Camille Dreyfus Teacher-Scholar Awards Program
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The Selective Synthesis of Aromatics and Furans From
THE SELECTIVE SYNTHESIS OF AROMATICS AND FURANS FROM BIOMASS-DERIVED COMPOUNDS by Eyas Mahmoud A dissertation submitted to the Faculty of the University of Delaware in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Chemical Engineering Summer 2016 © 2016 Eyas Mahmoud All Rights Reserved THE SELECTIVE SYNTHESIS OF AROMATICS AND FURANS FROM BIOMASS-DERIVED COMPOUNDS by Eyas Mahmoud Approved: __________________________________________________________ Abraham M. Lenhoff, Ph.D. Chair of the Department of Chemical and Biomolecular Engineering Approved: __________________________________________________________ Babatunde A. Ogunnaike, Ph.D. Dean of the College of Engineering Approved: __________________________________________________________ Ann L. Ardis, Ph.D. Senior Vice Provost for Graduate and Professional Education I certify that I have read this dissertation and that in my opinion it meets the academic and professional standard required by the University as a dissertation for the degree of Doctor of Philosophy. Signed: __________________________________________________________ Raul F. Lobo, Ph.D. Professor in charge of dissertation I certify that I have read this dissertation and that in my opinion it meets the academic and professional standard required by the University as a dissertation for the degree of Doctor of Philosophy. Signed: __________________________________________________________ Dionisios G. Vlachos, Ph.D. Member of dissertation committee I certify that I have read this dissertation and that in my opinion it meets the academic and professional standard required by the University as a dissertation for the degree of Doctor of Philosophy. Signed: __________________________________________________________ Donald A. Watson, Ph.D. Member of dissertation committee I certify that I have read this dissertation and that in my opinion it meets the academic and professional standard required by the University as a dissertation for the degree of Doctor of Philosophy. -
Curriculum Vitae Kazimer Lennon Skubi
CURRICULUM VITAE KAZIMER LENNON SKUBI Skidmore College Department of Chemistry Office: (518) 580-5147 815 North Broadway Email: [email protected] Saratoga Springs, NY 12866 ORCID: 0000-0002-9689-1842 EDUCATION AND TRAINING Yale University 2017–2020 NIH F32 Postdoctoral Fellow (Advisor: Patrick Holland) University of Wisconsin–Madison 2011–2017 Ph.D. in Chemistry (Advisor: Tehshik Yoon) Thesis Title: “New Strategies for Catalytic Stereocontrol in Photochemical Synthesis” Carleton College 2007–2011 B.A. in Chemistry, summa cum laude ACS-Certified Degree, Distinction in Major, Distinction in Senior Integrative Exercise PROFESSIONAL EXPERIENCE Visiting Assistant Professor of Chemistry, Skidmore College, Saratoga Springs, NY 2020–present NIH F32 Postdoctoral Fellow, Yale University, New Haven, CT 2018–2020 Postdoctoral Associate, Yale University, New Haven, CT 2017–2018 Graduate Student Research Assistant, University of Wisconsin–Madison, Madison, WI 2015–2017 Graduate Student Teaching Assistant, University of Wisconsin–Madison, Madison, WI 2011–2015 TEACHING EXPERIENCE Skidmore College CH 125: Principles of Chemistry + Lab Fall 2020 University of Wisconsin–Madison (Teaching Assistant) CHEM 344: Organic Chemistry Laboratory Fall 2011, Spring 2012 CHEM 345: Organic Chemistry II Spring 2014 CHEM 346: Intermediate Organic Chemistry Laboratory Fall 2013, Fall 2014, Fall 2015 CHEM 636: Introduction to NMR Fall 2012, Spring 2013 CHEM 637: Advanced Methods in NMR Summer 2013 Carleton College (Teaching Assistant) CHEM 123: Introductory Chemistry Fall 2009 CHEM 233: Organic Chemistry I Winter 2010, Fall 2010, Winter 2011 CHEM 234: Organic Chemistry II Spring 2010, Spring 2011 MENTORING EXPERIENCE Graduate Student Mentor, Holland Research Group 2017–2020 Fundamentals of Inclusive Teaching (Yale Center for Teaching and Learning) Fall 2018 Teaching in Science and Engineering: The College Classroom (UW–Madison Dept. -
Synthesis, Catalysis, and Chemistry
