formation of coastal barriers cannot, however, be directly correlated with a eustatic fall of sea level, as the former is highly dependent on the amount of sand available offshore and along the coast. Transportation of gravels increased in the coastal region presumably as a result of the establishment of the present hydrodynamic regime. The rate of sea-level rise decreased and the longshore drift was established in the . They were deposited on the seaward flank of the Midley Sand mainly as a result of southwesterly longshore drift. Near Broomhill, at Tishy’s Sewer, biogenic sediments resting on low level shingle at an altitude of C.+0.8 m OD, are dated as 3410±60 yr BP (Tooley and Switsur 1988). To the west and southwest of Lydd, near Scotney Court, clay with roots (at +3.0 m altitude) resting on such a bank are dated to 27401400 yr BP and a 4.5 cm thick peat overlying the clay has been dated as 2050190 yr BP (Green 1968). The latest addition of the storm beach gravels at the power station site is believed to have occurred within the last 750 years according to Greensmith and Gutmanis (1990) and within the last 350 years according to Hey (1967). Waller et al. (1988) have investigated the logs of boreholes and augered to depths of 12 m or more around the western periphery of Walland Marsh and lower river valleys adjacent to that area. They obtained several 14C dates for this area which will be discussed later. The boreholes drilled on the coastal gravels include a few near Rye, reported by Lake and Shephard-Thom (1987) and a large concentration of boreholes near Dungeness point drilled as a part of a site survey for the Nuclear Power Stations. Collectively, they have proved 36.4-40.0 m of unlithified sediments. Basal Gravels deposits are essentially shelly sandy gravel lags and have been proved in many boreholes penetrating the bedrock. They usually vary between 0.02 and 1.1 m in thickness, but can reach as much as 2.8 m (BH 28) in some of the deeper depressions carved into bedrock. Bivalves present, typify intertidal and subtidal zones to water depths of 80 m or more (chapter 3). The shells are also concentrated in centimetre thick seams of fine to medium shelly sandy lag-gravels which occur sporadically through out the succession with larger

121 fragments being preserved occasionally in the gravel seams. Broken shells are present throughout the sands and the interbedded brown and black (iron monosulphidic) clayey silt and silty clay succession.

FIRST-ORDER 14C DATING Four of the 14C dates out of five dates published by Greensmith and Gutmanis (1990) were done by conventional methods. The fifth was dated by the AMS method. First-order 14C Dating, developed at UCL initially for neotectonic research, is an economical and less time-consuming method than either of the above. Moreover, sample preparation does not involve expensive equipment, which hitherto has restricted the use of 14C dating in many geological problems. Standard laboratory equipment is used for the preparation of samples and cheap, quick and reliable “‘C ages up to about 12,000 yr BP have been produced primarily on marine shells (Vita-Finzi 1983). Despite its simplicity and cost-effectiveness, the results were consistent with conventional 14C dating, within the range of the last 7000 to 12,000 years. The upper limit is expected to extend to 21,000 years in future. The methodology was initially described by Vita-Finzi (1983) and has subsequendy been modified and improved (Vita-Finzi 1991); the principles were adapted mainly from methods used for biochemical (Passmann et al. 1956, Jeffay and Alvarez 1961, Schramm and Lombaert 1963)) and hydrogeological (Eichinger et al. 1980, Qureshi et al. 1989) problems.

SAMPLING Shells were obtained from both the Basal Gravels and from the middle of the sequence for dating by the First-Order 14C dating method. The depths of the samples ranged from -34.3 to -20.5 m OD. The mollusc shells were dominated by bivalves with a few gastropods and consisted of species found in intertidal to subtidal and offshore zones of the English Channel. The samples were recovered from two of the cores for which 14C dates were already available (31 and 102) and from cores 39 and 12. One sample was from the Basal Gravels, BH 102 at -34.3 m. The rest were from the shelly layers of the Middle Sands both at the base of the succession and from about halfway up the Middle Sands unit, BH 12 at 20.5 m OD.

122 CONTAMINATION The majority of the dating problems in shells are due to inferior stratigraphic control and unrecognized contamination. Close stratigraphic control can be ensured by careful sampling and a detailed knowledge of the emplacement of the datable material. Evidence for displacement of the shells from one depositional horizon to another can be recognized in the lithofacies or in the state of preservation of the shells, for example, the evidence of wear on the external surfaces. When a sample is contaminated by extraneous carbon its 14C/12C ratio changes by processes other than radioactive decay and hence the date becomes erroneous. In most cases the main contamination problems in shells are mineralogical and structural carbonate alteration, recrystallization and dissolution. Some shells contain both aragonite and calcite, but many shells are wholly aragonitic. Only a few are calcitic. Taylor et al. (1969) state that nacreous structures in bivalves are invariably aragonitic, and no example of calcitic structures is recorded from gastropods. A number of structural and chemical changes take place when occurs. According to Land (1967) the change from aragonite to calcite can take place by recrystallization, dissolution and reprecipitation and phase transformation. The last is uncontaminated, the second is totally contaminated and the openness of the system would determine the contamination of the first. Four main types of structure form in material that is or has been subjected to diagenetic effects. They are etching of the crystal surfaces (Alexandersson 1978, Walker 1979), formation of neomorphic aragonite (Purdy 1968), formation of neomorphic calcite (retaining fine-scale/coarse-scale primary structure), formation of drusy calcite (fine crystalline calcite changing to sparite or cryptocrystalline structure by crystal growth or replacement) and total alteration of the structure preserving only relics of aragonite (Walker 1979, Bathurst 1975). The last takes the form of individual third-order lamellae surrounded by neomorphic calcite. The effect of the different types of change on the radiocarbon date of a sample will largely depend on the openness of the system in which the diagenesis takes place. Some types of recrystallization are easier to eliminate than others.

123 The carbonate of shells can, and in some cases does recrystallize under normal field and/or laboratory conditions (Chappell and Polach 1972). When this occurs, it is often accompanied by an exchange of carbon with a different isotopic composition from that of the original shell; this leads to a false age measurement. On the other hand, shell alteration is detectable, particularly any alteration in mineralogy and crystal structure, by studying both modern and fossil shells using X-ray crystallography or infra-red spectroscopy and by studying shell structures in thin section and by scanning electron microscopy. The shells in the present study were cleaned by mechanical abrasion followed by mild leaching with dilute HC1 to remove the surface carbonate which might have exchanged carbon with the environment. Surface treatment will not remove internal contamination affecting the shell as a whole. For molluscs which deposit their carbonate as aragonite, recrystallization to calcite can readily be detected by X-ray diffraction (Vita- Finzi and Roberts 1984). Typical shell aragonitic and calcitic microstructures can be identified in thin section or by scanning electron microscopy (Walker 1979). In this study representative shell samples were checked for recrystallization and dissolution by means of both SEM and XRD. The shells showed pure aragonitic mineralogy (Fig. 4.1). Scanning electron micrographs of Nucula shells showed vertical stacks of lenticular unaltered nacreous ultrastructure and confirmed the absence of contamination (Plate 4.1).

ISOTOPIC FRACTIONATION The average isotopic composition of carbon compounds found in nature is about 99% 12C, 1% 13C and 10'10% 14C. If there is a change in the stable isotope ratio during the formation of a sample, there will be a change in the 12C/14C ratio of twice the amount. The dates in this study were normalised to the usual 513C value of -25%« for shells as is determined by radiocarbon laboratories.

SAMPLE PREPARATION FOR FIRST-ORDER 14C DATING The conventional techniques used for 14C dating are gas counting where 14C is measured as C02 or CH4-gas, and liquid scintillation counting where ,4C is counted as benzene (Polach and Stipp 1967, Tamers 1975). Benzene is prepared from acetylene by

124 Fig. 4.1 X-ray diffractograms of aragonitic shells from Dungeness.

c CD o CD CD

CD

30 24 26

° 20 CU Ka ° 20 CU catalytic trimerization. In the First-Order 14C dating method at UCL, however, following Eichinger et al. (1980), C02 produced from the sample was trapped in a 1:1 mixture of absorbing solution and scintillator. The main advantage of this method is the simplicity of the sample preparation. Following Vita-Finzi (1983,1991) 20 g of shell sample were hydrolysed with 50% HC1. The COz thus generated was used to flush the system. A mixture of 10 ml of Carbosorb (the trapping agent) and 5 ml of Permafluor V (scintillation mixture) was prepared in a standard 20 ml low potassium glass vial to which was screwed a stainless steel cap designed to facilitate the absorption. The whole system is then connected as shown in the Fig.4.2. The gas was dried by passing through a tube packed with desiccant magnesium perchlorate before being trapped in the vial. The rate of reaction was controlled by varying the speed of a magnetic stirrer and by limiting the flow of acid into the shell material. As the reaction continued the absorption of C02 in the Carbosorb was accompanied by a temperature increase of the vial. The total time taken for complete absorption was about 30 to 40 minutes. Once the saturation was reached, the temperature of the mixture began to fall making the surface of the vial cool and when weighed there was no further weight gain. This gain in weight was in each case about 1.26 g which agreed with the 1.3 g stated by the manufacturers to be the maximum absorption level. The remaining 5 ml of Permafluor was added to make the mixture 1:1 and the vial was sealed for counting.

MEASUREMENT OF 14C The method requires a measurement of the rate of disintegration of 14C in a standard sized sample. This count rate is then compared with that for the modem reference standard and also a background standard. The standard represents the initial 14C of all samples and the background radioactivity of the measurement system when no 14C is present. Samples and standards are counted sequentially in the same containers under the same conditions. The samples were counted in a multisample, refrigerated Packard Tri-carb 2260 XL Liquid Scintillation Counter for 1000 minutes. Low potassium glass diminished the background activity. Twenty (20) ml samples ensured the largest range of counts per minute (cpm) values between modem and background standards and by almost filling the

126 HCL 50%

MAGNESIUM PERCHLORATE DRIED MAR

PERMAFLUOR a n d (C) CARBOSORB CaCO

MAGNETIC STIRRER

Fig. 4.2 First-order 14C dating rig at UCL

127 vial reduced the problems of photomultiplier cross-talk. The 2260XL has a lower background activity and greater stability due to refrigeration than the Packard 1050 previously used at UCL.

AGE CALCULATION Three separate measurements are taken. These are the 14C/12C ratios or count rates for the sample, for the modem standard and for background. The background count rate is subtracted from the sample and modem standard count rates, and from these values the depletion of 14C of the sample with respect to the modem standard is calculated.

THE UNCERTAINTY OR ERROR TERMS Radioactive decay events occur randomly in time, so that measurements made to determine the decay rate can only estimate the true value within certain limits. Long counting times yield higher precision results because more atoms are detected. Most radiocarbon dates are quoted with a precision of one standard deviation, which implies a 68% probability that the true value lies between the +18 and -15 limits.

RESULTS The results are presented in Table 4.1. The dates obtained from other laboratories are also presented in Table 4.2 (Greensmith and Gutmanis 1990). All the dates were calibrated using the curves of Stuiver et a l (1986). The present set of dates confirmed the Late Holocene age of the lowest 14 m of the sequence of the boreholes sampled. They are between 560±95 yr BP (cal. age) and 3100±145 yr BP (cal. age) (shown as 561±94 yr BP and 3099±143 yr BP in Table 4.1 and Table 4.2).

,4C DATES IN THE ROMNEY MARSH AREA Several 14C dates are available in the area and they were related directly or indirectly to sea-level changes and in determining changes in palaeoenvironments. These are shown in Table 4.3. The deepest deposit dated in the area is from Tilling Green, Rye. Here the basal peat has been dated to 9565±120 yr BP (Welin et al. 1974). This and other old dates from the peat in the whole region represent the first colonisation of the land by plants in

128 Table 4.1: First-order 14C dates from Dungeness.

B o r e ­ D e p t h Material Age Calib.age# (yr L a b . h o l e b e l o w ( y r BP) N o . O D ( m ) BP)

3 1 3 2 .4 Natica alderi Nucula 1 3 5 0 ± 2 0 0 9 0 0 1 2 2 0 UCL nucleus, Nucula turgida, 2 1 8 Corbula gibba.

3 9 3 2 .9 Natica alderi,C.gibba, 1 6 0 0 1 2 5 0 11511251 UCL Trivia arctica, Nucula 2 1 9 turgida & Nassarius reticulatus

1 2 2 0 .5 Macoma balthica, 11001100 655194 UCL Mysella bidenta, Tellina 2 2 0 fabula, T.tenuis, Abra nitida, Scrobicularia plana & Ensis siliqua.

1 0 2 3 4 .3 Natica alderi, Spisula 3 0 0 0 1 1 5 0 2 7 5 5 1 1 7 4 UCL subtruncata, Chlamys 2 2 1 varia, Nassarius reticulatus, Pholadacea spp.& Modiolus phasiolinus.

1 0 2 3 2 .4 Acanthocardia 10001100 561194 UCL tuberculata & Natica 2 2 2 alderi.

# after Stuiver et al. 1 9 8 6

129 Table 4 .2 :14C dates from Dungeness (from Greensmith and Gutmanis 1990).

S a m p l e D e p t h Material Age 5 1 3 C C a l i b . L a b . N o . b e l o w (yr a g e # N o . O D ( m ) B P ) + (yr BP)

1 9 - 3 2 .1 Mactra 2890±80 0.53 2745± BETA corallina 6 5 1 8 6 3 0 &Scrobicularia plana

3 1 - 3 2 .5 Drifted wood 3140±80 -28.6 2911± HAR 1 0 4 5 8 6 1

3 1 - 3 3 . 6 M.corallina & 2 0 8 0 ± 1 6 4 7 ± BETA S.plana 1 1 0 1 4 3 2 0 6 6 7 / E T H 2 9 9 1 *

1 0 1 - 3 3 .8 Acanthocardia 1 3 7 0 ± 8 0 0 .2 4 9 1 3 ± BETA echinata 8 7 2 7 7 8 9

1 0 2 - 3 4 . 2 Ostrea edulis 3 2 7 0 ± 9 0 0 .8 7 3 0 9 9 ± BETA 1 4 3 2 7 7 9 0

+ ages normalized to 5l3C=-25% ? # after Stuiver et al. 1 9 8 6 * AM S determination

130 Table 4.3: Radiocarbon dates from Romney Marsh area (based on Waller et al. 1988, and Tooley and Switsur 1988).

L ocality Material Radiocarbon Date Lab. No. Wheelsgate, Shells from creek filling at c.+3m C1550±120 BP NPL25 Old Place, Icklesham Transition from peat to upper 1830180 BP SRR 2893 esturine deposit at -1.16m OD Scotney Court Farm. Lydd From 5cm thick peat layer 2050190 BP NPL 91 overlying clay with roots Panel Bridge, Pett Peat at +1.36m OD 2670180 BP SRR 2885 Scotney Court Farm, Lydd Roots in day c.+3.0m OD 27401400 BP NPL 92 Panel Bridge, Pett Peat at +0.38m OD 2980180 BP SRR2886 Higham Farm, Kenardington Wood in peat at c.+3m OD 3020194 BP NPL 23 Tishy's Sewer, Broomhill-A Silty Limus detrituosus 3060160 BP Q 2650 Tishy's Sewer, Broomhill-I Silty Limus detrituosus 3160160 BP Q 2652 Court Lodge, Old Romney Wood in peat at c.+3m OD 3340192 BP NPL 24 Tishy's Sewer, Broomhill-I Limus detrituosus with flints 3410160 BP Q 2651 Tishy's Sewer, Broomhill-A Silty Limus detrituosus 3520160 BP Q 2649 Blackwall Bridge, Wittersha Peat at c.-1.5m OD 35601100 BP IGS/C14/13 Brede Bridge, Brede Peat (Tilia decline) at +0.4m OD 3690170 BP SRR 2645 Panel Bridge, Pett Peat (Tilia decline) at -0.76m OD 3700190 BP SRR 2687 Roman fort, Wood in colluvium at 6.3m OD 4400150 BP SRR 2301 Blackwall Bridge, Wittersha Peal at c.-2.8m OD 48451100 BP IGS/C14/14 Panel Bridge, Pett Peat (Ulmus dedine) at -3.42m OD 5040180 BP SRR 2888 Horsemarsh Sewer Silty Limus detrituosus 5150170 BP Q 2648 Pett Level, Pett Wood from submerged forest at 52051105 BP IGS/C14/55 approx. OD Pett Level, Pett Peat from submerged forest at 53001100 BP IGS/C14/56 approx. OD Horsemarsh Sewer Silty Limus detrituosus 5500170 BP Q 2647 Panel Bridge, Pett Peat at -4.22m OD 5540180 BP SRR 2889 Brede Bridge, Brede Transition from hyposaline clay to 59701150 BP SRR 2646 peat at -5.35m OD Panel Bridge, Pett Peat al -6.14m OD 7000190 BP SRR 2890 Panel Bridge, Pett Peat at -7.61m OD 93801100 BP SRR 2891 Tilling Green, Rye Peat at -22.5m OD 95651120 BP IGS/C14/116 Panel Bridqe, Pett Peal at -8.42m OD 99601110 BP SRR 2892

131 response to a rise in ground water level due to warmer climate in the early Flandrian (Shephard-Thom 1975). This was followed by a thick sequence of inorganic deposition in the area related to rise in sea level. There are not many 14C dates available in the area for this period . At Horsemarsh Sewer, Kenardington, a date at about -3.42 m OD of 550Q±70 yr BP reflects a transgressive overlap, as organic silty sediments pass up into the clayey silt reflecting a brackish lagoon environment (Tooley and Switsur 1988).

DATES FROM THE MAIN MARSH PEAT 14C dating in conjunction with detailed palynological studies has provided evidence of not only the age of this main marsh peat but also of erosion and gaps during the peat deposition (Tooley and Switsur 1988, Waller et al. 1988) The marshland peat had long been considered to have formed in the post-Neolithic period, for a flint flake of Neolithic to early Iron-Age date was found in the submerged forest off Pett Level, a geographical continuation of the marshland peat. Later Welin et al. (1972) dated the forests at Pett Level to 53001100 and 52051100 yr BP. The date available from the Brede valley at -5.35 m OD of 59701150 yr BP marks the transition between the lower inorganic sediments and the upper peat here (Waller 1987). At -3.33 m OD, in the main peat bed, a regressive overlap has been dated to shortly before 5150170 yr BP. This has been corroborated by pollen data (Tooley and Switsur 1988). At Wittersham Bridge the peat was dated to 48451100 and 35601100 yr BP at two levels (Welin et al. 1971). At Pannel Bridge a peat level at -3.42 m OD with a date of 5040180 yr BP marks the Ulmus (elm) decline which has both environmental and as well as anthropogenic implications. An age of 3700190 yr BP was obtained for the Tilia decline (Waller 1987). Among the later dates of the peat of the main marshland include a specimen from a ditch-side, 0.46 m below the upper surface of the peat horizon and 1.83 m below the ground surface, 648 m S 10° W of Higham Farm, and a portion of a tree trunk trapped in the peat in a ditch-side 693 m E 42° S of Court Lodge were dated to 3020194 and 3340192 yrs BP respectively (Smart et a l 1966). At Tishy’s Sewer two dates at +0.8 m OD and at 0.9 m OD yielded ages of 3410160 BP (for regressive overlap) and 3160160 yr BP (transgressive overlap). Both these dates place the organic strata at the base of the low in the shingle in Flandrian

132 Chronozone III, and a post-elm decline date was inferred from the tree pollen assemblages. The main peat at Horsemarsh Sewer lies at altitudes from c. -3.3 m to +0.2 m OD, within the range of the altitudes for the main peat development in the valleys of the Pannel Sewer and the river Brede, Tillingham and Rother west of Walland Marsh and Pett Level recorded by Waller et al. (1988). A high rate of peat accumulation of 0.25 cm per year and a progressive plant evinced from the pollen assemblages have been suggested to be indicative of a rising relative sea level for this period (Tooley and Switsur 1988). Similarly the upper contact of the peat with the estuarine deposits is marked by one date of 1830±80 yr BP at Old Place, Icklesham at -1.16 m OD (Waller 1987). The main peat, ranging from about 6000 yr BP (Brede Bridge) to about 2000 yr BP (Brede Bridge and Lewes Brooks peat), has been interpreted by Shephard-Thom (1975) as occurring in a sheltered location about 5000 yr BP when the sea had risen to more or less its present position.

DATING OF THE BARRIER BEACHES Further west, along the south coast at Langney Point, Eastbourne, the barrier beaches have been ascribed to the early Flandrian (Jennings and Smyth 1982a). Near Dungeness, Eddison (1983a, 1983b) claimed that they formed prior to the formation of submerged forest at Pett and hence before 5300±100 yr BP (Welin et al. 1972). Green (1968) obtained two dates of 2740±400 yr BP and 2050±90 yr BP from roots in clay and an overlying thin peat respectively; the clay rests on the early shingle at Scotney Court and is correlated by them to the Blue Clay and the thin peat is correlated to the main peat of the marshland. Tooley and Switsur (1988) dated some of the early shingle to before 3410±60 yr BP. According to Greensmith and Gutmanis (1990) the barrier was established between 5000 and 3000 yr BP by the development of a SW-NE trending series of banks or barriers parallel to the palaeoshoreline and represented mainly by the Midley Sand. Initially the barrier was mainly sandy, and gravel accretion increased just before 3410160 yr BP.

IMPLICATION OF THE RECENT DATES AT DUNGENESS The 14C dates obtained from the area fall between 3100 to 560 yr BP. The Basal

133 Gravels are dated by First-order 14C dating to about 2755±175 cal. yr BP and the Middle Sands ranged between 1150±250 cal yr BP and 560±95 yr BP (shown as 2755±174 yr BP, 1151±251 yr BP and 561±94 yr BP in Table 4.1). The youngest date is from transported shells at -32.4 m OD whereas the date from -20.5 m OD is 655±95 cal. yr BP (655±94 yr BP in the Table 4.1).

134 Plate 4.1

SEM micrograph showing unaltered shell ultrastructure in Nucula sp.

135 CHAPTER FIVE PROVENANCE

INTRODUCTION Provenance is a term used to embrace all the factors relating to the production or birth of a sediment (Pettijohn 1975:484). Most often it refers to the source rocks from which the materials are derived. Each type of source rock tends to yield a distinctive suite of minerals (Table 5.1) which therefore constitute a guide to the character of that rock. Once the nature of the rock is known, the source region can be interpreted from the local geology of the area. The composition of a sediment, however, is not precisely that of the source region, as its composition has been altered by selective losses and enrichment, by abrasion during transport, by selective sorting during deposition and by alteration or solution during diagenesis after deposition. Fundamentally, then, the clastic sediments are the insoluble residues left after mechanical disintegration and chemical breakdown of some preexisting rocks or sediments. Provenance is deduced most readily from this residue, which constitutes their gravel composition and detrital mineralogy. Rock particles are considered to be very informative of all detrital components (Dickinson 1970). Sediments of the near-shore zone are known to have been derived from a number of different sources (Davis 1985b). Subaerial terrestrial hinterland provides a large quantity of sediment, much of which is carried seaward by rivers and eventually reaches the sea for dispersion to the beach and beyond. Another direct source of beach material is erosion of the coast itself. An important source of beach and near-shore material is the reworking and landward movement of sediment from the inner shelf. This is of particular significance during rises in sea level, as for instance during the Holocene transgression. Perhaps the most volumetrically significant immediate source of beach sediment is longshore transport in the surf and intertidal zone from nearby or distant sources depending on the wave regime and coastal environmental dynamics. Both light minerals such as quartz and feldspar and heavy detrital minerals have been used as guides to provenance (Pettijohn 1975:484-6). Quartz is ubiquitous and occurs in nearly all possible types of parent materials. Heavy minerals have been found exceptionally useful as clues to the nature of the source rocks as they are diagnostic of

136 Table 5.1: Detrital mineral suites characteristic of source rock types (from Pettijohn 1975).

Reworked sediments Barite Leucoxene Glauconite Rutile Quartz® (especially with worn Tourmaline, rounded overgrowths) Zircon, rounded Chert Quartzite fragments (orthoquartzite type) Low-rank metamorphic Slate and phyllite fragments Quartz and quartzite fragments Biotite and muscovite (metaquartzite type) Feldspars generally absent Tourmaline (small pale brown euhedra Leucoxene carbonaceous inclusions)

High-rank metamorphic Garnet Quartz (metamorphic variety) Hornblende (blue-green variety) Muscovite and biotite Kyanite Feldspar (acid plagioclase) Sillimanite Epidote Andalusite Zoisite Staurolite Magnetite

Acid igneous Apatite Zircon, euhedra Biotite Quartz (igneous variety) Hornblende Microcline Monazite Magnetite Muscovite Tourmaline, small pink euhedra Sphene

Basic igneous Anatase Leucoxene Augite Olivine Brookite Rutile Hypersthene Plagioclase, intermediate llmenite and magnetite Serpentine Chromite

Pegmatite Fluorite Muscovite Tourmaline, typically blue (indicolite) Topaz Garnet Albite Monazite Microcline

* Italicized species are more common.

137 a particular type of source rock even if present in small amounts as accessory minerals. Varietal features, such as inclusion, colour, form, and habit also serve as a guide to the source rock type. Krynine (1946) recognized 13 subspecies of tourmaline. Similarly, varieties of zircon have been used as guides to provenance. Clay minerals are also of value in provenance studies when they have not undergone any environmentally induced diagenetic changes as believed by Grim (1953). The clay mineralogy of a sediment may correspond rather closely with that generated in a given source region especially during the Quaternary (Bishop and Jones 1979). Reading provenance history especially in a nearshore region is a difficult task. Multiple sources and multiple cycles may have been involved. It may be difficult to separate the immediate source from the ultimate source of the sediment (Vita-Finzi 1971). In summary, all kinds of geologic evidence have to be put together to reach any sensible conclusion. The detailed sedimentological characters including the textural properties and detrital mineralogy of these sediments with a bearing on the source area will be discussed below.

TEXTURE

GRAIN-SIZE CHARACTER As we have seen, the sediments of Dungeness are predominantly composed of fine sand with a variable amount of silt, clay and medium to coarse sand and pebbles depending on sampling position. Sand content varies between 99.68 % to 45.85% (Table 2.1). Silt and clay content varies from 0.33% to 44.15%, but usually it is between 5 to 10 %. Most of the samples have a median in the fine sand range (2-3(|)) and are well sorted and most are symmetrically skewed. Denudation of local rocks both by river and by marine erosion is the most likely source for any coastal deposit. The Lower Cretaceous Hastings Beds underlie the Holocene sediments of Dungeness and are also exposed in the surrounding area forming the main catchment bedrocks for the fluvial system in the area. They thus probably supplied both the river alluvium and the coastal marine and perimarine elastics. The grain- size characteristics of the Wadhurst Clay, Ashdown Beds, Tunbridge Wells Sand and

138 Weald Clay noted in Bunin and Scaife (1988) are presented here in Table 5.2. Samples of the Hastings Beds Group (excluding gravels) have mean grain sizes ranging from fine sand to clays, and a more variable sorting, skewness and kurtosis. As the Dungeness and other recent sediments studied here are very similar in grain size to the arenaceous facies of these local Cretaceous bedrocks it is suggested here that most of the Holocene sediments were probably derived from these older rocks. There are two ways in which the detritals could have been brought to the area: either by the local rivers or from offshore areas during the Flandrian transgression and from . The river valley alluvial deposits in this area are much finer and consist mainly of coarse silt with only a limited admixture of fine sands (Burrin and Scaife 1988). Hence, the rivers such as the Rother, the Brede and the Tillingham supplied mainly silt to the coastal area. This relatively finer fraction may have been deposited in the low energy tidal flat or lagoon area on the landward side and some of it may have been dispersed into offshore areas where wave action and tidal currents are less effective, but these certainly did not transport the large proportion of fine sand of Dungeness. However, the limited amount of fine sands present in the river alluvium has been attributed to reworking of Hastings Beds sediments because of the presence of both the lower Cretaceous and modem pollen in the Rother valley sediments (Burrin and Scaife 1988). In view of the limited supply of sand by the rivers during the Holocene and the similarity of grain size properties between the Holocene sediments and the arenaceous facies of the older local Cretaceous rocks, it is suggested here that the Holocene sediments of the coastal region were largely derived from reworked Cretaceous bedrock offshore and inshore. As the solid geology of the floor of the English Channel in this region (Fig. 5.1) is more or less a continuation of that of the inland geology (Hamilton 1979, Smith 1989), there is little difference in sedimentology between present land and the sea. Marine and tidal erosion of offshore Cretaceous rocks during the Flandrian transgression must have produced a large amount of similar sediment debris. The fine sand in the estuarine region in this area has already been attributed by Burrin (1983) to sands from the nearshore region. The silt and clay fraction of the sediments at Dungeness shows some internal variation in terms of percentage of different size fractions present between the samples, but all the samples analysed had a significant and usually dominant peak in the coarse silt

139 Table 5.2: Comparison of grain size parameters of Holocene sediments and of local Lower Cretaceous Bedrocks (after Burrin and Scaife 1988).

Locality Sample Median/ Sorting Skew ness Kurtosis Mean In 0 Dungeness Borehole 12 2.40 - 2.72 VWS-WS NSym P-L Borehole 13 2.40 - 2.61 WS NSym P-M Borehole 16 2.58 - 2.88 WS-MS NSym M-VL Borehole 23 2.50 - 2.65 WS-MWS NSym-PSk P-VL Borehole 24 2.40 - 3.30 WS-PS NSk-PSk P-VL Borehole 26 2.60 - 3.85 WS-MS NSym P-VL Borehole 38 2.50 - 2.83 WS-PS NSym-VPSk P-L near Old Midley Church Midley Sand 2.30 VWS NSym L Lydd-on-Sea Modem Sand 2.70-3.00 VWS-WS NSym L Blue Sand 3.99 - 4.06 MS PSk L Royal Military Canal Blue Sand 4.10-4.18 MS PSk P Small Hythe Blue Clay 4.23 - 4.85 PS-VPS NSym L-VL Snargate Blue Clay 5.48 - 5.79 PS-VPS P-VPSK P-M Royal Military Canal Black and grey 3.84 - 3.88 ws-vws VNSk L Sands and Silts Rhee Wall Black and grey 4.06 MS NSym M Sands and Silts Royal Military Canal Grey Sand 3.26 - 4.28 MS NSym-VPSk P-M Small Hythe Grey Mottled Sands 5.97 VPS VPSk P Silts and Clays Royal Military Canal Grey Mottled Sands 4.63 - 5.59 PS VPSk P-VL Silts and Clays Snargate Grey Mottled Sands 4.86 PS VPSk M Silts and Clays Rother Valley Alluvial fill 5.00 - 7.00 PS-VPS PSk-VPSk L-VL High Wealden Bedrocks Wadhurst Clay 6.30 - 7.30 PS PSk-NSk VL High Wealden Bedrocks Tumbridge Wells Sand 2.90 - 3.80 MS-VPS NSk-NSym P-M (arenaceous facies) High Wealden Bedrocks Tumbridge Wells Sand 4.00 - 6.50 PS NSk-NSym M-VL (argillaceous facies) High Wealden Bedrocks Ashdown beds 2.90 -3.80 MS-VPS NSk-NSym P-M (arenaceous facies) High Wealden Bedrocks Ashdown beds 3.60 -7.10- MS-VPS NSk-Nsym P (argillaceous facies)

Keys: Sorting Skewness Kurtosis MS=Moderately PSk=Positively L=Leptokurtic PS=Poorly VPSk=Very positively VL=Very leptokurtic VPS=Very poorly NSym=Nearly symmetrical M=Mesokurtic WS=Well VNSk=Vey negatively P=Platykurtic VWS=Very well

140 >* 3 1 C o> 00 C CD o T“ o x z ® +-• .c«-* E a CO o E z o • V- ca> a c c CO c £ re O £ .c O CO .c 25 CO O) c 0 5 HI C a> LU £ C >*— o o <0 >» re 0 5 o o a> o s z a> 05 c 2 o o (0 o 3 o l_ a. CO (TJ TJ E c TJ re a > >* 05 O Q. O E a> 05 w TJ T~ rec in#c CO UL o

141 range i.e. at 5 to 6 to 6 grain size range, they are most probably either reworked Pleistocene deposits with some loessic material or sediments supplied by rivers through the lagoons, estuaries and tidal inlets.

