In Memory of Davide Calamari Emerging Pollutants In Memory of Davide Calamari (Section Editor: Paola Gramatica) Benzotriazoles, Alkylphenols and Bisphenol A in Municipal Wastewaters and in the Glatt River, Switzerland Dimitra Voutsa1,2, Paul Hartmann1, Christian Schaffner1 and Walter Giger1* 1 Swiss Federal Institute of Aquatic Science and Technology (Eawag), 8600 Dübendorf, Switzerland 2 Environmental Pollution Control Laboratory, Department of Chemistry, Aristotle University, 54124 Thessaloniki, Greece * Corresponding author (
[email protected]) In memory of Davide Calamari DOI: http://dx.doi.org/10.1065/espr2006.01.295 Conclusion. The investigated contaminants occur at quantita- tively measurable but varying concentrations in municipal Abstract wastewaters and in the Glatt River reflecting their ubiquitous input into wastewaters and their different behaviour during bio- Background. Many organic micropollutants occur at trace con- logical wastewater treatment. centrations in municipal wastewater effluents and in the aquatic environment. Some of these xenobiotic chemicals can be con- Keywords: Alkylphenol; benzotriazole; bisphenol A; corrosion sidered as 'emerging' contaminants and some are suspect to inhibitors; endocrine disrupters; nonylphenol; octylphenol; tolyl- have endocrine disrupting effects. Among the latter are non- triazole; xenoestrogens ylphenol (NP), octylphenol (OP) and bisphenol A (BPA), which deserve special attention due to their ubiquitous occurrence in the aquatic environment. Introduction The complexing agents benzotriazole (BT) and tolyltriazole (TT) are applied as anticorrosive agents (e.g. in cooling and hy- The complexing agents benzotriazole (BT) and tolyltriazole draulic fluids, in antifreezing fluids, in aircraft deicing fluids, (TT, a mixture of 4- and 5-methyl isomers in benzene ring in dish washing liquids for silver protection), as antifogging of BT) (Fig.