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DOI: 10.1590/2317-4889201820180146

ARTICLE

Exploratory plays of Pará-Maranhão and Barreirinhas basins in deep and ultra-deep waters, Brazilian Equatorial Margin Bruna da Silva Pellegrini1* , Hélio Jorge Portugal Severiano Ribeiro1

ABSTRACT: The Pará-Maranhão and Barreirinhas are exploratory frontier basins. After the discoveries in deep/ultra-deep water turbidites at the correlated African equatorial margin and French Guiana (Jubilee and Zaedyus plays), the exploratory interest was retaked for those basins. Using 2D seismic interpretation, it was search to identify hydrocarbon accumulations potential focusing on turbiditic reservoirs. Three plays types linked to three margin distinct segments were identified: shallow waters, faulted shelf border and deep/ultra-deep waters. The shallow waters and faulted shelf border plays are related to two petroleum systems: Caju-Travosas and Travosas-Travosas. The Caju Group (Late Albian-Early Cenomanian) and Travosas For- mation (Cenomanian-Turonian) source rocks occur between 2,400 and 3,700 m below sea water bottom for shallow waters play, and between 1,300 and 4,800 m for faulted shelf border play. The deep/ultra-deep waters play is related to three petroleum systems: Codó-Travosas, Caju-Travosas and Tra- vosas-Travosas. The source rocks from Codó Formation (Aptian) occur between 2,860 and 4,550 m, from Caju Group (Late Albian-Early Cenomanian) between 2,200 and 3,800 m and from Travosas Formation (Cenomanian-Turonian) between 1,430 and 2,860 m. In the African equatorial margin, the oil window top is located around 2,700 m below sea water bottom. Thus, it can be concluded that Pará-Maranhão and Barreirinhas source rocks would also be able to generate oil/gas in the specified depths. KEYWORDS: Pará-Maranhão basin; Barreirinhas basin; petroleum ; petroleum prospecting; plays.

INTRODUCTION The Jubilee play, located in Tano Basin at Ghana off- shore, corresponds to one of the most important oil fields The Brazilian equatorial margin includes Foz do Amazonas, of Guinea Gulf, and comprises turbiditic fans and chan- Pará-Maranhão, Barreirinhas, Ceará and Potiguar basins, with nels systems of the Cenomanian-Turonian, with shales of shows of oil and gas in exploratory wells along the whole Late Cretaceous as source rocks. Jubilee discovery made margin, as well as well-known production fields at Potiguar exploratory investments increase significantly in the region and Ceará basins. However, when compared to Brazilian east of Guinea Gulf and lead to discovery of petroleum fields margin, those basins are very poor studied, specifically Pará- with the same characteristics in the margin of Ivory Coast, Maranhão and Barreirinhas at deep and ultra-deep waters. Sierra Leone and Liberia. Based on the theory of conju- Despite this, in recent years, these basins have attracted more gated margins, the same play was successfully tested in interest in petroleum prospecting due to the significant dis- the offshore region of French Guiana, where the Zaedyus coveries in related African equatorial margin basins (Guinea field was discovered, also in turbiditic sandstones and Gulf) and in French Guiana. This interest emerge because very similar to Jubilee play. The success of Zaedyus dis- both African and South American equatorial margin are con- covery suggests that there may be a second, world-class sidered analogous, since they were formed in the same geo- petroleum system analogous to Jubilee along the South logical context of transformant tectonic, culminating in the American side of the equatorial conjugate margin at deep opening of equatorial Atlantic Ocean in Cretaceous. and ultra-deep waters.

1Laboratório de Engenharia e Exploração de Petróleo, Universidade Estadual do Norte Fluminense Darcy Ribeiro – Campos dos Goytacazes (RJ), Brazil. E-mails: [email protected], [email protected] *Corresponding author. Manuscript ID: 20170146. Received on: 12/14/2017. Approved on: 07/26/2018.

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The understanding of transforming , as well Maranhão state and its adjacent continental shelf, occupy- as the evolution of the basins associated to this tectonic ing an area of 46,000 km2 approximately, with 8,500 km2 regime is of great importance, since there is still an explor- located at onshore portion (Feijó 1994, Trosdtorf Júnior atory frontier related to Brazilian equatorial margin basins. et al. 2007). The limit between these basins is arbitrary since In addition, the seismic-stratigraphic interpretation and there is no geological feature that justifies their separation. seismic geomorphology are indispensable tools for the off- The origin and evolution of Brazilian equatorial mar- shore study of these basins, especially in deep and ultra-deep gin basins were considered analogous with Brazilian east margin waters where there’s no information from exploratory wells. basins for many years, where the most important offshore oil Using seismic facies analysis and seismic geomorphology is fields are located, including Santos, Campos, Espírito Santo possible to interpret the internal and external architecture and Sergipe-Alagoas basins, for example. However, while at the of depositional elements in subsurface, and so help to iden- eastern margin the origin and evolution of basins are related tify possible plays related to turbiditic sandstone at deep and to divergent tectonics and is where the three classical tectonic ultra-deep waters. stages are recognized (, transitional and ), the equatorial margin is characterized by directional and/or oblique tectonics associated with transformant faults zones, GEOLOGICAL SETTING culminating with Atlantic Ocean formation. The main characteristics of Brazilian equatorial margin The Brazilian equatorial margin includes all West- basins include: late continental rupture when compared Northwest (WNW) basins located in emerged and offshore to basins of the eastern margin (with the exception of Potiguar areas along the states of Amapá, Pará, Maranhão, Piauí, basin continental rift); continental rupture controlled by Ceará and Rio Grande do Norte, and includes, from east transforming tectonics with dextral directional kinematics; to west, Potiguar, Ceará, Barreirinhas, Pará-Maranhão and subsidence and uplift events of diachronic character con- Foz do Amazonas basins, besides the Marajó, Cassiporé, trolled by divergent, transtensive or transpressive tecton- São Luís — Ilha Nova, Bragança-Viseu and Tacutu . ics of each margin segment; sub-basins present contrasting The Pará-Maranhão is exclusively offshore basin, located at histories in terms of thermal flow, sedimentary facies distri- Pará and Maranhão states, occupying an area of approximately bution, magmatism and deformation episodes; the absence 48,000 km2 with elongated geometry at SE-NW direction of transitional evaporitic sequence at Aptian, as well as the as shown in Figure 1 (Brandão & Feijó 1994, Soares et al. absence of structures and sedimentation associated with salt 2007). The Barreirinhas basin covers part of the coast of tectonics as found in the eastern margin basins (Françolin & Szatmari 1987, Szatmari et al. 1987, Matos 1999, 2000, Milani et al. 2000, Mohriak 2003, Zálan 2004, Basile et al. 2005, Brownfield & Charpentier 2006). Matos (1999, 2000) proposed the systematization of an evolution model for Brazilian equatorial margin and defined three main tectonic stages: pre-transformant, sin-transfor- mant and post-transformant. The same model can be applied to African equatorial margin basins, including the offshore basins of Sierra Leone, Liberia, Cote d’Ivoire, Ghana, Togo, Benin, and western Nigeria, and can also be applied to off- shore basins of Guyana, Suriname and French Guiana on the South American margin. These east-west aligned basins of both Africa and South American are characterized by similar structural and sedimentary features, due to their common origin as transtensional rifting and wrench during the breakup of the African and American paleocontinents (Brownfield & Charpentier 2006). The pre-transformant stage (pre-Albian) corresponds to rifting processes that preceded the formation of Equatorial Source: modified from Mohriak (2003). Atlantic, including the Triassic-Jurassic stretching and frag- Figure 1. Map of the Brazilian basins with location of mentation phase which formed the Tacutu, Marajó and Pará-Maranhão and Barreirinhas basins. Cassiporé rifts and associated magmatism, as well as Potiguar