SCANNING ELECTRON MICROSCOPY OF QUARTZ Sand samples examined from the Holocene sediments from the three sampling sites (borehole sands from Dungeness, Modem Sand at Lydd-on-Sea and Midley Sand from an old sand bank) showed various mechanical and chemical textural features already described in chapter 2. The surface features of the sands of the Wealden Beds showed an abundance of diagenetic modifications such as secondary growth of silica and etching and a paucity of mechanical features. The surface microtextures of the Holocene sediments broadly resemble sediments deposited in the present nearshore environment with moderate roundness and presence of mechanical "V"s and other small scale mechanical breakage such as conchoidal fractures, small fracture blocks as well as some chemically oriented "V"s and irregular solution and precipitation, the last two indicative of relatively low energy marine environment and exposure respectively (Krinsley and Doomkamp 1973). The Holocene sediment grains analysed here are generally rounded (66.6%) and about 40% grains are angular. In detail,

142 30-

2 0 -

30 - B

ac 0 2 0 - 1

10 -

30-

2 0 -

Phi

Fig. 5.2 Typical relative frequency distribution of valley fill and floodplain sediments of the southern England rivers (from Burrin 1981).

143 they have medium to low relief with many conchoidal fractures (60%-40%), large irregular blocky breakage (86.6%-46.6%), isolated "V" shaped blocks (80%-33%), mechanical "V"s mainly in projected surface (80%-46%), irregular pits (93%-60%), large flat areas (60%-26.6%), small conchoidal fractures (80%-33.3%), chemical oriented "V"s (53.3%-46.6%) and irregular solution and precipitation surfaces (86.6%-46.6%) with some upturned plates, parallel, radiating and arcuate steps, dish shaped fractures, sickle pits and different types of scratches (Plate 2.2 to 2.7). The sediments from Dungeness have more angular grains compared to the samples from the Midley Sand and display more large flat areas, irregular pits and chemical features. On the other hand Midley Sand quartz sand grains showed more various blocky topographies. Abundant mechanical "V"s indicate subaqueous transport and other nearshore depositional mechanisms. A few grains in each of the three samples also exhibit very high relief and angularity. A few grains plotted in the surface variability plot showed crystal growth and diagenetic etching similar to the surface texture of the grains from the Hastings Beds sands indicating some fresh Cretaceous sediment mixture (Plate 2.8). Reworking of these sediments during the Pleistocene period more than once is not ruled out considering the roundness achieved by a large proportion of grains; the extensive evidence of solution and precipitation is probably due to repeated subaerial exposure and/or alternating low energy deep marine water solution followed by subsequent exposure and silica precipitation. Abrasion by marine processes probably recurred during interglacials with raised sea levels, and by fluvial processes especially during lowered sea levels. The surface microtextures reflect several stages of reworking and probably multiple sources. Some of the grains show fresh fractures typical of recent littoral deposits. Quartz grains in the silts were also studied from the Dungeness cores. They are very angular and contain surface-adhering clay particles (Plate 2.9). Although many of the grains show a considerable degree of weathering and irregular silica precipitation and solution, the conchoidal fractures thought by Millar (1984) to indicate a windblown origin are still very clearly visible. This is in contrast to the microtextures of the silts studied from the sediments of the Hastings Beds succession beneath the Holocene sediments at Dungeness, which have completely different surface textures with evidence for both silica precipitation in the form of regular crystal growth, and chemical etching. These features probably indicate a low energy marine environment (Plate 2.9).

144 DETRITAL MINERALOGY At Dungeness, all the samples examined were of similar detrital mineralogy, with angular to rounded quartz as the major component (89 to 96.5 %). The rest includes glauconites (2 to 6 %), feldspars (traces to about 2.5 %) and chert (about 4.5 %) (Fig 2.5). This indicates that a large proportion of this sediment is derived from sedimentary rocks. The heavy minerals and detrital clay minerals were extracted and studied separately.

HEAVY MINERAL ANALYSES Heavy mineral analysis of sediments from three sampling localities gave further clues to provenance determination. The percentages of different heavy minerals separated from three different size fractions (2-3(j), 3 and 4) are different. Overall they contain predominantly stable mineral species such as zircon, tourmaline, garnet and rutile with some inclusions of less stable species such as staurolite, kyanite and almost unstable amphibole, epidote group of minerals and pyroxenes. Zircon is more concentrated in the finer fraction (3<})-4

145 Table 5.3: Comparison of heavy mineralogy of Dungeness sediments and of Lower Cretaceous Bedrocks (after Burrin and Scaife 1988). (/) * 2 ** UJ E JO 3 © CO O © a o © aj E N CO XI CD o « E 0 © © o k_ © l | tqoo too o o o o o t o o q t o CO o O O O O O O O O O IO CO O cococDcocviTtcviirir^ O O O O O O l O t O t cvicooicdh^T-^ior^o O O O o o o o o o io o o o fl ^CON O C j^ p afflN N O C CM CDN CO N to o o o n n o o o in o o in o o T— T— T— Cvi-r-Cvi-r-CDT— o o o o o o o o o d i v c o i o i ’ - r J o d i C v D c l O^ ^ - l O C O O C O ' t ^ O o o O O O n i o o o n i n i m n i n i o cviio’ CVJCVJCOM-M-CDCOCOCO t to o ooooooooo - T O o o O ^ ^ c © CO CO ~ i C 05 © O C - CVJ T- 1 t G G CO CVJ -T-CVJCVJCVJCOCOCO © }-’ C ^ ^ C\ -r- CD - r - \j C ^ ^ CD t 5 0 CVJ O JC V -C cvi r^- cd to" to co L O o LO O o O CO CO ^ n o o in ci co c\i ’ - i CO ^ CO T— CO t t O O O -COCO t- co o o n n o o i in o in o o in o o in T I OU O t U) O to O O U) O IO IT) “ T “ C\ CJ CO ~ T “ T CNJ \i C T“ T“ T“ - ci v v r c ci cvi cvi co rr cvi cviT-' cvi O t O C O O O O l O l O O O cvi cvi o o o cvi^rcvicDcvicvi^rcvicvicvi to to IO io O to to O io IO o o cd to io o o in o o o o in in in in in o o o o in o o 5 Oc' O0 ^ o cvicvi o' ^ IO co' CO05 05 O O l O l O O O t O O CM l O O cd 5 o 5 CM 05 io IO CO05 o IO o o CO 10.10IO io o o CVJCVJCO-^-^CDCOCOCOOO - COT- CVJ T- CO T- T- -i-T-^-CVJCVJCVJCOCOCOCO o o 146 © © 5 c 05 © ^ c © = to o o o to o o o CO 0 0 G ~ G ■sj- CO © co oi’ N

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' Holocene sediments are of different origin as the local Lower Cretaceous rocks do not contain these minerals in similar proportion to the Holocene sediments at Dungeness (Allen 1949, 1967). Also the presence of garnet up to about 36% suggests a different source than the local lower Cretaceous sediments. However, the Tertiary sedimentary rocks exposed extensively in the eastern English Channel and the southern North Sea contain large amounts of garnets and other metamorphic minerals in them. Morton (1989) in a report for British Geological survey showed the distribution of six important heavy minerals from 70 sea-bed samples on the UK continental shelf (Appendix 7). The two samples near Dungeness (50+00/508 and 50+00/518) had the maximum amount of zircon (up to 40.9%) and garnet (up to 37.5%) with a variable amount of epidote, hornblende, clinopyroxene and tourmaline. He suggested that the source of these were the Mesozoic and Tertiary sediments of southern Britain. For southern North Sea sediments he postulated a Scottish provenance with a homblende- epidote-gamet-clinopyroxene assemblage. One possibility is that the sediments at and around Dungeness were derived from the widespread mantle of Pleistocene drift deposits, perhaps a periglacial mixture of bedrock and windblown sediments (coversand and loess), incorporated into the coastal sediments either directly during the Flandrian transgression or recycled through the rivers flowing into the eastern English Channel. The alternative explanation is that the Pleistocene and early Holocene sediments of the southern North Sea, including some distributed along the present coastline of northern France, also contributed material to the Dungeness area during the late Holocene. Thus the H mineral group of Baak (1936), which is present in the northern French coast and is a mixture of northern Scandinavian facies and the Rhine-Meuse facies minerals characterised by an assemblage of gamet-epidote group-sassurite-homblende, augite, tourmaline and staurolite (Baak 1936) and Scottish derived sediments of Morton (1989) are also present in the Dungeness sediments. Heavy minerals of the silt fraction (4(J>-7(J)) from three samples (38/37.5; 38/36; 12/19.5) from Dungeness borehole cores and three samples from the Modem Sand samples were studied. Sample 38/36 and 12/19.5 showed the presence of garnet, amphibole (hornblende), epidote group and staurolite (although in very small quantities) and dominant zircon and rutile (Fig. 2.6.3). Other minerals present were garnet,

147 tourmaline, apatite, kyanite and some unidentifiable items, similar to the heavy mineral composition of fine sand fraction. Sample 38/37.5 has mainly zircon, rutile and tourmaline. The heavy mineral suites of the coarse silts at Dungeness were compared with the heavy minerals in the coarse silts of the river Rother valley sediments (Burrin and Scaife 1988, Millar 1984) (Table 5.4). Brickearth examined by Smart et al. (1966) also contains zircon, rutile, staurolite, hornblende, epidote, brown and green tourmaline, garnet, kyanite, sapphire, zoisite, hypersthene and rare alkali-amphiboles. These sediments as described before in the grain size description have a large proportion of windblown sediments in them. The alluvial coarse silts contain a lot of semistable and less stable mineral species such as staurolite (4.1 to 12.3%), epidote (up to 38%), hornblende (up to 21.9%) and chlorite (up to 2.8%). They were interpreted to be loessic as the loess deposits from Kent and Essex contain a large proportion of similar unstable heavy mineral species (Catt et al. 1974, Eden 1980). The presence of minerals such as hornblende, epidote group and staurolite in the silt fraction of Dungeness sediments supports the suggestion of the inclusion of these loessic sediments in the coastal sediments. The concentration of zircon in such proportions (up to 89%) in the finer sediments may be due to the sandy nature of the sediments. However, 38/36 with a relatively high silt+clay content (19.72%) contains more staurolite (4%), kyanite (3%), epidote (1%) and garnet (4%) than 12/19.5 with 2.68% silt+clay% . In the latter, staurolite, epidote and amphibole were not found. As the existing rivers do not supply a large amount of clastic sediment into the coastal region at present, it is difficult to estimate exactly how much it contributed in the past.

TOURMALINE VARIETIES Tourmaline coloured varieties were studied from four Dungeness borehole core samples (12/19.5, 38/15, 38/36 and 38/37.5) and one each from the Modem Sand and Midley Sand. Brown (about 63%) and green (about 23%) coloured tourmalines were predominant and blue, multicoloured, pink, yellow and fibrous varieties occurred in relatively smaller amounts (Fig. 2.7). Although tourmaline is typically a mineral of granite pegmatites and granites and appropriately occurs in abundance on the sediments near southwest England (Morton 1989); it is also commonly found in metamorphic and sedimentary rocks. The

148 Table 5.4: Comparison of heavy mineralogy of coarse silt fractions of Dungeness sediments and of the Rother Valley fill sediments (after Burrin and Scaife 1988, and Millar 1984). (fi * < T3 £ £ Ui O oc 3 >• 00 £ (ft a a CO o CO 0) CO « c 0 H o a N E a a c © 3 O 0 c fl> 3 E 0 o co E a a >_ o a> o o ■M-o a OOO O IO V C a> in o o o o c 00 r^ D OJ rc ^ o o o o v> C CD 0 c 0 3 o t o o o c D o r ^ o o o 0 0 C D ^ ' u S c D L O C n c D o d c v j o o i o) in cvi o o o o o O co co o co co T- T- 00O0)0)N0)(DC0lAS 00 D '- l CD in in o o o o — t - CMT- 00 — LO ''I" CD CO Q) O 1 "r. o ci ) c?> c\i cvi o) -" r^.‘ o ^ O O O (O S N(0 ) O O 0 N S 00 N CO CO O) O O o O ■<*; CO 0 "O "O "O T CC > CL CL £ CL £ £ £ £ £ C MC V JT -T - C V J t ^ CO CM O t t C t O) o) CD cn r : : r CD cn o) O) 0 0 0 >N O O O 0 (/>(/)(/> O M O C I V C - ) \ o i c i co id co in o' c\i

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CO magnesian tourmalines or dravites are found in metamorphic and metasomatic rocks and are usiially brown in colour (Deer et al. 1985:91). Schorl-elbaite series with high Fe- content usually belong to granitic rocks (Deer et al. 1985:95). They are normally black in colour and yellowish in thin section. The multi-coloured varieties are normally of hydrothermal origin. However, there is a complete range of composition between Mg-rich and Fe-rich tourmaline members, and it is difficult to interpret tourmaline on the basis of colour alone. Tourmaline is resistant to both mechanical abrasion and chemical corrosion and hence is seen in abundance in sedimentary rocks (Krynine 1946, Pettijohn 1975). In the lower Cretaceous Ashdown Sandstone Bed and Ashdown Pebble Bed, the tourmalines are either of mixed-colour or green (Allen 1949). Other tourmalines including blue, yellow, colourless and particoloured varieties were much less common. In contrast, the tourmalines of the Holocene sediments at Dungeness contain more brown coloured tourmalines compared to green tourmalines which were probably derived from other nearby sedimentary sources such as Cretaceous and Tertiary sediments. The surface microtexture and roundness seen in some tourmaline grains (Plate 2.14.c) by scanning electron microscopy indicate a sedimentary source for these tourmalines. Microprobe analyses of a few grains of polished tourmaline (Appendix 10) showed they had an Fe content of between 4.5 and 16.1% with an average 10%, whereas Mg content varied from 1% to 7.65%. Although these data are not fully reliable, as EDS system used for analyses could not analyse tourmaline completely because of the presence of boron and other light elements in its structure, they give some indication that the tourmaline in the Holocene sediment was not derived solely from granitic rocks. Moreover the tourmalines were probably recycled through the Cretaceous and Tertiary sediments.

GARNET GEOCHEMISTRY Several attempts have been made to relate garnet composition to parent rock lithology in broad terms (Wright 1938, Troger 1959, Sobolev 1965, Deer et al. 1985, Morton 1985b). Almandine-pyrope garnets are commonly from high-grade Ca-free metamorphic rocks, almandine-grossular garnets are either from medium grade amphibole schists or from skams and granites. Spessartine-rich garnets belong to metamorphic pelites, skams or granite skams. However, garnet is commonplace in sedimentary rocks

150 because of its resistance to diagenesis. Microprobe analysis of all the garnets reveals largely four end members, almandine, pyrope, grossular and spessartine. The samples are dominated by almandine-rich garnet with a low to medium amount of pyrope (<10%-40%) and grossular (<10%-50%). Almandine-pyropes are from high grade Ca-free metamorphic rocks, almandine-grossular from either medium grade amphibole schists or skams and granites (Deer et al. 1985). High grade metamoiphics outcropping on the Norwegian landmass and parts of the Orkney-Shetland Platform contain almandine garnets with varied amount of pyrope and grossular (Morton 1985b). The former have contributed much in the way of minerals to the Quaternary sediments of the southern North Sea and many of the garnets at Dungeness may have been derived indirectly from these sources. In addition there are some Mn rich and also some high grossular garnets in these sediments (Fig. 2.8-2.9). Spessartine-rich garnets belong to metamorphic pelites, skams or granite skams. Grossulars usually occur in thermally and regionally metamorphosed impure calcareous rocks. The Comubian and the Armorican massifs were the main source areas for the Mesozoic and Tertiary rocks of eastern England. They are now exposed in the south-west of England, Brittany and Normandy and are characterised by metasediments and intrusion of granites. Garnets derived from these sources are of mixed metamorphic and granitic origin. The shape and SEM surface texture of some of the Mn rich garnets displayed etching and abrasion features indicating recycling from sedimentary rocks rather than directly from metamorphic and granitic rocks.

SEM SURFACE MICROTEXTURE STUDY OF THE HEAVY MINERALS The shape and surface microtexture of some grains of zircon, tourmaline, garnet, staurolite and kyanite show that they have been under the influence of very high energy processes such as glacial action (Plate 2.13.b, 2.13.e). In contrast there are also very well rounded amphiboles, epidotes and tourmalines in the Dungeness sediments which could be windblown (Plate 2.14.C, Plate 2.14.e, Plate 2.15.b, Plate 2.15.e, Plate 2.15.f). The presence of etched and mamillated garnet, etched staurolite and kyanite and euhedral prismatic tourmaline and euhedral zircon indicates that they were probably reworked from older sedimentary rocks (Plate 2.13.b, c, d, f). Some of the mineral grains, however,

151 are abraded at their edges with small pits reflecting the subaqueous littoral environment (Plate 2.13.C, Plate 2.16.c).

GLAUCONITE ANALYSES The SEM study shows that with respect to moiphology the glauconites resemble those described by Odin and Matter (1981). XRD analysis shows distinct peaks at 10A with some extension in its left shoulder indicating limited expandable layer, typical of glauconites (McRae 1972). KzO content was determined by bulk sample analysis by ICP method (Appendix 11 and Table 5.5). Microprobe analysis of representative grains from 5 samples showed high K20 (up to about 9%), relatively high Si02, and low A120 3 and MgO. Many grains are oxidized at the surface and weathered and are therefore not likely to reveal true nature of the minerals in bulk analysis. The interior of the polished grains was analysed in microprobe analysis and the results proved that the glauconites are derived from both Cretaceous and Tertiary rocks as some of the grains, although fresh- looking and without any oxidation contain 5.56 % KzO and most others contain 7.1% to about 9.5 % of K20, and are hence of mixed source. McRae and Lambert (1968) have studied the mineralogy of the glauconitespresent in the Tertiary and Mesozoic rocks of southeast England. According to their studies Tertiary glauconites have low potassium content of about 5% , whereas Mesozoic glauconites have up to about 7.9% K20. Although the results obtained by McRae and Lambert (1968) cannot be compared directly with the glauconite analyses of the Dungeness sediments, the conclusion that the older Cretaceous glauconites are more mature and hence contain more K20 than the younger Tertiary glauconites applies to Dungeness Holocene glauconites. The variations in the K20 contents here therefore indicate mixed sources. These were probably derived from the solid Cretaceous rocks offshore and the hinterland, others being recycled from Pleistocene deposits either through the local fluvial system or the Holocene marine transgression. The probable source for the glauconite includes the near Top Ashdown Pebble Bed and more distant offshore Lower Greensands.

152 Table 5.5: Comparison of glauconlta analysis of Dunganass sadlmants with McRaa and Lambart'a (1968) glauconite analysis of Cretaceous and Tertiary sediments of .

L ocality Sample/Borehole Depth In m. Form ation C.E.C. K20% (m-eq/100gm of glauconite) (Cretaceous glauconites)

Copt Point, 1 Chloritic Marl 11.00 7.90 Wrotham 2 Gault 15.00 7.10 Great Chart, Ashford 3 Sandgate beds(L.Greensand) 19.00 6.60 Chilmingt on Green, Ashford 4 Hythe beds(L.Greensand) 20.00 6.70 Boughton Quarries, 5 Hythe Beds 20.00 6.70 Smeeth, Ashford 6 Gault 20.00 6.70 Brabourne Lees, Ashford 7 Folkestone Beds(L.Greensani 25.00 6.60 East , Folkestone 8 Folkestone(L.Greensand) 24.00 6.10 Boughton Quarries, Maidstone 9 Hythe Beds(L. Greens and) 26.00 5.80 Brabourne Lees, Ashford 10 Folkestone Beds(L.Greensam 28.00 5.50

(Tertiary Glauconites)

Sturry, 1 1 Woolwich Beds 26.00 5.80 Sturry, Canterbury 12 Woolwich Beds 27.00 5.80 Sturry, Canterbury 13 Old haven Beds 30.00 5.30 Sturry, Canterbury 14 London Clay (basal) 30.00 4.10 Dane John Quarry, Canterbury 15 Thanet Sands (basal) 35.00 4.50

(Holocene Glauconites from joastal sediments) !

Dungeness 13 19.50 (a) 21.85 4.65 13 19.50 (d) 15.98 4.28 24 22.50 (b) 4.93 24 22.50 (C) 31.90 4.93 24 22.50 (d) 18.60 5.51 24 35.50 (d) 23.59 4.02 38 24.00 (d) 24.46 5.11 Lydd-on-Sea N1 (modern sand) surface 12.68 3.99 N2 (modem sand) surface 1.55

(K20 content from Microprob e Analysis)

Dungeness 13 19.50 5.56 13 19.50 7.80 13 19.50 8.50 24 22.50 6.90 24 22.50 7.30 24 22.50 9.20 24 35.50 5.18 24 35.50 6.67 24 35.50 7.66 38 24.00 6.90 38 24.00 8.75 38 24.00 7.30 Lydd-on-Sea N1 (modern sand surface 9.75 N1 (modern sand; surface 7.03 N1 (modern sand) surface 3.87

Note : 1. a = >2.5 0 fraction ; b = >3 0 fraction ; c = 30-40 fraction ; d = whole sample 2. Three typical glauconite microprobe analyses for K20 are shown In each sample.

153 Holocene greenish sediments of the Rother valley (Burrin and Scaife 1988), the filled palaeovalleys on the floor of the English Channel (Destombes et al. 1975), the Hastings Beds and the local windblown deposits, namely the brickearth also contain a lot of glauconite and may also have contributed glauconite to the Holocene sediments in the region.

CLAY MINERALOGY The clay minerals present in the fine sediments at Dungeness are mainly illite (about 64.17 %), kaolinite (about 14.4 %), some mixed clay (about 20.18 %) and very little chlorite. The adjacent Wealden and Upper Purbeck strata are reported to contain kaolinite and illite and a quantity of a clay mineral which, being collapsible to 10A after heating to 375°C, is one of the following: a)illite-smectite, where a discernible peak forms around 17 A upon glycolation, b)degraded illite, where a wide range of spacings up to 30A is formed after glycolation, and c)vermiculite, which has a 14A air-dried peak which is unaffected by glycolation (Tank 1962, Perrin 1971, Lake and Shephard-Thom 1987). The Purbeck Beds and the Ashdown Beds are dominated throughout by kaolinite and illite. Randomly interstratified illite-smectite is common in the uppermost Purbeck Beds and above the Cliff End Sandstone. Chlorite is confined to minor amounts in the beds immediately above the Cinder Bed. In general the clays of the Hastings Beds are disordered kaolinite, illite and a chloride mineral (Butterworth and Honeybome 1952) and usually contain more kaolinite. Degraded illite and vermiculite are also present. The Weald Clay consists of a mixture of illite and disordered kaolinite and illite is generally dominant in the Gault (Keeling 1963). The clay fraction of six samples of Pleistocene brickearth, thought to be a reworked loessic sediment, were found to contain an abundant clay mineral with 10A basal spacing, probably illite or glauconite, kaolin and an appreciable amount of quartz. A weak line at 14A, which persisted after heating to 550°C for two hours, has been identified as being due to chlorite (Smart et al. 1966). The clay mineralogy of the finer fraction of the Dungeness sediments is very similar to the clay mineralogy of the brickearth, which is a reworked loess. Nevertheless the Weald Clay and the Gault which occur in nearby areas including the offshore areas also contain similar clay minerals with high proportion of illite and kaolinite. Thus it is

154 very difficult to determine the actual source of these clay minerals here. The SEM surface texture of the coarse silt fraction and the grain size characteristics of the silt fraction described above indicate a loessic origin for some of the finer fraction but not all of it.

PROVENANCE The detrital components of the Holocene sediments from Dungeness described above indicate that the constituents of the Dungeness sediments were derived from multiple sources and that the three main probable sources are the local Cretaceous and Tertiary sedimentary rocks, Pleistocene reworked loessic and other aeolian sediments, and Pleistocene river and glacial outwash sediments from the southern North Sea. The nature and mechanism of distribution of these sediments during the Quaternary are discussed below.

INLAND AREAS ADJACENT TO DUNGENESS Inland, as described in the various local memoirs of the British Geological Survey (Shephard Thom et al. 1966, Smart et a l 1966, Lake and Shephard-Thom 1987) and regional geological reports (Gallois 1965), the Pleistocene deposits are mainly two types: widespread solifluction or Head deposits formed by local ice fields or permanent snow occupying the higher grounds during periglacial cold conditions and silty loams of a windblown loessic nature (Pitcher et al. 1954). The latter were deposited on the slopes and fills of many of the valleys and are typically of uniform texture and dark brown in colour and are normally friable and sandy. Every gradation of grain size exists within them and they are commonly referred to as brickearth. In the thicker and more extensive spreads the unweathered brickearths are calcareous. In places they are very similar to the deeply weathered bedrock particularly when it is silty, because weakly consolidated silts and poorly sorted arenaceous deposits seem to be susceptible to destructuring by permafrost. All gradations exist between in-situ deposits and their soliflucted derivatives. The products of early Pleistocene events were largely reworked during subsequent periods of periglacial, fluvial or marine activities, more so in case of the head and other arenaceous and argillaceous soliflucted material so that little of these deposits survived in place. During relatively warmer interglacial periods, however, sea level was higher as a

155 consequence of the waning of the polar ice-sheets. To the west, the Brighton at about +7.5 m OD at Black Rock is generally believed to be of Ipswichian Interglacial age (West 1972). At Cliff End, an elevated with the floor at +18.2 m and yielding signs of Mesolithic occupation (Palmer 1972, 1977) has provided evidence for the position of an early Post-Glacial shoreline (Lake and Shephaid-Thom 1987). During interglacial periods the rivers aggraded their lower reaches, filling the "buried valleys", and laid down spreads of gravels in their floodplains. Surviving remnants of terrace gravels in the Brede and Tillingham valley lie at +15 to +18 m OD (7 to 10 m above the alluvium); they represent one period of aggradation and are thought to belong to the Ipswichian. The gravels are of local origin. Their main components are pebbles of sandstone and siltstone of Wealden Beds set in a ferruginous sandy matrix.

THE ENGLISH CHANNEL AND THE SOUTHERN NORTH SEA The floor of the English Channel and southern North Sea continued to be subaerially modified until shortly after 10,000 yr BP (Jelgersma 1979)), when they were rapidly submerged by the Flandrian transgression, the sea penetrating the of Dover by 9600 yr BP and linking up with the North Sea by 8600 yr BP (D’Olier 1972), and by 8300 yr BP the whole area was submerged and a complex tidal system was operating as a result (Jansen et al. 1979). As a direct consequence of the postglacial rise in sea level, a large volume of detritus has been reworked by marine processes. Much of this material may have been derived from preexisting fluvial, fluvio-glacial and periglacially reworked deposits on the floor of the Channel and the North Sea including the aeolian deposits. The origin of these sediments during the Pleistocene Period is not known in detail. Although in general terms the floor of the Channel is flat, there is a complex anastomosing pattern of infilled and partially infilled valleys and deeps in the Dover Straits and eastern English Channel extending and connecting with a larger valley further west, many cutting more than 30 m into the general level of the sea floor in the central and eastern province of the Channel (Destombes et al. 1975, Dingwall 1975) (Fig. 5.3). The periphery of this system shows clear links to the present day rivers in southern England and northern France; however, for the main part of the Channel, the system contrasts markedly with those presently on land. The origin of these palaeovalley systems has been ascribed to glacial, fluvio-glacial, fluvial, tidal current scouring and catastrophic

156 so* ->FOSSE'-- pe IA~<- CH ague ZT ^

^fossE oe L'iLE VIERGE LEGEND FOSSE DOUESSANT, d e e p s

C Z -~ J infilled channels

» C l i f f S

Fig. 5.3 The deeps and infilled channels of the English Channel (from Hamilton 1979)

157 processes (Hamilton and Smith 1972, Destombes e ta l 1975, Dingwall 1975, Smith 1985, 1989). Destombes et al., (1975) postulated a glacial origin for these deeps which is in accordance with the English Channel glaciation hypothesis of Kellaway et a l (1975). Recently a catastrophic flood origin has been suggested by Smith (1985, 1989). Dingwall (1975) favoured a mid-Tertiary fluvial origin and later reworked by tidal currents for these system. Destombes et a l (1975) found evidence of a Brorup age (50,000 yr BP) in the sediments of the channel infillings in the Dover Straits (known as the Fosse Dangeard) area. The palaeovalley system on the eastern English Channel has been connected to a much larger Seine-Solent River system further west. Both the Thames and Rhine systems flowed into English Channel on many occasions during the Pleistocene. At other times they flowed into the ice-ponded lakes in the Southern North Sea Basin (Prentice 1972a). Large volumes of water periodically escaped this lake towards the south along the line of the Straits of Dover and perhaps carried sediments not only of fluvial but also of glacial and aeolian coversand origin. Following the withdrawal of the ice-sheets during the early Postglacial, these rivers flowed through the Straits of Dover southwards (Baak 1936, Jelgersma 1961, 1979, D ’Olier 1972, 1975, Oele and Schiittenhelm 1979) and must have deposited a large amount of sediment on the floor of the Channel. During the ensuing Flandrian transgression, waves and currents redistributed this material to various coastal areas along with sediments derived from deep scouring of the solid floor of the channel (Stride 1963). At present both the UK coast of the southern North Sea and the English Channel suffer from strong tidal currents (Fig. 5.4) with bedforms indicating the direction of sediment transport (Fig. 5.5) as well as the current strength (Howarth 1982, Johnson et al. 1982). The floor is covered with sand and gravel (Fig. 5.6). In fact solid rock is exposed at several places on the English Channel floor. The Pleistocene deposits and local bedrocks were eroded and modified into typical bedforms according to the current strength. Baak (1936) studied the heavy mineral content of the southern North Sea. According to him H and NH groups, containing many unstable species such as epidote, amphibole, pyroxene and garnet, occur mainly along the east coast of the southern North Sea. He was of opinion that the same groups could be traced southwards along the French coast as far south and west as Normandy. Kruit (1963) concluded that these are Rhine-

158 Fig. 5.4 Outline map of mean spring near-surface tidal current strength on the continental shelf around the British Isles (from Howarth 1982)

159 •** bed-load parting net sand transport directions dommantlY tidal dominantly non-tidal local direction on shed edge banks net direction unknown

200km

Fig. 5.5 Net sand transport directions on the continental shelf around the British Isles (from Johnson et al. 1982)

160 Key Mud

Sand, with ridges os shown Gravel

Fig. 5.6 Map showing the distribution of sediment types off the southern coast of England (from Selley 1988)

161 Meuse facies. However, Jansen et al. (1979) suggested that mineralogical differences between sands of different origin along the Dutch coast are apparent only in the coarse fraction. Baak pointed to the presence of a mixture of fluvioglacial Fenno-Scandinevian material and Pleistocene Rhine sand in the northern coast of France, although the coarse deposits there are of local origin. As neither the Rhine nor the Thames are at present important supplier of sand to the North Sea (Terwindt et a l 1963, Prentice et al. 1969), this sand reached the area in early Holocene times. After passing through the Straits of Dover 9600 yr BP, the sediments moved northwards. Kirby and Oele (1975) noted a southerly provenance for the gravel fraction of some early Holocene deposits of the Fairy Bank and Sandettie area. This perhaps contributed the early sediments near Dungeness. Smith (1985) proposed that the more recent transient features of the Channel floor such as sand banks, sand ribbons and sand waves and a thin wedge of superficial sediments are a pattern which postdate the palaeovalley pattern and hence were deposited after the Dover Straits opened. Superficial deposits on the floor of the Channel are typically of shelly sand with a variable content of gravel (Fig. 5.6) made up of flint, chert, sandstone, vein-quartz, rare schist and granite (Larsonneur et al. 1979). Extensive studies have been made of the bedforms and internal structure of sediments around the British Isles and these have been related to tidal and wave regimes and patterns of transport (Stride 1963, 1982). Beg (1967) showed that the Goodwin Sands and the central parts of the Thames estuary had a similar heavy mineral suite as the H and NH group of Baak and suggested that these sediments constituted the latest addition to the sedimentary complex of the Thames Estuary. Prentice (1972a) proposed that the decline in the coastal accretion of the Netherland coast might have been associated with a leakage of sand southwards. Stride (1963) has shown clearly a sand stream which moves southwards along the English shore of the southern North Sea. The present tidal regime in the Straits of Dover is very complex, being influenced by water movements in both the English Channel and the Southern North Sea. Kirby and Oele (1975) have found that south-facing asymmetrical sand waves to the west of Sandettie Bank and the Col are potentially mobile and moving southwards. The Corallian Crag material spread southwards in the Outer Gabbard stream. The presence of the relatively unstable heavy minerals in the Goodwin Sands and the English Channel is also probably the result of a southward movement of the sea bed sediments of the southern North Sea.