University of Massachusetts Amherst ScholarWorks@UMass Amherst Doctoral Dissertations Dissertations and Theses July 2017 Nanoporous Solid Acid Materials for Biomass Conversion into Value-Added Chemicals: Synthesis, Catalysis, and Chemistry Hong Je Cho University of Massachusetts Amherst Follow this and additional works at: https://scholarworks.umass.edu/dissertations_2 Part of the Catalysis and Reaction Engineering Commons Recommended Citation Cho, Hong Je, "Nanoporous Solid Acid Materials for Biomass Conversion into Value-Added Chemicals: Synthesis, Catalysis, and Chemistry" (2017). Doctoral Dissertations. 952. https://doi.org/10.7275/9584937.0 https://scholarworks.umass.edu/dissertations_2/952 This Open Access Dissertation is brought to you for free and open access by the Dissertations and Theses at ScholarWorks@UMass Amherst. It has been accepted for inclusion in Doctoral Dissertations by an authorized administrator of ScholarWorks@UMass Amherst. For more information, please contact [email protected]. NANOPOROUS SOLID ACID MATERIALS FOR BIOMASS CONVERSION INTO VALUE-ADDED CHEMICALS: SYNTHESIS, CATALYSIS, AND CHEMISTRY A Dissertation Presented by HONG JE CHO Submitted to the Graduate School of the University of Massachusetts Amherst in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY May 2017 Chemical Engineering © Copyright by Hong Je Cho 2017 All Rights Reserved NANOPOROUS SOLID ACID MATERIALS FOR BIOMASS CONVERSION INTO VALUE-ADDED CHEMICALS: SYNTHESIS, CATALYSIS, AND CHEMISTRY A Dissertation Presented by HONG JE CHO Approve as to style and content by: ______________________________________ Wei Fan, Chair ______________________________________ Friederike Jentoft, Member ______________________________________ Ashwin Ramasubramaniam, Member ___________________________________ John Klier, Department Head Department of Chemical Engineering ACKNOWLEDGEMENTS This work was supported by Catalysis Center for Energy Innovation (funded by the US Dept. -
Catalysis and Reaction Engineering Division 2020
Catalysis and Reaction Engineering Division 2020 Held at the 2020 AIChE Annual Meeting Online 16 – 20 November 2020 Volume 1 of 2 ISBN: 978-1-7138-2313-1 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2020) by AIChE All rights reserved. Printed with permission by Curran Associates, Inc. (2021) For permission requests, please contact AIChE at the address below. AIChE 120 Wall Street, FL 23 New York, NY 10005-4020 Phone: (800) 242-4363 Fax: (203) 775-5177 www.aiche.org Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2633 Email: [email protected] Web: www.proceedings.com TABLE OF CONTENTS VOLUME 1 (19A) CATALYTIC REACTION PATHWAYS AND PROCESS SYNTHESIS FOR BIOMASS CONVERSION TO HIGH-VALUE CHEMICALS FOR ORGANIC DYE AND POLYMER APPLICATIONS .................................................................................................................................................. 1 Hochan Chang, Ishan Bajaj, George W. Huber, Christos T. Maravelias, James A. Dumesic (19B) SUPERACID POLYMER CATALYSTS FOR HYDROXYMETHYLFURFURAL PRODUCTION .................................................................................................................................................... 2 Ibeh S. Omodolor, Sarah A. Walz, Subhash Kalidindi, Vimantha Bamunuarachchi, Ravikumar Gogar, -
Basic Research Needs for Catalysis Science
Basic Research Needs for Catalysis Science Report of the Basic Energy Sciences Workshop on Basic Research Needs for Catalysis Science to Transform Energy Technologies May 8–10, 2017 Image courtesy of Argonne National Laboratory. DISCLAIMER This report was prepared as an account of a workshop sponsored by the U.S. Department of Energy. Neither the United States Government nor any agency thereof, nor any of their employees or officers, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of document authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. Copyrights to portions of this report (including graphics) are reserved by original copyright holders or their assignees, and are used by the Government’s license and by permission. Requests to use any images must be made to the provider identified in the image credits. This report is available in pdf format at https://science.energy.gov/bes/community-resources/reports/ REPORT OF THE BASIC RESEARCH NEEDS WORKSHOP FOR CATALYSIS SCIENCE Basic Research Needs for Catalysis Science TO TRANSFORM ENERGY TECHNOLOGIES Report from the U.S. Department of Energy, Office of Basic Energy Sciences Workshop May 8–10, 2017, in Gaithersburg, Maryland CHAIR: ASSOCIATE CHAIRS: Carl A. -