486 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Bruna da Silva Pellegrini & Hélio Jorge Portugal Severiano Ribeiro

rift opening at Noecomian-Barremian (Matos 1999, 2000, (Aptian), including Codó Formation; Rift III (Albian), includ- Milani et al. 2007). The Neocomian rifting that occurred ing Canarias Group; Drift (Late Albian to Recent), including at Potiguar Basin coincided in time with rupture in eastern Caju and Humberto de Campos groups, besides basaltic mag- margin of Brazil and implantation of Recôncavo-Tucano- matism of Late Cretaceous, Eocene and Miocene. Jatobá and Sergipe-Alagoas rifts (Szatmari et al. 1987, Soares Those basins are considered analogous to Ivory Coast & Rossetti 2005). However, the Barremian-Aptian limit and Tano basins in Guinea Gulf, all of them located between registers an important phase of and intracontinental Romanche and São Paulo Transform Zones. fracturing, with sediments accumulation in several depocen- The Brazilian equatorial margin basins have source ters, such as Potiguar, Ceará, Barreirinhas, Pará-Maranhão, rocks in five main stratigraphic intervals: marine shales of Bragança-Viseu/São Luís and Foz do Amazonas basins Devonian (Pimenteiras Formation in the Pará-Maranhão (Matos 2000). The rifting pattern along the equatorial margin and Barreirinhas basins); lacustrine shales of Neocomian presents E-W segments alternated with SE-NW segments. (Pendência Formation in the Potiguar basin); lacustrine The syn-transforming stage (Albian-Cenomanian) and lagoons shales of Aptian (Cassiporé and Codó forma- marks the period from the establishment of first oceanic tions in the Foz do Amazonas basin, Codó Formation in accretion centers at equatorial margin until the end of the Pará-Maranhão and Barreirinhas basins, Mundaú and control of transforming faults at basins. At this stage, the Paracuru Formation in the Ceará basin, Pescada and Alagamar transtensive and transpressive processes acted concom- formations in the Potiguar basin); calcilutites and marine itantly, generating simultaneous subsidence and uplift shales of Albian-Cenomanian (Limoeiro Formation in the events in different basins (Matos 1999, 2000). The tec- Foz do Amazonas basin, Caju Group in the Pará-Maranhão tonic environment at equatorial margin in Albian was con- and Barreirinhas basins); marine shales of Cenomanian- trolled by translational movement between South America Turonian (Travosas Formation in the Pará-Maranhão and and Africa, with dextral directional movement along the Barreirinhas basins). transforming faults. In addition, the Albian period is Thus, at Pará-Maranhão and Barreirinhas basins characterized by continental and shallow marine depo- there are four main source rocks, corresponding to sitional environment with siliciclastic sedimentation in marine shales of the Pimenteiras Formation (Devonian), intracontinental basins. Open marine conditions occurred lagoons shales of the Codó Formation (Aptian), calci- from Upper Albian, indicating the definitive disconnec- lutites and marine shales related to Caju Group (Late tion between Africa and South America (Szatmari et al. Albian-Cenomanian), and marine shales of the Travosas 1987, Azevedo 1991, Matos 2000, Basile et al. 2005). Formation (Cenomanian-Turonian) (Soares et al. 2007, According to Matos (2000), at Barreirinhas basin and Trosdtorf Júnior et al. 2007). Mundaú sub-basin (Ceará basin) the deformation was The reservoirs occur at four main stratigraphic intervals essentially transtensive, dominated by distension, while at Brazilian equatorial margin: fluvial-deltaic sandstones of at Pará-Maranhão and Potiguar east the transtention were the Neocomian-Albian (Cassiporé Formation in the Foz do dominated by directional movement associated to São Amazonas basin, Canárias Group in the Pará-Maranhão basin, Paulo and Chain Faults. The Piauí-Camocim sub-basin Bom Gosto and Barro Duro formations in the Barreirinhas (Ceará basin) has one of the most important transpres- basin, Mundaú and Paracuru formations in the Ceará basin, sive deformation records, with compressive structures Pendência, Pescada and Alagamar formations in the Potiguar such folds and faults (Zalán & Warme 1985). basin); shelf sandstones and turbiditic sandstones of Late From Cenomanian, equatorial margin basins started the Cretaceous-Paleogene (Limoeiro Formation in the Foz do drift , which was given in a context of trans- Amazonas basin, Travosas Formation in the Pará-Maranhão forming passive margin until the Santonian. From the Upper and Barreirinhas basins, Ubarana Formation in the Ceará Santonian to Recent, the drift phase occurs at divergent con- basin, Açu and Ubarana formations in the Potiguar basin); ditions. This last phase is characterized by a predominance of porous and fractured calcarenites of the Paleogene (Amapá distensional deformation in addition to continuous thermal Formation in the Foz do Amazonas basin, Ilha de Santana subsidence that is post-rupture lithospheric cooling conse- Formation in the Pará-Maranhão basin); shelf sandstones quence (Matos 1999, 2000, Basile et al. 2005). and turbidite sandstones of Neogene (Orange Formation The Pará-Maranhão and Barreirinhas basins are com- in the Foz do Amazonas basin). posed of five main mega sequences, as described by Soares Therefore, at Pará-Maranhão basin there are three main et al. (2007) and Trosdtorf Júnior et al. (2007): intracra- reservoir rocks, including fluvial-deltaic sandstones of the tonic (Paleozoic), including Canindé Group; Rift Canárias Group (Albian), fractured limestones, banks, II (Aptian), including “Inominate” Formation; Pre-Rift III reefs, talus deposits and carbonate turbidites of the Ilha de