162 By about 5000 to 6000 yr BP the sea had almost reached its present position (Kidson and Hey worth 1978) and several coastal bars and spits originated from the reworked sediments. Erosion increased along pans of the coast, and so supply of sediments also increased. Studies of the directional bedforms (Johnson et al 1982) of the sea bed sediments suggest that there is a bedload convergence in the Straits of Dover (Fig. 5.6). The net tidal transport in the eastern English Channel at present is entirely eastward with a bedload parting occurring along the Isle of Wight-Cherbourg line. In the western Channel the net tidal transport is westwards, but with subordinate eastward movement locally. In the Straits of Dover strong tidal currents (in the order of 75-125 cm/s) prevent the sand from being deposited on largely bare Chalk floor but does not preclude the transport of sediment through it. Heavy mineral study of seabed sediments by Morton (1989) shows the presence of presumably northern derived minerals such as garnet, amphibole, epidote and pyroxenes in the English Channel. The present study indicates that this group of sediments is also present in the coastal sediments of Dungeness. These sediments especially at Dungeness are however mixed with not only the local tidally scoured bed rock sediments both from offshore and alongshore transport, but also with the river-borne fine-grained loessic sediments. During storms, sands were thrown onto fishing vessels being eroded from the seafloor at Dogger Bank (Stride 1973). Storms are known to have removed fine grained material up to about 200-300 pm from the southern North Sea and the English Channel floor (Eisma et al. 1979, Hamilton 1979). Part of these sediments from southern North Sea may have moved south by superimposed unidirectional currents once they had been entrapped by storms.

SUMMARY The heavy minerals of the sediments at and around Dungeness clearly show a mixed origin. Much of the coarse silt grade sediments containing a loessic component must have been derived from the rivers flowing into the area. The reworked loessic sediments have a dominant peak in the coarse silt range and contain unstable minerals such as epidote, amphibole and staurolite. Size analysis of the fine grained sediments from Dungeness show that, although it forms a very small proportion of the sediment, there is

163 a clear peak in the frequency curve in the coarse silt range (Fig. 2.3). The heavy minerals of the silt fraction and fine sand fraction also contain semistable and unstable heavy minerals such as epidote, amphibole, pyroxene, staurolite and kyanite. Recently loess and loessic deposits have been identified widely in southeast England. River alluvium often comprises a mixture of loessic materials and local sedimentary rocks, the mixing being caused by intense periglacial weathering during the Pleistocene period. As regards the finer facies in the study area therefore, the most likely source is loess introduced by fluvial action, although the argillaceous sediments of local bed rock of Cretaceous age may have contributed some of the material. These three different groups of samples (Midley Sand, Modem Sand and Dungeness sediments) clearly belong to the same or similar sources as demonstrated by similar heavy mineralogy, tourmaline colour varieties, and garnet geochemistry. If the Midley Sand is considered as an early barrier, it must have derived much of its sediment from the floor of the English Channel during the Flandrian transgression, with the sediment movement northwards after the opening of the Straits of Dover. In the beginning sediments were deposited in the form of tidal flats and sand banks. Most probably the Midley Sand was deposited in a beach environment. This is indicated by the very well sorted nature of these sediments and the blocky SEM microtextures and abundant mechanical V s on them. Also when the Midley Sand formed probably as a barrier, coastal erosion and longshore transport must have been already established. Owing to a change in the dynamics of water movement in the English Channel and southern North Sea, the sediments which had originally moved north in the early Holocene now were transported south in parts of the southern North Sea, and provided much sediment to the sandy facies at Dungeness. In the eastern English Channel, however, the sediments still move eastwards. A sand wave offshore near Rye has been identified by Stride (1963) to be moving east towards Dungeness. A large proportion of the sand, however, may have been reworked from the Midley Sand itself by erosion and transport offshore of nearshore sediments. This is indicated by the similarity not only with regard to the detrital mineralogy between all these sediments, but also from grain size and surface microfeature characteristics similarities. Dungeness sediments were therefore derived from this barrier system through shoreface erosion and mechanism, from offshore as well as from alongshore supply of sediments (Fig. 5.7). The presence of relatively more quartz grains

164 with large flat surfaces, irregular solution and precipitation, relatively more edge abrasion and elongate shape (Plate 2.7.e) lend some support to the view that they may have been modified by tidal inlet transport as these features have been identified more in inlet grains by Williams and Thomas (1989) in Fire Island, New York. The relatively coarse facies (fine sands) landwards in the marshlands and in the lower reaches of the Rother valley may also have been supplied from the sea by nearshore marine activities as was suggested by Bunin and Scaife (1988) earlier. There are however, differences in grain size and sorting which suggest that they were deposited in different environments. The similarities in mineralogy of different plausible sources such as land derived loessic and other head deposits, river deposits and marine-derived ancient fluvial and glacial sediments, make it difficult to quantify the contribution of the different sources. Moreover, if they all have been weathered and reworked during several stages of periglacial period during the Quaternary, it will be difficult to distinguish between them. Probably all these sources contributed in part to the coastal sediments at Dungeness. Nonetheless the Midley Sand was most probably deposited much earlier than the sands at Dungeness.

165 a) 1 r “U o o c g a> •Hg -C OJC o <-*- O a L. T> ^ ,OT a O J= O) d) O to CX c ^ ^ c O £ I 1 + <1> 2 ° > . o > r ^ U E ^__ o o ^ 0) “O . Q SJ c o LT) JQ X) O M nO / Z Z s ' ggga Ov / / i / ) S / ( / / > / r* \ / ' 0 3 V / ( \ N y I \ / \ \ / \ \ \ N I \ \ \ \' "V rI— r>\ I \ SO*"' \ \ \ \ \ \ \ \ \ \ I \ \ > \ 4 \ ) i 1 \\'_ y }oJi m \\ I \ \ .::::::::.oii— \ \ X-f co \ /’ J i M llllllillllfc:^ ^ ^ LS

......

«■ % % WW$ w h Ml N 1js NM M Fig. 5.7 Fig. 5.7 Generalised palaeogeography of Dungeness c. 3000 yr BP and directions of sediment i i m * transport (after Greensmith and Gutmanis 1990)

166 CHAPTER SIX DEPOSITIONAL ENVIRONMENTS

INTRODUCTION Clastic deposits record not only their predepositional characters, that is their provenance and transportation history, but also their depositional environments. A sedimentary environment is defined, according to Pettijohn (1975), by a particular set of physical and chemical variables that correspond to a geomorphic unit of stated size and shape. However, precise identification of an environment cannot be done solely on the bases of the physical, chemical, and biological characters of a sedimentary unit. The mineralogical and physical properties of sediments overlap between environments, and fossils may be displaced, so giving a misleading impression of the exact environment of deposition. On the other hand, recent depositional sequences show that the subdivisions of major sedimentary environments are organized in regular pattern, particularly well observed in vertical sequences. The principle encompassed by Walther’s Law of Facies, is that facies which lie laterally close to each other will be preserved vertically one over the other. Formation of a vertical sequence is the result of sedimentary processes, for example progradation, transgression, regression and so on. During these processes lateral migration of adjacent facies generates sequences of subfacies, the latter being characteristic of different depositional environments. For example a prograding coastline produces a coarsening-upward sequence, whereas a shallowing channel as well as a transgressive sea will produce a fining-upward sequence. Recognition of such patterns in vertical profile enables us to reconstruct detailed environments. Thus, now-a-days environmental reconstruction is more and more carried out by examining both the physical, chemical and biological characteristics of individual units as well as their arrangement in vertical profile, that is to say in stratigraphic section as well as with reference to the geometry of the sedimentary bodies. Individual units or facies are identified by typical texture, structure and composition. Their vertical and lateral arrangement are studied by a three-dimensional approach which considers their vertical succession and lateral extension, and is usually obtained from lithological logs and geophysical data. In this chapter the probable environments of deposition of the sediments at

167 Dungeness will be discussed by taking into account the the vertical and lateral distribution of lithology, fauna and 14C dates. The other relevant variables which may have affected such as regional setting, sea level position, climate and related processes will also be discussed in brief. The coastline of southeast England is variably influenced by geological structure, lithology, and the marine energy input into the area. As a result, varieties of coastal geomorphological features such as cliffs, bays, estuaries and extensive level spreads of recently deposited sand and shingle are produced (Fig. 6.1) Among them are extensive low-lying areas associated with river estuaries and areas of intertidal flat and quiet water condition located behind or within the protective influence of spits and related barrier features. This apron of low lying Flandrian estuarine and marine deposits merge inland with the present alluvial flood-plains of the rivers. Detailed studies of the alluvium of Sussex and Wealden rivers have been achieved (Jones 1971, Thorley 1971, Burrin and Scaife 1984). Several shingle and sand spits and barrier structures whose size and shape vary in response to energy input and coastal configuration include major structures like Chesil Beach, Hurst Castle Spit, Dungeness and Langney Point, minor spits across the mouth of the river Adur and Ouse, recurved spits on the Solent at Hurst Castle and Calshot, double spits at the entrance of Poole harbour, Newton Bay, Christchurch Bay, Pagham Harbour, and flanking various inlets near Portsmouth, the parallel structures which caused the blocking and sedimentation of Sandwich Bay and many more small spits and bars. These have been described in terms of their and manner of sedimentation (Kidson 1961, 1963, Hardy 1964, Steers 1964, 1981, Evans 1965, Hey 1967, King 1972, Prentice 1972b, Greensmith and Tucker 1971, Straw and Clayton 1979, Jones 1981, Jennings and Smyth 1985). Various processes responsible for the formation and evolution of such structures such as longshore drift, landward barrier migration, local reversed drifting or counter drifting, sea level changes and coastal dynamics such as wave and tide regime as well as combination of different processes (Robinson and Cloet 1953) have been proposed. Along the eastern coast of southeast England, sediment movement is south and southwestward, but is interrupted at a number of places i.e. the Wash and Thames estuary which act as sediment traps (Stride 1973, Jansen et al. 1979). On the south coast the

168 Areas of Holocene marine / eatuarine sedimentation., lea surfaces close to present M.H.W.S.T. Zones of nearshore accretion .. / • > ■ ; ESS Shingle accumulation Cliffs formed in ‘soft rocks', <25 m. 0.0 Cliffs formed in 'hard' rocks Sand Dunes Land slide features Sand ridges Sea - floor hollows

Occurrence of gravel Fanland Clay & clayey sands a

Principal sediment transport paths

East Anoha

LONDON f

The Weald

Chesil L Beach

"Fig. 6.1 Sketch map of coast of south and southeast England showing various shingle barriers (from Devoy 1982).

169 sediment movement in the littoral zone is essentially eastward (Stride 1963, Johnson et al. 1982, Devoy 1982) and Dungeness is acting as a sediment trap (Jenning and Smyth 1990, Nicholls 1990). Although much work has been done on the morphological evolution of these depositional features, only few attempts have been made to study subsurface information in detail. Thus, their detailed environment of deposition, the mechanism of their evolution and their relationship to the wider framework of coastal environments are still incomplete. Some of the studies which deal with the deep Holocene succession under such coastal shingle structure include the study of Jennings and Smyth (1982a, 1982b, 1985, 1987) on the coastal deposits at Langney Point. The coarsening-upwards sequence here has been related to general increase in the energy of the coastal system over time at Langney Point. Moreover, this occurred as the rate of Flandrian sea-level rise decreased. The estuarine conditions established after 8770±50 BP continued uninterrupted during the initial rapid rate of sea-level rise and transition to a high energy environment occurred during the period of slower sea-level rise. During the Atlantic and Subboreal period coastal barrier deposits developed in many other nearby areas. In the lower reaches of the river valleys, peat grew as a result of sheltered condition provided by these coastal barriers. The deposits recorded in the boreholes at Dungeness are relatively young as shown by the 14C dates of between 560±95 and 3100±145 cal. yr BP, listed in chapter 4. The dates were obtained from mixed shell assemblages containing both shallow and deep water species. During the period when the sediments at Dungeness were deposited the contemporary regional sea-level position was about -8 m to +2 m OD (Fig. 6.2). The 14C dates obtained from Romney Marsh are broadly consistent with this. When plotted together with the 14C dates from Romney Marsh in a regional sea-level curve, the 14C dates obtained from Dungeness show no relation to the sea level and are much lower than the rest (Fig. 6.3). The transported and mixed nature of the shell assemblage, the brown coating on some of the shells, and the lithology of the sediments suggest that shallow water shells were transported and deposited offshore. Climatic changes in long and short periodic cycles are known (Lamb 1977). Climatic changes in historical times are also reported (Lamb 1984, Jelgersma 1990).

170 5 5 6 8 1/2- LIFE 5 7 3 0 1/2- LIFE

Im sl

LU > LU

30 < LU CO

6 0 < 20 LEGEND LU

WORLDWIDE HOLOCENE EUSTATIC I— SEA-LEVEL INTERPRETATIONS UJ 9 0 LU FAIRBRIDGE , 1961 30 CO LU JELGERSMA , 1961,1966 CC CL — SHEPARD , 1963 120 - o CURRAY , 1965 (Mean) 4 0

MILLIMAN 8 EMERY , 1968 LU 150 CD MORNER , 1969

BLOOM , 1970 CL TERS , 1973 LU 180 C l

6 0

Fig. 6.2 Worldwide Holocene eustatic sea-level interpretations (from Kraft and Chrzastowski 1985)

171 RADIOCARBON AGE (BP)

JO. 000 9.000 8.000 7.000 6.000 5,000 4.000 3.000 3.000 1.000

-♦3 •© -0

--1 0

--2 0 (Rye]

Dungeness dales DEPTH DEPTH (metres) --30 • P e a t o Woody materials o S h ell --40 ° First-order 14C d a te s

Fig. 6.3 General Holocene relative sea-level curves and new First-order 14C dates from Dungeness (after Greensmith and Gutmanis 1990)

172 Between 4950-3950 yr BP most of highland and lowland Britain were afforested as a result of overall climatic amelioration. As the Arctic became cooler after 3950 yr BP the atmospheric circulation changed and cooling in the British Isles set in between 2950-2250 yr BP, between 650-250 yr BP, and around 1450-1050 yr BP. A marked drop in temperature level by 2°C between 2950 and 2250 yr BP engendered great storminess, resulting in coastal changes and increased wetness of the bogs in western districts. Between 2250 and 850 yr BP, there was increasing warmth and dryness particularly around 1650-1550 yr BP. From about 750 yr BP global cooling set in again accompanied by another epoch of great storms. These storms are recorded on the Romney Marsh area and have been put forward as the cause of the destruction of Winchelsea and Promehill near the mouth of the present Rother and the inundation of a large part of the Walland Marsh (Lewis 1932, Green 1968).

BARRIER BEACH ENVIRONMENTS The shore zone is the zone bounding the land and the sea. The nature of a shore zone depends on the kind and volume of sediment supplied to it, sea-level changes and the tectonic setting. The everchanging relation between the land and sea due to changes in the above factors leads to transgression and regression and commonly results in an orderly vertical sequence of facies. Among the important shore zone depositional environments are deltas, barrier and beaches. Beach and barrier islands occur along wave-dominated coasts of low relief, or coasts which are characterized by sea cliffs of bedrock (Elliott 1986). Barrier islands are depositional structures separating shallow-marine environments on the seaward side from lagoons and marshes on the landward side. They themselves have been dissected by transverse inlets, hence the name of instead of barrier beaches. Thus Oertel (1985) defined a barrier island system as consisting of six major interactive coastal environments (Fig. 6.4). Studies dealing with barrier islands have had a long history going back to DeBeaumont in 1845. Some later studies provide excellent predictive models including those of Bernard et a l 's (1962) on Galveston Island, Texas, van Straaten’s (1965) work on the Dutch coast and Hoyt (1967), Howard and Scott (1983) and Oertel (1979) along the Georgia coast, Kraft (1971) along the Delaware Coast, and Hayes’ (1969) study of New England beaches. The study of barrier islands has

173 (3)

INLET AND INLET

: BARRIER 'LATFORM

Fig. 6.4 Schematic diagram of a barrier island system illustrating the six interactive sedimentary environments (from Oertel 1985)

174 concentrated on the USA, doubtless because 55% of all world’s barrier-island coastlines are in that country.

ORIGIN OF BARRIER ISLAND There are three important theories of barrier development: 1. upbuilding of offshore bars by onshore transport by shoaling waves (De Beaumont 1854 in Oertel and Leatherman 1985), 2. periodic breaching of longshore spits or bars by storm or tidal action (Gilbert 1885 in Hoyt 1967); 3. partial submergence of ridges developed onshore during post-glacial rise of sea level (Hoyt 1967). In addition Schwartz (1971) stressed the multiple causality of barrier island formation. Oertel and Howard (1972) pointed to the flushing out of estuaries during ebb tide by jet flow which would then build up a series of ramp shoals on the seaward side of tidal inlets between barrier islands. Longshore current systems resediment the sand from these ramp shoals and accrete sand to the barrier islands. However during periods when sediment discharge out of the estuaries is low, the ramp shoals undergo an erosion and are destroyed. At this stage the longshore currents become erosional, leading to progressive degradation of barrier islands. The major depositional processes operating on barrier islands are wind-driven wave systems. The increasing asymmetry of waves approaching the shoreline is crucial to shore accretion and stability, as without it all sediment transport would be offshore (Carter 1988:51). The seaward beach face of the barrier island has been divided into several distinct zones according to wave modification between offshore and backshore and its variation during different weather conditions (Fig. 6.5). They are, from offshore to backshore: inner shelf, offshore transition, lower shoreface, upper shoreface, foreshore and backshore. Each zone is characterised by distinctive processes, hence sediments with distinctive texture and structure. The height and periodicity of the waves and the depth of sediment scour of such waves are a function of wind velocity. The orientation of the approach of wave fronts on the shore is also very critical. The effect of shoaling of the wave fronts is 1: to reduce the velocity of the approaching wave front, and 2: to orient and refract the wave front nearly parallel to the shore. This shoaling process generates a longshore current which transports sediment parallel to the shore and turns seaward near a rip channel (Fig. 6.6). Longshore currents

175 S w ash z o n e ----- - - Breaker zone- Shoaling wave zone Oscillatory wave zone A eolian d u n es

B sh o re S h o reface Offshore - transition O ffshore F 'shore

MHW MLW

Parallel lamination Mean fairweather wave base and x-b single sets G rad ed Ephemeral fields of symmetrical Mean storm b ed s and asymmetrical ripples, and w ave b ase possibly dunes, often wiped out during storms and replaced by Storm-dominated deposition, unless shelf storm-deposited facies such as regime impinges - storm-generated sand 'laminated and bioturbated beds of laminated (h-c-s) and bioturbated facies' - extent of bioturbation facies prevail, possibly with mud-silt variable, but tends to decrease interbeds deposited during fairweather landw ards periods

Fig. 6.5 Beach face subenvironments, processes and facies (from Elliott 1986)

176 Lindwa>d-di'«citd * It' * m «i mnipoft irt ™#tt — 1 JLJtt J.

TV long$hor» currtntl 7V

Fig. 6.6 Wave-induced nearshore circulation system of longshore currents and seaward-directed rip currents (ffom Elliott 1986) help in the formation of spits and barriers. Rip channels are active mainly during storms and transport sediments onto the lower beachface. Higher longshore velocity occurs during storm periods, erosion increases, sediment transport volume increases and thus major morphological and sedimentological changes take place during this period. Because a wind system might change seasonally, the direction of wave approach and resulting longshore current systems might also change seasonally. On the seaward side of a barrier, coarser sands are deposited on the beach (foreshore) and upper shoreface, and finer sands are deposited on the lower shoreface. Silt and clay accumulate seaward on the adjacent shelf bottom. During storms, much coarse sediments are eroded and gravel size material is dumped on the wave cut platform on the landward side of the backshore environment. On the other hand, the near coastal zone, on the seaward side, beach and upper shoreface, is eroded extensively. In the case of transgressive barrier island coast, transgression displaces whole barrier systems landward (Fig. 6.7). However, very little of the barrier island structure is preserved by transgression. Wave systems associated with rising sea level bulldoze this sand landward, and what is left behind is a thin veneer of sand. This is known as ravinement zone as discussed by Swift (1968) and it tends to be very thin when preserved at all. Kraft (1971) and Swift (1968) clearly show that transgressive barrier systems have a very low preservation potential. On the other hand in a prograding situation or regression, as the barrier system grows seaward, it gradually encroaches on lower shoreface and eventually onto the shelf bottom to produce a coarsening-upward sequence (Kraft and Chrzastowski 1985) (Fig. 6.7). In the place of tidal channels, however, the sequence is dominated by channel facies.

RECONSTRUCTION OF THE DEPOSITIONAL ENVIRONMENT AT DUNGENESS In view of their age and depth of occurrence Dungeness Middle Sands sediments were probably deposited in water of about 35 m in depth. Under normal fair weather conditions there is very little deposition in this zone and owing to relatively quiet conditions the sediment composition is limited to fine grained, bioturbated muddy sediments. In contrast, at Dungeness moderately well to well sorted sands alternate with laminated silty sand, sandy silt, clayey silty sand and occasionally thin layers of lag

178 TRANSGRESSION

LAGOON OCEAN

3 SE A L E V E L

...T ime - DEPOSITIONAL SURFACES

LEGEND

7 -NEARSHORE MARINE 6 - BARRIER 5 - BACK - BARRIER MARSH

4 - SUBLAGOONAL BARRIER 3 -LAGOON

2 - FRINGING MARSH

_ l - PRE- HOLOCENE

REGRESSION

OCEAN LAGOON S E A L E V E L * «■

LEGEND ” - W E A T H E R E D . STRATlGRA^HIC LAMINATED. UNITS '*>

2 -LAMINATED VERY FINE

3 -BORED AND BEDDED SHOREFACE 1 ' . BARRIER. VERY FINE SANDS AND SILT -V 4 -nearshore marine, interbeddeo sands ' 's./5y/ and silt-clay with shells 3 - LAGOONAL , MIXED SANDS AND SILT - CLAY 6 - PRE- HOLOCENE

Fig. 6.7 Models of transgressive and regressive barrier stratigraphic sequence illustrating the concepts of Walther’s Law (from Kraft and Chrzastowski 1985)

179 gravels with shell and wood fragments (Plate 6.1). The sands contain broken shells of Tellina and Spisula species which occur in open water marine conditions in the English Channel and the southern North Sea (van Straaten 1965, Wilson 1982). Often these sands and silts are laminated. However, the lamination is unlikely to be of intertidal foreshore origin, not only because it contains deep water fauna but also because heavy mineral segregation typical of foreshore laminations is absent. On the other hand the lithology, grain size and sorting as well as some shallow water shell species suggest the inclusion of shallow water sediments and the action of waves and currents. This is comparable to most of the modem storm deposits reported from the North Sea and other inner shelf and lower shoreface zones around other parts of the world. In these reports, a characteristic suite of very distinctive nearshore sediments of sands and silts interbedded with bioturbated mud were found and storms and hurricanes were considered to be the main factors in the genesis of these interbedded sand with bioturbated mud. All these sand and silt successions begin with a sharp base and grade upwards into muddy shelf sediments. The sand layers are either evenly laminated or have developed as laminated rhythmites in which the lower laminae are thicker and coarser grained and grade upwards into thinner and finer grained laminae. The presence of escape traces of benthonic animals in these sand layers show that the sands are deposited rapidly (Reineck and Singh 1971). In ancient lithified sediments the storm sediments are identified by hummocky-cross-stratification (Walker 1984b), which can be recognized in cores by low- angle lamina dips, low-angle lamina intersection, and the occasional gentle curvature of the laminae. A combination of waning storm-generated unidirectional flows with superimposed oscillatory storm wave action can form these structures (Dott and Bourgeois 1983, Walker et al. 1983, Swift et al. 1983). They all display similar sedimentological characteristics (Fig. 6.8). Storm deposits, as recorded in shoreface and transition zones (between storm wave base and fair weather wave base), usually display an erosive base, basal lag deposits of mud clasts, shells, plant debris and/or rock fragments, horizontal to low angle lamination, which in three dimensions is probably hummocky-type cross stratification, wave-ripple cross-lamination and a top burrowed unit (Fig. 6.9). The thickness of these deposits varies from very thin to 0.50 m thick as have been recognized in the transition zone of the California shelf, and 3 m as at Fire Island, USA (Elliott 1986). Thicker beds occur in rip channels and may be produced by the amalgamation of

180 A Of MEXICO • EASTERN SHELF. U S A . Hurricane Carl* graded send layer Ftre island shoreface storm sands m imemiy 18-36 m wale* depth) (al 5-21 m water depth) ^ 0* "> —— r Posi'Csfia mud lav** Brogenically-reworked (or 3 n w ove-nppie lam.) sand " T n » ( ■ FAIR WEATHER)___ Graded Carla n orm layer Finely laminated I qramed eppmi sand, memty horirontal in 1- 10 cm thick low angle stratification |> hummocky) < (• WANING STORM FLOW)

Foram • v? i t IPebb*v basal lag PEAK STORM FLOW) ' j *P re- Carla homopemred mud Ctrl* storm ♦ - Homogemred I :.J=TVi lever on i jMud r~7)s.i. rZj^M ■*' Wave ripples tame tcale

C NORTHERN BERING SHELF O CALIFORNIA SHELF Bioturbation N o f ion Sound graded norm layers (Water depth 10-30 m| <20 m water 0 100% St depth) Sd r Transition aone laminated to burrowed sand layers

|l- 5 cm) Plant Mud Silt F Sand 4 fragments * Shell i Bourne's turbidite layers fragments

Fig. 6.8 Offshore storm deposits from contrasting settings ( from Johnson and Baldwin 1986).

181 Distal deposits

Planar erosional or non-deoosmonal bases prevail Proximal deposits

Sculptured erosional bases Storm duration prevail

Planar Wave ripples and erosional cross-lamination or non depositional Parallel lamination bases prevail Shells and mud clasts Storm duration

Fig. 6.9 Generalised sequence of modern storm deposits (from Johnson and Baldwin 1986)

182 successive beds. The determination of the lateral extent of individual storm beds has been met with difficulties (Elliott 1986). Reineck et al. (1967, 1968), Gadow and Reineck (1969) and Reineck and Singh (1980) described frequent, thin, graded sand and shell layers and evenly laminated sand and silt layers from the North Sea in water depths of up to 40 m. They attributed them to transfers by storm surge density currents which transport intertidal sands and fauna up to 40 km out into the deep offshore. In the case of wave or weather-dominated shelves the oscillatory effects of surface waves suspend the bottom fine sediments into the water column. The suspension may then be subjected to net transport by the residual currents. On modem shelves storm-driven currents are known to be strong enough to move appreciable quantities of sand. During such conditions the sea bottom can be subject to powerful scouring forces. On the Oregon continental shelf (Komar et al. 1972) long period storm waves from the southwest stir the bottom to water depths of 204 m. Sediments of 200-300 pm in size move in suspension over large distances during storms in the southern North Sea and English Channel floors (McCave 1971, Eisma et al. 1979, Hamilton 1979). With onshore or alongshore wind, the water column of the entire shoreface and adjacent innershelf is set into motion during storms (Swift et al. 1972). The faunal assemblage at Dungeness contains a mixture of Mactra corallina, Scrobicularia plana, Cerastoderma edule, Ostrea edulis and Acanthocardia echinata and deeper water species such as Corbula gibba, Spisula sp., and Trivia sp.. This type of mixed assemblage at Dungeness in lag-concentrates could have been produced by redistribution during storms. Moreover the 14C age and depth of the sediments in relation to the contemporary sea level suggest that some of the shallow water shells have been transferred outwards from the coastline. The steepness of the slope to the southeast of Dungeness point, down to a depth of over 20 m may have helped in the production of relatively powerful periodic offshore-directed currents during storms. The laminated and graded sands, silts and silty sands and clayey silty sands at Dungeness can readily be ascribed to storm deposition (Reineck and Singh 1972, Morton 1981). In contrast to these beds, there are also beds lacking detectable lamination which can only be termed massive, structureless or unlaminated. These are similar to massive graded deposits described in many storm deposits in the offshore and below storm wave base innershelf zone (Walker 1984). The grading in these beds at Dungeness is not visible

183 because the sediments are well sorted. Lack of lamination may also reflect the depositional conditions, such as mass dumping during storms, or it may be due to the destruction of any original lamination by organic activities. In the core material at Dungeness, mottling due to textural differences is visible and suggests some bioturbation. The effects of intermittent storm scouring are noticeable at Dungeness at several levels represented by shelly gravelly lag concentrations. Scouring is indicated during the emplacement of the Top Gravels as its base is usually sharp, and varies in depth between -3.45 m and -15 m OD. The Top Gravels layers have all the properties of upper shoreface, foreshore and storm beach deposits. Being coarse grained these were probably concentrated near the breaker zone in the upper shoreface, subsequent waves and storm waves built them into ridges. The morphology and evolution has been described in detail by previous workers (Lewis 1932, Lewis and Balchin 1940, Eddison 1983a,b.). These episodic high-energy events of brief duration account for much of the sedimentary record preserved in some modem and ancient shelf sediments and have been attributed to various origins, including density currents generated by storm-surge ebb (Hayes 1967a), clouds of suspended sediment formed by waves (Reineck and Singh 1972,1980), in situ sorting of sand and shell by wave induced pressure fluctuations (Powers and Kinsman 1953), wind-forced currents and turbidity currents. The disagreement is owed to the range of explanations available for any one sedimentary feature and the difficulties encountered in measuring the process directly at the time of occurrence. For example, the flat bed mode of transport is most readily envisaged for unidirectional flow and it may develop during the deposition of sand from turbidity currents: parallel lamination is a common feature of turbidite sandstone beds. Horizontal laminations in turbidites are discussed by Kuenen (1966). However Reineck (1963) believed that laminated sand was partly produced by deposition of suspension clouds of sand in still waters or in slowly moving waters (current velocity less than 20 cm/s) which may not necessarily need a turbidity current. Other workers have suggested horizontal laminations as part of large hummocky cross stratification produced by the interaction between unidirectional offshore flow and onshore-moving oscillatory wave motion. Hummocky cross stratification has been identified in ancient storm deposits but has yet to be described in modern sediments.

184 A brief description of how each of the processes work is given below (also see Fig. 6.10).

STORM SURGE EBB CURRENT Hayes (1967a) proposed this mechanism whereby storm waves approaching the beach face erode large areas of shelf and beach face sediments and transport them landwards. The landward asymmetry of the waves raises the water level at the shoreline and results in breaching of the aeolian dunes backing the beach face. Sediment-laden waters pour into the lagoon, are briefly stored and, as the storm wanes, are subsequently dispersed offshore by way of the washover channels in seawards directed, storm-surge ebb currents.

WIND-FORCED OR GEOSTROPHIC CURRENTS These currents are created by wind stress applied to the water surface either in a single layer, in which the entire water column moves in the wind direction, or in a two- layer circulatory system, in which the wind-driven surface waters move landward whilst the bottom waters move offshore (Morton 1981, Swift et al. 1983). In this mechanism, bottom currents have maximum velocities during the storm rather than after, and sediment is entrained by the storm waves. Wind-forced currents are probably most effective in rip- channels, with deposition taking place in the channel mouth area on the lower beach face or beyond it on the open shelf. If this is the case, individual storm beds and groups of beds will tend to be concentrated at the mouths of rip channels rather than being evenly distributed.