Iron-Catalyzed Amino-Oxygenation and Aminofluorination of Olefins
Georgia State University ScholarWorks @ Georgia State University Chemistry Theses Department of Chemistry 8-11-2015 Iron-Catalyzed Amino-Oxygenation and Aminofluorination of Olefins Jeffrey Sears [email protected] Follow this and additional works at: https://scholarworks.gsu.edu/chemistry_theses Recommended Citation Sears, Jeffrey, "Iron-Catalyzed Amino-Oxygenation and Aminofluorination of Olefins." Thesis, Georgia State University, 2015. https://scholarworks.gsu.edu/chemistry_theses/77 This Thesis is brought to you for free and open access by the Department of Chemistry at ScholarWorks @ Georgia State University. It has been accepted for inclusion in Chemistry Theses by an authorized administrator of ScholarWorks @ Georgia State University. For more information, please contact [email protected]. IRON-CATALYZED AMINO-OXYGENATION AND AMINOFLUORINATION OF OLEFINS by JEFFREY D. SEARS Under the Direction of Hao Xu, PhD ABSTRACT The first chapter of the thesis describes an iron(II)-catalyzed intermolecular amino- oxygenation of alkenes. This amino-oxygenation method is found to be compatible with a broad range of synthetically valuable alkenes and affords the corresponding 1,2-amino alcohols with excellent regio- and diastereoselectivity. Additionally, practical synthetic procedures for the amino-oxygenation of styrene, a fully functionalized glycal, and indene are described. The second chapter of the thesis describes a regioselective and diastereoselective iron(II)-catalyzed intermolecular aminofluorination of alkenes using nucleophilic fluorinating reagents. This method affords new vicinal amino fluorides that were previously difficult to prepare. In both the amino-oxygenation and aminofluorination reactions, bench-stable hydroxylamine derivatives functioned as both the oxidant and amination reagents. Preliminary mechanistic studies suggested that an iron-nitrenoid is a possible reactive intermediate on both reaction pathways. -
Read Laura's Thesis Chapter
Communicating Research to the General Public At the March 5, 2010 UW-Madison Chemistry Department Colloquium, Prof. Bassam Z. Shakhashiri, the director of the Wisconsin Initiative for Science Literacy (WISL), encouraged all UW-Madison chemistry Ph.D. candidates to include a chapter in their Ph.D. thesis communicating their research to non-specialists. The goal is to explain the candidate’s scholarly research and its significance to a wider audience that includes family members, friends, civic groups, newspaper reporters, program officers at appropriate funding agencies, state legislators, and mem- bers of the U.S. Congress. Over 20 Ph.D. degree recipients have successfully completed their theses and included such a chapter. WISL encourages the inclusion of such chapters in all Ph.D. theses everywhere through the cooperation of Ph.D. candidates and their mentors. WISL is now offering additional awards of $250 for UW-Madison chemistry Ph.D. candidates. The dual mission of the Wisconsin Initiative for Science Literacy is to promote literacy in science, mathematics and technology among the general public and to attract future generations to careers in research, teaching and public service. UW-Madison Department of Chemistry 1101 University Avenue Madison, WI 53706-1396 Contact: Prof. Bassam Z. Shakhashiri [email protected] www.scifun.org May 2014 Controlling the Chemistry of Photogenerated Radicals with Lewis and Brønsted Acid Co-Catalysts By Laura Ruiz Espelt A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy (Chemistry) at the UNIVERSITY OF WISCONSIN!MADISON 2014 Date of final oral examination: 08/06/2014 The dissertation is approved by the following members of the Final Oral Committee: Tehshik Yoon, Professor, Chemistry Clark Landis, Professor, Chemistry Shannon Stahl, Professor, Chemistry Jennifer Schomaker. -
Badger Chemist the Newsletter of the Department of Chemistry at the University of Wisconsin-Madison