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Santana Formation (Paleogene), and turbidite sandstones was: Black (1984), Françolin & Szatmari (1987), Szatmari et of the Travosas Formation (Late Cretaceous-Paleogene). al. (1987), Azevedo (1991), Silveira (1993), Brandão & Feijó At Barreirinhas basin there are three main reservoirs, includ- (1994), Feijó et al. (1994), Silveira et al. (1994), Anjos (1999), ing shelf sandstones of the Bom Gosto and Barro Duro for- Matos (1999, 2000), Schiefelbein et al. (2000), Mohriak mations (Albian) and turbiditic sandstones of the Travosas (2003), Pasley et al. (2004), Zalán (2004), Basile (2005), Formation (Late Cretaceous-Paleogene) (Soares et al. 2007, Brownfield& Charpentier (2006), Milani et al. (2007), Soares Trosdtorf Junior et al. 2007). et al. (2007), Trosdtorf Júnior et al. (2007), Soares Júnior et al. (2008), Jewell (2011), Nóbrega (2011), Soares Júnior et al. (2011), Fabianovicz (2013), Ferreira (2013), and Borsato DATASET AND METHODS et al. (2016). Four main horizons and four main stratigraphic inter- The data used in seismic interpretation correspond to post vals were interpreted. The interpretation of possible sandy stack 2D seismic lines and well informations, all of which turbidites, considered as potential petroleum reservoirs, provided by the National Agency of Petroleum, Natural Gas was made considering horizons with high reflectance, and Biofuels (ANP). The location of seismic lines and well low frequency and lens geometry in 2D seismic data. informations used are presented in Figure 2. Due to the quality of the 2D seismic data, the interpre- Seismic data consist of 15 seismic lines, with 10 in dip and tation was mainly concentrated at deep basin and con- 5 in strike direction. Nine lines are located at Pará-Maranhão tinental shelf, because the region of transition between basin and six lines at Barreirinhas basin. In addition, informa- these segments has noisy seismic data, making interpret- tion of eight wells were used, being five in the Pará-Maranhão ing difficult and imprecise. basin and three in the the Barreirinhas basin, all of them located in continental shelf and shelf border, with no infor- mation at deep and ultra-deep waters. In these cases, seismic SEISMIC INTERPRETATION information available in literature and well informations of shallow waters was extrapolated to that region. The well Four major horizons were interpreted on studied seismic informations used include geophysical profiles, lithological lines, which were chosen based on other seismic interpretations description, hydrocarbons shows, geochemical and chronos- in the region, and based on the main unconformities present tratigraphic data. For the eight wells available for this paper, in the two basins (Silveira 1993, Silveira et al. 1994, Anjos two are considered subcomercial oil producers, one is consid- 1999, Matos 1999, 2000, Brownfield & Charpentier 2006, ered subcomercial gas producer, one is considered to contain Soares et al. 2007, Trosdtorf Júnior et al. 2007, Fabianovicz gas, and four others are considered non-commercial or dry. 2013, Ferreira 2013). A fifth horizon, the seabed, has not The OpendTect® software was used for the interpretation of been interpreted since it is explicit, and consists in the top seismic data.The main published papers of both Brazilian and of the most recent sedimentary interval. The four inter- African equatorial basins used to help seismic interpretation preted horizons are Basement Top (BT), Albian Top (AT), Cretaceous Top (CT) and Oligocene Top (OT). These hori- zons delimit, respectively, the base of four sedimentary inter- vals, called Early Cretaceous (EK), Late Cretaceous (LK), Paleocene-Oligocene (P-O) and Miocene-Recent (M-R), whose top is the seafloor. The oceanic basement is characterized by chaotic inter- nal configuration and it is delimited on top by BT horizon (Fig. 3). The horizon is commonly cut by normal faults composing horsts and (Fig. 4). An ocean ridge, a notable geomorphological feature, occurs at Pará-Maranhão basin seismic lines, attributed to São Paulo Transform Zone, which isolated the proximal depocenter of continental margin from its most distal portion towards the ocean basin. At seis- mic data of Barreirinhas basin does not occur the São Paulo Transform Zone because the basin is eastwards of its limit. The basement was better interpreted at deep basin Figure 2. Location of seismic lines and wells. region because the seismic lines lose resolution in deeper

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parts at continental shelf. According to Soares et al. (2007) In the seismic line 0275-09740 is possible to observe an and Trosdtorf Júnior et al. (2007), at continental shelf the abrupt change in reflectors inclination present in EK inter- basement of Pará-Maranhão basin is composed of São Luis val (Fig. 4), which can be attributed to an unconformity Craton and Santa Luzia-Viseu Belt, while at Barreirinhas between the Aptian and Albian. This unconformity is well basin the basement is composed of São Luís Craton and characterized in the literature and stratigraphic charts of the Gurupi Belt. At deep/ultra-deep waters the basement is basins, and is attributed to change from an anoxic evaporitic composed of basaltic rocks. marine environment to marine shelf, which marks the tran- The EK interval overlays the BT horizon and presents sition from sag basin pre-rift stage to rift stage (Soares et al. subparallel to divergent internal reflections pattern with 2007, Trosdtorf Júnior et al. 2007). sheet and wedge external geometry, which are indicative The LK interval overlays the AT horizon, and presents of syn-tectonic deposition. The sequence top is the AT internal configuration ranging from parallel to subparal- horizon, defined by reflectors with onlap terminations lel reflections of low continuity and sheet external geom- above its surface (Fig. 4). The Late Albian is character- etry at continental shelf and deep basin, and also shows ized as the breakup, which is the moment when there chaotic internal configuration which are characteristic of was the rupture between South American and African mass transport deposits (Fig. 5) at deep basin. In the con- paleocontinents. So this surface is characterized by a text of studied area, this sequence is attributed to shallow significant regional unconformity which occurs in both marine deposition with high energy sands deposition of Pará-Maranhão and Barreirinhas basins, and is associated Areinhas Formation, and carbonates deposition of Bonfim with eustatic fall caused by the South Atlantic opening and Ilha de Santana formations in low energy at conti- (Matos 1999, 2000, Soares et al. 2007, Trosdtorf Júnior nental shelf. At deep basin, this sequence is interpreted as et al. 2007). The entire EK interval, as well as the under- uniform and predominantly pelitic deposition in confor- lying basement, is cut by normal faults, often showing mity with underlying surface, in a low energy deep marine horsts and grabens configuration, which is characteristic environment attributed to Travosas Formation. Moreover, of the rift phase (Fig. 4). is also common the presence of sandy turbidites attributed

A B

Figure 3. In (A) is presented 0270-3019 seismic line (Two Way Time—TWT vertical scale) showing basement with chaotic internal configuration. In (B) is presented 0270-3010 seismic line (TWT vertical scale) showing magmatic intrusion into overlying sedimentary package with chaotic internal configuration.

