Affinity of Small-Molecule Solutes to Hydrophobic, Hydrophilic, and Chemically Patterned Interfaces in Aqueous Solution
Affinity of small-molecule solutes to hydrophobic, hydrophilic, and chemically patterned interfaces in aqueous solution Jacob I. Monroea, Sally Jiaoa, R. Justin Davisb, Dennis Robinson Browna, Lynn E. Katzb, and M. Scott Shella,1 aDepartment of Chemical Engineering, University of California, Santa Barbara, CA 93106; and bDepartment of Civil, Architectural and Environmental Engineering, University of Texas at Austin, Austin, TX 78712 Edited by Peter J. Rossky, Rice University, Houston, TX, and approved November 17, 2020 (received for review September 30, 2020) Performance of membranes for water purification is highly influ- However, a molecular understanding that links membrane enced by the interactions of solvated species with membrane surface chemistry to solute affinity and hence membrane func- surfaces, including surface adsorption of solutes upon fouling. tional properties remains incomplete, due in part to the complex Current efforts toward fouling-resistant membranes often pursue interplay among specific interactions (e.g., hydrogen bonds, surface hydrophilization, frequently motivated by macroscopic electrostatics, dispersion) and molecular morphology (e.g., sur- measures of hydrophilicity, because hydrophobicity is thought to face and polymer configurations) that are difficult to disentangle increase solute–surface affinity. While this heuristic has driven di- (11–14). Chemically heterogeneous surfaces are even less un- verse membrane functionalization strategies, here we build on derstood but can affect fouling in complex ways.
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