Demystifying Mass Transfer in Electrolyzers Through Rapid Prototyping with 3D Printed Parallel Plate Cells
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Catalysis and Reaction Engineering Division 2019 Held at the 2019 AIChE Annual Meeting Orlando, Florida, USA 10 - 15 November 2019 Volume 1 of 2 ISBN: 978-1-7138-0541-0 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2019) by AIChE All rights reserved. Printed with permission by Curran Associates, Inc. (2020) For permission requests, please contact AIChE at the address below. AIChE 120 Wall Street, FL 23 New York, NY 10005-4020 Phone: (800) 242-4363 Fax: (203) 775-5177 www.aiche.org Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2633 Email: [email protected] Web: www.proceedings.com TABLE OF CONTENTS VOLUME 1 (8A) DEMYSTIFYING MASS TRANSFER IN ELECTROLYZERS THROUGH RAPID PROTOTYPING WITH 3D PRINTED PARALLEL PLATE CELLS ............................................................................1 Stéphane Weusten, Luc Murrer, Mattheus De Groot, John Van Der Schaaf (8B) ADDITIVE MANUFACTURING OF CATALYST SUPPORT STRUCTURES WITH IN OPERANDO ADJUSTABLE MASS TRANSPORT AND FLOW CHARACTERISTICS............................................3 Sebastian Trunk, Giang Do, Wilhelm Schwieger, Hannsjörg Freund (8C) ROLE OF 3D PRINTED AND LED-DRIVEN PHOTOSTATION IN PHOTOCATALYTIC AND PHOTO-FENTON ACTIVITY OF IRON OXIDE DOPED GRAPHITIC CARBON NITRIDE ........................4 Mathew M. Desipio, Dipendu Saha (8D) SOLUTION-BASED 3D PRINTING OF HIERARCHICAL MICROPOROUS POLYMERS FOR ENERGY-EFFICIENT ADSORPTION ....................................................................................................................5 Fengyi Zhang, Yao Ma, Jianshan Liao, Victor Breedveld, Ryan Lively (8E) TITANIUM/TITANIA ELECTROCATALYST FOR HYDROGEN EVOLUTION SYNTHESIZED VIA A COMBINATION OF 3D PRINTING AND ANODIZATION..................................................6 Patricia Taboada-Serrano, Xiang Li, Costas Tsouris (8F) ADVANCED MANUFACTURING ENABLING PROCESS INTENSIFICATION FOR CATALYTIC PROCESSES .................................................................................................................................................7 Matthew S. Ide, Changmin Chun, Anastasios Skoulidas, William A. Lamberti, Dave Dankworth (12A) DEVELOPMENT OF MULTI-ENZYME IMMOBILIZED BIOCATALYTIC PROCESSES FOR SYNTHESIS OF SMALL MOLECULE APIS..........................................................................................................8 Rachel S. Bade, Jacob H. Forstater, Shane T. Grosser, James P. Corry (12B) COMPUTATIONAL EXPLORATION OF PEPTIDE HYDROLYSIS BY SERINE PROTEASE: COMBINED REACTION PATH AND PROCESS VARIABLE ANALYSIS .........................................9 Ashraf Ali, Ashley Caroline Massey, Shounak Datta, Andrew J Adamczyk (12C) COOPERATIVE CATALYSIS FOR SELECTIVE OXIDATION WITH HYBRID GOLD NANOPARTICLE ENZYME MATERIALS.................................................................................................................... 10 Chinmay Verma, Joseph Brindle, Patrick Nelson, Michael M. Nigra (12E) STRUCTURE-BASED PREDICTION AND DESIGN OF POLYPEPTIDE SUBSTRATE SPECIFICITIES OF GLYCOSYLTRANSFERASES ..................................................................................................... 11 Sai Pooja Mahajan, Yashes Srinivasan, Jason Labonte, Matthew P. Delisa, Jeffrey J. Gray (12F) MECHANISTIC STUDY OF GLYCYL RADICAL ENZYME............................................................................ 12 Zhongyue Yang, Heather J. Kulik (12G) STRUCTURE--FUNCTION RELATIONSHIPS IN COOPERATIVE BIOCATALYSIS BY MULTI--ENZYME ASSEMBLIES ................................................................................................................................... 13 Mason Smith, Prabhu Ponnandy, Fei Wen (12H) EXPANDING THE UTILITY OF AMINE DEHYDROGENASES TOWARD THE BIOCATALYTIC PRODUCTION OF CHIRAL AMINES............................................................................................ 14 Robert D. Franklin, Conner Mount, Umair Alvi, Bettina Bommarius, Andreas S. Bommarius (35A) SINGLE-POT HYDROCARBON PRODUCTION FROM AQUEOUS PHASE PYROLYSIS OIL OXYGENATES USING MULTIFUNCTIONAL RED MUD-SUPPORTED NICKEL CATALYSTS ....................................................................................................................................................................... 15 Hossein Jahromi, Foster Agblevor (35B) MAPPING REACTION PATHWAYS OF BIOMASS FAST PYROLYSIS USING ISOTOPICALLY LABELED PLANT CELL CULTURE .............................................................................................. 16 Zhongyu Zhang, Christopher M. Saffron (35C) TURNING FOOD WASTE INTO NITROGEN-DOPED BIO-CARBOCATALYST ........................................ 