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to Travosas Formation inside the pelites of the same for- depositional processes of higher energy. Unit top is the OT mation (Soares et al. 2007, Trosdtorf Júnior et al. 2007). horizon, which is characterized by reflectors in conformity The top of the sequence is the CT horizon, which is defined in continental shelf and by onlap terminations at deep basin by onlap terminations above its surface and occurs as a (Fig. 6B). At the faulted shelf border the reflectors are often regional unconformity in the stratigraphic charts of Pará- folded and may also show a disrupted pattern due to the Maranhão and Barreirinhas basins (Fig. 5). large number of synthetic listric faults present in this margin The P-O interval overlays the CT horizon and presents segment (Fig. 6C). The interval is associated to deposition subparallel to complex sigmoid-oblique internal configura- of sandy lithotypes of Areinhas Formation and carbonates tion with sheet and slope filling external geometry at conti- of Ilha de Santana Formation at continental shelf, and depo- nental shelf (Fig. 6A). Parallel reflections with medium to sition of pelites and sandy turbidites of Travosas Formation high continuity configurations occurs at deep basin, indi- at the most distal segments (Soares et al. 2007, Trosdtorf cating lithological alternations and sheet external geometry, Júnior et al. 2007). According to mentioned authors, there besides chaotic internal configuration which are character- is a regional unconformity present in Brazilian equatorial istic of mass transport deposits (Fig. 6B). The continuity basins stratigraphic charts related to the Oligocene interval, of the reflections decreases in continental shelf, probably which is assigned to OT horizon of this study. indicating the greater presence of sands associated with The M-R interval overlays OT horizon and is character- ized by parallel internal configuration, sometimes showing contorted configuration, with medium to high continuity and sheet external geometry (Fig. 7A). The relative contin- uous reflectors indicate existence of lithological alternation between fine sands and clays. The sequence may also present free pattern and sheet external geometry, which indicates the presence of homogeneous or non-stratified lithologies related to hemipelagites. As well as last intervals mentioned before,

Figure 4. 0275-09740 seismic line (TWT vertical scale) with emphasis on Early Cretaceous interval and Albian Top horizon. The Early Cretaceous interval is Figure 5. 0270-3019 seismic line (TWT vertical scale) characterized by subparallel to divergent internal with Late Cretaceous interval and Cretaceous Top reflections pattern, and Albian Top horizon is defined horizon at deep basin. The interval is characterized by reflectors with onlap terminations above its surface. by parallel to subparallel reflections of low continuity The dashed red line is attributed to an unconformity internal configurations, and chaotic seismic facies between the Aptian and Albian. The basement and which are characteristic of mass transport deposits. Early Cretaceous intervals are often cut by normal The Cretaceous Top horizon is defined by reflectors faults characteristics of rift phase. with onlap terminations above its surface.

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M-R interval is characterized by the presence of synthetic lis- Formation and carbonates of Ilha de Santana Formation at con- tric faults which occur predominantly at the shelf border, often tinental shelf, and deposition of pelites and sandy turbidites of showing reflectors with folded pattern (Fig. 7B). This interval Travosas Formation at the most distal segments (Soares et al. is also related to deposition of sandy lithotypes of Areinhas 2007, Trosdtorf Júnior et al. 2007).

B A

C

Figure 6. In (A) is presented 0275-01180 seismic line (TWT vertical scale) at continental shelf, showing Paleocene- Oligocene interval with internal configuration ranging from parallel to complex sigmoid-oblique. In (B)is presented 0275-01180 seismic line (TWT vertical scale) at deep basin, showing Paleocene-Oligocene interval with parallel internal configuration and chaotic internal configuration which are characteristic of mass transport deposits. The Oligocene Top horizon is characterized by onlap terminations above its surface. In (C) is presented 0270-3010 seismic line (TWT vertical scale) at shelf border, showing Paleocene-Oligocene interval with folded internal configuration due to listric faults present at this margin segment.

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A B

Figure 7. In (A) is presented 0239-247 seismic line (TWT vertical scale) at deep basin showing Miocene-Recent interval, which presents contorted and parallel internal configuration with medium to high continuity and sheet external geometry. In (B) is presented 0239-209 seismic line (TWT vertical scale) at shelf border, showing Miocene-Recent interval with folded internal configuration due to listric faults present at this margin segment.

CONSIDERATIONS ABOUT SOME of rollovers , apparently with axes in NW-SE direc- IMPORTANT STRUCTURAL FEATURES tion, which can work as trap for hydrocarbons. The age of this set of faults is post-transformant stage because it affects almost The analysis of the seismic sections suggests a differ- all stratigraphic sequence of the basins, with the exception ence in the structural styles of the intervals deposited above of post Oligocene thin sedimentary cover deposited during and below the AT horizon. The structural framework of drift tectonics. In some seismic lines of Barreirinhas Basin, Basement and EK sequences is characterized by the presence reverse faults at continental rise related to this same tectonic of large synthetic and antithetical normal faults, commonly event were interpreted, as shown in Figure 9. configuring horsts and grabens (Fig. 8), which were formed The São Paulo Transform Zone corresponds to one of during rift stage of Brazilian equatorial margin and persisted the most expressive transformant zone of the planet. until the end of Albian (Soares et al. 2007, Trosdtorf Júnior In the seismic sections of Pará-Maranhão basin this feature et al. 2007). The structural framework of LK, P-O and M-R occurs as a notable ocean ridge which isolated the proximal sequences is characterized by synthetic and antithetic lis- depocenter of continental margin from its most distal por- tric faults which occur mainly at the shelf border (Fig. 8). tion towards the ocean basin (Fig. 8). At Barreirinhas basin This same type of fault also occurs at SW and NE border of this feature does not occur because the basin is located east- São Paulo Transform Zone. This set of faults generates a series wards of São Paulo Transformant Zone limit.

492 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Bruna da Silva Pellegrini & Hélio Jorge Portugal Severiano Ribeiro

Figure 8. 0235-09740 seismic line (TWT vertical scale) showing two set of faults. The first one occurs in pre-Albian units and is related to rift phase, which is characterized by horsts and grabens configuration. The second occurs in post-Albian units and are related to listric faults at shelf border and to São Paulo Transform Zone border at deep waters.