DENSITY-DRIVEN TURBIDITY CURRENTS This idea came from studies on ancient successions in which turbidites were closely associated in vertical sequences with nearshore, wave-produced facies (Walker 1984b). Storm generated turbidites in the Jurassic Femie-Kootenay Formations are sole marked sandstone beds, l-20cm thick and characterized by parallel lamination grading upwards into current ripple lamination. Palaeocurrents derived from sole marks and internal structures indicate seaward-directed flow (Hamblin and Walker 1979). Walker (1984a) proposed that storms produce cyclic wave loading of rapidly

185 Storm winds STORM-SURGE EBB

Storm surge tide briefly stores sediment-laden waters in lagoon

° O ' O 6 m +

Fairweather wave base (FWB) As storm abates, storm surge ebb H-C-S currents emerge from washover Storm wave base (SWB) sands channels and flow seawards Turbidity current?

Storm winds GEOSTROPHIC CURRENTS COASTAL SURFACE DOWNWELUNG

Surface wind-forced current

FWB Seaward-directed SWB geostrophic current, H-C-S sands interacting with wave orbital motions to deposit h-c-s beds

Fig. 6.10 Mechanisms of storm erosion and deposition by storm processes ( from Elliott 1986)

186 deposited fine sediment, which in turn causes liquefaction of the substrate. As this liquefied sediment flows downslope, the combination of flow acceleration and expulsion of pore fluid may be sufficient to suspend fine and very fine sand and generate a turbidity current. There is an extensive literature on the effects of storm waves on the substrate, liquefaction and sediment slumping (Saxov and Nieuwenhuis 1982). The moving liquefied sediment mass could be accelerated to become a turbidity current with a relatively steeper slope (Morgenstem 1967).

SUSPENSION CLOUDS As the energy of the storm decreases, the sand eroded on the coast is transported away by the retreating waters into the open sea, and is retained in suspension because of the high energy of the rough sea. With decreasing wave energy the individual suspension clouds settle, forming parallel sand layers. As generally only slow bottom currents are present, the sediment deposited is not reformed into ripples, but sedimented as laminated sand. In the North Sea it has been observed during storms that much sand is present in the form of suspension clouds in the turbulent water. During the genesis of storm-sand layers, storms render the water very turbulent and much sand can be kept in suspension, so that turbulent water flowing away from the coast can transport sand to the open shelf in large quantities. Because of the interference of waves, the turbulence produced by waves is rather irregular. With decreasing energy in the upper turbulent zone the suspension clouds sink down and are deposited in the form of parallel laminae. Later, with decreasing wave action, fine-grained sediments are deposited together with sand. Generally, separation into sand and mud layers is well developed. The sand laminae become thinner upwards, whereas mud laminae become thicker. Thus, a graded rhythmite is produced. In the last phase, very fine-grained sediment- silty clay to clayey silt with rather ill-defined laminae is deposited. Which of the above mechanisms operated at Dungeness is impossible to dicide. As such very high-energy storm processes are difficult to record even in modem day coasts and shelves because of their destructive nature. In the absence of accurate process- response mechanism, the Dungeness sediments can broadly be described as storm- generated deposits. However, the thinner laminated and graded silty clays and clayey sandy silts and the sands and silty sands may be a product of a storm-surge ebb current

187 carrying much of the river and lagoonal sediments with it as well as wind-driven currents. The thicker massive and graded sands (grading is not clear because of the good sorting of the sands) may have occurred as a result of the density-driven turbidity currents of Walker (1984a) accelerated at the Dungeness Point where even the present slope is relatively steep.

EVOLUTION OF A BARRIER UNDER THE INFLUENCE OF STORMS AT DUNGENESS Once initiated, barrier coastlines undergo modification through longshore spit progradation, coastal straightening and shoreface recession and progradation. This is related to the balance between the rate of rise of sea level and the rate of sediment supply. Rapid with low to moderate sediment supply would shift the barrier landward. A slow relative sea-level rise and abundant sediment supply favour upward growth. A possible stillstand or a slight fall in sea level together with an increase in sediment supply allow the barriers to prograde and build upwards (Swift 1975). The prograding barriers move over their shorefaces, which in turn move towards offshore and innershelf region. Under normal weather conditions there are two areas of deposition in the beach face. The first is the shoreface zone characterised by abundant day-to-day sand transport above the fairweather wave base. The depth of fairweather wave base varies but normally lies in the 5 to 15 m range (Walker 1984a). Below the fairweather wave base in the offshore and innershelf region there is normally quiet deposition of mud with extensive bioturbation by organisms that graze and mine the substrate. It is fundamental that sand does not normally cross below the fairweather wave base. During storms, wave action is intensified, the zone of wave activities widens considerably as long waves break farther from the shore, and the wave base deepens as well. Much sand goes into suspension and is transported in whatever direction the currents flow. Many kinds of water motion may take place including the generation of offshore currents caused by waves and by piling up of water by winds and thus scouring of nearshore sand. The suspended sand moves offshore, alongshore or towards the shore. The destructive and erosive effects of storms and the resulting great changes in the coastal morphology (Devoy 1980) and, to some extent, the ability of damaged coast

188 to recover from the effects of a storm are well known. In contrast, the depositional aspects of storms were not clearly understood until recently. Studies of the depositional aspects of hurricanes, typhoons and other severe storms began in carbonate sediments of tropical regions and were later on extended to coastal areas containing noncarbonate terrigenous sediments (Hayes 1967a,b, Swift 1969, Reineck and Singh 1972, Kumar 1973, Kumar and Sanders 1974). Kumar and Sanders (1976) studied the modern barrier chain along the south shore of Long Island, New York, and of the adjacent parts of the Inner Continental shelf, Hayes (1967a) described the storm deposits in the Gulf of Mexico, which are found as far as 30 km from the land and in water depths of up to 40 m; Reineck et al. (1967, 1968) and Gadow and Reineck (1969) described storm deposits from the North Sea, found as far as 45 km from the coast and in water depths of up to 40 m; Reineck and Singh (1971) described similar layers from the Gulf of Gaeta in the , found up to 20 km from the coast and in water depths of up to 300 m. These storm deposits are divided into Proximal and Distal deposits, ^Tie former deposits are deposited in the lower shoreface and offshore transition (terminology taken from Elliott 1986 and mentioned in chapter 6) and are composed dominantly of sand. They are at first influenced by unidirectional currents which may give way to storm waves. The more distal deposits are finer grained, thinner and deposited below storm wave base. The top of these facies may grade into mud, but more commonly the top contact is disrupted by bioturbation. On the basis of the data in the present study, the Dungeness foreland and its vertical sedimentary sequence can thus be interpreted as late Holocene prograded barrier coastline deposits. The surface storm beach shingle ridges are underlain by upper shoreface and foreshore shingle and sand deposits. The laminated, graded and massive largely silty sandy sediments beneath these sandy gravels have been interpreted as offshore and partly lower shoreface storm deposits. Also the transported shallow water shells and drifted wood fragments in the Basal Gravels and the Middle Sands yielding radiocarbon dates of between 560 and 2900 yr BP are believed to have been washed down the beach face as a result of storm processes. The processes influencing such a storm­ generated prograded coastline environment will be discussed below.

189 EVIDENCE OF PROBABLE STORM ACTIVITIES IN THE SURROUNDING AREAS Waller et al. (1988) pointed to a considerable hiatus and erosion towards the end of the organic accumulation between c. 3700 yr BP and c. 1830 yr BP in Walland Marsh and adjacent lower river valley areas. Tooley noted incision and creek meandering in the Broomhill area post-dating c.3060 yr BP. Jennings and Smyth (1982a) also reported several barrier breaching episodes during this and later periods near east Sussex coast. The Holocene successions in the Thames estuary and the Fens show marked channelling episodes from c. 3000 yr BP onwards, and a periodic extension of freshwater influences is implied by significant peat accumulation (Devoy 1982). Lamb (1977) has also deduced particularly wet and cold periods during the sixth and ninth centuries AD. In the Netherlands during the Dunkerque transgressions between 3500 and 1150 yr BP the sea broke through weak places in the coastal barriers. Climatic changes are thought to have been responsible for this cyclic development, which apparently may be related to the succession of transgressions and regressions in the coastal area. Wave action on the sea floor, which was almost ineffective in the early Holocene because of high sea level, appears to have increased again during the periods of increased storm frequency since c.3000 yr BP (Oele and Schiittenhelm 1979). Storm waves can today remove the upper two meters of sand waves at a water depth of 18-20 m (Terwindt 1971, McCave 1971) and can move sand on the sea floor in the entire southern North Sea (Draper 1967), but the effect is slight at depths of over 30 m. The climatic scene during the late Holocene, with a drop of 2°C in the average temperature (Lamb 1977) due to Arctic cooling between 2950 and 2250 yr BP, is clearly consistent with intense storms which postulated for the nearshore deposits at Dungeness. The gradual shallowing water due to heavy sedimentation would in due course cause progradation, producing a coarsening-upward regressive sequence.

EVOLUTION OF DUNGENESS The marine connection between the English Channel and the North Sea by the way of the Straits of Dover existed during the Ipswichian, and is demonstrated by higher sea level and several raised beaches including the +7.5 m Sussex raised beach (Destombes et al. 1975, Shephard-Thom 1975). During the Devensian, maximum sea level fell to

190 about -100 m (Jones 1981) and much of the English Channel floor was drained by a river system (Dingwall 1975, Hamilton 1979). There is no unanimous geological evidence for this period at Dungeness. During the Flandrian transgression of the last 10,000 years sea level rose about 45 m and led to the formation of a wide range of important depositional features. Some 8000-9000 years ago, the sea transgressed across a marine planation surface at about -32 to -35 m OD and reworked most of the Pleistocene deposits originally mantling this surface, into the overlying Holocene succession. During the initial stages of the Flandrian transgression, the rate of sea-level rise was very high and the whole area was inundated forming an embayment in the Romney Marsh area. As sea level stabilised near its present level 5000 years ago, a SW-NE trending barred depositional shoreline with tidal gaps through it began to form. This is represented mainly by the coarse-grained Midley Sand (Green 1968, Lake and Shephard- Thom 1987, Greensmith and Gutmanis 1990). That this period in southeast England coincided with a marked reduction in the rate of relative sea-level rise has been suggested by many workers (e.g. Devoy 1982). In the Thames estuary at c.4500 yr BP a brief is indicated by the formation of biogenic sediments and the poor state of pollen preservation, probably due to lowered water tables and oxidation. From c.3000 yr BP onwards the relative mean sea level was probably slightly below OD and rose intermittently to its present elevation. Flint gravel was not supplied in quantity to the coast hereabouts until this time. The first gravel banks on the west and southwest of Lydd are dated to c.3410 yr BP (Tooley and Switsur 1988). Increased storminess and coastal erosion may have enhanced gravel movement. Present-day Dungeness was the site of a prograding subtidal lower shoreface and offshore apron, which sloped in places down to depths of 20-30 m below contemporary sea level. The detailed form of the apron surface along the strike is difficult to reconstruct from the limited available data. The fluvial sediments might have been routed through the lagoon and breaches in the barrier, and fine grained silty loessic sediments were periodically flushed across the littoral zone and down the apron especially when storm and river flood conditions prevailed. Palaeochannels and other irregularities in the rock head may have influenced the early positioning of apron channels, guiding sediment from the apron fringe into the

191 palaeovalley system offshore. On the surface of the apron, sands and silts derived from the hinterland, and sediments including gravels from the beach face, offshore erosion and longshore transport accumulated. Quieter phases were expressed by normally graded and fine grained deposits, and stormier phases by vertically graded and laminated beds. Periodic deposition from wind-forced currents, in which storm-driven surface currents were returned simultaneously offshore as turbid flows along the bottom, appear to have been an important mechanism of transport during storms and were assisted by high run-off rates from the land (Hayes 1967a,b, Reineck and Singh 1972, Morton 1981). The rate of sediment deposition and coastal progradation was not constant.

192 Plate 6.1

Sand with thin intermittent dark coloured siltv, clavev laminations.

1 9 3 CHAPTER SEVEN WIDER IMPLICATIONS

INTRODUCTION The processes that influence the development of any coastal unit depend on three factors: sea-level changes, sediment supply and tectonic setting of the area. Changes in these factors are normally recorded in sedimentary sequences. It is difficult to differentiate one from the other as each of them is dependent on the others. By analysing the region as a whole, it may be possible to find out at least in general terms, the regional and local causes of coastal evolution at Dungeness. In particular, the question still remains of how much the Dungeness record has been influenced by tectonics. In order to evaluate deformation the local sea-level sequence needs to be compared with that of adjoining parts of NW Europe. The position of Dungeness is critical as it is situated at the boundary of the eastern English Channel with the Southern North Sea and thus is located near an offshore bedload convergence. It also acts as a sediment trap for littoral sediment drift in the eastern English Channel. Storm waves from both the regions influence the sediment pattern in the area. Hence the broad region to be considered includes part of the southern North Sea and the coastal areas as well as part of the English Channel and its coastal areas. The review has been restricted by the unequal availability of literature. The southern North Sea areas accordingly are treated in greater detail than the Engish Channel areas. The Pleistocene is not clearly recorded in this region. During part of the Pleistocene the region under review, being situated beyond the limit of direct glaciation, was subject to periglacial conditions. As a result periglacial deposits such as solifluction and loess deposits were formed (Jones 1981). Rock-wastage and solifluxion were extreme, giving rise to Coombe Deposits and Heads. Head brickearth blown off the outwash plains left by the retreating ice-sheets was deposited. The product of earlier events were largely reworked later by periglacial, fluvial and marine agencies, so that very little older than the latest Glacial survived in place. Low sea level during glacial stages caused the periodic exposure of extensive

194 tracts of sea-floor. Relative sea level fell to a maximum of about -110 to -130 m in the North Sea region (Jansen et al. 1979, Jelgersma 1979) and to about -100 m in the English Channel (Jones 1981) during the Devensian, the last glacial stage. Much of the English Channel floor and part of the southern North Sea were drained by river systems (Hamilton 1979). The enormous discharge achieved by these drainage systems resulted in marked incision generating well defined systems of palaeovalleys down the floor of the Channel (Fig. 5.3), and creating large amounts of sediment debris ready for later transport. A sequence of early Pleistocene marine levels has been identified and mapped in Dorset, Hampshire, Sussex and on the French coast near Dieppe. However, there is uncertainty over whether these flats are really marine erosion features. Also they have not been traced to the east of Beachy Head on the English Channel coast, hence the detailed palaeogeography of the coastal areas remains unclear for this period (Jones 1981:262). Although both the western English Channel and the North Sea may have existed throughout the Pleistocene, the Straits of Dover are comparatively recent in origin (Prentice 1972a). Kellaway et al. (1975) and Destombes et al. (1975) identified the Ipswichian shoreline near the old sea cliffs landward of the Dungeness foreland and adjacent marshlands. A recent investigation of landslides at Lympne (Hutchinson et al. 1985) indicates that the cliff line here was probably abandoned by c.5000 yr BP.

COASTAL SEDIMENTATION The early Holocene here is marked by peat and other silty, clayey tidal flat sedimentation. The southern and the northern North Sea became connected about 8300 yr BP. Tidal waves from the English Channel and from Scotland met and gave rise to turbulence and tidal scour. Linear ridges and the closed depressions were formed in the southern North Sea and the eastern English Channel (Jelgersma 1979, Eisma et al. 1979, Hamilton and Smith 1972). Unconsolidated deposits derived from the erosion of the sea floor became available for the tidal flat, beach and sand environments after 7800- 7500 yr BP when the sea level was at -20 m and had penetrated into most coastal areas (Jelgersma et al. 1979). This coincided with a relatively stable sea level. In the Atlantic period, 8000 years ago, a coastal barrier system began to form. In France this happened in the early Adantic, whereas in the Netherlands it happened in the Middle Atlantic to

195 Subboreal period. In Germany it is even younger. Some of the offshore sand banks have been interpreted as beach barriers. But they differ in structure and form from modem barriers. In western Holland a sequence of beach barriers started to form at about 5000 yr BP (5300-4700 yr BP) and was completed by around 4500 yr BP. They were soon afterwards covered by aeolian sands to form the Older Dunes deposits (Jelgersma et al. 1970). New ridges were built at the western side of the first series until 3500 yr BP (c.4700-3800 yr BP), although some wind deposition continued until medieval times. By 3700 yr BP the barrier was extensive and the Holland Peat, developed on the lagoonal and tidal flat sediments behind the barrier. The series of later Dunkerque transgression started 3500-3000 yr BP as the sea broke through weak places in the coastal barrier. These were controlled by the nature of the shore (Pons et al. 1963) and were due to either eustatic fluctuation of sea level or by a succession of wet and dry climatic phases. In the latter case increased river activity during wet periods together with greater storminess could have been responsible for transgressive periods. Salt marsh had begun to grow on these deposits by 2600 yr BP. Considerable quantities of sand became available for aeolian transport and were blown from the beach over the Older Dunes deposits. The Holocene sequence of the Netherlands is very similar to sequences derived from investigations in north-west Germany and the Fenlands of East Anglia. During the early phase on the German North Sea coast, nearly uninterrupted clastic sedimentary sequences were deposited, and a unidirectional upward and landward shifting of marine and brackish facies zones took place (Menke 1976). The formation of the intercalated peat layers started about 6500 yr BP, when the rate of sea-level rise decreased, and came to an end at about 2600 yr BP. Thereafter intercalated peats were formed to a very limited extent only until 1600 yr BP in lowlying moist areas, whereas soils developed on drier locations. The extensive Holland Peat does not have a parallel in this area because the barrier system is weak.

196 HOLOCENE SEA-LEVEL CHANGES SOUTHERN NORTH SEA Fig. 7.1 shows a sea-level curve for the southern North Sea area, both for the offshore area during early Holocene and for the coastal region during the late Holocene period. Sea level rose continuously during the Holocene. Jelgersma (1961) published pollen-analytical data from peat dredged from the bottom of the North Sea and Jelgersma et al. (1979) reported two radiocarbon dates for the base of the peat from borings; one of 9445180 yr BP at -47 m OD and the other of 9935155 yr BP at -46 m. Behre and Menke (1969) made pollen analyses of the Lower peat at -45 m OD and dated them as of Preboreal in age (between 10,300 yr BP and 9,500 yr BP). These peats, found in large areas of the southern North Sea, are interpreted as the relics of a peat layer formed by a rise in the water table during the submergence of the present North Sea area. The Lower Peat is overlain by a thin layer of fresh-water clay passing into brackish-water and estuarine clay, known as Elbow Clay. Behre et al. (1979) estimates the age of the overlying brackish clay to be 84851125 yr BP and 81901140 yr BP. Sea level is assumed to have been below the depth of the Lower Peat 9900-9400 yrs BP but above the depth of the brackish water clay during the period 8400-8100 yrs BP. Peat formation had started by 84251170 yr BP on the Leman and Ower Bank (Godwin 1960). The sea was at -34 m OD during the Boreal (c. 8700 yr BP) (Greensmith and Tucker 1973). Jelgersma (1979) and Menke (1976) also published sea-level curves for the southern North Sea and obtained an average rate of 20 mm/ yr, a high rate of rise, for the early Holocene without any fluctuations (Fig. 7.1). In the central part of the German sector of the southern North Sea, the Lower Peat is found at about only -38 m OD. Ludwig et al. (1981) proposed a relative sea-level curve for the southern North Sea region for the depth zone above the -46 m level on the basis of radiocarbon and palynological dating. There was a steep sea-level rise here between 8600 and 7100 yr BP equivalent to 21 mm/ yr. Jelgersma (1979) also reconstructed 5 hypothetical shorelines for the early Holocene period. According to her, during the transition from the Weichselian to the Holocene the shoreline was at the present 65 m isobath line. The 50 m isobath was the coastline just before the submergence of the area SE of Dogger Bank and before the estuarine Elbow Clay deposition. At 8700 yr BP sea level was about 36 m below the

197 i. . Hlcn rltv e-ee cre o h Nrh e ( rm egrma 1979) a Jelgersm from ( Sea North the for curve sea-level relative Holocene 7.1 Fig. -Q a Depth i LO- 0 2 30- 60- 55- 3S- 5- 7 50- - 198 present level. At 8300 yr BP sea level was at the 30 m isobath. The connection between the North Sea and the English Channel through the Straits of Dover was effected during this period (Jansen et al. 1979). The Dogger Bank remained an island temporarily. By 7800-7500 yr BP, when sea level was at -20 m, the present circulation pattern was established (Jelgersma et al. 1979). The unconsolidated deposits eroded from the seafloor became an important sediment source for the tidal flats, beach and sand dune environments which contain a record of sea level changes inland of the present coastline.

German coast Menke (1976) assumed a continuation of the early steep sea-level rise (21mm/ yr) until 6500 yr BP to a height of about -7 m or -5 m. There followed a large number of minor negative oscillations of mean high water level between 6500 and 1800 yr BP, notably a temporary fall at about 2800 yr BP and 2000 yr BP. These negative oscillations are controversial being inferred from intercalated peat layers formed between 6500 and 2600 yr BP and up to about 1600 yr BP in lowlying areas. Such intercalated layers occur in the typical cyclic sedimentary sequences of the coastal zone and have not been used to interpret every regressive overlap (terminology from Shennan 1982) of peat on top of clastic brackish sediments as an indicator of a sinking sea level (Streif 1979). Peat formation in this position is quite possible under the influence of a rising sea level as long as the bog growth rate is slightly greater than the corresponding rate of sea-level rise, as in case of the Netherlands. Linke (1979) (in Shennan 1987a) developed a mean high water level curve, without negative oscillations. It shows a steep rise in sea level between 7000 and 4500 yr BP and a slow rise until 2400 yr BP. Thereafter the rise stagnates until 1250 yr BP and again rises continuously to its present level.

The Netherlands By 7800-7500 yr BP sea level was at -20 m and had penetrated into most coastal areas (Jelgersma et al. 1979). Jelgersma (1961, 1979) used 14C dating of peat layers directly overlying the uneven Pleistocene surface to establish the chronology of sea-level change between 8000 and 2500 yr BP. 14C dates on the lowest point in peat layers of a given age, in her view represent the mean sea level, and the curve shows a continuously rising sea level for the last 8000 years with a gradual decrease in rate after 6000 yr BP

199 (about 5.8 mm/yr). The average rise of sea level has been much slower during the last 4000 years (2.9 mm/yr) than in the preceding period (Fig. 7.1).

Belgium Baeteman (1985) and Paepe and Baeteman (1979) described the sediments in Belgium and their environment of deposition. Three 14C dates have been obtained, of which two are on peat at a depth of about -2 m (Belgium Ordnance Datum level at Oostende:OP and is 2.33 m lower than the Dutch Ordnance Datum level:NAP). It gave an age of 4150-2900 yr BP. A second peat layer at -5 m OP has been dated to 5830 yr BP. A peat at -11.5 m OP has been related to the Lower Peat of the southern North Sea but no date is available for this. Sea level was probably at -2 m OP (-4.33 m NAP) at 4150 yr BP and rose to -2.33 m NAP or OP during 2900 yr BP, a rise of about 1.6 mm/yr.

France On the North Sea coast of France the sea did not reach -32 m line until 8250 yr BP (Somme 1979, Ters 1973). In the late Boreal and early Atlantic a sandy to pebbly deposit related to a coastal barrier system was formed and migrated landward (-30m to - 15m NGF) During the Atlantic (8000-5000 yr BP) and Subboreal (5000-2500 yr BP) transgressive phases most of the tidal Calais deposits and the shingle spit system were formed. A series of transgression and regressions phases were noted within the main Calais deposits (Roeleveld and Somme 1975). The rate of sea level rise during the Atlantic was slow, hence the shingle spits grew upwards from -10 m NGF onwards.

ENGLISH CHANNEL AREA The first detailed study of the lower valley alluvium was by Jones (1971, 1981) in the Vale of Brooks (Ouse Valley, south of Lewes). Three major lithostratigraphic units were recognised: fluvial sands and gravels overlying the bedrock or soliflucted Chalk (Coombe Rock); bluish or greenish grey silty clays with interbedded peats; and grey to black sands, silts and clays with estuarine shells. Peats near the base of the silty clays have been dated to 6290±180 yr BP and 5677±167 yr BP, while the upper limit of this

2 0 0 organic material (at -2.3 m OD) was dated to 3190±125 yr BP. Accurate dating of this transgressive overlap may not have been achieved, however, as the surface of these fen deposits appears to be truncated and rises to OD elsewhere. The investigation of Jennings and Smyth (1982a, 1982b, 1985) at Langney Point, Eastbourne, has shown that freshwater conditions here were replaced by estuarine deposits at -25.94 m OD, these in turn being overlain by a thin peat (from -24.82 m OD to -24.70 m OD). Shephard-Thom (1975) reported two dates, one of 9510±75 yr BP at a depth of - 27.30 m OD and the other of 876Q±50 yr BP at a depth of -24.7 m OD, on peat at Langney Point. Jennings and Smyth (1985) obtained a further date of 8770150 yr BP from the transgressive overlap between the thin peat and a subsequent bluish-grey estuarine clay. These clays are replaced at -14.20 m OD by marine sands which coarsen at c. -4 m OD into the shingle forming Crumbles Spit. The effect has been ascribed to an increase in coastal energy at a time when the rate of sea-level change was much slower. At 4000 yr BP the coast line was at its most landward position. At Willingdon level, the Holocene sediments consist of gravel overlying bedrock which is replaced by a bluish grey estuarine clay (from c. -7.5 m OD to -1.0 m OD). These sediments are in turn overlain by a thin peat dated to between 3750140 yr BP and 3390140 yr BP (Jennings and Smyth 1985) and an upper clay in which a change from estuarine to freshwater conditions was recognised. At 3400 yr BP, when MSL was at OD, the coastline again shifted seaward and an extensive sandy gravelly spit and Willingdon peat developed. Estuarine conditions returned to this area 800 yr BP as a result of a diminution in sediment supply, corresponding possibly with a period of maximum spring tides and storms. A continuous line of gravel developed broken only by a small tidal inlet. In the western Pevensey levels a tripartite sequence consisting of a lower clay overlain by peat and an upper clay was recognised (Barnes 1974). Pottery in the peat was tentatively dated to the medieval period. A similar tripartite sequence was subsequently identified in the eastern levels, where the lower bluish grey clay/peat contact was dated to 3715±40 yr BP and peat formation at one site continuing beyond 480±50 yr BP (Moffat 1984). At Combe Haven, a small valley between Bexhill and Hastings, gravel is overlain by essentially blue estuarine clays with intercalated peats at c.-6 m OD. The largely organic unit which follows (6020170-5900±50 yrs BP) was protected by barriers. The significant change in the hydrological regime of the river consequent upon forest clearance

2 0 1 modified the barrier and resulted in a transgressive overlap, superseded by an orange- stained clay which appears to have been deposited under estuarine conditions in the lower reaches of the valley. Southwestern England, the Channel Islands and Wales are discussed by Heyworth and Kidson (1982), who showed that here sea level at 9000 yr BP was slightly more than 30 m below its present level. A significant slowing in the rate of rise occurred about 6000 yr BP when sea level was still some 6 m below present. Relative sea-level changes have been studied mainly in coastal, low-lying marine/estuarine alluvium throughout the Channel coast. The rate of sea-level rise was high during the early Holocene. Peat, dated from Langney Point, east Sussex and Tilling Green, Rye at depths of -27.3 m OD to -22.5 m OD, ranged in age from 95651120 yr BP to 8760175 yr BP (Lake and Shephard-Thom 1987). The lower sections of the river valleys were filled with freshwater clays interbedded with thick oak and alder fenwood peats as a response to rising sea level. Hodson and West (1972) at Fawley, Southampton, found evidence of a marine incursion at a depth of -21 m near Calshot in the form of a clay and silt sequence containing shells of Macoma balthica, indicative of tidal flat sedimentation followed by salt marsh and then peat. The upper surface of the peat has been dated to 36891120 yr BP. At the top of the peat further marine inundation took place, with sedimentation occurring in salt marsh conditions. Submerged peat at -36 m in the Solent has been identified by Dyer (1975). At Langney Point, on the east Sussex coast, the early Holocene rapid rise in sea level has been marked by continuous estuarine deposits whereas towards the late Holocene when the sea-level rise slowed down, the energy of the coast increased and the coarsening upward sequence was formed. During the mid-Flandrian, c.6000-5000 yr BP, the influence of a regional cause responsible for a reduction in the rate of sea-level rise or of a fall in relative sea level is apparent. The lower Ouse, Brede and Rother valleys and Combe Haven all contain thick organic deposits of mid-Flandrian age. Although they are confined to topographically sheltered situations, a lessening of marine influence appears to have occurred. Willingdon Level appears exceptional, the absence of thick peat here being attributed by Jennings and Smyth (1985) to a relatively limited freshwater input. Replacement by estuarine sediments in the Lewes area, in the Ouse valley, is recorded at levels of -6.5 to -2.3 m OD. The variability in the height of the contact has

2 0 2 been ascribed to contemporary river erosion, tidal scouring and the formation of freshwater deposits above OD before the estuarine incursion (Jones 1971, Thorley 1971). Other protected sites in the Stour, Rother, Tillingham, Brede and Arun display similar sedimentary sequences (Burrin 1983, Burrin and Scaife 1988, Jennings and Smyth 1982a, Waller et al. 1988). In Poole Harbour, Gilbertson (1967) studied estuarine sediments indicating coastal freshwater conditions immediately prior to c.3500 yr BP. According to him this phase was followed by renewed marine inundation to levels above OD by c.2500 yr BP. The upper estuarine unit above the main peat deposits is recorded widely in the area: in the Ouse (Jones 1971, 1981), Combe Haven (Jennings and Smyth 1982a), the western side of Romney Marsh and associated river valleys, and on Willingdon Level (Jennings and Smyth 1985). The available radiocarbon evidence for the initiation of this phase (c.3400 yr BP at Willingdon Level, c.3200 yr BP in the Ouse and c.1800 yr BP in the Brede) suggests that these deposits are not confined to one period. Such incursions may be the result of variations in sediment supply, storminess and other coastal changes.

HOLOCENE CRUSTAL MOVEMENTS AND SEA-LEVEL CHANGES Despite so much of work on relative sea-level changes, a firm conclusion about crustal movements in the region has yet to be reached. The following discussion will summarise various views in this particular field of investigation. Jelgersma (1979) suggested that, in the southern North Sea basin, a continuous rise of sea level during the Holocene was the result of both a eustatic sea-level rise and tectonic downwarping. Although deep seated tectonic activity could cause variable rates of apparent sea-level rise in different parts of the area, Eden et al. (1978) and D’Olier (1981) suggest that both the Tertiary and the Quaternary have witnessed a combination of long-term tectonic subsidence and glacio-isostatic movements. Caston (1979) has produced an isopach map of the Quaternary sediments in the North Sea which show the complex nature of the depositional setting. In the Netherlands, slight tectonic downwarping due to its position in the North Sea basin was to be expected, but subsidence values obtained from the elevation and age of the interglacial Eemian marine deposits (Jelgersma 1961) are only between 0.15mm/yr to 0.35mm/yr. Accordingly tectonic subsidence during the Holocene is thought to be unimportant and sea-level change to be eustatic largely, even though tectonic movements

203 may vary in intensity over time. A recent analysis of tide gauge data for north-west Europe (Emery and Aubrey 1985) based on tidal data compiled by the Permanent Service for Mean Sea Level at Bidston, Birkenhead, purports to show subsidence in southern England of some 2 to 8 mm/yr, which is several times greater than the +1 mm per year global sea level trend for the past century (Gomitz et al. 1982). Although slight crustal downwarping has occurred throughout southern and south­ eastern England and most of Wales for at least the last 4000 years, the type of movement in some areas of southern and south-east England is more complicated than simple linear subsidence. The highest estimated rates, up to 2mm/yr, are for the Thames estuary and Norfolk. Subsidence in the Thames estuary could be due to activity on the London Basin syncline, errors in geodetic levelling and metropolitan drainage works (Akeroyd 1972). In Norfolk, reference to subsidence at a rate of 1.5 mm/yr is indicated (Coles and Funnel 1981). The values for subsidence since 7580 yr BP, and since 4500 yr BP, were calculated to be 1.77 mm/yr and 1.33 mm/yr respectively, since 1600 BP the rate has been 1.72 mm/yr. On the basis of the depth of submerged forests Churchill (1965) determined differential subsidence in south, southeast and southwest England. He and Hawkins (1971) suggested downwarping in excess of 6 m since 6500 yr BP for southeast England relative to the southwest. The sinking of southern England and western France could, in part, be related to the continued collapse of a former forebulge associated with ice bodies. Other tectonic factors may also be of importance. Flemming (1982), using a data set of 143 sea-level index points from all over England dated between 118±48 yr BP and 9961±200 yr BP and all levelled to OD (Newlyn), showed uplift of about 2.5 mm/yr over the highlands to -0.5 mm/yr over extreme south-west England. He showed a pattern of both uplift and subsidence in southern Britain and uplift on the south-east coast. Shennan (1987a) compared relative sea-level curves from North Sea coasts with Momer’s (1980) regional eustatic curve, and calculated uplift and subsidence values for thirteen coastal units. For the unit closest to Dungeness area, the curves of relative sea- level change for the Thames estuary of Devoy (1979) indicated a subsidence rate of 1.2 mm/yr for the last 5000 years. From 8000 yr BP to 5500 yr BP local uplift was shown. According to Shennan (1989) the subsidence rate over the period of the last 3000 years

204 has been on average about -0.85±0.18 mm per year. This compares reasonably well with Churchill’s (1965) estimate of -0.92 mm per year over the last 6500 years for tectonic subsidence in the eastern English Channel.