Badger Chemist The Newsletter of the Department of Chemistry at the University of Wisconsin-Madison Established 1953, No. 57, 2014 BADGER CHEMIST Ten People, Ten Stories Ever since joining the faculty at the University of Wisconsin-Madison 25 years ago, one of the things that has most impressed me is the astounding variety of science, classes, and other activities that happen in our department each day. If you were to explore the Chemistry Building and talk to 10 people, each one might easily tell you a different story about an exciting new research project, a meaningful class experience, a poster or publication in progress, or a new program for students or the community. With this issue of the Badger CONTENTS Chemist, we aim to give you a taste of this great diversity of teaching, research, and outreach. New Badger Chemists .................................... 2 Whether you have fond memories of learning the ins and outs Alumni News ................................................... 4 of the department’s chemical instruments (page 15), you want to Chemistry News .............................................. 5 find out the latest update on the Chemistry Building Project (page Awards and Honors ....................................... 11 Features ......................................................... 15 6), you’re curious what chemistry majors are learning in the lab Shakhashiri ACS Presidency Reflections ...... 19 these days (page 17), or you want to meet our newest professor New Faculty Profile ...................................... -
Deciphering Biomass Fragmentation Using Millisecond Micro-Reactor Kinetics
Deciphering Biomass Fragmentation using Millisecond Micro-Reactor Kinetics A DISSERTATION SUBMITTED TO THE FACULTY OF UNIVERSITY OF MINNESOTA BY SAURABH MADUSKAR IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Adviser: Paul J. Dauenhauer MAY 2018 © Saurabh Maduskar 2018 Acknowledgements First and foremost, I would like to thank my advisor, Paul Dauenhauer, who guided me throughout my Ph.D. and provided mentorship in research and professional development. His excitement and creativity towards solving challenging problems motivated me to complete the research projects. The work culture in Dauenhauer research group helped me accomplish both professional and personal goals in my graduate life. I would like to thank Dauenhauer group alumni Andrew Teixeria, Christoph Krumm, Alex Paulsen, Luke Williams for their support, mentoring, and guidance during initial years of my PhD. I would also like to thank my current lab mates Kristeen Joseph, Katherine Vinter, Omar Abdelrehman, Greg Fracas, Vineet Mallikal for their continued support and encouragement. I specially thank my batchmates Kristeen and Katie for baring with me throughout the long journey of graduate school. I would like to thank the department of Chemical Engineering and Materials Science, University of Minnesota and the department of Chemical Engineering, University of Massachusetts Amherst for giving me an opportunity to work as a research assistant and graduate student with some of the brightest people I have known. I would like to thank the professors and mentors I have had at both the universities, continually igniting that spark of curiosity, forcing me to work harder. Finally, I would like to thank my family, and friends; without their support, I undoubtedly would not have made it to this point today. -
42 National Organic Chemistry Symposium Table of Contents
42nd National Organic Chemistry Symposium Princeton University Princeton, New Jersey June 5 – 9, 2011 Table of Contents Welcome……………………………………………………………………………….......... 2 Sponsors / Exhibitors…..……………………………………………………………........... 3 DOC Committee Membership / Symposium Organizers………………………….......... 5 Symposium Program (Schedule)……...…………………………………………….......... 9 The Roger Adams Award…………………………………………………………….......... 14 Plenary Speakers………………………………………………………………………........ 15 Lecture Abstracts..…………………………………………………………………….......... 19 DOC Graduate Fellowships……………………………………………………………....... 47 Poster Titles…………………………...……………………………………………….......... 51 General Information..………………………………………………………………….......... 93 Attendees………………………………..……………………………………………........... 101 Notes………..………………………………………………………………………….......... 