PETROLEUM SYSTEMS

The main source rocks of Pará-Maranhão and Barreirinhas basins are marine shales of Pimenteiras Formation (Devonian), lagoons and anoxic evaporitic marine shales of Codó Formation (Aptian); calcilutites and marine shales of Caju Group (Albian-Cenomanian) and marine shales of Travosas Formation (anoxic events of Cenomanian-Turonian) (Soares et al. 2007; Trosdtorf Júnior et al. 2007, Fabianovicz 2013, Ferreira 2013). According to Schiefelbein et al. (2000), correlated oil samples of these basins has transitional marine origin and mixture of organic matter of lacustrine and marine origin. The main reservoirs of Pará-Maranhão basin are flu- vial-deltaic sandstones of the Canárias Group (Albian), fractured limestones, banks, reefs, talus and carbonate tur- bidites of the Ilha de Santana Formation (Paleogene) and Figure 9. 0239-0163 seismic line (TWT vertical scale) turbiditic sandstones of the Travosas Formation (LK to showing reverse faults at continental rise of the Barreirinhas basin. Paleogene). The main reservoirs of the Barreirinhas basin

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correspond to marine sandstones of the Bom Gosto and and Zaedyus play in French Guiana. In this way, three Barro Duro formations (Albian) and turbiditic sandstones possible petroleum systems were identified in the seis- of the Travosas Formation (LK to Paleogene) (Soares et al. mic lines of both Pará-Maranhão and Barreirinhas: 2007, Trosdtorf Júnior et al. 2007, Fabianovicz 2013, Codó-Travosas (source rock from Aptian and reser- Ferreira 2013). voir from LK to Paleogene), Caju-Travosas (source Although there are others possible petroleum systems, rock from Albian-Cenomanian and reservoir from this research focused on identification of plays associ- LK to Paleogene) and Travosas-Travosas (source rock ated to turbiditic sandstones of Travosas Formation, from Cenomanian-Turonian and reservoir from LK to which can be correlated to Jubilee play in Guinea Gulf Paleogene). The Figure 10 shows the stratigraphic charts

Source: modified from Soares et al. (2007), Trosdtorf Júnior et al. (2007). Figure 10. Pará-Maranhão and Barreirinhas basins stratigraphic charts showing the identified possible petroleum systems.

494 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Bruna da Silva Pellegrini & Hélio Jorge Portugal Severiano Ribeiro

of Pará-Maranhão and Barreirinhas basins showing these petroleum systems identified in this research. The interpreted turbiditic sandstones have reflectors with high acoustic impedance contrasts, low frequency, lense external geometry and longitudinal extension vari- able, ranging from 1 to 15 km. This seismic facies was identified in three distinct segments of the margin: shallow waters, faulted shelf border and deep/ultra-deep waters. Turbidites of shallow waters generally have the smallest extension and are identified at the base of progradant clino- forms, with internal configuration ranging from oblique tangential to oblique-sigmoidal complex. Turbidites asso- ciated to faulted shelf border are limited by listric faults and commonly occur at rollover anticlines. The turbidites of deep/ultra-deep waters are the most extensive, reach- ing up to 15 km, and are commonly associated with mass transport deposits. In this way, as the main plays focused in this paper are associated to turbidites, such plays were also identified in three distinct segments of the margin: shallow waters play, faulted shelf border play and deep/ultra-deep waters play. The last one is the most importante in this research, since it is cor- related to Jubilee play in Guinea Gulf and Zaedyus play in *Well location is projected. French Guiana. Figure 11. 0275-8780 seismic line (TWT vertical scale) showing the play associated to shallow water turbidites Shallow waters turbidite plays of Late Cretaceous at the base of progradant clinoforns. The plays of shallow waters occur as turbidites at pro- gradant clinoforms base of continental shelf (Fig. 11) and belong to Travosas Formation (LK). The possible source rock could be the marine shales and calcilutites of the Caju Group (Late Albian-Early Cenomanian) and marine shales of the Travosas Formation (Cenomanian-Turonian), and migration occurs directly from source rock to reservoir as shown in Figure 12. The seal rocks are also the shales of Travosas Formation, and the trap is of stratigraphic type by depositional pinch-out. Seven wells information available for this research pres- ent geochemical data obtained from lateral sample or drill cuttings, and 543 samples were analyzed for the percent- age of Total Organic Carbon (TOC), corresponding only 245 samples to Albian to Turonian source rock interval. These measurements were obtained both in shales with intercalations of siltite, sandstones, marls, calcisiltites and Figure 12. Schematic geological section based on the seismic line 0275-8780 (TWT vertical scale), showing limestones belonging to Travosas Formation. From these the play associated to shallow water turbidites of the 245 samples, 116 present TOC below 0.5%, and there Late Cretaceous. The hydrocarbon generated by source is no potential as source rocks; 62 samples present TOC rocks of the Caju Group (Late Albian-Early Cenomanian) between 0.5 e 1.0%, with low potential as source rock and Travosas Formation (Cenomanian-Turonian) in the case of carbonate rocks; 58 samples present TOC migrated to turbiditic sandstones of the Travosas Formation (Late Cretaceous). The trap is stratigraphic between 1.0 e 1.5%, with some potentital as source rocks; type, consisting in sandstones inside shales. The red and only 9 samples present TOC above 1.5%, reaching arrows indicate the possible hydrocarbon migration a maximum of 1.66%. routes. The well location is projected.

495 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Exploratory plays of Pará-Maranhão and Barreinhinhas basins

Considering the Hydrogen Index (mgHC/gTOC) ver- sus Oxygen Index (mgCO2/gTOC) of the samples from Albian to Turonian obtained from the wells, it was verified that they have mainly Type II and Type III organic matter. According to Tissot & Welte (1984), Type II organic mat- ter, which is derived from autochthonous marine organic matter deposited in a reducing environment, is favorable to oil and gas generation, while Type III organic matter, which are originated from terrestrial plants, is favorable to gas generation at great depths. A total of 208 samples from six wells was used for Maximum Temperature (Tmax) analysis. Of these, 11 sam- ples have Tmax below 400ºC, and 164 samples have Tmax between 400 and 440ºC and are considered immature according to Tissot & Welte (1984). On the other hand, 28 samples presented Tmax between 440 and 470ºC, and are considered at mature zone. Finally, only five samples presented Tmax above 470°C and are considered senile. According to well data, the depth of Late Albian-Early Cenomanian and Cenomanian-Turonian source rocks at the continental shelf of Pará-Maranhão and Barreirinhas basins occurs approximately between 2,400 and 3,700 m below sea water bottom. At this depth, there is the pos- sibility of oil and gas generation, and more details will be discussed in the next topics.