205 CHAPTER EIGHT SUMMARY OF THE FINDINGS AND FUTURE WORK

The main objectives of the present study have been successfully achieved. The principal findings and conclusions are as follows:

1. The detailed petrography, including the texture and the detrital mineralogy, of the thick sandy unit in the middle of the Holocene succession, the Middle Sands has now been established. The deposit consists mainly of moderately well to well sorted silty sands with only a limited amount of finer and coarser admixtures. The surface microtexture of the quartz and heavy mineral grains, studied by scanning electron microscopy, revealed features of subaqueous, aeolian, high-energy glacial, subaerially weathered and reworked sedimentary origin. Some of the grains represent fresh input from local sedimentary source without much alteration of the surface features whereas others have signs of multiple history on them. Although quartz is the main detrital component, glauconite, feldspar, chert, heavy minerals and clays are also present in minor proportion. A wide variety of heavy minerals were identified in the fine and very fine sand fractions. Zircon, tourmaline, garnet and rutile were predominant among them. Variable amounts of amphibole, the epidote group of minerals, kyanite, staurolite, pyroxene and apatite were also found. Garnets were found to be mainly almandine with a variable proportion of pyrope, grossular and spessartine. A few grains were grossular-rich. Clays are mainly illite, kaolinite with a minor proportion of smectite, mixed clay and chlorite.

2. Although green Holocene sediments are widely recognised in the area, there has been little investigation of the cause of this coloration. The present study showed that, although it may be partly due to the presence of an iron compound in a reducing, impermeable environment, part of it is due to glauconite and glauconitic clay particles derived from the local Tertiary and Cretaceous sediments. The mineralogical nature and detrital origin of the glauconites were proved by detailed microscopic, XRD and microprobe analyses.

3. The source of the sediments in the Middle Sands succession were established as

206 unambiguously as possible. Holocene sediments in this region are a complex mixture of local sedimentary material and Pleistocene sediments of aeolian, fluvial and fluvioglacial origin. This is demonstrated in this thesis by grain-size analyses, the surface microtextures of quartz and heavy minerals, and detrital mineralogy especially heavy mineralogy and garnet geochemistry. Glauconite analyses proved that the local sedimentary sources included both Cretaceous and Tertiary materials.

4. Greensmith and Gutmanis (1990) had identified mollusc shells in the Basal Gravels and established their age by conventional 14C dating and the AMS 14C method. In this study shells were identified both from the Basal Gravels and the Middle Sands units and dated by the First-Order 14C method. The dates were found to be compatible with those obtained earlier and further proved the late Holocene origin of this part of Dungeness foreland.

5. An outline of the depositional environment and the style of sedimentation for this area had been proposed by Greensmith and Gutmanis (1990). Detailed study of the boreholes and the sedimentary texture, structure and faunal content of the deposits not only supported the ideas of by Greensmith and Gutmanis (1990) but also refined them. Thus the bulk of the sediments were shown to have been deposited in the lower shoreface and offshore zones during storm conditions. The contemporary regional sea-level position ranged from about -8m to +2 m OD. There is no evidence of large scale tectonic subsidence or faulting in the area, and of sediments was at minimum because the sediments were mostly sandy and coarser. Moreover, the periods of increasing storminess identified by Lamb (1977) are compatible with some of the phases of sedimentation at Dungeness dated by the 14C method.

FUTURE WORK The results obtained from the present study demonstrate that the modem coastal environment at Dungeness is very dynamic and that a large proportion of it formed during the last 3000 years. The area is still undergoing changes and continuing to evolve, with the eastern and southeastern coast prograding and the western coast retreating. The Holocene succession here is not a simple function of sea level, sediment supply or

207 tectonic subsidence. It is the product of sediment accumulation during relatively stable sea level conditions on an exposed coast. The studies undertaken so far in this area cannot provide a comprehensive picture of the distribution and nature of the Holocene deposits of Dungeness. This applies in particular to the early Holocene, concerning which there is virtually no information over the greater part of the region. Deep cores and dates from the Marsh, the Midley Sand and from the modem beach at Lydd-on-Sea are required to determine the future shape and structure of Dungeness and to establish the development of the whole area throughout the Holocene. It is not known how far neotectonic movements, exemplified by a significant earthquake in the Dover Strait region in 1853 (Neilson et al. 1983), have contributed to the accumulation of coastal sediments whether directly by triggering turbidity currents or indirectly by creating large waves. According to Smith (1989) the whole of southern England, the eastern Channel and northern France are actively rising (see also Vita-Finzi 1988). The presence of highly angular, fractured quartz grains and certain types of fractures normally seen in quartz grains fractured by shearing, as well as some of the laminated and graded layers in the Holocene succession, hint at tectonic disruption of the Dungeness area and show that the problem would repay investigation.

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y.u* C2' (1 3 .0 0 ) f<&*' :s .c d - 22.:Q__

a .o o

(2.601

268 BH - 28

j 0 « o m j | S if ju O e o r n | ° : r | S u a u ICTVotr^flii‘^T i.0.0. I Svm oo* 1 S v m o o * n>*oi ngn r 0.0. S v m o o > I T^«*rm r m • O • 0 ■ '-• w. 10.2Ck 5.3025

h C-V- i?

*•( 0 . £0

! I

5.5C ):

t[, && t ! ?-od I -- is. 50 ils-1 3 f - I- - 50) F~ I: r -

[ - r

(6.2C)

27.20-32.20- % f^-U ,

4.30)1 7±*-£„v c •-

• C .3 0 ) | m

—;o .c o -3 5 . cqS

269 BH-29

S t r a t a j Oeotn | Lev*’ j Strata Oeotn Level S t r a t a i m i | S v m o o * rrSot/w r^O .D .l Svmooi I

(0 20)1 d L i . i tZL. 43 -15.90i.v- _ 2 1 . 50t16 ,0 Q: X

(l'wlS)l l-o-

J.2.45 -6 .9 5 .22.65417.15r l-;l. |(0.S 5)i ;;v:£z£vvj .13.00-7.£0 0« ^ *jro .ao)( .Ov© ■. W .23 .45-17.95.

1.49J f

4.4 5 -a. 95 r - c (3.05) - o .[0.93)1 co. so) o . c I I 2 r o . r © j5 .38-9.88 g

’.-.w v.-o-- - :• o \ -

■: « o v .••.:•• - .-p.; *CT ,: cr- O- “ _d_p‘26. . 3U50-.21.o a

*’:V d 5.3 0 -LL 3C»=>-—■ :'r.: o-.i j -.W .v .

O *

l " - • o ::

t 1. IPS

r •43.10) i i o : .- i i *• O’­

er..:.-.- o

Or « -

• O , 9 0 -1 4 . 4C;V. a . ^ . - •La. 27)| - \X-\Jtf~- 2 0 .17 14.67 ■_ 2L * O 10.50•5.00 9 v o - . . * : ■VO . /

270 BH- 29A

j Oeotn j Lew* Oeotn | O«0in wiW l Strata | Oeotn | Levvi j Strata rrscKr>3 ,*m.0.9. i Svmoo* lT>*o«rwir(n>d-0- I Svmoo*

■ K.

2.47)1 r - : *" 1 CL 30) i r Jt i * x] J ' i - 22.CO-26.50 r •l -* I i L t f t ’ft 3 0 -7 .3 0 X TLi.50) f-

(0.90)

- f t

(4.001 •l_ J : JI h : t. - J * ! 1 . i1 [

i ( 0 .3 H 136.25430.7^5-22.3 t V - 2 6 .5 0 .•?* ...... ■ - a.5o)

• i_ ft'ft-iu-j ♦J t r iLl. - r i J 2 7 . 7 5- 3 2 ^ 5iLi^_4iil • j o . 0 3 ) 1 (O .23 i h x 'IK !] HI —23 .COt 3250 - 1 ; aii*'-: ■ -23 ,4043290 =CTvtH •f I l5£? i ko.aoi k -^ .i llCjCjL-J 39. CO-33. 50.-.-.-W i rr?.C5-3 3.5!2CC=z= .i i [ , j ( 0.45)1 2 9 .5 3 - 24.CJL _19. 50-r34 .CQ-~— f 1 1 5 - : - ^ io.CO -4.50 t e S S * I I fc'->=q 1 'c^>501 1 (1.75)1 OQ,3 > ( 2 .4 7 ) (2.301 C'fc.M - WWI .. ■■ I

271 BH-31

Oeotn u*v«i Ocom L«v«t Strat* Imi | (mi j tTScur*u;m-0.0.. [TKcx/>yi»*m-Q- 0 - SymOO* n>>oenasrm. 0 .0 .<

; (7 . 25)

m■o:-S>: ? * o-Q, (1 .6 0 3 .0 0 ) „ I.00U 5.50 A J(o. 20 i ^ jr -c "LI. 20i5.80 2 1 .4 0 t 16.00 4

! 3 .7 5 ) 1 (0 .9 0 ) 3l.90-26.5CT*-' i - t b .4 6 ) | [ j- >22.30*16. 2 .2 0 * 2 6 . 9Ct, 1 2 .5 0 - 7 .1 0

>fc- Iff

( 2.10

3 .7 5 1 .6 5 (2.CC5! Jl-

24 .4 0 4 1 9 .0 0 t;j;-:-'*-- =4.501-9.10* U o .25 l f t 35\ -14.75-9.35 ' r ~ - 2 4 .7 5 t 1 9 .3 S ~ ? :-:-- Jl4.9049.SO -t W m a.isji W-.'s.- 3 i 1

2S .9 0 -20.5CCt e a 16.00-J-30. SC ij-i r-tf.' .tv. (0 .4 0 ] 36.40- (1.25 —16.60' •11.2C •JO. 35) 1 .0 5 16.95-rll.S5

27.15r21.7S; (7.255 (0 .2 5 ) 27.40422.( - .7 .45r3 2 .03- To.400 | 1 | 0 .4 5 ‘ a . 95) ,11c. - 2 7 .8 0 422.4<£j£lSi K'.-.-.C.'';.- 7.90432.50. . j t u X «ai.ioo 1.10

;1 8 .9 0 ( 5C > L v)-:; ■X Jtt - 2 8 . 90h2 3. SQ tt 00-3 3.604; |To.30)( X •xJ:--. 9.lO-j33.7o£ nl9.2CH13.8a8<~ 0 . 3o| ] .!(0 . 30>i ..y-V- 9 . 40-*34 .OC - lr U •ro .3 0 ) ILL. x. 4C ( 3 .OO j

(1 .6 0

272 BH-32

Oeotn L*v«i S t r a t a O e o t n ) U m i S trata 0«Oin j Ltvwl I sSirna if Oeotn I Lewi S t r a t a I m i I Im i I 1 Thocrw art r "V- 0 . 0 . ' S v m o o * 0 0 SvmOO* fTSorakr[TSo>nm»»#m-0 -0 . S vm oot 3 0 .0 7 30.14 (6 .7 0 } 3 0 .2 0 * 0 .4 5 2 5 .1 0 :c (0 .3 5 t*

6 1 .0 0 -2 5 . _11.20-5.3St 3 1 .1 7 31.241 to. 60)1 L31.30: J ll. 30*6.4S I FTT

< 4.50) It.-rr^nr- x.— yc1

C. 2 0 ) i 2.40)1 f- i *r _- - I -lit

14 .OOi-3.6: <7, -29 .05" _ * __ _4.50 iO.35 4 .4 5 ■34. 70—29 . 35 t

25.15-29.30U (2.30) Is. 35—30.Qoi.j^ J ^5 . 40-130. OS

i6:3S-21.0CU -26. 4 3 -2 1 . 16. SOhILIS— ~ 2 .3 5 ) j l o . 3ol-11.4S [ • * +

Jl ( 1 . 4 3 1 2 . 44). (6 .5 0 x c 8.25-32.90 8.37-^3.02 ^S2S ^g.45-33.10_

ia . 92-23. STt (0 .6 5 ) -S9.CO-23 .65 £. 1 0 - 3 3 .7 5 61656905

ba.TS ] i*9.32 i 2 .5 7 ) (7.74)1 fe?.?6 :

<1.45)1

273 BH-33

O r o m U r v n O r a m I L r v r i S l K U I Oram . Lr»«i Sum ( m l I I imi I I rrhouw Jtm .o.0.: Symbol I TKo»vnrm.O.O. I Svmoo*

■ (1 .5 0 0 i 6.20! '3? —ill.20-5.35r

[:-.v .-u £ c.v (3.001 (2.SO) f r. i

i~- -v t ^ " f -

4 . SO 1 . 3 5 [ X "(O.SO» tea3v?: r Vregvpsa I _5.oo 0 .8 S .0 -5 .2 5 (2 3 .2 0 ) f —

( 2 3 .2 D ) F " E - -

* * -r'

( 6.201 ifi* 3 3 .3 0 i - 3 2 .

”0 .401 "38.701 -32. 55ij- p-

g = S

+1.301 -tX=

40.00f-J+. 1

274 BH-34

O t o m I L « v * i 0»otn- I l_rv»i Srraii Ocovn L*v«* j Ototn |*c«v«r | ( m i | (mt I IThot/wrffiO'fr) !The*rwii»'>yO. 0 . J rr>wwi|lm.0.0^Svmoo.

(3.00}

2.00)| 12.COi-5.80l

( 0 .3 0 ) ll2.3Or7.60cV'? 3

-3.00 2. 20

f o- (1.70)1

"X

i.7 Q iO.SO

2 5 .5 7

— MT (•i. 201 •>?— -

o X

33.37 3 3 .IT

9.00 - 3.30 i ; I - x — • 1 .3 8 )

-39. 75 t 34.5 (3.001

275 BH - 35

— -j______- Oeotn 1 Sirata O«otn L*wi Sfrata I 0«Oti I leva. ! Si 41* IOcom lavei Strata Imi | (mi ) (mi I [Tboww^O.O.i Svmoot TVouwnvO.O. Svmom lT iv * t > « i,m -0 . C K S\ (Tin. i1>iC fe

( 4 .2 0 ) «&c>

! &?g« 1 IcfS-.^.C i l . 7o-o. sopgv^

(1.90)

k - (7.503I hj.so-3-4"- ' u

( 2 4 .5 0 )

J (2

-'X

2 4 .5 0 )

— 7 . £0 2 .2 1 f-“ '

38.101-32. 9C_— _

(4.20)1 ( 1 .5 0 P ^ 0 ° tl-rnr-; n'lCv,19=.*'c-

2§>3

>‘(7*£ bc& C ^ g c SJ&J

276 BH - 36

0«rn I Lewi Sir^ii O e o i O e o t n C c o t n m i | ■0 . 0. S v m o o * lTSowiaii*fn*0»0.!

m m l -5-.°^ ti.oox rZr&v. ( 7 .6 0 _1. 30 '4.50

I "14.20)1

( 2 2 .9 0 ) ( 1 .7 0

2 2 .9 0

• 9 .o a50

5 .2 0 0 . 3 0

° o^v 3 J-vfo-j;ffcSS&S ggg-s t e a l i f - fe ’s l - r ?*QaCL< 3_7. JO-31.9C (O. 30)1 QOVo -37.70-32.20^ .r-O o-o-l

( 2 2 .SO) l;o-e

i§g&i L“-oO)| i

i-P ;i -39.95 & > ^ O cj.N

fvS^iA O 9 o I $:b'o/o-1 (O.lo *orv&o'aQ» o .• t. r o.oQq 3

277 BH - 37

I Oeoin J Ltvvt j Strata O e o t n L e v * S t r a t a 0.m nj|!m.Q D.^ Svmooi rrhoww'i'.O.O. S v m o o < ITt-ou^nfm.O-O. S v m o o * .0 .0 .:

(4 .9 5 i L_x— J l

t o ■o)

. 40 L. I____1 [-X-J (0.350 to fe: V‘ iO-.-oMCE?-9^ 3 L &£&&: S '. 2. o0*-3.25), —X— __ >gygyrS P o -.v , ! ; - ! : * ■a-i I (i. 40) ( 2 2 .5 0 ) i X

4 . 70 0.65 r-rziHfi E p I IS .00-9. | 65f ___ _ _ M~ gS&cl

1 3 .2 0

(2 3 .5 0 )

3.00

J23.5 0 1 -3 3 .Jc :' 9^99939

(4.950

( 4 .0 0 ) :i?^ ■V;--°

278 BH - 38

Oeotn Lewi Strata I 0«om lew Strata O eo tn | Lew i S trata | lrr»i | I rTV w m r^ O -1 Svmoo 1T>'o

;c*trsr' ’ .CO)

(4.0OJ

22.50

(1.50) (2.5CI (14.30)

24.oo*-La.4£;

.500

.50

(3 .00 i ■xO O'* 3.30 ■32.7 V.^vC 0.70)1 I (2.50) 39.00 -33.45 41437590

o ■ LO. 00 t-4.4SS£:'?;°

(2.CO

279 BH - 39

)«oin I Lcm 0«om I Lc**i (mi | Sum 5THou-^#^m-0*0-' [TK

2 0 . 781 - 2S.4S. G .00) I 10. 4 7 J

r2.00-5. 70 i

f ! (2.301

(4.101

14.30- 9.00------

(10.00)

35.35r30.0£ o.isi f; 5.50f-30 . 24f

(5.73 2.700

>> i i r i i 38.20t32.9C.

p-0 0-i.oj :0.43 xZO-Q'°\ ■28.534-33.3^ 'i1(0.39) 1 79.02 (-33.71

p & 3 -„E>7o.3tt 4.O.0C1-4.7O _£Q.O 3 14.75____ J m s 14 qi _2 -oo) 5.04)

280 BH - 40

S trata Oeotn Level S t r a t a O e o t n Oeotni [ | Level La* (m i | (m i [Thome»tilm.O.D. S v m o o * IThchrau* ^ O* 0. Svmoo* (Thotrveu* m . 0 .0 .' S v m o o * I VySJL' j y

v **- (5.40)

(3.CC3

(1.30)

13.20-7.951. (24.30)

i (■-- 50 U- (24.30)

B.OQ ■O. 7S

24.30)

38.001-32.IS

(S.40) •=38.25 -33.0

(1.25

39.50 -34. x - X •

X - X " (1.15) X * X •

X \ 'x . • X X . X .' X

X X

281 BH -50

Ococn I L*v*i Srrata O#o in I m i I rrv -o u w ^ m .O .0 .1 SvmocM

282 BH - 51

Deom I ltv«i S tr a u (m i | I 0 < a tn I L*»#I S trata Imr-f- - - I Th^r^av* ^ O • 0. Svmoo* JlTSotn<»u‘m-0.0. (1.30)1

.0.50-4.95*:

3.40)1

3.40 -2.15

(2.60)

•■'•'•'.■O-.VP 6.00 ■0.4SL (0.60)

37 . 50- 31. 95; re.som-i.os

(2.40)

CJ

^9.00 - 3.45

;L.50)

283 BH - 52

Oeotn || Level Levi S irai* Oeotn Level S trata fmi (m i I fThdmou^ ^ 0.0 . Svmbo* TNauwirtn-O.D. Svm oot

I 3 . S 0 , *0 * 0-7

rO-O^Fr~&,bc KTp-t (3.9CJI V.e'jOt

L2.00-t7.00

CO.SOU

L2 . 8 0 -t7.80

.9 0 - 1 . 1 0 g ^ o ?

i £ ? H [25.50 (i.ro)l I*.’

S.. o o - o . o o L-V;

^(1.00) 6.00 ■•1.00

-i8.40J33.4C 171155738889467155

:2 .4 0 )

3.40 -J3.40

(8660)

(3 .6 0 )

284 BH - 101

Depth Radioed Legend Depth Radioed Legend Depth Red re d Legend Depth (Thick) Level (Thick). Level (Thick) Level {Thick)

5.04 0 o o -15.06 (2 0 . 1 0 ) (3 SO) ■ ° o ■ -15.16 20.10 f.-. ■ 30.10 ° o ° (0 . 10) -25.31 o o .o ’ (0.25) ° o ° 20.20 a o.? o- 1 30.35 °o.°o -25.51 - (0. 20) (0.65) - 30.55 n ° o -15.81 °'o. 20.85 - % ° c oc °o°- °o -- -O ■O . o 6 - ° o o c O . o • o r 0 6 .° O.n9 o -o ' 0. °- |o^ . ° • 0.1 0 i (2.47) 0. 9 o - • O O ■ O o. 0.0 . 0-00 ° .O '° • e o .0 . • O . °< 3£ ' °o o (3.65) . ?iV> ° b o'- °o°0 °0N -27.98 O Cbc-fcP - 33.02 ■“28.08" : (0. 10) -° O 0 ° = ° c 0 Oo o • ° ■ 33.12 o -.0 .0 -28.38 ■ (0.30) 0 • o ■ V °6 7 33.42 • O-o O - O ^ O.O- ■ (0.49) ■o-o *>. o ■ o • ° o -28.87 - 0 o o. o 0 Q, b • of- ■ 0 n ’ «’ * *„ • '"O ■„ °O.0 •O..0 k'O-o- -19.46 24.50 9 o-o o- o. (0.40) _ 0 O O-o ■ -19.86 24.90 *. • / if .* (2 0 . 1 0 ) - (20.10) © _ o - o •V *./*/* . ° 0 -° *TT*; c.’. °°•0 ° * 0 o °. ■ ° o (1.40) . '0 ■ o o. o ° ■ ‘O' ™ °0O° .o 0? • ,x‘ - O- o 0-0 > • ° o > ■ -11.26 26.30 • K • •* o ° 0 ° (0.30) ^ (5.03) o. 0? ‘ • > \ * -21.56 o ; o- 26.60 : ° o °. o.o • •. • .* x *, - 0-0 o : a - °. V ° O q ; o • o'C—1 )••o 9o. - o • n°-°' o ° 0 o o v . o • o .o ° -o ■ ° D -O • o - 0 ' o ° . o o 0. 0 ' • X .*t . • • t o • o o ■ o o o . •.0 • •0; ;o- ■ of ° - o ° ■ o .- o (3.50) ° 0° -o: ;

° o ° dP o ■ °.o *• .• *.*.<* o -33.90 38.94 • 0 o o •o °- d -33.93 — — 7 (0.03) ° c O • ------38.97 ° ■ o o O '.o.o O °. O 9 • ------O p - o. o.o OTo.O ------~ (2.79) •O-o. O o ° o °'o'°O . oo ------

285 BH - 102

Backioad Legend Depth D td n d Legend Depth Badboed Legend Depth Bedcad legend Depth Laval Abide) Laval (Ihidc) Laval (Ihidc) Laval (Ihidc)

5.04 r -15.01 (3.05) OO-o ; (0.50) 20.05 ; P < ■’•’•.o'.-’- O . o. O. O-o o a'P o 69 o- : Q ° 0 ? i V o V a • • ••’* :•/ ■ o ° - (1.00) - -■ °

a o - ° .

~ ~~ o o ° — ' — -T-. O • O. •: ’ * */ * * ’° o c -28.76“ ° a * ,.’x . o °6 °b • -8.96 O* 0 * 0 o ’ o *° o ’ o © o * -« o - o-o * ° 1 ©• -o ■ V-'-r • .A° .o . - - 0°0 °» :* V v ° o -o* = ^ 0o0 ©• 0 Q : (i.70) - (1 0. 0 0 ) ^O-o0^1° ' O . © O o- o • . 0 . 0 0 o-p.b • y'.-.-r-] -20.52 7 (3.45) o‘ 3? ® >° o. o . — — O. o : 15.70 V /0 • X. — — -20.98 X > o.of K . . o - : (i.30) 00.0 X • O • nf ■ X . . 9 * * • “. (oo * o ^ V / .v*- • j j ‘J.- ; _ — ; .. «b- • -11.96 - 17 00 ’ — —. * y \ *.* • *. ’ -32.21 ! 37.25 0. 0 ° . - - - •O. o. ! \ * ^ * u~m • 5 . o o • ,* ’• X • s*1 • » °-0.0 °0o. 7 (7.78) o • O'O . V • ■ . * ; (i.97) o-’ o?.. .' * • o - - (3.05) - \ v . - - of*.O 0-0 N O O ■u V .*• K - ° *0 ! • \ ; - - ’ • ", • o / • -34.18 ■ 39.22 o ■ ; -.o;- « - 2 o V °«°o f-0 i (0.25) o -34.43 _ 39.47 O? - "" ------■0° o ? o .* .•*«•* ; (0.50) .0 • o. -Las o . o KLQfl . * *: • -3 4 .9 3 ' 23.97

286 BH - 103

G rand L*v»I

4.95 m *.0.0. I

Bsdjoad I^ g o n d E*pth Radioed Legend Cfcpth I*v«l (Ihidc) Uwel (Ihidc) o o 4.95 . ' o.< o . O oo-o o. o - ° & ,° (2.40) ° b o 0 -?6°l (11.50) ■Oo O°o ^ ° 0b ° - '° ° o ° . C 7 ° 0 21.40 • i ? - feoQo -6.55 11.50 o. "o. O ® . ■° c # O ' ° O. -.x • O-o

& * ' •*• O O. (1.60) 0 • * a o \ • •• • O. (1.50) • • t., ^ o - o * -o . ?O o ° *o • • O ■ O • O -18.05 23.00 -8.05 13.00 O.’ o ' O o. o o • o •© . Q ’ °- © • o. ° o ■© °o.o o. . ' '© o o.o , ° ' O O o ol o b ° o .O O . o-o-o o ° o O o- *=>c°-o (11.65) 4 'o S « o O o A°- • O 0.'o ■o' r? o , o o O o o o (11*50) O .o. O' °- o O • o • G- O■ °o' o ° o ,'o o o 0 - (6 . 0 0 ) o. o . • ~ •o° O . o 0 . o ° 0 ° • O. b °o £v

287 Grain size frequency distributions!

% 100

80

60 — a— 12/18.5 12/19.5 12/25.5 -A- 12/30.6 40 12/35.5

0.5 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 12

288 % 100

80

13/16.8 13/19.5 13/28 50 -B- 13/30 -X- 13/33.5 40 13/37

0.5 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 13

289 o 1 0 0

90

80

70

60 16/24

H- 16/25.6 50 16/26.5

40 - e - 16/27.8

30

20

1 0 _

0 0 j 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 16

290 o 1 0 0 23/11 90 H— 23/13 23/16.5 80 -B- 23/17.3 -X- 23/18 70 23/18.8 -A- 23/19.4 60 -X- 23/21.35

50

40

30

20

10

0^ 0 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Borehole No. 23

291 % 100

90

80

60 23/23

H- 23/23.75 50 23/24.5 40 23/26

0 ^ — X — ------1------1------1------0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Borehole No. 23

292 % 100

70 24/14.75 24/17.5 60 24/18.5 -B- 24/20 -X- 24/22.5 24/23 40 -A ~ 24/30 -X- 24/32

0.5 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 24

293 % 1 00

90

80

24/32.5

- 4 - 24/34 24/34.6 50 -B- 24/35 24/35.5 40 24/37.5

20

0.5 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 24

294 o 1 0 0

90

80

70

60 26/15.5 26/17.5 50 26/18

40 -B- 26/18.5

30

20

10[

0 ^ 0 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Borehole No. 26

295 1 0 0

90

80

70 38/18

60 - 4 - 38/21 38/25.5 50 -B- 38/28 -X- 38/30 40 38/36 -A- 38/37.5 30

20

10

0 : 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 38

296 Grain-size distributions: cumulative curves

Cumulative % 1 0 0

12/18.5 -B- 12/19.5 50 12/25.5 -A- 12/30.6 40 -X- 12/35.5

0.5 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 12

297 Cumulative % 00

90

80

70

13/16.8 60 13/19.5 13/28 50 - e - 13/30 -A- 40 13/33.5 - k - 13/37 30

20

10

0 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 13

298 Cumulative % 100

90

80

70

16/24

16/25.6 50 16/26.5 40 -X- 16/27.8

0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Borehole No. 16

299 Cumulative %

23/11 23/13 60 23/16.5 - e - 23/17.3 50 -X- 23/18 23/18.8 -& r 23/19.4 -X- 23/21.35

0.5 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 23

i 300 Cumulative % 1 0 0

90

80

70

60 23/23 - t - 23/23.75 50 -B- 23/24.5

40 - e - 23/26

30

20

0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Borehole No. 23

301 Cumulative % 100

----- B----- 23/23 23/23.75

-B- 23/24.5 23/26

0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units

Borehole No. 23 Cumulative °/< 1 0 0

90

80

70 —- 24/14.75 - + - 24/17.5 60 24/18.5 ! -B - 24/20 50 -X - 24/22.5

40 - 0 - 24/23 -A " 24/30 30 S- 24/32

20 '

1 0 '

oi 0 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 24

303 Cumulative % 1 0 0

90

80

70

24/32.5 60 24/34 24/34.6 50 -B- 24/35 24/35.5 40 24/37.5 30

20

10 ■ )

0^ 0 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 24

304 Cumulative % 1 0 0

80

60 26/15.5

26/17.5

26/18 40 26/18.5

30

0.5 1 1.5 2 2.5 3 3.5 4 4.5

Size in phi units Borehole No. 26

305 Cumulative % 1 0 0

90

80

70 38/18 60 H- 38/21 BK- 38/25.5 50 -B- 38/28 -X- 38/30 40 38/36 -A- 38/37.5 30

20

10< :----- 0

0^ 0 1 1.5 2 2.5 3 3.5 4 4.5 Size in phi units Borehole No. 38

306 SEM surface microfeatures on quartz grains I

Sample from Borehole 38, Depth 36 m. (Dungeness Sand) ______1 2 3 4 5 6 7 8 9 10 11 12 1 3 1 4 1 5 Total % Angular/rounded RARR RAR A R A A AR R R 40/60 Topographically Positive Areas Very High Relief 0.0 High Relief e • * 20.0 Medium Relief * e • • 26.6 Low Relief •• * • *** ** 66.6 Smooth 0.0 Topographically Negative Areas Very High Relief 0.0 High Relief e 6.6 Medium Relief • * * 60.0 Low Relief * • e • 0 * 40.0 Smooth 0.0 Concholdal Fractures e * e e Concave Up ** • 46.6 Convex Up 0.0 Dish Shaped * * e 20.0 Concholdal Fracture and Arcurate Steps * e 13.3 Radiating Steps * * * * e 33.3 Edge Abrasion Cracks * 13.3 Severe Edge Abrasion • 6.6 Moderate Edge Abrasion *• * e * 40.0 Mild Edge Abrasion e • e e 26.6 Large Irregular Blocky Depression * * • • * •** * 66.6 Isolated Large ”V"shaped Blocks * e e * ** 53.3 Large Blocks • * e * 33.3 Large Flet Areas • ••• e * 60.0 Parallel Straight Scratches * * e 46.6 Curved Scratches * 13.3 Mechanical "Vs Projecting Surface * • • 80.0 Depressed Areas * 6.0 Irregular Pits 93.3 Sickle Pits * 6.6 Small Concholdal Fractures **• e e * •• 80.0 Smooth Capping Layer * • e • 26.6 Irregular Solution/Precipitation Surface * • 86.6 Chemical Oriented "Vs • * e 53.3 Large Isolated Chemical "Vs • 6.6 Upturned Plates •*• e 26.6 Crystallographlc Overgrowths * 6.6 Nos. 1-15 are grains. * means presence of feature.

