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Vibrationally Excited Hydrogen Halides : a Bibliography On
VI NBS SPECIAL PUBLICATION 392 J U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards National Bureau of Standards Bldg. Library, _ E-01 Admin. OCT 1 1981 191023 / oO Vibrationally Excited Hydrogen Halides: A Bibliography on Chemical Kinetics of Chemiexcitation and Energy Transfer Processes (1958 through 1973) QC 100 • 1X57 no. 2te c l !14 c '- — | NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology, the Institute for Computer Sciences and Technology, and the Office for Information Programs. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consistent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry, and commerce. The Institute consists of a Center for Radiation Research, an Office of Meas- urement Services and the following divisions: Applied Mathematics — Electricity — Mechanics — Heat — Optical Physics — Nuclear Sciences" — Applied Radiation 2 — Quantum Electronics 1 — Electromagnetics 3 — Time 3 1 1 and Frequency — Laboratory Astrophysics — Cryogenics . -
Ammonia As a Refrigerant
1791 Tullie Circle, NE. Atlanta, Georgia 30329-2305, USA www.ashrae.org ASHRAE Position Document on Ammonia as a Refrigerant Approved by ASHRAE Board of Directors February 1, 2017 Expires February 1, 2020 ASHRAE S H A P I N G T O M O R R O W ’ S B U I L T E N V I R O N M E N T T O D A Y © 2017 ASHRAE (www.ashrae.org). For personal use only. Additional reproduction, distribution, or transmission in either print or digital form is not permitted without ASHRAE’s prior written permission. COMMITTEE ROSTER The ASHRAE Position Document on “Ammonia as a Refrigerant” was developed by the Society’s Refrigeration Committee. Position Document Committee formed on January 8, 2016 with Dave Rule as its chair. Dave Rule, Chair Georgi Kazachki IIAR Dayton Phoenix Group Alexandria, VA, USA Dayton, OH, USA Ray Cole Richard Royal Axiom Engineers, Inc. Walmart Monterey, CA, USA Bentonville, Arkansas, USA Dan Dettmers Greg Scrivener IRC, University of Wisconsin Cold Dynamics Madison, WI, USA Meadow Lake, SK, Canada Derek Hamilton Azane Inc. San Francisco, CA, USA Other contributors: M. Kent Anderson Caleb Nelson Consultant Azane, Inc. Bethesda, MD, USA Missoula, MT, USA Cognizant Committees The chairperson of Refrigerant Committee also served as ex-officio members: Karim Amrane REF Committee AHRI Bethesda, MD, USA i © 2017 ASHRAE (www.ashrae.org). For personal use only. Additional reproduction, distribution, or transmission in either print or digital form is not permitted without ASHRAE’s prior written permission. HISTORY of REVISION / REAFFIRMATION / WITHDRAWAL -
Questions ALKENES: REACTIONS with HYDROGEN HALIDES
Chemguide – questions ALKENES: REACTIONS WITH HYDROGEN HALIDES 1. State Markovnikov's Rule. 2. Show the structural formulae for the main product of each of the following addition reactions between various alkenes and a hydrogen halide. (This question is also testing your ability to write the structures for alkenes given their names. If you can't do that, get it sorted out before you continue!) a) ethene and hydrogen bromide b) but-2-ene and hydrogen chloride c) but-1-ene and hydrogen chloride d) propene and hydrogen iodide e) 2-methylbut-2-ene and hydrogen iodide f) but-1-ene and hydrogen bromide where everything is pure g) but-1-ene and hydrogen bromide in the presence of oxygen or organic peroxides 3. a) How does the rate of the reaction change as you go along the series HF – HCl – HBr – HI? b) Briefly explain the trend you have given in part (a). c) How does the rate of reaction change as you go from ethene to propene to 2-methylbut-2-ene? d) Alkyl groups (like methyl and ethyl groups) have a tendency to “push” electrons away from themselves towards the double bond. (i) How does this help to explain the way the attractiveness of the double bond varies from ethene to propene to 2-methylbut-2-ene? (ii) The mechanism for the reactions involves the formation of intermediate ions with the positive charge on a carbon atom (carbocations). The intermediate carbocations in these cases would be + + + CH CH CH CHCH CH CCH CH 3 2 3 3 3 2 3 CH3 Why does this help to explain the variation in reactivity that you should have given in part (c)? www.chemguide.co.uk. -
Preparing to Manufacture Hydrogen Peroxide