Faulted shelf border turbidite plays The play of faulted shelf border occurs as turbidite lenses limited by a set of synthetic and antithetic listric faults and belong to Travosas Formation (LK to P-O) as presented in Figure 13. The possible source rock could be the marine shales and calcilutites of the Caju Group (Late Albian-Early Cenomanian) and marine shales of the Travosas Formation itself (Cenomanian-Turonian), and Figure 13. 0275-8780 seismic line (TWT vertical scale) showing probable play associated to faulted migration occurs through listric faults from the source shelf border turbidites of the Late Cretaceous and rocks to the reservoir (Fig. 14). The seal rocks are also Paleocene-Oligocene. the shales of Travosas Formation and the traps are dom- inantly of mixed type, with depositional pinch-out and strong structural component of rollovers anticlines and associated faults. sedimentary package as a whole was 2,600 m/s, while the The depth of Late Albian-Early Cenomanian and average speed for water was 1,500 m/s. Based on this data, Cenomanian-Turonian source rocks was obtained by it was inferred that Late Albian-Early Cenomanian and approximation, based on the horizons interpreted in seis- Cenomanian-Turonian source rocks occur approximately mic data. The sedimentary package as a whole has aver- between 1,400 and 4,500 m below sea water bottom at age seismic depth between 1,100 and 3,500 ms below Pará-Maranhão basin, and approximately between 1,300 sea water bottom at Pará-Maranhão basin, and between and 4,800 m below sea water bottom at Barreirinhas 1,000 and 3,700 ms at Barreirinhas basin. For conver- basin. In these depths, there is the possibility of oil and sion of time to depth, it was used an average velocity gas generation, however the possibility of oil biodegrada- obtained from the Vertical Seismic Profile (VSP) well tion to the shallower reservoirs must be considered. More data of shallow waters. The average speed used for the details will be discussed in the next topics.

496 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Bruna da Silva Pellegrini & Hélio Jorge Portugal Severiano Ribeiro

Figure 14. Schematic geological section based on the seismic line 0275-8780 (TWT vertical scale), showing the play associated to faulted shelf border turbidites of the Late Cretaceous and Paleocene-Oligocene. Hydrocarbons generated by source rocks of the Caju Group (Late Albian-Early Cenomanian) and Travosas Formation (Cenomanian-Turonian) migrated by listric faults to turbiditic sandstones of Travosas Formation (Late Cretaceous to Paleocene-Oligocene). The trap may be stratigraphic and/or structural type. The red arrows indicate the possible hydrocarbon migration routes.

Deep/ultra-deep waters turbidite plays The play of deep and ultra-deep waters occurs as lenses of turbidites and belongs to Travosas Formation (LK and Figure 15. 0275-8780 seismic line (TWT vertical scale) P-O) as shown in Figure 15. There are three possibles showing the play associated to ultra-deep water source rocks for this play: the lagoon shales of the Codó turbidites of Late Cretaceous to Paleocene-Oligocene. Formation (Aptian), marine shales of the Caju Group (Late Albian-Early Cenomanian) and marine shales of The approximate depth of source rocks from Aptian, the Travosas Formation (Cenomanian-Turonian). In the Late Albian-Early Cenomanian and Cenomanian-Turonian first case, the hydrocarbons generated by shales of the was obtained by approximation, based on the horizons Codó Formation migrated through the contact between interpreted in seismic data. These source rock intervals intrusive rocks of São Paulo Transform Zone and basin were identified only in seismic lines of Pará-Maranhão sedimentary package and then by listric normal faults basin, since the seismic lines of Barreirinhas basin have towards turbidites of the Travosas Formation. In the sec- poor resolution in depth, and are not possible to make ond case, the hydrocarbons generated by shales of the an accurate interpretation. The Aptian source rock has Caju Group migrated through the listric faults to turbid- average seismic depth from 2,200 to 3,500 ms below sea ites of the Travosas Formation or migrate directly from water bottom, and the Late Albian-Early Cenomanian/ source rock to turbidites. In the third case, the hydro- Cenomanian-Turonian source rocks have average seismic carbons generated by shales of the Travosas Formation depth from 1,100 to 2,900 ms. For conversion of time to migrated through the listric faults to turbidites of the depth an average velocity obtained from the VSP wells Travosas Formation or migrate directly from source rock data located at continental shelf was used. Thus, the aver- to reservoir. The seal rocks are the shales of the Travosas age speed used to the sedimentary package as a whole was Formation itself, and the trap is stratigraphic type (dep- 2,600 m/s, while the average speed for water was 1,500 ositional pinch-out). The schematic geological section m/s. Based on this data, it was inferred that the Aptian with this play is presented in Figure 16. source rock depth is aproximately from 2,860 to 4,550 m

497 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Exploratory plays of Pará-Maranhão and Barreinhinhas basins