117 (Cover Photo by Chris Lillja for Princeton University Facilities. Copyright 2010 by the Trustees of Princeton University.) -------42nd National Organic Chemistry Symposium 2011 • Princeton University Welcome to Princeton University On behalf of the Executive Committee of the Division of Organic Chemistry of the American Chemical Society and the Department of Chemistry at Princeton University, we welcome you to the 42nd National Organic Chemistry Symposium. The goal of this biennial event is to present a distinguished roster of speakers that represents the current status of the field of organic chemistry, in terms of breadth and creative advances. The first symposium was held in Rochester NY, in December 1925, under the auspices of -
Frontiers at the Interface of Homogeneous and Heterogeneous Catalysis
FRONTIERS AT THE INTERFACE OF HOMOGENEOUS AND HETEROGENEOUS CATALYSIS Meeting of the Catalysis Science Program Chemical Sciences, Geosciences and Biosciences Division Office of Basic Energy Sciences U.S. Department of Energy Westin Annapolis Annapolis, Maryland June 30 – July 2, 2013 This document was produced under contract number DE-AC05-060R23100 between the U.S. Department of Energy and Oak Ridge Associated Universities. FOREWORD The 2013 Catalysis Science Program Meeting is sponsored by the Division of Chemical Sciences, Geosciences and Biosciences, Office of Basic Energy Sciences (BES), U.S. Department of Energy. It is being held on June 30 through July 2, 2013, at the Westin Annapolis Hotel, Annapolis, Maryland. The purposes of this meeting are to discuss the recent advances in the chemical, physical, and biological bases of catalysis science, to foster exchange of ideas and cooperation among participants, and to discuss the new challenges and opportunities recently emerging in energy technologies. Catalysis activities within BES emphasize fundamental research aimed at initially understanding and finally controlling the chemical conversion of natural and artificial feedstocks. The long-term goal of this research is to discover fundamental principles and produce ever more insightful approaches to predict structure-reactivity behavior. Such knowledge, integrated with advances in chemical and materials synthesis, in situ and operando analytical instrumentation, and chemical kinetics and quantum chemistry methods, will allow the control of chemical reactions along desired pathways. Ultimately, this new knowledge should impact the efficiency of conversion of natural resources into fuels, chemicals, materials, or other forms of energy, while minimizing the impact to the environment. This year’s meeting is focused on three topical areas: (i) the interface of homogeneous and heterogeneous catalysis, (ii) catalysis for biomass or solar energy conversion, and (iii) molecular catalysis, with an emphasis on organic synthesis. -
Demystifying Mass Transfer in Electrolyzers Through Rapid Prototyping with 3D Printed Parallel Plate Cells
Catalysis and Reaction Engineering Division 2019 Held at the 2019 AIChE Annual Meeting Orlando, Florida, USA 10 - 15 November 2019 Volume 1 of 2 ISBN: 978-1-7138-0541-0 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2019) by AIChE All rights reserved. Printed with permission by Curran Associates, Inc. (2020) For permission requests, please contact AIChE at the address below. AIChE 120 Wall Street, FL 23 New York, NY 10005-4020 Phone: (800) 242-4363 Fax: (203) 775-5177 www.aiche.org Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2633 Email: [email protected] Web: www.proceedings.com TABLE OF CONTENTS VOLUME 1 (8A) DEMYSTIFYING MASS TRANSFER IN ELECTROLYZERS THROUGH RAPID PROTOTYPING WITH 3D PRINTED PARALLEL PLATE CELLS ............................................................................1 Stéphane Weusten, Luc Murrer, Mattheus De Groot, John Van Der Schaaf (8B) ADDITIVE MANUFACTURING OF CATALYST SUPPORT STRUCTURES WITH IN OPERANDO ADJUSTABLE MASS TRANSPORT AND FLOW CHARACTERISTICS............................................3 Sebastian Trunk, Giang Do, Wilhelm Schwieger, Hannsjörg Freund (8C) ROLE OF 3D PRINTED AND LED-DRIVEN PHOTOSTATION IN PHOTOCATALYTIC AND PHOTO-FENTON ACTIVITY OF IRON OXIDE DOPED GRAPHITIC CARBON NITRIDE ........................4 Mathew M. Desipio,