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Safety Data Sheet SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of the substance Barium titanate (BaTiO3) Identification number 056-002-00-7 (Index number) Registration number - Document number 1PL Synonyms BARIUM TITANATE * Barium titanium oxide (BaTiO3) * Barium(IV) titanate Materion Code 1PL Issue date 01-August-2019 1.3. Details of the supplier of the safety data sheet Supplier Company name Materion Advanced Chemicals Inc. Address 407 N. 13th Street 1316 W. St. Paul Avenue Milwaukee, WI 53233 United States Division Milwaukee Telephone 414.212.0257 e-mail [email protected] Contact person Laura Hamilton 1.4. Emergency telephone number Version number 01 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Not available. Uses advised against None known. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The product has been assessed and/or tested for its physical, health and environmental hazards following the regulations ABNT NBR 14725-4: (Safety data sheet for chemicals (SDS)) (Aug. 26, 2009) The substance has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. According to GHS criteria. Classification according to Regulation (EC) No 1272/2008 as amended Hazard summary CAUTION Harmful if inhaled. Harmful if absorbed through skin. Harmful by inhalation and if swallowed. 2.2. Label elements Label according to Regulation (EC) No. 1272/2008 as amended Contains: Barium titanate Hazard pictograms Signal word Warning Hazard statements H302 Harmful if swallowed. H302 + H332 Harmful if swallowed or if inhaled Precautionary statements Prevention P261 Avoid breathing dust/fume. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. Material name: Barium titanate (BaTiO3) SDS EU 1PL Version #: 01 Issue date: 01-August-2019 1 / 8 P271 Use only outdoors or in a well-ventilated area. Response P301 + P312 If swallowed: Call a poison centre/doctor if you feel unwell. P304 + P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. P311 Call a poison centre/doctor. P330 Rinse mouth. Storage Not available. Disposal P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Supplemental label None. information 2.3. Other hazards The Safety Information Sheet Chemicals of hazardous chemical can be obtained through phone, email or on the company website. SECTION 3: Composition/information on ingredients 3.1. Substances General information Chemical name % CAS-No. / EC REACH Registration No. Index No. Notes No. Barium titanate 100 - 056-002-00-7 Classification: Acute Tox. 4;H302 List of abbreviations and symbols that may be used above CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. M: M-factor vPvB: very persistent and very bioaccumulative substance. PBT: persistent, bioaccumulative and toxic substance. #: This substance has been assigned Community workplace exposure limit(s). Composition comments The full text for all R- and H-phrases is displayed in section 16. SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. 4.1. Description of first aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician or poison control centre immediately. Skin contact Remove and isolate contaminated clothing and shoes. Wash the skin immediately with soap and water. Immediately flush skin with plenty of water. Get medical attention immediately. Wash clothing separately before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Get medical attention if irritation develops and persists. Ingestion IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. If swallowed, seek medical advice immediately and show this container or label. IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel unwell. Rinse mouth. Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 4.2. Most important Not available. symptoms and effects, both acute and delayed 4.3. Indication of any Provide general supportive measures and treat symptomatically. Treat symptomatically. In case of immediate medical attention shortness of breath, give oxygen. Oxygen, if needed. Keep victim warm. Keep victim under and special treatment observation. Symptoms may be delayed. needed Material name: Barium titanate (BaTiO3) SDS EU 1PL Version #: 01 Issue date: 01-August-2019 2 / 8 SECTION 5: Firefighting measures General fire hazards No unusual fire or explosion hazards noted. 5.1. Extinguishing media Suitable extinguishing Water. media Unsuitable extinguishing None known. media 5.2. Special hazards arising Not available. from the substance or mixture 5.3. Advice for firefighters Special protective Wear suitable protective equipment. equipment for firefighters Special firefighting In the event of fire, cool tanks with water spray. procedures Specific methods Cool containers exposed to flames with water until well after the fire is out. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Local authorities should be advised if significant spillages cannot be contained. Keep unnecessary personnel personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Fully encapsulating, vapour protective clothing should be worn for spills and leaks with no fire. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. For emergency Keep unnecessary personnel away. responders 6.2. Environmental Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or precautions onto the ground. 6.3. Methods and material for Stop the flow of material, if this is without risk. Dike far ahead of spill for later disposal. Prevent containment and cleaning up entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. 6.4. Reference to other Not available. sections SECTION 7: Handling and storage 7.1. Precautions for safe Minimise dust generation and accumulation. Do not taste or swallow. Avoid breathing dust. Avoid handling contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Use only outdoors or in a well-ventilated area. Wear personal protective equipment. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Handle and open container with care. 7.2. Conditions for safe CAUTION storage, including any Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in a incompatibilities well-ventilated place. Keep out of the reach of children. Use care in handling/storage. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoring Follow standard monitoring procedures. procedures Derived no effect levels Not available. (DNELs) Predicted no effect Not available. concentrations (PNECs) 8.2. Exposure controls Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should controls be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Material name: Barium titanate (BaTiO3) SDS EU 1PL Version #: 01 Issue date: 01-August-2019 3 / 8 Individual protection measures, such as personal protective equipment General information Not available. Eye/face protection Chemical goggles are recommended. Face-shield. Eye wash fountain is recommended. Skin protection - Hand protection Wear protective gloves. Not normally needed. - Other Wear protective gloves. Wear chemical protective equipment that is specifically recommended by
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