PREPARING TO MANUFACTURE HYDROGEN PEROXIDE Part of the Hydrogen Peroxide Propulsion Guide The early laboratory preparation of hydrogen peroxide was based on the technique that Thenard used during the initial preparation of hydrogen peroxide. In this technique, barium nitrate, purified by recrystallization, was decomposed by heating in air in a porcelain retort. The resulting oxide was further oxidized by heating in a stream of oxygen to a dull red heat. The barium peroxide which formed was then dampened, ground, and dissolved in hydrochloric acid (nitric acid was used in Thenard’s initial experiments). A slight excess of sulfuric acid was then added to precipitate barium sulfate and regenerate hydrochloric acid. The procedure of barium peroxide solution and sulfate precipitation was repeated several times in the same solution to increase the peroxide concentration (concentrations of up to 33 percent by weight hydrogen peroxide could be achieved in this manner). The concentrated solution containing water, hydrogen peroxide, and hydrochloric acid, along with accumulated impurities, was cooled with ice and saturated with barium peroxide; iron and manganese impurities in the solution were then precipitated out as phosphates. The hydrochloric acid was removed by the addition of silver sulfate and the sulfate ion was removed by the subsequent addition of barium oxide. Further concentration was accomplished by vacuum distillation until “no further density increase occurs.” Thenard reported that 100 w/o hydrogen peroxide (on the basis of density data and the measurement of the volume of oxygen released) could be obtained by this technique. The first record of commercial production of hydrogen peroxide appeared in the 1865 to 1875 period. -
Ammonia in Drinking-Water
WHO/SDE/WSH/03.04/01 English only Ammonia in Drinking-water Background document for development of WHO Guidelines for Drinking-water Quality _______________________ Originally published in Guidelines for drinking-water quality, 2nd ed. Vol. 2. Health criteria and other supporting information. World Health Organization, Geneva, 1996. © World Health Organization 2003 All rights reserved. Publications of the World Health Organization can be obtained from Marketing and Dissemination, World Health Organization, 20 Avenue Appia, 1211 Geneva 27, Switzerland (tel: +41 22 791 2476; fax: +41 22 791 4857; email: [email protected]). Requests for permission to reproduce or translate WHO publications – whether for sale or for noncommercial distribution – should be addressed to Publications, at the above address (fax: +41 22 791 4806; email: [email protected]). The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The World Health Organization does not warrant that the information contained in this publication is complete and correct and shall not be liable for any damages incurred as a result of its use. -
Chlorine and Hydrogen Chloride
This report contains the collective views of an nternational group of experts and does not xcessarily represent the decisions or the stated 1 icy of the United Nations Environment Pro- '€mme, the International Labour Organisation, or the World Health Organization. Environmental Health Criteria 21 CHLORINE AND HYDROGEN CHLORIDE 'ublished under the joint sponsorship of Ic United Nations Environment Programme. the International Labour Organisation, and the World Health Organization / \r4 ( o 4 UI o 1 o 'T F- World Health Organization kz Geneva, 1982 The International Programme on Chemical Safety (IPCS) is a joint ven- ture of the United Nations Environment Programme. the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the environment. Supporting activities include the development of epidemiological, experi- mental laboratory, and risk assessment methods that could produce interna- tionally comparable results, and the development of manpower in the field of toxicology. Other relevant activities carried out by the IPCS include the development of know-how for coping with chemical accidents, coordination of laboratory testing and epidemiological studies, and promotion of research on the mechanisms of the biological action of chemicals. ISBN 92 4 154081 8 World Health Organization 1982 Publications of the World Health Organization enjoy copyright protec- tion in accordance with the provisions of Protocol 2 of the Universal Copy- right Convention. For rights of reproduction or translation of WHO publica- tions, in part or in loto, application should be made to the Office of Publica- tions, World Health Organization, Geneva. Switzerland. The World Health Organization welcomes such applications. -
Method for Removing Impurities from Anhydrous Hydrogen Chloride