307 S am ple MS1 (Midley Sand from near Old Midley Church)

1 2 3 4 5 6 7 8 9 1 0 11 1 2 1 3 1 4 1 5 Total % Angular/rounded RR RR AAR RRRA RR A A 33.3/ Topographically Positive Areas 66.6 Very High Relief 0.0 High Relief 0.0 Medium Relief • • a a 73.3 Low Relief * • a a a a a a 53.3 Smooth 0.0 Topographically Negative Areas Very High Relief 0.0 High Relief 0.0 Medium Relief * a a a • 66.6 Low Relief • a 46.6 Smooth a • 13.3 Concholdal Fractures Concave Up * a a 20.0 Convex Up 0.0 Dish Shaped a 6.6 Concholdal Fracture and Arcurate Steps • a 13.3 Radiating Steps * a 13.3 Edge Abrasion Cracks * a 13.3 Severe Edge Abrasion a 6.6 Moderate Edge Abrasion a a • 20.0 Mild Edge Abrasion a 6.6 Large Irregular Blocky Depression • a 86.6 Isolated Large "V'shaped Blocks a • a a »•• 80.0 Large Blocks a a a • * a a • 53.3 Large Flat Areas a a a 20.0 Parallel Straight Scratches * a a a a a a a 53.3 Curved Scratches a a a 20.0 Mechanical "Vs • Projecting Surlace a a a a a • a a a a 73.3 Depressed Areas * a a a • 26.6 Irregular Pits a a a a a a a • a • a 73.3 Sickle Pits a • 13.3 Small Concholdal Fractures a a a a . 33.3 Smooth Capping Layer • a 13.3 Irregular Solutlon/Preclpltation Surface • 73.3 Chemical Oriented "Vs e a a a a •• 46.6 Large Isolated Chemical "V"s • 6.6 Upturned Plates a a 13.3 Crystallographlc Overgrowths a 6.6 Nos. 1-15 are grains. * means presence of feature.

308 Sam ple N1 (Modem Sand from Lydd-on-Sea)

1 2 3 4 5 6 7 8 9 10 11 1 2 1 3 1 4 1 5 Total % Angular/rounded A R AA R RA A R A R A R A A 40/60 Topographically Positive Areas Very High Relief 0.0 High Relief a 6.6 Medium Relief • •**•• 40.0 Low Relief • a a • a a 40.0 Smooth • 6.6 Topographically Negative Areas Very High Relief 0.0 High Relief 0.0 Medium Relief • « a 53.3 Low Relief a a a a 26.6 Smooth a a 13.3 Concholdal Jpractures * * a Concave Up • • a • • 60.0 Convex Up a 6.6 Dish Shaped * a a 20.0 Conchoidal Fracture and Arcurate Steps * a a a 26.6 Radiating Steps a a * a 26.6 Edge Abrasion Cracks • 6.6 Severe Edge Abrasion 0.0 Moderate Edge Abrasion * • a a 26.6 Mild Edge Abrasion a a 13.3 Large Irregular Blocky Depression • a • a a a a 46.6 • Isolated Large "Vshaped Blocks a • * a 33.3 Large Blocks * * a a 26.6 Large Flat Areas a a 13.3 Parallel Straight Scratches * a •• 33.3 Curved Scratches a 6.6 Mechanical "Vs Projecting Surface • a a a a a 46.6 Depressed Areas * * a a 20.0 Irregular flls e a • a a • a a a 60.0 Sickle Pits 0.0 Small Conchoidal Fractures * * •• * a . a a 60.0 Smooth Capping Layer 0.0 * • * Irregular Solutlon/Preclpltatlon Surface *• a a 46.6 ** Chemical Oriented "V"s •*•*. 46.6 a * Large Isolated Chemical "Vs • a . 33.3 Upturned Plates * • « 13.3 Crystallographlc Overgrowths • • a a 33.3 No. 1-15 are grains. * means presence of feature. Detrltal mineralogy of Dungeness sediments In thin section o Q £ 2 — 4 CO a> aj c a> (A oj 3 k_ N <0 n i O O O l O L O O O O O L O M-incococoM-cjcoTrcvico^-io O L O l O L O L D C O O L O O ’-T-i-i-i-ojcvicococomco O - L i O L O O - N O 0)00000)0)0)0)0>0)0>0)^0) O O O O O O O O O COTfiOtONCOOCOW^rtlON O O O L O o L o o o i o i n i o o q i o o q ^■cDocvico-i-iocvj^-^rW^o i o ] V C i V C I V C M C J V C J V C M C I V C M C M C M C J V C J V C o o O L O L O O O O L O O I O I O L O L O L O L oco^cviocvicoT^t-^cocoi-cvi o + cvi n i + CJ + + + + + 310 + W U) O * - r - JQ *c5 15 ■a ■a o o 4—> #c CM 4~« o 4-4 § 4» < C c CD c . Q 3 o o O o CD O) c <0 c c CD E d c CD 3 _ v CD 8 c 3: co 3 + /3 d II APPENDIX 6 Heavy mineralogy of Midley Sand and Modern Sand sediments ______Q Q X CM CO (0 o a> CO 0> k- CO o O) > >» >* "a> "© cc < "o> "a> O JZ ja 2 U L 2 CO +— CO < * - * a> 3 E a CO . w c o CL| o CO CO CO c E L C © 3 5H aj co a> o n i t o o o o o o v o cvi o> cvi o o t o o o n i o o a> o co n o i n i o o co co O C N O C o i N <£) cvi CO o o o o i i- CVJ CO - i -i- eo o cvi n i n i -<* n i o o n i n i o ? o c 5 CO ^ CO "D _CD O — J _ C © >* >* © T3 CO o s > -’ \ c\j c\i n i > co o> ct cm z TJ > co n i cvi cd cd cvi

“ 2 o • ■O CVJ o o *L—* o . X CO O) _ k CO o o c CO 3 © CO co © c © _ v © . Q © © © O . Q O c © © © © > » > 311 Heavy mineralogy of 30-40 fraction . DC 2 < .© £ 2 LLI 2 0) 0) 3 E o a. O a 3 to E aj © © D t ' - T CVJ LO - 1 - o CO 1 CD O O f> L o CD CO C D C i v c O C O l O I o O C o o t lO O o o o o ? o c P CO ^ © ^ T3 © O : x O N O C N o o o Cvi o CO D C O L O D C O L O C O O CO Csj C O C j v c O C O lO O OO CVJ o C —I > © TO TO 03 »_ © o >s t o l T-" T-' -’ o o

O C D C ^ CO C -^ o T o 2 2 V CO O C CVJ

'© 2 TO CVI o o 4-1 © co 3 c o O © © o> c © © CO > , > © o . a k_ © a. © © © © © o o c © © k— 312 Heavy mineralogy (< 40) of coarse silt fraction CO < •O n JZ LU < — CO c 0 N - h 0> CO o O o o C O k. E CO c o>

Locality 3 Garnet Kyanite ' I- O' LO O o ir- LO Z Lydd-On-Sea T— 82.5 7.0 1.5 1.0 LO cvi o o i r h cvi LO - h o o 4.5 0.5 0.5 i *— 'co X T3 o o vP CM c in 3 o c o a> O) CO c CD k_ CO O Q. o W o c CO O > >N CO k_ CD a> CO CD C CD co CO 313 ------J V4 kivu ^VWUIWIUJ IIVU1 L/UII^Vii^JO

56 0.0 N

« 322 « 1*3 «110*

* to * 221 * 313

« 31 52 0.0 N

273

* 37 VI 114

48 0.0 N 0 6 0.0 W 2 0.0 W

BGS SITE POSITIONS

Sample no. CP EP GT HB TO ZR Total Folk class Mean

50+00/508 5.7 10.8.37.5 2.8 2.3 40.9 88.0 S 1.62 50+00/517 5.1 20.5 33.0 11.4 5.7 24.4 88.0 S ' 1.34

CP = C1 inopyroxene EP = Epidote GT = Garnet HB = Hornblende TO = Tourmaline ZR = Zircon

Relative abundances (in %) of the six major detrital translucent heavy mineral species in seabed sediments on the UK continental shelf f together with available grain size data. "Total" refers to the proportion of the heavy mineral suite that the six minerals together comprise.

314 % % distribution of Tourmaline varieties.

Locality Borehole/Sample Depth In m Brown Green Multicoloured Fibrous Blue Pink Yellow o i r? Oi O O CO CO CO CO - T CO CO CM D O) 05 O O 5 0 ) O ) O (D O w © N 0 ( CD - r C 1- 1 CM - T Dungeness 19.50 19 + 10 cm M + + + + CM i

o i o c o c o c 15.00 14 O O 00 CO O CO cm M O M + CM CO CM

36.00 1 8 37.50 22 N W z cm t t T CO -

near Old Midley Church 0.90 19 cm Lydd-on-Sea CO surface 23 315 APPENDIX - 9 1 Electron microprobe analysis of detrital garnets

SAMPLE NO. 24/35.5

Si02 T.i203 Ti02 FbO Cr203 HnO NgO Cat) Total

1 37.46 22.00 N.0. 33.70 N.D. 0.86 4.50 1.06 99.59 2 38.76 20.33 0.60 2.95 N.D. N.D. 0.38 36.68 99.70 O 37.49 21.48 N.D. 30.46 N.D. 1.31 1.18 7.91 99.83 4 37.94 21.69 N.D. 29.85 N.D. 0.43 3.25 6.18 99.34 5 39.13 22.66 N.0. 28.25 N.D. 0.80 7.55 1.38 99.78 6 38.62 20.11 0.41 4.60 N.D. 0.84 N.D. 35.08 99.66 7 37.24 21.31 N.D. 35.38 N.D. 0.21 1.81 3.76 99.70 8 37.86 21.65 N.D. 33.48 N.D. 0.71 4.53 1.07 99.30 9 37.97 22.09 N.D. 30.11 N.D. 0.66 5.41 3.25 99.49 10 37.29 21.38 0.24 30.69 N.D. 5.91 2.24 2.09 99.84 11 38.08 21.96 N.D. 29.21 N.D. N.D. 4.34 5.72 99.31 12 38.37 22.21 N.D. 27.57 N.D. 0.40 6.03 5.04 99.62 13 37.05 21.27 0.19 31.32 N.D. 0.69 1.29 7.75 99.56 14 37.64 21.67 0.29 27.77 N.D. 2.62 2.10 7.33 99.43 15 36.88 21.27 N.D. 31.61 N.D. 0.71 1.43 7.66 99.56 16 37.07 21.03 0.17 30.89 N.D. 0.47 1.45 8.58 99.66 17 37.48 21.43 N.D. 33.14 N.D. 0.55 3.65 3.39 99.63 18 38.51 22.15 N.D. 21.22 N.D. 0.91 4.09 12.69 99.57 19 37.55 21.81 N.D. 32.70 N.D. 0.40 3.52 3.63 99.61 20 37,50 21.51 0.13 30.83 N.D. 0.50 2.60 6.61 99.72 21 37.80 21.94 N.D. 29.92 N.D. N.D. 3.28 6.78 99.72 22 37.78 21.75 N.D. 30.00 N.D. 2.39 3.77 3.91 99,59 23 36.51 20.65 N.D. 20.01 N.D. 19.96 0.15 2.23 99.50 24 38.27 21.99 0.21 24.56 N.D. 1.17 2.27 11.16 99.62 Tc. 4. t - 38.01 21.85 N.D. 27.51 N.D. 3.03 1.78 7.41 99.59 26 37.53 21.53 N.D. 27.38 N.D. 2.70 1.80 8.80 99.78 27 37.49 21.80 0.16 27.38 N.D. 0.24 1.95 10.57 99.59 28 37.29 21,08 N.D. 33.92 N.D. 0.79 2.29 3.97 99.34 29 37.13 21,19 N.D. 25.38 N.D. 7.21 0.96 7.77 99.64 30 37,67 21,77 N.D, 31.97 N.D, 2*. 70 4.09 1,53 99.72 31 37.54 21.20 N.D. 25.64 N.D. 0.50 0,85 13.75 99.47 32 37.50 21.50 N.D. 29.55 N.D. 2,75 1.21 7.33 99.84 33 38,07 21.77 N.D. 28.61 N.D. 0.61 4.04 6.33 99.44 34 38.50 22.25 0.20 21,42 N.D, 0.27 3,73 13.50 99.87 35 37.06 21.26 N.D. 30.13 N.D. 1.49 0.97 8.73 99.65 36 37.33 21.62 N.D. 28,89 N.D. 0.60 2.21 8.91 99.56 37 37.83 21.89 N.D. 27.08 N.D. 0,45 3.06 9.30 99.61 38 36.62 21.30 N.D. 29.64 N.D. 8.51 1.65 1.88 99.60 39 37.68 21.71 N.D. 27.39 N.D. 0.37 2.14 10.59 99.89 40 37,37 21.38 N.D. 29.03 N.D. 0.93 1.85 9,03 99.59 41 37.71 21.66 N.D. 29.21 N.D. 0.96 1.86 8.37 99.76 42 37.14 21.54 N.D. 36,83 N.D. 0.75 2.84 0.59 99.68 43 37.57 21.49 .N.D. 30.55 N.D. 0.43 2.55 7.12 99.70 44 37.62 21.46 N.D. 28.41 N.D. 2.17 1.07 9.18 99.90 45 38.66 21.79 N.D. 25.30 N.D. 0.50 6.40 7.19 99.84 46 38,36 21.55 N.D. 24.64 N.D. 0.34 6,27 8.31 99.47 47 37.42 21.42 N.D. 30.75 N.D. 5.29 2.69 1.88 99.44 48 38.10 22.30 N.D. 31.34 N.D. 0.75 6.25 0.90 99.63 49 37.64 21.55 N.D. 26.07 N.D. 1.93 2.63 9.86 99.67 50 38.28 22.12 N.D, 22.71 N.D, 0.40 5.46 10.66 99.63

316 I SAHPLE HQ. 26/18

Si02 A1203 Ti02 FeO Cr203 MnO HgQ CaQ Total

1 37.54 21.78 N.D. 33.00 N.D, 0.75 2.49 5.50 101,06 2 38.52 22.14 N.D. 26.06 N.D. 0.42 5.84 6.80 99.78 3 37.82 21.73 N.D. 28.02 N.D. 2.35 1.63 8.14 99.68 4 39.09 22.68 N.D. 27.41 N.D. 5.23 3.12 2.14 99.68 5 36.39 20.43 0.53 15.35 N.D. 19.86 0.24 6.58 99.39 6 37.29 21.81 N.D. 30.36 N.D. 0.28 2.29 7.83 99.86 7 37.02 21.37 0.18 19.53 N.D. 15.74 0.80 5.17 99.82 8 37.19 21.63 N.D. 32.10 N.D. 2.99 1.28 4.44 99.62 9 37.08 21.53 0.17 32.98 N.D. 0.48 3.28 4.10 99.61 10 37.82 21.93 N.D. 34.44 N.D. N.D. 4.36 0,93 99.48 11 37.55 21.65 N.D. 30.20 N.D. 1.13 1.48 7.75 99.77 12 37.29 21.59 N.D. 30.91 N.D. 1.16 1.77 6.88 99.60 13 36.91 21.36 N.D. 33.69 N.D. 4.37 2.30 0.94 99.57 14 37.53 21.44 N.D. 35.43 N.D. 0.26 2.08 3.01 99.74 15 38.33 22.11 0.20 20.73 N.D. 0.76 2.32 15.18 99.62 16 38.67 21.72 N.D. 25.56 N.D. 1.31 3.84 8,76 99.86 17 a8.BB 22.54 N.D. 24.71 N.D. 0.59 8.51 4.46 99.68 18 37.73 22.19 N.D. 32.35 N.D. 1.81 4.82 0,93 99.81 19 38.07 21.65 N.D. 28.98 N.D. 1.91 1.98 7.28 99.86 20 37.55 21.63 N.D. 31.45 N.D. 0.60 3.19 5.15 99.56 21 37.55 21.57 N.D. 30.73 N.D. 0.90 2.61 6.32 99.67 22 37.99 21.58 0.25 25.87 N.D. 0,56 2.81 10.79 99.86 23 37.07 21.13 N.D. 32.99 N.D. 2.10 1.48 4.B5 99.61 24 37.94 21.70 N.D. 35.64 N.D. 0.46 3.52 0.70 99.95 25 37.64 21.82 N.D. 29.57 N.D. 1.35 2.88 6.56 99.83 26 36.99 21.11 N.D. 29.24 N.D. 3.01 0.98 8.14 99.46 27 38.70 22.18 N.D. 28.11 N.D. 0.58 6.53 3.70 99.80 28 36.84 21.46 N.D. 36.34 N.D. N.D. 2.69 2.27 99.60 29 37.08 21.52 N.D. 32.63 0.23 1.58 1.69 4.77 99.50 30 37.26 21.90 N.D. 31.86 N.D. * 0.34 0.76 7.82 99.93 31 37.78 21.67 0.20 2B.9B N.D. 1.99 1.21 8.86 100.68 32 37.88 21.82 N.D. 27.94 N.D. 1.34 6.33 3.76 99.06 33 37.93 22.20 N.D. 30.43 N.D. N.D. 3.08 7.11 100.75 34 37.20 21.53 N.D. 35.00 N.D. 0.65 1.97 4,01 100.35 35 37.94 21.80 N.D. 34.55 N.D. 1.33 3.18 2.08 100.88 36 37.12 21.42 N.D, 29.78 N.D, 1.31 1.25 8.07 98.96 37 37.31 21.89 N.D, 31.18 N.D. 6.36 2.93 1,06 100.73 38 38.12 21.28 N.D. 14.52 N.D. 7.41 0.48 17.43 99.23 39 37.51 21.59 N.D. 31.63 N.D. 0.75 4.59 1.84 97.91 40 37.97 21.90 N.D. 33.39 N.D. 0.91 4.48 1.50 100.14 41 37.64 21.13 0.21 30.57 N.D. 1.16 1.35 7.95 100.02 42 37.65 21.77 N.D. 36.49 N.D. 1.16 2.08 2.26 101.39 43 37.56 21.86 . N.D. 33.97 N.D. 3.07 2.94 1.33 100.73 44 38.43 22.03 N.D. 31.59 N.D. 1.15 3.20 5,09 101.49 45 37.60 21.23 0.21 11.90 N.D. 14.38 N.D. 15.33 100.63 46 38.74 22.56 N.D. 33.20 N.D. 1.12 5.28 1.10 102.00 47 38.16 21.85 N.D. 31.65 N.D. 0.78 1.77 7.70 101.91 48 37.54 21.78 N.D. 33.00 N.D. 0.75 2.49 5.50 101.06 49 37.82 21.73 N.D. 28.02 N.D, 2.35 1.63 8.14 99.68 50 37.02 21.37 0.18 19.53 N.D. 15.74 0.80 5.17 99.82

3V7 SAHPLE NO. 3B/15

Si02 A1203 Ti02 FeO Cr203 HnO HgO CaO Total

1 37,66 21.18 N.0. 20.27 N.D. 4.51 0.25 15.68 99.54 n L 37.55 21.54 N.D. 31.20 N.D. 2.97 1.54 4.83 99.63 3 38.17 21.92 N.D. 34.33 N.D. 1.06 1.98 2.14 99.60 4 37.64 21.27 N.D. 14.92 N.D. 11.45 0.27 14.16 99.71 5 3B.42 21.46 0.27 16.42 N.D. 2.47 0.49 20.14 99.66 6 37.95 21.81 N.D. 26.80 N.D. 1.28 1.92 9.82 99.57 7 38. IB 21.75 N.D. 31.02 N.D. 0.76 4.00 4.22 99.93 & 37.68 21.83 N.D. 29.74 N.D. 4.65 2.57 3.29 99.75 9 37,44 21.76 N.D. 30.07 N.D. 1.02 2.21 7.26 99.76 10 36.73 21.58 N.D. 30.58 N.D, 7.45 2.06 0.49 98.88 11 38.58 22.21 N.D. 29.77 N.D. 0.36 5.06 3.58 99.57 12 38.00 22.Oi 0.18 27.01 N.D. 4.48 0.93 7.14 99.74 13 37.67 21.95 N.D. 34.09 N.D. N.D. 4.18 1.61 99.50 14 37.96 21.52 0.18 27.25 N.D. 2.65 1.23 8.93 99.71 15 38.14 21.75 N.D. 32.10 N.D. 0.98 4.85 1.61 99.43 16 37.71 21.76 N.D, 32.82 N.D. 2.11 3.31 1.74 99.45 17 37.83 21.64 N.D. 30.29 N.D. 0.44 3.33 6.27 99.80 IB 37.82 21.55 N.D. 33.45 N.D. 0.84 1.76 4.20 99.60 19 38.42 22.44 N.D, 25.69 N.D. 5.35 6.01 1.85 99.76 20 37.46 21.80 N.D. 34.61 N.D, N.D. 2.23 3.43 99.53 21 37.68 21.58 N.D, 32.30 N.D. 2.32 1.37 4.23 99.47 22 37.55 21.30 N.D. 30.01 N.D. 5.79 3.17 1.69 99,50 23 37.91 21.56 N.D. 13.64 0.19 9.05 0.30 16.87 99.51 24 37,72 22.09 N.D. 31.79 N.D. 0.52 2.79 4.57 99.48 25 37.85 21.53 0.17 30.60 N.D. 0.46 1.95 7.12 99.67 26 37.25 21.39 N.D. 36.59 N.D. 0.33 3.32 0.61 99.49 27 37,59 21.36 0.23 14.43 N.D. 9.15 0.28 16.86 99.88 28 37.63 21.71 N.D. 33.61 N.D. 0.55 2.90 3.34 99.73 29 37.65 22.02 N.D. 24.78 N.D. 8.94 5.46 0.77 99.62 30 33.22 21.96 N.D. 24.57 N.D. 4.59 1.79 8.52 99.65 31 37.94 22.13 N.D. 26.47 N.D. 5.61 5.87 1.76 99.78 32 37.64 21.63 N.D. 34.67 N.D. N.D. 2.26 3.24 99.45 33 37.43 21.62 N.D. 32.88 N.D. 2.50 1.33 3.71 99.46 34 37.79 21.27 N.D. 29.64 N.D, 5.93 3,23 1.69 99.54 35 38.59 21.88 N.D. 24.54 N.D. 0.86 7.46 6.15 99.47 36 37.91 22.16 N.D, 29.11 N.D. 0.40 2.36 7.89 99.84 37 38.03 22.14 N.D. 25.79 N.D. 0,68 3.84 8.93 99.41 38 38.16 21.90 N.D. 25.82 N.D. 3.70 1.33 8.34 99.24 39 37.82 21.73 N.D. 30.23 N.D. 1.80 2.04 5.93 99.54 40 39.29 22.69 N.D. 22,24 N.D. 0.33 8.92 6.05 99.52 41 38.39 22.24 N.D. 30.71 N.D. 0.61 5.41 2.40 99.75 42 37.84 21.63 0.18 27.77 N.D. 0.63 1.76 9.81 99.62 43 37.80 21.85 N.D. 27.62 N.D. 5.95 3.32 3.06 99.60 44 37.64 21.36 0.19 31.08 N.D. 1.70 1.24 6.65 99.86 45 38.62 22.11 .N.D. 27.92 N.D. 0.51 5.42 5.25 99.82 46 38.38 22.10 N.D. 24.41 N.D. 0.49 5.19 8.99 99.56 47 38.92 22.48 N.D. 26.19 N.D. 0.59 9.36 1.80 99.34 4B 37.70 21,55 N.D. 32.39 N.D. 2.61 4.13 1.34 99.73 49 38.38 22.28 N.D. 29.85 N.D. 0.90 6.98 1.22 99.60 50 39.51 28.77 N.D. 6.57 N.D. N.D. N.D. 24.75 99.61

318 SAMPLE NO. MSI (Midley Sand)

IV • Si 02 A1203 Ti02 FeO Cr203 MnO MgO CaO Total

i 36.69 21.03 N.D. 28.10 N.D. 2.09 1.91 7.12 96.94 2 38.84 22.47 N.D. 29.60 N.D. 0.29 7.15 1.58 99.93 3 38.59 22.29 N.D. 34.49 N.D. 0.59 4.50 2.24 102.70 4 37.42 22.35 N.D. 33.10 N.D. 0.54 4.25 2.50 100.15 5 35.73 21.00 N.D. 2B.40 N.D. 6.82 1.55 4.05 97.56 A 35.79 21.46 N.D. 35.43 N.D. 0.22 3.35 1.04 97,28 7 37.57 21.35 N.D. 26.17 N.D. 1.28 2.47 9.64 98.48 8 36.67 21.04 N.D. 32.53 N.D. 0.13 1.72 5.38 97.46 9 36.66 20.87 N.D. 29.86 N.D. 1.37 1.41 7.27 97.44 10 37.79 21.55 N.D. 22.32 N.D. 0.69 5.33 10.12 97.81 11 38.20 21.42 N.D. 21.90 N.D. 0.64 4.60 11.39 98.14 12 37.05 20.87 N.D. 30.88 N.D. 2.90 2.44 4.65 98.79 13 36.67 21.13 N.D. 37.94 N.D. N.D. 2.08 0.73 98.55 14 37.20 21.71 N.D. 27.21 N.D. 0.85 1.83 10.12 98.92 15 38.39 21.83 N.D. 19.03 N.D. 0.41 8.90 8.27 96.83 16 37.02 21.37 N.D. 28.46 N.D. 0.91 1.10 9.44 98,31 17 36.55 21.16 N.D. 32.00 N.D. 0.39 1.85 5.49 97.43 18 37.38 21.45 N.D. 29.58 N.D. 0.32 6.89 1.57 97.18 19 39.41 22.95 N.D. 32.86 N.D. 0.38 5.92 2.24 103.76 20 38.05 22.08 N.D. 31.23 N.D. 0.36 5.61 2.15 9 9 .4B 21 37.81 21.63 N.D. 30.03 N.D. 2.20 1.34 7.13 100.15 22 38.67 22.05 N.D. 24.38 N.D. 0.47 2.80 12.55 100.92 23 38.53 22.26 N.D. 30.08 N.D. 0.28 7.29 1.55 99.99 24 38.34 26.97 N.D. 3.62 N.D. 0.15 1.91 23.05 94.03 25 37.43 21.10 N.D. 9.01 N.D. N.D. 2.66 23.57 93.78 26 37.43 21.12 N.D. 32.80 N.D. 1.87 2.24 3.76 99.22 27 38.53 21.84 N.D. 30.18 N.D. 0.86 2,64 7.43 101.48 28 3B.49 22.19 N.D. 29.87 N.D. 0.37 2.23 8.76 101.92 29 38.74 27.30 N.D. 3.31 N.D. N.D. 2.09 23.33 94.77 30 38.42 22.19 N.D. 31.17 N.D. 0.29 2.35 7.57 101.99 31 37.78 21.13 N.D. 23.55 N.D. 13.63 0.65 4.74 101.48 32 38.55 22.15 N.D. 29.63 N.D,* 2.44 1.47 7.51 101.75 33 38.77 22.00 N.D. 29.83 N.D. 0.58 2.02 8.78 101.99 34 38.96 22.09 N.D. 28.92 N.D. 0,80 5.25 4.82 100.83

319*. Si02 A12Q3 Ti02 FeO Cr 203 NnO NgO CaD Total

1 36.47 12.97 2.14 10.06 N.D. 0.26 N.D. 36.33 98.22 2 36.15 13.14 1.94 . 10.04 N.D. 0.27 0.06 35.86 97.46 3 38.27 20.56 0.47 3.11 N.D. 0.24 0.10 36.18 98.93 4 36.65 21.67 0.16 27.02 N.D. 7.37 1.13 5.05 99.04 5 36.62 22.02 0.22 28.22 N.D. 7.29 1.17 5.11 100.65 6 38.44 23.01 N.0. 25.45 N.D. 0.48 9.74 2.00 99.12 7 34.95 20.48 N.D. 18.01 N.D. 18.14 0.83 2.38 94.79 8 37.14 21.78 N.0. 33.29 N.D. 0.26 2.60 4.03 99.10 9 35.80 21.18 0.18 18.23 N.D. 19.42 1.13 2.38 98.31 10 37,49 22,27 N.D. 35.51 N.D. 2,20 2.34 2.15 101.97 11 37.15 21.96 0.19 33.14 N.D. N.D. 1.61 6.61 100.65 12 38.46 22.85 N.D. 31.13 N.D. 1.69 4.58 4.17 102.88 13 37.50 22.61 N.D. 29.75 N.D. 1.56 4.44 4.47 100.33 14 36,73 21.78 N.D. 12.85 N.D. 27.47 0.23 2.75 101.82 15 36.19 21.28 0.18 12.16 N.D. 26.56 0.32 2.53 99.21 16 36.19 21.28 0.18 12,16 N.D. 26.56 0.32 2.53 99.21 17 38.65 22.95 0.17 29.49 N.D. 0.53 4.74 6.15 102.68 18 37.34 22.29 N.D, 28.69 N.D. 0.51 4.53 6.12 99.48 19 36.42 21.77 N.D. 30.49 N.D. 1.27 2.52 5.83 98.29 20 35.75 21.45 N.D, 31.76 N.D. 9.26 0.69 0.28 99.18 21 37.29 22.07 N.D, 29.75 N.D. 0.78 3.65 6.21 99.74 22 39.21 23.47 N.D. 19.72 N.D. 0.34 11.16 5.74 99.63 23 36.73 21.78 N.D. 29.88 N.D. 0.47 1.78 8.32 98.95 24 36.25 21.62 N.D. 29.54 N.D. 5,77 2.28 2.05 97.51 25 36.53 21.55 N.D. 28.89 N.D. 3.39 1.64 6.20 98.20 26 37,03 22.04 N.D. 33.58 N.D. N.D. 3.06 4.14 99.84 27 37.81 22.15 N.D. 21.99 N.D. 1.25 2.04 14.29 99.53 28 36.78 21.42 N.D, 27.52 N.D. 3.10 1.43 8.61 98.86 29 37.51 22.06 0,21 30.66 N.D. 1.98 1.68 7.03 101.11 30 36.15 21.33 N.D. 37.04 N.D. N.D. 2.58 0.50 97.60 31 37.99 21.06 0.93 2.77 N.D. 0.54 0.21 34.74 98.25 32 35.95 21.62 N.D. 21.65 N.D. 16,69 0.90 1.57 98.37 33 36.78 21.65 0.31 20.60 N.D. 6.33 0.89 12.53 99.07 34 36.66 21.65 0.27 30.95 N.D. 0.34 1.83 6.75 98.45 35 36.81 21.62 N.D. 27.57 N.D. ‘ 1.09 2.48 8.37 97.94 36 37.57 22.35 N.D. 28.90 N.D. 0.59 5.03 4.62 99.06 37 36.55 21.19 0.26 30.33 N.D. 0.97 1.44 7,66 98.39 38 36.08 21.71 N.D. 30.91 N.D. 2.96 4.26 1.00 96.92 39 36.98 21.70 N.D. 30.72 N.D. N.D. 2.69 6.51 98.59 40 36.37 21.72 N.D. 35.71 N.D. 1.56 2.09 1.53 98,99 41 36.34 21.61 N.D. 34.53 N.D. 1.49 3.49 1.15 98.59 42 36.94 21.77 N.D. 28.73 N.D. 0.56 2.05 8.74 98.79 43 36.48 21.96 N.D. 29.54 N.D. 7.27 3.05 0.97 99.27 44 36.83 21.90 N.D. 31.52 N.D. 0.40 5.13 2.41 98.18 45 35.90 21.39 N.D. 30.21 N.D. 4.87 3.20 1.12 96.69 46 36.52 22.09 N.D. 32.16 N.D. 1.52 5.08 1.25 98.62 47 37.60 21.76 N.D. 33.68 N.D. 0.84 3.03 2.71 99.60 48 36.21 21.70 . N.D. 31.67 N.D. 2.44 2.28 3.54 97.83 49 37.90 20.87 0.22 4.45 N.D. 1.32 0.02 32.48 97.27 50 35.96 21.20 N.D. 30.13 N.D. 0.29 1.84 6.49 95.91

