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Badger Chemist the Newsletter of the Department of Chemistry at the University of Wisconsin-Madison Badger Chemist The Newsletter of the Department of Chemistry at the University of Wisconsin-Madison Established 1953, No. 57, 2014 BADGER CHEMIST Ten People, Ten Stories Ever since joining the faculty at the University of Wisconsin-Madison 25 years ago, one of the things that has most impressed me is the astounding variety of science, classes, and other activities that happen in our department each day. If you were to explore the Chemistry Building and talk to 10 people, each one might easily tell you a different story about an exciting new research project, a meaningful class experience, a poster or publication in progress, or a new program for students or the community. With this issue of the Badger CONTENTS Chemist, we aim to give you a taste of this great diversity of teaching, research, and outreach. New Badger Chemists .................................... 2 Whether you have fond memories of learning the ins and outs Alumni News ................................................... 4 of the department’s chemical instruments (page 15), you want to Chemistry News .............................................. 5 find out the latest update on the Chemistry Building Project (page Awards and Honors ....................................... 11 Features ......................................................... 15 6), you’re curious what chemistry majors are learning in the lab Shakhashiri ACS Presidency Reflections ...... 19 these days (page 17), or you want to meet our newest professor New Faculty Profile ....................................... 20 (page 20) or professor emeritus (page 29), we hope these pages ICE ................................................................. 21 will help keep you informed and engaged with your many fellow WISL .............................................................. 23 In Memoriam ................................................. 25 Badger Chemists. Professor Hans Reich Retirement ................. 29 ___________________________________ Finally, if we haven’t seen you in a while, we’d love to catch Badger Chemist is an annual publication for up with you. Join us for a department reception at one of the alumni and friends of the Department of Chemistry ACS National Meetings, stop by for a visit next time you’re at the University of Wisconsin-Madison. in Madison, or attend a special event like the upcoming Reich Executive Editor Celebration Symposium (see page 30 for details). Matt Sanders, [email protected] With very best regards, Managing Editor Libby Dowdall, [email protected] Contributing Writers Grace Pham, [email protected] Rachel Schulze, [email protected] Robert J. McMahon To update your contact information, visit Helfaer Professor and Chair ls.wisc.edu/update.html. [email protected] Please send items for Badger Chemist to [email protected]. PS: Visit go.wisc.edu/stories to meet a few of the many unique 1101 University Ave., Madison, WI 53706 608.262.1483 students who help make the Department of Chemistry a great place. ©2014 Board of Regents of the University of Wisconsin System BADGER CHEMIST New Badger Chemists Ph.D. DECEMBER 2012 Lisa Johnson (Gellman) Development of Alpha/beta Peptides as Fusion Inhibitors of HIV and Agonists of Glucagon-Like Peptide-1 Receptor (GLP-1R) Aaron Almeida (Gellman) Insight into Protein Structure Using Parallel Beta-Sheet Model Peptides Alexander Clemens (Burke) Synthesis of Garner’s Aldehyde and Efforts Toward the Synthesis of Tapentadol via an Asymmetric Hydroformylation/Reductive Amination Sequence Based Approaches for the Control of Amelia Peterson (Coon) Robert Cunningham (Li) Bacterial Biofilms Application of the Orbitrap Mass Mass Spectrometry Applications Daria Fedyukina (Cavagnero) Analyzer to Targeted Proteomics for Comparative Proteomics and Role of Long-Range Interactions and and Gas Chromatography/Mass Peptidomic Discovery Ribosomal Electrostatics In Protein Spectrometry of Small Molecules Tianning Diao (Stahl) Folding Roberto Risi (Burke) Palladium-Catalyzed Aerobic Katherine Paulsen (Burstyn) Development and Applications Alpha,beta-Dehydrogenation of Investigating the Diverse Role of of Asymmetric Hydroformylation Carbonyl Compounds: Method Metals in Protein Structure and Tandem Reactions: The Total Development and Mechanistic Study Function Syntheses of (+)-Patulolide C, Robert Sturm (Li) Emily Guinn (Record) (-)-Pyrenophorol, (+)-Decarestrictine Mass Spectrometry Method Developing Solutes as Quantitative L and (+)-Prelog-Djerassi Lactone Development for Targeted and Probes of Protein and Nucleic Acid Danielle Stacy (Blackwell) Discovery Neuroproteomics and Processes Design, Synthesis, and Biological Peptidomics Craig Gutman (Brunold) Evaluation of Small