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and Respiration can probably balance out the gases necessary for even in a small, sealed glass container floating in outer *.

*as long as it is kept from freezing. are falible. ^l

Biosphere 2

z 2 was our attempt to design an completely independent of and live in it. z It failed because the people ran low on breathable . z This proves that Biosphere 1 (Earth) is a complex that we cannot yet duplicate perfectly. z Let's attempt to understand why. First some background info: Chemystery.

Elements of Life: (Earth, Air, ) z The greeks believed all H - is composed of 4 O - Oxygen “Organic” C - elements form elements: earth, air, N - covalent bonds. P - water and fire. S - Ca - z They weren't too far off, Na - Sodium but the first three K - Charged Cl – Chloride or salts elements are composed Mg – of ~92 chemical Fe - and other trace elements... elements from stardust.

z The fire element for life: (Fire) Sunshine measured in joules or calories. represents the energy contained in the bonds between the elements. have two different strategies to deal with an incomplete set of .

z Atoms may give or take an or two and become positive (electron poor) or negative (electron rich) ions.

z Atoms may share electrons in covalent bonds.

z Polar bonds are covalent bonds that have some characteristics of ionic bonds.

z Biochemicals are composed of covalent bonds. What is a Calorie?

z 1000 calories = 1 Calorie (kilocalorie)

z 1 calorie = 4.18 joules

z A 100 uses 100 joules per , or ___ Calories per second.

? Calories/ second ? How long does it take the light bulb to burn a Calorie (kcal)? Chemical reactions may store or release energy.

z Covalent bonds form when two atoms have a lower energy state when they are together, rather when they are apart.

z Each type of covalent bond stores a different amount of energy.

z The process by which covalent bonds form and break is called a .

z Reactants ---> Products

z Bonds broken ----> Bonds formed

z If there is energy released during a chemical reaction, it is because the bonds formed have a lower energy state than the bonds broken. Respiration and Photosynthesis are the basic chemical reactions of life.

Photosynthesis: light from the +

CO2 + H2O ----> CH2O + O2

Respiration: CH2O + O2 ----> CO2 + H2O + cellular energy and/or heat

z During photosynthesis store energy from the sun in the bonds of .

z Energy stored in the chemical bonds of carbohydrates is released during respiration and used to do work in living cells. Q: How much energy is released during respiration?

Respiration: CH2O + O2 ----> CO2 + H2O + cellular energy and/or heat C-H bond: 99 kcal / mole C=O bond: 180 kcal/mole O=O bond: 119 kcal/mole O-H bond: 111 kcal/mole

Breaking bonds requires energy, forming bonds releases energy.

1 mole = 6.02 x 1023 atoms or molecules. 1 mole of hydrogen with an atomic of one is equal to one gram. Q: How long could 1 mole of CH2O (about 30 grams of , or one soft- drink) power our 100 watt light bulb? Plants are made mostly of air!

z Plants create carbohydrates (sugar, ) from and water.

z Carbon dioxide is a CH O and O 2 2 - in air. CO2, H2O, NO3 , 3- PO4 , minerals, And other z This gas is a for plants.

z Other organic elements are also nutrients for plants. Nutrients feed plants which manufacture the building blocks of life.

Nutrient Carbon in dioxide gas water and in water and from air soil

(CO2) (NO3-) (PO43-) Cellular Carbohydrates DNA, RNA

“machine” (CH2O) and fats (CnH2n + 2) Cellular Energy , “blueprint” storage transport, for making locomotion proteins Plants and recycle each others waste products in the presence of sunshine. z Animals respire.

z Plants photosynthesize (and respire too).

z Sunshine is required to fuel the plants that feed Photosynthesis the animals.

z Animals inhale oxygen which plants release, and plants take up Respiration carbon dioxide which animals exhale. are living networks in which the only waste product is low-grade heat.

z Nutrients are constantly recycled as long as there is energy from sunshine.

z When there is an accumulation of wastes, an will invade or evolve to use the excess waste. Ecosystems are living networks in which the only waste product is low-grade heat.

z Nutrients are constantly recycled as long as there is energy from sunshine.

z When there is an accumulation of wastes, an organism will invade or evolve to use the excess waste. The first on Earth was eventually used by other .

z 1 billion years ago, the Earth was anaerobic (had no oxygen

gas - O2).

z Carbohydrates were created with a primitive photosynthesis that did not involve oxygen, and anaerobic life used to get energy from .

z (- ) evolved to produce oxygen, and poisoned anaerobic life.

z Organisms eventually evolved to use oxygen (aerobic life). Respiration evolved because it is very energetically favorable.

z A fire needs three things: heat (initial energy input), fuel and oxygen.

z Respiration is very similar to combustion.

z All that must happen is to harness the “fire” and use it to drive mechanisms in the body and cells. Photosynthesis evolved once, it has been copied many, many .

z All plants contain , an which harvests .

z Chloroplasts store energy from sunshine in the chemical bonds of carbohydrates (sugars).

z Cyanobacteria are the ~1000X mag. ancestors of all chloroplasts.

z Basically, cyanobacterial cells are living within all cells! This is an example of . Respiration also evolved sparingly.

z Respiration evolved to use oxygen.

z Mitochondria are in animals (and plants too) that allow them to respire carbohydrates and gain cellular energy. picture of mitochondria z Mitochondria are also called the Mitochondria give energy to the “powerhouse” of the . ~1000x cell in exchange for protection magnification z Mitochondria are descended from a and carbohydrates. bacterium that evolved to use oxygen very efficiently.

z Eukaryotic Cells provide protection and to the mitochondria, while the mitochondria provide cellular energy to the eukaryotic cells.

z They can afford this arrangement because there is SO much energy in oxygen vs. fermentation. Eventually respiration balanced photosynthesis.

z Equilibrium is the state in which all processes are in balance and there is no accumulation of wastes.

z Oxygen is maintained at a fairly O2 21 % stable 21% in our , at higher , combustion proceeds more quickly and consumes oxygen. This is an

CO2 example of a negative – Levels decreased a process that acts to cancel its (however they are Hypothetical concentrations own trigger. increasing currently)

Time (after cyanobacteria evolved) Gaia.

z The earth is a which sustains the conditions necessary for life.

z James Lovelock pioneered the idea in 1970, and growing evidence supports his ideas. Negative and Positive can influence Earth’s in important ways. Initial addition of carbon dioxide. Extra heat could cause more evaporation. The added water vapor could trap more heat. Or could cause the sun’s rays to be reflected and cool the surface? What one is the positive and which one the here? Can we balance photosynthesis and respiration in a sealed glass jar?

z You will get your very own ecosystem in a glass jar.

z How long can it survive on its own?

z What might prevent it from lasting forever? We can't yet duplicate Gaia.

z So let’s treat her well…