Table 1. Comparison between the source rocks and reservoirs of Pará-Maranhã/Barreirinhas basins with Guinea Gulf basins. Pará-Maranhão and Guinea Gulf Basins Barreirinhas Basins Source rocks Source rocks Devonian-transitional marine shales Devonian-marine shales (Pimenteiras Formation) __ Neocomian-lacustrine shales Aptian lagoon shales __ (Codó Formation) Middle Albian - __ terrestrial shales Late Albian to Early Cenomanian - marine shales Late Albian - marine shales and calcilutites (Caju Group) Figure 16. Schematic geological section based on the seis- Cenomanian-Turonian - marine Cenomanian-Turonian - mic line 0275-8780 (TWT vertical scale), showing the play shales (Travosas Formation) marine shales associated to deep/ultra-deep water turbidites of the Late Reservoirs Reservoirs Cretaceous and Paleocene-Oligocene. The hydrocarbons Late Cretaceous to Paleogene - generated by source rocks of the Codó Formation (Ap- Cretaceous – turbidites tian) migrated through the contact between the intrusive turbidites (Travosas Formation) rocks of São Paulo Transform Zone and basin sedimentary Source: based on Brownfield & Charpentier (2006), Soares et al. (2007), package, and then through the listric faults to turbidites Trosdtorf Júnior et al. (2007), Fabianovicz (2013), Ferreira (2013). of the Travosas Formation (Paleocene-Oligocene). The hy- drocarbons generated by source rocks of the Caju Group (Albian-Cenomanian) migrated through listric faults to The Pará-Maranhão and Barreirinhas basins have marine turbidites of the Travosas Formation. The hydrocarbons source rocks from Devonian (Pimenteiras Formation), and generated by source rocks of the Travosas Formation Guinea Gulf basins also have Devonian marine source (Cenomanian-Turonian) migrated through listric faults to rocks known according to Brownfield & Charpentier turbidites of the Travosas Formation or migrate directly from source rock to reservoir. The red arrows indicate the (2006). According to the same author, there is a known possible hydrocarbon migration routes. source rock in Guinea Gulf from Neocomian lacustrines shales in the northern Dahomey Embayment, Congo basin below sea water bottom, the Late Albian-Early Cenomanian and Ivory Coast basin, but which were not found in the source rock depth should be approximately from 2,200 to studied Brazilian basins. The source rocks from Aptian 3,800 m, and Cenomanian-Turonian source rock depth of the Codó Formation present in both Pará-Maranhão should be approximately from 1,430 to 2,860 m. and Barreirinhas basins have lagoon and marine evapo- It is also important to consider the proximity of the deep/ ritic anoxic origin according to Soares et al. (2007) and ultra-deep waters play with the intrusive rocks of the São Trosdtorf Júnior et al. (2007), and there is no source rock Paulo Transform Zone, which may have warmed those of this origin in the Gulf of Guinea. The source rocks source rocks constituting an atypical petroleum system. related to Middle Albian in the Guinea Gulf, consisting Thus, although the source rocks may be at maturity depth, of gas-prone terrestrial source rocks, and there is no corre- it can also be senile due to the high anomalous temperatures. spondence in the Brazilian basins. The Late Albian source rock, consisting of marine transgressive oil-prone source rocks present in the Guinea Gulf basins (Brownfield & DISCUSSION Charpentier 2006), may be correlated to the source rocks from Late Albian-Early Cenomanian of the Caju Group, As mentioned before, the Pará-Maranhão and Barreirinhas present in both Pará-Maranhão and Barreirinhas basins, basins are considered correlate to Ivory Coast and Tano which is composed of shales and cacilutites deposited in a basins of the Guinea Gulf, and there are similarities between transgressive marine depositional environment according existing petroleum systems, including source rocks with to Soares et al. (2007) and Trosdtorf Júnior et al. (2007). similar characteristics and formed at same geological time Finally, the source rocks from Cenomanian-Turonian interval, as well as reservoirs with the same characteris- of the Travosas Formation present in Pará-Maranhão and tics related to turbiditic sandstones, as shown in Table 1. Barreirinhas basins may be correlated to marine black

498 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Bruna da Silva Pellegrini & Hélio Jorge Portugal Severiano Ribeiro

shales related to anoxic events of Cenomanian-Turonian upward along faults from deeper source rocks. The seals of the Guinea Gulf basins. According to Brownfield & correspond to marine shales with minor fault-related Charpentier (2006), anoxic oceanic conditions that char- seals, while the traps include pre-transform traps related acterized the Middle Cretaceous and continued into the to fault blocks, syn-transform structural and stratigraphic Turonian worldwide affected the Gulf of Guinea result- traps, and post-transform stratigraphic traps (Brownfield ing in the deposition of black shale source rocks from & Charpentier 2006). Cenomanian-Turonian in the Ivory Coast and Tano basins. According to Dickson et al. (2016), total sediment Samples analyzed from deep sea drilling sites both north thicknesses along both transform margins of South and south of the Gulf of Guinea indicate that these source America and Africa exceed values associated with source rocks contain more than 10% of organic matter consist- maturity, depending on source position within the sed- ing in Type II kerogen. According to Mello et al. (1989), iment column. According to the same authors, oils and the anoxic conditions also prevailed during most of the other hydrocarbon evidence attest to the presence of Cenomanian-Santonian interval in the Brazilian continen- working source rocks along both margins, and effective tal margin too. The anoxic events in the Brazilian basins Cretaceous (Cenomanian–Turonian and possibly Albian) were intermittent, rather than continuous, covering rela- marine source rocks intervals have been demonstrated in tively short periods of time, most of them associated with oils sample set for both margins. sea level rises. The black shales of Cenomanian-Turonian Assuming that the approximate oil window top present in both Brazilian and African margins were depos- depth occurs at 2,700 m bellow sea water bottom in ited under the anoxic conditions of the Second Cretaceous the offshore of Guinea Gulf according to MacGregor Global Oceanic Anoxic Event (OAE-2), characterized by et al. (2003), it can be inferred that source rocks of periods of deposition of shale facies enriched in organic Pará-Maranhão and Barreirinhas basins must be at the matter in almost every ocean of the world (Mello et al. oil window depth too, since the source rocks of those 1989, Schiefelbein et al. 2000). basins reached the burial depth equal to or greater According to MacGregor et al. (2003) and Brownfield than 2,700 m bellow sea water bottom in all the plays & Charpentier (2006), the most important source rocks (shallow waters, faulted shelf border and deep/ultra- within Guinea Gulf Province are Albian, Cenomanian and deep waters). The source rocks of Late Albian-Early Turonian marine shales, with Type II and II-III oil-prone Cenomanian and Cenomanian-Turonian, for exam- kerogen and Type III terrestrial kerogen. These source ple, would beat an approximate depth from 2,400 to rocks are distributed throughout the offshore part of the 3,700 m below sea water bottom at shallow waters Guinea Gulf Province, and are expected to increase in and from 1,300 to 4,800 m below sea water bottom thickness and quality into deep waters. Two main areas of at faulted shelf border. At deep/ultra-deep waters the hydrocarbon generation were interpreted by MacGregor source rocks from Aptian would be at an approximate et al. (2003): the offshore of Ivory Coast and Tano basins; depth from 2,860 to 4,550 m, the source rocks of the offshore of Keta and Benin basins and the Dahomey Late Albian-Early Cenomanian would be from 2,200 Embayment. to 3,800 m, while the source rocks of Cenomanian- These two probable “oil kitchens” are only present Turonian would be from 1,430 to 2,860 m below sea in deep waters, where the source rocks have reached a water bottom. temperature of at least 100ºC and a vitrinite reflectance It is also important to consider the proximity of the of 0.6%, which are values equivalent to source rock deep/ultra-deep waters play with the intrusive rocks of below 2,700 m of overburden. Heat flow may increase the São Paulo Transform Zone, which may have warmed into the deep waters, as continental crust is thinner, those source rocks composing an atypical petroleum sys- giving shallower generation thresholds. According to tem. However, although the source rocks may be at matu- MacGregor et al. (2003), for the Guinea Gulf basins the rity depth, it may also be senile due to the high anoma- hydrocarbon generation started in the Late Cretaceous lous temperatures. for the Albian to Cenomanian source rocks and contin- Finally, although all interpreted plays (shallow waters, ues to the present. For the Turonian source rocks, hydro- faulted shelf border and deep/ultra-deep waters) should carbon generation possibly started in the Early Tertiary reached the burial depth for oil /gas generation, it is and also continues to the present. The reservoir rocks in important to emphasize that the greatest interest of this Guinea Gulf are mostly Cretaceous turbidite sandstones research are related to the deep/ultra-deep waters play, with minor potential of limestone units, and the migra- since Jubilee and Zaedyus plays are also located in deep/ tion was either directly from adjacent source rocks or ultra-deep waters.