320 SAMPLE NO. Hi (Modern Sand)

Si02 A1203 Ti02 FeO Cr203 HnO HgO CaO Total

1 36.93 20.97 N.D. 25.32 N.D. 0.34 4.72 3.41 91.70 2 36.99 21.22 N.D. 24.56 N.D. 0.35 4.93 3.48 91.52 3 38.37 21.31 N.D. 24.64 N.D. 0.31 5.01 3.58 93.23 4 38.44 22.25 N.D. 29.48 N.D. 0.57 3.01 6.19 99.94 5 39.38 22.35 N.D. 28.58 N.D. 0.66 6.17 4.10 101.24 & 38.81 22.31 N.D. 36.13 N.D. 2.58 1.96 2.50 104.28 7 39,83 23.21 N.D. 26.09 N.D. 0.94 6.26 7.04 103.36 8 39.19 22.55 N.D. 30.91 N.D. 1.89 1.82 8.68 105.04 9 38.41 22.16 N.D. 30.23 N.D. 1.95 1.61 8.24 102.59 10 38.04 21.87 N.D. 32.30 N.D. N.D. 1.43 7.63 101.26 11 37.78 21.88 N.D. 35.41 N.D. 2.17 2.19 2.23 101.66 12 37.66 21.66 N.D. 30.47 N.D. 2.03 1.33 8.03 101.17 13 38.15 21.77 N.D. 27.13 N.D. 3.47 1.27 9.94 101.73 14 37.73 21.76 N.D. 29.21 N.D. 1.55 1.39 9.23 100.87 15 3 8 .IB 22.18 N.D. 32.96 N.D. 0.28 2.74 5.81 102.13 16 37,66 21.81 N.D. 29.52 N.D. 1.41 1.82 7.95 100.17 17 39.09 22.41 N.D. 29.85 N.D. 0.74 3.85 7.28 103.21 18 38.32 21.82 N.D. 31.47 N.D. 0.64 1.32 7.88 101.44 19 37.14 21.47 0.17 24.86 N.D. 17.11 0.72 0.35 101.82 20 38.08 22.10 N.D. 36.06 N.D. 1.42 2.70 1.37 101.71 21 37.88 21.80 N.D. 33.07 N.D. 2.05 1.42 5.64 101.86 22 38.04 22.03 N.D. 30.59 N.D. 0.52 2.84 7.69 101.71 23 37.55 21.34 N.D. 32.58 N.D. 4.02 1.36 4.84 101.68 24 38.15 21.76 N.D, 34.39 N.D. 0.21 2.74 4.59 101.84 25 38.12 21.94 N.D. 29.85 N.D. 7.53 2.39 2.82 102.64 26 38.37 22.37 N.D. 31.88 N.D. 1.38 2.64 5.56 102.19 27 38.31 21.84 N.D. 30.36 N.D. 1.17 1.92 8.04 101.65 28 38.39 21.84 N.D. 29.51 N.D. 1.32 1.70 9.57 102.32 29 38.33 22.18 N.D. 28.83 N.D. 2.38 1.84 8.79 102.35 30 37.49 21.52 N.D. 33.06 N.D. 2.79 1.73 3.74 100.33 31 38.73 22.41 0.18 31.40 N.D. N.D. 4.12 5.65 102.49 32 38.17 22.18 N.D. 35.61 N.D. 0.90 2.89 2.41 102.15 33 38.22 22.43 N.D. 34.76 N.D. O’. 38 4.26 2.01 102.06 34 38.67 21.95 N.D. 29.03 N.D. 0.81 3.20 6.16 101.81 35 37.73 21.77 N.D. 27.19 N.D. 3.78 1.25 9.53 101.25 36 39.04 22.36 N.D. 25,77 N.D. 1.86 4.15 8,85 102.02 37 38,70 22.19 N.D. 29.80 N.D. 1.24 2.34 7.59 101.85 3B 38,19 22.33 N.D. 28.80 N.D. 1.37 1.68 9.64 102.00 39 39.96 22.63 N.D. 20.90 N.D. 0.30 7.68 10.26 101.73 40 39.00 22.23 N.D. 32.31 N.D. 2.97 3.42 3.70 103.62 41 38.30 22.19 N.D. 36.53 N.D. 0.94 3.89 0.91 102.77 42 38.04 22.24 N.D. 35.95 N.D. 1.10 2.97 1.50 101.80 43 37.81 22.31 N.D. 35.31 N.D. 1.90 3.16 1.60 102.09 44 38.70 22.61 N.D. 24.43 N.D. 0.61 2.80 13.14 102.28 45 38.33 21.98 N.D, 34,58 N.D. N.D. 1.81 5.99 102.68 46 37.24 22.24 .N .D. 28.47 N.D, 0.37 6.56 3.19 98.06 47 38.67 21.95 N.D. 29.03 N.D. 0.81 3.20 8.16 101.81 48 37.81 22.31 N.D. 35.31 N.D. 1.90 3.16 1.60 102.09 49 37.49 21.52 N.D. 33.06 N.D. 2.79 1.73 3.74 100.33 50 38.70 22.19 N.D. 29.80 N.D. 1.24 2.34 7.59 101.85

321 SAHPLE NO. 24/35.5

NutbET of ions on the b asis of 24 Oxygens HDleZ end aeabers

Grain No Si 02 A1203 Ti02 FeO MnO HgO CaO Total Al. Sp. Py* S r. And.

1 5.94 4.11 0.00 4.47 0.12 1.06 0.18 5.83 76.70 1.98 18.24 3.09 2 5.93 3.66 0.07 0.38 0.00 0.09 6.01 6.13 0.65 0.00 1.47 88.09 9.78 3 6.00 4.05 0.01 4.08 0.18 0.28 1.36 5.89 69.18 3.01 4.80 23.00 - 4 6.00 4.04 0.01 3.95 0.06 0.77 1.05 5.82 67.85 0.99 13,15 17.97 - 5 6.04 4.12 0.01 3.64 0.11 1.74 0.23 5.71 63.78 1.85 30.38 3.99 - 6 5.94 3.64 0.05 0.59 0.11 0.04 5.78 6.15 3.57 1.78 0.65 83.74 10.24 7 6.00 4.04 0.01 4.76 0.03 0.43 0.65 5.88 81.09 0.49 7.35 11.07 - 8 6.00 4.04 0.01 4.44 0.10 1.07 0.18 5.79 76.69 1.65 18.44 3.14 - 9 5.96 4.09 0.00 3.95 0.09 1.27 0.55 5.86 67.50 1.51 21.58 9.32 - 10 6.00 4.05 0.03 4.13 0.80 0.54 0,36 5.83 70.84 13.80 9.18 6.16 -

11 5.98 4.07 0.00 3.84 0.01 1.02 0.96 5.83 65.80 0.25 17.35 16.52 - 12 5.96 4.07 0.00 3.59 0.05 1.40 0.84 5.88 61.03 0 70 23.74 14.27 - 13 5.94 4.02 0.02 4.20 0.09 0.31 1.33 5.94 70.80 1.58 5.17 22.43 - 14 5.98 4.06 0.04 3.69 0.35 0.50 1.25 5.79 63.75 6.08 8.56 21.50 -

15 5.93 4.03 0.01 4.25 0.10 0.34 1.32 6.01 70.73 1.59 5.69 21.89 - 16 5.°5 3.98 0.02 4.15 0.06 0.35 1,48 6.04 68.71 1.07 5.76 24.42 - 17 5.98 4.03 0.00 4.42 0.07 0.87 0.58 5.94 74.41 1.25 14.59 9.74 - 18 5.97 4.04 0.01 2.75 0,12 0.94 2.11 5.91 46.51 2.03 15.81 35.59 - 19 5.97 4.09 0.00 4.35 0.06 0.84 0.62 5.86 74.23 0.94 14.23 10.55 - 20 5.97 4.04 0.02 4.10 0.07 0.62 1.13 5.92 69.37 1.14 10.43 19.07 - 21 5.97 4.09 0.01 3.95 0.02 0.77 1.15 5.89 67.11 0.29 13.08 19.51 - 22 5.98 4.06 0.00 3.97 0.32 0.88 0,66 5.85 67.94 5.49 15.19 11.30 - 23 5.98 3.98 0.01 2.74 2.77 0.04 0.39 5.94 45.76 46.95 0.67 5.54 1.00 24 6.00 4.06 0.02 3.22 0.15 0.53 1.87 5.78 55.73 2.66 9.17 32.42 - 25 6.03 4.08 0.01 3,65 0,41 0.42 1.26 5.73 63.62 7.06 7.31 21.94 - 26 5.98 4.05 0.00 3.65 0.36 0.43 1.50 5.94 61.40 6.14 7.19 25.26 - 27 5,94 4.07 0.02 3.63 0.03 0.46 1.79 5.91 61.32 0.57 7.79 30.30 - 28 5.99 3.99 0.02 4.56 0.11 0.55 0.68 5.90 77.29 1.83 9.28 11.60 - 29 5.97 4.01 0.01 3.41 0.98 0.23 1.34 •5.96 57.25 16.48 3.83 22.44 - 30 5.98 4.08 0.00 4.25 0.36 0.97 0.26 5.83 72.77 6.21 16.58 4.44 - 31 5.96 3.97 0.01 3.41 0.07 0.20 2.34 6.01 56.62 1.11 3.34 38.81 - 32 6.00 4.06 0.01 3.96 0.37 0.29 1.26 5.87 67.35 6.33 4.90 21.40 - 33 5.98 4.03 0.01 3.76 0.08 0.95 1.07 5.85 64.25 1.39 16.13 18.18 - 34 5.96 4.06 0.02 2.77 0.04 0.86 2,24 5.91 46.92 0.61 14.56 37.89 - 5.95 4.02 0.00 4.05 0.20 0.23 1.50 5.99 67.60 3.41 3.89 25.10 - 36 5.93 4.05 0.00 3.84 0.08 0.52 1.52 5.96 64.41 1.37 8.77 25.42 - 37 5.96 4.06 0.01 3.57 0.06 0.72 1.57 5.91 60.31 1.01 12.11 26.49 - 38 5.94 4.08 0.01 4.02 1.17 0.40 0.33 5.92 67,99 19.72 6.72 ' 5,51 - 39 5.96 4.05 0.01 3.62 0.05 0.50 1.80 5.97 60.67 0.84 8.44 30.05 - 40 5.96 4.02 0.01 3.87 0.12 0.44 1.54 5.97 64.76 2.09 7.35 25.79 - 41 6.00 4.06 0.00 3.89 0.13 0.44 1.43 5.88 66.05 2.20 7.51 24.24 - 42 5.98 4.08 0.00 4.96 0.10 0.68 0.10 5.84 84.88 1.73 11.67 1.73 - 43 5.97 4.03 0.00 *4.06 0.06 0.60 1.21 5.94 68.43 0.97 10.19 20.41 - 44 6.01 4.04 0.00 3.79 0.29 0.25 1.57 5.91 64.16 4.95 4.30 26.57 - 45 5.99 3.98 0.01 3.28 0.07 1.48 1.19 6.02 54.49 1.12 24.57 19.82 - 46 5.95 3.94 0.01 3.20 0.05 1,45 1.38 5.88 52.72 0.85 24.65 18.96 2.80 47 6.00 4.05 0.01 4.13 0.72 0.64 0.32 5.81 71.00 12.32 11.04 5.56 - 48 5.96 4.11 0.00 4.10 0.10 1.46 0.15 5.81 70.59 1.69 25.11 2.60 - 49 5.95 4.02 0.01 3.45 0.26 0.62 1.67 6.00 57.50 4.31 10.31 27.81 - 50 5.92 4.03 0.01 2,94 0.05 1,26 1,77 6.02 48.84 0.88 20.93 29.35 -

A1,=A!sandine Sp.=Spessartine Py.=Pyrope Gr.=Srossular And.=Andraoite

322 SAMPLE NO. 26/18

Nuttber of ions on the b asis of 24 Oxygens MoleZ end aeabers

Grain No Si02 A1203 Ti02 FeO MnO MgO CaO Total Al. Sp. Py. 6 r. And.

1 5.93 4.06 0.01 4.36 0.10 0.59 0.93 5.98 72.91 1.68 9.82 15.56 _ 2 5.98 4.05 0.01 3.38 0.06 1.35 1.13 5.92 57.14 0.93 22.83 19.10 - 3 6.00 4.07 0.01 3.72 0.32 0.38 1.38 5.81 64.08 5.46 6.61 23.85 - 4 6.13 4.19 0.00 3.60 0.70 0.73 0.36 5.38 66.82 12.93 13.56 6.69 - 5 5.92 3.92 0.06 2.09 2.74 0.06 1.15 5.94 33.50 46.12 1.00 15.31 4.00 6 5.94 4.09 0.00 4.04 0.04 0.54 1.34 5.96 67.79 0.64 9.13 22.41 - 7 5.97 4.06 0.02 2.64 2.15 0.19 0.90 5.87 44.87 36.62 3.27 15.24 - 8 5,98 4,10 0.02 4.32 0.41 0.30 0.77 5.80 74.50 7.03 5.25 13.20 - 9 5.93 4.05 0.02 4.41 0.06 0.78 0.70 5.95 74.03 1.09 13.10 11.77 - 10 6.00 4.10 0.01 4.57 0.00 1.03 0.16 5.76 79.29 0.04 17.91 2.75 - 11 5.99 4.07 0.02 4.03 0.15 0.35 1.32 5.86 68.78 2.62 5.98 22.60 - 12 5.96 4.07 0.00 4.13 0.16 0.42 1.18 5.89 70,17 2.65 7.17 20.01 - 13 5.96 4.07 0.00 4.55 0.60 0.55 0.16 5.87 77.58 10.17 9.44 2.78 - 14 6.02 4.06 0.01 4.75 0.04 0.50 0.52 5.81 81.89 0.62 8.56 8.93 - 15 5.96 4.05 0.02 2.70 0.11 0.54 2.53 5.87 45.90 1.86 9.14 43.03 - 16 6,05 4.00 0.00 3.34 0.17 0.90 1.47 5.88 56.84 2.94 15.23 24.99 - 17 5.96 4.07 0,00 3.17 0.08 1.94 0.73 5.92 53.51 1.30 32.82 12.36 - 18 5.97 4.14 0.00 4.28 0.24 1.14 0.16 5.82 73.63 4.17 19.51 2.68 - 19 6.04 4,05 0.01 3.84 0.26 0.47 1.24 5.81 66.20 4.42 8.06 21.32 - 20 5.97 4.06 0.01 4.18 0.08 0.76 0.88 5.90 70.94 1.34 12.81 14.88 - 21 5.98 4.05 0,00 4.09 0.12 0.62 1.08 5.91 69.24 2.03 10.47 18.22 - 22 5.98 4.00 0.03 3.41 0.07 0.66 1.82 5.96 57.15 1.25 11.06 30.49 - 23 5.99 4.02 0.0 0 4.45 0.29 0.36 0.84 5.94 75.02 4.84 5.97 14.13 - 24 6.05 4.08 0.00 4.75 0.06 0.84 0.12 5.77 82.34 1.08 14.51 2.08 - 25 5.97 4.08 0 ,0 0 3.92 0.18 0.68 1.12 5.90 66.46 3.09 11.54 18.90 - 26 5.95 4.00 0.02 3.93 0.41 0.23 1.40 5.98 65.77 6.85 3.89 23.44 - 27 6.01 4,06 0.00 3.65 0.08 1.51 0.62 5.85 62.32 1.31 25.83 10.54 - 28 5.93 4.08 0.0 0 4.89 0.00 0.65 0.39 5,94 82.45 0.08 10.87 6.59 - 29 5.95 4.07 0,02 4.38 0.22 0.40 0.82 * 5.82 75.26 3.69 6.89 14.03 - 30 5.97 4.14 0.0 0 4.27 0.05 0.18 1.34 5.84 73.15 0.78 3.08 22.99 - 31 5.98 4.05 0.02 3.84 0.27 0.29 1.50 5.89 65.13 4.52 4.85 25.50 - 32 5.95 4.04 0.00 3.67 0.18 1.48 0,63 5.96 61.57 2.97 24.74 10.59 - 33 5.94 4.10 0.02 3.99 0.00 0.72 1.20 5.91 67.53 0.04 12.19 20.24 - 34 5.96 4.06 0.02 4.69 0.09 0.47 0.69 5.93 79.00 1,49 7,92 11,56 - 35 6.01 4.07 0,01 4.57 0.18 0.75 0.35 5.86 78.11 3.03 12.83 6.02 - 36 5.99 4.07 0.01 4.02 0.18 0.30 1.39 5.89 68.19 3.05 5.09 23.67 - 37 5.95 4.11 0.00 4,16 0.86 0.70 0.18 5.89 70.55 14.56 11.79 3.05 - 38 6.02 3.96 0.01 1.92 0.99 0.11 2,95 5.94 31.81 16.66 1.85 48.65 1.00 39 6.02 4.09 0.01 4.25 0.10 1.10 0.32 5.77 73.67 1.79 19.03 5.48 - 40 5.99 4.07 0.01 4.40 0.12 1.05 0.25 5.83 75.54 2.06 18.08 4.32 - 41 6.01 3.98 0.03 4.08 0.16 0.32 1.36 5.92 6B.94 2.64 5.43 22.71 0.78 42 5.95 4.07 0.00 . 4.84 0.16 0.49 0.38 5.87 82.46 2.66 8.33 6,54 - 43 5.98 4.10 0.0 0 4.52 0.42 0.70 0.23 5.86 77.18 7.07 11.86 3.84 - 44 5.99 4.05 0.00 4.12 0.15 0.74 0.85 5.86 70,24 2.58 12.68 14.48 - 45 5.93 3.95 0.02 1.57 1.92 0.03 2.59 6.02 24.58 31.89 0.49 40.53 2.49 46 5.98 4.11 0.00 4.29 0.15 1.21 0.18 5.83 73.54 2.51 20.80 3.12 - 47 5.96 4.02 0.02 4.14 0.10 0.41 1.29 5.94 69.63 1.74 6.94 21.67 - 48 5.93 4.06 0.01 4.36 0.10 0.59 0.93 5.98 72.91 1.68 9.82 15.56 - 49 6.00 4.07 0.01 3.72 0.32 0.38 1.38 5.81 64.08 5.46 6.61 23.85 - 50 5.97 4.06 0.0 2 2.64 2.15 0,19 0.90 5.87 44,87 36.62 3.27 15.24 -

A1,=Alsandine Sp.=Spessartine Py.=Pyrope 6r.=Srossular And.=Andradite

323 SAMPLE No.38/15

Nu»ber of ions on the b asis of 24 Oxygens MoleZ end senbers

No Si 02 A1203 Ti02 FeO NnO NgQ CaO Total Al. Sp. Py. Sr. And.

1 5.98 3.96 0.02 2.69 0.61 0.06 2.67 5.99 44.24 10.18 1.00 43.07 1.50 2 6.02 4.07 0.00 4.18 0.40 0.37 0.83 5.79 72.23 6.98 6.34 14.32 - 3 6.08 4.12 0.01 4.58 0.14 0.47 0.37 5.57 82.21 2.57 8.44 6.58 - 4 5.98 3.98 0.01 1.98 1.54 0.06 2.41 5.96 32.71 25.83 1.00 39.93 0.50 5 5.99 4.06 0.02 3.54 0,17 0.45 1.66 5.82 60.77 2.94 7.76 28.54 - 6 6.03 4.05 0.00 4.10 0.94 0.71 0.71 6.48 63.29 14.53 11.03 11.03 - 7 6.01 4.11 0.00 3.97 0.63 0.61 0.56 5.78 68.66 10.86 10.58 9.72 - 8 5.96 4.08 0.00 4.00 0.14 0.53 1.24 5.90 67.80 2.32 8.89 20.99 - 9 5.92 4.10 0.00 4.12 1.02 0.49 0.08 5.72 72.11 17.78 8.64 1.47 - 10 6.03 4.09 0.01 3.89 0.05 1.18 0.60 5.72 68.04 0.89 20.59 10.47 - 11 6.05 4.13 0.02 3.59 0.60 0.22 1.22 5.64 63.77 10.72 3.92 21.59 - 12 5.98 4.11 0.02 4.52 0.00 0.99 0.27 5.80 77.97 0.02 17.05 4.72 - 13 6.03 4.03 0.02 3.62 0.36 0.29 1.52 5.81 62.36 6.13 5.01 26.18 - 14 6.02 4.05 0.01 4.24 0.13 1.14 0.27 5.79 73.17 2.26 19.73 4.70 - 15 6.01 4.09 0.01 4.37 0.29 0.79 0.30 5.76 75.91 4.95 13.64 5.15 - 16 5.99 4.04 0.02 4.01 0,06 0.79 1.06 5.92 67.76 1.00 13.26 17.98 - 17 6,05 4.06 0.01 4.48 0.11 0.42 0.72 5.73 78.14 1.99 7.31 12.55 - 18 6.00 4.13 0.00 3.35 0.71 1.40 0.31 5.77 58.14 12.27 24.23 5.36 - 19 5.99 4.11 0.01 4.63 0.02 0.53 0.59 5.77 80.31 0.26 9.23 10.20 - 20 6.04 4.07 0.02 4.33 0.31 0.33 0.73 5.70 75.89 5.51 5.72 12.74 - 21 6.01 4.02 0.00 4.02 0.79 0.76 0.29 5.86 68.54 13.39 12.91 4.93 - 22 5.96 4.00 0.01 1.79 1.21 0.07 2.84 5.94 30.21 20.33 1.20 47.88 - 23 5.99 4.13 0.02 4.22 0.07 0.66 0.78 5.72 73.72 1.21 11.52 13.56 - 24 6.02 4.03 0.02 4.07 0,06 0.46 1.21 5.81 70.02 1.05 7.93 20.86 - 25 5.97 4.04 0.01 4.91 0.05 0.79 0.11 5.85 83.88 0.77 13.56 1.79 - 26 5.95 3.98 0.03 1.91 1.23 0.07 2.86 6.06 31.52 20.23 1.07 47.17 - 27 6.00 4.08 0.01 4.48 0.07 0.69 0.57 5.82 76.97 1.27 11.83 9.79 - 28 5.94 4.10 0.01 3.27 1.20 1.28 0.13 5.88 55.62 20.33 21.84 2.21 - 29 6,04 4.09 0.01 3.25 0.61 0.42 1.44 5.73 56.68 10.72 7.34 25.17 - 30 5.96 4,10 0.01 3.43 0.75 1.37 0.30 5.90 58.97 12.65 23.30 5.02 - 31 6.02 4.08 0.00 4.69 0.01 0.54 0.56 5.80 80.89 0.24 9.31 9.57 - 32 6,02 4.10 0.01 4.42 0.34 0.32 0.64 * 5,72 77.27 5.94 5.56 11.16 - 33 6.03 4.00 0.01 3.96 0.80 0.77 0.29 5.82 67.95 13.77 13.21 4.96 - 34 5.95 3.98 0.01 3.17 0.11 1.72 1.02 6.01 52.67 1.86 28.54 16.90 - 35 5.99 4.13 0.02 3.85 0.05 0.56 1.34 5.79 66.41 0.92 9.60 23.07 - 36 5.95 4.08 0.01 3.38 0.09 0.90 1.50 5.86 57.57 1.53 15,28 25.55 - 37 6.04 4.09 0.02 3.42 0.50 0.31 1.50 5.73 59.69 8.66 5.48 26.18 - 38 6.01 4.07 0.01 4.02 0.24 0.49 1.01 5.76 69.80 4.20 8.42 17.52 - 39 5.97 4.06 0.00 2.83 0.04 2.02 0.98 5.67 48.09 0.73 34.37 16.75 - 40 6.01 4.11 0.01 4.02 0.08 1.26 0.40 5.78 69.58 1.40 21.85 6.96 - 41 6.00 4.04 0.02 3.68 0.09 0.42 1.67 5.85 62.86 1.45 7.09 28.46 - 42 6.00 4.09 0.00 3.67 0.60 0.79 0.52 5.78 63.44 13.84 13.60 9.00 - 43 6.03 4.03 0.02 4.16 0.23 0.30 1.14 5.83 71.41 3.95 5.08 19.57 - 44 6.02 4.06 0.00 3.64 0.07 1.26 0.88 5.84 62.30 1.15 21.54 15.01 - 45 5.96 4.05 0.00 .3 .1 7 0.07 1.20 1.50 5.95 53.24 1.09 20.20 25.11 - 46 5.96 4.06 0.00 3.36 0.08 2.14 0.30 5.87 57.21 1.31 36.45 5.03 - 47 6.00 4.04 0.00 4.31 0.35 0.98 0.23 5.88 73.35 5.99 16.69 3.90 - 48 5.98 4,09 0.01 3.89 0.12 1.62 0.20 5.83 66.65 2.04 27.78 3.48 - 49 5.84 5.01 0.00 0.81 0.01 0.01 3.92 4.77 17.03 0.29 0.17 82.22 - 50 6.01 4.09 0.01 4.37 0,29 0.79 0.30 5.76 75.91 4.95 13.64 5.15 -

AI.=AI»andine Sp.=Spessartine Py.=Pyrope Gr.=6rossular And.=Andradite

324 SAMPLE NO. MSI (Hidley Sand)

Nuaber of ions on the b asis of 24 Oxygens Nolei end leaders

Grain No Si02 A1203 Ti02 FeQ HnO HqO CaO Total Al. Sp. py. 6 r. And,

i 5.99 4.05 0.02 3.84 0.29 0.47 1.25 5.85 65.60 4.92 7.95 21.28 _ 2 6.02 4.10 0.00 3.84 0.04 1.65 0.26 5.79 66.20 0.66 28.50 4.52 - 3 5.92 4.15 0.00 4.43 0.08 1.03 0.37 5.90 75.03 1.29 17.44 6.24 - 4 5.91 4.16 0.01 4.38 0.07 1.00 0.42 5.87 74.51 1.23 17.03 7.20 - 5 5.91 4.10 0.01 3.93 0.96 0.3B 0.72 6.00 65.52 15.92 6.36 11.96 - 6 5.90 4.17 0.00 4.89 0.03 0.82 0.18 5.93 82.46 0.53 13.89 3.12 - 7 6.00 4.02 0.01 3.50 0.17 0.59 1.65 5.91 59.17 2.92 9.98 27.92 - e 6.00 4.06 0.02 4.46 0.02 0.42 0.94 5.84 76.36 0.29 7.20 16.16 - 9 6,01 4.03 0.00 4.09 0.19 0.35 1.28 5.91 69.24 3.21 5.84 21.59 - 10 5.95 4.00 0.01 2.94 0.09 1.25 1.71 6.00 48.98 1.56 20.83 28.47 - 11 6.01 3.97 0.00 2.88 0.08 1.08 1.92 5.97 48.06 1.34 18.20 24.78 7.58 12 6.00 3.98 0.01 4.18 0.40 0.59 0.81 5.99 69.83 6.65 9.86 13.46 - 13 6.00 4.08 0.01 5.19 0.02 0.51 0.13 5.86 88.65 0.37 8.65 2.17 - 14 5.95 4.09 0.01 3.64 0.12 0.44 1.74 5.93 61.38 1.94 7.37 29.27 - 15 5.97 4.00 0.02 2.48 0.05 2.06 1.38 5.99 41.35 0.88 34.46 23.04 - 16 5.99 4.08 0.01 3.85 0.12 0.27 1.64 5.88 65.44 2.12 4.53 27.83 - 17 5.99 4.08 0.00 4.38 0.05 0.45 0.96 5.85 74.92 0.90 7.72 16.46 - 18 5.98 4.04 0.02 3.96 0.04 1.64 0.27 5.91 66.92 0.73 27.80 4.55 - 19 5.96 4.09 0.01 4.15 0.05 1,33 5.38 10.92 38.03 0.44 12.21 49.25 - 20 5.98 4.09 0.00 4.10 0.05 1,32 0.36 5.85 70.20 0.82 22.50 6.20 - 21 6.01 4.06 0.02 4.00 0.30 0.32 1.22 5.84 68.41 5.09 5.42 20.83 - n li 5.99 4.02 0.00 3.16 0.06 0.65 2.08 5.96 52.98 1.05 10.83 34.94 - 23 5.99 4.08 0.00 3.91 0.04 1.69 0.26 5.89 66.35 0.61 28.68 4.36 - 24 5.92 4.91 0.01 0.47 0.02 0.44 3.81 4.75 9.85 0.40 9.24 80.25 - 6.02 4.00 0.00 1.21 0.02 0.64 4.06 5.95 20.37 0.40 10.73 68.25 - 26 6.04 4.02 0.01 4.42 0.26 0.54 0.65 5.87 75.35 4.37 9.20 11.08 - 27 6.01 4.02 0.01 3.94 0.11 0.61 1.24 5.92 66.48 1.91 10.34 20.96 - 28 5,97 4.06 0.01 3.88 0.05 0.52 1.46 5.92 65.49 0.81 8.72 24.61 - 29 5.92 4.92 0.00 0.42 0.02 0.48 3.82 4.74 8.91 0.40 10.07 80.52 - 30 5.98 4.07 0.00 4.06 0.04 0.54 1.26 * 5.91 68.59 0.65 9.21 21.35 - 31 6.03 3.97 0.01 3.14 1.84 0.15 0.81 5.93 52.61 31.02 2.52 12.64 1.01 32 6.02 4.08 0.01 3.87 0.32 0.34 1.26 5.79 66.60 5.59 5.68 21.67 - 33 6.01 4.02 0.01 3.87 0.08 0.47 1.46 5.89 65.73 1.30 7.91 24.78 - 34 6.02 4.02 0.01 3.74 0.11 1,21 0.80 5.86 63.81 1.80 20.66 13.61 -

A! .=A!aanoine Sp.=Spessartine Py.=Pyrope Gr.=GroES>jler And.=Andradite

325 SAMPLE NO. HS2 (NIDLEY SAND)

Nuaber of ions on the b asis of 24 Oxygens Hole* end aeabers

6rain No Si02 A1203 Ti02 FeO HnO HgO CaO Total Al. Sp. Py. 6 r. And.