17 Elvis Ebikade, Dionisios G. Vlachos (35D) COMPARING PYROLYSIS OF D-ARABINOSE AND L-FUCOSE TO D-XYLOSE...................................... 18 Ankush Jain, Arnab Bose, Phillip R. Westmoreland (35E) THE MECHANISM OF XYLOSE PYROLYSIS................................................................................................... 19 Ali Zolghadr, Paul Dauenhauer, Chowdhury Ashraf, Jim Pfaendtner (35F) CORE-SHELL STRUCTURED ZSM-5/MCM-41 CATALYSTS FOR CATALYTIC FAST PYROLYSIS OF BIOMASS............................................................................................................................................... 20 Lei Yu, Oluwole Ajumobi, Vijay T. John, Julia A. Valla (35G) PYROLYSIS KINETICS OF LIVE AND DEAD WILDLAND VEGETATION FROM THE SOUTHERN UNITED STATES ........................................................................................................................................ 22 Elham Amini, Mohammad-Saeed Safdari, Thomas Fletcher, David R. Weise (36A) SINGLE ATOM CATALYSTS SUPPORTED ON DEFECTIVE HEXAGONAL BORON NITRIDE: STABILITY AND ACTIVITY FOR CO OXIDATION ............................................................................... 23 Roberto Schimmenti, Manos Mavrikakis (36B) PT/HBN CATALYST ACTIVITY FOR SYNGAS PRODUCTION: THE ACTIVE ROLE OF HBN ...................................................................................................................................................................................... 24 Leonardo Garro-Mena, Keith Hohn (36C) ELUCIDATING THE SUPPORT EFFECTS OF PEROVSKITE OXIDES FOR THE RATIONAL DESIGN OF SINTER-RESISTANT CATALYSTS................................................................................... 25 Kandis Leslie Abdul-Aziz, Soham Shah, Samuel Sayono (36E) REVISITING EFFECTS OF ALKALI AND ALKALINE EARTH CO-CATION ADDITIVES TO CU/SSZ-13 STANDARD SELECTIVE CATALYTIC REDUCTION CATALYSTS ............................................ 26 Yanran Cui, Yilin Wang, Eric D. Walter, Donghai Mei, Janos Szanyi, Yong Wang, Feng Gao (36F) TWO-DIMENSIONAL TRANSITION METAL CARBIDES AS SUPPORTS FOR TUNING THE CHEMISTRY OF CATALYTIC NANOPARTICLES FOR EFFECTIVE SHALE GAS DEHYDROGENATION ..................................................................................................................................................... 28 Yue Wu (36G) FLAME SPRAY PYROLYSIS DESIGNED DEFECTIVE CATALYSTS FOR CARBON DIOXIDE CONVERSION.................................................................................................................................................. 29 Emma Lovell, Jason Scott, Rose Amal (36H) METHODS OF COATING CERAMIC SUPPORTS WITH CARBON IN THE CASE OF SUPPORTED NI-BASED CATALYSTS FORMULATIONS......................................................................................... 30 Esma Ines Achouri, Nicolas Abatzoglou, Jamal Chaouki (37G) MESSAGE PASSING ATTENTION NETWORKS FOR REACTION RATE ESTIMATION........................ 33 Sai Krishna Sirumalla, Richard H. West (37B) BLUE WHIRL PHENOMENON- A POTENTIAL FUEL FLEXIBLE AND SOOT FREE COMBUSTION ................................................................................................................................................................... 34 Paul M. Anderson, Sampath Gunukula, Dat T. Tran, Ivan C. Lee (37D) DEGRADATION KINETICS OF A LIQUID MINERAL OIL ............................................................................ 35 Arnab Bose, Emily A. Heckard, Phillip R. Westmoreland (37C) PYROLYSIS, LAMINAR FLAME SPEEDS, AND IGNITION DELAY TIMES FOR ISOPROPYL NITRATE..................................................................................................................................................... 36 C. Franklin Goldsmith, Mark Fuller, Nabiha Chaumeix (37E) PREDICTING THE COMBUSTION PROPERTIES OF HYDROFLUOROCARBON (HFC) REFRIGERANTS USING THE AUTOMATED REACTION MECHANISM GENERATOR (RMG) ..................... 37 David Farina Jr., Sai Krishna Sirumalla, Nathan Harms, Richard H. West (37F) PROPANE PYROLYSIS FACILITATED BY PHENYL RADICALS: A COMBINED EXPERIMENTAL AND KINETIC MODELING STUDY ............................................................................................. 39 Peng Yu, Hsi-Wu Wong (37A) PRODUCTION AND SEPARATION OF A LOW FRAGMENTATION THERMAL NAPHTHALENE PITCH................................................................................................................................................... 40 William Lamie, Mark C. Thies (37H) A DFT STUDY OF SO2 BINDING ON CUO OXYGEN CARRIER UNDER CHEMICAL LOOPING WITH OXYGEN UNCOUPLING CONDITIONS. .....................................................................................