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CONCLUSION interpreted in seismic data, and occurs at depths approx- imately from 1,300 to 4,800 m below sea water bottom. Four major seismic horizons were interpreted: BT, The deep/ultra-deep waters play occurs as lenses of tur- AT, CT and OT. These horizons delimit the base of four bidites and belongs to Travosas Formation (LK to P-O). seismic stratigraphic intervals, named EK, LK, P-O and There are three possible source rocks for this play: the M-R, whose top of the latter is the seafloor. lagoon shales of the Codó Formation (Aptian), calcilu- The structural analysis of the seismic lines suggests two tites and marine shales of the Caju Group (Late Albian- different structural styles. The first one occurs in the Pre- Early Cenomanian) and marine shales of the Travosas Albian interval and is composed by large normal faults, Formation (Cenomanian-Turonian). In the first case, the commonly configuring horsts and grabens, which were hydrocarbons generated by shales of the Codó Formation formed during rift stage of Brazilian equatorial margin migrated through contact between intrusive rocks of São and persisted until the end of Albian. The second occurs Paulo Transform Zone with basin sedimentary package in Post-Albian interval and is characterized by synthetic and then by listric normal faults towards turbidites of and antithetic listric faults which occur mainly at the the Travosas Formation. In the second case, the hydro- shelf border and also at São Paulo Transform Zone bor- carbons generated by shales of the Caju Group migrated der. These listric faults compose a series of rollovers anti- through listric normal faults to turbidites of the Travosas clines, apparently with axes in NW-SE direction, which Formation or migrate directly from source rock to tur- can work as trap for hydrocarbons. bidites. In the third case, the hydrocarbons generated by Although there are others possible plays in Pará- shales of the Travosas Formation migrated through listric Maranhão and Barreirinhas basins, this research focused normal faults to turbidites of the Travosas Formation or on identification of plays associated to turbiditic sand- migrate directly from source rock to turbiditic reservoirs. stones of the Travosas Formation, which may be cor- The source rocks depths of the Codó Formation (Aptian) related to Jubilee play in Guinea Gulf and Zaedyus play are approximately 2,860 to 4,550 m below sea water bot- in French Guiana. So, three play types in three distinct tom, for the Caju Group (Late Albian-Early Cenomanian) segments of the continental margin were identified: shallow should be approximately from 2,200 to 3,800 m, and waters, faulted shelf border, and deep/ultra-deep waters. for Travosas Formation (Cenomanian-Turonian) should The deep/ultra-deep waters play is the most extensive be from 1,430 to 2,860 m. Those depths were obtained and more important, since it is correlated to Jubilee and by approximation, based on the horizons interpreted in Zaedyus plays, which are also in deep/ultra-deep waters. seismic data. It is important to consider the proximity The plays of shallow waters occur as turbidites at pro- of the deep/ultra-deep waters play with the intrusive gradant clinoforms base of continental shelf and belong to rocks of São Paulo Transform Zone, which may have Travosas Formation (LK). The possible source rock could warmed those source rocks and composing an atypical be the marine shales and calcilutites of the Caju Group petroleum system. (Late Albian-Early Cenomanian) and marine shales of It is possible to affirm that there are similarities between the Travosas Formation (Cenomanian-Turonian), and the petroleum systems of the Gulf of Guinea and the migration occurs directly from source rock to reservoir. Pará-Maranhão and Barreirinhas basins, including source According to well data, the depth of the Late Albian-Early rocks with similar characteristics, composed of marine Cenomanian and Cenomanian-Turonian source rocks at shales of Late Albian to Turonian with Type II and III the continental shelf occurs approximately from 2,400 Kerogen, as well as reservoirs with the same characteris- to 3,700 m below sea water bottom. tics related to turbiditic sandstones of Late Cretaceous at The faulted shelf border play occurs as turbidites lenses deep/ ultradeep waters. Considering that the top depth limited by a set of listric faults and belong to Travosas of the oil window occurs about 2,700 m the offshore of Formation (LK to P-O). The possible source rock would Guinea Gulf, according to litherature data, it can be con- be the marine shales and calcilutites of the Caju Group cluded that at Pará-Maranhão and Barreirinhas basins (Late Albian-Early Cenomanian) and marine shales of there must be a generation of oil and/or gas at shallow the Travosas Formation itself (Cenomanian-Turonian), waters, faulted shelf border and deep/ultra-deep waters and migration occurs through listric faults from the plays based on the depths inferred. source rocks to the reservoir. The depth of the Caju Although the Pará-Maranhão and Barreirinhas basins Group (Late Albian-Early Cenomanian) and Travosas are still relatively poorly explored, with few wells only in Formation (Cenomanian-Turonian) source rocks intervals shallow waters, and none in deep/ultra-deep waters, they was obtained by approximation, based on the horizons present a great exploratory potential due to the similarity

500 Brazilian Journal of Geology, 48(3): 485-502, September 2018 Bruna da Silva Pellegrini & Hélio Jorge Portugal Severiano Ribeiro

with the Tano and Ivory Coast basins of Guinea Gulf. importance for the opening of new exploratory perspectives The recent discoveries in African Margin and French along the Brazilian equatorial margin as a whole. Guiana present a strong evidence for a major petroleum system working in the deep water areas and with source rocks and reservoirs common to both sides of the con- ACKNOWLEDGEMENTS jugate margin. The drilling density in both Pará-Maranhão and Barreirinhas The authors thank Universidade Estadual do Norte basins are still relatively low, and the majority of wells have Fluminense (UENF) and Laboratório de Engenharia been drilled in the shallow waters, with no information at e Exploração de Petróleo (LENEP) for infrastructure ultra-deep waters. In addition, the 3D seismic data existing and institutional support, the National Agency of are scarce and confidential. So, the researches in the region are Petroleum, Natural Gas and Biofuels (ANP) for the pro- insufficient when compared to the other Brazilian basins of vision of seismic lines and well data, and the Comissão de the eastern margin. The survey of 3D seismic, in addition to Aperfeiçoamento de Pessoal do Nível Superior (CAPES) for drilling of wells in deep/ultra-deep waters, would be of great the provision of scholarship.

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