Molecule and Craig Tainter (Skinner) Exploring the Mechanisms of Redox Peptide Quorum Sensing Modulators Three-Body Interactions, Structure and Potential Tuning and Substrate/ Kevin Williamson (Yoon) OH-Stretch Spectroscopy of the Water active-Site Interactions in Iron- and Regio- and Stereoselective Hexamer and Amorphous Solid Water Manganese-Bound Superoxide Oxyamination of Olefins with Gene Wong (Landis) Dismutases and Synthetic Analogues N-Sulfonyl Oxaziridines Rhodium-Catalyzed Asymmetric Samuel Henry (Keutsch) AUGUST 2013 Hydroformylation of Alkenes Using A Novel Detection Method of Adam Dunkelberger (Crim) Diazaphospholane Ligands and Glyoxal and Application of Glyoxal Photoisomerization Dynamics of Application With Wittig Olefination Measurements to Studies of Candidate Molecules for Vibrational Photochemically Driven Atmospheric MAY 2013 Control Experiments Oxidation Michelle Benson (Hamers) Emily Dunkelberger (Zanni) Samira Musah (Kiessling) Synthesis of Stable Interfaces on Using Two-Dimensional Infrared Synthetic Substrata to Instruct SnO2 Surfaces for Charge-Transfer Spectroscopy as a Tool for Studying Human Pluripotent Stem Cell Fate: Applications Amyloid and Membrane Proteins From Novel Ligands to Functional Anthony Breitbach (Blackwell) Biomaterials Puja Goyal (Cui) Novel Chemical- and Materials- The Proton Pumping Mechanism of chem.wisc.edu 2 BADGER CHEMIST Cytochrome c Oxidase: Insights from Hynes, Kieran Andrew B.S. and B.A. QM/MM Simulations Jones, Amy Elizabeth Kristy Kounovsky-Shafer (Schwartz) Kammerer, Bradley William Development of Nanoconfinement DECEMBER 2012 Kerlin, Kelly Jean Systems for Genomic Analysis Hinrichs, Gergana I. Kim, Yuyong Dongxu Shu (Tang) Izhar, Izarin Izmir Bin Kotecki, Shawn Thomas Rhodium and Platinum Catalyzed Meinig, Arthur Joshua Kwiatkowski, Anthony Carl Cycloadditions from Propargylic Sesing, Nicholas R. Lauder, Travis Beck Esters and Ethers Shin, Sanghun Leskinen, Heather Lee Nicole Woodards (Li) Steinhoff, Nicholas Charles Mehan, Alexandra Christina Mass Spectral Analysis of Crustacean Weis, Matthew Anthony Melcher, August Michael Signaling Peptides Using a Multi- Moua, James Dimensional Strategy Niemeyer, Zachary Louis MAY 2013 Plant, Isaac Nathan Justin Wiens (Nathanson) Alexander III, Robert Charles Ristow, Jacob Jeffrey The Chemistry of Solvated Electrons Bean, Jero M. Russell, Damian Simon at the Vacuum–Glycerol Interface Burchardt, Kaitlyn Henrietta Sauter, Mark S. Joseph Yeager (Hamers) Cai, Wenting Schellenberg, Jonathan Tomsic Surface Chemistry of Silicon Anodes Chew, Kit Shawn Snyder, Gretchen Ann for Next-Generation Lithium and Chow, Clara Chiting Syed, Anoushka Nadeem Lithium-Ion Batteries Cleland, Spencer Carl Urbain, Lucas T. Kuang Yu (Schmidt) Conway, Caitlin Ann Veldre, Kiley Marie First Principles Studies of Gas DeBoth, Gwendolyn Annette Walters, Megan Marie Adsorption in Metal Organic DeCloux, Kyle Steven Wiensch, Eric Michael Frameworks Degregorio, Zachary Patrick Wood, Emily Rose Derus, Tyler Stephen Yang, Tzuhsiung Drake, Ryan James Frankiewicz, Amanda Rae He, Shushan AUGUST 2013 Heitkamp, Claire Olivia Karraker, Sara Nicole Hetue, Robert Gregory Menden, Patrick Robert Porubsky, Nicholas James Stay in Touch with Your Fellow Badger Chemists Find out news about the department and upcoming alumni events by signing up for Chemistry Alumni E-News. Visit go.wisc.edu/alumnienews to sign up today! Connect with fellow alumni by joining our Department of Chemistry Alumni group on LinkedIn by visiting go.wisc.edu/chemalumni. Find us on Facebook: facebook.com/UWMadisonChem Follow us on Twitter: twitter.com/UWMadisonChem 3 University of Wisconsin-Madison Department of Chemistry BADGER CHEMIST Alumni News Buchanan (Ph.D. ’13, Zanni), a second-generation UW- Reich Group Reunites at ACS Meeting to Honor Madison chemistry graduate student (see photo above). Reich’s 70th Birthday Professor Hans Reich and past Reich group members met Leslie Klevay (B.S. ’56) has received the Medical Alumni for dinner at a recent ACS National Meeting to celebrate Citation Award from the UW-Madison School of Medicine and the occasion of Reich’s 70th birthday. In attendance were Public Health in recognition of his distinguished achievements (from left to right in photo above) Marty Cohen (Ph.D. in medical practice, academics, and research. Klevay is ’79), Nathan Haese (Ph.D. ’80, Woods), Ieva Reich, Martha published widely on the health benefits of dietary copper. Kelly (Ph.D. ’83), Robert Dykstra (Ph.D. ’93), Sue Wollowitz (Ph.D. ’80), Steve Peake (Ph.D. ’79 ), Amanda Jones (Ph.D. In the fall, Michael Konopka (Ph.D. ’06, Weisshaar) became ’07), and Hans Reich. an assistant professor of chemistry at the University of Akron. He previously served as a postdoc in Professor Mary ACS Honors Djerassi at National Meeting
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