1 5.96 2.50 0.26 1.38 0.04 0.00 6.36 6.50 2.00 0.61 0.00 62.30 35.53 2 5.94 2.54 0.24 1.38 0.04 0.02 6.31 6,47 1.54 0.60 0.31 67.85 29.67 5.90 3.74 0.05 0.40 0.03 0.02 5.98 6.12 1.47 0.49 0.32 88.88 8.80 4 5.95 4.14 0.02 3.67 1.01 0.27 0,88 5.83 62.85 17.37 4.68 15.04 - 5 5.86 4.15 0.03 3.78 0.99 0.28 0.88 5.92 63.79 16.69 4.73 14.79 - 6 5.89 4.16 0.02 3.26 0.06 2.23 0.33 5.89 55.39 1.05 37.77 5.58 - 7 5.97 4.12 0.02 2.57 2.62 0.21 0.44 5.84 44.01 44.90 3.63 7.46 - 8 5.97 4.13 0,00 4.48 0.04 0.62 0.69 5.83 76.78 0.62 10.68 11.90 - 9 5.90 4.11 0.02 2.51 2.71 0.28 0.42 5.92 42.45 45.78 4.70 7.08 - 10 5,92 4.15 0.00 4.69 0.29 0.55 0.36 5.90 79.47 4.98 9.33 6.17 - tt 5.91 4.12 0.02 4.41 0.02 0.38 1.13 5.94 74.17 0.29 6.41 18.96 - 12 5.91 4.14 0.00 4.00 0.22 1.05 0.69 5.95 67.16 3.68 17.62 11.54 - 13 5.89 4.19 0.00 3.91 0.21 1.04 0.75 5.93 65.94 3.49 17.55 12.71 - 14 5.89 4.12 0.01 1.72 3.73 0.06 0.47 5.99 28.77 62.31 0.93 7.89 - 15 5.93 4.11 0.02 1.67 3.69 0.08 0.45 5.88 28.36 62.75 1.31 7.57 - 16 5.93 4.11 0.02 1.67 3.69 0.08 0.45 5.88 28.36 62.75 1.31 7.57 - 17 5,91 4.14 0.02 3.77 0.07 1.08 1.01 5.93 63.62 1.16 18.22 17.00 - 18 5.89 4.14 0.02 3.78 0.07 1.06 1.03 5.95 63.59 1.14 17.88 17.38 - 19 5.90 4.15 0.01 4.13 0.17 0.61 1.01 5.93 69.63 2.93 10.24 17.05 - 20 5.90 4.17 0.01 4.38 1.29 0.17 0.05 5.90 74.33 21.94 2.88 0.85 - 21 5.91 4.12 0.01 3.94 0.10 0.86 1.05 5.97 66.05 1.74 14.46 17.66 - 22 5.89 4.16 0.01 2.48 0.04 2.50 0.92 5.95 41.66 0.72 42.01 15.51 - 23 5.91 4.13 0.02 4.02 0.06 0.43 1.43 5.95 67.54 1.06 7.18 24.09 - 24 5.95 4.19 0.00 4.06 0.80 0.56 0.36 5.79 70.13 13.88 9.63 6.24 - 25 5.94 4.13 0.00 3.93 0.47 0.40 1.08 5.88 66.83 7.94 6.77 18.37 - 26 5,91 4.15 0.01 4.48 0,01 0.73 0.71 5.93 75.63 0.13 12.30 11.94 - 27 5.93 4.09 0.01 2.88 0.17 0.48 2.40 5.93 48.66 2.80 8.05 40.49 - 28 5,89 4,04 0.02 3.69 0.42 0.34 1.48 5.95 62.04 7.08 5.76 24.87 - 29 5.93 4.11 0.02 4.05 0.26 0.40 1.19 5.91 68.60 4.47 6.70 20.15 - 30 5.96 4.15 0.01 5.11 0.00 0.63 0.09 5.83 87.61 0,00 10.86 1.52 - 31 5.87 3.84 0.11 0.36 0.07 0.05 5.75 * 6.05 2.97 1.15 0.82 87.80 7.19 32 5.93 4.20 0.01 2.98 2.33 0.22 0.28 5,81 51.32 40.09 3,80 4.79 - 33 5.89 4.08 0.04 2.76 0.86 0.21 2.15 5.99 46.05 14.31 3.57 35.91 - 34 5.93 4.13 0.03 4.19 0.05 0.44 1.17 5.85 71.59 0.82 7.55 20.03 - 35 5.94 4.11 0.02 3.72 0.15 0.60 1.45 5.91 62.91 2.52 10.11 24.47 - 36 5.93 4.16 0.00 3.81 0.08 1.18 0.78 5.87 64.99 1.35 20.16 1^ - 37 5.95 4.06 0.03 4.13 0.13 0.35 1.33 5.94 69.43 2.26 5.86 22.46 - 38 5.91 4.19 0,01 4.24 0.41 1.04 0.18 5.86 72.25 7.00 17.77 2.99 - 39 5.93 4.10 0.02 4.12 0.02 0.64 1.12 5.90 69.83 0.33 10.90 18.95 - 40 5.92 4.17 0.01 4.86 0.22 0.51 0.27 5.86 82.93 3.68 8.64 4.54 - 41 5.90 4.14 0.01 4.69 0.20 0.84 0.20 5.94 78.97 3.44 14.23 3.36 - 42 5,93 4.12 0.01 3.86 0.0B 0.49 1.50 5.93 65.07 1.30 8.26 25.37 - 43 5.89 4.18 0.00 3.99 1.00 0.73 0.17 5.89 67.74 16.90 12.46 2.85 - 44 5,90 4.14 0.01 . 4.22 0.06 1.23 0.42 5.92 71.31 0.93 20,71 7.01 - 45 5.93 4.16 0.00 4.17 0.68 0.79 0.20 5.85 71.32 11.65 13.46 3,36 - 46 5,87 4.18 0.00 4.32 0.21 1.22 0.22 5.96 72.50 3.46 20.41 3.62 - 47 5.93 4.16 0.01 4.56 0.12 0.73 0.47 5.88 77.60 1.96 12.44 8.00 - 48 5.93 4.19 0.00 4.34 0.34 0.56 0.62 5.85 74.12 5.78 9.52 10,58 - 49 5.95 3.86 0.03 0.59 0.18 0.00 5.46 6.23 9.40 2.81 0.08 87.71 - 50 5.96 4.14 0,01 4.17 0.04 0.45 1.15 5.82 71.71 0.70 7.79 19.79 -

326 SAMPLE NO. N1 (Modern Sand)

Nutber of ions on the bd5i £ of 24 Oxygens Hole! end aethers

Grain Nc« Si 02 A1203 Ti02 FeO HnO HgO CaO Total Al. Sp. Py. Gr. And.

1 6.16 4.13 0.01 3.54 0.05 1.18 0.61 5.38 65.76 0.89 21.88 11.34 _ n L 6.17 4.17 0.00 3.43 0,05 1.23 0.62 5.34 64.24 0.90 22.99 11.65 - 3 6.25 4.10 0.00 3.36 0.04 1.22 0.62 5.24 64.07 0.82 23.20 11.90 - 4 6.03 4.11 0.01 3.67 0.08 0.71 1.04 5.70 67.83 1.35 12.38 18.23 - 5 6.01 4.02 0.01 3.65 0.09 1.40 0.67 5.81 62.80 1.49 24.15 11.56 - 6 5.99 4.06 0.00 4.66 0.34 0.45 0.41 5.87 79.46 5.73 7.69 7.04 - 7 5.95 4.09 0.00 3.26 0.12 1.39 1.13 5.91 55.15 2.03 23.58 19.07 - B 5.94 4.03 0.01 3.92 0.24 0.41 1.41 5.99 65.49 4.05 6.89 23.57 - 9 5.96 4.05 0.01 3.92 0.26 0.37 1 V 5,94 66.09 4.32 6.27 23.08 - 10 5.99 4,06 0.01 4.25 0.00 0.33 1.29 5.87 72.40 0.00 5.68 21.91 - M 5.97 4.09 0.00 4.68 0.29 0.52 0.38 5.87 79.83 4.95 8.80 6.42 - 12 5.95 4.03 0,01 4.05 0.27 0.31 1.36 6.00 67.53 4.52 5.20 22.66 - 13 5.9S 4.02 0.00 3.56 0.46 0.30 1.67 5.99 59.42 7.69 4.97 27,88 - 14 5.95 4.05 0.01 3.86 0.21 0.33 1.56 5.95 64,82 3.47 5.49 26.22 - 1!'. 5.95 4.08 0.00 4.30 0.04 0.64 0.97 5.94 72.36 0.61 10.71 16.32 - 16 5.93 4. OS 0.00 3.92 0.19 0.43 1.35 5.90 66.50 3,22 7.33 22.95 - 17 5.95 4.02 0.02 3.80 0.09 0.87 1.19 5.95 63.80 1.57 14.67 19.91 - 13 6.01 4.03 0.01 4.13 0.09 0.31 1,32 5.86 70.45 1.48 5.29 22.58 - 19 5.95 4.05 0.02 3.33 2.32 0.17 0.06 5.88 56.59 39.45 2.94 1.02 - 20 6.00 4.10 0.01 4.75 0.19 0.63 0.23 5.81 81.82 3.26 10.91 3.97 - 21 5.98 4.05 0.00 4.37 0.27 0.33 0.95 5.93 73.67 4.62 5.63 16.08 - 22 5.93 4.05 0.00 3.99 0.07 0.66 1.29 6.00 66.47 1.12 10.99 21.42 - 23 5.96 3.99 0.01 4.32 0.54 0.32 0.82 6,01 71.92 8.99 5.35 13.66 - 24 5.99 4.02 0.01 4,51 0.03 0.64 0.77 5.95 75.81 0.48 10.77 12,94 - i. t' 5.97 4*05 0.01 3.91 1.00 0.56 0.47 5.94 65.82 16.81 9.41 7.96 - 26 5.96 4.10 »'f >')M 4,14 0.18 0.61 0.93 5.86 70.71 3.07 10.41 15.81 - 27 5.99 4.02 0.01 3.97 0.15 0.45 1.35 5.92 67.02 2.59 7.54 22.73 - 28 5.96 4.00 0.01 3.84 0.17 0.39 1.59 6.00 63.97 2.83 6.57 26.58 - 29 5.95 4.06 0.02 3.74 0.31 0.42 1.46 5.94 62.98 5.25 7.15 24.63 - 30 6.00 4.06 0.00 4,42 0.38 0.41 0,64 5.86 75.43 6,43 7.04 10.93 - 31 5.94 4.05 0.02 4.03 0.02 0.94 0.93 5.92 68.02 0.32 15.89 15.65 - 32 5.96 4.09 0.00 4.65 0.12 0.67 0.40 5.85 79.53 2.05 11.53 6.89 - 33 5.94 4.11 0.01 4.52 0.05 0.99 0.33 5.89 76.72 0.86 16.75 5.67 - 34 5,97 3.99 0.01 3.75 0.11 0.73 1.35 5.94 63.07 1.78 12.36 22.71 - 35 5.93 4.03 0.02 3.57 0.50 0.29 1.60 5.98 59.73 8.42 4.89 26,80 - 36 5.99 4.04 0,00 3.30 0.24 0.95 1.45 5.95 55.53 4.04 15.94 24.41 - 37 6.02 4.07 0,00 3.87 0.16 0.54 1.26 5.84 66.31 2.79 9.24 21.65 - 3S 5.94 4.10 0.01 3.75 0.18 0.39 1.61 5.93 6 , 2 0 3.04 6.56 27.14 - 39 5.98 3.99 0.02 2.61 0.04 1.71 1.64 6.01 43.51 0.64 28.49 27.37 - 40 5.98 4.02 0.00 4.14 0.39 0.78 0.61 5.91 70.01 6.53 13.19 10.27 - 41 5.95 4.06 0.00 4.75 0.12 0.90 0.15 5.93 80.12 2.11 15.22 2.55 - 42 5.97 4.12 0.01 4.72 0.15 0.70 0.25 5.82 81.18 2.52 11.97 4.33 - 43 5.93 4.13 0.00 4.63 0.25 0.74 0.27 5.90 78.46 4.27 12.52 4.55 - 44 5.91 4.07 0.00 3.12 0.08 0.64 2.15 6.00 52.00 1.32 10.60 35.84 - 45 5.96 4.03 0.02 4.50 0.02 0.42 1.00 5.94 75.73 0.2B 7.07 16.80 - 46 5,89 4.14 0.02 3.76 0.05 1.55 0.54 5.91 63.69 0.81 26.16 9.14 - 47 5.97 3.99 0,01 3.75 0.11 0.73 1.35 5.94 63.07 1.78 12.36 22.71 - 48 5.93 4.13 0.00 4,63 0.25 0,74 0.27 5.90 78.46 4.27 12.52 4.55 - 49 6.00 4.06 0.00 4.42 0.38 0.41 0.64 5.86 75.43 6.43 7.04 10.93 - 50 6.02 4.07 0.00 3.87 0.16 0.54 1.26 5.84 66.31 2.79 9.24 21.65 -

A] .=Hlisar.d:ne Sp.=Spessertine Py.=Pyrope Or .=5rcs£ular And.=Andradite

327 APPENDIX - 10

Electron microprobe analysis of selected heavy minerals

Microprobe Analysis of Touraaline

SAMPLE NO. 24/35.5

6 rain No. Si 02 A1203 Ti02 FeO Cr203 MnO HgO CaO K20 Na2Q

1 39.65 36.09 1.02 17.62 0.03 0.14 1.77 1.73 0,05 1.88 2 42.09 38.39 0.68 7.74 0.06 N.D. 7.66 1.45 N.D. 1.90 3 40.81 40.29 0.33 14.70 N.D. 0.08 1.35 0.11 0.08 2.17

SAMPLE NO. 26/18

Grain No. SiQ2 A1203 Ti02 FeO Cr203 MnO MgO CaO £20 Na2Q

i 41.13 36.47 1.02 14.31 0.00 0.18 3.70 0.27 0.05 2.74 2 37.61 34.92 0.73 16.62 0.00 0.00 2.81 0.32 0.08 2.74 3 38.33 35.58 0.86 6.75 0.18 0.00 6.17 0.09 0.04 1.95

SAMPLE NO. 38/15

Grain No. Si02 A1203 Ti02 FeO Cr203 MnO MgO CaO £20 Na20

1 40.67 40.71 0.28 13.68 N.D, 0.21 1.69 0.17 0.05 2.55 2 40.08 36,42 0.96 16.75 0.05 0.25 1.77 0.90 0.14 2.54 3 40.55 39.24 0.15 16.77 0.07 0.20 0.37 0.19 0.02 2.19 4 42,38 38.45 0.67 7.94 0.41 N.D. 7.04 0.66 0.07 2.58 40.47 38.27 0.61 13.33 N.D. 0.21 2.88 0.62 0.06 2.35 6 41.82 39.23 1.26 8.55 0.13 N.D. 6.42 0,48 0.06 2.05 7 40.72 40.45 0.47 11.99 N.D. N.D. 3.53 0.18 0.10 2.33

I i

328 SAMPLE NO. HS2 (Hidley Sand)

u. Si 02 A1203 Ti02 FeO Cr203 HnO HgO CaO K20 Na20

1 35.10 32.84 0.57 4.57 0.14 N.D. 7.65 0.09 0.07 2.18 2 34.25 31.59 1.01 11.22 0.08 0.04 3.89 0.74 0.06 1.96 3 33.86 32.64 0.16 15.74 0.05 N.D. 0.70 0.48 0.01 2.51 4 34.39 31.98 1.09 10.52 0.06 0.10 4.64 0.93 0.03 2.20 5 34.03 32.56 1.10 12.41 0.02 0.10 3.20 0.56 0.04 2.02 6 ii.v.5 30.91 1.37 14.64 0.05 0.07 2.69 1.10 0.06 1.98 7 34.86 32.74 0.93 6.30 0.06 0.09 6.66 0.77 0.01 2.08 8 34.58 34.59 0.57 8.30 0.04 N.D. 4.33 0.34 0.04 1.70 9 33.82 29,34 1.00 14.69 N.D. 0.02 3.35 1.26 0.10 2.00 10 33.88 33.05 0.53 12.36 N.D. 0.06 1.94 0.25 0.01 2.03 11 34.01 31.01 0.77 12.85 0.06 0.09 3.78 0.71 0.06 2.16 12 34.30 31.24 1.06 11.21 N.D. 0.05 4.15 0.72 0.05 2.01 13 34.29 30.41 0.21 13.35 0.12 N.D. 3.58 0.72 0.04 2.08 14 33.04 33.67 0.72 12.33 N.D. 0.19 1.13 0.10 0.03 2.18 15 33.77 27.06 0.93 14.79 0.04 0.06 4.68 1.71 0.03 1.99 16 34.79 26.88 0.07 12.11 0.13 0.09 5.53 0.88 N.D. 2.44 17 33.76 30.74 1.06 12.33 N.D. 0.16 3.49 0.60 0.09 2.18 IS 33.98 29.49 1.24 11.04 0.01 0.00 4.91 0.82 0.03 2.21 19 34.24 31.62 0.34 13.27 0.06 0.11 2.24 0.27 0.06 2.20 20 33.76 30.38 1.32 12.16 N.D. 0.02 3.82 0.90 0.02 1.90 21 34.03 30.29 1.30 11.96 N.D. 0.05 4.42 1.07 0.11 2.59 22 34.12 31.38 0.39 16.10 N.D. 0.22 0.20 0.22 0.61 3.07 X J 36.74 31.98 0,38 3.76 0.63 N.D, 9.58 1.79 0.04 2.91

SAHPLE NO. N1 (Nodern Sand) lo, Si02 AJ203 Ti02 FeO Cr203 NnO MgO CaO K20 Na20

1 37.09 32.04 0.47 7.46 0,05 0.03 7.55 0.40 0.02 2.67

329 Hicroprobe Analysis of Aaphibole

SAHPLE NO. 24/35.5

6rain No Si 02 A1203 Ti02 FeO Cr2Q3 HnO NiO HgO CaO K20 Na2Q Total

1 53.49 3.30 0.55 13.99 0.23 0.22 0.01 15.83 11.60 0.14 0.60 99.94 2 46.94 6.53 1,87 7.54 0.03 0.11 0.21 12.04 23.66 0.10 0.78 99.80

SAHPLE NO. 26/18

6rain No Si02 A1203 Ti02 FeO Cr203 HnO NiO HgO CaO £20 Na20 Total

1 44.14 12.60 0.64 15.55 0.00 0.29 0.25 10.74 12.42 0.85 1.64 99.14 2 47.10 10.49 0.63 14.71 0.11 0.42 0.00 12.B1 12.11 0.21 1.60 100.19 46.82 8.79 2.52 8.17 0.09 0.09 0.05 11.51 24.53 0.05 0.64 103.26 4 45.91 12.63 1.49 15.80 0.00 0.00 0.00 11.10 11.75 0.70 1.69 101.07 5 48.32 26.41 0.16 2.19 0,16 0.02 0.08 1.32 16.72 0.01 0.00 95.39 A 42.29 13.31 0.73 10.47 0.03 0.06 0,11 10.23 9.40 0.26 2.75 89.65

SAHPLE NO. 38/15

6 rain No Si02 A1203 Ti02 FeO Or 203 NnO NiO HgO CaO m Na2G Total

1 47.93 13.78 0.17 9.99 0.35 0.24 0.17 13.89 11.69 0.15 1.63 100.00 2 43.6? 14.33 0.67 16,29 0.02 0,29 N.D. 10.28 11.47 0 .4 2 ’ 2.23 99.69 3 48.26 7.34 1.26 14.85 0.11 0.29 N.D. 13.27 12.38 0.74 1.43 99.92

SAHPLE NO. HS2 (Hidley Sand)

No Si02 A1203 Ti02 FeO Cr203 HnO NiO HgO CaO K20 Na2Q Cl Total

1 40.68 13.21 0.54 17.35 N.D. 0.34 0.05 9.17 11.33 0.60 1.62 N.D. 94.90 2 41,96 12.66 0.61 13.59 0.07 0.34 N.D. 11.45 11.24 0.61 1.76 N.D. 9* .2? 3 40.75 12.45 0.B3 18.84 0.08 0.37 N.D. 8.55 10.00 0.95 2.25 N.D. 95.07 4 49.55 4.02 0.24 12,70 0.18 0.46 N.D. 14.84 12.33 0.24 0.63 N.D. 95.19 5 45.63 7.77 0.97 14.19 0.14 0.38 N.D. 12.32 11.34 0.44 1.05 N.D. 94.28 6 45.12 10.83 0,69 13.90 0.19 0.32 N.D. 12.04 12.55 0.72 1.17 0.08 97.60 7 44,95 10.63 0.66 14.19 0.19 0.17 N.D. 12.15 12.25 0.72 1.31 0.14 97.35 8 42.46 14,38 0,59 J4 .9 3 0.22 0.14 0.03 9.81 10.19 0,51 2.33 0.05 95.64 9 42.77 14.36 0.66 15,07 0.15 0.19 0.18 9.88 10.19 0.52 2.19 0.07 96.22 10 42.64 14.41 0.48 14.82 0.91 0.26 N.D. 9.87 10.22 0.56 1.84 N.D. 96.01 11 44.72 10.63 0.56 14.01 0.22 0.29 N.D. 12.02 12.30 0.69 1.32 0.03 96.78

330 Hicroprobe Analysis of Pyroxene

SAHPLE NO. 24/35.5

Grain No. Si02 A1203 Ti02 FeO Cr203 HnO NiO HgO CaO K20 Na2G Total

1 52.97 2.89 0.03 17.70 0.04 0.52 N.D. 11.91 13.19 0.18 0.51 99.94

SAHPLE NO. 26/18

6rain No. Si02 A1203 Ti02 FeO Cr2Q3 HnO NiO HgO CaO K20 Na20 Total

i 47.99 3.12 0.56 11.12 0.02 0.43 0.07 13.41 12.51 0.38 0.54 90.15 2 56.27 1.90 0.31 10.93 0.10 0.39 N.D. 17.63 13.09 0.19 0.48 101.30 3 56.62 4.55 0.15 6.70 0,37 0,12 0.05 33.34 0.30 0.05 0.15 102.39

SAHPLE NO. 38/15

Grain No. Si02 Ai 203 Ti02 FeO Cr203 HnO NiO HgO CaO K20 Na20 Total

1 56.01 1,98 0.16 8.36 0.64 0.09 N.D. 31.14 1.30 0.04 0.27 99.99 2 51.64 7.16 0.68 2.46 0.88 0.02 N.D. 14.03 21.00 N.D. 1.95 99.81

SAHPLE NO. HS2 (Hidley Sand)

6ram No. Si 02 A1203 Ti02 FeO Cr203 HnO NiO HgO CaO r.2G Na2G Total

i 53.73 0.42 N.D. 11.75 0.05 0.27 0.25 16.33 12.01 0.08 0.43 95.31

SAHPLE NO. N1 (Hodern Sand)

Grain No. Si02 A1203 TiO? FeO Cr2Q3 HnO NiO HgO CaO K20 Na20 Total

\ 51,51 3.08 0.74 6.70 0.19 0.17 N.D. 16.24 20.76 N.D. 0.63 100.02

Hicroprobe Analysis of Epidote

SAHPLE NO. 26/18

Grain No. Si02 A1203 Ti02 FeO Cr203 HnO NiO HgO CaO K20 Na20 Total

1 3S.76 27.54 0.11 7.93 0.08 0.18 N.D. 0.01 24.86 0.03 N.D, 99.49 2 39.06 26.22 0.12 9.60 0.07 0.00 0.00 0.08 24.18 N.D. N.D. 99.33 39.57 26.91 0.02 9.02 0,06 0.11 N.D. 0.08 24.20 N.D. O.iS 100.13

SAHPLE NO. HS2 (Hidley Sand)

6rain No. Si02 A1203 Ti02 FeO Cr 203 HnO NiO HgO CaO K20 Na20 Total

1 36.51 25.31 0.15 9.15 0.07 0.17 0.13 0.11 22.50 0,06 N.D. 94,15 2 37,36 27.48 0.11 7,49 0.08 0.09 0.06 0.11 22.99 0.10 N.D. 95.86

SAHPLE NO. N1 (Hodern Sand)

Grain No. Si02 A1203 Ti02 FeO Cr2G3 HnO NiO HgO CaO r.20 Na2G Total

1 38.37 24.82 N.D. 10.36 N.D. 0.28 N.D. N.D. 23.91 N.D. 0.08 97.81

331 Glauconite analyses

Hicroprobe Analysis of Glauconite

SAHPLE NO. 13/19.5

u. Si02 A1203 FeO HgO CaO r.20 Na20 P205

1 52.93 4.27 23.78 2.08 0.15 7.12 . 0.23 0.04 2 46.35 5.42 24.85 2.59 0.21 7.90 0.21 0.06 3 47.25 5.64 25.91 2.62 0.19 7.83 0.22 0.11 4 49.84 8.94 21.03 2.66 0.11 8.60 0.15 0.08 5 50.92 9.13 21.74 2.78 0.11 8.56 0.12 0.17 6 48,84 10.79 21.44 2.22 0.19 7.41 0.18 0.23 7 51.56 10.64 18.57 3.00 0.16 7,80 0.07 0.14 8 44.23 8.47 22.69 2.84 0.90 5.56 0.13 0.34 9 52.14 7.15 19.24 4.11 0.20 8.50 0.15 0.07 10 49.68 7.54 21.55 2.57 0.14 8.41 0.15 0.16 11 48.24 8.34 24.16 2.48 0.18 7.85 0.38 0.18

SAHPLE NO. 24/22.5

D. Si 02 A1203 FeO HgO CaO K20 Na2Q P205

1 43,33 7.20 28.06 2.51 0.37 6.37 0.27 0.50 2 54.50 8.90 17.27 1.99 0.37 6.13 0.06 0.14 3 51.53 6.89 21.39 2.70 0.33 6.05 0.32 0.10 4 46.21 5.22 26.30 3.95 0.34 7.80 0.15 0.44 5 43.72 5.38 24.71 3.75 0.38 7.35 0.33 0,40 6 37.94 7.51 30.73 2.06 0.31 6.01 0.17 0.24 7 53.16 10.43 16.98 4.17 0.13 7.87 0.31 0.06 8 49.14 4.70 22.66 4,45 O. 9.21 0.20 0.15 9 51.14 5.08 22.29 5.07 0.19 9.21 0.17 0.04 10 49.89 4.73 22.48 4.49 0.15 9.36 0.16 0.14 11 52,84 5.99 21.45 5.29 0.17 9.53 0,36 0.11 12 49.32 9.63 22.04 2.33 0.19 8.52 0.12 0.20 13 49.35 8.34 23.97 2.18 0.07 8.70 0.16 0.16 14 45.07 6.85 26.33 2.39 0.33 6.90 0.09 0,45 13 40.56 5.25 26.64 2.37 0.28 6.42 0,19 0.12 16 36.88 7.55 29.68 3.47 0.33 2.71 0.25 0.22 17 52.02 9.38 18.68 3,97 0.49 8.50 0.16 0.26 18 48.52 5.20 27.94 2.29 0.16 8.53 0.27 0.00 19 49.33 8.78 20.21 3.15 0.12 8.13 0.18 0.11 20 44.93 7.42 22.97 2.45 0.13 8.02 0.30 0.17 44.93 7.69 . 23.11 2.44 0.10 7.88 0.12 0.06

332 Brain Nc. Si02 A1203 FeO MgO CaO r.20 Na20 P205 Total

1 46.43 12.47 24.19 2.34 0.35 6.67 0.29 0.12 92.85 4T 48.35 7.81 22.39 2.65 0.30 7.66 0.18 0.06 89.41 3 32.03 4.67 43.77 2.60 0.42 5.19 0.31 0.21 89.20 4 50.11 8.71 21.15 2.97 0.06 8.27 0.19 N.A. 91.46 5 49.89 3.96 24.72 4.16 0.29 8.41 0.06 N.A. 91.49 43.27 6 8.62 21.83 2.48 0.49 7.13 0.28 N.A. 84.29 7 43.03 7.22 25.45 2.41 0.47 5.77 0.16 N.A. 84.50 8 51.30 6.76 19.96 3.95 0.25 7.64 0.17 N.A. 90.02 9 52.14 6.06 19.94 4.67 0.12 9.00 0.17 N.A. 92.08 10 49.71 7.28 22.07 3.64 0.41 7.77 0.33 N.A, 91.22 11 33.31 3.42 35.89 2.88 0.29 5.32 0,10 N.A. 81.20 12 33.26 3.42 35.91 2.87 0.29 5.32 0.10 0.79 81.95 13 46.28 10.99 24.58 2.01 0.16 6.80 0.30 0.41 91.52 14 49.98 9.01 21.37 3.06 0.18 7.96 0.11 0.17 91.83 15 46.55 4.55 25.50 4.13 0.26 8.58 0.29 0.03 89.89 16 50.05 6.47 20.23 4.16 0.09 8.65 0.23 0.29 90.17 17 49.64 7.54 24.10 2.77 0.34 7.38 0.45 0.20 92.42 18 39.23 6.19 30.76 2.71 0.39 6.98 0.27 N.A. 86.52 19 47.42 9.76 22.09 2.39 0.19 7.61 0.18 0.26 89.90 20 49.98 7.03 21.79 3.45 0.10 8.54 0.24 0.18 91.30

SAHPLE NO. 38/24

Grain Nc. Si02 A1203 FeO HgO CaO K20 Na2Q P205 Total

i 49.90 9.61 20.85 2.50 0.09 8.11 0.21 0.16 91.43 2 51.86 9.10 20.57 3.03 0.33 6.13 0.21 0.10 93.33 3 42.73 8.98 26.12 2.12 0.26 6.97 0.15 0.40 87.73 4 47.57 9,05 23.71 1.96 0.18 8.00 0.17 0.04 90,67 5 35.46 8.98 31.09 2.00 Or. 17 6.44 0.34 0.40 84.88 6 35,49 8.80 28.86 1.86 0.21 6.09 0.03 0.41 81.73 7 48.97 4.83 21.18 4.33 0.16 8.75 0.18 0.12 88.53 8 47.74 5.13 25.64 3.53 0.41 8.09 0.23 0,19 90.96 9 48.79 10.66 18.52 2,33 0.56 6.69 0.13 0.08 87.77 10 46.56 5.85 23.52 3,33 1.41 7.77 0.09 0.95 39.47 11 48.62 4.61 23.93 2,71 0.93 7.28 0.24 0.06 88.37 12 49.66 5.32 22.42 4.36 0.02 8.42 0.12 0.20 90.51 13 47.72 6.92 23.62 3.04 0.66 6.53 0.21 0.17 88.86 14 50.50 5.24 22.07 4.06 0.09 8.37 0.02 0.05 90.40 15 48.79 5.35 23.10 3.61 0.54 7.27 0.03 0.34 89.02 16 50.79 7.37 23.42 2.64 0.28 7.92 0.06 0.23 92.71

333 SAHPLE NO. N1 (Hodern Sand)

Si 02 u • A1203 FeO HgO CaO K20 Na20 P205 Total

i 47.42 9.76 22.09 2.39 0.19 7.61 0.18 0.26 89.90 2 49.98 7.03 21.79 3.45 0.10 8.54 0.24 0.18 91.30 3 45.57 7.68 24.65 1.79 0.19 7.54 0.28 N.A. 87.70 4 36.94 4.50 30.25 3.29 0.16 6.48 0.16 N.A. 5 81.78 46.22 5.69 25.10 3.07 0.10 8.16 0.21 N.A. 88.55 6 45.61 9.74 22.37 2.88 0.13 7.18 0.31 N.A. 88.22 7 47.73 4.20 22.87 4.02 0.06 8.80 0.19 N.A. 87.88 8 3B.65 8.31 26.77 3.60 0.50 5.67 0.30 N.A, 83.81 9 41.67 5.05 23.50 2.08 0.16 7.87 0.32 N.A. 80.65 10 45.37 6.51 23.27 2.66 0.09 7.67 0.18 N.A. 85.75 11 44.16 6.43 21.34 4.48 0.05 5.55 0.28 N.A. 82.29 12 34.68 7.36 29.39 2.23 0.19 5.91 0.22 N.A. 79.98 13 43.06 7.22 21.50 3.00 0.21 6.66 0.39 N.A. 82.03 14 44.51 5.50 23.71 2.12 0.16 7.85 0.21 N.A. 84.06 15 44.58 3.95 2 1 .9B 4.20 0.12 7.96 0.15 N.A. 82.95 16 45.91 8.25 25.90 2.80 0.82 6.84 0.27 N.A. 90.80

334 Pulk analysis of selected oxides in glauconites by !CP tethod.

Saaple No. A1203 FeO HgO CaO Na2D K20 Ti02 Cation Exchange in aeg/ldGge

13/19.5 6.95 24.57 2.65 1.55 0.16 4.28 0.94 15.98 (whole satplel 13/19.5 7.35 24.64 2.86 1.63 0.16 4.2 0.39 (whole sasple) 13/19,5 7.23 26.15 2.68 1.44 0.2 4.65 0.24 21.85 (>2.5phi) 24/22.5 7.61 27.07 3.13 1.21 0.39 4.93 0.41 31.905 (>3phi) 24/22.5 (3-4Phi) 6.63 32.13 3.61 1.26 0.88 4.99 0.33 24/22.6 7.61 25.68 3.15 0.85 0.27 5.51 0.13 18.611 (whole sasple} 24/35,5 7.38 28.15 2.81 1.22 0.16 4.02 0.28 23.59 38/24 7,37 27.04 3.17 1 0.08 5.11 0.12 24.459 Ni 6.34 42.81 2.15 1.8 0.75 1.55 1.45 N2 6.71 26.85 2,66 0,87 0.17 3.99 0.55 12.68

Dungeness saeples are na»ed according to the EH no. and depth. For exaeple 13/19.5 aeans BH 13 and depth 19.5 b. Ni and N2 are saapies froa Hodern Sand at Lydd-on-See. APPENDIX - 12

Semiquantitative estimation of clay by following the method

proposed by Weir et al (1975).

Formulae followed

1 Kaolinite/2.5+1 lllite+1 Smectite+1 Chlorite/2 =100

Sample No. 16/2-4

27/2.5+48+15+1/2=74.3

Kaolinite = 14.4 9f

lllite = 64.179/

Mixed Clay = 20.18^

Chlorite = 0.6729;

3 36