Europaisches Patentamt 0 380 014 J European Patent Office (iO Publication number: A1 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 90101184.1 (?) int.ci.5:C01B 7/07 @ Date of filing: 22.01.90 © Priority: 27.01.89 US 303513 © Applicant: THE DOW CHEMICAL COMPANY P.O. Box 1967 © Date of publication of application: Midland, Michigan 48641 -1967(US) 01.08.90 Bulletin 90/31 © Inventor: Repman, Josef F. © Designated Contracting States: 31 Wagon Lane Loop BE DE ES FR GB IT NL Angelton, Texas 7751 5(US) Inventor: Morris, Thomas E. 324 Linden Lane Lake Jackson, Texas 77566(US) Inventor: Hill, Thomas F. 128 Lily Lake Jackson, Texas 77566(US) Representative: Sternagel, Hans-Gunther, Dr. etal Patentanwalte Dr. Michael Hann Dr. H.-G. Sternagel Sander Aue 30 D-5060 Bergisch Gladbach 2(DE) © Method for removing impurities from anhydrous hydrogen chloride. © A method to purify impure gaseous hydrogen chloride containing unsaturated chlorinated hydrocarbons in an amount less than that necessary to inhibit purification comprising exposing the impure hydrogen chloride to an ultraviolet light source in the presence of gaseous chlorine for a sufficient time for the gaseous chlorine to react with organic impurities in the hydrogen chloride to form heavier organic compounds and thereafter separating the heavier compounds from the hydrogen chloride. < O 00 CO a. LU Xerox Copy Centre EP 0 380 014 A1 METHOD FOR REMOVING IMPURITIES FROM ANHYDROUS HYDROGEN CHLORIDE This invention pertains to hydrogen chloride and more in particular to a method to remove impurities from anhydrous hydrogen chloride. Hydrogen chloride is produced as a byproduct in many chemical processes. -
Reactions of Alkenes and Alkynes
05 Reactions of Alkenes and Alkynes Polyethylene is the most widely used plastic, making up items such as packing foam, plastic bottles, and plastic utensils (top: © Jon Larson/iStockphoto; middle: GNL Media/Digital Vision/Getty Images, Inc.; bottom: © Lakhesis/iStockphoto). Inset: A model of ethylene. KEY QUESTIONS 5.1 What Are the Characteristic Reactions of Alkenes? 5.8 How Can Alkynes Be Reduced to Alkenes and 5.2 What Is a Reaction Mechanism? Alkanes? 5.3 What Are the Mechanisms of Electrophilic Additions HOW TO to Alkenes? 5.1 How to Draw Mechanisms 5.4 What Are Carbocation Rearrangements? 5.5 What Is Hydroboration–Oxidation of an Alkene? CHEMICAL CONNECTIONS 5.6 How Can an Alkene Be Reduced to an Alkane? 5A Catalytic Cracking and the Importance of Alkenes 5.7 How Can an Acetylide Anion Be Used to Create a New Carbon–Carbon Bond? IN THIS CHAPTER, we begin our systematic study of organic reactions and their mecha- nisms. Reaction mechanisms are step-by-step descriptions of how reactions proceed and are one of the most important unifying concepts in organic chemistry. We use the reactions of alkenes as the vehicle to introduce this concept. 129 130 CHAPTER 5 Reactions of Alkenes and Alkynes 5.1 What Are the Characteristic Reactions of Alkenes? The most characteristic reaction of alkenes is addition to the carbon–carbon double bond in such a way that the pi bond is broken and, in its place, sigma bonds are formed to two new atoms or groups of atoms. Several examples of reactions at the carbon–carbon double bond are shown in Table 5.1, along with the descriptive name(s) associated with each. -
Disinfectant Concentrations, Contact Times, and Use Settings for Products Effective Against Coronavirus SARS-Cov-2
Disinfectant Concentrations, Contact Times, and Use Settings for Products Effective against Coronavirus SARS-CoV-2 This table provides disinfectant concentrations, contact times, and use settings for EPA's List N, which covers antimicrobial products effective against SARS-CoV-2 but does not specify disinfectant concentrations. Our list will help you ensure you're using an effective disinfectant at a sufficient concentration and contact time to kill SARS-CoV-2 in appropriate settings. This table accompanies ECRI's article "Disinfectant Concentrations, Contact Times, and Use Settings for EPA's List of Products Effective against Coronavirus SARS-CoV-2, the Cause of COVID-19," available at http://ly.ecri.org/epalist. It was last updated on June 2, 2021. The Last Updated column, below, refers to the date when ECRI last reviewed EPA’s information for the product listed. EPA Reg. Primary Registered Active Disinfectant Disinfectant Disinfectant Healthcare Institutional Home Last No. Product Name Concentration Contact Time Use Use Use Updated (by weight) (min) 10190-14 Penetone XF-7117 n-Alkyl (50% C14, 40% C12, 4.34% 10 No Yes No November 10% C16) dimethyl benzyl 2020 ammonium chloride Octyl decyl dimethyl 3.25% ammonium chloride Didecyl dimethyl ammonium 1.63% chloride Dioctyl dimethyl ammonium 1.63% chloride 10324-105 Maquat 128 PD n-Alkyl (60% C14, 30% C16, 4.50% 10 Yes Yes Yes November 5% C12, 5% C18) dimethyl 2020 benzyl ammonium chloride n-Alkyl (68% C12, 32% C14) 4.50% dimethyl ethylbenzyl ammonium chloride 10324-108 Maquat 256-MN n-Alkyl -
Effects of Post-Manufacture Board Treatments on Formaldegyde Emission
Effects of post-manufacture board treatments on formaldehyde emission: a literature review (1960-1984) George E. Myers treatments. At present I suggest that impregnation of Abstract boards with aqueous solutions (Method 1) is likely to be This paper reviews the literature dealing with the the most reliable because it should permit the use of a many post-manufacture board treatments used to re large scavenger excess and also allow neutralization of duce formaldehyde emission from urea-formaldehyde board acidity to reduce resin hydrolysis. bonded boards. Such treatments have almost solely used one or more of five chemical or physical principles: 1) formaldehyde reaction with NH3, 2) formaldehyde reaction with oxygenated sulfur compounds, 3) formal This is the fifth in a planned series of six critical dehyde reaction with organic -NH functionality, 4) pH reviews of the literature on different aspects of the adjustment, and 5) physical barrier. I have categorized problem of formaldehyde emission from adhesively the available reports according to four primary board bonded wood products. The series was initiated at the treatment methods that use the five principles in differ Forest Products Laboratory, Madison, Wis., in response ent ways. The four primary treatment methods are: to a need expressed by industry representatives for an 1. Application of scavengers as solids or aqueous independent evaluation and summation of data from solutions. Ammonium bicarbonate and carbonate have diverse sources. The six aspects being reviewed concern been used as solid powders, while the solutions involved the effects of formaldehyde-to-urea mole ratio (F/U) a variety of ammonium salts, ammonium and alkali (48), ventilation rate and loading (49), temperature and metal salts with sulfur-containing anions, and urea and humidity (51), separate additions to wood furnish or other compounds having -NH functionality; veneer (52), post-manufacture treatments of boards, 2. -
Ammonium Acetate
Right to Know Hazardous Substance Fact Sheet Common Name: AMMONIUM ACETATE Synonyms: None CAS Number: 631-61-8 Chemical Name: Acetic Acid, Ammonium Salt RTK Substance Number: 0085 Date: April 2002 Revision: March 2011 DOT Number: UN 9079 Description and Use EMERGENCY RESPONDERS >>>> SEE LAST PAGE Ammonium Acetate is a white, crystalline (sand-like) solid Hazard Summary with a slight vinegar-like odor. It is used in chemical analysis, Hazard Rating NJDOH NFPA textile dyeing, and preserving meats. HEALTH 2 - FLAMMABILITY 1 - REACTIVITY 0 - POISONOUS GASES ARE PRODUCED IN FIRE Reasons for Citation f Ammonium Acetate is on the Right to Know Hazardous Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; 4=severe Substance List because it is cited by DOT and IRIS. f Ammonium Acetate can affect you when inhaled. f Contact can irritate and burn the skin and eyes. f Inhaling Ammonium Acetate can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. SEE GLOSSARY ON PAGE 5. FIRST AID Eye Contact Workplace Exposure Limits f Immediately flush with large amounts of water for at least 30 No occupational exposure limits have been established for minutes, lifting upper and lower lids. Remove contact Ammonium Acetate. However, it may pose a health risk. lenses, if worn, while flushing. Seek medical attention. Always follow safe work practices. Skin Contact f Quickly remove contaminated clothing. Immediately wash contaminated skin with large amounts of water. Inhalation f Remove the person from exposure. f Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. -
H Atom Attack on Propene Claudette M
ARTICLE pubs.acs.org/JPCA H Atom Attack on Propene Claudette M. Rosado-Reyes,* Jeffrey A. Manion, and Wing Tsang National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, United States bS Supporting Information d ABSTRACT: The reaction of propene (CH3CH CH2) with hydrogen atoms has been investigated in a heated single-pulsed shock tube at temperatures between 902 and 1200 K and pressures of 1.5À3.4 bar. Stable products from H atom addition and H abstraction have been identified and quantified by gas chromatography/flame ionization/mass spectrometry. The reaction for the H addition channel involving methyl displacement from propene has been determined relative to methyl displacement from 1,3,5-trimethylbenzene þ f d þ (135TMB), leading to a reaction rate, k(H propene) H2C CH2 Â 13 À 3 CH3) = 4.8 10 exp( 2081/T)cm/(mol s). The rate constant for the abstraction of the allylic hydrogen atom is determined to be k(H þ propene f d þ Â 13 À 3 CH2CH CH2 H2) = 6.4 10 exp( 4168/T)cm /(mol s). The reaction of H þ propene has also been directly studied relative to the reaction of H þ propyne, and the relationship is found to be log[k(H þ propyne f acetylene þ þ f þ À ( þ CH3)/k(H propene ethylene CH3)]=( 0.461 0.041)(1000/T) (0.44 ( 0.04). The results showed that the rate constant for the methyl displacement reaction with propene is a factor of 1.05 ( 0.1 larger than that for propyne near 1000 K.